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Permit B93-0162 - CHEMICAL WASTE MANAGEMENT - PARTITIONS, DOORS, ADA RESTROOM AND RAMP
i C4rnICAL WASTE rnw\clevi ekrT; .11\JC•_ CERTIFICATE OF OCCUPANCY OCCUPANCY .• • • I , • • ,, • „ . , • • • •, 63,00 ::SOUTACENTER:-BOULEVARD'; - 100 TUKWI LA KINGTON 98188 • . , ..• THIS CERTIFICATE.:•I UNIFORM BU.ILDXN,G ..•.:..wAt:;144;3;compLy4N, :ROA:0A gGOAREti SE. CERT11041,,Nart,T THAT .ftt. THE.),(IME1 0Alid TflE VAR.I.OUS '.00.111;q1katadEtti3OF0 TI-t CZ1Y ' Ed • ArPfACABb CITY FIRE*OgDES Ten 1(11,64..:A• 307 OF THE IS STRUCTURE ING. BUILDING FOLLOWING: CHEMICJf%L WAST.EHA GEMp1i INC Per1t A opvt*:PK. E Su i eft. N 230449.0, �4EItHOLD-- .. 1.' , I v • , •, • „ 'it, ,. ... ,,, ,, ri • :'.. , 190e of :*kgri os04 4.00i1.6 '-';(.PF, ig,51''''':"1:7 ' . 0 d OM Rtirt14iL a ''' t .,, k. . ,n •o,, , „ .,: ':' '` ,,. ...' • .-,:', ',. . ' t ft ' ,v• • • . „ • , • • (Aie 0111110144 Community Development / Public Works • 6300 Southcenter Boulevard, Suite 100 • Tukwila, Washington 98188 BUILDING PERMIT (206) 431 -3670 Permit No: B93 -0162 Type: B -BUILD Category: ACOM Address: 1120 ANDOVER PK E Location: Parcel #: 262304 -9098 Zoning: CM Type Const: III -N Gas /Elec: Wetlands: Water: N/A Contractor License No.: SEATTCR101BZ Status: ISSUED Issued: 05/24/1993 Expires: 11/20/1993 Type of Occupancy: OFFICE Slopes: N Sewer: N/A TENANT CHEMICAL WASTE MANAGEMENT, INC. 1120 ANDOVER PK E, TUKWILA, WA 98188 OWNER . LEUTHOLD DONALD W _ 1120 ANDOVER PARK;E, ::7UKWILA'`WA'°9818 CONTRACTOR SEATTLE CONSTRUCTION RESOURCES.. 413 3RD AVENUE'' WEST°;,., 5;EATTLE, WA 9811,9 CONTACT 'DAVID LEWIS" • 119 PI-NESTREET:.;,, SE'ATTLE, WA 98101 -hone: 206 282 -7500 Phone:. 206 223 -4999 **** * * * * * * * * *, ** ** * *. *'* * ** ** * ** *' aka * * *.* * ** sir****• k*.*** ** ** * *.** * * *.* *** *** * ** * **** Permit Descripfion: ADD 4RtITIONS AND DOORS \'.HAF DICAPRESTROOM AND SETBACKS`'., Units: 001 `' _.w Front. 0 Back` Bui 1 ding��s 001 �..:n Le`F;t: :., 0. Right Fire Protection ,' �;.. :.r ti '..:.. UBC Edi i;`1.on: 1991 . <.... R? �' Valuation: r, , 00Y0'\ 00 624,d60 ' ' rTota1 .Permit Fee: ******* 0,,***** k***;***,**.****, t4*,* ik** 4****,o**, kli **_ * "* * * * * * * * ** * " * * * * * *,* * *: *: * * * ** Permit Center Au;tho ized Signature I hereby tcert i Fy "that I have read and examined� th j s ,permi t anal ,knew the same to b`e;� trti`e and correct. All prov=is j'ons 'of, :law.; and ord.i,nanc.es', governing ° =th`is' "w'ork will be complied ,with, .wh.ether specified her,eth or not The granting4<of this permit does not•°presume` tn`'give authority to violate or cancel they +p;rov,isions of any other state or ;local laws regulating construction off4he per;form7nce' o,f,:vggrk., .,I :sin` authorized 0-!:Sign for and obtain this build1 permi� Signature: Print Name: *K-F ./t q3 This permit shall become null and void °` "if " °` :the .work .is not commenced within 180 days, from the date of :issuance, or Af the work As suspended or abandoned for a period of 180 days from the last inspection. CITY OF TUKWI Department of coTtanunity Development — Permit Cente " 6300 Southcenter Boulevard - #100, Tukwila, WA 98188 (206) 431 -3670 • Building Permit Application Tracking PLAN CHECK NUMBER 69'3- olucp PROJECT NAME Ch. ?xr\i C O% ,1 Q OAD-M -2 SITE ADDRESS SUIT O. I \moo C\ \fey Pk - INSTRUCTIONS TO STAFF • Contacts with applicants or requests for information should be summarized in writing by staff so that the status of the project may be ascertained at any time. • Plan corrections shall be completed and approved prior to sending to the next department. • Any conditions or requirements for the permit shall be noted in the Sierra system or summarized concisely in the form of a formal letter or memo, which will be attached to the permit. • Please fill out your section of the tracking chart completely. Where information requested is not applicable, so note by using "N /A ", date and initial. DEPARTMENTAL REVIEW "X" in box indicates which departments need to review the project. PARTME DATE PROV! .UIREMENT$ INTENTS ....................... BUILDING - initial review FIRE • PLANNING UBLIC WORKS N�A 3R 5 ( 93K.. CONSULTANT: Date Sent - (ROUTED) &jI ig(ri) INIT: t FIRE PROTECTION: FIRE DEPT. LETTER DATED: Date Approved - prinkiers 0 Detectors N/A INIT: ZONING: REFERENC FIL NOS.: MINIMUM SETBACKS: N- 3 UTILITY PERMITS REQUIRED? I 9 / 5?, INSPECTOR: S //'j.- BAR/LAND USE CONDITIONS? INIT: PUBLIC WORKS LETTER DATED: s- E- .VENN Yes ■ No O OTHER BUILDING - final review /q3 'BUILDING OFFICIAL TYPE OF CONSTRUCTION: INIT: CERT. OF OCCUPANCY? Yes O No UBC EDITION (year): ic111 REVIEW COMPLETED AMOUNT OWING: CONTACTED DATE NOTIFIED BY: (init.) 2nd NOTIFICATION BY: (init.) 3RD NOTIFICATION BY: (init.) 01/08/93 CITY OF TUKWILA Department of Community Development - Building Division 6300 Southcenter Boulevard, Tukwila WA 98188 (206) 431 -3670 BUILDIkG PERMIT APPLICATION PLAN CHECK e3-o1 I NUMBER DESCRIPTION ": AN40UNT BUILDING. PERMIT FEE PLAN CHECK FEE BUILDING SURCHARGE :; • •:RCPT#. DATE: OTHER: TOTAL'' SITE ADDRE 1 i 20 ge-ei' SUITE # 12 1 VALUE OF C NSTRUCTION - $ 5) PR JECT MeitA NAME/TENANT , 0 1 lVi OF • New Building 0 Rack Storage meAr 1 , 0 Addition , Tenant Improvement 0 Reroof Remodel (residential) 7O 2 'fi'l PICf1F i ACCOUNT # @ L2a30 t-I - CiOn (commercial) U Demolition (building) 0 Other TYPE WORK: DESCRIBE WORK TO BE DONE: AAPP PA TS I � .P�11 j BUILDING USE (office, warehouse, etc.) �( LUA OctSi�✓ NATURE OF BUSINESS: 4 , . ° C91c WILL THERE BE A CHANGE IN USE? ,64 No 0 Yes If Yes, new building requirements may need to be met. Please explain: SQUARE FOOTAGE - Building: '90 Tenant Space: Area of Construction: 'Ica) WILL THERE BE STORAGE OR USE OF FLAMMABLE, COMBUSTIBLE OR HAZARDOUS MATERIALS IN THE BUILDING? 0 No 0 Yes IF YES, EXPLAIN: PROPERTY OWNER. it # yI, . :i,rL9 1 r._.,�„_ PHONE y iG,1,,,(,,� ADDRESS 257 t� 4 ' "'''' J1 pe_L-i' I o „' n 1j JT1 PHONE /2e/2_0 ZIP( �'�G�-GV CONTRACTOR C 1 o .��,nties5TR -t�. j 2e �,,,4r ., ��- f� ��-t �.300 .�` -4-�� -C6 ADDRESS r �d �- t -- .,- _,._,A ail ... � . EXP. DATE G ZIP im (C WA. ST. CONTRA TOR'S LICENSE # ARCHITECT y - PHONE S'411C1 ADDRESS 11a. 43..� 1 1 . v 1- '� 4 (i) • ZIP C �LC� 1 IIEREBY;,CERTIF:Y :THAT 1: BE TRUE:AND;CORRECT . BUILDING OWNER OR AUTHORIZED :HAVE:READ AND :EXAMINED: THIS APPLICATION:' :A ORIZFED` :APPLY. FOR :THIS P,IERMI. PHONE //z5 �gcc7 CITY/7_I A 50( PHONE a F AGENT ADDRESS CONTACT PERSON APPLICATION SUBMITTAL In order to ensure that your application is accepted for plan review, please make sure to fill out the application completely and follow the plan submittal checklist on the reverse side of this form. Handouts are available at the Building counter which provide more detailed information on application and plan submittal requirements. Application and plans must be complete in order to be accepted for plan review. VALUATION OF CONSTRUCTION Valuation for new construction and additions are calculated by the Department of Community Development prior to application submittal. Contact the Permit Coordinator at 431 -3670 prior to submitting application. In all cases, a valuation amount should be entered by the applicant. This figure will be reviewed and is subject to possible revision by the Building Division to comply with current fee schedules. BUILDING OWNER / AUTHORIZED AGENT If the applicant is other than the owner, registered architect/engineer, or contractor licensed by the State of Washington, a notarized letter from the property owner authorizing the agent to submit this permit application and obtain the permit will be required as part of this submittal. EXPIRATION OF PLAN REVIEW Applications for which no permit is issued within 180 days following the date of application shall expire by limitations. The building official may extend the time for action by the applicant for a period not exceeding 180 days upon written request by the applicant as defined in Section 304(d) of the Uniform Building Code (current edition). No application shall be extended more than once. if you have any questions about our process or plan submittal requirements, please contact the Department.pf Community Development Building Division at 431 -3670. DATE APPLICATION ACCEPTED DATE APPLICATION EXPIRES 03/16/91 COMMERCIAL SUBMITTAL CHECKLIST NEW COMMERCIAL BUILDINGS /ADDITIONS Completed building permit application Assossor Account Number • Two sets (2) of the following Specifications �' Structural calculations •stamped by a .Washington State licensed .,` engineer I J Soils roporl stamped by a Washington Stateliconsed engineer Topographical survey I Energy calculations stamped by a Washington State liconsed: engineer or architect ... L..J Legat description Working drawings, stamped by a Washington State licensed'' architect, .which include Siteplan • Architectural drawings •.Structural drawings Mechanical drawings • • Civil drawings Landscape plan Completed utility permit application [1 Six.(6) sets of civil drawings one for entire project COMMERCIAL TENANT IMPROVEMENTS r i Completed building permit application (one for each structure tenant) .:; Asiessof Account Number Two (2) sets of constructon pians.whlch include . , , �. Site plan • Locabon of tenant space •: Exist rig and proposod parking • Landscape, plan (if applicable, i e , change of, use) Ovoraf building plan Tenant location '.Use of adjacent (common wail) tenant Overall dimensions of building orsquare footage plan of propos tenant space • Tenant space ed plan with use'of each :room labelled :Exit doors ,ogress:patterns • ;New walls ; oxisting wall, and walis;to be demolished:' Construction details Cross sections showing wall •construction. and method of attachment tor;floor and;cefling n Structural calculators stamped by a Washington State licensed: engineer m ay. be required if structural work is to be done (2 sets) NOTE IJ any udhty work J� to be done; submitsoparate' uNGtypermit ; application, and plans: NOTE :Seeutllity permit application and.checklist for peoitic •utili ^ubmitta/ roquirements RACK STORAGE Completed :building, permit application Assessor Account: Number :. Two (2) seta :of.... plans which include:. 11' Building floor plan showing it •.Entiire.space,where:racks Will be located Exit doors . Dimensions of all:aisles Tonant space floor: plan showing rack storage layout; aisles an ';exits NOTE' include: dimensions of racks (height, :width and length), aisles:: :. and exit ways on plan, 'Structural calculations stamped by a Washington State licensed; engineer (rack storage 8', and ovor) REROOF ;: Completed building perrnit apphcatlon (one for each :Assessor. Account Number ('Narrative describing existing roof materiai:being . 'materiai;being.installed.:: NOTE A cert�fication.Jotter Js required prior to :final Inspection and sig off of the pormlt ANTENNA/SATELLITE DISHES. • Completed building permit application Assessor Account Number Two (2) sets of plans, which include 11 :Site Plan (sho■ing building and location of antennalsatellite dish Details antenna/satellite dish and method of attachment: RESIDENTIAL NEW SINGLE: FAMILY:: DWELLINGSIADDITIONS: Completed building permit application (one. for each structure Legal description:. RESIDENTIAL REMODELS Li Completed building permit application •Assessor Account Number Assessor Account Number; one for each structure ::Two (2):sets of working drawings,'which inciu •Site plan •:•oundation plan Floor plan Roof plan Building :elevations (alt views :Building cross section tructural framing plans NOTE if any utthty work is to be done provide utility permit appticatlol and plan¢ must be submitted::. ....:, : :... Two sets(2) of working drawings; :which include, • Site,plan (pit plan; &how closest hydranrlocafion Foundation plan Induda:access to b "ullding showing Floor plan .: wldth and length of across j:; .:Roof plan • Building elevations (ail views .Building cross section Structural•framing plans.;. 11 Washington:State,Energy Code data Completed utility permit application Six (6) sets of site plans showing utilities' NOTE: Building site plan and utility site plan may bo combined, Sae • utility permit application and checklist forspecific submittal requf remains Addtfional topographical and soils informat on may be roquusd if unique site conditions.: • REROOFS' Completed bulldintj permit application Assessor Account Numb "e Narrative describing existing roo, material being installed; NOTE, A crirtipcatlon, letter Js required, prlor to final Inspection and si • </of of the permlt. . fort ?ash being remove n.' 4,44c;.0,L.;4•Ick..k,.**Lif,L4c* * ft Is, 4*******Or**.A***•,,,!***.• '. • • . • :TRANSMIT GENERA 30.00 leif*i4i***,!ilif;,v4,*ii.**.#4!40*****)Oi,it**442****4'es'irk...40,.A.4v,*.*"..k* •i TOFAL 30.00 L••.' ''.• -.:.•36000.-631Q.1./94"...16100—• • - • • • . " • . • • • • • ' • • • L CHANGE LOU'''. 0162,L,- Type: • • . CASH 30.00 ••• • •, •• • ... • • • • . • - • u4/94 :'••••• • , - • .'"9617A000 "' • ". Site ddres: 1120 ANDOVER E • ••• • , „', ';•, • •, ,",', ,'„ •••• M0 h H. CHEMICAL . ..• " 4,4 -,.'-iioiv..4..ir''.4.44';'44:...k***,7k,i,*••*.t,t..,**.if,!,,*..*.4:1., FV066(iiii: /C0 Toial Fees: 64.0 • rsiiy • .• • ••• 0. WI 11.1 .464 ..... OMR G. W* le* 'W.* WI OW SW• WO ■W •W‘ V* • • .0 WM WO OW .. .. IW• ■•• ••• W., In./ MI. •••• •••• • , • - . ,„ . • , . „ . . ,,.. ,, .-.-. . ", ,, - - - - • - - : ' ' '''''; ' - . , . . , . , . .. , ,. , .. , .. - ,. „ ',, ,.., ....., ,.. , , . ', . , , ,.. .'. •• „...,....,.;,.....,. ... - ". , -".",,:, " ., " , . .. . ":. , ", ',.. " ,", . .,`„""" ; • '' . , .. „ - , ., , . ,.,,, ',• - . ": . - , , • •,, , •,:, ' . .. '. ,.., •• • C . .'„ • , ,.., . .. ., . , . ,., • , .:,• '. •.: . ,."....•, ,',-...• '1,.. .,„ . , , .. • . . * * *. * ** .h'*4'•h4k * *** * *kik. * * *�F_ *h. ** kh * :� **:** * *kk * ** *:4004. ** * * **. * **• :,44fir * *. CITY OF 'TUKWI L A,. WA TRF1N91411•2: * * * *** * " k* 'k ** • . k _ * * • ANSMIT .Number t)0 c�53�:Aauri,ar 23.4.00. US124 g /4 � Permit' N0 093 01.62 P.arcal 'flat: .2't,2304 -9096, ..Addr'eas; 11:20. AN! ow..:ft ::Plt H Payme,rt`Me'i.Mod: CHECK ': Nota i "arh: ,RH TT ORY]EL.I� 'Xniti': DLM:. * * * *k *' *,h * * *k *.* *k* *; * k * *k *k *kkkk * * *. *: *. * * * *** * * *:4* *: *kk * Account`' Cade :` Deecr i pt i aM GENERA 234.00,:: TOTAL'. 234.00;" CHECK 234.00 CHANGE 0.00:; 0945A000 15 :03 ;' Pp.l,d. • • 0.00/3`22:.100 9.UILDI "NG ' NONRC ,. 234` »00 ,Tatal' (TMfa Paymerit> Total : Fees:: ' 624.60 All Payments: 624.6'0 0 a1 ance: .00 rem. k************, k+ E, k******************: 4** *•A. * * * * ** * * * * * *k* * * *k * * * * * ** CXTY OF TUKW1LA, -WA TRANSMIT ' ****************** k************ k*; 4* *h*** * *** * * *k * ** * * * ** * * * *k* ** TRANSMIT, Number^: 93000577 Art : s � �a.6a (35 /07rMAG)351 Permit No y 1393-0162" : Type: B.-BUILD HUILDXNG PERMIT Par�ce1 Na • 262304 -9003 Site Address. 1120 ANDOVER PK E Payment 'Method': CHECK Notation: EMICK HOWARD NEL. Xnita 5Lp,; **•**** k************, k****•************** * * * * * * * * *** * **hk * * * * * ** 'Account Code Description Paid 000/322.1.00 BUILDING .. NONRC8 234.00 :000/345.83.0 PLAN CHECK - NCINRC:3 152.10 000/3136.904 STATE BUILDING SURCHARGE 4.50: Total (This Payment) t 390.60.' GENERA TOTAL CHECK • 390.60 390.60: 390.60 CHANGE 0.00 0492A000 15 :09 Total Fees: 390.60 A11. Pgtyment a 390. 6.0. 13e110cgt .00 CITY OF TUKWILA Address: 1120 ANDOVER PK E Permit No: B93 -0162 Tenant,: CHEMICAL WASTE MANAGEMENT, INC. Status: ISSUED Type: B -BUILD Applied: 05/07/1993 Parcel #: 262304 -9098 Issued: 05/24/1993 ********'******** * * * **'k * * * * *•k * * * * * * *•k *•k * •k *•k* k * * * * * * * * * * * * ** * * * * * * * *•k* * * ** k ** Permit Conditions: --,_.� �._,.._. _ 1 . 1 . AREA DEVOTED TO ,S(JC�H, STORAGE SHALL ' "NOT..,E,XCEEQ 400 SQ. ET OF THE TOTAL AREA-.t bE, THir WAREHOUSE .� _. . 2. 2. CUSTOMERS WH1L°H 'USE z.CWMI' S WASTE{, {CONSOLIDATION "'SERVICE SHALL NOT EXrcEE g�MORE THAN' =48D:,a.F::�:Ct1MXS TOTAL CUSTOMERS SERV ED BY THE rTUK;W'XLAa SIZE, „ ,' ,' <{ itr;v, ,y '', ; 3. SUCH STORA(aE/ANDD NANO.. I`NG��SHALL!'` NOT'PROVI,DE REVENUES F 17;,47 r✓ 4. 4. STORAgpi AND' TR}ANySPORT SHALL '�•,MEET, AT A MINIMUM, 'FEDERAL SAFETY�r'STANDARDS'i FOR SUCH ACTIVITIES PER WAC 173 - 303:,- '`'''" `,., 5. No changes"w,.i 11 be, made'.to th "e p1art,s" unless approved by,= -the `• Arch tect.'land the'Tukwlla Bu4ding' Division. 6. P 1 umb.itng,,;,permi tsha l 1 be obta, ,ned- through the Seatt,l a K'1,:‘,''. ng Couri•ty' Department of Pith l'i.c H'ealth., Plumbing will l,e , 'Pay, ins e ted«,by that agency,. inci1udinga a;i'1`ga;s piping n, (29' - 722) . i' h? r.,, ? i ,' .t j 7. E l eic t,r i ca 1 }per�'m;it_f�sha i•1 ...he 1ok tali rnediitfhrough ::the Wash:::'' ng St Division cif Labor an. °�Industri s.'and "-':a :l1 electicaj' work wi l i :be lnspected_'`rb;v lt`a`,t,�age'ncy (248 -6657) rx:t vi �k, f K,ti 8. A11' mechanica1` wotrs kl�shal ,l1be:'un`aer,.,separate' permit trough the .Qr�i ty ofh. f u.: ;.r ..A',.., n ,,:t. , % c Tukwila '.',.. „,,.. ,,. „,r `'r, .\ �;', ,,:..:w• I.. t`•., . ,r..,, - 4, j a ., 4 A /` w, , 9. All Aikrm,itsi� ii,spection records, a4rtd .apprroved.f.plens 'shall b main'�tyained % °� 'vai 14ab1e at the Job i'te'priaor to the sir`ar:4‘'''' . ,o any co, st uttiyi�on. These documents'' ocumen sr' ai`...e •.to'�.be'~ a�intayine. „,. avai Pa,b'1et u,ntl 1 final inspection Japprovail is,,. granted. ,:p4 10. Any ne; ' ei 1 ing grid and 1 fight f.1, tu`re,/lnstal�l�at.ibn is requir d"to meet lat�era1 bracing, a ui /h erj,ts "'°for Se,i,smic Zone 3 �. �,,� �� �...� q ��. �. 11. .Partition'.'w i1s''l /iat'tache�d''et�o cei1ing grid, must be l`ateral' braced if °o et: eight (8) feet i nl ;length`: o''i't"x` '` 12. Any exposed`,16insulations backing materia1 shall have e :Flame Spread Rating of5 or 1ess '.a.riel4 material shall bf,e.' .i°denti- f ication showirig: �` � ��ie., f ire pe�•for*N�nC�i rating ng there;psi•" 13. Notify the City of: Tukwila Bui ildirhg'Divisi,pn:'p.'.l.or" to placing any concrete: h1s pr4oce.durer.1s iIrs= "a "ddition to any requirements for special am' °`iri' pe.cti , `^ ,s — 14. All rack storage requires a separate permit through the City of Tukwila. Structural calculations stamped by a Washington State licensed Structural Engineer are required for rack storage over eight (8) feet in height, 15. There shall be no occupancy of the bui1ding(s) unti1 the final inspection has been completed by the Tukwila Sul lding Inspector. 16. A CERTIFICATE OF OCCUPANCY WILL BE REQUIRED FOR THIS PERMIT. 17. This tenant space has been classified as a Group 8, Div.2 occupancy for the intended use provided that the hazardous materials to be stored in each of three "control areas" does not exceed the exempt amounts listed in U.B.C. table 9 -A & 9 -8. Storage in excess of these amounts in any control area voids this bu'Ilding classification and this permit approval. 18. Validity of Permit. The issuance of a permit or approval of ..1...... ........Art ,....a.1...... .....A . a.,r J _ -.L.-11 ._._.. a_ - -_ strued• to be. a 'permit for,' an approval of any .Violation of any of. the provisions of this code or of any other ordinance of the j sdiction. .No permit pres('ing togive authority or violate or cancel the provisions or this code shall be valid. City f Tukwila FIRE DEPARTMENT 444 Andover Park East Tukwila, Washington 98188 -7661 (206) 575 -4404 Fire Department Review Control #B93 -0162 (512) John W. Rants, Mayor May 19, 1993 Re: Chemical Waste Management - 1120 Andover. Park East Dear Sir: The attached set of building plans have been reviewed by The Fire Prevention Bureau and are acceptable with the following concerns: 1. The total number of fire extinguishers required for your establishment is calculated at one extinguisher for each 3000 sq. ft. of area. The extinguisher(s) should be of the "All Purpose" (2A, 10B:C) dry chemical type. Travel distance to any fire extinguisher must be 75' or less. (NFPA 10, 3 -1.1) Extinguishers shall be installed on the hangers or in the brackets supplied, mounted in cabinets, or set on shelves (NFPA 10, 1 -6.9), and shall be installed so that the top of the extinguisher is not more than 5 feet above the floor. (NFPA 10, 1 -6.9) Extinguishers shall be located so as to be in plain view (if at all possible), or if not in plain view, they shall be identified with a sign stating, "Fire Extinguisher ", with an arrow pointing to the unit. (NFPA 10, 1 -6.3), (UFO 10.505A) Clear access to fire extinguishers is required at all times. They may not be hidden or obstructed. (NFPA 10, 1 -6.5) Fire extinguishers require monthly and yearly inspections. They must have a tag or label securely attached that indicates the month and year that the inspection was performed and shall identify the company or person performing the service. (NFPA 10, City f Tukwila FIRE DEPARTMENT 444 Andover Park East Tukwila, Washington 98188-7661 (206) 575 -4404 Page number 2 John W. Rants, Mayor 4 -3, 4 -4 and 4 -4.3) Every six years, dry chemical and halon type fire extinguishers shall be emptied and subjected to the applicable recharge procedures. (NFPA 10, 4 -4.1) If the required monthly and yearly inspections of the fire extinguisher(s) are not accomplished or the inspection tag is not completed, a reputable fire extinguisher service company will be required to conduct these required surveys. (NFPA 10A -4 -4) 2. No point in a sprinklered building may be more than 200 feet from an exit, measured along the path of travel. (UBC 3303(d)) Exit doors shall be openable from the inside without the use of a key or any special knowledge or effort. Exit doors shall not be locked, chained, bolted, barred, latched or otherwise rendered unusable. All locking devices shall be of an approved type. (UFC 12.106(c)) Obstructions, including storage, shall not be placed in the required width of an exit, except projections as permitted by the Building Code. Exits shall not be obstructed in any manner and shall remain free of any material or matter where its presence would obstruct or render the exit hazardous. (UFC 12.104(a)) Dead bolts are not allowed on auxiliary exit doors unless the dead bolt is automatically retracted when the door handle'is engaged from inside the tenant space. Exit hardware and marking shall meet the requirements of the Uniform Fire Code. (UFC 12.106 - 12.111) Gates and barriers shall be openable without the use of a key or any special knowledge or effort. Gates and barriers in an exit shall not be locked, chained, bolted, barred, latched or otherwise rendered unopenable at times when the building or area served Cit ::' f Tukwila FIRE DEPARTMENT 444 Andover Park East Tukwila, Washington 98188 -7661 (206) 575 -4404 Page number 3 by the exit is occupied. (UFC 12.107(b)) John W. Rants, Mayor Gates and barriers installed across an exit shall be of sufficient size as to be capable of opening so that the clear width of the opening is not less than the exit width required by the Building Code. (UFC 12.107(c)) When two or more exits from a story are required, exit signs shall be installed at the required exits and where otherwise necessary to clearly indicate the direction of egress. (UBC 3314(A)) Manually operated edge or surface mounted flush bolts and surface bolts are prohibited. (UFC 12.106(c)) 3. All new sprinkler systems and all modifications to existing sprinkler systems shall have fire department review and approval of drawings prior to installation or modification. New sprinkler systems and all modifications to sprinkler systems involving more than 50 heads shall have the written approval of the W.S.R.B., Factory Mutual, Industrial Risk Insurers, Kemper or any other representative designated and /or recognized by The City of Tukwila, prior to submittal to the Tukwila Fire Prevention Bureau. No sprinkler work shall commence without approved drawings. (City Ordinance #1646) Contact The Tukwila Fire Prevention Bureau to witness all required inspections and tests. (UFC 10.503) (City Ordinance 01646) 4. Satisfactory provisions shall be made for containing or neutralizing spills or leakage of hazardous materials. (UFC 80.301(L)) Material safety data sheets for all hazardous materials on the premise shall be readily available on site for emergency personnel. (UFC 80.106) Visible hazard identification signs shall be placed at City ®f Tukwila FIRE DEPARTMENT 444 Andover Park East Tukwila, Washington 98188 -7661 (206) 575 -4404 Page number 4 John W. Rants, Mayor entrances to locations where hazardous materials are stored, dispensed, used or handled in quantities requiring a permit. Individual containers, cartons or packages shall be conspicuously marked or labeled in accordance with nationally recognized standards. (UFC 80.107) "No Smoking" signs shall be conspicuously posted within and at all entrances to hazardous materials storage areas. 5. Required fire resistive construction, including occupancy separations, area separation walls, exterior walls due to location on property, fire resistive requirements based on type of construction, draft stop partitions and roof coverings shall be maintained as specified in the Building Code and Fire Code and shall be properly repaired, restored or replaced when damaged, altered, breached, penetrated, removed or improperly installed. (UFC 10.601) This review limited to speculative tenant space only - special fire permits may be necessary depending on detailed description of intended use. Any overlooked hazardous condition and /or violation of the adopted Fire or Building Codes does not imply approval of such condition or violation. Yours truly, . The Tukwila Fire Prevention Bureau cc: T.F.D. fie ncd 4,' c City of Tukwila FIRE DEPARTMENT 444 Andover Park East Tukwila, Washington 98188 -7661 (206) 575 -4404 TUKWILA FIRE DEPARTMENT FINAL APPROVAL FORM Gary L. VanDusen, Mayor Control No. Permit No. Project Name L Ielt/ / /e4 J ki 4 5 Address //:10 ,9,f L= 11 Am Suite # Retain current inspection schedule Needs shift inspection : q•• n. w. T..> f.»->..;. w.•.,-:, ^,.-- �ov�...na-'+- �'r;:�'Fr ->n• i-.-:.• r.+'• rwi�r••• ,wtr«.•'?..-.,•rr..n.r- .«..�z.Y . .. \,„ Approved without correction noticer, Approved with correction notice issued Sprinklers: Fire Alarm: Hood & Duct: Halon: Monitor: Pre-Fire: Permits: Authorized Signature .Dat T.F.D. Form P.P. 85 INSPECTION RECORD 0 Retain a copy with permit CITY OF TUKWILA BUILDING DIVISION 6300 Southcenter Blvd., #100, Tukwila, WA 981 8pedaf instructions: 4414 re-" t!hri,A:..` ,S,*r i3c3 0i(DZ (206) 431 -3670 ::°":' Date Wanted: 44' / 8, Requester; am p.m. red per applicable codes.; . D Corrections required prior to approval.: ;OO REINSRECTION FEE REQUIRED. Prior, to:,reinspection, fee must be, 6300 Southcenter:BIvd., Suite 100. Calhto schedule reinspection. t, 11 INSPECTION RECORD C.y Retain a copy with permit CITY OF TUKWILA BUILDING DIVISION 8300 Southcenter Blvd., #100, Tukwila, WA 98188 (206) 431 -3670 ter h .• : �ntii0 �' � M.• : { 74f taste Called; Spada! Instructions; Cate Wanted. t .. Lit/ e ;' am. p.m. Requester t,ti1: ` Y ! in . Phone No.: ,,.,... r" — o c �J 0 Approved perapplicable;i;odes. NI. Corrections required prior to approval. f! �� r (=` •M /No I`1-? Gr rt" A?) G z;a n {' A••• 1)R•06: r y -) • 744-1 S IS A .... I`-ti , J -t _ t n1 `a P rr K 1 A r-) . r $30.00 REINSPECTION FEE REQUIRED. Prior to reinspection, fee must be paid at 6300 Southcenter Btvd., Suite 100. Call to schedule reinspection. ( INSPECTION RECORD C. Retain a copy with permit CITY OF TUKWILA BUILDING DIVISION 6300 Southcenter Blvd., #100, Tukwila, WA 98188 6c13- ©i loll MIT M0. / (206) 431 -3670 r : -- iQr \1 um wa�+:� o rl I1as Address: • O :J. • 1 .1 a Called: -- _ • ii, -11"1 mut . , Date ranted: -' 3 1-'q q am. p.m. ppI Requester. NebR4. . IYI • Phone Na: - -� c7 " 0 Approved per applicable codes. COMMENTS: K. Corrections required prior to approval. t (t�—z✓i - V tri-vC o w rA a rc-- tM u S— av1 Lk1w a ►� � �-�- To A k..1 A47 P 1.6 1-14-k S t "S A- 3 N art.._ t N SPc 'y t4 . Vii, youfa— A) xi Ar4 At; • 1NsP -c- '1 ifzttv,rsi..: $30.00 REINSPECTION FEE REQUIRED. Prior to reinspectlon, fee must be paid at 6300 Southcenter Blvd., Suite 100. Call to schedule reinspection, INSPECTION RECORD 0 , Retain a copy with permit CITY OF TUKWILA BUILDING DIVISION 6300 Southcenter Blvd., #100, Tukwila, WA 98188 (206) 431 -3670 ro ect: 1 ype of ins :. ion: . •.rasa: 7 r: e a :,: Date Wanted: - Co - /1— 95 am Special Instructions: 2 p w- Requester; A 14 i-ferr" Phone No,: 7S / 7..3(,0 c>ce.Approved per applicable codes. COMMENTS: ❑ Corrections required. prior to approval, Al — % Date 4-1/1.3 ns�:. . or O .' 1.00 REINSPECTION FEE, REQUIRED.. ,Prior to reinspection, fee must be paid at . 6300 Southcenter Blvd, Suite 100. Call to. schedule_ reinspection. INSPECTION RECORD 0 Retain a copy with permit CITY OF TUKWILA BUILDING . DIVISION 6300 Southcenter Blvd., #100, Tukwila, WA 98188 (206) 431 -3670 ro ect: L.kevo tc.(t.. Wen=- t■fh-ct . ype o nspection: c.-041-1966.-- . 3" pwc pr P4 1e- S g $,J440s of Om Nth- ...... Address: ) 12.0 Ai P. • Date Called: 1p -7 Special Instructions: .- c k). v.: 1- re-0 ),S4 r.- Date Wanted: (a '' �r am; p.m. Requester: p st ?s m c -S ntdres Q E6LuI 26-a ?v ria4r. 044 -u-- Ac sa. Phone No.: ti'' /2,4. ❑ Approved per applicable codes. Corrections required prior to approval. COMMENTS: 4 c.-041-1966.-- . 3" pwc pr P4 1e- S g $,J440s of Om 77 ft. .:S70-t P . z it K G a-A-6 &rn S N ill E-)vs 2 i>2.4.bn.,_ . /9x4,9/ Hilo T? -rrx.- K/E S 70 ,6 �c` . A4-1s i 71 eiL v\ -12G' /g--/d / NSu orJ citt -- fh RhseAcg • eA P,aer-mU—Yrni 4 AA5 $- Wc.t._.' 71Jr.1 Gt i F A ato wN w ti-e W it Th S t-r nvcc^ • st ?s m c -S ntdres Q E6LuI 26-a ?v ria4r. 044 -u-- Ac sa. P 0G' Dx4P T sr' c• 1J / NA. Jl-og.., -ter° .Dc1dR..s. 4 G)rn e4.- emir fih -W /4 141 A- 'efdAz -r/ S7-( -4 Pr , I L - b 4 ,A l ' _'t'11 -4-+ r rto OS, : A t 4 . 4 - r v i e Gu+ ti -kottm t:.. 1914V 06- 6/1,44.► ti=p..: ` r;1 VA rJ SPhce'. , Ole-- -ri". u 41.. , ■NA — ni4--- V i0 wHSE tiri-r-te- Da-41 ..Te:Si"' is ' /tiav2. Inspector: �- 3_9r3, ❑ $30.00 REINSPECTION FEE REQUIRED. Prior to relnspection, fee must be paid at 6300 Southcenter Blvd., Suite 100. Cali to schedule reinspection. INSPECTION RECORD Retain a copy with permit CITY OF .TUKWILA BUILDING DIVISION 6300 Southcenter Blvd., #100, Tukwila, WA 98188 (206) 431 -3670 • ro ec4 I W.: o , nsped • n: ' / AI I ?D o vw Special Instructions: 1 .6 Date Wanted: b , t9. . 61m t Requester: Phone No.: 0 Approved per applicable codes. Corrections required prior to approval. COMMENTS: Inspector: Dade: Ciz O 10.00 REINSPECTION FEE REQUIRED. Prior to relnspection, fee must be paid at 6300 Southcenter BIVd., Suite:100 CaIIto schedule reinspection. INSPECTION RECORD 0 Retain a copy with permit CITY OF TUKWILA BUILDING DIVISION 6300 Southcenter Blvd., #100, Tukwila, WA 98188 (206) 431 -3670 ro eot: y ype of ns n: W,a a -c"13. uSc -^. C .,t4 "tic.. 1TN toe, • •..rem = -s1;1- 40,,,.. .Z:t as ass . I:, .:.; % Special Instructions: pa 1 a F 2— Date Wanted: -Z, r q--- am p.m Requester: -C> (...„,,,z c ..a! Phone No.: , `) �J,,59 ,,, 'z j V • ►J A L ■ o, U c.- ( A..-. 0 aflrL- 142E r N . ❑ Approved per applicable codes. Corrections required prior to approval. COMMENTS: , co » tic. �; -'7[.1 .. t i r x.:iL.. / n! C.044-(/20/1.• y . G L- to -a.4 • . ` 1N'-'1.11- oF' ( 11 it . 3 -'. 9A i -ii-T r1 W,41.1.- r n) W,a a -c"13. uSc -^. C .,t4 "tic.. 1TN toe, • = -s1;1- 40,,,.. .Z:t as ass . [.� Gbr,.ri. Mc'`e9S c`w a to•JS ( rt•: CAct6K17 -J, ►n1S'S Y! /Li lCr 't.(t A3rw f'r�l�'!' Lr� . .. Ot`" . S -...-.D tJ : nl ' A ' ''to -0 A- Nivea.• 4-1 D (NC t.tt D ' A tit., ' »11T S etom it - ili4C1c.S . 06a- G1 1 . c . t11,-. _ .4A: 2A nt .. “-- . S oil C.; 7 r S . 4,6 ,,, 'z j V • ►J A L ■ o, U c.- ( A..-. 0 aflrL- 142E r N . lb-ti2.. -,,. r..1n�" IN t cZ M° : -2c.> aC��-� .■/,rfi1 -t-. AN,c0 t---c ti� Sit <.- N- ►.lea- ' 1,00:... _ .__xtcy- Wrnl L w' I -t 12,7 CA 0-1 -14- i S-'P S KE N Ora 4.-""i" :: 2: '" 4-AAA s c D' _ aNts-D Pcil its . $30;00'Rf`INSPECTION FEE REQUIRED. :Prior to reinspection, fee must be paid at `6300 Southcenter Blvd., Suite 100. Call to schedule reinspection. 71t, INSPECTION RECORD 0 Retain a copy with permit CITY OF TUKWILA BUILDING DIVISION 6300 Southcenter Blvd., #100, Tukwila, WA 98188 PERMIT N0. r (206) 431 -3670 Project: c-Nen t a 1 sisr h- t.4.,- A-LL c -) LI �� l.{ — . OA (A‘ WT . Type of Inspection: 1 "j 1?-A -NIS I'K-%0 /4c ' eaek-ro iA . N tl-∎.- Address: the p -t- 1 i A Pgvk)E L 1G%.: JA J S PP-c.E- • Date Called: E-frn hn 4 171 /P-Le 1J Pro*- . seN A.'1 S L6- worn fire . Special InstnMions: 1 `a UF- ca.., Date Wanted: S - 2$ ,9� 'Aral Requester: Phone No.: ❑ Approved per applicable codes. 'Corrections required prior to approval. COMMENTS: ' a 1 sisr h- t.4.,- A-LL c -) LI �� l.{ — . t\1 Cw.9 L. --1- J,1, Ow. . AP 12. A-vn. P fz Prt Lt t,1�-t "WO 1 "j 1?-A -NIS I'K-%0 /4c ' eaek-ro iA . (2 (S Or Arl_tJ 4 = f %Z-- t=1 F.1 /n- . • 1. 1L ... a _ - the p -t- 1 i A Pgvk)E L 1G%.: JA J S PP-c.E- • 15) :trni„.fr t Ce- r- 1„4.4,rAE Go0ricv.a AR-LO O /0J E-frn hn 4 171 /P-Le 1J Pro*- . seN A.'1 S L6- worn fire . _th I ❑ $30.00 REINSPECTION ,FEE REQUIRED' Prior to reinspection, fee must be paid at 6300 Southcenter Blvd., Suite 100. Call to schedule reinspection. INSPECTION RECORD 0 Retain a copy with permit • CITY OF TUKWILA BUILDING DIVISION 6300 Southcenter Blvd., #100, Tukwila, WA 98188 PERMIT NO. (206) 431 -3670 — ' Pro]ec1: CHtz.. )1c,tr, mrh :T pe ns n. w3 Address: late Called: Special Instructions: Date Wanted: s- 3 7— 9. am. m) Requester: cS- C Phone No.: li 5'; - soS' r \ Approved per applicable codes.: ❑ Corrections required prior to approval: COMMENTS: ❑ $30.00 REINSP ECTION FEE REQUIRED. Prior to reinspection, fee must be paid at 6300 Southcenter BIvd., Suite 100. Cali to schedule reinspection. INSPECTION RECORD 0 Retain a copy with permit CITY OF TIJKWILA BUILDING DIVISION 6300 Southcenter Blvd., #100, Tukwila, WA 98188 ro ect; CG �y . 1 uie,Ah - ype o ns n; /'72,41.?ay i1/4. •a, Address: // p r-' c---26 Called: -2 Special Instructions: Date Wanted2, y Requester: _� Phone No.: 9 li g- 5(951 Approved per applicable codes. COMMENTS: ' 0 Corrections required prior to approval. 0 $30.00 REINSPECTION FEE REQUIRED. Prior to reinspection, fee must be paid at 6300 Southcenter Blvd„ Suite 100. Call to schedule reinspection, INSPECTION RECORD 0 Retain a copy with permit CITY OF TUKWILA BUILDING DIVISION 6300 Southcenter Blvd., #100, Tukwila, WA 98188 49.3 cold" Z, PERMIT NO. (206) 431- 670' .';"'! Project: —77,1575T nsped n: rasa: f f �� 'p Date Called: 5. Special Instructions: /c9OO Date Wanted: 5.-- .— 5'• C3).. p.m: Requester: Phone I. : Approved per applicable codes. ❑ Corrections required prior to approval. COMMENTS: ' A nspector: . � 01 e: ❑ $30.00 REINSPECTION FEE REQUIRED. Prior to reinspection, fee must be paid at 6300 Southcenter Blvd., Suite 100. Call to schedule reinspection. INSPECTION RECORD 0 Retain a copy with permit CITY OF TUKWILA BUILDING DIVISION 6300 Southcenter Blvd., #100, Tukwila, WA 98188 PERMIT NO. (206) 431 -3670 Projed: ...G. , Type o n�i sl -pedE '' Special Instructions: Date Wanted: .-5—.2.-C--4 3 �,m, Requester: roe -'°f Phone No.: Approved per applicable codes. COMMENTS: ' ❑ Corrections required prior to approval. ❑ $30.00 REINSPECTION FEE REQUIRED. Prior to reinspection, fee must be paid at 6300 Southcenter Blvd., Suite 100. Call to schedule reinspection. INSPECTION RECORD Retain a copy with permit CITY OF TUKWILA BUILDING DIVISION 6300 Southcenter Blvd., #100, Tukwila, WA 98188 (206) 431-3670 -1574-a: y—ri—De or Inspection: gr: reSS: ifizs At.p...... .41 e . : , : 11, .......2...x.r i 3 Special Instructions: Date Wanted: am. Requester: Phone No.: [lit...Approved per applicable codes. El Corrections required prior to approval. o $30.00 REINSPECTION FEE REQUIRED. Prior to reinspection, fee must be paid at 6300 Southcenter Blvd., Suite 100. Call to schedule feinspection. Date: INSPECTION RECORD C Retain a copy with permit CITY OF TUKWILA BUILDING DIVISION 6300 Southcenter Blvd., #100, Tukwila, WA 98188 (206) 431 -3670 ProJect:6 ), 1 /Cc/ 640e /�'tV lei- Type of Inspection: - rr(%QSTiQac, /�D�'1 Address: r jf2 l.—� Date Caled: -- ns : zr & {y ° I� -41 ` `' ` �* bate Wanted: lO' 9 am p.m. p�uester: Phone No.: O Approved per applicable codes. 0 Corrections required prior to approval. COMMENTS: t"' SA<'Cf l L& r- p'►� ��"S ll�.0 Gl' .-e".Gs -rG S S ••C Oyu S .17., //s, // v. ' t f-'v r- r f-e7 II s e /jLe.,- X Co, Sd C 4„5 7 6.4-4 4su 5 ❑ $30.00REINSPECTION FEE REQUIRED. Prior to reinspection, fee must be paid at 6300 Southcenter Blvd., Suite 100. CaII to schedule reinspection. o.: —fie: CITY OF TUKWILA 6300 SOUTHCENTER BOULEVARD TUKWILA, WA 98188 * EREVESVON SL5EMTTAL * DATE 1 09.S PROJECT NAME AppREss CONTACT PERSON 1-.24auwizsai ARCHITECT OR ENGINEER PLAN CHECK/PERMIT NUMBER *51" 0102 1/1(44 gelEf3. PHONE =4-C19A TYPE OF REVISION: PI L. LO Srpktornaes SHEET NUMBER(S) 6. "Cloud" or highlight all areas of r visions and date revisions. SUBMITTED TO: CFO REOEIVED _ 917 I?F Tulcr44 NAY 1 7 1993 PIRMIT °stiffen C EMICK HOWARD NELSON & SEIBERT 119 Pine Street, Suite 303 • Seattle, Washington 98101 2 0 6 2 2 3 Date: 5•17ecte Project: 64 Wart 120 T t GjI) Attn: Address:L aui LA 4 9 9 9 TRANSMITTAL Job #:105 ITEMS TRANSMITTED "Attached Quan. Date ❑. Copy of Letter ❑ Change Order ❑ Original Drawings ❑ Sepias — Prints ❑ Specifications ❑ Samples ❑ Shop Drawings 0 es �11a •+ ❑ Under Separate Cover Description REASON TRANSMITTED (Approval �] _Review and Comment ❑ For Information • ❑ As Requested ❑ Approved as Submitted • ❑ Approved as Noted ❑ Correct and Resubmit ❑ Not Approved ❑ Return Signed Original REMARKS tze . $44rr 4136n•oi &� vrnowst. - s-n2Arurzfrt, t4 O f ci rt Signed . • CC: '% /61C/ CITY OF TUKWILA • MAY 1 7 1993 PERMIT CENTER CITY OF TUKWILA 6300 SOUTHCENTER BOULEVARD TUKWILA, WA 98188 * `~ LEWUSWVSO'dW SL MUTTAL * DATE S, °� PROJECT NAME 6H19\4i,r.„At-1 J 11.44- i T ` ADDRESS `9J krt, O' k.S . feL- ICS. CONTACT PERSON 1rAPA) Lc PHONE 0 '4,19 ARCHITECT. OR ENGINEER PLAN CHECKIPERMIT NUMBER U Ike- TYPE OF REVISION: Jr; IC.TO 1J,7 1 4€t L .(0/ !CFI SHEET NUMBER(S) b•frial 4° • "Cloud" or highlight all are of revisions and date revisions. uJ 0 LT. S LL. 0 IV • w 0 0? • #1999E L6P 90Z 4- 0889EZ.Z90Z .99 :9 t.E6 -4 -9 r.t9 -LNBS VII. NOTIFICATION AND REPORTING In the 'event of a hazardous material, substances, or waste release, the EC (or the Environmental Manager) will be responsible to notify regulatory agencies. The Figure V11 -A, Agency Notification chart, identifies the agencies to be notified in the event of a hazardous material, substance, or waste release: VIII. CWM HAZARDOUS MATERIALS INFORMATION AND LOCATIONS The following hazardous materials and wastes are stored in three general areas at the Tukwila facility: ADMINISTRATIO[�L UI. FII ice_ DESCRIPTION HAZARD QUANTITY Inks / toners Flammable` Toxic Aerosols/‘ Flammable /. 10 aerosols Toxic Window Cleaner Corrosive 2 pints Cleanser Corrosive / 5 lbs. Oxidizer Liquid Paper Flammable / 1:gait/ Toxic Liquid Paper Thinner Flammable / 1 gal Toxic Alkaline batteries Corrosive 5 lbs B. SHOP BUILDING AND SURROUNDING ARE DESCRIPTION HAZARD QUANTITY Miscellaneous oils and Flammable / 10:galsV lubricants combustible / Diesel fuel Combustible 10 gal `� Unleaded fuel Flammable / 10 gals toxic Antifreeze : combustible / 1 gals toxic Alkaline cleaners Corrosive . . 5 gals Propane Flammable / 2 small toxic cylinders Oxygen . Oxidizer Acetylene Flammable / toxic Window Cleaners. Aerosols Flammable /,: toxic Flammable /:. toxic 1 cylinders 1 cylinders 2 gals `to' 20 cans Hexane Flammable 11 gals "/ Acetone Flammable 1 gal Paint Thinner Flammable 1 gal. Lacquer Thinner r Flammable 1 :quart Isopropyl Alcohol Flammable, 15 gals Methanol Methylene Chloride NAOH pellets NAOH 10% solutions Sodium Bicarbonate Paint Stripper Sulfuric Acid Ferric Sulfate 10% Ferric Chloride 10% Sodium Hydroxide 10% Hydrochloric Acid 10% Ferric Sulfate Ferric Chloride Ferrous Sulfate Muriatic Acid Sulfur Flammable'!. Toxic 3 gals Corrosive 1 kg Corrosive 16 ounces Corrosive 2 lbs. Toxic 3 gals Corrosive 300 ml. Corrosive 200 ml. Corrosive 200 ml. Corrosive 100 ml., Corrosive 10 ml. '6 ounces Corrosive 100 grams Corrosive . 900 grams Corrosive. 500 grams Corrosive : 3 gals Toxic 1 kg Citric Acid Corrosive 5 kg Less than 10 Chemical Corrosive 6 ":gals Solutions International Cleaner C. WASTE TRANSFER AREA • DESCRIPTION Flammable Liquids Locker Corrosive Material Oxidizer Other Toxic Material HAZARD Flammable / combustible / toxic Qttocopae , cotweb 1.4,143,1-0 1,2o Gat ce.466sir no Cam(, CLASS IQ' -A 13,20o ;oat C1JWW Tr-11. g. Corrosive / toxic ' ; 1007 GALS Oxidizer / corrosive Toxic 10001 Quanitities of material in this category will not exceed the number than can be stored in one truck trailer. All material will be packaged in accordance with all applicable Transportation Regulations. At no time will these drums be staged on the warehouse floor. c s4- Z 4 = z m -�. 4000 IX. EMERGENCY PREPAREDNESS A. TRAINING. All personnel receive initial and annual instruction in the purpose and implementation of the site contingency plan. At least one site contingency plan drill and critique will be preformed annually. A number of facility personnel have been trained to provide first aid and CPR. At least one person per work area per shift is current in First Aid /CPR certification. ARRANGEMENTS WITH LOCAL HOSPITALS AND AUTHORITIES The local fire department (identified in Section III(D)(1)and medical BUILDING DIVISION NOTE CONDITIONS OF OCCUPANCY CLASSIFICATION PERMIT # B93 -0162 The use of the tenant space at 1120 Andover Park E. (Chemical Waste Management, Inc.) remains classified as a Group B, Division 2 Occupancy as defined in the Uniform Building Code. To maintain this classification, the exempt amounts of hazardous materials (as listed in U.B.C. Table 9- A and 9 -B) shall not be exceeded in each of the (3) control areas noted on the approved plans. CONDITION FOR CONTROL AREA I. "WASTE TRANSFER AREA" The following specific types of hazardous materials were indicated but the quantities are unknown. Consequently, the following exempt amounts of these materials may not be exceeded in control area I. FLAMMABLE LIQUIDS COMBUSTIBLE LIQUIDS CLASS II CLASS III -A CLASS III -B CORROSIVE OXIDIZERS TOXIC SOLIDS LIQUIDS CLASS 4. CLASS 3 CLASS 1 360 GALLONS 360 GALLONS 660 GALLONS UNLIMITED 10,000 # 1,500 GALLONS 1# SOLID 1# LIQUID 20# SOLID 20# LIQUID 8,000 # SOLID 8,000 # LIQUID 1,000 # The noted limits of these hazardous materials is based upon the schedule of materials anticipated in the "Waste Transfer Area ". ALL STORAGE OF HAZARDOUS MATERIALS IN THIS CONTROL AREA WHICH EXCEEDS THE EXEMPT AMOUNTS IN U.B.C. TABLES 9 -A AND 9 -B, VOIDS THIS PERMIT APPROVAL. BUILDING DIVISION NOTES Accessible toilet room facilities shall be subject to all requirements of Chapter 31 of the Washington State Building Code including the following specific items. 1. An unobstructed floor space shall be provided within the toilet room of sufficient size to inscribe a circle with a diameter not less than 60- inches. Doors in any position may encroach into this space not more than 12- inches. 2. Water Closet: The lateral distance from the center line of the water closet to the nearest obstruction, including grab bars, shall be not less than 18- inches on one side and 42- inches on the other side. Height of water closets shall be a minimum of 17- inches and a maximum of 19- inches measured to the top of the seat. 3. Grab Bars : Grab bars shall be installed at one side and at the back of the water closet. The top of grab bars shall be not less than 33- inches and not more than 36- inches above and parallel to the floor. Grab bars located at the side shall be a minimum 42- inches in length with the front end positioned not less than 18- inches in front of the water closed, and located not more than 18- inches from the center line of the water closet. Grab bars located at the back shall be a minimum of 36- inches in length. Grab bars shall be mounted not more than 9 inches behind the water closet seat. 4. Sink shall be mounted with the rim surface no higher than 34- inches above the finished floor. Hot water and drain pipes exposed under lavatories and sinks shall be insulated or otherwise covered. 5. Shower stall be minimum 36 "x36" nominal and shall have a seat. A clear floor space of 36 "wide by 48" long shall be provided adjacent to the shower stall. Grab bars shall be installed parallel to the floor. All grab bars shall be installed not less than 33- inches and not more than 36- inches above the floor of the clear space. A grab bar, not less than 18- inches in length, shall be installed on the wall opposite the clear floor space, one end of which shall terminate at the wall opposite the seat. A grab bar not less than 27 inches in length shall also be installed on the wall opposite the seat. Faucets and controls shall be located on the same wall as the shower spray unit, and shall be installed not less than 38- inches or more than 48- inches above the shower floor. M E M O DATE 5/18/93 TO FROM SUBJECT BUILDING CODE ISSUES. # OF PAGES C W M ,INC. FILE 593 -0162 RSB 1 APPLICANT SUBMITTED A HAZARDOUS MATERIALS INVENTORY KEYED TO VARIOUS LOCATIONS IN THE BUILDING. ONE = THE ADMINISTRATION AREA, AND THE OTHER WAS THE WAREHOUSE AREA.. DISCUSSIONS WITH ROBERT MITCHELL INDICATED THAT THE LISTED HAZARDOUS MATERIALS (IF TOTALED FOR ALL AREAS) COULD POTENTIALLY EXCEED THE EXEMPT AMOUNTS ALLOWED IN A GROUP B, DIVISION 2 OCCUPANCY. RESOLVE: DEVELOP THREE CONTROL AREAS WITHIN THE BUILDING TO HOUSE THREE QUANTITIES OF EXEMPT AMOUNTS OF HAZARDOUS MATERIALS AS FOLLOWS: 1. WAREHOUSE WASTE TRANSFER AREA (LOCATION OF CONTAINER VAN STORAGE) 2. SOUTH PORTION OF WAREHOUSE AREA WITH DESIGNATED FENCED IN AREA. 3. ADMINISTRATION OFFICE AREA. NOTE: THE MATERIALS TO BE CONSOLODATED IN THE CONTAINER VAN STORAGE AREA HAS BEEN STATED IN THEHAZMAT STATEMENT, BUT THE QUANTITIES ARE UNKNOWN. CONSEQUENTLY, BUILDING PERMIT CONDITIONS WILL STATE THE EXEMPT AMOUNTS ALLOWED. IN THIS AREA. FLAMMABLE LIQUIDS: 360 GAL. COMUST/BLE LIQUIDS: CLASS II 360 GAL CLASS III-A 660 GAL CORROSIVE OXIDIZERS' CLASS I11 -5 UNLIMITED SOLIDS LIQUIDS. CLASS 4 10,000 LBS 1,,500 GALS 1# SOLID 1# LIQUID 20# 'SOLID 20 # LIQUID 8000# SOLID 8000# LIQUID M E M O DATE 5/17/93 TO C W M INC. FILE FROM RSB SUBJECT PHONE CONV. W/ ROBERT MITCHELL # OF PAGES 1 C.F. / ROBERT MITCHELL OF C.W.M.,INC. TO DISCUSS THE MEMO I SENT TO DAVE THRUSDAY 13MAY93. DISCUSSED THE LOCATION OF THE PROPOSED STORAGE OF HA MATERIALS AS LISTED IN THE INVENTORY FROM'C.W.M.,INC. .RESOLVE: WILL DEVELOP AN ADDITIONAL CONTROL AREA BY INSTALLING FIRE RA DOORS IN EXISTING CONCRETE DEMISING WALL. CONSEQUENTLY, ONE CONTROL AR WILL BE THE AREA WHERE THE HAZMAT VAN WILL BE PARKED, ONE CONTROL AREA LOCATED IN THE SOUTH WAREHOUSE AREA (DEMISED BY THE EXISTING CONC WALL) THE THIRD CONTROL AREA WOULD BE DEFINED AS THE OFFICE AREA WHICH EXISTS AN OCCUPANCY SEPARATION WALL. .TOLD R.M. THAT THIS WOULD ALLOW THE BUILDING TO MAINTAIN THE B-2 OCCUPA DESIGNATION AND FURTHER ALLOW THE STORAGE VANS TO BE LOADED WITH THE FU EXEMPT AMOUNT OF HAZARDOUS MATERIALS. R.M. TO HAVE ARCHITECT SHOW THE INSTALLATION OF ONE HOUR FIRE RATED.DOO THE CONCRETE DEMISING WALL AND INDICATE ON THE PLAN THE LOCATION OF THE HAZARDOUS MATERIALS STORAGE LOCATION FOR THE SOUTH WAREHOUSE. IN ADDIT ASKED HIM TO NOTE THE EXISTING CONSTRUCTION OF THE DEMISING WALL. M E M O City of Tukwila John W Rants, Mayor Department of Community Development Rick Beeler, Director DATE 5/13/93 TO DAVE LEWIS, ARCHITECT FROM BOB BENEDICTO SUBJECT. C W M ,INC. T.I., PLAN REVIEW B93 -0162 # OF PAGES 1 I HAVE REVIEWED THE HAZMAT INFORMATION SUBMITTED AND REVISIONS TO THE PROPOSED APPLICATION WILL BE REQUIRED UNLESS MORE DETAILED INFORMATION IS PROVIDED. 1 TWO LISTS OF HAZARDOUS MATERIALS WERE SUBMITTED. ONE LIST WAS INCIDENTAL TO THE BUSINESS AND WOULD BE STORED ON SITE IN A FENCED IN AREA. THE OTHER LIST WAS THE ANTICIPATED HAZARDOUS MATERIALS THAT WOULD BE CONSOLIDATED IN THE WAREHOUSE FOR SHIPMENT. SINCE THIS BUILDING IS CLASSIFIED AS A B -2 OCCUPANCY AND IT IS PROPOSED TO BE USED AS SUCH THE TENANT WILL BE ALLOWED TO DEVELOP A MAXIMUM OF 4 CONTROL AREAS WITHIN THIS BUILDING WHERE THE EXEMPT AMOUNT OF HAZARDOUS MATERIALS MAY BE STORED IN EACH. THE ADMINISTRATION BUILDING AREA QUALIFIES AS ONE CONTROL AREA. IT WILL BE NECESSARY TO DEVELOP ONE CONTROL AREA FOR THE "SHOP BUILDING ". THE REMAINING WAREHOUSE AREA USED FOR CONSOLIDATION OF WASTE MATERIALS WILL BE ANOTHER. PROVIDE A PLAN SHOWING THE LOCATION OF THE REQUIRED CONTROL AREA THAT WILL BE USED FOR THE HAZARDOUS MATERIALS LISTED FOR THE SHOP BUILDING AND SURROUNDING AREA. (REFER SECTION 2.VIII, PAGE 11 "ACTION PLAN FOR C.W.M.,INC.) INCLUDE A CONSTRUCTION DETAIL FOR THE ONE HOUR OCCUPANCY SEPARATION WALL REQUIRED. THIS IS MY CONCLUSIONS OF THE REQUIREMENTS FOR THIS USE BASED UPON INFORMATION THAT HAS BEEN SUBMITTED SO FAR. OBVIOUSLY OTHER SOLUTIONS MAY BE AVAILABLE AND I WILL CONSIDER THEM IF YOU WISH TO MAKE A PROPOSAL. 6300. Southcenter Boulevard, Suite /1100 • Tukwila, Washington 98188 • (206) 431-3670 • Fax (206) 431-3665 Cl/ 4.)F TUKWILA Department of Community Development FAX TRANS' ' ITTAL FAX NUMBER: (206) 431-3665 TO: ---1"---Ve. Le_wis DATE: '14,1 93 TITLE: FROM: ' ---0. a= .' (eoc1Z COMPANY: 4:::64 j r NM KY.. AcaD - I (J �5e- l TITLE: . DEPARTMENT: . DEPARTMENT: L 1Lt1 Mci Ltbnwi�ii4: it rw4hiit{ vFwv. ri, W: iKK< J: L4N:< K«' Ciw4' 444i4 WCiWwwJ LwKiK{KL}:K4'+:iKLO:4:Kid+' tiK4:KN nVi•?:L• FAX NO. CALLED: 2o& x:23. 4`9'0 NUMBER OF PAGES TRANSMI'1-IED, INCL. Z THIS COVER SHEET: uitwR3• r+':; �. i�r:+ tf ;.f:Yf.v.'Rr::..iSi..l.:ilfii i+rXvr.K l�GiwitiL• r: Wir: 4>! .tirifi'iiiiiiY:C%i6'rr7rlil.:>l Nk4:0r'W ri4' rii$: fn4ri�i•: L' i% v7L4iLY' Fi3riviR ?i5+G» >i:4$iii}:if,•;p}iYi! %i4:Li'iliRV'R'r:S:vY:iLW' •i:"+% SUBJECT: - �' C0 a C4.M,tCAL mew. M . COMMENTS /MESSAGE: .rir %i'S•r n.NrNr...hlv:SYI!!N % iiiA•7 W ' r zc're-m aF, Revt Eat) c:004446Nrsi (2-fr.44-er 6-/03). 1n. Y. K+ WYLOiti4iwi::• iiYY:i<S+Gii4+ /lii43VriiKV:4iYiW 4Yil• K4: J44% W: vi: 4i: 4ri4iiii4iYiiiiviG: Wl+ mvl. 4+ ivY: ifN:i:KKKiV.4:iK'i•Y:4'N'+:4iN' .iK•:i4:4i>GY.iW:it4P WYi:VivnvHNiiw•i WAN. iiVYi:W.wliKi4riW >m.�K.4p•:4:P:K IF THIS COMMUNICATION IS NOT CLEARLY RECEIVED, PLEASE CALL: -- 3C9-10 iVotibia c :iW:ru%i6'riWi.Xfi6:biYi1N:tativ 744rifritiiN.vY/: iiriKi*Auv 4i#::•:.44feie,Yi4Ya: • LaUnvwMn' mhviy;L WWi: ii• Wu.N.4 4WiV4 iG iviKiMONtiY.L4:v6ifGiW-i,ii:It.`, nsvnwvnf3'oriverrn4mbw ii.».• Yee: Yh sr..'+. m., v1,. .iii:ii:44iiifrii»iibioJir';4fra244 DEPARTMENT OF COMMUNITY DEVELOPMENT 6300 Southcenter Boulevard, Tukwila WA 98188 Office: (206) 431-3670 MEMO. City of Tukwila John W. Rants, Mayor Department of Community Development Rick Beeler, Director DATE 5/11/93 TO Dave Lewis FROM Bob Benedicto SUBJECT Chemical. Waste Management # OF PAGES 1 of 1 I have reviewed the information transmitted yesterday via FAX and it seems that the approvals indicated are in regards to the zoning requirements and subsequent approval of a business license. Consolidation in closed containers and transfer to a van trailer remains the storage of hazardous materials in a building classified as a "B -2" office /warehouse. The letters indicates that a maximum of 400 square feet of the building will be used for parking this van. In order to consider an approval of this operation in this warehouse, additional information will be required. 1. The location of this 400 square feet of van storage area needs to be located on the building plan. 2. The type and quantities of hazardous materials to be stored in this building must be declared. 3. If the quantities of hazardous materials to be stored in this building exceed the exempt amounts stated in U.B.C. Table 9 -A modifications to the warehouse space may be required. 6300 Southcenter Boulevard, Suite #100 • Tukwila, Washington 98188 • (206) 13670 • Fax (206) 4313665 r Chemical Waste Management, Inc. 19002 72nd Avenue South Kent, Washington 98032 206/251 -6227 May 11, 1993 Mr. Bob Benedicto City of Tukwila Department of Community Development 6300 Southcenter Boulevard, Suite #100 Tukwila, Washington 98188 Mr. Bob Benedicto: The enclosed documents should satisfy the requirements, regarding hazardous materials, set forth in your letter to David Lewis, dated May 10, 1993. Our company intends to utilize the proposed warehouse space for storage of equipment and supplies that we utilize on outside contracted work. Our operation is similar to a construction companies and our equipment is similar as well. We do have small quantities of hazardous materials on -site that we store in cabinets, which are secured within a fenced area inside of the warehouse. These compounds are listed under Section 2,V111, which is on page 11, Chemical Waste Management, Inc. is not a generator of hazardous waste. As such we do not have an inventory of waste on -site, nor do we intend to in the future. We have been granted approval by the City of Tukwila Planning Department that would enable us to transfer waste material from one truck to another for consolidation purposes. This activity would occur occasionally on an as need basis, The location proposed for this activity is shown on the appropriate architectural drawings. For your information our current address and telephone number is: 19002 72nd. Avenue South Kent, Washington 98032 (206) 251 -6227 Fax: 251 -6679 The address and telephone number listed in the contingency plan will be accurate after our move in. Thank you in advance for your help in expediting the necessary permits. If you require any additional information, please contact me. RECVED CITY OF TU WILA MAY 1 2 1993 PERMIT CENTER ® Printed on «xycie0 pr,por Mr. Bob Benedicto May 11, 1993 Page 2 Sincerely:. Chemical Waste Management, Inc.. I Olitt. ' obert Mitchell Area Operations Manager Attachment. PERMIT CENTER Ptirited on Ncyclo4 • City of Tukwila Department of Community Development John W. Rants, Mayor BUILDING DIVISION Mr. David Lewis Emick Howard Nelson & Seibert, Inc. 119 Pine Street Suite 303 Seattle, WA 98101 Re: Chemical Management,Inc. Plan Review B93 -0162 Dear Mr. Lewis: Rick Beeler, Director The initial plan review by Building Division indicates that additional information and /or revisions to the proposed plans will be required to show compliance with Tukwila Ordinances. The following comments are applicable: 1. Provide two sets of plans with the architects seal, signature and date on each sheet. Will there be storage or or hazardous materials in the hazardous materials inventory is outlined in Appendix II -E, Fire Code. Declaration to be or designated representative. 0 use of flammable, combustible building? If yes, Provide a statement declaration. Form page 487, of the 1991 Uniform signed by the business owner The calculated occupant load of the second floor space exceeds 10. Consequently, two exits are required from this floor that provide egress to separate means for exiting the building. The proposed plan does not provide for this and therefore is not in compliance with chapter 33 of the Uniform Building Code. Prior to approval of this permit application Code complying exiting must be provided. 4. Provide additional detail of the barrier free bathroom facility. Show required clear floor spaces for the toilet room floor and the shower area. Indicate all grab bars room dimensions and door size. One "van accessible" parking space is required for this parking lot. Show location on site plan. Refer U.B.C. Section 3107 for specific details and indicate on site plan. 6300 Southcenter Boulevard, Suite #100 Tukwila, Washington 98188 • (2061)313670 • Fax (206) 431-3665 Please submit two copies of information and any revisions that develop. If you have any questions you may call this office : ' anytime between 8:30 AM and : 5:00 PM. SENT BY: 5 -10 -93 ; 16 :08 EMICK HOWARD NELSON SEIBERT, INC. 119 PINE ST. SUITE 303 SEATTLE, WA 98101 206- 223 -4999 206- 223 -4990 (PAX) Date: 541.01i/3 Project: d- M t& r To: i t -e(f' U, IL13" Fax. No.: 431' 6:25 Total Pages with cover: Message: 2082234990 -4 206 431 3885 ;# 1 RECEIVED MAY 1 01993 MMUNITY DEVELOPMENT FAX COVER SHEET Project No: 1407,11Y3 Z1-LD3 From: jwv Attn:Ragel=r fejp.1.0..,oicrt:3) aunt atiu aus r$615. o Ve2 CevWet. biz, -wet.l °1 a!7 (cw 1.a) 6-ttf cse-- T.tleWt(.A -- Psf-v4e RvotTw-likL- tit4-N 1e,14 (2.,QU Nip 0-t4c4e4tHe( Irtra4 (gP ►ib-r�,L. its SENT BY C 5 -10 -93 ; 16:09 MAY -10 -93 MON 1551 Chem Waste Managment A Chemical Waste Management. inc, '1002 '2 •,Anus Sour t.:in(. ;JAL^ ^ ^..4n 98032 206/251•i22' April 6, 1993 Mr. Al Robertson Kidder, Mathew, & Segner 12886 Interurban Avenue South Seattle, Washington 98168 Dear Mr. Robertson: 2082234990 -+ 208 431 3885;# 2 • ,( FAX N0. 2082516679 P,06 The purpose of this letter is to provide a brief narrative of our business intent as it applies to any hazardous material transfer activities proposed at the former FiberChem building. A large part of the customer services provided by our company is the transportation of hazardous materials. In order to be competitive our company must be able to provide these services quickly and efficiently. Since many of our customers generate small quantities of material, it is itnportant thatt a i aintain a'pdintof consolidation;} :Under Federal, and State regulations the transfer of hazardous material from truck to truck can occur at any public or private location if performed in a safe manner. Currently, our drivers are forced to perform this function in area's that lack optimum control. In addition, due to Department of Transportation "Hours of Service" regulations, our drivers are often required to spend the night in local hotels with their loaded truck in the parking lot. This situation would be improved by adding a local point of consolidation. This would he a controlled environment where containerized material could be transferred from one vehicle to another and :,held for :kmaximumpf:;1.0;'daysl During this 10 day period hazardous materials can be held at a "transfer facility" or;,the purposes,of consolidation` or ease of transportation. The proposed transferaatvity ;wouldentait: the -rnovernent :of containers 'o;avan4:#railetdcsigned.i 'ffOrThatardoilfiziatetiefransportation.f Under no condition would containers be set on the warehouse floor, nor would there be any opening , or physical contact with any of the material. Our company has internal requirements to insure the compliance with all applicable regulations. Typically these requirements are more stringent than those required by law. For the purposes of' our intended transfer activities a (tr`ach ngiand imo it9riz g system vill he developed to insure compliance and mitigate potential concerns. Thank you in advance for your help in obtaining the necessary local approvals for our proposed use. If you require additional information, please contact me at your earliest convenience. SENT BY:. • MO -10 -93 MON 15:52 Chem Waste Managment FAX NO 2082516679 P, 07 2062234990 -4 Mr, Al Robertson Page 2 Pacific Northwest Operation's Manager cc: Terry Pleasant 5 -10 -93 ; 16:10 ; MAY -10-93 MON 15,61 Chem Waste Managment hemlcel Waste M a j morlt, Inc. '1:1 ANN() 1,4atu( ?' t<V., I 4�'jI4I' yi'inf 01.09:2 2/.161”:.' April 22, 1995 'Ms. Ann Siegenthaler Associate Plannor City of Tukwila Department of Community Development 6300 Southcenter Boulevard, Suite #100 Tukwila, Washington 98188 "2062234990 -4 (:;\ FAX NO, 2062616679 208 431 3885 ;# 4 P.05 Dear Ms, Siegenthaler; Pursuant to our telephone conversation today, the following summary should address your questions regarding our operation. The proposed transfer activities will be used as a convenience to our small quantity generating customers, These customers make up less than 5% of our total customer list, All other customer generated material will continue to be directly shipped to a permitted facility. The "point of consolidation" concept is not intended to be a revenue producer. This activity is only valuable as a cost saver and convenience to our small customers. We anticipate that the cost savings as a result of these activities will be less than 1 - 2% of' our revenues in the Pacific Northwest. In terms of space dedicated to these activities, it would only require an area the size of a semi van, or 400 square feet. Thank you in advance for your help in obtaining the necessary business license if 1. can be of any further help, please contact me at 251 -6227, cerely: 1A114 bert Mitchell Area Operations Manager cc: Terry Pleasant Al Robertson SENT BY: • 5 -10 -93 ; 16:11 ; 20 ''94990 -. 206 431 3865;# 5 MAY -10 -93 MON 15:49 Chem Waste Menagment FAX NO. 2062516679 Pi 02 4 City of Tukwila John W. Rana, Mayor =.rd.;wy =Ca A' Department of Community Development Rick Beeler, Director April 29, 1993 Mr. Robert Mitchell Area operations Manager Chemical Waste Management, inc. 19002 72nd Avenue South Kent, WA 96032 RS: Business License Application for CWMI 1120 Andover Park Bast, Tukwila Dear Mr. Mitchell: in my letter to you dated April 5, 1993, I explained the basis for the Department of Community Development's (DCD) denial of the above business license application. in light of new information regarding CWMI's operational DCD has re- evaluated your proposal. The basis for approval of your license, our understanding of the nature of your business, and our revised decision are explained below. Under the Tukwila Zoning Code, hazardous waste storage is ytiot a� permitted use�'i(ITIC'a 11.4a1.�u4b) ,r.1 tr ' ii n tav 'i�i.•101's second aa3.A..1 descriptions of your business, it was apparent that the hazardous waste ,storage and transport you proposed was not incidental to your primary operation. Thus, the activities were not allowed uses in Tukwila. However, you have provided additional information which clarifies the nature of CWMI's operations, including a letter to Al Robertson 4/6/93, a phone conversation with me 4/22/93, and a letter to me 4/22/93. This new information is the basis of our revised decision. Our understanding of CWMT's activities related to hazardous waste storage is summarized below: 1. CWMI's primary activity at the Tukwila site will be support services for off -site activities. Off -site activities include hazardous materials transport from the point of generation to an out -of -state facility. Transport operations and facilities meet all of the applicable federal requirements. To support these off - site activities, CWMI's Tukwila site will provide a bade for sales (services), engineering, and field service staff. These activities do not involve hazardous materials storage at the CWMI site. .'.nn •7 .. • 14 . •......t •••••• •..AA, •R.f.....f.. TI7w..i.fw.+...w not 00 a /9AA1 Ao1 2A7A *. Cbv.MAA1 A21_41AC SENT BY: 5 -10 -93 ; 16:12 ; 20 34990 -0 206 431 3665:4* 8 MAY -10 -93 MON 1549 Chem Waste Managment FAX NO. 2062516679 P.03 Mt. R. Mitchell CWM.I, 4/29/93 Page 2 2. A secondary activity at the CWMI site will be the storage of small quantities of hazardous wastes, as defined by the Tukwila Zoning Code. This activity is conducted as a service to your customers which generate quantities too small for cost -- effective, direct out -of -state transport. At the customer's site, hazardous wastes are completely sealed in containers and prepared for transport. CWMX consolidates these small quantities of waste by collecting the ,containers in "shuttle vans," and transferring them, unopened, to a van trailer within the Tukwila warehouse. The van trailer is designed for hazardous material transportation. '3. Of the total warehouse area to be occupied by CWMX, (26,000 square feet) approximately 400 square feet will be used to store hazardous wastes in the van trailer. 4. Your letter of 4/22/93 indicates that: a) customers which use CWMI's waste consolidation service comprise less than 5% of your total customers= b) the storage activity is not a source of revenues for CWMI; and 0) CWMX's cost savings as a result of these activities will be less than 1-2% of revenues in the Pacific Northwest. Based on this new information, it is apparent that the proposed storage of hazardous wastes is incidental to CWMI's primary operation at the Tukwila site. As an incidental use, CWMI's hazardous waste storage is permitted by the Tukwila Zoning Code. Therefore, DCD has approved your business license application with the conditions noted below. For any storage or handling of hazardous wastes or substances (as defined by the Zoning Code TMC 18.06.342, 1$.06.344) at the above CWMI site: 1) Area devoted to such storage shall not exceed 400 square feet of the total area of the warehouse; 2) Customers which use CWMI's waste consolidation service shall not exceed more than 5% of CWMI's total customers served by the Tukwila site; provide revenues for CWMI? - 10-93 ; 16:13 • MAY-10 -93 MON 15:50 Chem Waste Managmen6 2062234990 -4 FAX N0. 2062516679 206 431 3685 ;# 7 P104 mr, R. Mitchell CWMi, 4/29/93 Page 3 Storage and transport shall meet, at a minimum, federal safety standards for such activities per WAC 173 -303. Now that DCD has approved ';your license application, 1 have forwarded it to the Tukwila Fire Department and Building Official for final review. These departments have indicated to me that CWMI will be able to satisfy their requirements. Upon approval by all departments, the City Clerk may issue your business license. Please note that there is a ten day appeal period (TMC 18.90.010) in which you or others may appeal the DCD decision regarding your license. Any appeal must state the reasons for the appeal, and be filed in writing with DCD within 1.0 days from the date of this bkrLLl�'.Y:. 1!4 jr] ;ttj L a ciodu veab £vox asoai lliaa44.Pr<< a soapy 4.£ 4-U 4 a r?or'+4 O4M+11 has been sent to Foster Pepper & Shafelman. Thank you for your 'efforts in working with me to clarify CWMZ Operations. If you have any questions concerning your business license, please contact me at 431 -3670: n Siegent Associate Planner c CONVERSATION RECORD DATE: / / ( / 9 MCN TUE WED 7N FRI SAT SUN TIME: /!0 :M. TYPE: ❑ Visit ❑ Conference elephone— Olncoming Qilutgoing Name of person(s) contacted or in contact with you: Organization (office, dept., bureau, etc.) Location of Visit/Conference: FOR OFFICE USE ONLY SUBJECT: SUMMARY: 74691 A-24,4:te -40 — /QV jile`teic Signature: Title: Date: City of Tukwila Nov 01, 1993 John W. Rants, Mayor Department of Community Development Rick Beeler, Director DAVID LEWIS. , 119 PINE STREET SEATTLE, WA 98101 Dear Permit Holder: Our records indicate that on Dec 08, 1993 one hundred and eighty days will have passed with no inspections having been called for under Tukwila Building Permit Numbe ;It.,:,.„1,..„1 Unless you call for an inspection, or obtain a written extension rom the Tukwila Building Official prior to that date, your above referenced permit will becomd null and void on Dec 08, 1993. If your project has been completed please call for final. If you are actively working on it please notify our office. If you have any questions or need further information to obtain an extension on your permit please call the Tukwila Building Divison at 431-3670. Sincerely, L7? Denise Millard Permit Coordinator Department of Community Development 6300 Southcenter Boulevard, Suite #100 • Tukwila, Washington 98188 • (206) 431-3670 Fax (206) 431-3665 EMERGENCY ACTION AND CONTINGENCY PLAN HAZARDOUS MATERIALS INVENTORY STATEMENT For Chemical Waste Management, Inc. 1120 Andover Park East Tukwila, Washington 98188 Telephone: (206) 575 -2250 Fax: (206) 575 -2260 Presented to: CITY OF TUKWILA DEPARTMENT OF COMMUNITY DEVELOPMENT 6300 SOUTHCENTER BLVD., SUITE #100 TUKWILA, WASHINGTON 98188 1 understand that tho Plan Check cr ;: are subject to errors and omissions c:,., c ._... ;I of plans does not authorize the violation of cny adopted code or ordinance t of contractor'$ copy of approved plane BY Dies „r '3 993 Print.d on r.oyclod p.p.r. TABLE OF CONTENTS SECTION 1 HAZARDOUS MATERIALS INVENTORY STATEMENT SECTION 2 EMERGENCY ACTION & CONTINGENCY PLAN PURPOSE II. FACILITY DESCRIPTION 111. •EMERGENCY CONTACTS IV. ADMINISTRATIVE RESPONSIBILITIES V. INTERNAL NOTIFICATIONS VI. EMERGENCY IDENTIFICATION VII. NOTIFICATION AND REPORTING VIII. HAZARDOUS MATERIALS INFORMATION AND LOCATION IX. EMERGENCY PREPAREDNESS X. FIRE PLAN XI. SPILL (RELEASE) PLAN XII. NATURAL DISASTERS 32 34 38 Page 10 11 11. XIII. BOMB THREATS XIV. DEMONSTRATIONS & STRIKES XV. SYSTEM RELATED. EMERGENCIES RECOVERY. RECEIVED CITY.OF TUKWl LA MAY) 2 19913 PERMIT CENTER TABLE OF CONTENTS CONTINUED SECTION 3. FIGURES V -A INTERNAL NOTIFICATION, FLOWCHART VI -A EMERGENCY IDENTIFICATION FLOWCHART VII -A.- AGENCY NOTIFICATION CHART HAZARDOUS MATERIALS INVENTORY STATEMENT Page 1 of 43 pages 2. Business Name: Chemical Waste Management, Inc. 3. Date: May 11, 1993 4. Facility Address: 1120 Andover Park East Tukwila, WA 98188 (206)575 -2250 5. Location of this storage facility: Tukwila, WA 6. Type of Storage: (Check all that apply for this facility) Aboveground Waste Materials Underground Waste Treatment System Hazardous Materials only - not a Hazardous Waste Generator Yes No 7. - Do you store any carcinogens? (If yes, attach a list of all carcinogens, the quantity range and a copy of the Carcinogen Registration Form for each). Yes No Do you claim .any hazardous materials to be trade secrets? You must ,also provide on this form the number of materials claimed to be trade secrets, their hazard class, and quantity range for each hazard class. • Use the table on the following ppage:to list hazardous:materials stored at the facility.: List all wastes separately and precede the chemical name with "waste ", e.g. "waste oil.." (DOT hazard class UN or NA number'can be obtained from Code of Federal Regulations, Title 49, Part 172.101, Hazardous Materials Table, Or shipping papers for' your. chemical: and wastes.. No waste. Chemical inventory provided in Section 2- VIII, page:11. 10.• Declaration Under penalty of perjury, -I declare :that the. information provided as part of this hazardous materials inventory statement is true and. correct. wt EMERGENCY ACTION AND CONTINGENCY PLAN I. PURPOSE The purpose of this Emergency Action and Contingency Plan is to provide employees of Chemical Waste Management, Inc. (CWM) essential information and guidelines to effectively respond to emergency situations. CWM is continuously developing, revising, and training CWM employees on Standard Division Practices (SDP) regarding maintenance and use of - equipment, hazardous materials, and waste management in order to mitigate potential emergency situations. A review of the emergency planning . procedures will be conducted on at least an annual basis. Required changes will be included within this document. These changes include significant new or revised processes or procedures that may affect emergency planning. IL FACILITY DESCRIPTION A. BUSINESS INFORMATION Division Offices Chemical Waste Management, Inc. 1120 Andover Park East Tukwila, Washington 98188 Telephone: (206) 575 -2250 Fax: (206) 575 -2260 Chemical Waste Management 11330 SW Clay St. Sherwood Or. 97140 Telephone: (503) 682 -2341 Fax:. (503) 682 -8353 Region Headquarters. Chemical Waste Management, Inc. 4227 Technology Drive. Fremont, California 94538 -4926 Telephone: (510) 770 -0575 Fax: (510) 656 -0566 Corporate Headquarters Chemical Waste Management, Inc. 3001 Butterfield Road Oak Brook, Illinois 60521 Telephone: (708) 218 -1500 Fax: (708) 572 -0203 CURRENT BUSINESS ACTIVITY Business activities conducted by CWM Technical Services includes contracted transportation of hazardous materials and waste, engineering services, waste management and transfer services and activities ancillary to these. Standard Industry Codes (SIC) include 4213, 8711, .9511.. FACILITY LOCATION / LAYOUT, The CWM facility in Tukwila is located in an industrial area off '180th (see Figure II -A). The facility is bordered on all sides with warehouse operations manufacturing or industrial developments. III. EMERGENCY CONTACTS A. Chemical Waste Management 1. Site Phone Number (primary) (206) 575 -2250 (alternate) (510) 770-0575 2. Site Fax Number (primary) (206) 575 -2260 (alternate) (510) 656 -0566 B. CHEMICAL WASTE MANAGEMENT, INC. PERSONNEL 1. Primary Contacts a. Emergency Coordinator (EC) Robert Mitchell Pacific Northwest Operations Manager' 22352 126th. Place SE Kent, WA 98031 Work Phone: ' (206) 575= 2250 Home Phone: (206) 630 -4351 Pager: 1- 800 -SKY -PAGE . PIN# 2775912 First Alternate . Paul Porter Operations Supervisor 21417 112th. Avenue SE Kent, WA 98032 Work Phone: (206) 575 -2250 Home Phone: (206) 859 -8164 c. Second Alternate Chris Zepernick Rust Operations Manager 7119 N.E. 101st Avenue Vancouver, Wa 98662 Work Phone (206) 575 -2250 Home Phone (206) 253 -5465 2. Support Personnel a. Terrence Virnig Northwest Technical Services Manager 3290 Top View Court West Linn, OR 97140 Work Phone: (503) 682 -2341 Home Phone: (503) 635 -2620 b. Kirk Brower Environmental Manager 97 S.W. Kingsgate Road Apt #J -32 Lake Oswego, OR 97035 Work Phone (503)682 -2341 Home Phone (503) 620 -5234 Pager: 1 -800- SKY -PAGE PIN #8626538 c. Andrea Bittinger. Pacific Northwest Health and Safety Manager 22180 S.W. Martinazzi Avenue Tualatin, OR 97062 Work Phone (503) 682 -2341 Horne Phone (503) 691 -2860 Pager: 1 -800- SKY -PAGE PIN# 2222144 d. Jim Bushnell, C.I.H. Rust Health and Safety Manager 6808 37th Avenue NE Seattle, WA 98115 Work Phone (206) 575 -2250 Home Phone (206) 523 -8658 Pager: 1- 800 - SKY -PAGE PIN# 5222345 e. Bob Brown Regional Health and Safety Manager 4227 Technology Drive Fremont, CA 94538 -6337. Work Phone: (510) 770 -0575 Home Phone: (510) 236 =6260 Mark DeFrances Communications and Marketing Manager.. Northern California/ Pacific Northwest 4227 Technology Drive Fremont, CA 94538 -6337 Work Phone: (510) 770 -0575 Home Phone: (415) 775 -2950 Michael Dory Human Resources Manager 4227 Technology Drive Fremont, CA 94538 -6337 Work Phone: (510) 7.70 -0575 Home Phone: (510) 606-1298 MEDICAL PROVIDERS 1. Virginia Mason Occupational Clinic 6720 Southcenter Boulevard; Suite 110 Tukwila, WA 98188 (206) 242 -3651 Valley Medical Center 400 S. 43rd Sreet Renton, WA 9 (206) 228 -3450 (206) 251- 5185 - Emergency . CITY OF TUKWILA SERVICES 1. City of Tukwila Fire Department, phone: a. 911, or b. (206) 575 -4404 2. City of Tukwila Police Department, phone: a. 911, or. b. (206) 433 -1804 3.. City of Tukwila Public Works. Department a. Sewer Emergencies, Phone: (1). (206) 433 -1860, or (2). After 5:00 pm, weekends, and holidays (206) 433 -1808. b. Storm Drain / Flood Emergencies, Phone: (1). (206) 433 -1860, or (2). After 5:00 pm, weekends, and holidays (206) 433 = 1808. Water Emergencies, Phone: (1). (206) 433-1860, or (2). After .5 :00 pm, weekends, and holidays (206) 433 -1808. • COUNTY County 'Emergency Management Civil Defense, Phone: (206) 296- 3830 2. County Department of Public Health, Phone: (206) 296 -4692 F. STATE AGENCIES 1. State Office of Emergency Services (OES), Phone: (206) 753 -2095 2. Washington Department of Ecology MS: PV -11 Olympia, WA 98504 -8711 Phone: (206) 459 -6322 Northwest Regional Office 3190 160th Avenue SE Bellevue, WA 98008 -5452 Phone: (206) 649 -7000 3. Air Quality Management District P.O. Box 47600 Olympia, WA 98504 -7600. Phone: (206) 459 -6255 Water Quality Control Board P.O. Box 47600 Olympia, WA 9985 04 -7600 Phone: (206) 459 -6327 . FEDERAL AGENCIES 1. National Response Center Phone: (800) 424 -8802 • 2. U.S. Environmental Protection Agency. Region X 75 Hawthorne Street Seattle, WA 94105 Phone: (206) 553 -1200 Emergency: (206) 553 -1263 e C 3. Department of Fish and Game Phone: (206) 753 -6600 4. U.S. Coast Guard Phone: (206) 286 -5400 IV. ADMINISTRATIVE RESPONSIBILITIES A. EMERGENCY COORDINATOR (EC) The EC is responsible to maintain an adequate state of emergency preparedness. Specific duties include: 1. Establishing and maintaining a liaison with local fire, police and appropriate specialized contractors. Regularly reviewing the staff for emergency preparedness. In conjunction with the Emergency Support Committee; developing, executing and documenting at least quarterly, tests, and exercises of the various components of the plan. ▪ Report annually to the Corporate Security Department regarding program status. . Serve as "Incident Commander" during emergency functions, taking charge of: a. Assessing the situation and possible hazards, ordering evacuations, medical care, shutdowns, etc.. . Activating internal facility or communications systems to notify all facility personnel. ▪ Notifying appropriate state or local agencies and site and corporate personnel with designated response roles. Directing other incident specific activities as outlined in -. the site plan. d. c e. Assuring measures to ensure that fires, releases, explosions, etc., do not occur, recur, or spread. The EC will utilize members Support Personnel, as necessary, for response activities. B. HEALTH AND SAFETY COORDINATOR Advises on health and safety aspects of emergency management. Includes determination of personal protection equipment (PPE), monitoring and decontamination recommendations. C. ENVIRONMENTAL MANAGEMENT COORDINATOR Advises on environmental issues. Includes regulatory required reporting, spill containment and clean -up activities. D. COMMUNICATIONS COORDINATOR Writes and /or delivers press releases regarding the on -going incident. Places and answers phone calls / communications to and from: fire department, police department, other contractor personnel and regional /corporate management personnel. V. INTERNAL NOTIFICATIONS Any CWM employee discovering a fire, explosion, chemical release, or hazardous situation must notify their supervisor immediately. The supervisor will assess the situation .and determine if an emergency exists. If a situation is more than minor incidental event, the supervisor will notify the Emergency Coordinator (minor incidents involving a chemical release or health and safety issues must still be reported to the EC or Health and Safety. Coordinator respectfully within 24 hrs). The Emergency Coordinator (EC) is the principal individual in an emergency. 9 and will serve as the central contact. Upon notification of an incident, the EC will assess the information available and determine further action. The EC will contact external primary emergency responders (Fire Dept., Police / Sheriff, Ambulance, etc.)and regulatory agencies requiring immediate verbal notification. The EC will oversee and coordinate with facility staff, emergency contractors. (if required), and regulatory agencies involved in emergency and remedial response (see Internal Notification Flowchart, Figure V -A). All CWM technical staff are trained in handling emergencies and chemicals. CWM staff will provide first responder actions within their training for any emergency until the EC is able to take control. VI. EMERGENCY IDENTIFICATION In this plan, emergencies are categorized into four general groups identified below: A. SPILLS (RELEASES) OF MATERIALS OR WASTES B. FIRES C. EXPLOSIONS, INCLUDING BOMB THREATS D. DISASTERS CAUSED BY NATURE Figure VI -A, Emergency Identification Flowchart, establishes guidelines for the discoverer of the emergency for reporting the incident. Minor spills of non- hazardous materials need not always be immediately reported to the EC. However, these incidents must be reported within 24 hours. Individual response plans for the groups identified above are, addressed subsequent sections of this document. VII. NOTIFICATION AND REPORTING In the event of a hazardous material, substances, or waste release, the EC. (or the Environmental Manager) will be responsible to notify regulatory agencies. The Figure V11 -A, Agency Notification chart, identifies the agencies to be notified in the event of a hazardous material, substance, or waste release: VIII. CWM HAZARDOUS MATERIALS INFORMATION AND LOCATIONS The following hazardous materials and wastes are stored in three general areas at the Tukwila facility: A ADMINISTRATION BUILDING DESCRIPTION Inks / toners Aerosols HAZARD QUANTITY Flammable / 5 gal Toxic Flammable / 10 aerosols, Toxic Window Cleaner Corrosive 2 pints Cleanser Corrosive / 5 lbs. Oxidizer Liquid Paper Flammable / 1 gal Toxic Liquid Paper Thinner Flammable, / 1 g Toxic Alkaline batteries Corrosive 5 lbs. SHOP BUILDING AND SURROUNDING AREA DESCRIPTION HAZARD QUANTITY Miscellaneous oils and Flammable / 10 gals lubricants combustible Diesel fuel Combustible 10 gal Unleaded fuel Antifreeze Alkaline cleaners Propane Flammable / 10 gals toxic' combustible / 1 gals toxic Corrosive 5 gals 2 small cylinders Flammable / toxic Oxygen Oxidizer 1 cylinders Acetylene Flammable / " 1 cylinders toxic, Window Cleaners Flammable /" 2 gals toxic Aerosols : Flammable / . 20 cans toxic Hexane Flammable 11 gals Acetone Flammable 1 gal Paint Thinner Flammable 1 gal Lacquer Thinner Flammable 1 ,quart Isopropyl Alcohol Flammabler 15 gals Methanol Flammable Methylene Chloride Toxic NAOH pellets Corrosive NAOH 10% solutions Corrosive Sodium Bicarbonate Corrosive Paint Stripper . Toxic Sulfuric Acid Corrosive 300 ml. Ferric Sulfate 10% Corrosive 200.m1. Ferric Chloride 10% Corrosive 200 ml. Sodium Hydroxide 10% Corrosive 100 ml.. Hydrochloric Acid 10% Corrosive 10 ml. Ferric Sulfate Corrosive 100 grams Ferric Chloride Corrosive : 900 grams Ferrous Sulfate Corrosive = 500 grams Muriatic Acid : Corrosive. 3 gals Sulfur Toxic 1 kg Citric Acid Corrosive 5 kg Less than 10. Chemical Corrosive 6 gals Solutions International Cleaner C. WASTE TRANSFER AREA DESCRIPTION HAZARD Flammable Liquids Locker Corrosive Material Oxidizer Other Toxic Material Flammable / combustible / toxic Corrosive / toxic Oxidizer / corrosive Toxic Quanitities of material in this category will not exceed the number than can be stored in one truck trailer. All material will be packaged in accordance with all applicable Transportation Regulations. At no time will these drums be staged on the warehouse floor. IX. EMERGENCY PREPAREDNESS A. TRAINING All personnel receive initial and annual instruction in the purpose and implementation of the site contingency plan. At least one site contingency plan drill and critique will be preformed annually. A number of facility personnel have been trained to provide first aid and CPR, At least one person per work area per shift is current in First Aid /CPR certification. . ARRANGEMENTS WITH LOCAL HOSPITALS AND AUTHORITIES The local fire department (identified in Section III(D)(1)and medical facilities (listed in the Section III(C)(1) and (2)) have received a copy of this plan, and have been invited to meet with the EC regarding any concern regarding this plan. C. SECURITY / ALARM SYSTEMS Security at the various facilities include: 1. CWM Facility The area where the hazardous materials are stored is secured. During normal working hours, the only access is via the receptionist. During off hours, only management personnel and other staff personnel with an immediate need are allowed on -site. Emergency alarm system consists of internal and external PA systems, as well as an interanl phone system within the facility. Further, all company vehicles are equipped with two -way radios of the same frequency as the site radio. Once initial notification of emergency situations are made, supervisor personnel will "cascade" the information to uninformed personnel. 2. Off -Site Services Operations which extend over multiple days may be fenced and locked during off - hours. During working hours, all site access is controlled by the supervisor in charge. As part of the site specific contingency plan development, as well as a Tailgate topic, the site alarm system will be described in detail. Included will be different alarms and their meanings as well as methods for "setting off" the alarm by. CWMI personnel. As soon as possible, contact will be made by radio or phone with the home office. S. Transportation Services In case of emergency situations during transportation activities, the driver shall contact public emergency services and the CWM office as soon as possible by two -way radio (including citizen band) or telephone. 15 E. INSPECTION Routine inspections are made every two weeks to identify any conditions which might lead to an injury or other emergency. A checklist is used to facilitate a thorough inspection. Hazardous waste accumulation areas and storage areas are inspected weekly, to verify the integrity of containers. . EMERGENCY SHUTDOWN In the event of an emergency situation, the EC will decide if critical equipment or utilities must be shut down. Designated site personnel will complete the shutdown activities. In situations where immediate shutdown is required, the manager or foreman for the department, location or job site may make the shutdown decision. Examples of critical equipment includes: 1. Computers. 2. Heavy equipment. 3. All utilities. . EVACUATION 1. CWNI Facility The EC will determine if evacuation of personnel from the facility is required. All non - essential personnel (as determined by the EC) will immediately leave the facility through the exit routes posted. Employees are to report to their supervisor at the primary designated area. Should the primary designated area be inaccessible due to the incident, an alternate area will be used to account for employees. Department managers will be responsible to account for their department personnel. Visitors and contractors will be the responsibility of employees whom they are visiting or the contract administrator. CWM primary and secondary evacuation routes are posted in all facility offices. 2. Off -Site Services X. FIRE PLAN • For remote job sites, evacuation procedures must be developed and included in the EMD Approval /Site Contingency Plan. All personnel will be required to review and understand these procedures during the Tailgate Safety Meeting. NOTE: All evacuation routes and procedures must be developed and implemented in conjunction with site- specific requirements. Use the site contact to determine appropriate action. GENERAL The foundation of this plan is fire prevention. The likelihood of a fire at the Tukwila facility is no more than at other warehousing operations. However, in the event of a fire, control will be left to the fire fighting professionals. Employees, trained in the proper use of fire extinguishers, may quell fires only in the incipient stage if the safety. of the employee is not jeopardized: . PLAN IMPLEMENTATION The plan will be implemented when an employee or other person notifies the Emergency Coordinator (EC) of a fire. The EC will: 1. Amass information from the employee, such as a. Are personnel injured? b. Location of fire. Size of fire. Hazard potentials. Possible fire suppression measures. The EC may also personally observe the incident to properly evaluate the situation. . Evaluate the situation, and prescribe emergency counter measures, which may include: a. Evacuation of the facility. . Contacting emergency services (Fire Department, Police, Ambulance). c. Verbal notification of required agencies. : ▪ RESPONSE PLAN 1. Minor Fires a. CWM Facility (1). Rescue injured personnel, if possible / necessary. (2). Identify potential hazards / material involved. (3). Evacuate area., (4). Notify supervisor / activate alarm, if necessary (5). Notify Health and Safety Manager (6) Verbally: notify agencies, if required. 18 C (7). Control and contain fire with emergency equipment. (a). Health and Safety Manager or the supervisor may determine whether the incident may be managed by on -site personnel. (b). Notify Fire Department (911). (8). Place debris and materials used in the clean -up is in containers, labeled, and dispose as hazardous waste. (9). Complete an incident report and forward to the Health and Safety Manager, and copy to the EC. (10). Complete written notifications to agencies, if required. (11). Conduct a formal critique of the incident and associated actions which result in a written report including recommendations for improvement. NOTE: Fire extinguishers are located in various places within the facilities. Employees should always be aware of the closest extinguisher. Off-Site Services Rescue injured personnel, if possible / necessary.. (2). Identify potential hazards / material involved. Evacuate area. (4). Notify supervisor. (5). Notify client. The client may implement their facility response plan, however, should the client allow UEI to continue, management of the incident, the following steps should. be observed: (6). Control and contain fire with emergency equipment. (a). Health and Safety Manager or the supervisor may determine whether the incident may be managed by on -site personnel. (b). Notify Fire Department (911). (7). Verbally notify agencies, if required. (8). Place debris and materials used in the clean -up is placed in containers, labeled, and disposed as hazardous waste. (9). Notify dispatch. (10). Complete an incident report and forward to the Health and Safety Manager, and a copy to the EC. (11). Complete written notifications to agencies, if required. (12). Conduct a formal critique: of the incident and associated actions which result in a written report including recommendations for improvement. All Other Fires CWM Facility (1). Rescue injured personnel, if possible / necessary: (2). Identify potential hazards / material involved: (3). Evacuate area. (4). Notify supervisor. Notify EC, Notify Fire Department (911). Verbally notify agencies, if required. (8). Facility evacuated, if required. (9). Place debris and materials used in the clean -up is in containers, labeled, and dispose as hazardous waste. (10). Complete an incident report and forward to the Health and Safety Manager, and copy to the EC. (11). Complete written notifications to agencies, if required. (12). Conduct a formal critique of the incident and associated actions which results in a written report including recommendation for improvement b. Off -Site Services (1). Rescue injured personnel, if possible / necessary. (2). Identify potential hazards / material involved. (3). Evacuate area. (4). Notify supervisor. (5). Notify client. The client may implement their facility response plan, however, should the client allow CWMI to continue management of the incident, the following steps should be observed. (6). Notify Fire Department (911). (7). Verbally, notify agencies, if required. (8). Facility evacuated, if required. (9). Notify dispatch / EC Place debris and materials used in the clean -up is in containers, labeled, and dispose as hazardous waste. C (11). Complete an incident report and forward to the Health and Safety Manager, and copy to the EC. (12). Complete written notifications to agencies, if required. (13). Conduct a formal critique of the incident and associated actions which result in a written report including recommendations for improvement. Emergency phone numbers are included in the Site Health and Safety Plan, EMD Approval and in the "Tailgate Safety Meeting Forms ". Make contact with emergency response agencies and sound appropriate alarms as soon as possible. c. Transportation Services (1). Park vehicle in a secure area, away from: (a). Residential areas. (b). Business districts.. (c). Traffic. (d). Sewer Systems. (2). Do not abandon the vehicle, but stay upwind from the fire. (3). Identify potential hazards / material with use of the manifest, bill of lading, or Emergency Response. Guide (ERG). (4). Flag Highway Patrol or other emergency service. (5). Contact dispatch, if possible and provide the following information: (a). Proper shipping name, hazard class, and ID number of materials. (b). CWM waste profile number. (c). Exact location. (d). Quantity of material spilled. (e). Location and distance to any streams, rivers, lakes or sewers. (f). Nature and extent of any injuries or property damage. (g). Name of government agencies on the scene, a business card would be preferable. Identify each regulatory representative with whom you have discussed the incident, such as: (i). Name. (ii). Representing agency. (iii). Office phone number. (h): If media or press are on the scene. (i). A telephone number where communications' with the scene can be established. (j).. An estimate of response and clean -up needs. (9). Warn all persons (excluding emergency responders) to keep away from the area (minimum distance 500 feet, actual distance to be determined by the D.O.T. [ERG)). (7). Protect manifest, paperwork, instructional materials and protective equipment for later use (9). Maintain communications with the dispatcher at a maximum of 30 minute intervals, where possible, unless otherwise. instructed. (10). Discussion of the incident (with persons other than UEI /CWI personnel) may be only with those. persons representing governmental agencies (eg. police, federal, state, county, or local health / environmental agencies, CHP, DOT, etc.). (11). Report only the facts, as you know them (refrain from adding personal comment). C (12). Provide all requested documentation (such as the Hazardous Waste Manifest, Bill of Lading, Material Safety Data Sheet - MSDS, Chain of Custody, Driver. Log, Emergency Response Guide book), however, these documents are not leave your possession. (13). Under no circumstances are you to discuss the incident with the media or news press (i.e., news reporters, cameramen, etc.). Press releases will only be handled by a designated CWM representative. (14). In most cases, CWM will provide emergency response services to remedy any contamination. (15). Place debris and materials used in the clean -up is in containers, labeled, and dispose as hazardous waste. Complete an incident report and forward to the Health and Safety Manager, and copy to the EC. Complete written notifications to agencies, if required. .(18). Conduct a formal critique of the incident and associated actions which result in a written report including recommendations for improvement. e XI. SPILL (RELEASE) PLAN A. GENERAL Spill and release incidents may be significant threats to heath, safety, and the environment. Control of spills or releases requires the talents of trained personnel. The likelihood of a large spill at the Kent facility is remote. B. RESPONSE PLAN 1. Small Spills a. CWM Facility (1). Rescue injured personnel, if possible / necessary. (2). Identify potential hazards. (a). Material involved. (b). Location (c). Threat to sewer system. (d). Migration off -site. (3). Evacuate area (4). Notify supervisor. (5). Notify Health and Safety Manager (6). Control and contain spill, as authorized by Health and Safety / Environmental Manager. (7). Verbally notify agencies, if required. (8). Place debris and materials used in the clean -up is in containers, labeled, and dispose as hazardous waste. (9). Complete an incident report and forward to. the Health and Safety Manager, and copy to the EC. (10). Complete written notifications to agencies, if required. (11). Conduct a formal critique of the incident and associated actions which result in a written report including recommendations for improvement. b. Off -Site Services (1). Rescue injured personnel, if possible ,/ necessary. (2). Identify potential hazards. (a). Material involved. (b). Location (c). Threat to sewer system. (d). Migration off -site. (3). Evacuate area. (4). Notify supervisor. (5). Notify client. The client may implement their facility response plan, however, should the client allow UEI to continue management of the incident, the following: steps should be observed. (6). Notify Dispatch / Health and Safety Manager. Control and contain spill, as authorized by Health and Safety / Environmental Manager. (8). Verbally notify agencies, if required.. (9). Place debris and materials used in the clean-up is containers, labeled, and dispose as hazardous . waste. (10). Complete an incident report and forward to the Health and Safety Manager, and copy to the EC. (11). Complete written notifications to agencies, if required. (12). Conduct a formal critique of the incident and associated actions which result in a written report including recommendations for improvement. Large Spill / Release CWM Facility (1). Rescue injured personnel, if possible / necessary. (2). Identify potential hazards. (a). Material involved. (b). Location (c). Threat to sewer system. (d). Migration off -site. (3).. Evacuate area (4). Notify supervisor. (5). Notify EC. (6): Notify Emergency Services (911), if 'required." (7). Evacuate facility, if required. (8). Control and contain spill, as authorized by Health. and Safety / Environmental Manager. Verbally notify agencies, if required. , Place debris and materials used in the clean -up is in containers, labeled, and dispose as hazardous waste. (11). Complete an incident report and forward to the Health and Safety Manager, and copy to the EC. (12). Complete written notifications to agencies, if required. (13). Conduct a formal critique of the incident and associated actions which result in a written report including recommendations for improvement. Off -Site Services (1). Rescue injured personnel, if possible / necessary. (2). Identify potential hazards. (a). Material involved. (b). Location (c). Threat to sewer system. (d). Migration off -site. (3). Evacuate area. (4). Notify supervisor. (5). Notify client The client may implement. their facility response plan, however, should the client allow UEI to continue management of the incident, the following steps should be observed. (6). Notify Emergency Services (91 1), if required. (7). Evacuate facility, if required. (8). Control and contain spill, as authorized by Health and Safety / Environmental Manager. Verbally notify agencies, if required. (10). Place debris and materials used in the clean -up is in containers, labeled, and dispose as hazardous waste. (11). Complete an incident report and forward to the Health and Safety Manager, and copy to the EC. (12). Complete written notifications to agencies, if required. (13). Conduct a formal critique of the incident and associated actions which result in a written report including recommendations for improvement. c. Transportation Services (1). Park vehicle in a secure area, away from: (a). Residential areas. (b). Business districts. (c). Traffic. (d). Sewer Systems. (2). Do not abandon the vehicle, but stay upwind from the spill. (3). Identify potential hazards / material with use of the manifest, bill of lading, or Emergency Response Guide (ERG). (4). Flag Highway Patrol or other emergency service. (5). Contact dispatch, if possible and provide the following information: (a). Proper shipping name, hazard class, and ID number of materials. (b). CWM waste profile number. Exact location. (d). Quantity of material spilled. (e). Location and distance to any streams, rivers, lakes or sewers. (f). Nature and extent of any injuries or property damage. (g). Name of government agencies on the scene. Identify each regulatory representative with whom you have discussed the incident, such as: (i). Name. (ii). Representing agency. (iii). Office phone number. A business card would be preferable. (h). If media or press are on the scene. (i). A telephone number where communications with the scene can be established. (j). An estimate of response and clean -up needs. (6). Warn all persons (excluding emergency responders) to keep away from the area (minimum distance 500 feet, actual distance to be determined by the D.O.T. [ERG]). (7). Protect manifest, paperwork, instructional materials and protective equipment for later use. (9). Maintain communications with the dispatcher at a maximum of 30 minute intervals, where possible, unless otherwise instructed. (10). Discussion of the incident (with persons other than ,. CWM personnel) may be only with those persons representing governmental agencies (eg. = police, federal, state, county, or local health / environmental agencies, CHP, DOT, etc.). (11).. Report only the facts, as you know them (refrain from adding personal comment). (12). Provide all requested documentation (such as the Hazardous Waste Manifest, Bill of Lading, Material Safety Data Sheet - MSDS, Chain of Custody, Driver Log, Emergency Response Guide book), however, these documents are not leave your possession. (13). Under no circumstances are you to discuss the incident with the media or news press (i.e., news reporters, cameramen, etc.). Press releases will only be handled by a designated CWM representative. In most cases, CWM will provide emergency response services to remedy any contamination. Place debris and materials used in the clean -up is in containers, labeled, and dispose as hazardous waste. Complete an incident :report. and forward to the Health and Safety Manager, and copy to the EC. (17). Complete written notifications to agencies, if required. (18). Conduct a formal critique of the incident and associated actions which result in .a written report including recommendations for improvement. XII. NATURAL DISASTERS Natural disasters can occur in many forms, but all generally affect large areas and many people in relatively brief period of time. Natural disasters will often place a considerable strain on local government support agencies (fire, police, civil defense). Natural disasters may cause other emergency situations simultaneously (for example, an earthquake may cause fires, injuries, spills or explosions). The actions identified in this plan are general, and should supplement local government programs and existing plans that are more comprehensive. A. TORNADOS Tornados are not common in the Western U.S. and will not be addressed in this plan. B. HURRICANES Hurricane force winds and gusts may occur on the West Coast, however, there is advance warning of their approach through the media, and therefore a contingency may be planned. High winds may directly impact transportation services and off -site services. Gusts can cause heavy materials to be hurled about causing damage and /or injury. Electrical power and related hazards must also be considered, C. EARTHQUAKES Earthquakes in the U.S. occur most frequently West of the Rocky Mountains, but damaging earthquakes can occur in most states. This is a natural disaster that typically offers very little or no advance warning. Casualties usually occur as a result of falling objects and debris, splintering glass, and fires. Fire exposures are particularly increased by ruptured gas and electrical lines and aggravated by damaged water mains and fire suppression systems. Coastal areas may also be affected by tidal waves (tsunamis) that could be caused by near or distant earthquakes. Additional sections of this Emergency Action Plan may be relevant during or after an earthquake may include Section IX, Emergency Preparedness, Section X, Fire Plan; Section XI, 32 Spill (Release) Plan. 1. Preparatory Activities Most preparatory activities for an earthquake involve careful design, construction, maintenance of structures and equipment, and thorough safety training of personnel. Specific preparatory activities may include: a. Bolting down water heater and gas appliances. b. Checking the integrity and flexibility of gas and electrical connections. c. Placing large and heavy objects on lower shelves, and securely fastening shelves to walls, d. Bracing or anchoring other high or top -heavy objects. a. Storing bottled goods, glass and other breakables in low or closed cabinets. f. Anchoring hanging objects such as overhead lighting fixtures. Keeping on hand batteries, portable radios, flashlights, . drinking water, nonperishable foods and a sufficient number of fire extinguishers and first aid kits. . During an earthquake: a. Keep calm. Don't run or panic. b. Stay where you are. If indoors, stay indoors. Most injuries occur as people are entering or leaving buildings. c. If indoors; take cover under a desk, heavy table or bench, or against inside walls and doorways. Stay away from glass, windows and outside doors. Don't use candles, matches or open flames either during or after the tremor. Douse all fires. If outdoors; move away from buildings and utility wires. C f. If in a moving car, stop but stay in the vehicle. Avoid stopping near or under buildings, overpasses and utility wires. 3. After an earthquake: a. Be prepared for additional tremors or "after- shocks ". b. Address injuries and orderly evacuations as specified under "Medical Emergencies" and "Personnel Movement c. Continue to monitor radio for latest information on the emergency from the local authorities. . Check water, gas and electrical lines and valves for damage or leaks. e. Assure sewage lines are intact before using sanitary facilities. f. Restrict access to downed power lines or objects in contact with downed lines. If electrical wiring is shorting out, shut off current at the main box. Use telephones only for essential emergency purposes. . FLOODS Floods are not :a major concern at the: Tukwila /Transportation facility. When working at customer sites with flood zones, follow directions of their plans. XIII. BOMB THREATS Bombs and the threat of their use is a common tool of terrorists and criminal extortionists, but .they most frequently occur, as a means of retaliation by employees, ex- employees and others with real or imagined grievances. f The vast majority of bomb threats are threats only, with no actual or intended explosive device. The desired effect of such a threat is to extort, embarrass, disrupt, frustrate, panic or cost the targeted manager or operation. On the other hand, enough actual bombings occur to warrant prudent planning and minimum safeguards. This portion of the Emergency Action Plan will deal with preventive measures and the proper and safe handling of actual threats. A. PREVENTIVE MEASURES The most basic preventive measure is to properly secure a facility so that an explosive device cannot be easily placed. The physical security measures are summarized in PAD A310, "Physical Security Procedures ". Further support in security can be provided by the Corporate Security Department. A higher probability of bombs or bomb threats due to a history of past threats, a neighborhood or community trend, or a situation involving a particularly vengeful individual may warrant more extensive measures such as more stringent security, training programs, package inspections, ore involved search and evacuation procedures and recorders on appropriate phones. Such a higher probability will also warrant more contact with local law enforcement authorities. In any case, local law enforcement agencies can often provide support such as pamphlets, training and assistance with planning. Many departments have bomb control and disposal specialists who can offer.. extensive support. MANAGEMENT OF RECEIVED BOMB THREATS 1. Phoned in Bomb Threats Keep the caller on the line as long as possible. If possible, record the conversation. Use the attached checklist during the call to freshly note all relevant information. If not indicated, ask the caller for the location of the bomb and the time of possible detonation. c. Inform the caller that the building is occupied, and the detonation of a bomb could result in death or injury to many innocent people. d. Pay particular attention to peculiar background noises such as motors running, music, and any other noise which may give a clue as to the location of the caller. e. Listen closely to the voice (male or female), voice quality (calm, excited), accents, unique phrasing, and speech impediments. Does this voice immediately remind you of a certain individual? If so, note it. f. Report the call and gathered information immediately to the EC. g. The EC will notify local police and fire departments. 2. Written Bomb Threats a. Save all materials, including any envelope or container. b. Once the message is recognized as a threat, further unnecessary handling should be avoided. Every possible effort must be made to retain evidence such as fingerprints, handwriting or typing, paper, and postal marks which are essential to tracing the threat and identifying the writer. c. Report the threat immediately to the EC. d. The EC will notify local fire and police departments. 3. Threat analysis A determination should be made as to the credibility of the threat. For example, authentic threats tend to be more specific as to time and location while false threats tend to be very general and broad. This analysis should be made with the close direction and assistance of the policy or fire departments. In making this analysis, consider: a'. Time of day and day of the week. b. Mode (telephone, mail). c. Specificity of threat (place, time). d. Identity of caller (male, female, child). e. Attitude (serious, prankster). f. Possibility of access to allow placement of explosive device. 4. Threat Response The proper response to the threat may be: a. Ignore the warning. b. Conduct limited search of specific area. c. Conduct general search of facility. d. Order limited evacuation of a particular area. e. Order general evacuation. See Section IX, Emergency Preparedness for evacuation. procedures. . Searches The decision to search for a possible bomb should be carefully made with the close interaction between the EC and the police or fire departments. The best search team is made up of volunteers, who are familiar with the search area, working along with trained fire or police department personnel. Specific areas should be assigned to each searcher or search team. The EC and law enforcement personnel should coordinate from a central location to allow for easy response from the searchers. The searchers should look for and check: a. Threatening labelling such as "danger ", "explosive ". b. An item that fits the threat description. c. An item that appears to be "out of place" or unrecognized. d. An object making strange noises. e. Near entrances (inside and outside of doors). f. Near exits. g. Around and in waste . receptacles. h. In rest rooms, phone booths, store rooms, closets, . stairwells, hallways, and in nearby vehicles. Should suspicious objects be found, they are NOT TO BE TOUCHED. The should be immediately reported to the EC and police. XIV. DEMONSTRATIONS & STRIKES Although demonstrations are not expected at.CWM offices offices are non - union, these are not expected: Only the EC or their delegate is authorized to speak with demonstrators or the news media. The EC will determine if outside resources are required to prevent disruption to the management of the facility. and since all XV. SYSTEMS RELATED EMERGENCIES A systems disaster is defined as a major disruption to the equipment or facility that prevents access to or processing of data that is essential to the operation of the facility. In case of systems emergencies, CWM data may be processed at the CWMI office in Sherwood,Oregon. XVI. RECOVERY Only in extraordinary circumstances will a facility be totally demolished by a disaster. As a consequence, facilities for re -entry will be in varying stages of disrepair, and certain steps should be followed prior to re- entry. A. STRUCTURAL INTEGRITY All structures that appear to have significant structural damage shall not be reoccupied until a qualified engineer or contractor makes the determination for re- entry. Additionally, buildings and grounds should be examined for precarious equipment, structures or furniture, live and exposed electrical wiring, escaping gas, dangerous chemicals and /or damaged bottles or tanks of oxygen, acetylene, etc. Areas that can be safely reoccupied should then be identified, and priority functions should be given the use of those areas. Usable equipment, tools, supplies, furniture, etc. should be cleaned (if necessary) and put back to use or stored in a secure and safe holding area. B. DECONTAMINATION Immediately after the emergency, any recovered waste, contaminated soil or other materials will be appropriately isolated and disposed. Care will betaken not to combine incompatible wastes. Decontamination procedures shall . be followed before returning previously contaminated items back to service. . EMERGENCY EQUIPMENT After an emergency event, all emergency equipment that has been used will be cleaned, repaired or recharged so that it is fit for use or will be replaced. An inspection of all safety equipment shall be 39 conducted before any re- occupancy or operations are resumed. The Division Health and Safety Manager will coordinate these activities. PERSONNEL SUPPORT The Communications Manager will review the personal effects the . emergency and coordinate support activities. The EC shall coordinate, as necessary, a team to assess the community effects. FIGURE V -A INTERNAL NOTIFICATION FLOWCHART EMPLOYEE SUPERVISOR. EMERGENCY. DISCOVERED NO YES CWM EMERGENCY.. COORDINATOR SUPPORT. PERSONNEL PRIMARY EMERGENCY RESPONDERS (911) CONTROL CONTAIN`. NOTIFY HEALTH & SAFETY OR MANAGER:. EMERGENCY RESPONSE. CONTRACTORS REGULATORY AGENCIES • • FIGURE V! -A :.. . ...' :...-'„' :.:::,•:':-::„''-.'--',,...-.-..;:''..'-':'1-.::....::..::.-,.::.::,:--::-..:.-::•::,:::.-•:-..:.-.-.v:;-.•.:.,;-.,:--„..",-.....-..,. . --:„-2 '•-,.:... -.: . .:-: ..:-,:..- ,..•:,-l.',::-' -- .:.,'-'--':i''i' -.•. :..::-..••.: •, •..•..•:' .;-.- . - ••:- • • • ' •- . -. ' - , . . - EMERGENCY !QENTIFICATlON FLOWCHART . v EMERGENCY DISCO COVERED SPILL /RELEASE FIRE NATURAL EXPLOSION DISASTERS YES FIRE_OR YES. SPILL OR • EXPLOSION. EXPLOSION RELEASE NOTIFY EC -., ' POTENTIAL? POTENTIAL? INVOLVED? NO NO NO • RISK: OF IS HAZARDOUS SEE SPILL • • YES .GENERATING YES: MATERIAL RELEASE • TOXIC SUBSTANCE I 1.::::-.:.... FUME • FUME' . OR • .,;.., WASTE INVOLVED? FIRE INVOLVED? • I NO ) ! . NO ` NO H Ga z c'. O a oa • 0 • H. SEE EXPLOSION z z 0a f7 H Ig. O H •-• o Z W W aO K XE403 3 u)HHWW HH. c!) H U) 00 U 4. w H Ei W 0:• • Z, xw wt 0 Qs z RELEASE SITUATION CITING FIGURE VII -A AGENCY NOTIFICATION CHART IMMEDIATE WRITTEN REPORT CERCLA hazardous substance NRC / OES CERCLA / SARA / (40 CFR, Part 302.4) above King County RCRA /.CA Health the reportable Quantity (RQ) and Safety Code / CCR, Title 22 Extremely hazardous substance SARA (40 CFR, Part 355) above RQ 011 or fuel, more than 1,000. Clean Water Act / gallons or "harmful quantity" CA Water Code or RQ substance into or upon navigable waters • • Oil or fuel, more than 42 gallons OES / DOE OES / King County OES / DOE DUE DATE No later than thirty days No later than thirty days NRC / OES / RWQCB EPA Region X /DOE No later than sixty days . NRC.= National Response Center OES Office' of • Emergency Services RWQCB . Regional .Water Control Board smayea CHEMICAL MATERIAL SAFETY DATA SHEET EXXON CHEMICAL AMERICAS • P.O. BOX 3272. HOUSTON. TEXAS 77001 A O,v,s,on of EXXON CHEMICAL COMPANY, A O,v,sson ot,EXXON CORPORATION 05/11/89 PAGE 1 NO.9203CCCC SECTION 1 PRODUCT IDENTIFICATION & EMERGENCY INFORMATION PRODUCT NAME . • • Acetone CHEMICAL NAME 2- Propanone " • ' ' ' CAS 67 -64.1 CHEMICAL FAMILY Ketone PRODUCT APPEARANCE;CESCRIPTICN .. • , Clear colorless liquid with a cnarac:eristic pungent c=r. - EMERGENCY TELEPHONE NUMSE:IS: EXXON CHEMICAL AMERICAS 713- 870 -660Q0 CHEYITREC ' 800- 424 -9300 SECTION 2 HAZARDOUS INGREDIENT INFORMATION This product is hazardous as defined in 29 CFR1910.12CC. OSHA HAZARD .. Flammable .. PEL: TLV ... '. Eye irritant .. .... , •• • • For additional information see Section 3. . ,• .. -'• •! -. . • - SECTION 3 ' HEALTH "INFORMATION & PROTECTION • -.11M1 - .:••. -: -, • . .- .....-- .NATURE_OF-HAZARD EYE CONTACT tT, 4 ;4 .....7• rt 1.i.4:1,--; . ".:4;1_ ;4 •• 15.itn : r _r -.:: .�.. ' '..Irr.itating,..'and ho% .wi.Ll.._injur..e_eye_tissue _it _r,-emaved_promptty , _, ,, _,, _,, SKIN CONTACT: , :. -' .,..,-.;.,7•.,,,.., _ Frequent or prolonged contact may irritate and cause dermtitis.' - .��•. Low order of toxicity. � :.: ._•� ..;.' >.._ • INHALATION: • ty. �`�.= ..7.17:7..7:::::,::77.- •.7: '. •.... .::.1 . ' ?• :, :.. °i:.•. • — —Hi -eyes * gh'vapoF concentrations- are"irri tat ing -to "the 'and -the '•respiratory- tract,' may cause headaches'and dizziness, are anesthetic and may have: .:;.1::.•1:. other central •nervous ;system effects _ ...., ; t •=f ; = .•1,*- ,,, .0:c - =•- • , :,,,• . INGESTION: .,'., .....;.;:..:1 .. .. _ . - • . - ... , ... ... : , _ .. , . .. -. „ Minimal . taxicity.... ....;. ..,,_ :,_.'� • ._ .: — ;' -.,•,....-;:w.,..,. . Smal 1_ :amounts . of the, liquid asp f, rated into the respiratory �systern during .!...."1/..ii... ingestion, or,.from vcmiting,••may ,cause ,broncniopneumonla or•.pulmonary z..........7.... , edema. .? .. : .. :..._ ..: .... ". ... -;,:._ _. : -..: =_;_ _._,'7 -- .'_' : _', t,r ..;_•: .-_ :i Lte: _ ',,•!;.'...; . - ... ,FIRST .AID • _.: , •' • : - .: • • -- • _.. .:: .•.,• n: EYE CONTACT: �,: _ _ :� i:Nr.. _ . -,. 1., .. i :1:: _ ;,.: �': • -! .' .. . _ :... 77 . .Z _, _ :. . Immediately flush eyes with large' amounts^ of water for at ~least 15 - • - ' - ... • . minutes. -Get prompt medical.'attentlon. . . . . SKIN CONTACT: • • - -. °- • _ .. Immediately flush with large amounts of, water;;juse soap ;if,.avallable.. __,,, •. Remove contaminated clot ping, -lncludirig shoes. _after flushfng'had begun. INHALATION: '. ,•, ,.., _- ; • . _ L ... ..: _ ii : ; • ::. Using proper respiratory protection,,lmmediately-�remove the affected •;.. ,_ victim ,from exposure. .Administer arteiflcial ;rest:Oration if .breathing r,. 1s stopped. Keep at rest. Call *for prompt medical`attent1an._.__ _„ ._____ .. ::; .��L31V limmiuman CHEMICAL "®- 05/11/89 Acetone MA I ttiiML 5,AI ETY DATA SHEET •r PAGE 2 NO.92030000 INGESTION: 411- First aid is normally not required. ACUTE TOXICITY DATA I5 AVAILABLE UPON REQUEST. WORKPLACE EXPOSURE LIMITS OSHA REGULATION 29CFR1910.1000 REQUIRES THE FOLLOWING PERMISSIBLE EXPOSURE LIMITS: A TWA of 750 ppm (1800 mg /m3) and a STEL of 1000• ppm (2400 mg /m3) for Acetone. THE'ACGIH RECOMMENDS THE FOLLOWING THRESHOLD LIMIT VALUES: A TWA of 750 ppm (1780 mg /m3), and a STEL of 1000 ppm (2375 mg /m3) for Acetone. PRECAUTIONS PERSONAL PROTECTION For open systems where contact is likely, wear long sleeves, chemical resistant gloves, and chemical goggles. Where contact may occur, wear safety glasses with side shields. ' Where concentrations in air may exceed the limits given in this Section and engineering, work practice or other means *of exposure reduction are not adequate, NIOSH /MSHA approved respirators may be necessary to prevent overexposure by Inhalation. VENTILATION The use of mechanical dilution ventilation is recommended whenever this product 1s used in a confined• space, is heated above ambient temperatures. or is agitated. Use explosion -proof Vent ilat +ion "equipment:" SECTION 4 FIRE & EXPLOSION HAZARD . ... 4 FLASHPOINT: 0 Deg F. _METHOD: TOC FLAMMABLE LIMITS: LELi'2.6 UEL:'13.0 0.77 Deg F." ~' AUTOIGNITION TEMPERATURE: 1,090 Deg F. — _ -. - .. .. — .. • • . . ... • •1 ... .4. - -• • GENERAL HAZARD - ..., ;'� •, Extremely Flammable, material will readily 'i grii•te at 'ambient' temperatures., • ' Flammable Liquid, can release vapors that form flammable,mixtures at temperatures at or above the flashpoint. 'Empty' containers retain 'product residue (11quid: and /or vapor) and can 'be dangerous. 00 NOT PRESSURIZE,' CUT, =WELD, BRAZE, `SOLDER, DRILL, "GRIND, ''OR . ' EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES, OF IGNITION; THEY MAX EXPLODE AND CAUSE INJURY OR DEATH. Empty drums should be completely drained,':properly bunged and promptly re- . turned to a drum reconditioner, or properly disposed of. FIRE FIGHTING . • -' • Use water spray to cool fire exposed surfaces and to protect personnel. • Shut off 'fuel• to fire. If a leak or spill has not 'ignited, •use.water ' • • • ~ spray to disperse the vapors . : .,. : • _ •,. .;. Either allow fire:to burn under controlled conditions or'exti'nguishWith •• - alcohol type foam and dry chemical, 'Try 'to cover liquid spills with foam..' •''• DECOMPOSITION PRODUCTS UNDER.FIRE CONDITIONS No unusual CalAILLi • 1I$ O, ON milmmummin CHEMICAL -- 05/11/89 MATERIAL SAFETY , DATA SHEET Acetone PAGE 3 NO. 9203COCC • • SECTION .5 SPILL CONTROL PROCEDURE • LAND SPILL Eliminate sources of ignition. Prevent additional discharge of material, if possible to do so without hazard. For small spills implement cleanup procedures: for large spills implement cleanup procedures and, if in • • ' public area, keep public away and advise authorltres. Also, if this • product is subject to CERCLA.reporting (see Section VII) notify the National Response Center. .... • Vapors /dust can be harmful /fatal, Warn occupants of downwind areas. Prevent liquid from entering sewers, watercourses, or low areas. Contain spilled liquid with sand or earth. Do not use combustible materials such as sawdust. . . . Recover by pumping (use an explosion proof or hand pump) or with a suitable absorbent. . Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. . . • . WATER SPILL Eliminate sources of ignition. Vapors /dust can be harmful /fatal. Warn occupants and shipping in downwind areas. Consult an expert on disposal of recovered material and ensure • conformity to local•disposal.regulations. • • - •' . ' SECTION 6 NOTES. • . . HAZARD RATING INFORMATION'•• •• • • . .NPCA /HMIS . NFPA .. „ , KEY . Health - 3 1 '_ :.''.•..: . • . r ;4 sn., Severe Flammability 3 • 3' 3 F Serious :. 'Reactivity '.. ., 0 • ;0 . 2 = Moderate .... • .., _ ---- •--- .....1 • n •51 fight .. ...-. • ...:.•t:;,i.1..: ::11.1•. .. :•.. . . ... :. ., ..0.; 0.= Minimal • ------This product contains -low-levels,-up to 50 ppm, • of .Benzene . ,Benzene is .... ..•, ,,.- •,,,., listed as a human and animal,'. carcinogen by OSHA, NTP and ,IARC.. :7 :::.. . , .... • . :'.. :c:.: ∎•: • MCI' 7.:,:.; 7.i . ; ; ;o :-_ :; ..... ... ._ _ • • . • • • ' ').!.:.!•.?.. ... • T . . r , : r . : J: 1 . . *•...•'1• -::! -1..; . ".:7•:".1 -! ':3! ;T .. .r4•..i:'41 }% -'7 . ..+.• - - In -' .., - • . • •• SECTION 7- REGULATORY INFORMATION TSCA: . This product is listed on the'TSCA Inventory at CAS Registry Number 67 -64 -1 CERCLA: • If the reportable quantity of this product is accidentally spilled,••the incident is subject to the provisions of the Comprehensive Response, Compensation and Liability Act (CERCLA) and must be reported to the National Response Center by calling 800-424 -8802. • • • The reportable spill quantity of this product is 5,000 pounds. This product contains: .. . 7. • • • Ali WI I CY3iML. wki-� T Y . DATA SHEET CHEMICAL . 1°"'"mimm 05/11/89 Acetone rSARA TITLE III: Under the provisions'of Title III, Sections 311/312 of the Superfund Amendments and Reauthorization Act, this product is classified into the following hazard categories: Immediate healtn, Delayed Health, Fire. This product contains the following Section 313 Reportable Ingredients: COMPONENT CAS NO. MAXIMUM % Acetone 67 -64 -1 100.0 PAGE 4 NO.92030000 SECTION 8 TYPICAL PHYSICAL & CHEMICAL PROPERTIES SPECIFIC GRAVITY: 0.79 at 68 SOLUBILITY IN WATER, WT. % AT 'F: 100.00 at 68 SP. GRAV. OF VAPOR, at 1 2.00 EVAPORATION RATE. n -Bu Acetate =l: 11.6 VAPOR PRESSURE, mnHg at 'F: 213 at 77 56 at 23 VISCOSITY OF LIQUID, CST At 'F: 0 at 68 • atm (Air =1): FREEZING /MELTING POINT, 'F: -138 BOILING POINT, "F: 133 SECTION 9 REACTIVITY DATA STABILITY: Stable CONDITIONS TO AVOID INSTABILITY: Not Applicable - -' HAZARDOUS'POLYMERIZATION: Will not. occur " • COND. TO AVOID HAZARDOUS POLYMERIZATION: Not Applicable MATERIALS AND CONDITIONS TO 'AVOID INCOMPATIBILITY: Caustics, amines, alkanolamines, aldehydes, ammonia, strong oxidizing agents, and chlorinated compounds. •' - AZARDOUS DECOMPOSITION PRODUCTS: None : • • •r SECTION 10 TRANSPORT .A'ND STORAGE U.S. DOT CLASSIFICATION:' Flammable Liquid ELECTROSTATIC ACCUMULATION HAZARD: No, but use proper grounding procedure STORAGE TEMPERATURE, 'F: Ambient STORAGE /TRANSPORT PRESSURE. mmHg: Atmospheric UN NUMBER : • - • ' U.S. DOT Identification Number: UN 1090 LOADING /UNLOADING TEMPERATURE, 'F: Ambient , VISC. AT LOADING /UNLOADING TEMP., cST: 0 ERENCE NUMBER: IDHA -C -00001 OR ADDITIONAL PRODUCT INFORMATION. CONTACT YOUR TECHNICAL SALES' REPRESENTATIVE 'OR ADDITIONAL HEALTH /SAFETY INFORMATION. CALL 713 -870 -6885 DATE May PREPARED: 11,1989 S. SUPERCEDES ISSUE DATE: May 2,1989 • ISMS • Acetylene Material Safety Data Sheet Industrial Gas Division Air Products and Chemicals, Inc. P.O. Box 538 Tel. (215) PA 18105 • YRNE SPECIALTY GASES, INC. Tel. (r.7 �) 461.4971 • TWX ..10.651.3680 CABLE AIRPROD TELEX 84.7416 118 SO. MEAD ST. SEATTLE, WA 9810E 1200/ PRODUCTS t EMERGENCY PHONE: 800- 523.9374 IN PENNSYLVANIA: 800- 322.9092 ISSUE DATE Issued: 31 January 1978 REVISIONS Rev: 10 July 1986 TRADE "IAMF AND SYNONYMS Acetylene, Ethyne, Ethane ..... C,H, MW: 26.04 , CHEMICAL NAME AND SYNONYMS Acetylene, Ethyne, Ethane •'HEMICAL FAMILY Alkynes CASff74.86.2 HEALTH HAZARD DATA THRESHOLD LIMIT VALUE Acetylene Is classified as a simple asphyxiant and has no threshold limit value (TLV). Acetylene is not listed as a carcinogen by NTP, IARC, or OSHA. SYMPTOMS IF INGESTED. CONTACTED WITH SKIN. OR VAPOR INHALED Symptoms such as headaches, dizziness, shortness of breath, and loss of consciousness may occur if the gas is present In quantities sufficient to dilute the oxygen concentration in air. Symptoms of anoxia occur only when the gas concentrations are within the flammable range and the mixture has not ignited. (DO NOT ENTER AREAS WITHIN THE FLAMMABLE RANGE DUE TO THE IMMEDIATE FIRE AND EXPLOSION HAZARD.) Use a suitable flammable gas meter (explosimeter) calibrated for acetylene to measure concentrations of gas in the air, TOXICOLOGICAL PROPERTIES Acetylene is a simple asphyxiant, Irritant, and anesthetic. About 100 mg per liter may be tolerated for 0.5 -1.0 hour. There is no experimental evidence of chronic harmful effects. RECOMMENDED FIRST AID TREATMENT First degree and minor second degree thermal burns from fires should be immersed in cool water for 30 minutes. Major sec• and and third degree burns should be covered In the cleanest material available. Seek Immediate aid of a physician. Persons suffering from lack of oxygen should be moved to areas with normal atmosphere. Assisted respiration and supplemental oxygen should be given if the victim Is not breathing. ' FIRE AND EXPLOSION HAZARD DATA FLASH POINT (Method used' AU10 ',Nll'I)N fiiMh r FLAMMABLE LIMITS OF (- 18C) (CC) 581F (305C) 1 In air @ 1 atm LEL 2,5% UEL 100% EXTINGUISHING MEDIA 7 ELECTRICAL CLASSIFICATION Carbon dioxide, dry chemical, Halon GROUP Class 1, Group A SPECIAL FIRE FIGHTING PROCEDURES Stop gas flow and fight fire conventionally. Use water spray to keep cylinders or other containers cool if exposed to fire. Keep personnel well away since containers can rupture violently when exposed to fire. For additional information, see Compressed Gas Association Safety Bulletin SB.4. UNUSUAL FIRE AND EXPLOSION HAZARDS ACETYLENE'IS EXTREMELY FLAMMABLE AND EXPLOSIVE. IT MAY DECOMPOSE VIOLENTLY IN ITS FREE STATE UNDER PRESSURE IN EXCESS OF 15 PSIG. It burns with an Intensely hot flame. Potential explosion hazard exists from reignitlon If fire is extinguished without shutting off acetylene source. Ignites very easily due to low minimum Ignition energy; very wide flammable limits. Acetylene gas has an approximate specific gravity of 1.0 and tends to stay in pockets rather than dissipate. PHYSICAL DATA BOILING POINT I'F ■ T FREEZING POINT I "FI @ 1 atm - 119.2F (- 84.0C) I @ 1 atm - 113.4F (- 80.8C) VAPOR PRESSURE IDsial ! SOLUBILITY IN WATER 62.2F (16.80) 590 psia (40 atm) j @ 64F (18C), 1 atm 1.0 CuFt /CuFtH2O VAPOR DENSITY (lbncu 111 @ 68F (20C), 1 atm 0.0681 SPECIFIC GRAVITY (AIR. II 1 LIQUID DENSIT r (lb/cu In SPECIFIC GRAVITY 04,0=1) 62 68F (20C), 1 atm 0.906 @ - 116F (- 82C), @ -116F (- 82C), 1 at 38,76 l 1 atm 0.621 APPEARANCE AND ODOR Pure acetylene is colorless and odorless, Impurities In carbide generated acetylene impart a characteristic garlic•llke odor. 3)Air Products and Chemicals, Inc. 1979 Printed In U.S.A. 310.813 REACTIVITY DATA STABILITY UNS1ABLE X ..01(.1riCtiS rC, r•:UIC Never utilize free gas outside the cylinder at pressures in excess of 15 psig. Avoid ! I STABLE I mechanical shocks to containers of acetylene. Never expose cylinders or acetylene ■ ,.. :, :: l i systems to sources of heat. j COMPATIBILITY (MeterI&.10 eY.0 ) :) ' )-1 ^ :;,..•. ' Oxidizers such as oxygeni.and:halogens. Forms explosive compounds with copper, brass, copper salts, Hg and Hg salts, K, Ag and I Ag salts, and HNO3. HAZARDOUS DECOMPOSITION PRODUCTS Acetylene will decompose Into elemental carbon and hydrogen under the above conditions. HAZARDOUS POLYMERIZATION MAY OCCUR CONDITIONS r0 /WOW WILL NOT OCCUR x , SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Ventilate area to prevent flammable mixture from forming. Remove sources of ignition, heat, sparks, etc. Avoid entering area of flammable atmosphere, Carefully remove cylinders with slow leaks to a remote outdoor location. Contact Air Products for assistance. WASTE DISPOSAL METHOD Do not attempt to dispose of residual gaseous acetylene in cylinders. Return to Air Products for disposal. SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION (Specify type) Oxygen- deficient atmospheres are in the flammable range. DO NOT ENTER. Respirators will not function. VENTILATION LOCAL EXHAUST SPECIAL Natural or mechanical Mechanical ventilation for enclosed storage areas must ' where gas is present. meet National Electrical Code requirements for Class 1, Group A MECHANICAL (General) OrttER PROTECTIVE GLOVES Ordinary leather work gloves recommended for cylinder handling. Welders gloves required for cutting and welding operations, EYE PROTECTION Gafety glasses recommended for handling cylinders. Welders goggles, etc., required for cutting and welding. 1ER PROTECTIVE EOUIPMENT Leather sleeves, leather apron and other standard protective equipment for cutting and welding. . SPECIAL PRECAUTIONS' SPECIAL LABELING INFORMATION Acetylene shipments must be in accordance with Department of Transportation (DOT) regulations using the DOT "FLAMMABLE GAS" label, Consult DOT regulations for details on the shipping of hazardous materials. SPECIAL HANDLING RECOMMENDATIONS ! Use only in well ventilated areas. Acetylene gas cylinders contain gas at high pressure and should be handled with care. Use a pressure- reducing regulator set at less than 15 psig. Always keep acetylene cylinders upright and secure cylinders when In use. Never expose an acetylene cylinder to heat. Always open and close acetylene valves slowly. Return cylinders to Air Products with positive pressure and cylinder valve closed. Avoid dragging, rolling, or sliding cylinders, even for a short distance. Use a suitable hand truck. For additional handling recommendations on compressed gas cylinders, consult Compressed Gas Association Pamphlet P -1, SPECIAL STORAGE RECOMMENDATIONS Storage of 2500 cubic feet or less Is permissible within buildings. Storage in excess of 2500 cubic feet must be outdoors or In well ventilated special rooms or buildings. Keep cylinders away from sources of heat. Storage should not be in heavy traffic areas to prevent accidental knocking over or damage from passing or falling objects. Valve caps should remain on cylinders not connected for use. Segregate full and empty cylinders. Keep acetylene cylinders storage areas away from storage of oxygen and other oxidizers. Storage areas should be free of combustible material. Avoid exposure to areas where salt or other corrosive chemicals are present. Store acetylene cylinders with the valve end up. See Compressed Gas Association Pamphlet P -1 and National Fire Protection As- sociation Standard No. 51 for additional storage recommendations. SPECIAL PACKAGING RECOMMENDATIONS Acetylene is packaged in cylinders meeting DOT specification 8 or 8AL. The cylinder contains a porous filler saturated with acetone, The acetylene stored in the cylinder is dissolved in acetone. A full cylinder should not exceed 250 psig @ 70F. OTHER RECOMMENDATIONS OR PRECAUTIONS Acetylene cylinders should be stored and used in an upright position. When using acetylene, close the cylinder valve before shutting off the regulator to permit the gas to bleed from the regulator. Avoid hazardous mixtures and sources of ignition. Formation of explosive copper acetylides can be avoided by using copper alloys proved successful through use in industry. Compressed gas cylinders should not be refilled except by qualified producers of compressed gases. Shipment of a compressed gas cylinder filled without the permission I of the owner is a violation of Federal Law. _.; arious Government agencies (i.e.. Department of Transportation. Occupational Safety and Health Administration, Food and Drug It Administration and otners) may have specific regulations concerning the transportation, handling. storage or use of this product which will not be reflected in this data sheet. The customer should cevtew trlese regulations to ensure tnat ne is in full compliance. 01/30/92 09: 53 3M General Offices 3M Center St. Paul, Minnesota 65144 -1000 012x733.1110 Dune No.: 00 -617 -3082 I4ATERIAL. SAFETY DATA SHEET 3M LA ADH SYS. DIV. 002 00 -05 5851 DIVISION: INDUSTRIAL. SPECIALTIES TRADE NAM 5M Super 77 Sprey Adhesive 8M I.D. NUMBER: 62- 44343725-6 62- 44343726 -4 62- 4434 - 4030 -0 62.4434- 49350 62- 4434-4936 -8 ISSUED: NOVEMBER 8, 1990 SUPERSEDES: OCTOBER 22, 1990 DOCUMENT: 10-3312-5 n ^hexane hexane (other isomers) cvclohexene 110 -54 -3 none 110 -82 -7 Propane 74 -98 -6 ieobutene 75 -28 -5 dimethyl ether 115 -10 -6 non- volatile components N.J. T.S. Trade Secret2(T.S) Registry No. SOURCE OF EXPOSURE LIMIT DATA: ▪ ACOIH: American Conference of Governmental Industrial Hygienists - OSHA: 0coupationel Safety and Health Administration • CPIRO: Chemical Manufacture Recommended Guidelines - NONE: None Established HOWL: ++ rosin, aynthotzc polymer, resin and antioxidant, THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICAL OR CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OP SECTION 313 OF TITLE ISI OF THE SUPFRFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1936 AND 40 CFR PART 372: cyolohexane 10.0 - 20.0 50 port 10.0 - 20.0 500 ppm 10.0 - 20.0 300 ppm 10.0 - 20.0 1000 ppm 10.0 - 20.0 NONE NONE 10,0 - 20.0 1000 ppm 1.0 - 30.0 NONE NONE TWA ACM TWA ACGIH TWA ACGIN TWA OSHA NONE NONE TWA CMRL NONE NONE= ROILING POINTS Compressed pat VAPOR PRESSURE :. Compressed as VAPOR DENSITY: 2.97 Ai m 1 EVAPORATION RATE: 1.90 Ether * 1 SOLUBILITY ZN WATER: Nil SP. GRAVITY. 0.702 Water I= 1 PERCENT VOLATILE: 75.00 X VOLATILE ORGANICS: 527.00 9m /1 VISCOSITY: N/A APPEARANCE AND ODOR: Light cream colored, liquid in aerosol, sweet/fruity odor. F D P O II N t, -tfATk — -50.00 F T.C.C. FLASH POINT - Propellent FLAMMABLE LIMITS - LEL: N/A FLAMMABLE LIMITS - DEL.: Flamm, 6aa AUTOIONITION TEMPERATURE: N/D EXTZNOUXEHXNG MEDIA: CO2, foam, dry chemical AbbrevietionDs N/D - Not Determined N/A - Not Applicable 01/30/92 09:59 3M LA ADH SYS. DIV. 3M General Offices 3M Center St. Paul, Minnesota 55144.1000 812/133.1110 Duns No.: 00-617-3082 MATERIAL SAFETY DATA SHEET 003 00 -05 5852 }ISDS: SH Supsr 77 Spray Adhesive NOVEMBER 8, 1990 PAGE: 2 of 4 l�f ii -WIZ I j;l:i!AITI E11111 HAW; D SPECIAL EIRE FUMING PROCEDURES: Fire fighters should be equipped with self - contained breathing apparatus when fighting fires involving this material. UNUSUAI. FIRE AND EXPLUSICN HAZARDS: Extremely Flammable. (Treat as flammable pressurized container), Overheated, closed container adjacent to fire could explode due to Pressure buildup. NFPA- HAZARD- CODES: HEALTH 2 FIRE 4 REACTIVITY 0 UNUSUAL REACTION HAZARD; NONE STABILITY: Stable INCOWATIBILITY - MATERIALS TO AVOID: ; CONDITIONS TO AVOID: Do not store at temperatures above 120F. Do ` not puncture or incinerate container. HAZARDOUS POLYMERIZATION: Will Not Occur HAZARDOUS DECOMPOSITION PRODUCTS: CO, CO2 and smoke particles when sub5ectad to excessive heat or flame. SPILL RESPONSE: If cans rupture: Extinguish all ignition sources. Ventilate area. Observe prccauticna from other sec #ions. Contain spill.. Cover with absorbent materials as needed. Collect spilled material. Place An a U.S Dept. of Transportation - approved metal container, and 0001. RECOMMENDED DISPOSAL: Incinerate absorbed and partially full cans after mixing with flammable material in a permitted hazardous waste facility. Do not puncture or burn cans in household incinerator. Dispose of empty cans in a sanitary landfill. Disposal should be in accordance with apQplicable regulations. U.S. EPA HAZARDOUS WASTE NUMBER: D001 (Ignitable). ENVIRONMENTAL DATA: Volatile Organic Cameeund (VOC): Maximum VOC 527 grams /liter. Maximum VOC minus Water minus Exempt Solvents Ls 527 grams /liter. VOC's were calculated according to Rule 443,1 of the South Coast Air Quality Management Distriot (SCAQMD). SARA HAZARD CLASS: FIRE HAZARD: Yes PRESSURE: Yes REACTIVITY: No ANTE: Yes CHRONIC: Yes EYE CONTACT: Immediately flush eyos with Plenty of water for at heat 10 minutes, Abbrevieti.onss N/D Nut Determined N/A - Not Applicable 01/30/92 10:00 aM General Offices 3M Center St. Paul, Mlnneeota 551441000 012/733-1110 Duns No.: 00- 617-3082 MATERIAL SAFETY DATA SHEET 3M LA ADH SYS. DIV. 004 00 -05 5853 RODS: RN Super 77 Spree Adhesive f ti'! : i z >Ir,►.i. +a13'� T� �.i� t'LTSTICi' —1, PAGE: 3 of 4 Cull a physician. SKIN CONTACTS Wash affected area with soap and water. INHALATION: Move to unoontaminated air. Call a phy9icxasn. IF SWALLOWED: I4' swallowed, do not induce vomiting. Call a physician immediately. OT 1U FIRST AID: NONE FOR INDUSTRIAL. OR PROFESSIONAL USE ONLY. Keep product and its vapors ewaY from heat, sparks, flames and other aourcee of ignition. Extinguish and do not ignite any flame in the immediate work area. The vapors released by this product can sessile be ignited and burn explosively. Avoid prolonged breathing vapor and :mist (spray particulate). Use only in areas with sufficient ventilation to maintain vapor /spray conoentretione below recommended exposure limits. Do not use in confined areas or areas with little or no air movement. Local exhaust ventilation should be used if large quantities ere sprayed in a short period of time. Prevent eye and skin contact. Wear safety glasses and impervious gloves when handling product. Do not take internally. Intentional misuse by deliberately concentrating and inhaling or swallowing product may be fatal. Do not store at temperatures above 120F. Do not punoture or burn container in household incinerator. Keep out of the reach of children. Additional exposure limits: hexane (other iaomars) 1000ppm, SOEL, ACGIH, 3500mg/m3, STET, ACGIH. ADDITIONAL EXPOSURE LIIT f - --- EXPOSURE LIMITS ra00 mppn: TWA OSHA A 1800 mg/m3 TWA OSHA 1050 mg/m3 ACOIH 300 ppm TWA OSHA 1050 ms /m3 TWA OSHA 1800 mg /m3 TWA OSHA n exene n- hexane n- hawane cyclohexane cyolohexene Cerclohexano Propane SOURCE OF EXPOSURE LIMIT DATA: - ACGIH: American Conference of Governmental Induetrial Hyaieniete - OSHA: Occupational Safety and Health Administration AbbreViationa: N/D - Not Determined N/A " Not Applit:able 01/30/92 10:00 } , 3M LA ADM SYS. DIV. 00-05 3M Gems' Offices 5854 3M Center 8t. Paul, Minnesota 55144.1000 8181733.1110 Duns No.' 00 -617 -3082 MATERIAL SAFETY DATA SHEET As SODOI 311 Super 77 Spray Adhesive HOVEN= 8, 1990 PAGEr 4 of 4 4010 OFWAII:r,IF-f.11.111.M EYE CONTACT: Mey cause e,ya irritation upon direct contact, ,KIN CONTACTS Prolonged and repeated skin contact may dafat skin leading to irritation and dermatitis. n-Nexena may be absorbed through the skin in harmful amounts/. INHALATION: Vapor overexposure may cause roapiratory system irritation and temporary nervous system impairment (li0htM eadedneae). Symptoms may include weakness, dizziness headache, nausea and facial nuabneaa. There are reported instances ances where exposure to n-hexane vapor concentrations in excess of 800 ppm caused peripheral nerve damage. Bross overexposure such as is caused. by' intentional inhalation af concentrated vapors in a confined vessel can result in serious damage including asphyxiation and death. INDESTION: Accidental inuestion is unlikely from an aerosol container. Intentional concentration and swallowing the liquid product may cause severe digestive system irritation. Symptoms may include nausea, diarrhea and vomiting. Solvent aspiration into the lunge as a result of vomiting aeay cause lung damage, which can he fetal. Abbreviations: N/D -'Not Determined N/A - Not Aaplicable e. n orme on on s +a a ea repreeen s out' ourren .a o an .as opinion ass to the proper use in hendlin af this material under noraal conditions. An use of the material which is not in conformance with this Data Sheet or which involves using the material in combination with any. '. other materiel or any other procass is *he responsibility of the user, ., wY .ze 'd 1 r:1b ue LUNbU11tR FIFFHIRS MATERIAL SAFETY DATA SHEET COLGATE- PALMOLIVE COMPANY 300 Park Avenue New York, NY 10022 24 -sour Emergency Telephone Nanber: Pittsburgh Poison Canter Call Collect: (412) 692 -5596 Telephone Number For Informations 201 -878 -7533 P.2 Date Issued: January, 1989 SECTION I IDENTIFICATION Product Name: AJAX Laundry Detergent Product Code Number(s): 06517, 06518, 06519 CAS Number: Not applicable; product is a mixture. Chemical Names Not applicable; product is a mixture. Product'Tl+pe(Ceneral Information: A formulated laundry detergent powder packaged in 36 oz. (006517), 61•oz. (006518), and 125 oz. (006519) sizes in paperboard boxes. Contains No Phosphorus. **** A**************************** * * * *lr * ** **** * * *l**iril***** *** ** ***** * THE PITTSBURGH POISON CENTER RAS BEEN PROVIDED SPECIFIC * * INFORMATION FOR USE IN MEDICAL EMERGENCIES INVOLVING THIS * * PRODUCT. CALL COLLECT: (412) 692 -5596 * *** *** *** * ** * ***** * * ** * ***** ** lir * * * * * * * **** * ****k * *** * * *+ ***fir *1r*** ** SECTION II RAZARDOUS NGREDIENTS IDENTYTY INFORMATION THIS MIXTURE HAS NOT BEEN TESTED AS A WHOLE. Threshold Limit Value (TLV): None Established 08 AA Permissible.Expo , sure Limit (PEL): None Established This mixture contains the following hazardous ingredients at concentrations greater than 1.0x: Paine CAS 0 Conc. OSPEL ACGIH -TLV None - Not Applicable This mixture contains the following hazardous ingredients listed as carcinogens or.potential carcinogens by either the National Toxicology Program (NTP), International Agency for Research on Cancer (IARC) or OSHA, and present at a concentration greater than 0.1x: Name CAS 0 None - Not Applicable Concentration Page 2 o Codas No. 06517, 06519, 06519 • SECTION III PHYSICA CHEMICAL CRARACTERIS'rlCS Soiling Point: Density: 0.32 — Vapor Pressure: Eating Point: Vapor Density: Not Applicable 0.33 g/cc Not Applicable Not Applicable Not Applicable .Evaporation Bate: Not Applicable Solubility in Water: Very soluble Appearance /Odor: Light blue granular powder, floral odor pH: (12 Solution) 10.4 + 0.4 SECTION IV FIRE AND EXPLOSION HAZARD DATA Flash Point (Method): Not Applicable Estinfluishing Media: CO2, Foam, Dry Chemical S eeial Piren htin Procedures: Self — contained breathing apparatus and protective c othing s uld a worn when fighting chemical fires, SECTION V REACTIVITY DATA Stability: Unstable Conditions and Materials to Avoid: Hazardous Decomposition Products: Stable_ None Known None Known Hazardous Polymerization: May Occur Will Not Occur SECTION VI HEALTH HAZARD DATA Routes of Entry Inhalation: Yes Stcin: Yea THIS MIXTURE HAS NOT BEEN TESTED AS A WHOLE. Health Ramada: • • ingestion: Yes . Ingestion: Nausea, waiting and diarrhea eat Eye irritant upon direct contact jaw May cause skin irritation upon prolonged contact. Inhalation: Not known Medical Conditions Ganerally Aggravated by Exposure: blot 'Known • • Page 3 Code go. 06517, 06518, 06519 piirrstAid Procedures: Injestion: If you eat or drink this, you may throw up. Drink sips of water or milk. If vomiting continues, call your poison center or doctor. es: This product can cause eye irritation. If you get it in your eye, pour warm water through your eye for 15 minutes. If your eye still bothers you, cull your poison center or doctor. Skin: This may irritate your skin. Take off wet clothes. Pour warm water on your skin for 15 minutes. If not better, call your poison center or doctor. Inhalation: If you breathe some of this product, it may make you cough. ? some slow deep breaths of fresh air and sip some water. If you keep coughing, call your poison center or doctor. SECTION VII PRECAUTIONS FOR SAFE HANDLING AND USE Ste s to be Taken if Material is Released or S illed: Small spills can be brim up with a broom or vacuumed up. Waste Disposal Method: Preferred method is incineration at a licensed approved fecility. Eepty containers may be disposed as conventional waste. Precautions to be Taken in Handlin and Storin : Store in a cool dry place /7717 to 125 F . • SECTION VIII CONTROL 0 MEASURES �r Work/H lene practices: Ovoid contact with skin and eyes. Under normal• cond tions of product use, no special protection for eyes /skin is required. When preparing a paste rub or in soaking operations where splashing and akin and eye contact are possible, the use of eye protection (goggles) and rubber gloves is recommended. KEEP OUT OF THE LEACH 011 CHILDREN. a i • L`' LU C♦ =5R ct r • i Q • Q W Q , Section V— HEALTH HAZARD DATA omtoeral• Dectaber 1, Minn I400It PAIN cogpAyr n• • .142 art tuft.wot.ctotLAit I11111C11. 11. I0Oi7 300 t. 71410 Si0tt1 r 1 Det -t Fl 1 (alt 1 DOUS INGREDIENTS 0 0 • • f n J o • ▪ Y • E• < y '. ■ 9 n a • w AN Aw Section III — PHYSICAL DATA Section IX— SPECIAL PRECAUTIONS cG r 0 0 /rir11 1 -111hI vhl 1... 1 1 VM 1 M %j1 1LL. 1 The Sherwin•Williams Company THE SPECIALTY DMSION 6830 Cochran Rd. Solon, OH 44139.3308 Emergency Telephone 216 - 292 -7400 For ordering Information, additional copies of MSDS, etc., 1.800. 832 -2541 For technical Information only, 216 - 292.7400 THE OSHA HAZARD COMMUNICATION STANDARD 29 CFR 1910.1200 REQUIRES THAT THE INFORMATION CONTAINED ON THIS SHEET BE MADE AVAILABLE TO YOUR WORKERS. INSTRUCT YOUR WORKERS TO HANDLE THIS PRODUCT PROPERLY DESCRIPTION: KRYLON INTJEXT. ENAMEL PRODUCT TYPE: SPARY PAINT 'AEROSOL" 1 0-Apr•89 APPLICATION: ITEMS 1604 THRU 2505 -1604 SHADOW GRAY,1605 DOVE GRAY, 1606 PEWTER GRAY,1608 SMOKEGRAY.1617 PEARLGRAY 1801 CHROME YELLOW,1811 HARVESTGOL0,1813 OAISYYELLOW (OSHA SAFETYYELLOW),1902 BABY BLUE,1904TEAL BLUE,1905 COLONIAL BLUE,1910TRUE BLUE, 2002 PASTEL AQUA. 2003 JADE GREEN, 2008 AQUA TURQUOISE, 2009 AVOCADO, 2011 JUNGLE GREEN, 2012 CLOVER GREEN (SAFETY GREEN), 2110 HOT PINK 2116 SCARLET (OSHA SAFETY RED), 2117 BONFIRE. 2406 BURNT ORANGE, 2411 BRICK. 2412 LIGHT PEACH, 2414 MAUVE, 2504 BEIGE, 2505 CHIPPEWA SIGNAL WORD DANGER) THIS MATERIAL IS A "HEALTH HAZARD" AND /OR A "PHYSICAL HAZARD" AS DETERMINED WHEN REVIEWED ACCORDING TO THE REQUIREMENTS OF THE OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION 29 CFR PART 1910.1200 "HAZARD COMMUNICATION" STANDARD. CHEMICAL HAZARD RATING HEALTH =2(MODERATE) FIRE=4(EXTREME) REACTIVITY =O(LEAST) CHRONIC =' 29CFR1910.1200 HAZARDOUS INGREDIENTS /REPORTEOIIEALTH EFFECTS CAS /REGISTRY NO. MATERIAL DESCRIPTION RANGE THE INGREDIENTS LISTED BELOW HAVE BEEN ASSOCIATED WITH ONE OR MORE OF THE LISTED IMMEDIATE AND /OR DELAYED(') HEALTH HAZARDS. RISK OF DAMAGE AND EFFECTS DEPENDS UPON DURATION AND LEVEL OF EXPOSURE. BEFORE USING OR HANDLING. READ AND UNDERSTANO THE MSDS. 67.64.1 ACETONE 30.50 NOTE REVISED OSHA PEL CAN CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION. SIGNS AND SYMPTOMS MAY INCLUDE HEADACHE, DIZZINESS, NAUSEA, VOMITING. UNCONSCIOUSNESS AND EVEN ASPHYXIATION. —SEE FOOTNOTE C. ACGIH TLV: 750 PPM(1780 MG /M3) TWA :1000 PPM(2375 MGiM31 STEL OSHA PEL 750 PPM(1800 M0/M31 TWA :1000 PPM(2400 MB/M31 STEL NIOSH DOCUMENT NUMBER: 78.173 71-36-3 1- 8UTANOL 1-5 CAN CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION. SIGNS AND SYMPTOMS MAY INCLUDE HEADACHE, DIZZINESS. NAUSEA, VOMITING. UNCONSCIOUSNESS AND EVEN ASPHYXIATION. —SEE FOOTNOTE C. ACGIH TLV: SKIN • 50 PPM (150 MG /M31 CEILING OSHA PEL SKIN - 50 PPM (150 M6 /M3) CEIUNO 74.98.6 PROPANE 10.30 THIS MATERIAL IS A SIMPLE ASPHYXIANT. SIGNS AND SYMPTOMS OF OVEREXPOSURE INCLUDE CYANOSIS, RESPIRATORY DISTRESS, HEADACHE. DIZZINESS, DROWSINESS, UNCONSCIOUSNESS AND ASPHYXIATION. CAN CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION. —SEE FOOTNOTE C. ACGIH TLV: SIMPLE ASPHYXIANT • SEE ACGIH TLVS, APPENDIX E OSHA PEL 1000 PPM (1800 MO /M3) TWA 78.93.3 *METHYL ETHYL KETONE 5-10 NOTE REVISED OSHA PEL SUSPECT REPRODUCTIVE HAZARD. MAY CAUSE REPRODUCTIVE DISORDERS BASED ON ANIMAL DATA. METHYL ETHYL KETONE MAY POTENTIATE (SHORTEN THE TIME OF ONSET) PERIPHERAL NEUROPATHY CAUSED BY METHYL N -BUTYL KETONE OR N-HEXANE. METHYL ETHYL KETONE BY ITSELF HAS NOT BEEN SHOWN TO CAUSE PERIPHERAL NEUROPATHY. CAN CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION. SIGNS AND SYMPTOMS MAY INCLUDE HEADACHE, DIZZINESS, NAUSEA, VOMITING, UNCONSCIOUSNESS AND ASPHYXIATION. REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED OCCUPATIONAL OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND INHALING THE CONTENTS MAY LEAD TO ADDICTION AND MAY BE HARMFUL OR FATAL. —SEE FOOTNOTE C. ACGIH TLV: 200 PPM (590 MG /M31 TWA: 300 PPM (885 MG M31 STEL OSHA PEL 200 PPM (590 M8/M3) TWA: 300 PPM (885 MG /M3) STEL NIOSH DOCUMENT NUMBER: 78-173 108.10.1 METHYL ISO8UTYL KETONE 1-5 NOTE REVISED OSHA PEL CAN CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION. SIGNS AND SYMPTOMS MAY INCLUDE HEADACHE, DIZZINESS, NAUSEA, VOMITING, UNCONSCIOUSNESS AND EVEN ASPHYXIATION. —SEE FOOTNOTE C. ACGIH TLV: 50 PPM (205 MG /M3) TWA: 75 PPM (300 MG /M31 STEL OSHA PEL 50 PPM (205 M8 /M3) TWA: 75 PPM (300 M9 /M31 STEL NIOSH DOCUMENT NUMBER: 78-173 108.65.8 2- PROPANOL 1- METHOXY -, ACETATE —SEE FOOTNOTE C. ACGIH TLV: NONE ESTABLISHED OSHA PEL NONE ESTABUSHEO 5-10 108.88.3 *TOLUENE 1.5 NOTE REVISED OSHA PEL CAN CAUSE LIVER DAMAGE. CAN CAUSE KIDNEY DAMAGE. CAN CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION. SIGNS AND SYMPTOMS MAY INCLUDE HEADACHE, DIZZINESS, NAUSEA, VOMITING, UNCONSCIOUSNESS AND ASPHYXIATION. REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED OCCUPATIONAL OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND INHALING THE CONTENTS MAY LEAD TO ADDICTION AND MAY BE HARMFUL OR FATAL, — SEE FOOTNOTE C. ACGIH TLV: 100 PPM (375 MG /M3) TWA: 150 PPM (560 MG /M31 STEL OSHA PEL 100 PPM (375 MU /M3) TWA: 150 PPM (560 MO /M31 STEL NIOSH DOCUMENT NUMBER: 73-11023 1330.20.7 'XYLENE 10-30 NOTE REVISED OSHA PEL CAN CAUSE LIVER DAMAGE. CAN CAUSE KIDNEY DAMAGE. CAN CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION. SIGNS AND SYMPTC'.IS MAY INCLUDE HEADACHE. DIZZINESS, NAUSEA. VOMITING, UNCONSCIOUSNESS AND EVEN ASPHYXIATION. — SEE FOOTNOTE C. ACGIH TLV: 100 PPM (435 MG /M31 TWA: 150 PPM (655 MG /M31 STEL OSHA PEL 100 PPM (435 MG /M3) TWA: 150 PPM (655 MG/M31 STEL NIOSH DOCUMENT NUMBER: 75 -168 13463.67.7 'TITANIUM DIOXIDE 1-5 NOTE REVISED OSHA PEL CAN CAUSE LUNG FIBROSIS. PRE - EXISTING RESPIRATORY DISORDERS MAY BE AGGRAVATED BY EXPOSURE. — SEE FOOTNOTE C. ACGIH TLV: TOTAL DUST 10 MG /M3 TWA OSHA PEL RESPIRABLE FRACTION/TOTAL OUST 5110 M8 /M3 TWA FOOTNOTE C: AS OF THE DATE OF ISSUANCE OF THIS DOCUMENT. THIS MATERIAL HAS NOT BEEN LISTED BY NIP, IARC OR OSHA AS A CARCINOGEN PHYSICAL DATA VAPOR PRESSURE — SEE CAN PRESSURE VAPOR DENSITY HEAVIER THAN AIR SOLUBILITY IN WATER SPECIFIC GRAVITY LIGHTER THAN WATER EVAP RATE FASTER THAN BUTYL ACETATE SEE REVERSE SIDE SLIGHT CURRENT ISSUE: 10- APR -89 K0-1604 MATERIAL SAFETY DATA SHEET The Sherwin - Williams Company THE SPECIALTY DIVISION 6830 Cochran Rd. Solon. OH 44139-3908 For ordering Information, additional copies of MSDS, etc., 1400- 832 -2541 For technical Information only, 216- 292 -7400 Emergency Telephone 216 - 292 -7400 THE OSHA HAZARD COMMUNICATION STANDARD 29 CFR 1910.1200 REOUIRES THAT THE INFORMATION CONTAINED ON THIS SHEET BE MADE AVAILABLE TO YOUR WORKERS. INSTRUCT YOUR WORKERS TO HANDLE THIS PRODUCT PROPERLY DESCRIPTION: KRYLON INT /EXT. ENAMEL PRODUCT TYPE: SPARY PAINT 'AEROSOL" 10- Apr -89 APPLICATION: ITEMS 1601 THRU 2501 —1601 GLOSSY BLACK. 1602 ULTRA -FLAT BLACK 1603 CHARCOAL GRAY, 1613 SEMI -FLAT BLACK. 1631 BLACK LACQUER, 1704 SPANISH BROWN, 1803 MARIGOLD YELLOW (OLD CATERPILLAR YELLOW), 1804 BRIGHT YELLOW (JOHN DEERE YELLOW), 1809 SCHOOL BUS YELLOW, 1814 TOPAZ YELLOW (NEW CATERPILLAR YELLOW), 1901 REGAL BLUE, 1903 METALLIC BLUE, 2001 HUNTER GREEN. 2004 MOSS GREEN (JOHN DEERE/CASE GREEN(, 2005 ERIN GREEN (OLIVER GREEN), 2101 CHERRY RED, 2103 AMERICAN BEAUTY RED (INTL HARVESTER RED), 2108 BANNER RED. 2118 BURGUNDY. 2301 0.D. KHAKI, 2401 SUNSET ORANGE, 2404 MANDARIN ORANGE, 2410 POPSICLE ORANGE (SAFETYORANGE), 2501 LEATHER BROWN, 16012 GLOSSY BLACK.16022 ULTRA FLAT BLACK,16132 SEMI FLAT BLACK, 18042 BRIGHT YELLOW, 19012 REGAL BLUE. 20012 HUNTER GREEN, 21012 CHERRY RED, 21082 BANNER RED, 25012 LEATHER BROWN 11•111•111■ SIGNAL WORD DANGERI THIS MATERIAL IS A "HEALTH HAZARD" AND /OR A "PHYSICAL HAZARD" AS DETERMINED WHEN REVIEWED ACCORDING TO THE REQUIREMENTS OF THE OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION 29 CFR PART 1910.1200 "HAZARD COMMUNICATION" STANDARD. CHEMICAL HAZARD RATING HEALTH =2(MODERATE) REACTIVITY =0(LEAST) FIRE=41EXTREME) CHRONIC =• 29CFR1910.1200 HAZARDOUS INGREDIENTS /REPORTED HEALTH EFFECTS CAS /REGISTRY NO. MATERIAL DESCRIPTION % RANGE THE INGREDIENTS LISTED BELOW HAVE BEEN ASSOCIATED WITH ONE OR MORE OF THE LISTED IMMEDIATE AND /OR DELAYED (1 HEALTH HAZARDS. RISK OF DAMAGE AND EFFECTS DEPENDS UPON DURATION AND LEVEL OF EXPOSURE. BEFORE USING OR HANDLING, READ AND UNDERSTAND THE MSDS, 67.64.1 ACETONE 30-50 NOTE REVISED OSHA PEL CAN CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION. SIGNS ANO SYMPTOMS MAY INCLUDE HEADACHE. DIZZINESS, NAUSEA, VOMITING, UNCONSCIOUSNESS AND EVEN ASPHYXIATION. —SEE FOOTNOTE C. ACGIH TLV: 750 PPM(1780 MG /M3) TWA:1000 PPM(2375 MG /M31 STEL OSHA PEL 750 PPM(1800 MG/M3) TWA;1000 PPM(2400 MG/M3) STEL NIOSH DOCUMENT NUMBER: 78.173 71-36-3 1- BUTANOL 1-5 CAN CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION. SIGNS AND SYMPTOMS MAY INCLUDE HEADACHE, DIZZINESS, NAUSEA, VOMITING. UNCONSCIOUSNESS AND EVEN ASPHYXIATION. —SEE FOOTNOTE C. ACGIH TLV: SKIN - 50 PPM (150 MG /M31 CEILING OSHA PEL: SKIN - 50 PPM (150 MB /M3) CEILING 74.90.6 PROPANE 10-30 THIS MATERIAL IS A SIMPLE ASPHYXIANT. SIGNS AND SYMPTOMS OF OVEREXPOSURE INCLUDE CYANOSIS. RESPIRATORY DISTRESS, HEADACHE, DIZZINESS, DROWSINESS, UNCONSCIOUSNESS AND ASPHYXIATION. CAN CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION —SEE FOOTNOTE C. ACGIH TLV: SIMPLE ASPHYXIANT • SEE ACGIH TLVS, APPENDIX E OSHA PEL- 1000 PPM (1800 MO /M3) TWA 78-93-3 'METHYL ETHYL KETONE NOTE REVISED OSHA PEL SUSPECT REPRODUCTIVE HAZARD. MAY CAUSE REPRODUCTIVE DISORDERS BASED ON ANIMAL DATA. METHYL ETHYL KETONE MAY POTENTIATE (SHORTEN THE TIME OF ONSET) PERIPHERAL NEUROPATHY CAUSED BY METHYL N -BUTYL KETONE OR N- HEXANE. METHYL ETHYL KETONE BY ITSELF HAS NOT BEEN SHOWN TO CAUSE PERIPHERAL NEUROPATHY. CAN CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION. SIGNS AND SYMPTOMS MAY INCLUDE HEADACHE, DIZZINESS, NAUSEA, VOMITING, UNCONSCIOUSNESS AND ASPHYXIATION. REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED OCCUPATIONAL OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND INHALING THE CONTENTS MAY LEAD TO ADDICTION AND MAY BE HARMFUL OR FATAL. —SEE FOOTNOTE C. ACGIH TLV: 200 PPM (590 MG /M31 TWA: 300 PPM (885 MG M31 STEL OSHA PEL 200 PPM (590 MG /M3) TWA; 300 PPM (885 MG /M3) STEL NIOSH DOCUMENT NUMBER: 78.173 5 -10 108-10-1 METHYL ISOBUTYL KETONE 1-5 NOTE REVISED OSHA PEL CAN CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION. SIGNS AND SYMPTOMS MAY INCLUDE HEADACHE. DIZZINESS, NAUSEA, VOMITING, UNCONSCIOUSNESS AND EVEN ASPHYXIATION. —SEE FOOTNOTE C. ACGIH TLV: 50 PPM (205 MG /M3) TWA; 75 PPM (300 MG /M3) STEL OSHA PEL 50 PPM (205 MG/M3) TWA; 75 PPM (300 MB/M3) STEL NIOSH DOCUMENT NUMBER: 78-173 108-65-6 2-PROPANOL 1- METHOXY -, ACETATE —SEE FOOTNOTE C. ACGIH TLV: NONE ESTABLISHED OSHA PEL NONE ESTABLISHED 5-10 108.88 -3 *TOLUENE 1.5 NOTE REVISED OSHA PEL CAN CAUSE LIVER DAMAGE. CAN CAUSE KIDNEY DAMAGE. CAN CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION. SIGNS AND SYMPTOMS MAY INCLUDE HEADACHE, DIZZINESS, NAUSEA. VOMITING, UNCONSCIOUSNESS AND ASPHYXIATION. REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED OCCUPATIONAL OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN ANO NERVOUS SYSTEM DAMAGE. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND INHALING THE CONTENTS MAY LEAD TO ADDICTION • ANO MAY BE HARMFUL OR FATAL. —SEE FOOTNOTE C. ACGIH TLV: 100 PPM (375 MG /M31 TWA: 150 PPM (560 MG/M31 STEL OSHA PEL 100 PPM (375 MB /M3) TWA: 150 PPM (560 MO /M3) STEL NIOSH DOCUMENT NUMBER: 73-11023 1330.204 •XYLENE 10-30 NOTE REVISED OSHA PEL CAN CAUSE LIVER DAMAGE. CAN CAUSE KIDNEY DAMAGE. CAN CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION. SIGNS AND SYMPTOMS MAY INCLUDE HEADACHE, DIZZINESS, NAUSEA. VOMITING, UNCONSCIOUSNESS AND EVEN ASPHYXIATION. —SEE FOOTNOTE C. ACGIH TLV: 100 PPM (435 MG /M3) TWA: 150 PPM (655 MG /M3) STEL OSHA PEL 100 PPM (435 MO /M3) TWA: 150 PPM (655 MO /M3) STEL NIOSH DOCUMENT NUMBER: 75-168 FOOTNOTE C: AS OF THE DATE OF ISSUANCE OF THIS DOCUMENT, THIS MATERIAL HAS NOT BEEN LISTED BY NTP, IARC OR OSHA AS A CARCINOGEN PHYSICAL DATA VAPOR PRESSURE — SEE CAN PRESSURE VAPOR DENSITY HEAVIER THAN AIR SOLUBILITY IN WATER SPECIFIC GRAVITY LIGHTER THAN WATER EVAP RATE FASTER THAN BUTYL ACETATE BOILING POINT:APPEARANCE:ODOR PERCENT VOLATILE BY WEIGHT PERCENT NON-VOLATILE BY WEIGHT PRESSURE IN CONTAINER. PSIG a 70 F. SEE REVERSE SIDE SLIGh" Na 31 TO 69 11 TO 19 APPROX. 60 CLJRRFNT ISSI IF' 1 r,- APR•RO len., an, IVIH I tt-IIHL ,-1/41-t I Y UN I A Jfitt 1 The Sherwin- Williams Company THE SPECIALTY DIVISION 6830 Cochran Rd. Solon, 011 44139.3908 For ordering information, additional copies of MSDS, etc., 1-800-832-2541 For technical Information only, 216. 292.7400 Emergency Telephone 216- 292 -7400 THE OSHA HAZARD COMMUNICATION STANDARD 29 CFR 1910.1200 REQUIRES THAT THE INFORMATION CONTAINED ON THIS SHEET BE MADE AVAILABLE TO YOUR WORKERS. INSTRUCT YOUR WORKERS TO HANDLE THIS PRODUCT PROPERLY DESCRIPTION: KRYLON INTJEXT. ENAMEL PRODUCT TYPE: SPARY PAINT "AEROSOL" 10- Apr -89 APPLICATION: ITEMS 1501 THRU 2503 —1501 GLOSSY WHITE. 1502 FLAT WHITE. 1503 ANTIQUE WHITE, 1504 IVORY,1506 ALMOND, 1802 PASTEL YELLOW, 190G SLATE BLUE. 1929 PLUM (SAFETY PURPLE), 2413 CORAL. 2415 ROSE, 2502 LIGHT BEIGE, 2503 TAUPE, 15012 GLOSSY WHITE, 15022 FLAT WHITE, 15032 ANTIQUE WHITE, 15062 ALMOND SIGNAL WORD DANGER! THIS MATERIAL IS A "HEALTH HAZARD" AND /OR A "PHYSICAL HAZARD" AS DETERMINED WHEN REVIEWED ACCORDING TO THE REQUIREMENTS OF THE OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION 29 CFR PART 1910.1200 "HAZARD COMMUNICATION" STANDARD. CHEMICAL HAZARD RATING HEALTH =2(MODERATE) FIRE =4(EXTREME) REACTIVITY =0(LEAST1 CHRONIC =' 29CFR1910.I200 HAZARDOUS INGREDIENTS /REPORTED HEALTH EFFECTS CAS /REGISTRY NO, MATERIAL DESCRIPTION % RANGE THE INGREDIENTS LISTED BELOW HAVE BEEN ASSOCIATED WITH ONE OR MORE OF THE LISTED IMMEDIATE AND/OR DELAYED (') HEALTH HAZARDS. RISK OF DAMAGE AND EFFECTS DEPENDS UPON DURATION AND LEVEL OF EXPOSURE. BEFORE USING OR HANDLING. READ AND UNDERSTAND THE MSDS. 67-64-1 ACETONE 30 -50 NOTE REVISED OSHA PEL CAN CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION. SIGNS AND SYMPTOMS MAY INCLUDE HEADACHE. DIZZINESS. NAUSEA, VOMITING. UNCONSCIOUSNESS AND EVEN ASPHYXIATION. —SEE FOOTNOTE C. ACGIH TLV: 750 PPM(1780 MG,M31 TWA ;1000 PPM(2375 MG,M31 STEL OSHA PEL 750 PPMI1800 MO/M3) TWA :1000 PPM(2400 MG /M31 STEL NIOSH DOCUMENT NUMBER: 78.173 74-98-6 PROPANE 10.30 THIS MATERIAL IS A SIMPLE ASPHYXIANT. SIGNS AND SYMPTOMS OF OVEREXPOSURE INCLUDE CYANOSIS. RESPIRATORY DISTRESS HE.D.CuE DIZZINESS. DROWSINESS. UNCONSCIOUSNESS AND ASPHYXIATION CAN CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION. —SEE FOOTNOTE C. ACGIH TLV: SIMPLE ASPHYXIANT - SEE ACGIH TLVS, APPENDIX E OSHA PEL 1000 PPM (1800 MO /M3( TWA 78-93-3 'METHYL ETHYL KETONE 5-10 NOTE REVISED OSHA PEL SUSPECT REPRODUCTIVE HAZARD. MAY CAUSE REPRODUCTIVE DISORDERS BASED ON ANIMAL DATA. METHYL ETHYL KETONE MAY POTENTIATE (SHORTEN THE TIME OF C:iSET PERIPHERAL NEUROPATHY CAUSED BY METHYL N -BUTYL KETONE OR N- HEXANE, METHYL ETHYL KETONE BY ITSELF HAS NOT BEEN SHOWN TO CAUSE PERIPHERAL NEUROPATHY. CAN CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION. SIGNS AND SYMPTOMS MAY INCLUDE HEADACHE. DIZZINESS. NAUSEA, VOMITING. UNCONSCIOUSNESS AND ASPHYXIATION. REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED OCCUPATIONAL OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND INHALING THE CONTENTS MAY LEAD TO ADDICTION AND MAY BE HARMFUL OR FATAL. —SEE FOOTNOTE C. ACGIH TLV: 200 PPM (590 MG ;M31 TWA: 300 PPM (885 MG M31 STEL OSHA PEL 200 PPM (590 MG /MJ) TWA: 300 PPM (885 MG /M3I STEL NIOSH DOCUMENT NUMBER: 78-173 108-10-1 METHYL ISOBUTYL KETONE 1-5 NOTE REVISED OSHA PEL CAN CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION SIGNS AND SYMPTOMS MAY INCLUDE HEADACHE. DIZZINESS, NAUSEA. VOMITING. UNCONSCIOUSNESS AND EM/EN ASPHYXIATION —SEE FOOTNOTE C. ACGIH TLV: 50 PPM (205 MG /M3) TWA: 75 PPM (300 MG,M31 STEL OSHA PEL 50 PPM (205 MGIM3) TWA: 75 PPM (300 MG /M31 STEL NIOSH DOCUMENT NUMBER: 76 -173 108.65.6 2- PROPANOL 1-METHOXY-. ACETATE —SEE FOOTNOTE C ACGIH TLV: NONE ESTABLISHED OSHA PEL NONE ESTABLISHED 5-10 108.88.3 *TOLUENE NOTE REVISED OSHA PEL CAN CAUSE LIVER DAMAGE. CAN CAUSE KIDNEY DAMAGE. CAN CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION. SIGNS AND SYMPTOMS MAY INCLUDE HEADACHE, DIZZINESS, NAUSEA. VOMITING. UNCONSCIOUSNESS AND ASPHYXIATION. REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED OCCUPATIONAL OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND INHALING THE CONTENTS MAY LEAD TO ADDICTION AND MAY BE HARMFUL OR FATAL. —SEE FOOTNOTE C. ACGIH TLV: 100 PPM (375 MG,M31 TWA: 150 PPM (560 MG•M3) STEL OSHA PEL 100 PPM (375 MB /M3) TWA: 150 PPM (560 MB /M3I STEL NIOSH DOCUMENT NUMBER: 73-11023 1-5 1330-20-7 'XYLENE 10.30 NOTE REVISED OSHA PEL CAN CAUSE LIVER DAMAGE. CAN CAUSE KIDNEY DAMAGE. CAN CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION. SIGNS AND SYMPTOMS MAY INCLUDE hE.ADACHE. DIZZINESS, NAUSEA. VOMITING. UNCONSCIOUSNESS AND EVEN ASPHYXIATION. —SEE FOOTNOTE C. ACGIH TLV: 100 PP",I (435 MG,M31 TWA: 150 PPM (655 MG:M3) STEL OSHA PEL 100 PPM (435 MGIM3) TWA: 150 PPM (655 MO /M3I STEL NIOSH DOCUMENT NUMBER: 75-158 13463-67-7 *TITANIUM DIOXIDE • 5.10 NOTE REVISED OSHA PEL CAN CAUSE LUNG FIBROSIS. PRE - EXISTING RESPIRATORY DISORDERS MAY 3S AGGRAVATED BY EXPOSURE. —SEE FOOTNOTE C. ACGIH TLV: TOTAL OUST 10 MGIM3 TWA OSHA PEL RESPIRABLE FRACTION/TOTAL DUST 5 /10 MO /M3 TWA FOOTNOTE C: AS OF THE DATE OF ISSUANCE OF THIS DOCUMENT. THIS MATERIAL HAS NOT BEEN LISTED BY NTP. IARC OR OSHA AS A CARCINOGEN PHYSICAL DATA VAPOR PRESSURE — SEE CAN PRESSURE VAPOR DENSITY HEAVIER THAN AIR SOLUBILITY IN WATER SPECIFIC GRAVITY LIGHTER THAN WATER EVAP RATE FASTER THAN BUTYL ACETATE BOILING POINT•APPEARANCEADOR PERCENT VOLATILE BY WEIGHT PERCENT NON - VOLATILE BY WEIGHT PRESSURE IN CONTAINER. PSIG . 70 F. SEE REVERSE SIDE C I IRRFNT ISSI IF. 1 f1- APR.RO SL!G -17 NA NA r1T -'I) 11 TO 13 APPROX.60 kn. +cn +c r c Material Safety Data Sheet May be used to comply with OSHA's Hazard Communication Standard, 29 CFR 1910.1200. Standard must be consulted for specific requirements. IDENTITY (As Used on Label and Ust) ALCONO U.S. Department of Labor Occupational Safety and Health Administration (Non- Mandatory Form) Form Approved OMB No. 1218 -0072 Note: Blank spaces are not writhed. It any Item is not applicable, or'no information Is evadable, the spec must be marked to indicate that, • Section 1 Manufacturer's Name ALCONOX INC. Emergency Telephone Number CHEMTEL: 800 -255 -3924 Specific Gravity (H20 . 1) Address (Number, Street, City, State, and ZIP Coot) 9 EAST 40th SREET Telephone Number for Information 212 532 -4040 N.A. NEW YORK, NY 10 016 r Date Prepared FEBRUARY 18r 1993 Evaporation Rate _ (Butyl Mesta . 1) Signature of Prepare' (cptionar) Section 11 — Hazardous Ingredients/Identity Information Hazardous Components (Specific Chemical Identity; Common Name(s)) OSHA PEL ACGIH TLV Other Limits Recommended Wo (optional) THERE ARE NO INGREDIENTS I_N ALCONOX WHICH _APPEARED ON_ SITE OSHA STANDARD 29 CFR 1910 SUBPART Z Section III — PhyslcaUChem(cal Characteristics Boiling Pant N.A. Specific Gravity (H20 . 1) N -A- N.A. Vapor Pressure (mm Hg.) N.A. Melting Polyp , Vapor Density (AIR • t) N.A. Evaporation Rate _ (Butyl Mesta . 1) N.A. Solubdrty in Water APPRECIABLE (GREATER THAN 10 PER CEAIm ) Appearance and Odor WHITE POWDER INTERSPE• • WI Section IV — Fire and Explosion Hazard Data •••: Flash Pant (Method Used) NONE WATER CO D Special Fire Fighting Procedures FOR FIRES INVOLVING THIS MATERIAL DO NOT ENTER •WITIIQIIT PROTECTIVE EQUIPMENT AND SELF CONTAINED BREATHING APPARATUS_ Unusual Fire and Explosion Hazards Extinguishing Media Flammable Limits LEL N.A. UEL N.A. V V . • NONE tRNnrTiefira try .Uv1 r Section V — Reactivity Data Stability Unstable CcnclItione to Avoid Stabte XX Incompatibility (Mater/als fo Avold) AVOID STRONG ACIDS Hazardous Decomposition or Byproducts MAY RELEASE CQ GAS ON BURNING Hazardous Polymerization May Occur Conditions to Avoid NONE Will Not Occur XX Section VI -- Health Hazard Data Route(s) of Entry: Inhalation? YES Sdn? Ingestion? NO YES Health Hazards (Acute and Chronic) Carcinogenicity: INHALATION OF POWDER MAY PROVE LOCALLY IRRITATING TO MUCOUS MEMBRANES. INGESTION MAY CAUSE nisrnMr0RT AND /OR DIARRHEA. NO IARC Monographs NO OSHA Regulated? • Signs and Symptoms of Exposure Medical Conditions Generally Aggravated by Exposure EXPOSURE MAY IRRITATE MUCOUS MEMH ANM_ MAY CAUSE SNEEZING. RESPIRATORY CONDITIONS MAY BE AGGRAVATED BY POWDER Emergency and First Aid Procedures EYES —FLUSH WITH PLENTY OF WATER FOR 15 M ?__t UTES SKIN — FLUSH WITH PLENTY n7 WATEF INGESTION –DRINK LARGE QUANTITIES OF WATE GET MED , • ' • �.. • ' OR'1 Section VII -- Precautions for Safe Handling and Use Steps to Be Taken in Case Material la Released or Spilled MATERIAL FOAMS PROFUSELY. SHO AS MUCH'AS POSSIBLE ER. MATERIAL IS COMPLETELY BIODECJtADABLE, West DisposL al Method Si'iAL QUANTITIES MAY BE DISPOSED OF TN SEWER. LARGE QUANTITIES SHOULD__ BE DISPOSED • e a c'- " • • tr 1. •; • 1. . •.• Precautions to Be Taken In Handling and Stori STORE IN A DRY AREA TO PREVENT CAKING. Other Precautions NO SPECIAL REQUIREMENTS OTHER THAN THE GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICES EMPL•YED WI ,. ANY I D TRIG_ Section VIII -- Control Measures Respiratory Protection (specify lype) DUST MASK Protective Gloves USEFUL –NOT REQUIRED Other Protective Clothing or. Eoui �T REQUIRED Eye Protection USEFUL –NOT REQUIRED Work/Hygienic Practices NO SPECIAL PRACTICES REQUIRED Peg* 2 • us••• 'NU.p91.529/4S775 i� Date Issued: 08/19/91 Supercedes: 07/17/91 TEXACO MATERIAL SAFETY DATA SHEET NOTE: Read and understand Material Safety Data Sheet before handling or disposing of product 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION MATERIAL IDENTITY Product Code and Name: 02353 TEXACO ANTI - FREEZE COOLANT Chemical Name and /or Family or Description: Antifreeze Manufacturer's Name and Address: Texaco Lubricants Company a Division of Texaco Refining and Marketing Inc. P.O. Box 4427, Houston, TX 77210-4427 Telephone Numbers: TRANSPOkTATION EMERGENCY Company: (914) 831 -3400 CHEMTREC: (800) 424 -9300 HEALTH EMERGENCY Company: (914) 831 -3400 GENERAL MSDS ASSISTANCE (914) 838-7204 TECHNICAL INFORMATION Fuels: (914) 838 -7336; Lubricants /Antifreezes: (914) 838 -7509 Chemicals: (512) 459 -6543 ' 2. COMPOSITION /INFORMATION ON INGREDIENTS OSHA IARC Proouct and /or Component(s) Carcinogenic According to: Composition:. Chemical /Common Name * 1,2-ethanediol Water deionized NTP OTHER CAS No. Exposure Limit 107211 50ppm Ceiling -OSHA 80.00 - 94.99 50ppm Ceiling -ACGIH 7732185 None Established NONE X Range in % Product is hazardous according to OSHA (1910,1200). Componentls) is hazardous according to. OSHA or one or more state Rignt -to -Know laws, . 1.00 - 3,99, 3. HAZARD IDENTIFICATION EMERGENCY OVERVIEW Appearance and Odor: Fluorescent green liquid; mild odor DANGER! WARNING STATEMENT HARMF.UL OR FATAL IF SWALLOWED MAY CAUSE KIDNEY AND NERVOUS SYSTEM DAMAGE MAY CAUSE EYE IRRITATION KEEP OUT OF REACH OF CHILDREN AND PETS ATTENTION!. POSSIBLE BIRTH DEFECT HAZARD CONTAINS ETHYLENE GLYCOL WHICH MAY CAUSE BIRTH DEFECTS BASED ON ANIMAL DATA HMIS. NFPA Health 2 Reactivity: 0 Health: 2 Reactivity: Flammability: 1 Special:. - Flammability: 1 Special: POTENTIAL HEALTH EFFECTS_ EYE SKIN. INHALATION INGESTION. Primary Route of Exposure _ X X .X ' Page: 1 N.A:.- Not Applicable N.T. Not Tested > -'Greater Than. N.D. Not Determined < - Less Than PRODUCT CODE: 02353 Date Issued: 08/19/91 PRODUCT. NAME: TEXACO ANTI - FREEZE COOLANT Supercedes: 07/17/91 3. HAZARD IDENTIFICATION (CONT) Effects of Overexposure Acute Eyes: May cause irritation, experienced as mild discomfort and seen as slight excess redness of the eye. Skin: Prolonged or widespread skin contact may result in the absorption of potentially harmful amounts of material. Brief contact may cause slight irritation. Prolonged contact, as with clothing wetted with material, may cause more severe irritation and dis- comfort, seen as local redness and swelling. Inhalation: Vapors or mist, in excess of permissible concentrations, or in unusually high concentrations generated from spraying, heating the material or as from exposure in poorly ventilated areas or confined spaces, may cause irritation of the nose and throat, headache, nausea, and drowsiness. Ingestion: Toxic. Causes headache, weakness, confusion, loss of coordination, dizziness, difficulty walking, nausea, vomiting, decreased blood pressure, increased heart rate, pulmonary edema, kidney failure, unconsciousness, convulsions, and coma. Symptoms may be delayed. Severe poisoning may cause death. Sensitization Properties: Unknown. Chronic: Repeated ingestion may cause kidney damage. Medical Conditions Aggravated by Exposure: Repeated overexposure may aggravate existing kidney disease. Because of its irritating properties, repeated skin contact may aggravate an existing dermatitis (skin condition). Other Remarks: Ethylene glycol and diethylene glycoi are toxic when swallowed. A lethal dose for an adult is 1 -2 ml per kilogram, or about 4 ounces (one-half cup). Symptoms include staggering, slurred speech, loss of coordination, confu- sion, faintness, nausea, vomiting, increased heart rate, difficulty breath- ing, difficulty seeing, convulsions, and collapse. Symptoms may be delayed. Decreased urine output, kidney failure, and nervous system damage may also occur. FIRST AID MEASURES Eyes: Immediately flush eyes with plenty of water for at least 15 minutes. Hold eyelids apart while flushing to rinse entire surface of eye and lids with water. Get medical attention. Skin: Wash skin with plenty of soap and water for several minutes. Get medical attention if skin irritation develops or persists, Ingestion: If patient is conscious and can swallow, give two glasses of water (16 oz.) Induce vomiting immediately as directed by medical personnel. Get immedi- ate medical attention. Never give anything by mouth to an Unconscious or convulsing person. Page: 2. N.D. - Not Determined N.A.•- Not Applicable N.T. - Not Tested - Less Than > - Greater Than ;ID PRODUCT CODE: 02353 . Unusual or Explosive Hazards: None 6. ACCIDENTAL RELEASE MEASURES (Transportation Spills Call: CHEMTREC (800) 424 - 9300) Procedures in Case of Accidental Release, Breakage or Leakage: Ventilate area. Avoid breathing vapor. Use self - contained breathing apparatus or supplied air for large spills or confined areas. Contain spill if possible. Wipe up or absorb on suitable material and shovel up, Prevent entry into sewers and waterways.. Avoid contact with skin, eyes or clothing. 7. HANDLING AND STORAGE Precautions to be Taken in Handling and Storage: Minimum feasible handling temperatures should be maintained. Periods of exposure to high temperatures should be minimized. Water contamination should be avoided. 8. EXPOSURE CONTROLS /PERSONAL PROTECTION Protective Equipment (Type) Eye /Face Protection: Chemical -type goggles or face shield recommended to prevent eye contact. Skin Protection: Workers should wash exposed skin several times daily with soap and water. Soiled work clothing should be laundered or dry - cleaned at least once a week. Page: 3 N.D. - Not Determined < - Less Than N.A. - Not Applicabie N.T. - Not Tested. > - Greater Than PRODUCT CODE: 02353 PRODUCT NAME: TEXACO ANTIFREEZE COOLANT Date Issued: 08/19/91 Supercedes: 07/17/91 8. EXPOSURE CONTROLS /PERSONAL PROTECTION (CONT) Respiratory Protection: Airborne concentrations should be kept to lowest levels possible. If vapor, mist or dust 1s generated, use respirator approved by MSHA or NIOSH as appropriate. Supplied air respiratory protection should be used for cleaning large spills or upon entry into tanks, vessels. or other confined spaces. See below for applicable permissible concentrations. Ventilation: Adequate to meet component occupational exposure limits (see Section 2 Exposure Limit for Total Product: None established for this product; refer to Section 2 for component permissible concentration. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance and Odor: Fluorescent green liquid; mild odor Boiling Point (Degrees F.): 388 Percent VOC: 100 Specific Gravity: 1.13 (H20 =1) Vapor Density: 2.14 pH of undiluted product: 11.0 Solubility in Water: Sol. Vapor Pressure: LT 0.1 mrnhg Viscosity: 24 cP 0 20 C Other: Air= 1 10. STABILITY AND REACTIVITY This Material Reacts Violently With: (If others is checked below, see comments for details) Air Water Heat Strong Oxidizers Others None of These Y Comments: Do not add or formulate with amines. See Section 15, OTHER INFORMATION. Products Evolved When Subjected to Heat or Combustion: Carbon monoxide and carbon dioxide may be formed on burning in limited air supply. Boron, molybdenum and silicon compounds may also be released. OCCUR DO. NOT OCCUR ' Hazardous Polymerizations: _ X 11. TOXICOLOGICAL INFORMATION TOXICOLOGICAL INFORMATION(ANIMAL TOXICITY DATA) Median Lethal Dose (LOBO LCSO) (Species) Oral: Animal data does not reflect human toxicity; See Sections 3 & 15 Inhalation: N.D. Dermal: believed to be > 3 g /kg (rabbit); practically non -toxic Irritation Index, Estimation of Irritation (Species) Skin: believed to be 0.5- 1.0/8.0 (rabbit): slightly irritating Eyes: believed to be 15- 25/110 (rabbit); slightly irritating Sensitization: N.D. Other: Ethylene glycol has been shown to cause birth defects in laboratory animals. Continuous ingestion of a diet containing 1% or 2% ethylene glycol for two years produced liver and kidney damage, and bladder stones in rats. Page: 4 N.D. - Not Determined .N.A. - Not Applicable - Not Tested - Less Than > - Greater Than PRODUCT CODE: 02353. PRODUCT NAME: TEXACO ANTI- FREEZE COOLANT Date Issued: 08/19/91 Supercedes: 07/17/91 12. DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHODS This product has been evaluated for RCRA characteristics and does not meet the criteria of a hazardous waste if discarded in its purchased form. Under RCRA, it is the responsibility of the user of the product to deter- mine at the time of disposal, whether the product meets RCRA criteria for hazardous waste. This is because product uses, transformations, mixtures. processes, etc, may render the resulting materials hazardous. REMARKS To prevent contamination of drinking water supplies, & poisoning of chil- dren, aquatic life, wildlife, and farm and domestic animals, used anti- freeze solution, regardless of quantity, should never be discarded onto the ground, into surface waters, or into storm sewers. 13. TRANSPORT INFORMATION TRANSPORTATION DOT: PROPER SHIPPING NAME: N.D. IMDG: PROPER SHIPPING NAME: N.D. IATA: PROPER SHIPPING NAME: N.D. TDG: PROPER SHIPPING NAME: N.D. 14. REGULATORY INFORMATION A. SARA TITLE II1 Title III Section 302/304 Extremely Hazardous Substance: Component CAS No. Percent RO (lbs) TPO (lbs) NONE CERCLA Section 102(a) Hazardous Substance Component CAS No. Percent RO (lbs) Trisodium orthophosphate 7601549 0,1 -0.99. .5000 Disodium phosphate 7558794 0.1 -0.99 5000 Etnylene glycol 107211 80- 94.99 1 Title III Section 311 Hazard Categorization Acute Chronic Fire Pressure Reactive Not Applicable X X Title III Section 313 Toxic Chemicals Component CAS No. 1,2-Ethanediol 107211 B. WHMIS CLASSIFICATION CLASS D. DIV 2, SUBDIV A C. MICHIGAN CRITICAL MATERIALS No critical materials present. Percent 80-94.99. 15. OTHER INFORMATION Acute or chronic oral consumption of products containing ethylene glycol can produce significant adverse.health effects, including death, in 'humans and animals. Keep out of reach'of children and ,pets. Such products should not be used in potable (drinking) water systems or other systems where con -' tamination of potable water supplies is possible (e.g., recreatlonal ve -` htcles, winterizing potable water systems). Page :: 5 N.A: Not Applicable N.T. Not.Tested. N.O. - Not Determined < 7 Less.Than > - Greater Than PRODUCT CODE: 02353 PRODUCT NAME: TEXACO ANTI - FREEZE COOLANT 16. PRODUCT LABEL Date Issued: 08/19/91 Supercedes: 07/17/91 READ AND UNDERSTAND MATERIAL SAFETY DATA SHEET BEFORE HANDLING OR DISPOSING OF PRODUCT DANGERI 02353 TEXACO ANTI - FREEZE COOLANT WARNING STATEMENT HARMFUL OR FATAL IF SWALLOWED MAY CAUSE KIDNEY AND NERVOUS SYSTEM DAMAGE MAY CAUSE EYE IRRITATION KEEP OUT OF REACH OF CHILDREN AND PETS ATTENTION! POSSIBLE BIRTH DEFECT HAZARD CONTAINS ETHYLENE GLYCOL WHICH MAY CAUSE BIRTH DEFECTS. BASED ON ANIMAL DATA PRECAUTIONARY MEASURES DO NOT DRINK ANTIFREEZE OR SOLUTION AVOID CONTACT WITH EYES • AVOID BREATHING MIST OR VAPOR WASH THOROUGHLY AFTER HANDLING FIRST AID INGESTION: If, patient is conscious and can swallow, give two glasses of water (16 oz.) Induce vomiting immediately as directed by medical personnel. Get immedi- ate medical attention. Never give anything by mouth to an unconscious or convulsing person. INHALATION: If 'irritation, headache, nausea, or drowsiness occurs, remove to fresh air. Get medical attention if breathing becomes difficult or symptoms•persist. EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes. Hold • eyelids apart while flushing to rinse entire surface of eye and lids with water. Get medical attention, SKIN CONTACT: Wash skin with plenty of soap and water for several minutes. Get medical attention if skin irritation develops or persists. • NOTE TO'PHYSICIAN: Ethylene or Diethylene Glycol poisoning may.initially produce behavior changes, drowsiness, vomiting, diarrhea, thirst, and convulsions, Renal damage or failure with metabolic acidosis are late signs of poisoning, Immediate treatment,,may•reduce toxic effects, sup- plemented, if necessary with hemodialysis. Intravenous Ethanol in Sodium' Bicarbonate solution is a recognized antidote; other antidotes have been reported for Ethylene Glycol poisoning. Contact a poison center for. further treatment Information. FIRE In case of fire, use foam, dry chemical, or CO2. Use water spray to keep containers cool. Chemical /Common Name CAS No. Range in % * 1,2-ethanediol 107211 80.00 - 94.99 Water deionized 7732185 1.00 - 3.99 Product is hazardous according to OSHA (1910,1200). * Component(s) is hazardous according to OSHA or•one or more state Right -to -Know laws. Not classified as a hazardous material by DOT definition. HMIS Health : 2 Reactivity : Flammability: 1 Special National Fire Protection Association 'Health 2 Reactivity : 0 Flammability: 1 Special : - CAUTION: Misuse of empty containers can be hazardous. Empty containers can be hazardous if used to store toxic, flammable, or reactive materials. Cutting or welding of empty containers might cause fire, explosion or toxic fumes from residues. Do not pressurize or expose to open flame or heat. Keep.container closed and drum bungs in place. Page: 7 N.D. Not Determined .N.A. - Not Applicable. <:. Less Than > Greater Than N.T. • Not .Tested PRODUCT CODE: 02353. PRODUCT NAME:. TEXACO ANTI - FREEZE COOLANT Date Issued: 08/19/91 Supercedes: 07/17/91 Do not add or formulate with amines. The nitrites in this product may combine with•amines to form nitrosamines. Many nitrosamines have been found.to cause cancer in laboratory animals. • . Texaco recommends that all exposures to this product be minimized by strictly adhering to recommended occupational controls procedures to any potential adverse health effects. THE INFORMATION CONTAINED HEREIN IS BELIEVED TO BE ACCURATE. IT IS PROVIDED INDEPENDENTLY OF ANY. SALE OF'THE.PRODUCT FOR PURPOSE OF HAZARD COMMUNICATION AS PART.OF TEXACO'S PRODUCT. • SAF.ETY.PROGRAM. IT IS. NOT INTENDED TO CONSTITUTE PERFORMANCE INFORMATION CONCERNING THE .PRODUCT. NO EXPRESS. WARRANTY,•OR IMPLIED WARRANTY OF MERCHANTABILTIY OR FITNESS FOR A`PARTICULAR PURPOSE IS INFORMATION WITH RESPECT TO THE PRODUCT OR THE NFORMATION CONTAINED HEREIN. DATA SHEETS.ARE AVAILABLE FOR, ALL. TEXACO PRODUCTS. ,YOU. ARE URGED TO OBTAIN DATA SHEETS FOR ALL TEXACO PRODUCTS YOU BUY, PROCESS, USE OR DISTRIBUTE AND YOU ARE ENCOURAGED AND REQUESTED •TO ADVISE'THOSE 'WHO MAY COME IN CONTACT WITH.SUCH PRODUCTS OF THE INFORMATION CONTAINED HEREIN: • TO DETERMINE APPLICABILITY,OR EFFECT OF ANY LAW OR REGULATION .WITH RESPECT TO THE PRODUCT,'. USER SHOULD CONSULT HIS LEGAL ADVISOR OR THE APPROPRIATE GOVERNMENT AGENCY, TEXACO ,DOES NOT UNDERTAKE. :TO FURNISH ADVICE ON SUCH MATTERS.' avoid Date: 08 -19 -91 Date. Printed: 02-03 -92 New X Revised, .Supersedes: 07 -17 -91 regarding MSDS should, be directed Texaco Inc Manager, Product Safety P.O. Box 509 Beacon, N.Y. 12508 PLEASE SEE NEXT. PAGE FOR PRODUCT LABEL Page : :6 N;D .. Not'Determined N,.A r:.Not`Appliaable N...T Nat Tested .. - Less Than > Greater.: Than AMEREX CORPORATION P. 0, BOX 81, TRUSSVILLE, Al. 35173.0081 RESPONSIBLE PARTY: MSOS COORDINATOR MATERIAL SAFETY DATA SHEET DATE PREPARED: 8.1.91 TELEPHONE: 2056553271 SUPERSEDES: 8.22.88 EMERGENCY TELEPHONE NO. DAY /NIGHT: CHEMTREC 1- 800 - 424.9300 IDENTIFICATION PRODUCT NAME: FFFP LIQUID FOAM CONCENTRATE FIRE E X TiM atOtt ea SYNONYMS: ALCOSEAL 3-8%; PROTEIN HYOROLYSATE; FILM•FORMING FLUOROPROTEIN FOAM; ALCOHOL RESISTANT FILM-FORMING FLUOROPROTEIN FOAM; AMEREX MODEL 504 CHARGE; AMEREX MODEL 534 CHARGE HAZARDOUS INGREDIENTS MATERIAL CAS NO. Hexytene Glyool 107 -41.5 Mixturo of Hydrolyzed protein, Surface Active Agents and Inorganic Salts In Water None OSHA PEL Not Established Not Established ACGIH TLV 25 ppm ceiling Not Established OTHER INGREDIENTS MATERIAL CAS NO. NONE PHYSICAL AND CHEMICAL CHARACTERISTICS BOIUNG POINT ( °F): No Data SPECIFIC GRAVRY(H20.1) :1.09 VAPOR PRESSURE (MM HG): No Data PERCENT VOLATILE (%): 35 VAPOR DENSITY (AIR - 1): Not Measured EVAPORATION RATE: No Data SOLUBIUTY REACTIVITY MELTING IN WATER: 100% IN WATER: NA POINT( °F): 19 pH: NA APPEARANCE & ODOR: Dark brown liquid, strong animal odor. FLASH POINT (0F): NA AUTO IGNITION TEMPERATURE ( °F): NA FLAMMABLE LIMITS IN AIR BY VOL NA EXTINGUISHER MEDIA: None. This material Is an extinguishing agent. SPECIAL. FIRE FIGHTING PROCEDURES: None UNUSUAL. FIRE AND EXPLOSION HAZARDS: None PHYSICAL HAZARDS STABILITY: Stable CONDITIONS TO AVOID: None known INCOMPATIBILITY (MATERIALS TO AVOID): None known HAZARDOUS DECOMPOSITION PRODUCTS: None known HAZARDOUS POLYMERIZATION: Will not occur IiEALTH EFFECTS AND FIRST AID PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Store at 25 ° F to 120° F. Use original container or stainless steel. OTHER PRECAUTIONS: None. STEPS TO BE TAKEN IN CASE PRODUCT IS RELEASED OR SPILLED: 11 regulations permit, flush to sewer at 0.5% concentration. Product Is biodegradable. For large spills absorb with Inert material, Dispose of In accordance with local, state, and federal regulations. HMIS RATINGS: HMIS HAZARD INDEX MINIMAL 0 HEALTH 1 SLIGHT 1 FLAMMABILITY 0 MODERATE 2 REACTIVITY 0 SERIOUS 3 SEVERE 4 EFFECTS OF ACUTE OVEREXPOSURE FOR PRODUCT: EYES; Irritant. SKIN: Irritant. BREATHING: Irritant, SWALLOWING: Irritant, . • FIRST AID: IF IN EYES: Flush with water for 15 minutes. Seek medical attention. IF ON SKIN: Wash with soap and large quantity of water. IF BREATHED: Remove victim to fresh air. IF SWALLOWED: Induce vomiting and seek medical attention. PRIMARY ROUTES OF ENTRY: Eyes, Skin Contact, Breathing, Swallowing MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: None known. EFFECTS OF CHRONIC OVEREXPOSURE FOR PRODUCT: None known. PRODUCT LISTED AS CARCINOGEN OR POTENTIAL CARCINOGEN: NATIONAL TOXICOLOGY PROGRAM: [ 1 YES • IARC MONOGRAPHS: [X] NO [) YES [X] NO OSHA ( ) YES [X) NO CONTROL MEASURES AND PROTECTIVE EQUIPMENT RESPIRATORY PROTECTION (TYPE): Not normally required. VENTILATION: GENERAL. AREA Recommended LOCAL EXHAUST: Recommended SKIN PROTECTION: Rubber Gloves EYE PROTECTION: Safety Glasses, Goggles or Shield OTHER PROTECTIVE CLOTHING OR EOUIPMENT: None required WORK /HYGIENE PRACTICES: Use good personal hygiene and good housekeeping practices. SPECIAL PRECAUTIONS AND SPILL /LEAK PROCEDURES PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Store at 25 ° F to 120° F. Use original container or stainless steel. OTHER PRECAUTIONS: None. STEPS TO BE TAKEN IN CASE PRODUCT IS RELEASED OR SPILLED: 11 regulations permit, flush to sewer at 0.5% concentration. Product Is biodegradable. For large spills absorb with Inert material, Dispose of In accordance with local, state, and federal regulations. HMIS RATINGS: HMIS HAZARD INDEX MINIMAL 0 HEALTH 1 SLIGHT 1 FLAMMABILITY 0 MODERATE 2 REACTIVITY 0 SERIOUS 3 SEVERE 4 The information provided herein Is offered In good faith and Is to the best of our knowledge current. Although certain hazards ere described herein we cannot state that these are the only hazards which exist. Final determination of suitability and sale usage of this material Is the sole rosponsibiliiy of the user who Is obligated to review this data in the specific context of the Intended use and determine appropriateness. No guarantee Is implied or expressed regarding the accuracy of this information or the use of this material since the conditions of use are beyond our control, ANSULMMMARMEIE PROTECTION 542 j^Ir( E A- tKov►3t-a. ✓ MATERIAL SAFETY DATA SHEET HALON 1211 QUICK IDENTIFIER (In Ptah Common Nam*) Manulactur*r'e Nams: ANSUL FIRE PROTECTION, WORMALD U.S., INC. Emergency Telephone No.: (715) 735 -7411 Address: One Stanton Street, Marinette, WI 54143-2542 Other Information Calls: Same Prepared By: Saf= and Health De • artment SECTION 1 — IDENTITY Date Prepared: June 1, 1988 Common Name: (used on label) (Rade Name and Synonyms) Halon 1211, BCF Chemical Name: Bromochtorodif luoromethane CAS No.: N/A Chemical Family: Halogenated Hydrocarbon Formula: CF2CIBR SECTION 2 — INGREDIENTS PART A — HAZARDOUS INGREDIENTS Principal Hazardous Component(e) (chemical and common neme(s)): % CAS No. ACGIH TLV Bromnchlorodilluoromethane Greater than 99 353.59 -3 Not listed Acute Toxicity Data ihI rat LCL0 32 pph/15 M PART B — OTHER INGREDIENTS Other Component(s) (chemical end common name(s)) CAS No. Acute Tbxlclty Data None N/A N/A N/A SECTION 3 — PHYSICAL AND CHEMICAL CHARACTERISTICS (Fire and Explosion Data) Boiling Point: 26 or, Percent Volatile by Volume ( %): Solubility In Water: 100 Negligible Vapor Density (Air - I): 51 Specific Vapor Gravity (H20.1): 1 99 Pressure (mm Hg): Evaporation Rate (Butyl acetate - IF gas at room temperature 37.5 psi @70 °F Reactivity In Water: Unreactive and Colorless, sweet odor. Flash None to Flammable Limits Point: boiling In Air % by volume: N/A Extinguisher Auto•Ignlllon Media: N/A Temperature: N/A Special Fire Fighting Procedures: THIS IS AN EXTINGUISHING AGENT. Use water to cool fire- exposed cylinders or other containers. Self- contained breathing apparatus with full facepiece and protective clothing when re-entering unventilated fire areas where product has been used. Unusual Fire and Explosion Hazards: Containers are equipped with pressure and temperature relief devices, but rupture may occur under fire conditions and toxic decomposition by- products may be formed If used in fires over 900 °F. SECTION 4 — PHYSICAL HAZARDS Stability: Unstable ❑ Conditions Stable k► to Avoid: Decomposes under fire conditions above 900 °F, Incompatibility (Materials to Avoid): Active metals, such as aluminum and magnesium, and fires of metal h drides surdous Decomposition Products: erma • ecompos t on; = eg na • ecompos ng at temperatures a • • ve r r tog ve free hallgena, halogen acids and small amounts of carbonyl halides. These by- products have a sharp irritating odor. They are dangerous even in low concentrations, and In sufficient concentrations, can result in personal Injury or death. Hazardous Polymerization: Will Not Occur ki to Avoid: N/A May Occur 0 Conditions NOTE: As used In Ansul extinguishers or cylinders, Halon 1211 is a gas compressed under pressures up to 200 psi. SECTION 5 — HEALTH HAZARDS Threshold limit Value: None listed In ACGIH or OSHA. Routaa of Entry The effects of exposure to HaIon 1211 should disappear quickly upon removal from exposure. Eye Contact: The liquid form of this material can produce chilling sensations and discomfort. Skin Contact: Systemically toxic concentrations are unlikely to be absorbed through the skin in man. Evaporation of liquid from the skin can produce chilling sensations. Skin Injury does not result. Inhalation: Exposures to concentrations of this material above 4% for longer than one (1) minute can cause toxic side effects. Ingestion: Ingestion is not likely to occur since this material Is gas at room temperature. Symptoms Acute xposure: Dizziness, impaired coordination, reduced mental acuity, and cardiac effects above 4% concentration in excess of one minute. Unconsciousness or even death In heavier concentrations with longer exposures. Chronic Overexposure: Unknown Medical Conditions Generally Aggravated by Exposure: Cardiac problems Chemical listed as Carcinogen or Potential: National Toxicology Yea 0 Program: No A] I.A.R.C. Yes 0 Monographs: No Al OSHA: Yea 0 Nog) SECTION 6 — EMERGENCY AND FIRST AID PROCEDURES Eye Contact: Skin Contact: Inhalation: Immediately flush eyes with plenty of water for at least 15 minutes while holding lids open. If redness, Itching or a burning sensation 'develops, get Medical attention. Wash the material off the skin with copious amounts of soap and water for at least 15 minutes. If redness, itching, or burning occurs, get Medical attention. Remove victim to fresh air. If cough or other respiratory symptoms occur, consult Medical personnel. If not breathing, give artificial respiration, preferably mouth -to- mouth. If breathing Is difficult, give oxygen. Consult Medical personnel. Ingestion: If patient is conscious, give 1 or 2 glasses of warm water to drink and get Medical attention. DO NOT INDUCE VOMITING. Have victim Ile down and keep warm. NOTE TO PHYSICIAN: Product Is an asphyxiant and can Induce cardiac muscle sensitization to circulating epinephrine -like compounds. Do NOT give adrenalin or similar sympalhomimetic drugs. Do NOT allow victim to exercise until 24 hours following specific exposures. Freeze burns of mucosal tissue can develop following specific exposures. SECTION 7 — SPECIAL PROTECTION INFORMATION Respiratory Protection (Specify Type): Not normally necessary it controls are adequate. For high concentrations exceeding 4%, or If exposure is prolonged, use positive pressure air - supplied respirator. Ventilation Local Recommended Mechanical Recommended in low areas Exhaust: to control (General): or Indoors where vapors exposures. See may collect. mechanical. Protective Eye Chemical goggles recommended. Full faceshield Gloves: Plastic if working with liquid. Protection: In addition If splashing of liquid form Is possible. Other Protective Eye wash and safety showers are good safety practice In work area when working with Clothing or Equipment: liquefied product. SECTION 8 — SPECIAL PRECAUTIONS AND SPILL /LEAK PROCEDURES Precautions to be Taken In Handling and Storage: Store as a liquefied compressed gas in DOT approved pressure vessels away from high temperatures. If cylinder Is not connected to a system, It must be safety capped to protect against actuation of valve and release of agent. Other Precautions: Note incompatibility information in Section 4. Steps to be Taken in Case Evacuate area; ventilate to outside atmosphere. Cool or remove hot metal Material Is Released or Spilled: - surfaces or source of norrextingulshed flamer. - '^ Waste Disposal Methods: Dispose of In compliance with local, state, and federal regulations. N/A • Not Applicable NDA o No Data Available A. NSUL.. ^NsuLETTE. lECT" 2 t-tvt. C�}4 �utst..Q.V MATERIAL SAFETY DATA SHEET PLUS -FIFTY C OUICK IDENTIFIER (In Plant Common Name) Manufacturer's Name: ANSUL FIRE PROTECTION, WORMALD U.S., INC. Address: One Stanton Street, Marinette, WI 54143.2542 Emergency Telephone No.: Other Inlormatlon Calls: (715) 735.7411 Same Prepared By: Safety and Health Department Date Prepared: June 1, 1986 SECTION 1 — IDENTITY Common Name: (used on label) (Trade Name and Synonyms) Plus -Fifty C Dry Chemical Extinguishing Agent Chemical Name: N/A This Is a mixture CAS No.: Chemical Family: N/A Mixture Formula: N/A SECTION 2 — INGREDIENTS PART A — HAZARDOUS INGREDIENTS Principal Hazardous Component(e) (chemical and common name(s)): Muscovite Talc Magnesium Aluminum Silicate % CAS No. Less than 5 1318-94-1 20 mppcf' NDA Less than 5 8031.18.3 10 mg /M3 NDA ACOIH TLV Acute Toxicity Data 'Million particles per cubic foot PART 8 — OTHER INGREDIENTS Other Component(s) (chemical and common name(s)) Sndlum RU xrhnrta)a Methyl Hydrogen Polysiloxane CAS No. Acute Toxicity Data Oral LD50 (rat) Greater than 90 144 -55-8 4220 mg/kg Less than 1 63148-57-2 NDA Oral LD50p (rat) _Blue Pigment (Hostaperm Blue) Less (hart 0.1 0014714.8 6400 mglkg SECTION 3 — PHYSICAL AND CHEMICAL CHARACTERISTICS (Fire and Explosion Data) Boning PoInl: N/A Percent Volatile by Volume ( %): Solubility In Water. Appearance and Odor: N/A SIlDht Vapor Density (Air . 1): N/A Specific Gravity (H2O.1): Evaporation Rale N/A N/A Vapor Pressure (mm Hg): N/A Reactivity In Weler: Unreactive Blue colored powder, no characteristic odor. Flash Point: None Flammable Limits In Air % by Volume: N/A Extinguisher Auto•Ignlllon Media: N/A Temperature: N/A Special Fire Fighting Procedures: N/A THIS IS AN EXTINGUISHING AGENT Unusual Fire and Explosion Hazards: None SECTION 4 — PHYSICAL HAZARDS SIabllHy: Unstable O Conditions Stable j1) to Avoid: N/A ncom atiblllly (Materials to Avoid): Strong acids, Na K alloy and NH4H2PO4 Hazardous Decomposition Products: CO2 Hazardous May Occur L") Conditions Polymerization: WHI Not Occur )l to Avoid: N/A SECTION 5 — HEALTH HAZARDS Threeshold OSHA nuisance dust limit of 15 mg /M3 or ACGIH Nuisance dust value of 10 mgIM for the eight hour time-weighted average. Routes of Entry Eye Contact: Mildly Irritating for a short period of time. Skin Contact: May be mildly Irritating. Inhalation: Treat as a mineral dust. Irritant to the respiratory tract. Ingestion: Not an expected route of entry. Signs and Acute Symptoms Overexposure: Transient cough, shortness of breath. Chronic Overexposure: Talcosis, pulmonary fibrosis. Medical Conditions Generally Aggravated by Exposure: Reactive airway Chemical Usted as Carcinogen or Potential: National Toxicology Yes ❑ Program: No It7 I.A.R.C. Yes ❑ Monographs: Hoff OSHA: Yes ❑ No )13 SECTION 6 — EMERGENCY AND FIRST AID PROCEDURES Eye Contact: Skin Contact: Inhalation: Ingestion: Flush with large amounts of water; if Irritation persists, seek Medical attention. Wash with soap and water; If irritation persists, seek Medical attention. Remove victim to fresh air. Seek Medical attention If discomfort continues. If patient Is conscious, give large amounts of water and Induce vomiting. Seek Medical help. SECTION 7 — SPECIAL PROTECTION INFORMATION Respiratory Protection (Specly Type): Dust mask where dustiness Is prevalent, or TLV exceeded. Mechanical filter respirator If exposure is pro onge . Ventilation Local Mechanical Exhaust: Discretionary (General): Recommended Protective Gloves: N/A Eye Recommended as mechanical barrier Protection: for prolonged exposure Other Protective Clothing or Equipment: If irritation occurs, long sleeves and Impervious gloves should be worn. afalafilMaraMeirl SECTION 8 — SPECIAL PRECAUTIONS AND SPILL /LEAK PROCEDURES Precautions to be Taken In Handling and Storage: Should be stored In original container or Ansul flre extinguisher. Other Precautions: Do not mix agents, Steps to be Taken In Case Materiel is Released or Spilled: Sweep up. Waste Disposal Methods: Dis • ose of In com • Hance with local state, and federal re a ulations. N/A Nol Applicable NDA ■ No Data Available ANSUL TIRE ANSUL MARNETTE. PROTECTION 2542 _ r‘rC-. it,.4�,11S� X Manufacturer's Name: ANSUL FIRE PROTECTION, WORMALD U.S., INC. MATERIAL SAFETY DATA SHEET PWS -FIFTY B QUICK IDENTIFIER (In Plant Common Name) E y Tale nc No.: (715) 735 -7411 Address: One Stanton Street, Marinette, WI 54143 -2542 Other Information Calls: Same Prepared 8y: Safety and Health Department Date Prepared: Juno 1, 1988 SECTION 1 — IDENTITY Common Name: (used on label) (Trade Name and Synonyms) Plus -Fifty B Dry Chemical Extinguishing Agent CAS No.: N/A Chemical Name: N/A This is a mixture Chemical Family: Mixture Formula: N/A SECTION 2 — INGREDIENTS PART A — HAZARDOUS INGREDIENTS •1111•111104.11111. ANIIMOIMIMINIIMMOIMMINP Principal Hazardous Componential (chemical and common name(s)): % CAS No. ACGIH TLV Mute Toxicity Data Muscovite Talc Less than 5 1318.94 -1 20 mppct' NDA 'Million particles per cubic foot PART IT — OTHER INGREDIENTS Other Componeni(s) (chemical and common name(s)) CAS No. Acute Tbxiclty Data • 11 : d r : : Oral LDSp (rat) 4220 me ke Magnesium Stearate Less than 1 557.04.0 Blue Pigment (Hostaperm Blue) Lnsa than 05 00147.14:9 NDA Oral Lbw (rat) 8400 mg /kg , SECTION 3 — PHYSICAL AND CHEMICAL CHARACTERISTICS (Fire and Explosion Data) Bolling Point: N/A Percent Volatile • by Volume ( %): Solubility In Water: N/A Slight Vapor Density (Air - I): N/A Specula Gravity (H20 -1): Evaporation Rale ( - 1): N/A N/A Vapor Pressure (mm Hg): N/A Reactivity In Water: Unreactive Appearanco and Odor: Blue colored powder, no characteristic odor. Flash Point: None Flammable Limits In Alr % by Volume: N/A Extinguisher Auto•Ignitlon Media:. N/A Temperature: N/A Special Fire Fighting Procedures: N/A THIS IS AN EXTINGUISHING AGENT Unusual Fire and Explosion Hazards: None SECTION 4 — PHYSICAL HAZARDS Stab:ltly: Unstable 0 Conditions Stable $) to Avoid: N/A IncanPaltbltlty (Materials to void): Strong acids, Na K alloy and NH4H2PO4 )iazardous Decomposition Products: co Aarardau May Mir I] ondulona Poymedcation: Wlu Not Occur I"t) to Avoid: N/A ANSUL FIRE ANSUL MARiNETIE. 544143.2542 MATERIAL SAFETY DATA SHEET PLUS -FIFTY B QUICK IDENTIFIER (In Plant Common Name) Manufacturer's Name: ANSUL FIRE PROTECTION, WORMALD U.S., INC. Emergency Telephone No.: Address: One Stanton Street, Marinette, WI 54143 -2542 Prepared 8y: Safety and Health Department SECTION 1 — IDENTITY Other Information Calla: Date Prepared: (715) 735.7411 Same June 1, 1986 Common Name: (used on label) (Trade Name and Synonyms) Chemical Name: Plus -Fifty B Dry Chemical Extinguishing Agent N/A This is a mixture CAS No.: N/A Chemical Family: Mixture Formula: N/A SECTION 2 — INGREDIENTS PART A — HAZARDOUS INGREDIENTS Principal Hazardous Component(e) (chemical and common name(e)): % CAS No. ACGIH TLV Acute Tbxictty Data Muscovite Talc Less than 5 1318.94.1 20 mppct' NDA 'Million particles per cubic foot PART 8 — OTHER INGREDIENTS Other Component(s) (chemical and common name(,)) Sodium B(carhnnnte Magnesium Stearate CAS No. Acute Toxicity Data Oral LD50 (rat) GrRntnf than 95 144.55.8 4220 mg /kg Less than 1 557.040 NDA Oral LD500 (rat) 6400 mg /kg Blue Pigment (Hnntaperm Blue) LCIFIR than 0.5 00147 -14 -8 SECTION 3 — PHYSICAL AND CHEMICAL CHARACTERISTICS (Fire and Exploslon Data) Boiling Point: N/A Percent Volatile by Volume (%): N/A Vapor Density (Air .. 1): NIA Specific Gravity (H2O.1): Evaporation Rate ( 1): N/A N/A Vapor Pressure (mm Hg): NIA Solubility In Water: Slight Reactivity In Water: , Unreactive Appearance and Odor: Blue colored powder, no characteristic odor. Flash Point: None Flammable Limits In Air % by Volume: N/A Extinguisher Auto- Ignitlon Media: N/A Tbmperature: N/A Special Flre Fighting Procedures: N/A THIS IS AN EXTINGUISHING AGENT Unusual Fire and Explosion Hazards: None SECTION 4 — PHYSICAL HAZARDS Stablllly: Unstable 0 Conditions Stable gi to Avoid: N/A Incompatibility (Moterlate to Avoi(1): Strong acids, Na K alloy and NH4H2PO4 Hazardous Decomposition Products: CO - ey Occur r Con dons . ANSULAmNAZETTE. 2 i—tr°C.. �yL•nalns�L -vr Manufacturer's Emergency Nerve: ANSUL FIRE PROTECTION, WORMALD U.S., INC. •Telephone No.: MATERIAL SAFETY DATA SHEET FORAY QUICK IDENTIFIER (In Plant Common Name) Address: Prepared 9y. One Stanton Street, Marinette, WI 54143.2542 Safe and Health De artment SECTION 1 — IDENTITY Other Information Cane: (715) 735.7411 Same Date Prepared: June 1, 1988 Common Name: ( Ym.�el) (trade Name and Foray Dry Chemical Extinguishing Agent Chemical Name: Formula: CAS No.: N/A N/A This Is a mixture Chemical Family: Mixture N/A SECTION 2 — INGREDIENTS PART A — HAZARDOUS INGREDIENTS Principal Hazardous Component(s) (chemical and common name(s)): % CAS No. ACOIH TLV Acute Toxldly Data Muscovite Mica Magnesium Aluminum Silicate less than 5 12001-282 20 mppcf' NDA less than 5 8031.18 -3 10 mg/M3 NDA 'Million particles per cubic foot PART 5 — OTHER INGREDIENTS Other Component(e) (chemical and common name(s)) CAS No. Acute Toxicity Data Monoammonlum Phosphate Greater than 75 7722 -781 NDA Ammonium Sulfate Greater than 10 Methyl Hydrogen Polysiloxane Less than 1 Yellow Pi: ment Less than 0.1 7783.20.2 NDA 8314857.2 NDA 5468-75-7 NDA SECTION 3 — PHYSICAL AND CHEMICAL CHARACTERISTICS (Fire and Explosion Data) Soiling Point: NIA Percent Volatile by Volume ( %): • N/A Vapor Denny (Air • Ik N/A Solubility In Water: Slight Specific Gravity (H20.1): N/A Evaporation Rate ( • 1): N/A Reactivity In Water: Unreactive Vapor Pressure (mm Hg): N/A Appearance and odor: Yellow colored powder, no characteristic odor. Flash Point` None Flammable Limits In Alf % by Volume; N/A Extinguisher Auto•gnitlon Media: N/A Temperature: N/A Special Fire Fighting Procedures: N/A THIS IS AN EXTINGUISHING AGENT Unusual Fere and Explosion Hazards: None SECTION 4 — PHYSICAL HAZARDS Stability: Unstable ❑ Conditions Stable gi to Avoid: N/A Incompeubeity (Melanie to Avoid); Strong alkalis, Mg eraz r g."1"1"in Prods' NH and /or PO ma be evolved. May • cur Condit win Not Occur RI to Avoid: N/A Poepo maiden: SECTION 5 — HEALTH HAZARDS Thr sho ue: OSHA nuisance dust limit of 15 mg /m3 or ACGIH Nuisance dust value of 10 mg /m for the eight hour time-weighted average. Routes of Entry Eye Contact: Mildly Irritating for a short period of time. Skin Corned: May be mildly irritating. Inhalation: Treat as a mineral dust. Irritant to the respiratory tract. Ingestion; Not an expected route of entry. Signs end Acute Symptoms Overexposure: Transient cough, shortness of breath. Chronic Overexposure: Chronic fibrosis of the lung, pneumoconiosis. • Medical Conditions Generally Aggravated by Exposure: Reactive airway Chemical Listed as Carcinogen or Potential: National Toxicology Yna U t.A.R.C. Yes U OSHA: Yes ❑ Program: No7 Monographs: No Nod] SECTION 6 --- EMERGENCY AND FIRST AID PROCEDURES Eye Contact: Skin Contact: Inhalation: Ingestion: Flush with large amounts of water; If irritation persists, seek Medical attention. Wash with soap and water; if Irritation persists, seek Medical attention. Remove victim to fresh air. Seek Medical attention if discomfort continues. If patient is conscious, give large amounts of water and induce vomiting. Seek Medical help. SECTION 7 — SPECIAL PROTECTION INFORMATION Respiratory Protection (Specify Type): Dust mask where dustiness Is prevalent, or TLV exceeded. Mechanical filter respirator If exposure Is pro onge . Ventilation Protective Gloves: N/A Local Mechanical Exhaust: Discretionary (General): Recommended Eye Protection: Other Protective Clothing or Equipment: 11 irritation occurs, long sleeves and impervious gloves should be worn. Recommended as mechanical barrier for prolonged exposure SECTION 8 -- SPECIAL PRECAUTIONS AND SPILL /LEAK PROCEDURES Precautions 10 be Taken In Handling and Storage: Should be stored in original container or Ansul lire extinguisher. Other Precautions: Do not mix agents. Steps to be Taken In Case Material is Released or Spitted: Sweep up. Waste Disposal Methods: Dispose of in accordance with local, state, and federal regulations, NA • Not Applicable NDA • No Data Available HfllbUL. •,1401./L. N tint r,u,L.,w,. MARINETTE. W 541432542 MATERIAL SAFETY DATA SHEET PURPLE -K OUICK'IDENTIFIER (In Plant Common Name) Manufacturer's Nsme: ANSUL FIRE PROTECTION, WORMALD U.S., INC. Emergency Teleptwns No.: (715) 735.7411 Address: One Stanton Street, Marinette, WI 54143.2542 Other Information Calls: Prepared Sy: Safet and Health De • artment SECTION 1 — IDENTITY Common Name: (used on label) (Trade Namo and Synonyms) Purple•K Dry Chemical Extinguishing Agent Chemical Name: Formula: N/A This Is a mixture Date Prepared: Same June 1, 1988 CAB No.: N/A Chemical Family: Mixture N/A SECTION 2 — INGREDIENTS PART A — HAZARDOUS INGREDIENTS Principal Hazardous Component(a) (chemical and common name(s)): % CAS No. ACOIH TLV Acute Toxicity Data Muscovite Mica Magnesium Aluminum Silicate Less than 5 12001 -26.2 20 mppcf' NDA Less than 10 8031.18.3 10 mg/M3 NDA 'Million •articles er cubic root PART S — OTHER INGREDIENTS Other Component(s) (chemical and common nsme(s)) CAS No Acute Toxicity Data Potassium Bicarbonate Greater than 90 Methyl Hydrogen Polysiloxane Less than 1 289.14 -18 NDA 83148.57.2 NDA Purple Pigment Less than .05 Red Pigment SECTION 3 — PHYSICAL AND CHEMICAL CHARACTERISTICS (Fire and Explosion Data) Less than .05 69208-41-8 1103.38 -4 NDA NDA Bolling Point: N/A Percent Volatile by Volume ( %)I Solubility In Water: N/A Slight Vapor Density (Air - 1): NIA Specific Gravity (H20. 1): N/A Evaporation Rate ( ' 1): N/A Reactivity in Water: N/A Vapor Pressure (mm Hg): N/A Appearance and Odor: Violet colored powder, no characteristic odor. Flash Point: None Flammable Limits In Mr % by Volume: N/A Extinguisher Auto - ignition Media: N/A Temperature: N/A Special Fire Fighting Procedures: N/A THIS IS AN EXTINGUISHING AGENT Unusual Fire and Explosion Hazards: None SECTION 4 — PHYSICAL HAZARDS Stability: Unstable 0 Conditions Stable I(7 to Avoid: N/A ncompatibility (Materials to Avoid): Strong acids, NaK alloy and NH4H004 Hazardous Decomposition Products: CO2 Hazardous May Occur 0 Conditions Polymerization: Will Not Occur 10 to Avoid: N/A SECTION 5 — HEALTH HAZARDS T rr esvt OSHA nuisance dust limit of 15 mg /M3 or ACGIH Nuisance ance dust value of 10 mg /M for eight hour time-weighted average. Routes of Entry Eye Contact: Mildly Irritating for a short period of time. Skin Contact: May be mildly irritating. Inhalation: Treat as a mineral dust. Irritant to the respiratory tract. Ingestion: Not an expected route of entry. Signs and Acute Symptoms Overexposure: Transient cough, shortness of breath. Chronic Overexposure: Chronic fibrosis of the lung. Medical Conditions Generally Aggravated by Exposure: Reactive airway Chemical Listed es Carcinogen or Potential: National Toxicology Yes 0 Program: No I,A,R.C. Yes 0 Monographs: No p SECTION 6 — EMERGENCY AND FIRST AID PROCEDURES OSHA: Yes 0 Novi Eye Contact: Skin Contact: Inhalation: Ingestion: Flush with large amounts of water; if Irritation persists, seek Medical attention. Wash with soa• and water; If irritation •ersists seek Medical attention. Remove victim to fresh air. Seek Medical attention if discomfort continues. If patient is conscious, give large amounts of water and Induce vomiting. Seek Medical help. SECTION 7 — SPECIAL PROTECTION INFORMATION Respiratory Protection (Speclly Type): Dust mask where dustiness Is prevalent, or TLV exceeded. Mechanical filter respirator If exposure Is prolonged. Ventilation Local Mechanical Exhaust: Discretionary (General): Recommended Protective Gloves: N/A Eye Recommended as mechanical barrier Protection: for prolonged exposure Other Protective Clothing or Equipment: 11 irritation occurs, long sleeves and impervious gloves should be worn. SECTION 8 = SPECIAL PRECAUTIONS AND SPILL /LEAK PROCEDURES Precautions to be Taken in Handling and Storage: Should be stored in original container or Ansul fire extinguisher. Other Precautions: Do not mix agents. Steps to be Taken n Cese Material Is Released or Spilled: Sweep up. Waste Disposal Methods: Dispose of In compliance with local, state, and federal regulations. N/A • Not Applicable NDA - No Data Available ANSUL. MAJ1NE IE. 4td32542 I—trt vt IS '.✓ MATERIAL SAFETY DATA SHEET CARBON DIOXIDE OUICK IDENTIFIER (In Plant Common Nome) Menulacturar's Name: ANSUL FIRE PROTECTION, WORMALD U.S., INC. Emergency Teisphone No.: Address: One Stanton Street, Marinette, WI 54143.2542 IInnfoorrmation Calls: Prepared 8y: Safet and Health De artment Date Prepared: (715) 735.7411 Same June 1, 1988 SECTION 1 — IDENTITY Common Name: (used on label) (Trade Name and Synonyme) Chemical Name: Carbon Dioxide Carbonic Acid, Carbonic Anhydride CAS No.: 124 -38.9 Carbon Dioxide Chemical FamNy: Gas Formula: CO SECTION 2 — INGREDIENTS PART A — HAZARDOUS INGREDIENTS Principal Hazardous Component(s) (chemictd and common name(s)): Carbon Dioxide % CAS No. ACOIH TLV Acute Toxicity Data LCuo 100 124 -38-9 5000 ihl0,00 ppm /lm ppm 100,000 ppm PART 8 — OTHER INGREDIENTS Other Component(a) (chemical and common name(s)) None % N/A CAS No. Acute Toxicity Data N/A N/A SECTION 3 — PHYSICAL AND CHEMICAL CHARACTERISTICS (Fire and Exploalon Data) Boiling Point` N/A sublimes Percent Volatile by Volume ( %): Vapor 100 Density (Air . t): 1.5 Grravity (H20. t): 1.88 Vapor r re (mm Hp): 830 psi ® 20 °C Evaporation Rate N/A Gas at ( . t)` room temperature Solubility In Water: 88 ml COp per 100 mi H2O @ 20 °C Appearance and Odor: Colorless gas with no odor. Reactivity in Water: Slight -forms H2CO3 Flash Flammable Limits Point: None In Air % by Volume: N/A Extinguisher Autalgnitlon Media: N/A Temperature: N/A Special Fire Fighting Procedures: N/A THIS IS AN EXTINGUISHING AGENT Unusual Fire end Explosion Hazards: • Though gas cylinders are equipped with pressure and temperature relief devices, they should be removed from high temperatures or fire to avoid risk of rupture. SECTION 4 — PHYSICAL HAZARDS Stability: Unstable 0 Conditions Stable )"(i to Avoid: N/A Incompatibility (Materiels to Avo4d)Aeacts vi • orousl with Al + Na 0 Cs 0 LI K M. CH M. + Na 0 KHC Na Na . NaK Ti Hazardous Decomposition Products: None hazardous Polymerization: Will Not Occur Id to Avoid: N/A May Occur O Conditions NOTE: As used in Ansul extinguishers, cartridges, or cylinders, CO2 Is a gas compressed under pressures up to 880 psi at 70 °F. SECTION 5 — HEALTH HAZARDS Threshold Limit value: 5000 ppm is the OSHA PEL and the ACGIH TLV (TWA) Routes of Entry Eye Contact: Contact with CO2 snow (dry ice) can produce chilling sensations and discomfort, also frostbite. Skin Contact: Evaporation of liquid from the skin can produce chilling sensations. Frostbite can occur. Avoid CO2 snow (dry Ice). Inhalation: Vapor is heavier than air and can cause suffocation by reducing oxygen available for breathing. Breathing very high concentrations of vapor can cause lightheadedness, giddiness, shortness of breath muscular tremors and weakness, acrocyanosis. Also unconsciousness or even death. Ingestion: Ingestion Is not likely to occur since this material is gas at room temperature. Signs and Symptoms Acute Overexposure: Dizziness, impaired coordination, reduced mental acuity, headaches, tinnitus, difficulty breathing, drowsiness, depending on length of exposure and concentrations. Chronic Overexposure: None known when occupational exposures are below the TLV. Medical Conditions Generally Aggravated by Exposure: Respiratory problems Chemical Listed as Carcinogen or Potential: National Toxicology Yee 0 Program: No iR I.A.R.C. Yea 0 Monographs: No OSHA: Yes 0 No SECTION 6 — EMERGENCY AND FIRST AID PROCEDURES Eye Contact: Skin Contact: Inhalation: Immediately flush eyes with plenty of water for at least 15 minutes while holding lids open. If redness, Itching or a burning sensation develops, get Medical attention. Trent for frostbite if necessary. Wash the material off the skin with copious amounts of soap and water for at least 15 minutes. If redness, itching, or burning occurs, get Medical attention. Treat for frostbite If necessary. Remove victim to fresh air. If cough or other respiratory symptoms occur, consult medical personnel. If not breathing, give artificial respiration, preferably mouth-to-mouth, If breathing Is difficult, give oxygen. Consult Medical personnel. SECTION 7 — SPECIAL PROTECTION INFORMATION Respiratory Protection (Specl y Type): Not normally necessary if controls are adequate. If TLV Is exceeded or if exposure is prolonged, a self-contained breathing apparatus is recommended.. Venttlatlon Local Recommended In Mechanical Exhaust: (General): confined spaces. Recommended Protective Gloves: For contact with dry ice Other Protective Clothing or Equipment: Protective clothing for contact with dry Ice. P election: Chemical goggles recommended when handling liquid. Full faceshield In addition if splashing Is possible. SECTION 8 — SPECIAL PRECAUTIONS AND SPILL /LEAK PROCEDURES Precautions to be Taken Store containers in a clean, dry well•ventilated area, away from heat above 120 °F. Store as a in Handling and Storage: compressed gas in DOT approved vessels. II cylinder or cartridge is not attached to a system, It must be safety capped to protect against violent vessel movement or force of escaping gas if valve Is actuated or seal is punctured. Other Precautions: Note Incompatibility Information In Section 4. Steps to be Taken In Case Evacuate area; ventilate to outside atmosphere. Cool or remove hot, metal surfaces or source Material Is Released or Spitted: of non extinguished flames. Waste Disposal Methods: Dispose of In compliance with all local, state, and federal regulations. N/A a Not Applicable NDA No Data Available ANSUL WI 2 II • r MATERIAL SAFETY DATA SHEET MET-L-X QUICK IDENTIFIER (In Plant Common Name) Manufacturer's Name: ANSUL FIRE PROTECTION, WORMALD U.S., INC. No.: Address: One Stanton Street, Marinette, WI 54143.2542 Prepared By Safe and Health De • artment SECTION 1 — IDENTITY Otter InlormsXn Cans: Date Praprsd: (715) 735.7411 Same June 1, 1986 Common Name: (used on Iatal) OHO, Name and Synonyms) Met-L-X Dry Powder Extinguishing Agent CAS No.: N/A Chemical Name: Formula: N/A This is a mixture N/A SECTION 2 — INGREDIENTS Chemical Family: Mixture PART A — HAZARDOUS INGREDIENTS Principal Hazardous Component(s) (chemical and common name(s)): % CAS No. ACOIH TLV Acute Toxicity Data Saran (Vinylidene chloride acrylonitrlle coPolYtnerj Magnesium Aluminum Silicate 7 9010.78 -8 N/A NDA Less than 10 8031.18.3 10 mg/M3 NDA PART 3 — OTHER INGREDIENTS Other Component(s) (chemical and common neme(s)) Sodium Chinride Magnesium Stearate % Granter than 85 CAS No. Acute Tbxlahy Dela Oral L05 (rat) 7&47 -143000 5 3000 mg /kg Leas than 1 557-04-0 NDA SECTION 3 — PHYSICAL AND CHEMICAL CHARACTERISTICS (Fire and Explosion Data) Boiling Point: N/A Percent Volatile by Volume ( %): Solubility In Water: N/A Slight Specific Gravity (H20.1): N/A Vapor Evaporation Rate Density (Air • 1): N/A ( 1): N/A Reactivity In Water: Unreactive Pressure (mm 14g): N/A Appearance and odor: White colored powder, no characteristic odor. Flash Point: None Special Fire Fighting Procedures: Flammable Limits In Air % by Volume: N/A Extinguisher Auto-Ignition Media: N/A Tbmperature: N/A N/A THIS IS AN EXTINGUISHING AGENT Unusual Fire and Explosion Hazards: None SECTION 4 — PHYSICAL HAZARDS StaaWty: Unstable O Conditions Stable fit to Avoid: N/A (Mat Io Avoid): Violent reaction with BrF3, LI AIaardoue °ocomp°anton Products: Possible( traces of HCI Hazardous May Occur O Condllbna SECTION 5 — HEALTH HAZARDS Threshold ids: OSHA nuisance dust limit of 15 mglM CGIH Nuisance dust value of 1— 0 mg /M� for the eight hour time-weighted average. Routes of Entry Eye Contact: Mildly irritating for a short period of time. Skin Contact: May be mildly Irritating. Inhalation: Not expected with normal use. Ingealbn: Ingestion of large amounts can cause Irritation of the stomach. Signs and Acute Symptoms Overexposure: None expected with single exposure. Chronic Overexposure: None known. Medical Condi Ions Generally Aggravated by Exposure: N/A Chemical Listed u Carcinogen or Potential; National Toxicology Yea ❑ Program: No A-3 I.A.R,C. Yee ❑ Monographs: Not(] OSHA: Yes 0 Hop SECTION 8 — EMERGENCY AND FIRST AID PROCEDURES Eye Contact: Skin Contact: Inhalation: ingestion: Flush with large amounts of water; if Irritation persists, seek Medical attention. Wash with soap and water; if irritation persists, seek Medical attention. If effects occur, remove victim to fresh air. Seek Medical attention If discomfort continues. If patient Is conscious, give large amounts of water and induce vomiting, Seek Medical help. SECTION 7 = SPECIAL PROTECTION INFORMATION Respiratory Protection (specily Type): None required. Ventilation Local Mechanical Exhaust: Discretionary (General►: Recommended Protective Gloves: N/A Eye Protection: Recommended as mechanical barrier for prolonged exposure Other Protective Clothing or Equipment: If Irritation occurs, long sleeves and impervious gloves should be worn. SECTION 8 -- SPECIAL PRECAUTIONS AND SPILL /LEAK PROCEDURES Precautions to be Taken in Handling and Storage: Should be stored In original container or Ansul fire extinguisher. Other Precautions: Do not mix agents. Steps to be Taken In Case Materiel Is Released or Spilled: Sweep up. Waste Disposal Methods: Dispose of in compliance with local, state, and federal regulations. N/A • Not Applicable NDA - No Data Available CITRIC. ACIM CIT Canner Synonym OattMaray.tiurooeW* .ad 2dp0oap'I. 2. 3.0 opem. treartone sod ryeolnO/ao ae01 Oele�lryOa W So1U W,- Odorle.e Simla 111 no u n S wow. 5100 Oe none A cossets Soso peons sway. Avail con1ac1 soh sad and dun C44 tre deosnment rearm and Howe 0aeh.r9W maen01. Natty noel n6atn and poWOon control 191nca► Fire Canorwtole. Extinguish en dry c10111C018 weir. 0001 oe carton donee. Exposure P CALL FOR MEDICAL AID, DUST I65ae19 10 006. dose and throat II Inhaled wed Ca0sa downing or 01601 treeing. If n eyes. mold meads Open and rev r1e1 tram of water 11 breathing 1111 180130S0. 9011 ardc■01 reaaeon. If oruvwg a Odeo t cure omen. SOLID Imla to 111x1 and eyes. He' tl contaminated ad Remove COntamwaled n pant and 100.1. Ran *Homo lieu n do openly a wen. IF IN EYES. Mid anew, pan end Tan won ern 01 wale. IF SWALLOWED and wm d CONSCIOUS. 010e 0 re 01tmm 0,0* wale or 0104 0 C IF SWALLOWED and v.cum a UNCONSCIOUS OR HAVING CONVULSIONS. do (01,0.9 erupt 11000 r.Cnrn *Win war Water Pollution Dat9eran 00 10W.0 Han hall COIC•aabaa. May be clangorous t it enters water misses Nobly Roca Mann end meld. oilcan Nomy overbore of nearby into nta0 =. 1. RESPONSE TO DISCHARGE (806 Response Methods Handbook) Oi pone .ro limn 2. LABEL 2.1 Category; Nos 21 Cane; 0101 penmen* 3. CHEMICAL DESIGNATIONS 3.1 CO ConpetWBNy qua. No) 4,1.4 3.2 601011■18 HOC(CHICOIH),C01H 3.3 IMO /UN De.1901tbe Not Idled 3.4 DOT ID Nos Data not avian* 3.5 CAB Revelry Nos 77.924 4. OBSERVABLE CHARACTERISTICS 4.1 ►hyeleal Sure on snipped* Sold 42 Colon Wlye 4.3 Odor. Nora 5. HEALTH HAZARDS 5.1 Pe60o0101 Protective Equipment Oust 100* poppies t lade stein protean plops 52 Symptom* Fo6.w19 Woman Inhalation d dust make nom a 0 Croat Contact 0,101 .yes taus= nnatron 5.3 Trwtment of Eapo.utx IN(ULATION: move to bean e. EVES INat1 mmned1hly won p8 aceocal N11M a aster 901 medical ors if imam peseta SKIN: flush vin wan. 3.4 Threefold U net Value rte not 'valatle 5.5 Short Tenfm 6lalstlon Unite as not ovulate 5.6 Tolldty by hn9utioo Grads 1; oral LDa. - 11.7 9/09 Old 6.7 Late To•ldtyl Chore elects in henans 11 unmoral 5A Vapor (Gael Irritant Ch.O.leyM1.. Not meant 5.6 Liquid or Solid Inhant Chtscleretlon as not Inviable 5.10 Oda TIr11h0N! Warne 5.11 IDUI Value as not .veaab a . FIRE HALMS {.1 Flesh Pont 6601 tsnelrs nonlLet 00 son) u ftrinuvle unota M AM 028.2.29 n9/m' (duet) 64 Ftra 11 I91.at116 Agars Weer, loan, dry ct*neral carbon de eel= M Ftre E7ninsula WN Auras 104 to IM Woe D.t• not arari.b11 IA Spew H11s of CorMtwuat Procure Dee not av1.10le 6.6 Behavior ti Flt's Mean and ae00m00eaa The naceon a not hazardous. 0.7 Ignition Temperature 1,840•F Ipa.de) 5.11 Electrical Hord Not pennon, 6.5 Soriano Rata: Not peeper4 6.10 Adiabatic Slane Temperature ay nor 'vaaebi. /Con*. w) 11 HAZARD ASSESSMENT CODE (311 Messed Aasermannt Hanscom) 88 7. CHEMICAL REACTIVITY 7.1 RMOMr4y YAM Welsh No reaction 7.2 Rosa-Pity with Common Mahr101. WO corrode coma. Lr.C. alwtnlrRn .nil the alloys 7.3 Stability During Transport Stable 7,4 N.uaa80Yr9 Agents for Add. and Card= Not pel0ma4 7.5 Polymerizations Not pennant 14 Iamlha of PWpnaArstlae Ilot peer4 1.7 Molar Redo (Reactant 10 Produmk Data not meanie 7A Reactivity Group eta not avertable IL HAZARD CLASSIFICATIONS 11.1 Code of Federal 0.9ulatlonse N0f bated 11.2 NA* Heard Rang for Sue Water Traneport.11erc Not bead 111 NFPA Hated CI.e.IflnNorc Not lead 1. WATER POLLUTION 0.1 Aqua*: Toxicity 894 0565/4 N /golo56n /kaed /hale went 100 ppm/4e Misters aeb /TL./NII sat 0.2 W ets/fowl Tondly; as not moan= 1.3 15671o9k, Ory9ed 0em.,4 (00Dk 40 *, 5 day= 80%. 1020 day. M Food Clain Concentration Potwar= Nor* 0., 6.2 91 9.4 1. SHIPPING INFORMATION 0r 0 of Ptaltyo USP. Rupee 110.Iryd•ae pod Snoops Tomptitut= Anton Inert Abnoapsree No nelurtna, Venting Open 12. PHYSICAL AND CHEMICAL PROPERTIES 12.1 Physical BtM5 at 11•C and 1 ante Sour 13.2 140110faer Wept* 192.1 12.3 0=ktp Point at 1 sec Not pennant (demmgose= 12.4 Fr5e•ln9 Point 30TF ■ 150•C . 42e1( 123 Critical Temperature Not 1:e01ln1 124 Crated Pressure No pe00000 12.7 Spence Brevity; 1.54 U 20•C (.pad) 120 Liquid bees* Tension No pttiMrs 128 Uquld Weer Intathelal Tension Not pennon 1210 Vapor (heel Sp.dAO Granny; Not pennant 12.11 Raba of Spee % Hoots of Vega I0.ek Not pertinent 12.12 Latent Hut of V.podmen't Not pear, 12.13 Iles) of Combustion - 4,000 501/01 rs -2.220 cal /9 - -93.0 into 12.14 Heat nt Osoonpoattlor. Not p060*81 1215 HMI of Solution Not pertinent 12.15 Hest of POlymefnllat Not pertinent 12.25 Ilaet of Fusee% Otte nil 80eaaps 12.26 Laming Vallee Data not ar61M* 12.27 R01d Vapor 6(0usse rte rot 'variable 6. FIRE HAZARDS (C/ataload) 6,11 800K0 an186 AM to Fad Raba al. not .ulenb L12 61811 Terncarst r. as rsA.00001. JUNE 1985 C1T CITRIC ACID 12.17 SATURATED LIQUID DENSITY 12.18 LIQUID HEAT CAPACITY 12.19 LIQUID THERMAL CONDUCTIVITY 12.20 UOUID VISCOSITY • Temperature Pounds per 100 Temperature Pounds per Temperature British thermal Temperature British thermal unit Temperature (degrees Fl Pounds per cubic foot • Temperature (degrees F) British thermal unit per pound-F Temperature (degrees F) unit-Inch Per hour- square foot -F Temperature (fees Fl Cendpoiss 34 N N N N 38 O 0 0 0 38 T 7 T T " 40 P P P P • 42 E E E E 44 R T R T R T • R • T 48 I I, • R R 48 N N N N 50 E E E E 52 N N N N 54 T T T T 12.21 SOLUBILITY IN WATER 12.22 SATURATED VAPOR PRESSURE • 12.23 SATURATED VAPOR DENSITY 12.24 IDEAL GAS HEAT CAPACITY Temperature Pounds per 100 Temperature Pounds per Temperature Pounds per cubic Temperature British thermal unit (degrees F) pounds of water (degrees F) square Inch (degrees F) foot (degrees F) per pound -F 34 98,370 N N N 38 101.099 0 0 0 38 103,900 T T • T " 40 106.700 • 42 109.500 P P P 44 112.299 E ' E E 48 115.000 • R R R 48 117,799 T T T 50 120.599 I 52 123.400 N N N 54 126.099 E E E 58 128.900 N N N 58 131,699 T T T 80 134.500 62 137.299 64 140.000 88 142,799 68 145.599 70 148.400 72 151.099 74 153.900 76 158.699. . 78 159.500 80 162.299 82 . 165,000. 84 167,799 OHS14930 PAGE 001 OF 009 MATERIAL SAFETY DATA SHEET OCCUPATIONAL HEALTH SERVICES, INC. 11 WEST 42ND STREET; 12TH FLOOR NEW YORK, NEW YORK 10036 1- 800 - 445 -MSDS (1- 800 - 445 -6737) OR 1 -212- 789 -3535 FOR EMERGENCY SOURCE INFORMATION CONTACT: 1- 615- 366 -2000 SUBSTANCE IDENTIFICATION CAS NUMBER: 75 -09 -2 RTECS NUMBER: PA8050000 SUBSTANCE: DICHLOROMETHANE TRADE NAMES /SYNONYMS: METHANE, DICHLORO -j METHYLENE CHLORIDE; METHYLENE DICHLORIDE; AEROTHENE MM; NARKOTIL; S0LAESTHIN; BOLMETHINE; TC 523 EPDXY DISSOLVER (TECHFORM); LACCO METHYLENE CHLORIDE (PPG INDUSTRIES INC.);' AEROTHENE (R) MM SOLVENT (DOW CHEMICAL); EQUIPMENT FLUSHING SOLVENT (LOCTITE CORPORATION); LS -303 (POLYTECH); 20 -8135 STRIP SOLVE (BUEHLER LTD.); RCRA U080; STCC 4941132; UN 1593; CH2CL2 ;.OH614930 CHEMICAL FAMILY:. HALOGEN COMPOUND, ALIPHATIC MOLECULAR FORMULA: C- H2 -6L2 MOLECULAR WEIGHT: 84.93 CERCLA RATINGS (BCALE•0 -3):. HEALTH -3. FIRE.1 .REACTIVITY -0 PERSISTENCE.1 NFPA RATINGS (SCALE 0 -4): .HEALTH -2 FIRE -1 REACTIVITY -0 COMPONENT: DICHLOROMETHANE CAS(j 75 -09 -2 (: : 2 CONTAMINANTS: NONE EXPOSURE LIMITS: DICHLOROMETHANE (METHYLENE.CHLORIDE) :' 500 PPM OSHA TWA ; '.1000 PPM OSHA CEILING) 50 PPM (174 M0 /M3).ACGIH,TWA ' ACOIH A2- - SUSPECTED' HUMAN.CARCINOGEN, LOWEST FEASIBLE :LIMIT NIOSH RECOMMENDED EXPOSURE 100 PPM (360 M0 /M3)2DFO MAK,TWA; . 500 PPM (1800 M0 /M3) DF0 MAK 30 MINUTE'PEAK,.AVERAQE VALUE, 2 TIMES /SHIFT. MEASUREMENT METHOD :•.CHARCOAL TUBE•(2): CARBON DISULFIDE ;,:GAS' CHROMATOGRAPHY WITH FLAME IONIZATION DETECTION; (NIOSH VOL..III.#•1005).' 1000 POUNDS CERCLA.SECTION 103:, REPORTABLE QUANTITY' SUBJECT TO SARA SECTION 313 ANNUAL TOXIC CHEMICAL RELEASE REPORTING '. SUBJECT TO. CALIFORNIA PROPOSITION 65. CANCER AND /OR REPRO0UCTIVE'TOXICITY WARNING AND RELEASE REQUIREMENTS- (APRIL 1,,1988) COMPONENTS AND CONTAMINANTS PERCENT: 100.0 2000. PPM /5'MIN :IN 2 OHS14930. PAGE 002 OF 009 PHYSICAL DATA DESCRIPTION, CLEAR, COLORLESS LIQUID. WITH A MILD, CHLOROFORM -LIKE ODOR. POINT: 104 F (40 C) MELTING POINT: -139 F'( -95 C) SPECIFIC GRAVITY: 1.3266 VAPOR PRESSURE, 400 MMHG :D 24' C EVAPORATION RATE: (BUTYL ACETATE.1)_27.5 SOLUBILITY IN.WATERi 1 :32i tID 20 C .:'ODOR THRESHOLD: 25 -50 PPM VAPOR DENSITY,. 2.9 SOLVENT SOLUBILITY: SOLUBLE IN ALCOHOL, ETHER, DIMETHYLFORMAMIDE, PHENOLS, . ALDEHYDEB,KETONES, GLACIAL ACETIC ACID, TRIETHYL PHOSPHATE, ACETOACETIC ACID,;. CYCLOHEXYLAMINE; CHLORINATED SOLVENTS. VISCOSITY: 0.441 CPS 0 :20 C: FIRE AND EXPLOSION DATA FIRE AND EXPLOSION HAZARD: SLIGHT FIRE HAZARD. WHEN' EXPOSED TO HEAT OR FLAME, UPPER EXPLOSIVE LIMIT: 23% :'LOWER'-.EXPLOSIVE LIMIT:. .13%. AUTOIGNITION TEMP.: 1033.9 (555. Cr FLAMMABILITY.CLASS(OSHA):,IIIB FIREFIGHTING MEDIAi' DRY CHEMICAL OR CARBON DIOXIDE (1990 EMERGENCY RESPONSE'GUIDE000K,':DOT P,5800.5). FOR LARGER.FIRES, ;USE.,WATER SPRAY, FOG OR • REGULAR-FOAM... (1990. EMERGENCY RESPONSE GUIDEBOOK, DOT P 5800,5), r cFIGHTINOt .r -: t COOLING WATER.TO BIDES.OF CONTAINERS THAT ARE EXPOSED. TO PLAMES:UNTIL .._u AFTER.FIRE IS.'OUT. STAY'AWAY,FROM ENDS QF'TANKS. ISOLATE FOR :1 /2. MILE IN.: . ALL DIRECTIONS IF TANK;'RML CAR,OR..TANK TRUCK'IS INVOLVED IN. FIRE :.(1990 EMERGENCY RESPONSE GUIDEBOOK;' DOT.P 5800.5,• GUIDE PAGE14). •EXTINGUISH .USING.AGENTS :SUITABLE,FOR SURROUNDING,FIRE.; UBE.FLOODING:,QUANTITIES,, OF'WATER'.TO COOL . AFFECTED CONTAINERS,.'.A('PLYING; FROM. AS. PAR :A DISTANCE AS.'.' POSSIBLE:. AVOID BREATHING, HAZARDOUS' VAPORS; KEEP.UNWIND :: • TRANSPORTATION'.DATA DEPARTMENT.09 TRANSBORTATION'HASARD: CLASSIFICATION ,49- CFR.,172:101t • • DEPARTMENT OF TRANSPORTATION LABELING REQUIREMENTS 49- CFR`172401 AND NONE ' . OHS14930 PAGE.003 OF 009 D RTMENT OF TRANSPORTATION PACKAGING REQUIREMENTS: 49 -CFR. 173.605 ?TIONS, 49 -CFR 173.505 FINAL RULE ON HAZARDOUS MATERIALS REGULATIONS (HMR,'49 CFR PARTS 171 -180), DOCKET NUMBERS HM- 181, HM -181A, HM -1818, HM -181C, HM -181D AND HM-204. EFFECTIVE DATE OCTOBER 1, 1991. HOWEVER,' COMPLIANCE WITH'THE REGULATIONS IS AUTHORIZED ON AND AFTER JANUARY.1, 1991. (55 FR 52402, 12/21/90) EXCEPT FOR EXPLOSIVES, INHALATION HAZARDS, AND INFECTIOUS SUBSTANCES, THE. EFFECTIVE DATE FOR' HAZARD COMMUNICATION REQUIREMENTS IS EXTENDED TO OCTOBER 1, 1993. (56 FR.47158,'09/18/91). . U.S.. DEPARTMENT OF TRANSPORTATION SHIPPING NA14E -ID NUMBER, 49 CFR 172.101: DICHLOROMETHANE -UN 1593 U.S. DEPARTMENT OF TRANSPORTATION HAZARD CLASS OR DIVISION, 49 CFR 172.101: 6.1 - POISONOUS MATERIALS'. U.S. DEPARTMENT OF TRANSPORTATION PACKING GROUP, '49'CFR 172.101: PO III U.S. DEPARTMENT OF TRANSPORTATION LABELING REQUIREMENTS, A9 CFR.172.101 AND SUBPART E: KEEP AWAY FROM FOOD U.S. DEPARTMENT OF TRANSPORTATION PACKAGING AUTHORIZATIONS: EXCEPTIONS: 49 CFR 173.153 NON -BULK PACKAGING: 49 CFR 173.203 BULK PACKAGING) 49 CFR 173.241 U.S. DEPARTMENT Of TRANSPORTATION QUANTITY LIMITATIONS 49 CFR 172.101: PASSENGER AIRCRAFT. OR RAILCAR: 60.L CARGO AIRCRAFT ONLY) 220 L. ''TOXICITY DICHLOROMETHANE (METHYLENE CHLORIDE): TATION DATA: 162 MGEYE - RABBIT MODERATE, 10 MO EYE - RABBIT MILD1 MG/24 HOURS EYE-RABBIT MILD /.810MG/24 HOURS SKIN - RABBIT SEVERE! ,U0 MG/24 HOURS SKIN- RABBIT MODERATE. ' . TOXICITY DATA: 500 PPM /1'YEAR- INTERMITTENT INHALATION -HUMAN TCL01 500 PPM /8 HOURS INHALATION -HUMAN TCLO; 88000 MO /M3 /30,MINUTES INHALATION -RAT LC50; 552 PPM /6. HOURS /5 DAY INTERMITTENT ,INHALATION- RAT.TCLO1•14400 PPM /7 HOURS INHALATION -MOUSE LC50; 10000 PPM /7 HOURS INHALATION- RABBIT LCLO; LCLO; 5000'PP1/2 -HOURS INHALATION - GUINEA PIG LCLO; 14108 PPM /7 HOURS. INHALATION -DOG LCL01,43400 MO /M3/4.5 HOURS INHALATION -CAT LCLO1 357.MG/K0 ORAL -HUMAN LDL01,1600 MO /KO ORAL -RAT LD501;1900 MO /KG,ORAL- RABBIT LDLOt. 3 GM /KG ORAL -DOG LDL0, 6460 MO /KO'SUBCUTANEOUS -MOUSE L0501 2700 MO /K0 SUBCUTANEOUS - RABBIT LDLO1 200_MG /KO'INTRAVENOUS -DOG LDL01 916 MG /KG -' INTRAPERITONEAL-RAT L0501.'.437.MG/KG INTRAPERITONEAL =MOUSE LD501,950 MG /KO INTRAPERITONEAL -DOO LDL01 4770 M0 /KG UNREPORTED -MOUSE LD501 MUTAGENIC DATA': (RTECS) REPRODUCTIVE.EFFECTS :DATA (RTECS)1 TUMORIGENIC'DATA (R'TECS).',.. CARCINOGEN STATUS: ANTICIPATED HUMAN CARCINOGEN (NTP); :HUMAN INADEQUATE, EVIDENCE, ANIMAL, SUFFICIENT,. EVIDENCE (IARC GROUP -28).. EXPOSURE. BY INHALATXON INCREASED. THE,. INCIDENCE OF. BENIGN AND MALIGNANT LUNG AND LIVER TUMORS:IN MICE OF EACH SEX AND'THE.,INCIDENCE OR MULTIPLICITY OF. BENIGN MAMMARY TUMORS IN RATS OF EACH SEXj IN MALE:RATS;'AN INCREASED INCIDENCE 'OF SARCOMAS C OCA'.IN THE NECK WAS ALSO OBSERVED: EFFECTS: IRRITANT- INHALATION,..SKIN, EYE. rED E TOX ICITY LEVEL: MODERATELY TOXIC BY'INHALATION AND INGESTION. TARGET EFFECTS: CENTRAL NERVOUS SYSTEM DEPRESSANT; CHEMICAL ASPHYXIANT. POISONING MAY AFFECT THE BLOOD,' LIVER AND.KIDNEYS. AT INCREASED RISK FROM EXPOSURE.: PERSONS WITH SKIN, LIVER, KIDNEY; CARDIOVASCULAR.DISEASE OR ANEMIA ' ADDITIONAL DATA CONCURRENT EXPOSURE TO OTHER SOURCES OF CARBON MONOXIDE, ' SMOKING, OR PHYSICAL ACTIVITY MAY INCREASE THE•LEVEL OF CARBOXYHEMOGLOBIN IN THE BLOOD RESULTING IN ADDITIVE EFFECTS. ALCOHOL MAY ENHANCE THE TOXIC EFFECTS. STIMULANTS SUCH AS EPINEPHRINE MAY INDUCE CARDIAC ARRHYTHMIAS. ONE STUDY INDICATED THAT, CHRONIC EXPOSURE MAY BE ASSOCIATED WITH AN INCREASED RISK OF SPONTANEOUS ABORTION. DICHLOROMETHANE.CROSSES' THE PLACENTA AND.IS EXCRETED IN BREAST MILK. . OHS14930 ' PAGE 004 OF 009 HEALTH EFFECTS AND FIRST AID INHALATION: DICHLOROMETHANE. (METHYLENE CHLORIDE): IRRITANT /NARCOTIC /CHEMICAL. ASPHYXIANT /CARCINOGEN. . ACUTE EXPOSURE- HUMAN EXPOSURE TO 100, PPM HAS RESULTED IN UPPER RESPIRATORY • TRACT IRRITATIONS CONCENTRATIONS AS LOW AS 200 PPM HAVE PRODUCED.TEMPORARY NEUROBEHAVIOURAL'EFFECTS; 500 -1000 PPM.FOR 1 -2 HOURS HAS CAUSED . LIGHTHEADEDNESS AND ELEVATED CARBOXYHEMOGLOBIN LEVEL; 2300 PPM FOR 30 MINUTES HAS CAUSED NAUSEA AND NARCOSIS,' 5000 PPM HAS CAUSED HEADACHE, FATIGUE, NEURASTHENIC DISORDERS'AND.DIGESTIVE DISTURBANCES. OTHER SYMPTOMS MAY,INCLUDE DIZZINESS,. TINGLING, NUMBNESS OF THE EXTREMITIES, A SENSATION OF'HEAT,•A SENSATION OF FULLNESS•IN THE HEAD, DRUNKENNESS; STUPOR,'DULLNESS AND MENTAL - CONFUSION: MASSIVE.EXPOSURE MAY•CAUSE • PHARYNGEAL EROSION, PULMONARY, EDEMA, STAGGERING,'HEMOLYSIS WITH GROSS HEMATURIA, RAPID. UNCONSCIOUSNESS AND DEATH. RECOVERY IS GENERALLY COMPLETE•IF EXPOSURE 1S•TERMINATED BEFORE ANESTHETIC. DEATH. EXPOSURE TO HIGH LEVELS MAY ALSO CAUSE.CARDIAC ARRHYTHMIAS. CHRONIC EXPOSURE -.MORE THAN 100.WORKERS EXPOSED TO LEVELS BELOW.500 PPM HAVE. DEVELOPED HEALTH PROBLEMS INCLUDING SIGNIFICANT :UPPER RESPIRATORY . IRRITATION, EXACERBATION OF CORONARY•ARTERY DISEASE, AND A•HIGH INCIDENCE OF NEUROTOXICITYLINCREASED COMPLAINTS OF CHEST PAINS WERE REPORTED, AT CONCENTRATIONS OF-10, TO 35 PPM. REPEATED HUMAN EXPOSURE TO 500 -3600 PPM YAS CAUSED SIGNS OF.:TOXIC'ENCEPHALOPATHY WITH ACOUSTICAL AND OPTICAL 'DELUSIONS AND HALLUCINATIONS ::A CASE OF SERIOUS CEREBRAL DETERIORATION, WAS OBSERVED 'IN AN. INDIVIDUAL EXPOSED FOR SEVERAL YEARS TG ' DICHLOROMETHANE. IN A MORTALITY STUDY OF TWO,GROUPS•OF WORKERS,,ONE EXPOSED TO.:ACETONE'AND'THE OTHER'TODICHLOROMETHANE AND,ACETONE,,,A .,' STATISTICALLY,'SIGNIFICANT DIFFERENCE IN DEATHS.•FROM DISEASES:OF THE CIRCULATORY SYSTEM :AND.FROM:.ISCHEMIC HEART„ DISEASE'. WERE REPORTED FROM THE DICHLOROMETHANE AND ACETONE GROUP. IN ANOTHER MORTALITY STUDY OF •': WORKERS EXPOSED`TO DICHLOROMETHANE, -,A SIGNIFICANT:INCREASE IN HYPERTENSIVE DISEASE AND.A "SUGGESTIVE.EXCESS!!'OP PANCREATIC CANCER WERE REPORTED.' LIVER DISEASE.HAS BEEN.REPORTED IN WORKERS,• IN.ONE ".STUDY, AN'INCREASE .;( IN -SERUM BILIRUBIN WAS..OBSERVED IN. EXPOSED ,WORKERS ;•BUT NO OTHER SIGN.OF.LIVER INJURY, OR HEMOLYSIS MAO REPORTED:' ADVERSE LIVER'. EFFECTS''.;, WERE. OBSERVEDINSEVERAL ANIMAL SPECIES CHEMICALLY EXPOSED.. TESTICULAR ATROPHY WAS REPORTED IN MICE EXPOSED TO 4000 PPM;OVER:2•YEARS.., REPEATED,INNALATION BY. RODENTS. PRIOR TO AND /OR DURING, GESTATION, CAUSED,,.•. :. FETAL SKELETAL ABNORMALITIES AND BEHAVIORAL EFFECTS IN NEWBORN.OFFSPRING.,':., . REPEATED INHALATION,'INCREASED THE!'INCIDENCE.,OF BENIGN. ,AND :MALIGNANT LUNG AND'LIVER TUMORS IN MICEOF•EACH SEX AND THE. INCIDENCE' OR MULTIPLICITY OHS14930 PAGE 005 OF 009 117 OF BENIGN MAMMARY TUMORS IN RATS OF EACH SEX: IN MALE RATS, AN INCREASED INCIDENCE OF SARCOMAS LOCATED IN THE NECK WAS ALSO OBSERVED. FIRST AID- REMOVE FROM EXPOSURE AREA TO FRESH AIR IMMEDIATELY. IF BREATHING HAS STOPPED, GIVE ARTIFICIAL RESPIRATION. MAINTAIN AIRWAY AND BLOOD PRESSURE AND ADMINISTER OXYGEN IF AVAILABLE. KEEP AFFECTED PERSON WARM AND AT REST. TREAT SYMPTOMATICALLY AND SUPPORTIVELY. ADMINISTRATION OF OXYGEN SHOULD BE PERFORMED BY QUALIFIED PERSONNEL. GET MEDICAL ATTENTION IMMEDIATELY: • SKIN CONTACT: • DICHLOROMETHANE.(METHYLENE CHLORIDE): IRRITANT. ACUTE EXPOSURE-MAY CAUSE EFFECTS RANGING FROM MILD IRRITATION TO SEVERE PAIN„ PARESTHESIAS, AND POSSIBLY BURNS, DEPENDING ON THE INTENSITY OF CONTACT.. CHRONIC'EXPOSURE- PROLONGED OR REPEATED CONTACT MAY•CAUSE A DRY, SCALY AND FISSURED DERMATITIS DUE TO DEFATTING ACTION OF LIQUID:ON SKIN. FIRST AID- REMOVE CONTAMINATED CLOTHING AND SHOES IMMEDIATELY. WASH AFFECTED AREA WITH SOAP OR,MILD DETERGENT AND LARGE.AMOUNTS OF WATER UNTIL NO EVIDENCE, OF CHEMICAL. REMAINS (APPROXIMATELY 15 -20 MINUTES). GET MEDICAL ATTENTION IMMEDIATELY. • EYE CONTACT: DICHLOROMETHANE (METHYLENE CHLORIDE): IRRITANT. • ' ACUTE_ EXPOSURE- VAPOR CONCENTRATIONS ABOVE 2000 PPM MAY CAUSE IRRITATION. DIRECT CONTACT MAY CAUSE PAIN AND EXTREME IRRITATION,, BUT IT I8 NOT LIKELY TO CAUSE SERIOUS INJURY, 10 MG APPLIED TO RABBIT EYES PRODUCED •KERATITIS, IRITIS, INCREASED CORNEAL THICKNESS, AND INFLAMMATION. OF THE CONJUNCTIVA AND EYELIDS WITH SOME EFFECTS' LASTING UP TO TWO WEEKS.' CHRONIC EXPOSURE- REPEATED.OR PROLONGED EXPOSURE TO IRRITANTS MAY CAUSE CONJUNCTIVITIS, • FIRST AID- WASH EYES IMMEDIATELY WITH, LARGE AMOUNTS OF WATER OR NORMAL SALINE, OCCASIONALLY LIFTING, UPPER AND LOWER LIDS, UNTIL NO EVIDENCE OF CHEMICAL MAINS (APPROXIMATELY 15 -20 MINUTES). GET MEDICAL ATTENTION IMMEDIATELY. • St,vNSTI0N: DICHLOROMETHANE (METHYLENE CHLORIDE): NARCOTIC /CHEMICAL ASPHYXIANT. , . ACUTE EXPOSURE; MAY CAUSE, RAPID,, THEN,SLOWED RESPIRATION; GLOTTAL AND PHARYNGEAL EDEMA, INTRAVASCULAR HEMOLYSIS WITH GROSS HEMATURIA,' GASTROINTESTINAL ULCERATION AND HEMORRHAGE, AND CARBOXYHEMOGLOBINEMIA, THESE SYMPTOMS MAY PROGRESS RAPIDLY TO UNCONSCIOUSNESS AND LACK OF RESPONSE TO PAINFUL STIMULI, PHARYNGEAL. EROSIONS MAY.DISTURB THE SWALLOWING MECHANISM RESULTING IN ASPIRATION PNEUMONIA, IN ADDITION, SYMPTOMS OF'CENTRAL NERVOUS SYSTEM DEPRESSION MAY OCCUR,FOLLOWED BY CONVULSIONS AND PARESTHESIA OF,THE EXTREMITIES. LARGE DOSES MAY CAUSE ' LIVER AND KIDNEY'DAMAGE, THE. ESTIMATED LETHAL. DOSE, FOR AN ADULT IS. 25. GRAMS: CHRONIC EXPOSURE -. REPEATED INGESTION BY RATS AND MICE RESULTED IN HISTOMORPHOLOOICAL CHANGES IN THE LIVER.„ FIRST AID- REMOVE BY GASTRIC LAVAGE OR EMESIS. MAINTAIN BLOOD PRESSURE AND AIRWAY. GIVE OXYGEN .IF RESPIRATION I8 DEPRESSED.'DO NOT PERFORM GASTRIC OHS14930 PAGE 006 OF 009 AVAGE OR EMESIS IF.VICTIM IS UNCONSCIOUS. GET MEDICAL ATTENTION 4EDIATELY.(DREISBACH,HANDBOOK OF POISONING,: 12TH ED,): ADMINISTRATION.. .• GASTRIC LAVAGE OR OXYGEN SHOULD BE PERFORMED BY QUALIFIED MEDICAL PERSONNEL. ANTIDOTEt NO SPECIFIC ANTIDOTE. TREAT SYMPTOMATICALLY AND SUPPORTIVELY. REACTIVITY: STABLE UNDER NORMAL TEMPERATURES AND PRESSURES.' REACTIVITY INCOMPATIBILITIES:. DICHLOROMETHANE.(METHYLENE CHLORIDE): .ALKALI METALS: POSSIBLE EXPLOSIVE. REACTION..'. ALUMINUM: VIOLENT,: UNCONTROLLABLE;REACTION ABOVE 95 C. CAUSTICS (STRONG):'VIGOROUS,'.POSSIBLY VIOLENT REACTION.`. COPPER: MAY CORRODE AT ELEVATED. TEMPERATURES IN THE PRESENCE DINITROGEN PENTOXIDE: POSSIBLE EXPLOSION. . DINITROGEN TETROXIDE: FORMS'SHOCK- SENSITIVE MIXTURE. . IRON:. MAY CORRODE AT.ELEVATED•TEMPERATURES :IN.THE PRESENCE LITHIUM: FORMS SHOCK- SENSITIVE MIXTURE. MAGNESIUM: POSSIBLE - EXPLOSION. NICKEL: MAY CORRODE AT ELEVATED TEMPERATURES IN THE NITRIC ACID :, EXOTHERMIC REACTION YIELDING DETONABLE .( OXIDIZERSSTRONO): FIRE AND, EXPLOSION HAZARD. OXYGEN (LIQUID): EXPLOSIVE.REACTION ON IGNITION. PLASTICS, RUBBER. AND COATINGS: MAY BE ATTACKED. POTASSIUM:' EXPLOSIVE REACTION,.. . POTASSIUM HYDROXIDE +•N- METHYL -N- NITROSO UREA: POSSIBLE POTASSIUM TERT- BUTOXIDEs IGNITION REACTION. SODIUM:'FORMS SHOCK- SENSITIVE MIXTURE :' . ' MS SODIUM — POTASSIUM ALLOY: FOR SHOCK- SENSITIVE MIXTURE. STAINLESS STEEL :.MAY CORRODE AT'.ELEVATED'TEMPERATURES IN MOISTURE. TITANIUM: POSSIBLE VIOLENT REACTION.•' NC: POSSIBLE VIOLENT. REACTION..: ' G..OMPOS ITION: THERMAL DECOMPOSITION .PRODU,CTS•MAY :INCLUDE TOXIC AND HAZARDOUS. PHOSGENE` GAS,' TOXIC AND.CORROSIVE •FUMES.CF:'CHLORIDES, AND OXIDES'OF..CARBON. OF MOISTURE. OF MOISTURE.. PRESENCE OF MOISTURE. SOLUTION. EXPLOSION. THE PRESENCE OF POLYMERIZATION:; HAZARDOUS POLYMERIZATION %HAS NOT• BEEN TEMPERATURES AND PRESSURES:.'' ':STORAGE.AND DISPOSAL OBSERVE ALL FEDERAL, STATE;AND LOCAL.REGULATIONS :WHEN STORING OR, DISPOSING OF THIS SUBSTANCE,; FOR' AS8I8TANCE ,`CONTACT'THE.DISTRICT DIRECTOR OF THE'. ENVIRONMENTAL PROTECTION AGENCY: 08814930 ' PAGE 007 OF 009 r ECT AGAINST PHYSICAL DAMAGE. STORE IN COOL, DRY, WELL VENTILATED LION, AWAY FROM ANY AREA WHERE THE FIRE HAZARD MAY BE ACUTE (NFPA 49, .RDOUS.CHEMICALS DATA, 1975). STORE IN A TIGHTLY CLOSED CONTAINER. STORE UNDER' NITROGEN.. STORE AWAY FROM INCOMPATIBLE SUBSTANCES. '* *DISPOSAL ** DISPOSAL MUST BE IN ACCORDANCE WITH STANDARDS APPLICABLE TO GENERATORS OF . HAZARDOUS WASTE, 40CFR 262: EPA' HAZARDOUS WASTE NUMBER U080. • CONDITIONS TO AVOID, MAY BURN BUT, DOES NOT, IGNITE READILY. CONTAINER MAY EXPLODE IN HEAT OF FIRE.. SPILL AND LEAK PROCEDURES. SOIL SPILL: DIG HOLDING AREA SUCH AS LAGOON, POND OR PIT FOR CONTAINMENT. • DIKE FLOW OF SPILLED MATERIAL USING SOIL OR`SANDBAGSOR.FOAMED BARRIERS SUCH AS POLYURETHANE OR CONCRETE USE CEMENT POWDER' OR PLY ASH'TO•ABSORB LIQUID MASS. AIR SPILL: APPLY WATER SPRAY TO WATER SPILL: TRAP SPILLED MATERIAL AT:BOTTOM OR WITHIN SAND BAG BARRIERS; SUCTION HOSES TO REMOVE TRAPPED KNOCK DOWN'VAPORB, IN. DEEP WATER POCKETS, EXCAVATED HOLDING AREAS.' SPILL MATERIAL, THE CALIFORNIA SAFE DRINKING ,WATER.,AND'TOXIC ENFORCEMENT'ACT,OF1986 .. • (PROPOSITION,GS) PROHIBITS'CONTAMINATING ANY .KNOWN SOURCE OF DRINKING WATER ' WITH SUBSTANCES`KNOWN TO CAUSE CANCER' AND /ORs,REPRODUCTIVE.TOXICITY.' OCCUPATIONAL SPILL: i. .. SHUT OFF IONITION..SOURCES. STOPLEAK IV;YOU,CAN.DOIT'WITHOUT RISK. FOR SMALL' LIQUID SPILLS, TAKE UP: WITH SAND, 'EARTH OR OTHER ABSORBENT MATERIAL, FOR. LARGER SPILLS, DIKEFAR:AHEAD_OF.;SPILL FOR LATER.DISPOSAL,,NO SMOKING, FLAMES OR FLARES IN HAZARD•`AREAI KEEP UNNECESSARY PEOPLE AWAY:: '' REPORTABLE QUANTITY :(RQ)::1000 POUNDS THE SUPERFUND AMENDMENTS'AND REAUTHORIZATION ACT'(BARA):•BECTION,304 REQUIRES THAT A RELEASE .EQUAL.TO OR GREATER THAN THE REPORTABLE QUANTITY FOR THIS SUBSTANCE BE IMMEDIATELY REPORTED, TO. THE.: LOCAL EMERGENCY PLANNING COMMITTEE ;_.. AND THE STATE EMERGENCY. RESPONSE. COMMI SSION'(40,.CFR,"355.40)., ;IF :THE RELEASE OF,. THIS SUBSTANCE IS'REPORTABLE UNDER CERCLASECTION'.103, THE NATIONAL RESPONSE ; CENTER MUST 08' NOTIFIED° IMMEDIATELY A" (800).424 -8802 OR (202) 426- 2675 -IN THE OHS14930 PAGE 008 OF 009 ROPOLITAN WASHINGTON, D.C. AREA (40 CFR 302.6). PROTECTIVE EQUIPMENT VENTILATION: PROCESS ENCLOSURE RECOMMENDED TO MEET PUBLISHED EXPOSURE LIMITS. RESPIRATORi THE FOLLOWING RESPIRATORS AND MAXIMUM USE CONCENTRATIONS ARE RECOMMENDATIONS BY THE U.S. DEPARTMENT. OF HEALTH AND HUMAN SERVICES, NIOSH POCKET GUIDE TO CHEMICAL HAZARDS; NIOSH CRITERIA DOCUMENTS OR BY THE U.S. DEPARTMENT OF LABOR, 29 CFR 1910 SUBPART Z. THE SPECIFIC` RESPIRATOR SELECTED MUST BE BASED ON CONTAMINATION LEVELS FOUND IN THE WORK PLACE, MUST NOT EXCEED THE WORKING LIMITS OF THE RESPIRATOR AND BE JOINTLY APPROVED BY THE NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY AND HEALTH AND THE MINE SAFETY AND HEALTH ADMINISTRATION (NIOSH- MSHA)..,". DICHLOROMETHANE ,(METHYLENE'CHLORIDE): AT ANY DETECTABLE CONCENTRATION: ANY SELF- CONTAINED BREATHING APPARATUS THAT HAS A FULL FACEPIECE AND IS OPERATED IN A. PRESSURE - DEMAND' OR' OTHER POSITIVE - PRESSURE MODE. ANY SUPPLIED -AIR RESPIRATOR THAT HAS A FULL FACEPIECE AND IS OPERATED IN A PRESSURE - DEMAND: OR OTHER POSITIVE - PRESSURE MODE IN COMBINATION WITH AN AUXILIARY SELF - CONTAINED BREATHING APPARATUS OPERATED IN PRESSURE- DEMAND OR OTHER POSITIVE - PRE88URE MODE. ESCAPE - ANY AIR - PURIFYING ,FULL- FACEPIECE'RESPIRATOR (GAS MASK) WITH A CHIN - STYLE, FRONT -, OR BACK - MOUNTED ORGANIC VAPOR CANISTER. ANY APPROPRIATE ESCAPE -TYPE, SELF - CONTAINED BREATHING APPARATUS. • FOR FIREFIGHTING AND OTHER IMMEDIATELY DANGEROUS TO LIFE OR HEALTH CONDITIONS: ANY SELF - CONTAINED BREATHING :APPARATUS THAT HAS A FULL FACEPIECE AND IS OPERATED IN A PRE88URE - DEMAND OR OTHER POSITIVE- PRESSURE MODE. ANY SUPPLIED -AIR RESPIRATOR THAT HAS A FULL FACEPIECE AND I8 OPERATED IN :A" tPRESSURE- DEMAND OR OTHER POSITIVE- PRESSURE MODE IN COMBINATION WITH AN 111:: AUXILIARY :SELF- CONTAINED BREATHING'APPARATUS OPERATED IN PRESSURE-DEMAND- - OR OTHER POSITIVE- PRESSURE MODE, CLOTHING: EMPLOYEE MUST WEAR, APPROPRIATE PROTECTIVE (IMPERVIOUS)' CLOTHING AND EQUIPMENT TO PREVENT REPEATED OR'PROLONGED SKIN CONTACT WITH'THIS.SUBSTANCE GLOVES: : . EMPLOYEE MUST WEAR: APPROPRIATE'PROTECTIVE GLOVES TO" . PREVENTCONTACP,WITH SUBSTANCE. .:. EYE PROTECTION:.' EMPLOYEE MUST WEAR SPLASH -PROOF OR DUST- RESISTANT. SAFETY,000OLES FACESHIELD TO PREVENT CONTACT WITH THIS'SUBSTANCE.:'` EMERGENCY WASH FACILITIES: .. WHERE THERE I8 ANY'P088IBILITY THAT, AN' EMPLOYEE'$, EYES. AND /OR SKIN MAY.,BE EXPOSED'TO:THIS SUBSTANCE,' THE EMPLOYER SHOULD PROVIDE AN'EYE:,WASH FOUNTAIN': AND QUICK DRENCH.SHOWER WITHIN: THE IMMEDIATE WORK AREA FOR', EMERGENCY USE, 1(7 • COPYRIGHT 1993 OCCUPATIONAL HEALTH SERVICES,. INC.. ALL RIGHTS RESERVED. CREATION DATE: 09/26/04 REVISION DATE: 12/30/92 OHS14930 PAGE 009 OF 009 • '&t,>..\22. MATERIAL A17--. 17-v DA' A te ..;. o7it: —t PSI MSDS NUMBER 52,320 -2 PAGE 24 HOUR EMERGENCY ASSISTANCE 1 GENERAL MSDS ASSISTANCE BE SAFE READ OUP PPODUC:T SHELL: 713- 473 -9461 CHEMTREC: 800- 424 -9300 I SHELL: 713 -241 -4819 B ACUTE Ht.t H • F FIRE RFFCTWITv I S SECTION II -A PRODUCT /INGREDIENT NO. COMPOSITION CAS NUMBER PERCENT P SHELL DIESELINE 68334 -30 -5 100 SECTION II -8 ACUTE TOXICITY DATA NO. ACUTE ORAL LOSO ACUTE DERMAL LOSO ACUTE INHALATION LCSO P NOT AVAILABLE SECTION III HEALTH INFORMATION THE HEALTH EFFECTS NOTED BELOW ARE CCNSISTENT WITH REOUIREMENTS UNDER THE OSHA HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200). EYE CONTACT BASED ON ESSENTIALLY SIMILAR PRODUCT TESTING LIOUID IS PRACTICALLY NONIRRITATING TO THE EYES. SKIN CONTACT EASED ON ESSEENTIALLY SIMILAR PRODUCT TESTING LICUID IS PRESUMED TC BE MODERATELY IRRITATING TC Tr=! SKIN. PROLONGED OR REPEATED LICUIO CONTACT CAN RESULT IN DEFATTING AND DR'Ir:G OF THE SKIN WHICH MAY RESULT IN SEVERE IRRITATION AND DERMATITIS. MAY CAUSE MILO SKIN SENSITIZATION. RELEASE 0J•: :N0 HIGH PRESSURE USAGE MAY RESULT IN INJECTION OF DIL INTO THE SKIN CAUSING LOCAL NECROSIS. INHALATION INHALATION CF VAPORS OR MIST MAY CAUSE MILO IRRITATION TC THE I.:P =ER RESPIRATCRY TRACT. -!3H CONCENTRATIONS MAY RESULT IN CENTRAL NERVOUS SYSTEM DEPRESSIC`:. : >:HALAT :CV CF ^SIGH LEVELS CF 'AIST MAY RESULT IN CHEMICAL PNEUMONITIS. INGESTION INGESTION OF PRODUCT MAY RESULT IN VOMITING: ASPIRATION (BREATHING) CF VOMITUS INTO THE LUNGS MUST BE AVICDED AS EVEN SMALL QUANTITIES MAY RESULT IN ASPIRATION PNEUUONITIS. SIGNS ANO SYMPTOMS IRRITATION AS NOTED ABOVE. SKIN SENSITIZATION (ALLERGY) MAY BE EVIDENCED BY RASHES. ESPECIALLY HIVES. EARLY TO MODERATE CNS (CENTRAL NERVOUS SYSTEM) DEPRESSION MAY BE EVIDENCED BY GIDDINESS. PRODUCT NAME: SHELL DIESELINE MSDS 52,320 -2 PAGE 2 � ADACHE. DIZZINESS AND NAUSEA: IN EXTREME CASES, UNCONSCIOUSNESS AND DEATH MAY OCCUR. LOCAL 'ROSIS IS EVIDENCED BY DELAYED ONSET OF PAIN AND TISSUE DAMAGE A FEW HOURS FOLLOWING INJECTION•. 'IRATICN PNEUMONITIS MAY BE EVIDENCED BY COUGHING, LABORED BREATHING AND CYANOSIS (BLUISH SKIN): SEVERE CASES DEATH MAY OCCUR. ....GRAVATED MEDICAL CONDITIONS PREEXISTING SKIN AND RESPIRATORY DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT. PREEXISTING SKIN OR LUNG ALLERGIES MAY INCREASE THE CHANCE OF DEVELOPING INCREASED ALLERGY SYMPTOMS FROM EXPOSURE TO THIS PRODUCT. OTHER HEALTH EFFECTS KIDNEY DAMAGE MAY RESULT FOLLOWING ASPIRATION PNEUMONITIS. THE RESULTS OF ANIMAL BIOASSAYS ON MIDDLE DISTILLATE FUELS SHOW THAT PROLCNGED DERMAL CCNTACT PRODUCES A WEAK TO MODERATE CARCINOGENIC ACTIVITY. SEE SECTION VI FOR ADDITIONAL HEALTH INFORMATION. SECTION IV OCCUPATIONAL EXPOSURE LIMITS OSHA ACGIH OTHER NO. PEL/TWA PEL /CEILING TLV /TWA TLV /STEL • P • NO OSHA PEL OR ACGIH TLV HAS BEEN ESTABLISHED. SECTION V EMERGENCY ANO FIRST AID PROCEDURES EYE CONTACT FLUSH EYES WITH WATER. IF IRRITATION OCCURS, GET MEDICAL ATTENTION. CONTACT )VE CONTAMINATED CLOTHING /SHOES AND WIPE EXCESS FROM SKIN. FLUSH SKIN WITH WATER. FOLLOW BY rIING WITH SOAP AND WATER. IF IRRITATION OCCURS, GET MEDICAL ATTENTION. DO NOT REUSE CLOTHING UNTIL CLEANED. IF MATERIAL I5 INJECTED UNDER THE SKIN, GET MEDICAL ATTENTION PROMPTLY TO PREVENT SERIOUS DAMAGE; DO NOT WAIT FOR SYMPTOMS 70 DEVELOP. INHALATION REMOVE VICTIM TO FRESH AIR AND PROVIDE OXYGEN IF BREATHING I5 DIFFICULT. GET MEDICAL ATTENTION. INGESTION DO NOT INDUCE VOMITING. IF VOMITING OCCURS SPONTANEOUSLY, KEEP HEAD BELOW HIPS TO PREVENT ASPIRATION OF LIQUID INTO THE LUNGS. GET MEDICAL ATTENTION. NOTE TO PHYSICIAN IF MORE THAN 2.0 ML PER KG HAS BEEN INGESTED AND VOMITING HAS NOT OCCURRED. EMESIS SHOULD BE INDUCED WITH SUPERVISION. KEEP VICTIM'S HEAD BELOW HIPS TO PREVENT ASPIRATION. IF SYMPTOMS SUCH AS LOSS OF GAG REFLEX, CONVULSIONS OR UNCONSCIOUSNESS OCCUR BEFORE EMESIS. GASTRIC LAVAGE USING A CUFFED ENDOTRACHEAL TUBE SHOULD BE CONSIDERED. SECTION VI SUPPLEMENTAL INFORMATION REPEATED DERMAL APPLICATION OF HIGH LEVELS OF MIDDLE DISTILLATE FUELS IN EXPERIMENTAL ANIMALS HAS PRODUCED EXTREMELY SEVERE IRRITATION TO CORROSIVE ACTION ON THE SKIN. VARYING DEGREES OF LIVER AND <IDNEY DAMAGE WERE NOTED IN THESE STUDIES. INCLUDING CONGESTION. ENLARGEMENT. MOTTLING, AND NULTIFOCAL NECROSIS. WIDDLE DISTILLATE FUELS HAVE BEEN DEMONSTRATED TO CAUSE CHROMOSOME DAMAGE IN THE IN VIVO RAT BONE HARROW CYTOGENETICS ASSAY, ANO MUTAGENIC IN THE L5178Y MOUSE LYMPHOMA ASSAY. PRODUCT NAME: SHELL DIESELINE MSDS E2.320-2 PAGE 3 SECTION VII PHYSICAL DATA BOILING POINT! 325 (DEG F) • MELTING POINT: NOT AVAILABLE (DEG F) SPECIFIC GRAVITY: 0.8762 VAPCR PRESSURE: NOT AVAILABLE (H20.1) I MM HG) _ • SOLUBILITY: NEGLIGIBLE VAPOR DENSITY: >1 (IN WATER) (AIR ■1) EVAPORATION RATE (N -BUTYL ACETATE • 1): NOT AVAILABLE • APPEARANCE AND 000R: YELLOW LIQUID: STRCNG HYDROCARBON ODOR. SECTION VIII FIRE AND EXPLOSION HAZARDS FLASH POINT AND METHOD: FLAMMABLE LIMITS /14 VOLUME IN AIR 130 DEG F (PMCC) MIN. ' LOWER: N /AV UPPER: N /AV EXTINGUISHING MEDIA USE WATER FOG, -FOAM. DRY CHEMICAL OR CO2. CO NOT USE A DIRECT STREAM CF WATER. PRODUCT WILL FLC:.T AND CAN BE REIGNITED ON SURFACE OF WATER. SPECIAL FIRE FIGHTING PROCEDURES AND PRECAUTIONS CAUTION. COMBUSTIBLE. DO NOT ENTER CONFINED FIRE SPACE WITHOUT FULL BUNKER GEAR (HELMET WITH FACE SHIELD. BUNKER COATS. GLOVES AND RUBBER BOOTS). INCLUDING A POSITIVE PRESSURE NIOSH APPROVED SELF- CCNTAINTED BREATHING APPARATUS, CCOL FIRE EXPOSED CONTAINERS WITH WATER. IN THE CASE OF LARGE FIRES.. ALSO COOL SURROUNDING EQUIPMENT AND STRUCTURES WITH WATER. UNUSUAL FIRE AND EXPLOSION HAZARDS CONTAINERS EXPOSED TO INTENSE HEAT FROM FIRES SHOULD BE COOLED WITH WATER TO PREVENT VAPOR PRESSURE BUILDUP WHICH COULD RESULT IN CONTAINER RUPTURE. CONTAINER AREAS EXPOSED TO DIRECT FLAME CONTACT SHOULD BE COOLED WITH LARGE QUANTITIES OF WATER AS NEEDED TO PREVENT WEAKENING OF CONTAINER STRUCTURE. SECTION IX REACTIVITY STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR CONDITIONS AND MATERIALS TO AVOID: AVOID HEAT. FLAME AND CONTACT WITH STRONG OXIDIZING AGENTS. HAZARDOUS DECOMPOSITION PRODUCTS THERMAL DECOMPOSITION PRODUCTS ARE HIGHLY DEPENDENT ON THE COMBUSTION CONDITIONS. A COMPLEX MIXTURE OF AIRBORNE SOLID. LIQUID. PARTICULATES AND GASES WILL EVOLVE WHEN THIS MATERIAL UNDERGOES PYROLYSIS OR COMBUSTION. CARBON MONOXIDE AND OTHER UNIDENTIFIED ORGANIC COMPOUNDS MAY BE FORMED UPON COMBUSTION. SECTION X EMPLOYEE PROTECTION RESPIRATORY PROTECTION USE A NIOSH- APPROVED RESPIRATOR AS REQUIRED TO PREVENT OVEREXPOSURE. IN ACCORD WITH 29 CFR 1910.13. USE EITHER A FULL-FACE. ATMOSFHERE-SUPPLYING RESPIRATOR OR AN AIR - PURIFYING RESPIRATOR FOR ORGANIC VAPORS, PROTECTIVE CLOTHING • NO SPECIAL EYE PROTECTION IS ROUTINELY NECESSARY, AVOID PROLONGED OR REPEATED CONTACT WITH SKIN. WEAR CHEMICAL RESISTANT GLOVES AND OTHER CLOTHING AS REQUIRED TO MINIMIZE CONTACT. PRODUCT NAME. SHELL DIESELINE ADDITIONAL PRO- ECTIVE MEASURES • 'SE EAPLOSION -)ROOF VENTILATION AS REQUIRED TO CONTROL VAPOR CONCENTRATIONS. SECTION XI MSDS 52,320 -2 PAGE 4 • ENVIRONMENTAL PROTECTION SPILL OR LEAK MOCEDURES CAUTION. COMB ;STIBLE. ••• LARGE SPILLS ••• ELIMINATE POTENTIAL SOURCES OF IGNITION. WEAR APPROPRIATE RFt'IRATOR AND OTHER PROTECTIVE CLOTHING. SHUT OFF SOURCE OF LEAK ONLY IF SAFE TO 00 W. DIVE ANO •,NTAIN. REMOVE WITH VACUUM TRUCKS OR PUMP TO STORAGE /SALVAGE VESSELS. SOAK UP RESIDUE 11TH +.ABSORBENT SUCH AS CLAY. SAND. OR OTHER SUITABLE MATERIAL: PLACE IN NON- LEAKING CONTAINERS ANO ;£AL TIGHTLY FOR PROPER DISPOSAL. FLUSH AREA WITH WATER TO REMOVE TRACE RESIDUE: DISPOSE ',F FLU; -$ SOLUTION AS ABOVE. ••• SMALL SPILLS ••• TAKE UP WITH AN ABSORBENT MATERIAL AND PLACE IN NON - LEAKING CONTAINERS FOR PROPER DISPOSAL. WASTE DISPOSAL UNDER EPA - RCFA (40 CFR 261.21): IF THIS PRODUCT BECOMES A WASTE MATERIAL. IT WOULD BE IGNITABLE HAZAROOU; WASTt PROPER 01;P05Ai HAZARDOUS WASTE NUMBER 0001. REFER TO LATEST EPA OR STATE REGULATIONS REGARDING ENVIRONMENTAL PAzAROS UNDER FPA -CWA, •-'IS PRODUCT IS CLASSIFIED AS AN OIL UNDER SECTION 311. SPILLS INTO OR LEADING TO SURFACE WATERS •..AT CAUSE A SHEEN MUST EE REPORTED TO THE NATIONAL RESPONSE CENTER. 800 -424 -8802. • SECTION XII SPECIAL PRECAUTIONS KEEP LIQUID AND /APOR AWAY FROM HEAT, SPARKS AND FLAME. SURFACES THAT ARE SUFFICIENTLY HOT MAY IGNITE EVEN L10UT0 PRODUCT IN THE ABSENCE OF SPARKS OR FLAME. EXTINGUISH PILOT LIGHTS. CIGARETTES AND TURN OFF OT. ;.R SOURCES OF IGNITION PRIOR TO USE ANO UNTIL ALL VAPORS ARE GONE. VAPORS MAY - CUMULATE AND t"AVEL TO IGNITION SOURCES DISTANT FROM THE HANDLING SITE: FLASH -FIRE CAN RESULT. EP CONTAINERS ".LOSED WHEN NOT IN USE. USE (ONLY) WITH ADEQUATE VENTILATION. CONTAINERS. EVEN HOSE THAT HAVE PEEN EMPTIED. CAN CONTAIN EXPLOSIVE VAPORS. DO NOT CUT. DRILL. GRIND, WELD OR ZRFORM SIMILAR OPERATIONS ON OR NEAR CONTAINERS. WASH WITH SOAP AND WATER BEFORE EATING, .'INKING, SM0KIti, OR USING TOILET, FACILITIES. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE..'. • • SECTION XIII TRANSPORTATION REQUIREMENTS '. • DEPARTMENT OF TRANSPORTATION CLASSIFICATION: COMBUSTIBLE LIQUID 0.0.7. PROPER SHIPPING NAME: FUEL OIL. NA 1993 +---- •-- - - -_ -- - - Y--- -- - --- - ---- --- '---- __-------- - -- - -- SECTION XIV OTHER REGULATORY CONTROLS THIS PRODUCT IS LISTED ON THE EPA /TSCA INVENTORY OF CHEMICAL SUBSTANCES. THE INFORMATION CONTAINED HEREIN IS EASED ON THE DATA AVAILABLE TO US AND IS EELIEVED TO BE CORRECT. HOWEVER, SHELL, MAKES NO WARRANTY, EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA OR THE RESULTS TO BE.OSTAINEDFROM THE USE THEREOF. SHELL ASSUMES NO RESPONSIBILITY FOR INJURY. FROM THE USE OF THE PRODUCT DESCRIBED HEREIN. DATE PREPARED:OCTOBER 16, 1985 BE SAFE READ OUR PRODUCT SAFETYINFORMATION ..,AND PASS IT ON (PRODUCT LIABILITY LAW REQUIRES. IT ). SHELL OIL COMPANY PRODUCT SAFETY AND COMPLIANCE P. 0. 80X 4320' HOUSTON, TX 77210 • _ • . — — -•vi. 6.• • V II , ai:• 1 W , C•g4.1 C•OL 1i Midland Resources, Inc. 105 W. 11th, Suits A Lawrence, Ks. 88044 (913) 842.7424 EMERGENCY TELEPHONE NUMBER (913) 842.7424 (314) 241.7095 REVISED 12/1186 MATERIAL SAFETY DATA SHEET SECTION I— INFORMATION PRODUCT NAME: Fer Ei 'ri .= • - "A• e /.ii:..7 SECTION II— HAZARDOUS INGREDIENTS INGREDIENT C.A.S.# % BY VOL (optional) FeC La 7705 -08-0 40 SECTION III PHYSICAL DATA BOILING POINT(F °) 250 SPECIFIC GRAVITY(H20 =1) 1.2-1.48 VAPOR PRESSURE(mm Hg.) N/A MELTING POINT N/A VAPOR DENSITY(AIR =1) N/A EVAPORATION RATE(Butyl Acetate= 1) N/A SOLUBILITY IN WATER Soluble tiPPEARANCE AND ODOR: Reddish brown solution, no odor SECTION IV —FIRE & EXPLOSION HAZARD DATA FLASH POINT (METHOD USED): None FLAMMABLE LIMITS: EXTINGUISHING MEDIA: None SPECIAL FIRE FIGHTING PROCEDURE When heated in a fire may produce HCI gas. UNUSUAL FIRE AND EXPLOSION HAZARDS: None Non-Flammable SECTION V— REACTIVITY DATA STABILITY: UNSTABLE STABLE_ X INCOMPATABILITY(MATERIALS TO AVOID) Do not put in direct contact with metal HAZARDOUS DECOMPOSITION BYPRODUCTS None HAZARDOUS POLYMERZATION: MAY OCCUR WILL NOT OCCUR X SECTION VI— HEALTH HAZARD DATA HEALTH HAZARDS: Consult a physician or hospital. Will irritate eyes, mouth and throat. SIGNS AND SYMPTONS OF EXPOSURE Consult a physician or hospital. May cause nausea. vomiting, short- ness of breath, albuminuria and hematuria when swallowed. MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE Consult your physician. •MERGENCY AND FIRST AID PROCEDURES: Consult a physician or hospital. Stomach wash if swallowed, followed by saline catharsis and cenodyne: flush eyes and skin with plenty of water. oct• i Rum V il—rretiAU tI IUNb I-UH SAFE HANDLING AND USE STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Neutralize with Soda Ash or Lime, mix with sand and put Into EPA approved drums. To dispose of drums follow regulations established by local, Sta- and EPA. WASTE DISPOSAL METHOD: Neutralize and landfill In accordance with local, State and EPA regulations. PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Avoid damage to container. Ferric Chloride is highly corrosive to bare metal. Storage tanks or containers should be rubber Tined or con - structed from polyolefin or fiberglass, metal drums used for storing must have a polyolefin insert. SECTION VIII - CONTROL MEASURES RESPIRATORY PROTECTION (SPECIFIC TYPE) None VENTILATION LOCAL EXHAUST: None PROTECTIVE GLOVES: Rubber EYE PROTECTION: Safety glasses or face shield OTHER PROTECTIVE EQUIPMENT: Rubber apron and boots WORK/HYGIENIC PRACTICES: Wash gloves, clothing and equipment after completing work. EMERGENCY PHONE NUMBER (913) 842.7424 (314) 241.7095 e0 0 w °c O 3 w ` u u 7 @ O d '0 u ai ti p G 0 e _ P. O $ O " b. 8 a t2 v e E w E. ° 4 t. o ° = y 8 .a Y 7, = c a s E.= " i �` =u .� 13= t.o =O =g Ut z 0 G O o Solubility. Very soluble in water. z 0 FERRIC SULFATE v v b 2-1 41 ° w ° e Q l'iT e ra V ~ I. it mkiiglA l e g s -al z O r , g .. .� }}y�j^ e g rem ih�.4 _ rVT�i I I! i v2 .ne''' 8 c-g Hi "tql:8 t; wneestre 4911.6.241 "ii ii iii3 .2 1 u; �'U13. 1�i (EL kin thW w�_ v�3 w� v G O g g.g at 1 H C FRS FERROUS SULFATE 12.17 SATURATED LIQUID DENSITY 12.16 LIQUID HEAT CAPACITY 12.19 LIQUID THERMAL CONDUCTIVITY 12.20 LIQUID VISCOSITY Temperature Pounds per cubic (degrees F) loot Temperature British thermal (degrees F) unit per pound•F Temperature (degrees F) British thermal unit-inch per hour- square foot•F Temperature Cenbpoise (degrees F) N 0 T P E R T N E N_ T. 0 T P. R T E. N T N 0 E R T .. E. N T N 0 T • 12.21 SOLUBILITY IN WATER 12.22 SATURATED VAPOR PRESSURE 12.23 SATURATED VAPOR DENSITY: 12.24 IDEAL GAS HEAT CAPACITY Temperature (degrees F) Pounds per 100 pounds of water Temperature (degrees F) Pounds per square inch Temperature Pounds per cubic (degrees F) toot Temperature (degrees F) British thermal unit per pound•F,. 34 38 38 40 42 44 46 48 50 52 54 56 58 60 62 64 66 68 70 72 74 78 78 80 82 84 16,300 16,920 17,530 18.140 18,750 19.360 19,970 20.580 21.190 21.800 22,420 23.030 23.640 24.250 24.860 25.470 26.080 26.690 27,300 27.920. 28.530 29.140 29.750 30.360. 30.970 31.580. N 0 T P E R T . N E. N T 0. T I N E N ERROUS SULFATE FRS Common Synonyms ',nuvwas . ^ , 74.11 yunAln 7 ,urn • i !'nit S.,..% 4'01 es..., *n^ *Ater • • "0,0 a' '- '^ • '1 V : h4'.^1 *41.,•.1 7. a.l, a ••1'• 7'1,1 M., .-.^ ^... ,1,--.... Fire 'I:' rtammat •1 Exposure 5OLID ' 1wasowpd 00,1 Close 74.3414 vorrilllng�Or 1010 01 COnSC4U10051 SWALL(.%W Any .!1^ •1 CONSCIOUS. have 607117 Walk *4107 ^r mat a^0 1464 Vt.,. `OuC0 vOrmbng c SWALLOAEC anc vC^ 1 „NCONSCICUS OR HAVING CC'. . ILS'C'.S 90 ^,' ' • *7:601 4460 0,0710 *arm . Water Pollution ..ARMFUL 7O AOUATIC ,0 EIN VERY LOW CONCENTRATIONS Maya dangerous if 4 enters water rn0aM111. Notify local "141101 an0 0.40004 officials '•OIAy 0pera'0I6 00 nearoy *4110 Inla4„ 1. RESPONSE TO DISCHARGE 1541, R.oponw Method$ Handb00k) ;saute 04: •'.4110 2. LABEL 2.1 Category: NOM 2.2 Claes: N01 penlnenl 3. CHEMICAL DESIGNATIONS 2.1 CG Compote41y Cosa: Not Lsied 3.2 Formula: x.50, 7'+,0 3.3 IMO /UN D.1179n0t041: N01 079700 2.4 DOT ID No. 9'25 3.5 CAS Registry NO 7720.704 4. OBSERVABLE CHARACTERISTICS , 4.1 Physical SUM 4a6 *hipped): 5014 4.2 Cohn Green 4,3 Odor. Odorless 5. HEALTH HAZARDS 5,1 PeraOnal Protective Equipment Mast 0 oust is prow* 5.2 SYmptome F040wktg Exposure: INGES "I'J' abdominal rim, 701Cnm9, diarrhea dew/oration. 8-004, 01, '. :ralW$9, rape 0, w0as parse pillow tesorslron. low blood caesur.. 5.2 Tnumenl 00 Eaposure: INGEST:ON gne ^vos vnrnerestaty and then induce worming to strokng "^e pharynx 1077 a blunt o01Kt 1600 as a 18700'I handle. Gaslr'c ravage wile 1 putt 01 5% •93•0,11 4644" CO mood. 36 0000+3* p7.OSO011e d aomp7ly aveou , 01hMws, u14 *0160. 061 medCa 4710144 5.4 Thraulold Limit Value; Not Patient 6.6 Short Term 01310tton Limits: Not pennenl 5.6 Toeltlty by Inges0On: Grace 2 LI.v .. 05 t9 : 4, kg Iran 5.7 Late Toxicity: Teats not 100,labe 6.6 Vapor (Oar) Irritant Characteristics: Not pMn'.nl 5.9 Liquid or Solid Imian1 Characteristics: No'. 6.10 0607 Threatgb: Not pertinent 6 01 001.04 Value: '1'.1 Not Ava4A0f 169 -14" L1. - 86 .. J41 . Q1, 3 JUNE 1985 6 fIRC HAZARDS 10 HAZARD AS5(554E44 F 000E 6 7 Flesh 0040* 'N1 '4m^'afee 'S,0 Harlon Aawsamsnl lentib0ual 6 2 Fla*0a0l• Limns In Air •rN r' Irne.4700 SS 3 7 rue Extinguishing Agnate 'I 1' 1.1•17.1,1”1 6 4 riff EFbn5ule0740g Agents Not to 04 Used: Not IN"Irnn ^I 6 S 5P•CIa1 Harare, of Combustion II. HAZARD CLASSIFICATIONS Products: Not pour... 6 5 behavior in Far. •100 C...•'O "' 11 ' Code of Federal Pegulahons' t ' 19ntron temperatu.,, •.7.7 ..nor ape .117.71, 6 4 0.1.47,1 40441,4' NC. 74. ^r ^: 11 2 NAS Hassid Paling for bolt Wale, 6 9 Outnm9 Rate: Not 1.6.777-6107 Transportation "ICt !M1lnf 6 t2 Adiabatic Flame Temperature I1 2 NFPA Horan" Classthtstlon. ''.1t4 Not 1001,10070 'In1 l.yeq t 17 Stoicnromelric Air to Firm Ratio: Cola Not AWAnow t 12 Flame Tempenlui. 0,:a 4o, A.b4bl1 7. CHEMICAL REACTIVITY 7.7 Reactivity With Wrier. Ho nIC:dn 7.2 Reactivity watt Common 7440,01.0,: 40 1,0C1on 7.3 Stability During Transport: S'aD40 7.4 N0u0raltaing Agents for Acids and Caustics: Not p0n:neet 7.5 Polymenaallon: 1401 pe'tna^I 7.6 Inm011°, of Polyme1laabon: Not remnant 7.7 Molar Ratio IR,actanl to Product): Cala Not A•a•6044 7 6 Reactivity Group: Data Not A rm:able 12. PHYSICAL AND CHEMICAL PROPERTIES 12.0 Phyrtal blaze at 15'C and 1 atm: Sdd . 122 Molecular Weight 16996 13.3 Dotting ROM el 1 40rn: Not pertinent 12.4 Framing Poe* Nol pertinent 12.5 Cn110a1 7mye4310, ; Nol remnant S. WATER POLLUTION 12.6 Coble, 0,4aetan Not penman 12.7 304141.04 Greatly; 5,1 Aquatic Toxicity: t 90 at 15'C Hold) , 100 pan.'4 2 hr/bass 'WINO/ bash wale 104 Liquid SUrfaa Tension: Not pertinent .12.9 LIquld Water Interfacial Tension: 06 00m149 hrryri PILC,.1wn miler . Not pert 901 6.2 Waterfowl TOakhy: 010.1 Hal 1Y441bie 12.10 Vapor IOM) kook Oravltyt 6.2 6blogkal Oxygen D,mwid (OODP Not pertinent • Data not avaeaW$ 12.11 Ratio of Specific Hems of Vapor (oast: 610 Food Clam Coneentratlon Not Wawa None 12.12 ata n Heat of VOpa4at10n: Not peronenl 12.13 Heat of CaMIwUOn: Nol Immenl 12.14 Heal of Decomposition: Not ponlrmnt 12.16 H aat 00 50110100 Not pendent 12.14 toot 01 PoiymIohalblt Not pennant 12.26 Heat 01 Fuel= Data Not Avertable • 12.26 Umiting YAW: Data Not Ava41W, 12.27 MAO Vapor 0,0wlire: Data Not Avariaoe 9. SHIPPING INFORMATION 9.1 0144,0 01 Panty; USP. Celnnwwl ,. 5.2 $torage Tempsratura; An'oenl 1.2 Mat Atmwplurr. No 70ouremen7 3.4 V.n1M9: Open . • NOTES JUNE 1985 ,,-...-....... The Clorox Company 7200 Johnson Drive Material Safety Pleasanton. California 94566 Data Sheet �� Tel. (415) 647.6100 CLOROX-HMIS HEAUB 1- FLAMMABILITY 0 P RUMP Pauli Practice 1 Chemical Identification NAME: FORMULA 409 ALL PURPOSE CLEANER CAS no. N/A DESCRIPTION: GREEN LIQUID RTECS no. N/A Other Designations Manufacturer Emer- ency Procedure Formula 409 The Clorox Company 1221 Broadway Oakland, CA 94612 Notify your Supervisor Call your local poison control center or Rocky Mountain Poison Center (303) 573 -1014 II Health Hazard Data III Hazardous ingredients Mild eye irritant. Overexposure to this product may cause the Worker Exposure Limit of ethyLsro glycol monobutyl ether to be exceeded. Reports have associated blood and bona marrow damage with exposure to ethylene glycol monobutyl ether. No medical conditions are known to be aggravated by exposure to this product. Under normal consumer use conditions the likelihood of any adverse health effects are Low. FIRST AID: EYE CONTACT: Flush oyes with plenty of water. Ingredient Concentration Worker Exposure Limit Ethylene Glycol 0.5 -57. 25 ppm TLV -T-A Monobutyl Ether CAS 0 111 -76 -2 25 ppm, PEL Substance can be absorbed through the skin and may contribute to overall exposure. None of the ingredients in this product are on the IARC. OSHA or NTP carcinogen Lists. TLV -TWA+ Threshold Limit Value - Time Weighted Average. Source: ACGIH 1985 -86. PEI., Permissible Exposure Limit. Source: OSHA, SKIN CONTACT: Wash with water. INGESTION: Not an apparent hazard. INHALATION: Not an apparent hazard. IV Special Protection Information V Special Precautions Hygienic Practices: Wear safety glasses. With repeated or Not recommended for use on soft vinyl, varnishes or aluminum. If sprayed on these surfaces. rinse and wipe dry immediately. prolonged use, wear gloves. Engineering Controls: Use general ventilation to minimize exposure to vapor or mist. Work Practices: Minimize akin contact and inhalation of vapor or mist. VI Spill or Leak Procedures VII Reactivity Data Small quantities of lass than 5 gallons may be flushed down the drain. For larger quantities wipe up with an absorbent material or mop and dispose of in accordance with local. state and federal regulations. 1 Stable under normal use and storage conditions. VIII Fire and Explosion Data IX Physical Data Not flammable or explosive. Extinguishing media dater- mined by surrounding fire. pH- -• -- - -- -12.4 Solubility in water- ••• - -- complete Specific Gravity (1120+1)- .• ------- - -- •1.015 0347m 1983 THE CLOROX COMPANY 3/90 DATE PREPARED DATA SUPPLIED IS FOR USE ONLY IN CONNECTION WITH OCCUPATIONAL SAFETY AND HEALTH. Shell ENVIRONMENTAL DATA SHEET 7449 19.971 EDS NUMBER d 51,270-1 PAGE 1 PRODUCT ' RU 2000(R) (REGULAR UNLEADED GASOLINE) PRODUCT CODE `02100 SECTION I PRODUCT /COMPOSITION NO. COMPONENT CAS NUMBER PERCENT P RU 2000 (REGULAR UNLEADED GASOLINE) 1 ALKENES, CYCLOALKANES. ALKENES AND AROMATIC HYOROCARBONS 2 TOLUENE 3 XYLENE 4 BENZENE 5 N- HEXANE 6 TERT -3UTYL METHYL ETHER 7 PSEUDOCUMENE (1,2,4 - TRIMETHYLBENZENE) 8 CYCLCHEXANE 9 ETHYLBENZENE 10 NAPHTHALENE MIXTURE 100 MIXTURE 108 -88 -3 . 1330 -20-7 71 -43 -2 110-54 -3 1634 -04 -4 95 -63 -3 110 -82 -7 100-41 -4 91 -20 -3 BALANCE 0 -25 0 -25 0 -5 0 -3 0 -5 0-1 0-3 0 -1 SECTION II SARA TITLE•III INFORMATION NO,' EHS RQ (LBS) EHS TPQ (LBS) SEC 313 ( -1) ( -2) ('3) P 2 3 4 6 7 8 9 10 YES YES YES YES YES YES YES YES 313 CATEGORY ( -4) 311/312 CATEGORIES ( -5) H -1, H -2, P-3 FOOTNOTES - 1 ■ REPORTABLE QUANTITY OF EXTREMELY HAZARDOUS SUBSTANCE, SEC.302 '2 = THRESHOLD PLANNING QUANTITY, EXTREMELY HAZARDOUS SUBSTANCE, SEC 302 = TOXIC CHEMICAL, SEC 313 * CATEGORY AS REQUIRED BY SEC 313 (40 CFR 372.65 C), MUST BE USED ON TOXIC RELEASE INVENTORY FORM - HAZARD CATEGORY FOR SARA SEC. 311/312 REPORTING HEALTH H-1 • IMMEDIATE (ACUTE) HEALTH HAZARD H -2 = DELAYED (CHRONIC) HEALTH HAZARD PHYSICAL P -3 • FIRE HAZARD P -4 • SUDDEN RELEASE OF PRESSURE HAZARD P -5 • REACTIVE HAZARD - 3 -4 '5 SECTION III ENVIRONMENTAL RELEASE INFORMATION UNDER EPA -CWA, THIS PRODUCT IS CONSIDERED AN OIL UNDER SECTION 311. SPILLS INTO OR LEADING TO SURFA WATERS THAT CAUSE A SHEEN MUST BE REPORTED TO THE NATIONAL RESPONSE CENTER, 800- 424 - 8802. PRODUCT NAME: RU 2000(R) (REGULAR UNLEADED GASOLINE) EDS . ;. 51,270:1H PAGE SECTION IV RCRA INFORMATION' UNDER .EPA - RCRA (40'CFR 261.21), IF THIS PRODUCT BECOMES A.WASTE MATERIAL.• IT WOULD BE AN..IGNITABLE •'ZARDOUS WASTE, HAZARDOUSWASTE.NUMBER 000 1, .REFER. TO LATEST EPA OR STATE REGULATIONS REGARDING PR LSPOSAL. THE "INFORMATION CONTAINED HEREIN IS BASED ,ON THE DATA AVAILABLE TO, US AND IS BELIEVED TO. CORRECT. HOWEVER,'SHELL MAKES NO WARRANTY., EXPRESSED OR IMPLIED REGARDING,THE,ACCURACY OF THESE DATAOR;THE RESULTS TO BE OBTAINED FROM THE..USE THEREOF. SHELL'ASSUMES:NO RESPONSIBILITY FOR. INJURY FROM THE USE OF. THE. PRODUCT...DESCRIBED HEREIN. DATE PREPARED:MARCH 14, 1989. SHELL OIL COMPANY ENVIRONMENTAL AFFAIRS P. 0. BOX 4320 HOUSTON, TX 77210 FOR ADDITIONAL INFORMATION.ON THIS ENVIRONMENTAL DATA PLEASE CALL (713) 241 -2252 FOR EMERGENCY.ASSISTANCE PLEASE CALL SHELL (713) 473 -9491 CHEMTREC: (800) 424 -9300 , l.L -,t • • , i1AATERIAL SAFETY DATA SHEET. Radlator Spoclalty Company 1400 W. INDEPENDENCE BLVD. • CHARLOTTE, N.C. 2 20S • 704- 3774555 (IATERIAL SAFETY DATA SHEET May tae used to comply with OSHA's Hazard Communication Standard 29 CFR 1910.1200. Standard must be consulted for specific require- ments. SECTION 1 GENERAL INFORMATION U.S. DEPARTMENT OF LABOR Occupational Safety and Hearth Admtnistratidn. (Non- Mandatory Form) Form Approved OMB:No. 1218-0072 PRODUCT NAME CLASS CLEANER (PUMP) GC-2 PARTS NUMBER 7 NOTE: Blank spaces are not permitted. If any item is not applicable or no information Is available, the space must be marked to indicate that. . SECTION 11 . HAZARDOUS INGREDIENTS /IDENTITY INFORMATION COMPONENT. • WT:96 'C•A,S. NO. Inopropauol • • ' ,' .3.4 67 -63 -O ' 2- ButoxX- 1- Ethano3. " 2 -3 111 -76 -2 Comments: Components not identified are non - hazardous according to 29 CFR 1910.1200 `•cCTION W PHYSICAL./CHEMICAL CHARACTERISTICS • TLV (ACGIH XBYX ASHA - ----- -j ' 400 ppm (Alt) 25 ppm (Skin) Specific Grmvity (H20 1) 0.96 pH 9..19 Solubility in Water s ith1 p _ • Solubility in Solvent /e Flash Point (Method) - Fs _,BONE 96 Volatiles By Wt. cr-ea t.r Thrill en% Melting Point - FO NJA Bolling Point - F°..A Vapor Pressure (mmHg) _ N/A — Vapor Density (Alr =1) x/A Evaporation Rate (Butyl Acetate =1) N/A Appearance and Odor __IllUe LicuLts h Alight amincnia,ndnr_ SECTION Iii FIRE AND EXPLOSION HAZARD DATA EXTINGUISHING MEDIA: Non- 4laomiable Water Fog Foam 002 Dry Chemical SPECIAL FIRE FIGHTING PROCEDURES. Wear self- contained, positive pressure breathing appara- tus and protective clothes UNUSUAL FIRE AND EXPLOSION HAZARDS on Known. FROM :RADIATOR SPECIALTY e' %... a. • vs.. TO: SECTION V REACTIVITY DATA Stably _ Unstable • Corrosive . NO 2062516679 JAN 30, 1992 10 :54AM P.05 Hazardous Polymerization? Yes No Incompatibilities N/A Hazardous decomposition or Byproducts N/A SECTION VI HEALTH HAZARD INFORMATION Recommended TL of Product 25 ppm (Skin) 2-Butoxy-1-Ethanol ....... EYE CONTACT May.; be•. slightly irritating to pea. SKIN CONTACT Slight irritant. Prolog nag d exposure ln:t cause derma i is INHALATION Rapidly absorbed if Inhaled. • . . i • • , • . • :. m ADS - h. ,,t, • ,. . INGESTION HARMFUL IF ,SWALLOWED! ! May ... • .. - . : , - , nausea and cram. e. OTHER N/A • ' SECTION VII EMERGENCY AND FIRST AID PROCEDURES EYE CONTACT Flush with water for 15 minutes thoroughly. If adverse effects persist canta¢a a phvel.cien. SKIN CONTACT Wash with soap and water. Remove contaminated clothing and was .e ore re -use. INHALATION Move to fresh air. INGESTION Drink 2 Blouses of water. INI)UCK VOMITING!! Consult physician immediately SECTION VIII SPECIAL PROTECTION INFORMA CONSUMER BULK HANDLING (Prolonged Exposure) RESPIRATORY PROTECTION NIA .,� i f eTL s O xceeded, wear NIOSH approved VENTILATION Use with adequate ventilation General EYE PROTECTION N/A Goggles PROTECTIVE N/A CLOTHING Rubber gloves and apron. • SECTION IX PRECAUTIONS FOR SAFE HANDLIN SPILL C UB cagayJR m ens P 1mrdhtl ansier g8Bweiteddigomve, ventilate area WASTE DISPOSAL METHOD dispose of In accordance with all applicable government Sawa and regulations, STORAGE AND HANDLING PRECAUTIONS Store away froth.' oicic)it ing agents. OTHER PRECAUTIONS/ ammo CONTACT LJ NSrs TS INADVISABLE.. • x . ' • I ' t O► '4 , :..:. HAZARD INFORMATION LABEL DAl A HAZARD CODE" 4•Extreme 3410 2%Mod•nt• r -mbN limn. MACuvrv ,n•uw Supersedes RQpa• ember., 1986 OSHA Revleead April. 1987 Title I. Liebman Technical Director While Radiator Specialty Company believes this data Is accurate as of Cher vsIondate, w emektono warranty with respect toOxidate and we expr ulydlaolaim.n liability for reliance thereon. The data is offered solely for your Information, investigation, and verification. u J W .0 1-.w az OZ x N . O Ow W O oz ZW ■ lo 00 Uw WO Y S0 .00 0O= uz i M N =2 w 4 0 40101 .4 4 4 PHYSICAL DATA U r W 01 U J . 0 N 4 4 LL O A J 01 1 ii W > h v el • o a •. 00 c7 ¢ 1-• w ' N Z . r N 1- J W 4 W CC. W Z a' R w O 0 J . O. .m 0 0 Q 7 ' O U > J 0 J 0 N N 2-. N h W LL J' 0 R' Cr 10 W O M .• 0 0 . 3 U .. .. 2 Z z. 4 PI 0 o u i• . w 1 .a U - a u .- .1 C.X. wa m U J U 7 N W J W o a 0 O m 0 0' VAPOR DENSITY: 3.0 _ N (0 v M. MO 14-• M M 4 .1 0 .1 O 0 1-2 LL 4U N ;8 • M 4 R 8 0z 82 • "OW .1 W072 hN OW 1- 'WI t.4 1a -LL M. . 1 -1-NWO W4WN 00 W40. ' m 1- R 1• NV a3."•.I..J.. 1- 3 m r2 0200•'.. 124 ZWWW7 W0 'WY. 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OC V! ,� C u Y • .41 4 4 W 4 u) 0 0 W Reportable Quantity (RQ)(CNA /CERCIA) : 5000 lbs. state and federal regulations. ■ J 0 L 4 i Ensure compliance Control Heasurei Qccuoationat O O ■ M r 9 4 Y • y C. • O u • C• C .. C u • O* ._.. u ..a • 0 • . . r .. 4 .09 .4 0.dtl 4141 U 4 .40. O. 41 •• Mr . 4 • u • 7 U 0• .. 3 41441 u • 7 i• u •441 • 0 • 4941 0 •0 >• 4140 UL we 7 1. 0 11 • •r.. •0. 0•• • 0 O a0Y 4.•C 0•41.0 44> .41 410YC CV•0 L40ur 0.04 • . u 0.441y 74. V • 4.r > 4 -. C 9 X 4 0 C 41 C 41 C 7 • * 0 0. • • • • W 0404104 • 0 C)M C 0 V 0 Cr 41 •• 9 >.• 4 S9 U •O• r C 0 w. •• 9 •1 C •r • 4 • Y U •4 O O 411 .4r W • C.110.04 0 0 4. ) . O • 1. Ji D. •. 14.4141. u 0..0•• 41 • 41e .0 ✓ 40.40•••• C • U. • .4 • 4 y U 41 a/ .4 414.0 09 M 0.•! 1010.1a 4 .0 • 0.• \u • 0• • H •.4 • 0 NO Y. • 41 4. 0.r A • 4 0 9 41 41 v 4<..0.0 •4141 0774• r 0. O, 41 0 • 9 •.+00 ) •O•• 9 •M •U. C J • • ••Y41Oral .4 3 0. C • •.0 • O . y. C.' 0 7 • 4 741 • • • a 41 • r • 0 0. 41 0 w A y 0 0 0 04. 4 4. C. 1. • u C.C> C• a. 0 4141• .•AL . 7 >. 44)041• • ■ WM•41.0 •00 40.41 • • 0 0. 4 .9 • • • 4 > 0 • 40 •.4.l Y O • •r Y.•I 0. • 4 9■ ••• . 00 O.0 7 0 •) C 0. Ime L • • 0 • ... • • CI, A• C 400 0 X Q XA .44 •••• 9 40.4 C 4••7 0. H O W 40.440 Y 41• 4.0 41 0LY•. 7 >. C w C..1 C 041414101.41 .4 • 014 um... •.. . .. • 41 0 4 41 4 U• he C. 0 4.4 .G ▪ .•9.4 0•4141744141 . a >. . 4 o .0. r.4 u 7 > 0 4 7 • •. 0.41 • • 4 0 • • SO • . 440. 0 0 41004111 0. 41 41 0. 4 • in C) ) 411JL4 .4 041• )CY 014> 44 00. • • 0. 0 0 r . • •.1 A• O 11. 4 .. L C •• ▪ Y... w • 7 4144 9 id* .0 41 G. • • . • >. • 1< 1. 4 O•• N. • • > 4. 4 ......31 •.0 • 4 41>471 y. 4 .9 .4 • •94 0 • 404 • Y 1. 1•. v • • 0 41 • • C • I. •0.0 • 41 0 0• O../_ &&&&& 0 C Y O ro 4. • 4 • V a C -4 41 0. • Y•• r 0.4 14 4 ..•••• U L .. • 4 441....41 440.70 4041 •••• 4 • •. •. Z0 0. ••.4 • • O 0 • 41 0 41 0 41 . .0 ..9 4 V .. • C) v10.AJ O. N 0.uu 0.YUU4 4 tool O < • 0 11 •L O V • 41 0.. 4• • 0 C Y 0 •L • a s •vt v1 441414 4419139 u41Mr4 CC•CU 0 ).0 2. Exposure Limits: usut L!ulib Eflttll 0 Q 4 Y O . ... • •9 N ... > C mw o Y 0. u 4 O r a J 00 O. or 3 �� Skin Protection: Eye Protection: • • • • 0 be • •. • 0 • 0 • 4. 4 0 • • • 9 • ~ C • • • Y 4 41 . a• • > r 0 •• • 4 9 C • r C . 4 O 41 • A 0 0 41 7 w• r. a •00•.0+ a 4 Y y 14 0 • 040 ••41. OlrWp C • • • >Y O r ▪ 0 O 10 • 041 004.4 0K• U Y O41 41 .. V • • C V N N i• 41 U • C.4 ••• 41410-.. • • r 0 • ••. .• C 0. M 4 C 41 • L700 .4.0.0=14 • • . 0 49 u 00..•r>t00 • 4 • • .040 ) 0410.1.041 9 i. •94.414 4 Cu u la 41 00 r • w 4,•• •y 0x -� -.. I. 44.. • 0.0.41 0 a U tJW• .4 • • .044 Y • • OW 14 41 0 • 0 0 40. U 1.. 4. p.*' 4 0 41 • . C C 9• • Ca N a • •C • •Y.40OMN4WZ• C Y • • . C I) ) 41 4 7 14 0. = U• • U• • C u • F< • r• 410.0 • 440V•+C..Z F•7191 4147 • V•Y 0•.41400. 0 0.• 4. L.:.C4 400300 49 • Y Vr QC... h•• • • 9 • 4 • .. • 0 < 0 • 941* 41 Y41Orr 0=47110 10 /4491 • 0.0 • 41 0•• 9 1 010041 0.41 • • C 9 YOA400200• 0 ▪ 44 • 410 • >r 40. .*WO• • • O *,C• u C 411041 WO.y 4.• U 0 V 4.41 C4/970 1444 4 9 0 • 41 0 • 11 a0 M.4 >. W =• X441- •w0u .490114•+4 ~4 a•• •41••000 1..1 =0• 400 a • 4C••1492r 1.0 . 4 0. 41 u C W a W • •• •4 a 4 u i Y N< 0 OC • ). 0 0.090 •••4. <04 C.0 • • w 4. • • Y 40 2 • .0.41 •C44141 9•A0. <W2• • • r 0 4 U C 0 C W =Ca r • 0. 1. • 0 41 Y Y 0.• C l: Z W• 4. 0 0 • 0 00.0.0 =.4:441 V 4 • • .0 • S I X 41171•4044•C W o >i•.•. • 1..000V 0.02=2211 09 •441.44.0 IV • • C U 0 4 0... •0 4. • • .. 0uN • •Lw• .r2 • 4.4• .40 •.740.•40010 • 094.+•44 214-40• 4 14 0 41. 41.01. W• • 4 71111•0 W • •9404 •L0.00L240. O 7 N .4 • • 4 0 A • • .• 9 Y ..41 y 41 41 0 Y 460 y: ▪ • • ▪ A 4 N . V a.0 Y W 7 PI 7 0. A' C O 07• 7 4 • 7 YV O•VO >.0 4# 410 U QU 4 '......0 . y U 41 0 >. Y r 41 U • le • O O • _uw CU 'N V• 403, V7 U7 Q9 4u > w .L 0 ] 0 41 • 414 O y 4.. C • 0 • •r 41 • u. a M4 .0 a4. w �p IS Cu • 00 ...0 Jt▪ v Vr ^C • 7• . '41 q9 4• 00.x. 4 • 41• 0.CV • 4 0 0.0 • 0. Y • U4 U- • • • •OU 94 r ' C 74.41 .0 ... M• 0 1 C u 11 •• u •• C• >•• MU, 4. 7 0. C• in .0 3 0 • U • V• 41 00 0 .41 0 • 0 9 7 0 Nr.' ...... Y •.. .. ) . 4. U N• 01 6 0 Y 41 • 4 V C• V O Y w • w 40 •• W Y O O _ • • 0. O • II 4494 4> U a •4 W y o r.".•... • • w • Y.4 tool ..Ai Y • • 90 •'.+R Y 41 • • V L L9 4009 •M 49 ■ Y O w .• 4 N to. 41 • Y a 0 4 41 p w 11 4% v C L O.4 Y r > 2 4. 0 .. 41 1. 41 . A 41 4• X0.0 C� >) • • C 41 41 17174.; 41 t 100 7 4• C Yr Q 1041 ) >•.4 0.4 L 44.9 YO .a O41Y w 1.. 41 41241 8h C C . I4. Ya 0 . 4• 0 C C• y.. 4. y 41 6 4.. 0•e O Y Y yC CL OV 119 11L• 4100 - •0 2.O .1CY■ 00. 1 u.o0. • ]941• ru as• Y0. YS �v Fr• •A.4. . 417. eRU .• Oi•a40 414 00.0 4 0 •J7 • '•• U...u.0 .V9C R 1 • 4041 u ON9 .7.l .li > 0.7 „� 1 ;y0. 0 44 4. W..O. 0.041 .: ^4 R.C. •. CC • 0. 04. • 41 ] Ju 4441 • Y CLY• 0 V .V4. W>7 0 • 4100 040 :. Y .. 0.a 0 u 0 • > V Y 0. 4 1. 41 11 w C• > >. 0. 0 41 ) ) 4 44 0 40/..+43 YU Y >..l O ... 2.404 W 41414141 04 4• 410• ,•p. . 0 I. 4041 VCV •QC 41414 •2•. ^00 0441 • ~• Yr• • • C.. Nola• N NY0 410• CY• 114• v..Ur 4141• •• 4100• 0 ••� Oro�.Y oho US• .0 Odu )-. 2l�Y U0041 +•u• iU.V. 4. Y O. 4 1. 0. • 0 • I. C u 41• 40 0 41 M • O 0.r . 4. O N Y 1y5• 0 7 Y y M Y y Q 0 4 41 0. 10• 0 7. 0 0• O 4 O V• y 4. • • 0 1.0 ■. 0 41 0 V Y • .... 9• U u4 U.VC 44.0 9 11410. ,.:011 41.•4 401U 00•. -0414■ > I 41 kin Conte 4 y G H • wV O io 41 u 0 0 C 0 0 a ' .y WI .w • 0. • . ✓ C > M 04 r N U W M 40 I' dl Y 1~41 r a W 111 1,4 >1 r 40 41 4.o • v . 0 0 0. • C Y 0 O V 9 u • u 4 0 ..0G • 0 4 9 9 b• au 0 0 • ' ' P C • • 4.' O • pN w • 0 0 MATERIAL. SAFETY DATA $MEET CaiPt to 1rrn1 WAC 7M•so4$ aNt'pIU' Ch w Uch PnoducTs p.a. - e4 6 Seattle , Vish nrtt 9M198 mainAci A 1 bls gotA,1 nedNII sealse r1o11et11MTr p1111•11AA Me COMM own • pngRtAr. tam COMM MAYO 'MRA1D1011 NUM % 1AM �� 6noini rivrrumow*out TLI ,.'g•ls�,t leas than 10 490 ac/a3 980 si /si ..�.�. .,— —v. • nedNII sealse r1o11et11MTr p1111•11AA Me COMM own % 'MRA1D1011 NUM MTV 1AM wM1tA/Ol nods per Lbw ae iatrt o 2_aitd Wefts of Ctawlcal substance■ ■ November 19494. sal CfOM In MM. nr NRiAAS 11101 LIKALATIC81 29eseive inhalation of re►Ec rL o.w. nasal irritation, diastase., INCl3T O fe Can result in•daras• to throat and •sphasus. Me effects of 1 • •ter>t e •sure far of this material on • 1- -tea halt should avoidance of all streets of repetitive • sure. e•tion. tnhalat en := arsy. LJfyf are unknown for tbps siklpre at this tt*. • . .• ter for aL 1 st 14,1ja ea. Contact • Physio1&, IIICLLSTICNI Drink large qusnititi.s of Mater. or acidlo *.wfr$ .. o , vice • o t • ►. NOT Coo0letelr soluble in water. non■vtsooua liquid. ;pin% sweat 'der, • 457 MATERIAL SAFETY DATA SHEET Complies with OSHA Hazard Communication Standard 29 CFR 1910.1200 Date of Prep: 9'4'91 • f•: c• �;: i?;(:,•;•: y:¢.r:. r.: ?;. { ? ?c. }:.}Y?:,..r ; <: ?yr +:Y<i} •rr: '.:y,;•., 'r:i, ; {..N..'.,'.;::•0 ::•`:: % ?`LS:i: :•Ill:• }i }i:• } % • }ir /. %i ri: +r %/r, .{ r�,:f,.Jr •r Y . %� { ?:> �{! ff % %fr {i.}YT'i >r• "'•':•`'vrii ' ? i" .r'r.'•i • SUNNYSIDE CORPORATION 225 CARPENTER AVENUE WHEELING, ILLINOIS 80090 EMERGENCY TELEPHONE (708) 5415700 (800) 4249300 FOR INFORMATION: (708) 5415700 SUNNYSIDE CORPORATION CHEM TREC Product Class: Trade Name: Mixed Solvents Manufacturer's Code: 457 LACQUER THINNER NPCA HMIS: Product Appearance and Odor: Clear, colorless liquid; mild solvent odor. • INGREDIENT Acetone Ethyl Acetate Isopropyl Alcohol Light Aliphatic Solvent Naphtha Toluene 2But oxyathanol 457 Health: 2 Flammability: 3 Reactivity: 0 OCCUPATIONAL EXPOSURE LIMITS ACGIH ACGIH OSHA OSHA CAS # PERCENT TLV TLV PEL PEL jTWA) (STEL) , (TWA) (STEL) 67641. 750 PPM 1000 PPM 750 PPM 1000 PPM 213 MM Hg @ 75° F 141788 400 PPM 400 PPM 86 MM Hg @ 20° C. 87830 400 PPM 500 PPM 400 PPM 500 PPM 30.0 MM Hg @ 68° F. VAPOR PRESSURE 84742898 300 PPM 300 PPM 400 PPM Approx. 60 MM Hg @ 25° C. 108883 100 PPM 150 PPM 100 PPM 150 PPM Approx. 54 MM Hg @ 25 °C. 111762 25 PPM 25 PPM 0.8 MM Hg @ 20° C (SKIN) (SKIN) (For VM &P Naphtha CAS # 8032324) ! _r f ere j{:i•'/fr:�$' {�fr{d •;',} »M''ttyvG! }ri; { > >io::'.:5:'i%y: �. ^ii} i(. �.'•�r,'Yrr:l: �} }i }.:i: i'r,'$l,••:i:: i '::!i1.':;;. ? :" INHALATION: EYE CONTACT: SKIN CONTACT: INGESTION: Using proper respiratory protection, immediately remove the affected victim from exposure. Administer artificial respiration if breathing has stopped. Keep at rest. Call for prompt medical attention. Immediately flush eyes with large amounts of water for at least 15 minutes. Got prompt medical attention. Flush with large amounts of water; use soap if available. Remove grossly contaminated clothing, including shoes, and launder before reuse. If swallowed, do not induce vomiting. Keep at rest. Get prompt medical attention. } >• } >; :..•.,`:iii:: :£:v: }} {•;'•'c•7 �ii:•'So:•. •:.i'1. {k• •xm.. }> }:{.:• r.;6 'i }:•x:::: tit:}.. The following data represent approximate or typical values. They do not constitute product specifications. Vapor Density: % Volatile By Volume: Boiling Range: Evaporation Rate: Weight Per Gallon: Solubility in Water: 133304° F. Slower than ethor 8.64 lbs. Moderate Heavier than air 100% Flammability Classification: Flash Point: Lower Explosive Limit: Extinguishing Media: Unusual Fire and Explosion Hazards Special Fire Fighting Procedures: 'r; `': •••'iii {2� # {J;:i• Flammable liquid Class IB. 0° F. (Tag.Ciosed Cup) 2.6% @ 25 °C Either allow fire to burn under controlled conditions or extinguish with alcohol type foam and dry chemical. Try to cover liquid spills with foam. Extremely flammable. Material will readily ignite at ambient temperatures. Releases vapors that form flammable mixtures at or above the flash point. Use water spray to cool fire exposed surfaces and to protect personnel. Shut off "fuel" to fire. If a leak or spill has not ignited, use water spray to disperse. the vapors. C TRADE NAME: 457 Lacquer Thinner THRESHOLD LIMIT VALUE: EFFECTS OF OVEREXPOSURE: Inhalation: Skin Contact: Eye Contact: Ingestion: Carcinogenicity: Page 2 See Section 2. Breathing high vapor concentrations may result in respiratory tract irritation, central nervous system depression, liver and kidney damage. Brain cell damage may result from longt arm vapor inhalation. Prolonged or repeated skin contact can cause drying, cracking, or irritation of the skin. Severely irritating. If not removed promptly, will injure eye tissue, which may result in permanent damage. Small amounts of the liquid aspirated into the respiratory system during ingestion, or from vomiting, may cause bronchlopneumonia or pulmonary edema. None of the solvents in this product are listed as carcinogens or potential carcinogens by the NTP, IARC, or OSHA. Studies in experimental animals with 2But oxyethanol have produced damage to the red blood cell by inhalation, skin absorption and ingestion. Toxic liver effects in male rats were also observed. !'Y4$:r: :'l::v!nk ?•:.v::.:v:: x: f /. %:.. :.::.r.•r� ?: . v :.; u;i:y fF: i'�iF:: F: jy�' Yr p: {fv::r•'i /!ri r Stability: Conditions to Avoid: Incompatibility (Materiels to Avoid): Hazardous Deoompeition Products: Hazardous Polymerization: Stable Heat, sparks, and open flame. Strong oxidizing agents like liquid chlorine or concentrated oxygen. Thermal decomposition may yield carbon monoxide. Will not occur. 5 } >S. Ej:,•.;if.+;7.i :f5•. �r..' }} { $ff':fC'r•'f>' }n:'i,$: ?si:S`::: Steps to be taken in case material is spilled or released: Remove ignition sources, evacuate area, avoid breathing vapors or contact with liquid Reoover free liquid or stop leak if possible. Dike large spills and use absorbent material for small spills. Keep spilled material out of sewers, ditches and bodies of water. Waste disposal method:, Send to a licensed reclaimer or incinerator. Dispose of In accordance with local, state and federal regulations. •S:f. { S }:4: ^::::r.: ::: }:•ii'i:r :i:f.•::b:::.: •: {::::? {4'F... ..... f ^i: ?• :::............ yWy� ................. f..: ..::....... r...... ......... ::::.: n•.. ....w:::.....................,. w:.: ::.:................... n...t.v::G::. r.n � ...{W \:...{%$�•�f!:< Swr�{�.}•r..k:::I,.k r /Jrr,:::::.: :.... Respiratory Protection: Ventilation: Protective Gloves: Eye Protection: Other Protective Equipment: Appropriate vapor canister, selfcont wined breathing apparatus or suppliedair hose mask, if needed. Sufficient, in volume and pattern, to keep workroom concentration below current applicable OSHA safety and health requirements. See Seotion 2. Use explosionpr oof equipment. No smoking. Wear resistant gloves such as nitrile rubber. Chemical Safety Goggles Impervious clothing or boots, if needed. f of { / f {/ ,; % {,<, { <:• }p,;:,:r;a :i(f}ir;} { }i: % /fy,, } }ii:•r, :t: ^•4v�{:%;f {:•}i •'..r • • {:S'C�:+{}id+.'.y,.r 'ti;% 'lrf{i,'��' {' };;;•i; osiia #A •;•,r'r•�`}{i Y37 rr •.;�• •kr ?'s f'S� {., { {ryv;��,S,` { <: • ` ��. ? {�n:;fr.;it •...... .r�•. i'i {':: i'Fi: rr r:r J.K:••f.•• %�: :�f '•i }r::•.{•. :?v:ii Dept. of Labor Storage Category: Hygienic Practices: Additional Precautions: Empty Container Warning: Flammable liquid Class IB. Keep away from heat, sparks and open flame. Keep containers closed when not In use. Avoid eye contact. Avoid prolonged contact with skin. Wash skin with soap and water after contact. Ground containers when transferring liquid to prevent static accumulation and discharge. "Empty" containers retain residue (liquid and'dr vapor) and oan be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind or expose such containers to heat, flamer sparks or other sources of ignition. They may explode and cause injury or death. Do not attempt to clean since residue is difficult to remove. "Empty" drums should be completely drained, properly bunged and promptly returned to supplier or disposed of in an environmentally safe manner and in accordance with governmental regulations. F fir• -. `:: #;ice:;' >.: <':; >{ f l ff t { MK` n{•!{� ;`,r,: $ {r it "•.y::vY, This product contains the following toxio chemical(s) which are subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372: TOXIC CHEMICAL Acetone Toluene Glycol Ethers (Ethylene Glycol Monobutyl Ether) CAS # 67641 . 108883 111761 APPROXIMATE % BY WEIGHT 25.41 % 21.84% 2.31% M a t e r i a l S a f e t y D a t a S h e e t LYSOL(R) BRAND DISINFECTANT SPRAY - ORIGINAL, PRA, LIGHT, COUNTR Page: 1 Rev. Date 04/09/91 L & F Products 225 Summit Avenue Montvale, NJ 07645 Telephone Nimiber: (201) 573 -5700 (24 hrs) Energency Contact: !REC Emergency Phone Number: (800)424 -9300 BECI.'ION 41 - IDENTIFICATION Product: LYSOL(R) BRAND DISINFECTANT SPRAY - ORIGINAL, FRESH, LIGHT, COUNTRY SCENTS CAS Number:. Not Applicable EPA Reg. No.: 777 -53 Product Code: LC -111 Formula No.: Z2381, 421961, 820531 Synonyms: LYSOL BRAND DISINFECTANT SPRAY - ORIGINAL FRESH, LIGHT, COUNTRY SCENT NFPA Hazard Rating - Health: 1 Slight Fire: Level 1 Aerosol - Reactivity: 0 Negligible Special Hazards: Contents Under Pressure. Do not puncture or incinerate. Product Description: Aerosol Disinfectant This product is a registered pesticide. Use of this product in a manner not consistent with the label instructions is a violation of federal law. SECTION 42 - HAZARDOUS CHEMICAL COMPONENTS Component: CARBON DIOXIDE (AS CAS Number: 124 -38 -9 ACGIH TLU -TWA: 5,000 ppm ACGIH TLV -STEL: 30,000 ppm Component: ETHANOL CAS Number: 64 -17 -5 ACGIH TLV -TWA: 1,000 ppm PRJPELIAN'T) Percent of Mixture: 4.0 OSHA PEL -TWA: 10,000 ppm OSHA PEL-STEL: 30,000 ppm Component: ORTHO -Pf ENYLF H IOL CAS Number: 90 -43 -7 No Exposure Limits established by ACGIH or OSHA Percent of Mixture: 79.0 OSHA PEL -TWA: 1,000 ppm Percent of Mixture: . M[-- aterial Safety Data Sheet LYSOL (R) BRAND DISINFECTANT SPRAY - ORIGINAL, FRESH, LIGHT, COUNIRY Page: 2 Rev. Date 04/09/91 SECTION #3 - PHYSICAL DATA Boiling Point: 78 - 105 °C Vapor Pressure: 95 - 105 prig. Vapor Density (Air -1): >1 Specific Gravity: 0.835 @ 25 °C Solubility (H2O): Miscible pH: "10 at a Concentration of: 50% Appearance Aerosol spray can. SECTION #4 - FIRE FICHTIN'3 & EXPLOSION DATA Flash Point: 70 °F TCC (concentrate) Flammability Class: Level 1 Aerosol Lower Explosive Limit ( %): Not Determined Upper Explosive Limit ( %): Not Determined. Fire and Explosion Hazards Contents under pressure. Do not use near heat, spark or open flame. Do not puncture or incinerate container. Exposure to temperatures above 120 °F may cause bursting. Extinguishing Media Water spray, foam, dry chemical or carbon dioxide. Use media suitable for surrounding fire. Use water spray to cool fire exposed containers. Special Fire Fighting Instructions Wear self - contained breathing apparatus and protective equipment appropriate for fighting a typical chemical fire. Move containers away from fire if possible and safe to do so. Use water spray to cool fire exposed containers. SECTION #5 - EXPOSURE and EFFECTS - INHALATION Routes of Exposure - Inhalation None expected. Susceptible individuals may experience dizziness, drowsiness, nausea and vomiting if exposed to extremely high concentrations of the vapors. c .rid c e r l a i sate 1. y u a L. a J 11 C C t. L 4y 4 • J Rev. Date LYSOL(R) BRAND DISINFECTANT SPRAY - ORIGINAL, FRESH, LIGHT, CbUNTR 04/09/91 SECTION 45 - EXPOSURE and EF'F'ECTS - INHALATION continued... First Aid - Inhalation If required, remove to fresh air. SECTION 45 - EXPOSURE and EFFECTS - SKIN Routes of Exposure - Skin None expected. rErJrIoN 45 - EXPOSURE and EFFECTS - EYES Routes of Exposure - Eyes May cause mild temporary eye irritation. First Aid — Eyes If contact occurs, immediately flush eyes with plenty of low pressure water. Remove contact lenses to insure a thorough flush and continue to flush with water for at least 15 minutes. If irritation persists, get medical attention. SECTION 45 - EXPOSURE and EFFECTS - INGESTION Routes of Exposure - Ingestion Ingestion is very unlikely through the normal anticipated use of this. product. Ingestion of small quantities is not expected to cause any significant adverse effects. First Aid - Ingestion Administer water to dilute the ingested material. Consult a physician. Do not give liquids to an unconscious person. SECTION 45 - MISCELLANEOUS TOXICOLOGICAL INFORMATION CARCINOGENICITY: NTP - No IARC - No OSHA - No ' M a t e r i a l S a f e t y D a t a S h e e t Page: 4 Rev. Date LYSOL(R) BRAND DISIIF'ECTAN'T SPRAY -ORIGINAL, a LIB', CCKMY 04/09/91 SECTION #6 ■ REACTIVITY it POLYMERIZATION Stability: Stable Conditions to Avoid Avoid temperatures above 120°F. Incompatible Materials Strong oxidizing agents. Hazardous Decomposition Products Carbon dioxide, carbon monoxide, and unidentified organic compounds nay be formed during thermal decomposition. Hazardous Polymerization: Will not occur. SECTION #7 - SPILL, LEAK, & DISPOSAL PROCEDURES Steps to be Taken in The Event of Spills, Leaks, or Release For large spills, ventilate the area. Collect liquid and store in suitable containers for disposal. Waste Disposal Methods Dispose of in accordance with local, state and federal regulations. Other Environmental Information None of the ingredients of this product are listed under the SARA Title III, Section 313 List of Toxic Chemicals. SECTION #8 ■ SPECIAL PROTECTIVE MEASURES Ventilation None required. Eye Protection Material Safety Data Sheet Page: 5 Rev. Date LYSOL(R) BRAND DISINFECTANT SPRAY -ORIGINAL, FRESH, L/GST, COUNTR 04/09/91 SECTION 18 - SPECIAL PROTECTIVE MEASURES Continued... Skin Protection None required. Respiratory Protection None required. SECTION 49 - SPECIAL PRECAUTIONS - STORAGE & HANDLING Storage • & Handling Conditions • Store in a cool, dry location away from hot surfaces, dparks or flames. Do not use near fire, sparks or flame. C M a t e r i a l S a f e t y D a t a S h e e t LYSOL (R) BRAND DISINFECTANT DEODORIZING CLEANER Page: 1 Rev. Date 04/09/91 L & F Products 225 Summit Avenue Montvale, NJ 07645 Telephone Number: (201)573 -5700 (24 hrs) Emergency Contact: CHEMTREC Emergency Phone Number: (800) 424 -9300 SECTION #1 - IDENTIFICATION Product: LYSOL (R) BRAND DISINFECTANT DEODORIZING CLEANER CAS Number: Not Applicable EPA Reg. No.: 777 -44 Product Code: ID-17 Formula No.: 71861 -5 NFPA Hazard Rating - Health: 1 Slight - Fire: 0 Negligible - Reactivity: 0 Negligible Special Hazards: None Known. This product is a registered pesticide. Use of this product in a manner not consistent with the label instructions is a violation of federal law. SECTTION #2 - HAZARDOUS CHEMICAL CONP0NENTS Component: ALKYL (C12 -C16) DIMETBYIBENZYIAMMONIUM .CHLORIDES CAS Number: 68424 -85 -1 Percent of Mixture: 2.7 No Exposure Limits established by ACGIH or OSHA SECTION #3 - PHYSICAL DATA Boiling Point: Not Applicable Vapor Pressure: Not Determined Vapor Density (Air=1): Not Determined Specific Gravity: 1.02 Solubility (H20): Soluble pH: 8.35. M a t e r i a l S a f e t y D a t a S h e e t LYSOL (R) BRAND DISINFECTANT DEODORIZING CLEANER Page: 2 Rev. Date 04/09/91 SECTION *3 - PHYSICAL DATA Continued... Appearance Transparent fluorescent amber liquid. SECTION #4 - FIRE FIGHTING & EXPLOSION DATA Flash Point: >200 °F TCC Lower Explosive Limit ( %): Not Determined Upper Explosive T,imit ( %): Not Determined Fire and Explosion Hazards None expected. Extinguishing Media Use water spray, foam, dry chemical or carbon dioxide, as. suitable for the surrounding fire. Special Fire Fighting Instructions None required. SECTION #5 - EXPOSURE and EFFECTS - INHALATION Routes of Exposure - Inhalation None expected. SECTION #5 - EXPOSURE and EFFECTS - SKIN Routes of Exposure - Skin Repeated or prolonged contact may cause skin irritation. First Aid - Skin Wash exposed areas with soap and water. M a t e r i a l S a f e t y D a t a S h e e t LYSOL (R) BRAND DISINFECTANT DEODORIZING CLEAR Page: 3 Rev. Date 04/09/91 SECTION 45 - EXPOSURE and EFFECTS - EYES Routes of Exposure - Eyes May cause temporary eye irritation. First Aid - Eyes In case of eye contact, immediately flush eyes with low pressure water. Remove contact lenses to insure a thorough flush and continue to flush with water for least 15 minutes. Get medical attention. SECTION 45 - EXPOSURE' and EFFECT'S - INGESTION Routes of Exposure - Ingestion May cause gastrointestinal tract irritation. First Aid - Ingestion DO NOT INDUCE VOMITING. Drink several glasses of water. Contact a physician. SECTION #5 - MISCELLIANDOUS TOXICOLOGICAL INFORMATION Carcinogenicity: NTP: No IARC: No OSHA: No SECTION 46 - REACTIVITY & POLYMERIZATION Stability: Stable Conditions to Avoid None Incompatible Materials None known. Hazardous Decomposition Products. Carbon Dioxide, Carbon Monoxide and unidentified organic compounds may formedd during thermal decomposition. Hazardous Polymerization:, Will not occur ( Material Safety Data Sheet LYSOL (R) BRAND DISINFECTANT DEODORIZING CLEANER Page: 4 Rev. Date 04/09/91 SECTION 47 - SPILL, LEAK, & DISPOSAL PROCEDURES Steps to be Taken in The Event of Spills, Leaks, or Release Spills may be flushed into sewer with large quantities of water. Waste Disposal Methods Dispose of in accordance with local, state and federal regulations. Other Environmental Information None of the ingredients of this product are listed under the SARA Title III, Section 313 List of Toxic Chemicals. SECTION 48 - SPECIAL PROTECTIVE MEASURES ■•••■■•••■ Ventilation None required. Eye Protection None required. Skin Protection None required. Respiratory Protection None required. SECTION #9 - SPECIAL PRECAUTIONS - STORAGE1 BANDLMNd • • Storage & Handling Conditions None. 1(7,. OCCUPATIONAL HEALTH SERVICES, INC. 11 WEST 42ND STREET, 12TH FLOOR NEW YORK, NEW YORK 10036 1 -800- 445 -M800 . (1- 800 -445 -6737) OR 1 -212 -789 -3535 OHSLP119 PAGE 001 OF 010 MATERIAL SAFETY DATA SHEET FOR EMERGENCY SOURCE INFORMATION CONTACT: 1 -615- 366 -2000 . SUBSTANCE: 'METHANOL TRADE NAMES /SYNONYMS: INVH 11921, OHSLP119 CHEMICAL FAMILY: MIXTURE SUBSTANCE IDENTIFICATION CERCLA RATINGS (SCALE 0-3): HEALTH.3 FIRE.3 REACTIVITY -0 NFPA RATINGS ISCALE .0 -4): HEALTH.3 FIRE -3' REACTIVITY -0 COMPONENT: PHOSPHORIC ACID, CAS# 7664 -38 -2 COMPONENTS'AND CONTAMINANTS.. PERSISTENCE -0. COMPONENT: METHYL ALCOHOL CASH 67 -56 -1 COMPONENT: WATER EXPOSURE LIMITS:'. PHOSPHORIC ACID: 1 MG /M3 OSHA TWAT 3 MG /M3 OSHA STEL ' MO /M3 ACOIH TWAj.3 MO /M3;ACQIH STEL. 21G /M3 NIOSH RECOMMENDED TWA) 3 MG /M3 NIOSH RECOMMENDED,STEL MEASUREMENT METHOD: SILICA "GEL TUBE] SODIUM BICARBONATE /80DIUM CARBONATE; ION CHROMATOGRAPHY; (NIOSH VOL. :III`# 7903, INORQANIC'ACIDS). >: 5000 POUNDS CERCLA SECTION.103 REPORTABLE QUANTITY SUBJECT TO SARA SECTION;313 ANNUAL .TOXIC'CHEMICAL RELEASE REPORTING '* *OSHA LIMITS ADOPTED JANUARY 19, 1989.ARE SUBJECT ..TO THE DECISION :08' THE. • 11TH CIRCUIT COURT. OF APPEALS (APL -CIO 1.,..-OSHA ) AS OE JULY 7, 1992. ** METHYL ALCOHOL.(METHANOL): 200 PPM (362MG(M3)`OSHA'TWA ;(SKIN)j.250.PPM (328 MG /M3)'OSHA'STEL',' 200 PPM' (262 MG/M3) ACOIH -TWA (SKIN)„ 250.PPM';(328 MG /M3),-ACGIH STEL 200 PPM (262'MG /M3)'NIOSH. RECOMMENDED,TWA,,(SKIN); 250 PPM (328 MQ /M3)NIOSH RECOMMENDED,BTEL'' 200 PPM (262MG /M3);,DPO MAK TWA.(SKIN)9:` 400 PPM (524 MG/M3) DFG MAK'.30 MINUTE .PEAK, 'AVERAQE'.VALUE,:4 TIMES /SHIFT OHSLP119 ' PAGE 002 OF 010 EASUREMENT METHOD: SILICA GEL TUBE; WATER; GAS CHROMATOGRAPHY WITH FLAME JIZATION DETECTION; (NIOSH VOL. III # 2000', METHANOL). 5000 POUNDS CERCLA SECTION 103 REPORTABLE QUANTITY SUBJECT TO SARA SECTION 313 ANNUAL TOXIC CHEMICAL RELEASE REPORTING PHYSICAL DATA DESCRIPTION: CLEAR LIQUID WITH AN ALCOHOL ODOR, BOILING POINTt'148 F (64.5 C) . MELTING POINT: -144 F ( -98 C) SPECIFIC GRAVITY: 0.79 VAPOR PRESSURE: 97 MMHG 0 20 C EVAPORATION RATE: 5.9 (BUTYL ACETATE.1) SOLUBILITY IN WATER: COMPLETE VAPOR DENSITY: 1.1 • FIRE AND EXPLOSION DATA FIRE AND EXPLOSION HAZARDS DANGEROUS FIRE HAZARD WHEN EXPOSED TO HEAT OR FLAME. VAPORS ARE HEAVIER THAN AIR AND MAY TRAVEL A CONSIDERABLE DISTANCE TO A SOURCE OF IGNITION AND FLASH BACK. VAPOR -AIR MIXTURES ARE EXPLOSIVE ABOVE FLASH POINT. FLASH POINT: 52-54.F (11 -12.C) (CC) UPPER EXPLOSIVE LIMIT: 36.0% LOWER EXPLOSIVE LIMIT: 6.0% FLAMMABILITY CLASS(OSHA)t IS FIREFIGHTING MEDIA: . DRY CHEMICAL, CARBON'DIOXIDE,.WATER SPRAY OR•ALCOHOL- RESISTANT FOAM (1990 EMERGENCY RESPONSE GUIDEBOOK, DOT'P 5800.5). , LARGER FIRES,'USE WATER SPRAY,',F00 OR ALCOHOL-RESISTANT FOAM J EMERGENCY RESPONSE GUIDEBOOK, DOT P 5800.5). FIREFIGHTING: MOVE CONTAINER FROM FIRE•AREA IF.YOU, CAN DO IT WITHOUT RISK. DO NOT GET WATER INSIDE CONTAINER. APPLY. COOLING WATER .TO BIDES OF CONTAINERS THAT ARE;EXPOSED • TO FLAMES UNTIL i.WELL AFTER.FIRE IS OPT.' STAY -AWAY FROM ENDS•OF TANKB.•WITHDRAW IMIMEDIATELY IN CASE.OF.RISING SOUND'FROM VENTING SAFETY DEVICE ORANY DISCOLORATION OF•TANK DUE'TO FIRE; ISOLATE FOR 1 /2.MILE IN.ALL DIRECTIONS IF. TANK, RAIL CAR OR TANK.TRUCK IS. INVOLVED IN FIRE (1990 EMERGENCY RESPONSE GUIDEBOOK, DOT .P 5800,5, GUIDE PAGE'29).. EXTINGUISH ONLY, IF FLOW CAN BE STOPPED.,.000L.CONTAINERS WITH,FLOODING AMOUNTS OF WATER FROM AS FAR A.DISTANCE AS'POSSIBLE :.,DO NOT•USE WATER DIRECTLY.ON,. ' MATERIAL. IF. LARGE,AMOUNTS.OF.COMBUSTIBLE MATERIALS ARE.INVOLVED, USE WATER ' SPRAY AND FOG IN FLOODING AMOUNTS.., USE WATER SPRAY TO ABSORB FLAMMABLE, BR CORROSIVE VAPORS.' AVOID EATHING CORROBIVE,VAPORS, KEEP. UPWIND..' c DEPARTMENT OF TRANSPORTATION HAZARD CLASSIFICATION 49 -CFR 172.101: FLAMMABLE LIQUID OHSLP119 PAGE 003 OF 010 TRANSPORTATION DATA DEPARTMENT OF TRANSPORTATION LABELING REQUIREMENTS 49 -CFR 172.101 AND SUBPART E: FLAMMABLE LIQUID AND CORROSIVE • DEPARTMENT OF TRANSPORTATION PACKAGING REQUIREMENTS: 49 -CFR 173.119 EXCEPTIONS: NONE TOXICITY METHANOL (AS.USED :IN.PROTEIN'ASSAY KITS I AND Ti AND DYE REAGENT •CONC.): ' CARCINOGEN STATUS:.NONE.: • ACUTE•TOXICITY LEVEL: NO DATA •AVAILABLE. TARGET EFFECTS: NO DATA AVAILABLE..' AT INCREASED RISK.FROM EXPOSURE: PERSONS'WITH•LIVER DISORDERS: PHOSPHORIC ACID: IRRITATION'DATA: 595.MG/24 HOURS' SKIN - RABBIT SEVERE: 119 MG EYE - RABBIT TOXICITY DATA: 2740 MG /KG SKIN - RABBIT LDSO; 1530,140/KO ORAL -RAT LD50;. 220 M0 /KO UNREPORTED -MAN LDLO. ' CARCINOGEN STATUS; NONE. LOCAL EFFECTS: CORROSIVE INHALATION, 8KIN, EYE, INGESTION. ACUTE TOXICITY LEVEL: MODERATELY TOXIC'BY INGESTION; 'SLIGHTLY ABSORPTION. • TARGET EFFECTS: NO DATA AVAILABLE.' AT INCREASED RISK FROM EXPOSURE: PERSONS WITH PRE - EXISTING RESPIRATORY SKIN DISEASE. METHYL ALCOHOL. (METHANOL): ' IRRITATION DATA :720 MG /24 HOURS SKIN - RABBIT MODERATE; 40 MG EYE - RABBIT ' MODERATE; 100 M0 /24'HOURS:EYE- RABBIT MODERATE.. . TOXICITY DATA: 86,000 M0 /M3'INHALATION -HUMAN TCLO1 300 PPM•INHALATION -HUMAN ,'. L0; 64,000 PPM /4 HOURS INHALATION -RAT LC501•1000.PPM INHALATION-MONKEY- .':.,01 50 •GM /M3/2 HOURS INHALATION -MOUSE LCLO; 44,000 MG /M3 /6,HOURS • ..rMALATION- CAT.LCLO1 15,800 MG /KG SKIN- RADBIT :LD50;,'.393, M0 /KG SKIN - MONKEY,'• LDLO; 428 MO/KG ,ORAL -HUMAN LDLOj„143 MG /KG ORAL- HUMAN•LDL01 6422 MG /KO • ORAL -MAN LDLO;' 3429 M0 /K0 ORAL -MAN TDLO; 4 GM/MORAL-WOMAN TOLOj.7 GM /KG . ORAL - MONKEY LDSOj 5628. MG /KG ORAL -RAT L050 /.7300,M0 /K0'ORAL -MOUSE LD50J 14,200 M0 /K0'ORAL- RABBIT'LD50;'7500 MG /KG ORAL- DO0'LDLO19800.MG /KG,.,.:, SUBCUTANEOUS- MOUSE.LD50( 2131.;M0/K0 INTRAVENOUS =RAT LD50; 4710•MG /K0'. • INTRAVENOUS -MOUSE LD5O; 8907,MG /K0 INTRAVENOUS- RABBIT LD50p. ".4641, MG /KG . INTRAVENOUS -CAT ..L LDLOj:7529 MG /K0 INTRAPERITONEAL- RAT050J. •10;765 MO/K0. INTRAPERITONEM - MOUSE.LD50 ;'1826 M0/ K0' INTRAPERITONEAL- RABBIT,LD50j.,' 3556 MG /KG INTRAPERITONEAL- GUINEA PIG LD50j 8555,.M0/KO: INTRAPERITONEAL- HAMSTER;LD5068 M0 /KO UNREPORTED -MAN LDLO; MUTAGENIC', • DATA (RTECS); REPRODUCTIVE' EFFECTS. DATA,•(RTECS).' : CARCINOGEN STATUS: :NONE. LOCAL EFFECTS: IRRITANT - 8KIN,•EYE.•' 'ACUTE TOXICITY.LEVELt, SLIGHTLY TOXIC BY DERMAL.ABBORPTION AND INGESTI0N1':` RELATIVELY NON -TOXIC BY •INHALATION._ ' TARGET EFFECTS: CENTRAL imRyoutr. SYSTEM DEPRESSANT,'NEUROTOXIN, AT INCREASED RISK FROM.EXPOSUREi PERSONS WITH KIDNEY,.. EYE' OP. BKIN'DISORDERS.': OHSLP119: PAGE 004 OF 010 HEALTH EFFECTS AND'FIRST AID INHALATION: METHANOL (AS USED.IN PROTEIN ASSAY•KITS I.AND II AND DYE REAGENT CONC.):. ACUTE EXPOSURE -, MAY CAUSE•ASPHYXIATION. CHRONIC EXPOSURE- NO DATA AVAILABLE, PHOSPHORIC ACID: • CORROSIVE. SEE. INFORMATION ON ACIDIC CORROSIVES. ACIDIC CORROSIVES: ACUTE EXPOSURE- MAY CAUSE RESPIRATORY. TRACT'IRRITATION WITH COUGHING, ' .CHOKING," -AND POSSIBLY BURNS OF_THE MUCOUS MEMBRANES:' OTHER INITIAL.. .SYMPTOMS.MAY.INCLUDE DIZZINESS,- HEADACHE; NAUSEA AND WEAKNESS. IN SOME . ' CASES.PULMONARY."EDEMA •MAY'- DEVELOP, EITHER IMMEDIATELY:'IN SEVERE CASES, OR MORE LIKELY.AFTER A-LATENT'PERIOD OF'5 -72 HOURS. THE SYMPTOMS MAY.INCLUDE 'TIGHTNESS IN THE CHEST,;DYSPNEA,.FROTHY'SPUTUM, AND CYANOSIS. PHYSICAL:. FINDINGS MAY INCLUDE HYPOTENSION, WEAK,;RAPID.PULSE.AND MOIST RALES.''.,:. RECOVERY MAY BE PROLONGED"AND :,RELAPSES ARE POSSIBLE. :IN SEVERE EXPOSURES, DEATH DUE-TO'.ANOXIA•MAY,OCCUR WITHIN A FEW HOURS AFTER ONSET'OF: PULMONARY EDEMA SYMPTOMS OR FOLLOWING .A RELAPSE. : CHRONIC EXPOSURE - .DEPENDING ON'THE CONCENTRATION AND DURATION OF EXPOSURE, REPEATED OR 'PROLONGED EXPOSURE. MAY CAUSE•EROSION OF THE.TEETH,' INFLAMMATORY AND ULCERATIVE' CHANGES IN'THE MOUTH, 'AND POSSIBLY,JAW NECROSIS BRONCHIAL IRRITATION WITH COUGH AND FREQUENT ATTACKS OF BRONCHIAL PNEUMONIA MAY OCCUR. GASTROINTESTINAL DISTURBANCES ARE .ALSO POSSIBLE :. ' METHYL ALCOHOL (METHANOL):. NARCOTIC /NEUROTOXIN, 25,000, PPM :IMMEDIATELY DANGEROUS TO LIFE OR HEALTH. ACUTE EXPOSURE- MAY CAUSE ".IRRITATION OP.-THE-MUCOUS. MEMBRANES, COUGHING, OPPRESSION IN'THE-CHEST, TRACHEITIS, BRONCHITIS, TINNITUS, UNSTEADY GAIT, TWITCHING," COLIC, CONSTIPATION,-NYSTAGMUS, AND BLEPHAROSPASM. SYMPTOMS FROM OCCUPATIONAL., EXPOSURE INCLUDE PARESTHESIAS, NUMBNESS.AND SHOOTING PAINS',IN•THE :HANDS AND FOREARMS..METABOLIC.ACIDOSIS, AND, EFFECTS ON THE EYES AND CENTRAL NERVOUS :SYSTEM MAY.000UR AS, DETAILED IN ACUTE , INGESTION :' . . LHRONIC EXPOSURE- REPEATED.OR PROLONGED EXPOSURE MAY.CAUSE EFFECTS•AS IN ACUTE., INGESTION. REPEATED•EXPOSURE TO 200 -375 PPM CAUSED RECURRENT.' '' HEADACHES IN'WORKERS.- "EXPOSURE FOR 4 YEARS:TO 1200 -5000 PPM RESULTED.IN MARKED' DIMINUTION OF,VIBION AND :ENLARGEMENT OF, THE LIVER -IN A'WORIGNAN:.•, :' ".REPRODUCTIVE EFFECTS HAVE BEEN REPORTED IN ANIMALS FIRST AID- REMOVE',FROM EXPOSURE -AREA TO • FRESH' AIR' IMMEDIATELY:'IF'BREATHING •., HAS STOPPED GIVE: ARTIFICIAL, RESPIRATION:, MAINTAIN AIRWAY AND "BLOOD . PRESBURE•AND.ADMINISTER OXYGEN .IF'.AVAILABLE.'KEEP•AFFECTED PERSON•WARM AND: AT. REST. -TREAT SYMPTOMATICALLY AND. SUPPORTIVELY.", ADMINISTRATION:.0FOXYGEN'• SHOULD BE'PERFORMED BY QUALIFIED. PERSONNEL: GET MEDICAL' ATTENTION..'. SKIN CONTACT; PHOSPHORIC ACID: CORROSIVE ANIMAL STUDIES INDICATE -THAT SKIN ABSORPTION MAY OCCUR. SEE INFORMATION ' OH ACIDIC. CORROSIVES.. OHSLP119 PAGE 005 OF 010 (tCCORROSIVES: .UTE EXPOSURE- DIRECT CONTACT MAY CAUSE SEVERE PAIN, BURNS AND POSSIBLY BROWNISH OR YELLOWISH STAINS. BURNS MAY BE DEEP WITH SHARP EDGES AND HEAL SLOWLY WITH SCAR TISSUE FORMATION. CHRONIC EXPOSURE - EFFECTS DEPEND.ON THE CONCENTRATION AND DURATION OF EXPOSURE. REPEATED OR PROLONGED CONTACT MAY RESULT IN DERMATITIS OR • EFFECTS SIMILAR TO ACUTE EXPOSURE. METHYL'ALCOHOL (METHANOL): IRRITANT /NARCOTIC /NEUROTOXIN... ACUTE EXPOSURE -• CONTACT WITH LIQUID MAY.CAUSE.IRRITATION. SKIN ABSORPTION MAY OCCUR AND. CAUSE METABOLIC ACIDOSIS •AND EFFECTS ON THE EYES AND CENTRAL; NERVOUS SYSTEM AS DETAILED IN ACUTE INGESTION, CHRONIC EXPOSURE- .REPEATED OR.PROLONGED CONTACT WITH THE. LIQUID MAY CAUSE DEFATTING OF THE SKIN RESULTING IN ERYTHEMA, SCALING;. AND,ECZEMATOID DERMATITIS, CHRONIC ABSORPTION MAY RESULT IN METABOLIC ACIDOSIS.AND: EFFECTS AS DETAILED IN,ACUTE INGESTION.. FIRST AID- REMOVE CONTAMINATED CLOTHING AND SHOES IMMEDIATELY. WASH 'AFFECTED AREA•WITH SOAP OR MILD DETERGENT AND LARGE AMOUNTS OF•WATER UNTIL1N0 EVIDENCE OF CHEMICAL REMAINS (AT LEAST 15 -20 MINUTES).: IN, CASE OF CHEMICAL, BURNS, COVER AREA WITH. STERILE, .DRY DRESSING.' BANDAGE SECURELY, BUT NOT TOO TIGHTLY. GET MEDICAL ATTENTION IMMEDIATELY. EYE CONTACT: • PHOSPHORIC ACID: CORROSIVE. DIRECT CONTACT WITH A 0.16M SOLUTION:BUFPERED TO PH 2.5 CAUSED.A MODERATE,` BRIEF STINGING,SENSATION, BUT.NO INJURY WHEN APPLIED AS 'A SINGLE DROP IN HUMAN EYES. WHEN ADJUSTED TO PH 3.4, A DROP OF THE SOLUTION CAUSED NO DISCOMFORT. IRRIGATION.OF RABBIT EYES'FOR 5 MINUTES WITH PH 3.8 SOLUTION CAUSED SLIGHT TRANSIENT.EPITHELIAL EDEMA AND CONJUNCTIVAL HYPEREMIA, BUT THE EYE.WAS NORMAL WITHIN 24 HOURS,'WHEN INJECTED INTO. THE CORNEAL STROMA.OR• APPLIED TO THE CORNEA AFTER:REMOVAL OF THEEPITHELIUM,•IT CAUSED DETECTABLE•INJURY.BELOW PH:5,5. EYE BURNS MAY'RESULT FROM'SPLASHES OF'. CONCENTRATED SOLUTIONS. SEE INFORMATION ON ACIDIC CORROSIVES. (SIC CORROSIVES: 7TE EXPOSURE - '.DIRECT' CONTACT MAY,CAUSE PAIN, LACRIMATION,..PHOTOPHOBIA. ` - AND BURNS. IN MILD BURNS,, THE EPITHELIUM"- REGENERATES RAPIDLY AND THE EYE RECOVERS COMPLETELY'. IN SEVERE.CASES, THE.EXTENT.OF INJURY :MAY NOT,BE FULLY APPARENT FOR SEVERAL' WEEKS.. ULTIMATELY, THE:WHOLE CORNEA MAY;BECOME DEEPLY VASCULARIZED AND OPAQUE' RESULTING IN:BLINDNESS. IN THE WORST. CASES, THE EYE MAY BE TOTALLY.DESTROYED:,. CHRONIC EXPOSURE - ,EFFECTS DEPEND,ON THE- CONCENTRATION AND DURATION OF:. • EXPOSURE, REPEATED OR• PROLONGED. CONTACT MAY.• CAUSE. CONJUNCTIVITIS'OR • EFFECTS AS IN ACUTE. EXPOSURE'. METHYL ALCOHOL (METHANOL):' IRRITANT. ACUTE EXPOSURE - VAPORS MAY. CAUSE;. IRRITATION:• HIGH ,CONCENTRATIONB HAVE,'. BEEN•REPORTED.TO ;CAUSE`VIOLENT INFLAMMATION OF. THE CONJUNCTIVA AND EPITHELIAL DEFECTS ON THE'CORNEA."MILD.IRRITATION'MAY OCCUR WITH ' DILUTE SOLUTIONS/, THE, UNDILUTED •LIQUID HAS PRODUCED :MODERATE CORNEAL • OPACITY'AND,CONJUNCTIVAL REDNESS IN, RABBITS /'APPLICATION OF.A'DROP OF METHANOL IN RABBIT EYES'CAUSED A;MILD REVERSIBLE REACTION, GRADED'. 3 ON A. SCALE. OF 1 -10 AFTER 24 -- - - -- • ' OHSLP119 PAGE 006 OF 010 C RONIC EXPOSURE- .REPEATED OR PROLONGED CONTACT MAY CAUSE CONJUNCTIVITIS.T AID- WASH EYES IMMEDIATELY WITH-LARGE AMOUNTS-OF WATER, OCCASIONALLY, LIFTING UPPER AND:LOWER LIDS, UNTIL NO EVIDENCE OF CHEMICAL REMAINS (AT LEAST 15 -20 MINUTES). CONTINUE. IRRIGATING WITH.NORMAL SALINE UNTIL THE PH HAS RETURNED TO NORMAL (30 -60 MINUTES). COVER WITH STERILE BANDAGES.. GET MEDICAL ATTENTION IMMEDIATELY.. INGESTION: PHOSPHORIC ACID:' CORROSIVE. SEE INFORMATION ON ACIDIC CORROSIVES. ACIDIC CORROSIVES: ACUTE.EXPOSURE -,MAY CAUSE CIRCUMORAL BURNS'WITH DISCOLORATION AND CORROSION • OF THE MUCOUS MEMBRANES OF-.THE MOUTH, THROAT AND ESOPHAGUS ::THERE MAY BE IMMEDIATE PAIN AND DIFFICULTY OR INABILITY TO..SWALLOW OR.SPEAK. EPIGLOTTAL EDEMA MAY RESULT IN RESPIRATORY DISTRESS AND POSSIBLY ASPHYXIA. MARKED THIRST, NAUSEA, VOMITING AND DIARRHEA MAY OCCUR, DEPENDING ON THE AREA AND DEGREE OF CORROSION, THE VOMITUS MAY CONTAIN FRESH OR DARK BLOOD AND•LARGE SHREDS OF MUCOSA...SHOCK MAY OCCUR WITH :MARKED HYPOTENSION,' WEAK AND RAPID PULSE; SHALLOW RESPIRATION, AND CLAMMY SKIN. CIRCULATORY COLLAPSE MAY DEVELOP AND;IF,UNCORRECTED,•.LEAD TO RENAL FAILURE. IN,SEVERE CASES;, GASTRIC AND; TO A LESSER DEGREE,. ESOPHAGEAL PERFORATION MAY OCCUR WITH PERITONITIS ACCOMPANIED BY FEVER AND, ABDOMINAL RIGIDITY.•ESOPHAGEAL, . GASTRIC OR PYLORIC STRICTURE MAY OCCUR. WITHIN A FEW WEEKS, OR MAY BE DELAYED FOR MONTHS OR EVEN .YEARS.'DEATH MAY •RESULT. WITHIN A'SHORT TIME PROM ASPHYXIA,' CIRCULATORY COLLAPSE OR ASPIRATION OF EVEN MINUTE AMOUNTS, • IP DEATH IS DELAYED, IT MAY BE DUE'TO PERITONITIS, SEVERE NEPHRITIS, OR • PNEUMONIA. COMA•AND CONVULSIONS SOMETIMES OCCUR TERMINALLY. • CHRONIC EXPOSURE- DEPENDING ON THE CONCENTRATION,. REPEATED•INGESTION.MAY • RESULT IN INFLAMMATORY AND ULCERATIVE CHANGES IN THE' MUCOUS MEMBRANES OF THE MOUTH AND OTHER EFFECTS AS IN ACUTE INGESTION. METHYL-ALCOHOL-METHANOL): NARCOTIC /NEUROTOXIN ACUTE EXPOSURE- CAUSE•MILD AND :TRANSIENT INEBRIATION AND SUBSEQUENT DROWSINESS' FOLLOWED• BY, AN. ASYMPTOMATIC PERIOD LASTING 8-48 HOURS.', FOLLOWING THE DELAY, COUGHING, "DYSPNEA, HEADACHE,. DULLNESS, WEAKNESS, • `IERTIGO OR DIZZINESS, NAUSEA,. VOMITING, OCCASIONAL DIARRHEA ;`ANOREXIA,• ' VIOLENT PAIN"IN THE BACK, ABDOMEN,•.AND EXTREMITIES, - RESTLESSNESS, APATHY, OR DELIRIUM,': AND RARELY,' EXCITEMENT.AND.MANIA MAY OCCUR. RAPID, SHALLOW • RESPIRATION DUE-TO-METABOLIC ,ACIDOSIS,:COLD AND CLAMMY SKIN,,HYPOTENSION," CYANOSIS,. OPI STHOTONOS,CONVVLSIONS,.MILD TACHYCARDIA, CARDIAC. DEPRESS ION,. PERIPHERAL NEURITIS, 'CEREBRAL AND. PULMONARY EDEMA,UNCONSCIOUSNESS;`AND; COMA ARE._POSSIBLE: EFFECTS ON`THE.EYE MAY INCLUDE OPTIC NEURITIS,. BLURRED`' OR DIMMED•VISION, DILATED, UNRESPONSIVE.PUPILS, PTOSIS, EYE PAIN,' CONCENTRIC CONSTRICTION OF VISUAL. FIELDS, DIPLOPIA, CHANGE IN COLOR•. PERCEPTION, PHOTOPHOBIA, AND :OPTIC NERVE ATROPHY. PARTIAL BLINDNESS DR. • POSSIBLY DELAYED, TRANSIENT OR'PERMANENT BLINDNESS MAY.000UR. BILATERAL SENSORINEURAL'DEAFNESS HAS 'BEEN REPORTED.IN A SINOLE_CASE,:LIVER, ISIDNEY. HEART, STOMACH, INTESTINAL AND PANCREATIC DAMAGE MAY ALSO OCCUR :•.DEATH . MAY BE DUE TO RESPIRATORY. FAILURE. OR. RARELY FROM CIRCULATORY COLLAPSE. AS LITTLE AS 15 ML'HAS CAUSED BLINDNESS ;.THE USUAL FATAL DOSE IS; 60 -240 ML. PROLONGED' ASTHENIA AND IRREVERSIBLE EFFECTS ON. THE NERVOUS.: SYSTEM INCLUDING.DIFFICULTY IN:SPEECH,MOTOR DYSFUNCTION.WITH'RIGIDITY,' SPASTICITY;.AND HYPOKINESIS HAVE'BEEN REPORTED. • CHRONIC EXPOSURE- REPEATED INGESTION MAY CAUSE .VISUAL IMPAIRMENT AND OHSLP119 •' PAGE 007 OF 010 BLINDNESS.AND OTHER SYSTEMIC EFFECTS AS DETAILED IN ACUTE INGESTION. , tEPRODUCTIVE EFFECTS HAVE BEEN REPORTED IN ANIMALS. FIRST AID— SEEK MEDICAL ATTENTION IMMEDIATELY. TREAT SYMPTOMATICALLY AND SUPPORTIVELY.' MAINTAIN AIRWAY AND RESPIRATION. IF VOMITING OCCURS, KEEP . HEAD BELOW HIPS TO PREVENT ASPIRATION. IP A POISONOUS SUBSTANCE HAS BEEN INGESTED, REMOVAL BY EMESIS OR GASTRIC LAVAGE WITH APPROPRIATE'PRECAUTIONS TO PREVENT.ASPIRATION.I5 GENERALLY RECOMMENDED PROVIDED THE PATIENT I8 CONSCIOUS, NOT CONVULSING AND.THERE IS NO SIGN OF. CORROSIVE INJURY. ONLY QUALIFIED MEDICAL PERSONNEL SHOULD PERFORM GASTRIC LAVAGE. IF A CORROSIVE SUBSTANCE HAS-BEEN INGESTED,.DILUTION BY RINSING THE MOUTH AND GIVING WATER OR MILK TO,DRINK IS GENERALLY RECOMMENDED. IF PERFORATION HAS OCCURRED OR THE. VICTIM I8 UNCONSCIOUS, THE VICTIM'SHOULD.NOT BE GIVEN ANYTHING TO DRINK. REACTIVITY. REACTIVITY: STABLE UNDER .NORMAL TEMPERATURES-AND PRESSURES. INCOMPATIBILITIES: PHOSPHORIC. ACID:. BASES:- VIOLENT,. REACTION... CHLORIDES + STAINLESS STEEL: REACTS WITH :LIBERATION OF EXPLOSIVE HYDROGEN GAS: FERROUS METALS' AND ALLOYS: VERY'CORROSIVE,..EXPECIALLY WHEN HEATED. GRANITE: ATTACKED BY HOT- CONCENTRATED ACID. . METALS: REACTS, WITH •LIBERATION`OF EXPLOSIVE HYDROGEN GAS. NITROMETHANE: FORMS :DETONABLE MIXTURE. • PLASTICS, RUBBER, COATINGS MAY BE• ATTACKED . 'PORCELAIN: ATTACKED.BY HOT CONCENTRATED ACID. SODIUM TETRAHYDROBORATE: GENERATES HEAT 11ND MAY EXPLOSIVE ON RAPID • MIXING. METHYL ALCOHOL.(METHANOL): ACETYL BROMIDE: VIOLENT REACTION WITH FORMATION OF HYDROGEN BROMIDE. ALKYLALUMINUM.SOLUTIONS: VIOLENT REACTION. . ALUMINUM: CORRODES., 7RIUM PERCHLORATE: DISTILLATION'YIELDS HIGHLY' EXPLOSIVE ALKYL PERCHLORATE. 2YLLIUM HYDRIDE: VIOLENT REACTION,.. EVEN AT -196 C. , wi(OMINE: VIGOROUSLY. EXOTHERMIC. REACTION. CALCIUM CARBIDEi,VIOLENT REACTION. CHLORINE: POSSIBLE IGNITION. AND EXPLOSION HAZARD.. CHLOROFORM AND SODIUM HYDROXIDEz EXPLOSIVE REACTION.. CHROMIUM; TRIOXIDE , (CHROMIC:.ANHYDRIDE)'t.POSSIBLE IGNITION. ., CYANURIC CHLORIDE: VIOLENT REACTION.'. DICHLOROMETHANEF'. POSSIBLE,IGNITION AND EXPLOSION; DIETHYL ZINC: :POSSIBLE IGNITION. AND EXPLOSION," • HYDROGEN PEROXIDE + WATER: EXPLOSION HAZARD:, IODINE + ETHANOL + MERCURIC OXIDE:'CEXPLOSION HAZARD. LEAD: CORRODES:': LEAD PERCHLORATEs. EXPLOSION HAZARD MAGNESIUM: VIOLENT,, REACTION. MAGNESIUM ( POWDERED): MIXTURES ARE CAPABLE OF DETONATION. METALS: INCOMPATIBLE.' NICKEL: P088IBLE;IONITION IN THE' PRESENCE OF NICKEL CATALYST;' NITRIC ACID (CONCENTRATED)s'MIXTURES OF GREATER THAN 25% ACID MAY•DECOMPOSE'. OHSLP119 PAGE 008 OF 010 . IDIZERS (STRONG): FIRE AND EXPLOSION HAZARD.. C tCHLORIC ACID: EXPLOSION HAZARD. 0SPHOROUS TRIOXIDE: POSSIBLE'VIOLENT REACTION AND IGNITION. PLASTICS, RUBBER, COATINGS: MAY BE ATTACKED. POTASSIUM: POSSIBLE DANGEROUS. REACTION. ' POTASSIUM HYDROXIDE + CHLOROFORM: EXOTHERMIC REACTION. POTASSIUM TM- SOMME: FIRE AND EXPLOSION HAZARD. SODIUM +:CHLOROFORM: POSSIBLE EXPLOSION. SODIUM HYPOCHLORITE: EXPLOSION. HAZARD. ' SODIUM METHOXIDE + CHLOROFORM: VIOLENT REACTION. SULFURIC ACID: FIRE AND EXPLOSION HAZARD. ZINC: EXPLOSION HAZARD. DECOMPOSITION: THERMAL .DECOMPOSITION PRODUCTS MAY INCLUDE TOXIC AND HAZARDOUS FUMES OF FORMALDEHYDE AND'OXIDES OF CARBON. . POLYMERIZATION: HAZARDOUS POLYMERIZATION HAS NOT BEEN REPORTED. TO OCCUR UNDER NORMAL TEMPERATURES AND PRESSURES., .•STORAGE AND DISPOSAL OBSERVE ALL FEDERAL, STATE. AND LOCAL REGULATIONS WHEN STORING OR DISPOSING OF THIS SUBSTANCE. FOR ASSISTANCE,;CONTACT THE DISTRICT. DIRECTOR OF THE ENVIRONMENTAL PROTECTION AGENCY: * +STORAGE ** STORE IN ACCORDANCE WITH 29 CFR 1910.1061 KEEP IN A, TIGHTLY CLODED CONTAINER: STORE IN A.000L,•DRY, "VENTILATED AREA BONDING AND GROUNDINO:,SUBSTANCES WITH LOW ELECTROCONDUCTIVITY, WHICH MAY BE IGNITED BY ELECTROSTATIC SPARKS, SHOULD BE STORED.IN,CONTAINERS: WHICH MEET THE BONDING AND'GROUNDING GUIDELINES SPECIFIED IN NFPA 77- 1983, ,MIENDED PRACTICE.ON STATIC ELECTRICITY, : VRE AWAY FROM INCOMPATIBLE SUBSTANCES. * *DISP08AL ** .: DISPOSAL MUST BE,IN.ACCORDANCE.WITH STANDARDS :APPLICABLE'TO' GENERATORS OF HAZARDOUS WASTE;,°40`;CFR 262: EPA HAZARDOU$;.WASTE NUMBER D001..; 100 POUND CERCLA SECTION 103 REPORTABLE 'QUANTITY.• . ' • SPILL AND LEAK PROCEDURES': OCCUPATIONAL .SPILLs', SHUTOFF IGNITION SOURCES, DO NOT TOUCH.SPILLED MATERIAL. STOP 'LEAK yIF YOU', CAN DO IT WITHOUT` RISK.' USE WATER'SPRAY'TO REDUCE. VAPORS. .DO NOT .,GET'WATER' INSIDE CONTAINER. FOR;SMALL SPILLS,: TAKE. UP WITH SAND, OR OTHER ABSORBENT MATERIAL ANDPLACE.INTO :CONTAINERS FOR LATER DISPOSAL, FOR LARGER SPILLS,,; DIKE FAR.ANEAD OF.`BPILL'FOR LATER'DISPOSAL, NO SMOKING, FLAMES OR'FLARES IN,• OHSLP119 PAGE 009 OF 010 RD AREA. KEEP UNNECESSARY PEOPLE AWAY: ISOLATE HAZARD AREA AND DENY ENTRY. etTABLE QUANTITY (RQ)s THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (SARA) SECTION 304 REQUIRES THAT A RELEASE EQUAL TO OR GREATER THAN THE.REPORTABLE QUANTITY ESTABLISHED FOR THAT SUBSTANCE BE IMMEDIATELY:REPORTED TO THE LOCAL EMERGENCY PLANNING COMMITTEE AND THE STATE EMERGENCY RESPONSE COMMISSION (40 CFR 355.40). IF THE RELEASE OF THIS SUBSTANCE IS REPORTABLE UNDER CERCLA SECTION 103, THE NATIONAL RESPONSE CENTER MUST 05 NOTIFIED IMMEDIATELY AT (800) 424 -8802 OR (202) 426 -2675 IN THE METROPOLITAN WASHINGTON, D.C. AREA:(40 CFR.302.6). PROTECTIVE EQUIPMENT VENTILATION: PROVIDE LOCAL EXHAUST VENTILATION TO MEET PUBLISHED EXPOSURE LIMITS.: VENTILATION EQUIPMENT MUST BE EXPLOSION - PROOF. RESPIRATOR: THE .FOLLOWING RESPIRATORS ARE RECOMMENDED BASED ON INFORMATION FOUND IN THE PHYSICAL DATA, TOXICITY AND HEALTH EFFECTS "SECTIONS. THEY ARE RANKED IN ORDER FROM MINIMUM TO MAXIMUM.REBPIRATORY PROTECTION. THE SPECIFIC RESPIRATOR SELECTED:MUST BE. BASED. ON CONTAMINATION LEVELS FOUND ,IN THE WORK PLACE,MUST DE BASED ON THE SPECIFIC OPERATION, MUST NOT EXCEED THE WORKING LIMIT8 OF THE'RESPIRATOR AND MUST BE JOINTLY APPROVED BY THE NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY AND HEALTH. AND THE MINE SAFETY . AND HEALTH ADMINISTRATION (NIOSH- MSHA). ' ANY CHEMICAL CARTRIDGE RESPIRATOR WITH ORGANIC VAPOR CARTRIDGE($) AND A' FULL FACEPIECE. ANY OAS MASK WITH ORGANIC VAPOR CANISTER '(CHIN-STYLE OR FRONT- OR • BACK - MOUNTED CANISTER), WITH A FULL FACEPIECE.. ANY TYPE 'C' SUPPLIED -AIR RESPIRATOR WITH A FULL FACEPIECE OPERATED IN PRESSURE- DEMAND OR OTHER POSITIVE PRESSURE MODE OR WITH A PULL FACEPIECE,:;, HELMET OR HOOD OPERATED IN A CONTINUOUS -FLOW MODE, : . ! SELF - CONTAINED BREATHING :APPARATUS WITH A FULL FACEPIECE OPERATED IN.. •- PRESSURE- DEMAND.OR OTHER POSITIVE PRESSURE MODE. FOR FIREFIGHTING AND OTHER IMMEDIATELY DANGEROUS TO LIFE OR HEALTH CONDITIONS: ANY SELF - CONTAINED BREATHING APPARATUS THAT HAS A FULL FACEPIECE OPERATED IN. A. PRESSURE - DEMAND. OR .OTHER POSITIVE- PRESSURE MODE. ANY SUPPLIED- AIR•RESPIRATOR'THAT.HAS :A'FULL,FACEPIECE'AND IS'OPERATED..IN A: PRESSURE - DEMAND OROTHER POSITIVE - PRESSURE. MODE IN'COMBINATION.WITH AN.' AUXILIARY. SELF- CONTAINED BREATHING APPARATUS OPERATED.IN PRESSURE- DEMAND OR OTHER POSITIVE - PRESSURE MODE. CLOTHING: • EMPLOYEE MUST WEAR APPROPRIATE PROTECTIVE,(IMPERVIOUS) CLOTHING.AND „EQUIPMENT. TO PREVENT ANY POSSIBILITY OF SKIN CONTACT WITH THISSUBSTANCE,' ANY CLOTHING WET WITH A FLAMMABLE. LIQUID SHOULD BE IMMEDIATELY'REMOVED'AT. THE LOCATION WHERE;IT.IS'WETTED TO PREVENT BURNS FROM POSSIBLE IGNITION, OHSLP119 PAGE 010 OP 010 -WEE MUST WEAR APPROPRIATE PROTECTIVE GLOVES TO PREVENT CONTACT WITH THIS 8 BSTANCE. EYE PROTECTION: EMPLOYEE MUST WEAR SPLASH -PROOF OR DUST - RESISTANT SAFETY GOGGLES AND A FACESHIELD TO PREVENT CONTACT WITH THIS SUBSTANCE. . EMERGENCY WASH FACILITIES: WHERE THERE IS ANY POSSIBILITY THAT AN EMPLOYEE'S EYES AND /OR SKIN MAY BE, EXPOSED TO THIS SUBSTANCE, THE EMPLOYER SHOULD PROVIDE AN EYE WASH. FOUNTAIN AND QUICK DRENCH SHOWER WITHIN THE IMMEDIATE WORK AREA FOR EMERGENCY USE. 1993 OCCUPATIONAL HEALTH SERVICES, INC.. ALL RIGHTS RESERVED. CREATION DATEt 03 /21/91 REVISION DATE:. 12/04/92 J.J. 14:1.1 L N I Cl3KH Lunrl -Ul r 112 .. 1 OODB do: • atlta • Pilaff ptip 1 1 . • nor: OF: id, •' yi ' . illLLaL3nIEIiBHH Ud:_�11��J.. 1 • b • INTEGRA CHEMICAL COMPANY to Oaa. of Emergency. calf: oHearnato Docfrax443013. 710Tho(nas AV'ta SW; Renton, WA 90055 Phone: 208 - 277.8244 FAX ZO84ZTT'9O48 • Chemical Name • .,t. ',' MINERAL OIL, HEAVY 8042747-51 . . channel Panda and rowan Wallin , Uadefieed Mineral OU 8042 -49 -3 >99 OSHA PEL3sg! 3; ACOIH TLV:3.1f 3; STEM 10mghs3 • • _-� (Recommend std limits for oil mists) ' , �'. l; .'1!; .... ,1 ....'..,.I•:..:1t'.:L.1,: Bolin/ Pcnit Or Bangs > SW I., ir LI1 !'.;;'1• 1.Ie�,.'I'Ll!;.;G'.I; {{ �::. ;.:1q:.., .. '1: 'i' .1 L' :ee1':.•;t sU; i:'i!''al'11;I.,1- '' upestiH Osae0y 0120 -1) 0.145.0.903 apor Prmeuw (mw Ho) e 1 i Vapor Density (mot) Eeepora6an Rake No data c 1 w7 • Warr 1' Odin tsoleouny n 1100: i • awls • - a - . C mar oraar nia ugali, 1. 1 '.:r /.r, �1:. .... .... ... .... ...I. .f'. 1. ■:7.J l:: Li '1; .1 �.1. i1... 111 •4. ■1• .1.. Flap Post `am Vaned PI. ■mab4e I.tmits In ah (% try vcluiw) •400= 420 leg P COC U r No data Lower: No data q 1Qltttlir • y at 'l'' a8 s of den Arsto-faidgon Tramparallum Nedata • E itnainin0 Media t_._1 Wain Eptsy l Water Fag IIII Water Strata 002 11] t1y Chem in P] Ab0h01 Porte E] Foam [J isnh or 81nd (3par:fy)s o sot we water to tight lira I • Sparli l Fin Fighting Prowduns • Co Not Enka Balding ❑ Co Not Wafter ❑ Allow iirs*, Ban • • pg ottaa Asa* I Wear tall protective eh:ali is and breathing apparatus. • uouesral Firs & Explosion slon hands ❑ -Dust Evasion Phzstd i Cense:No 10 Mesh 0 Oars manning C) itrNlpe4" in • (Cpetijl: ;)lone. . .. , , ••• , .. '., 1:, .11.. I.:;� {^.1:. .: r,I"111;.,191,..1! ILn1 '11 ... - . • I. ..1d ..1 I , �, '.; .1 tit •e111 '91 j1:I1r >llal,. , rt' 8ta6Aity Hazardous Polymatratlon Conditions Connitwrng no . • . tfq PI bane Q (?Amiable/ 0 Cut Ocna Ell Wti not occur 0 Metmai Deoomp:shim [] Phew DegIaduen [ oitiot. 1 tnoompsltQilty - A,y'oid Contact Witty: L;7 ° Strong Ands i 0 Snag Mca,1n r] 9bvno Oxidizes 0 t81w1: • r— - • . • . - • • . Yt . ' rodacta - Thar.a and o • n: '^ May liberate COn a,ta os deoonpoaftios■ plains mar prod *Ce :mammon,, esilsarltls4 anima ooaposads. t( I .lJ�'II, L: �.� �. .I,,.�...A:':Lr ..!.:.1 .': )lims. •1. -: 1:: .1.:;1; 111.. e.;ri'I:I'"'9 rr tt A �' :: Y6 4'.: 174 p1''i: 11.11.':9 11R; l i'',1 . 1'1,''1. r • i. tfQ � r1a wt ✓ t Of hart Ware Waren Neutralize 12 =t5orri+iier pro P] Pn,ws! Baran of ttpil ❑ Otar (dpaolY)• 'NAME DPSPOCAiIMi;RHOD - Goan* Fodtual, State tad Lout Regulation for proper dtapoui EjAddlfuusl f7o{iwll iwtruabrte 1 UL t-. 1 :;./G 111 U14-1 LU1' HI 1 11 m ip , :. itilmAtcpuimpporr , • . ; . • I *. . • • .1.1Paps 2. ' • "• " " ' • ' '. ' .t ..., ::, ,..., ',.'•:. . ,.; ...• .. . .., . ', ., , . ,:• , : - .. . ' .. , TINvebeld z • • .1 Lions (TM: TIN& et0): See oration 2, II/sado= bindle:no • • 8Igas, Symptom dad Mao= of Mute ropootons: DenSal: No= eon= tly koona. . ' I ' • —. •• ; ,.I ".11 ; • ' . • I • I • , • II , SymapIemmi • - ro • No specific lafornattoa available. • GISININ011 Listed riolloil Or POWWOW CaraillOgre SY: 8Yee womdtdookor pogrom Ei Yea E V" L A. R. C. I/magmata OSHA NI Olken . No NO No • • •— • m : 0*, 1111P0110 I. Sasargesay Pivot Aid • rzi Woos YomaIng p2 Minot MOO= Ifomerg EJ took ModadAsslitanco INGO:RIC/11 17i] Odom (eptory): If Irritation or adverse ryaptosts develop, seek medical avast/am . I • • • i • 1,:il Flush =thecae end =ear ID Cask Medical Ataidanuo SKIN 00WfACT ca Other (Specify): If irritation @vela's, seek medical attention. . , •' • ' EYE; OONTACT RI Mush vitt, mew Ox at kwat 15 minnow pli Set* Medical Asaistrnoe ' in Maar Otpecify): If ire tidos inalops, seek myeloid *mottos. . . . I czi lifi4vtot=k;00;ostion 1-11 noodhloti a ANSA in grog meow Ankomno,. • lento= to truth sa INHALATION lar•-1 tekrantsesr moon 0 Cesar Wady): . . ' . . - • ' • • . . , .......•:.' . . , 1 1,, .1.: ••••.'•• ; • 1 ;:14,,'1:11.'1,:f.1:11..•.:). :'.2; .• : ' t- •":'" '' ' .. . . . . • Heeptratory Pinta:row - Una only NIOSH/MESA applinted ettalpateal ' ..,„..1 - I r.-.1 ggv.ccji6kod Li moose Roposor • Cortrkge moan vapor savintor III Combhodon vont/ilf ii OttoaNed Nr liolthilethr 11,.....,1 assignoppponagps . ca. Oar (peory):1 Hone needed soles, sae generate* tall/aloe =pen. . . • ifooNfolissio Ezi ta.1.4.44500,,,,41 m crLOOlgutorpOtiletkiiiy Hood • !Lida dreonternitation L.,j I-1 slatad (SPoellYit c:j Clhee(SpoollY):1 i. • Eyda Protection 1 Weston" Mono j • Stdvalt Goggles IIII raw Otiold Hand Protectios (glove typo) • [2 PVC) PI Neapran* CZ1 [Ikea Pg Iblialvileol! 1, 0 ethic 1 . --i. . • "'"77-."1 -0•71.• a 0, ...• 04,0•0 :,. ow 0% cad safety altaufm Weep , • .LC30 3 . at. - peaeallo . nm• apneas. • . . " , : : ' f ■ • • 1 ' ' ' ' . • . . , • • , • i ' s , t , . ', ':-! • i7,'...1.1, . :,),::1■ • 1. 1 I , ! I ."• r. •!1,:t1 14,11 X r1,' !'4'.1':-1,-1.! • ;h.: :I ■,..'.'.*:-.1.,!,;',....,.,1,;: ,,I,.1,17,,., ,!!,', , „ ., , , , , „ ,.. L ., , .. . . . STONACH AREA: , (21 tif.AVYSIL 0 FLAIIMAIII.eLAVO MI HANMABLESOM,1141-67/15WME ' III ■ c7AS9t250•E ACM • CORMS/Vi B4 • OVVIIER El 0470122,10 WOO r::: I iiesuv44zmiro , • 'r Storage • •• • 1 ! • nen . • • tm • • a coo . ry, we • • • Aura:sway .• clubmen •• • "Sr, • seamen • • • - cossuntos • • • • 1-r'l • dassose tad fon aproe so b , . of ifivealiskt. i . 001 Hazard Classification: Nat xezilated . • • . • ' • . . . UM Yos This yrocIud minas sonata:it at atonic/do. *sifted%) the repotting toquIvernonts of sedan allitlials Mei the CaPelforld SARA Lisdng azi No Amervinents end Reetshonzaion Antal 190S and 40 CFTI PeetS7IL, i • 1'1•1•.:.' , ., !' . :4', ;...,..- 1,11;';•j.,1•.,:r•4:'•••`,214.,1•tit;:iiii..ifIrilii•I•10.I..:*•;■, 1 t tt •• • - • ..; ; I t 1 '1 t• :Intl -;.1,,••••••:;:i‘it'j 4.•)0.1;8:..t:1(•j),1"431,1111:,t.I.O. 1,1,11„,i,..t ( ,•,1. I:11.1,1;i ',.'' :•,1',' ;i• 1 ,, .1, ' ,.1:.1...:i',.k:1.1'.1..lr..1.) ti a 1/.112:4("544 ktAlLsithigE4719:0111I . . ' ;)'‘ItAll:Sil;14iltiA • • • • .,W „wU Li,--am u ■..0 rrtuu uvuu i u vieube ilvo cv Material Safety Data Sheet DEERE & COMPANY John Deere Road Moline, Illinois 61265 (309) 766-2767 (309) 765.4292 Emergency JOHN DEERE PRODUCT NAME: Moly High- Temperature W Grease DATA SKEET NO: 8503- 40,060 LATEST REVISION DATE: 15 Feb. 1989 DEERE MDR: XJ JDR PART NO: TY6333, TY8347 SECTION I - PRODUCT IDENTIFICATION CUBICAL NAME AND SYNONYMS: Lubricating Grease • CHEMICAL FAMILY: Hydrocarbon FORMULA: Complex SECTION II - HAZARDOUS INGREDIENTS INUREMENT C TLV /?BL V. . CAS, =, Severely hydrotreated, heavy aaphthenic distillate 05 -70 5 mg /m * - 84742525 12- bydroay atearic acid 10 -I5 None - 108149 Lithium hydroxide 5 -10 None - 1310852 Ant iaony 0,0 -dialkylphos- phorodithloate 2- 5 None 3 - 15874488 Molybdenum disulfide 2- 5 5 ag /m - 1317335 Azelaio acid 1- 3 None - 123999 Additive package ** 1- 3 None - Mixture for oil mists ** manufacturer states this component is propietary SECTION III PHYSICAL DATA BOILING POINT: >7O0°F X VOLATILE VOLUME: Not applicable VAPOR DENSITY: Unknown APPEARANCE /ODOR: dark grey /petroleum FLASH POINT: >400 °F SP. GRAvITY (KATEiiu]) : 0.89 EVAPORATION RATE: Not applicable SOLUBILITY IN WATER: Negligible SECTION IV FIRE 8 EXPLOSION HAZARD DATA FLAMMABLE LIMIT - LEL: Unknown EXTINGUISHING MEDIA: Water fog, foam, dry chemical, carbon dioxide SPECIAL FIRE FIGHTING PROCEDURES: None UNUSUAL FIRE 4 EXPLOSION HAZARDS: Nome AMM. •M • MATERIAL SAFETY DATA SHEET PENNZOIL PRODUCTS COMPANY T E.1:.C:ATION; Emergency Telephone No. Trade Name PENNZOIL COMPANY P.O. BOX 2967 HOUSTON, TEXAS 77252 -2967 (713) 236 -6070 CAS Number: MIXTURE MS DS Code: 000275 NFPA Hazard Identification Degree of Hazard Hazard Ratings Health: 1 Fire: 1 Reactivity: 0 - Least 1 - Slight 2 - Moderate 3 - High 4 - Extreme PENNZOIL() MULTI - PURPOSE GEAR LUBRICANT 4096 MULTI - SERVICE LS 80W -90 COMPONENT NAME HAZARDOUS CAS NUMBER IN BLEND BASE LUBRICATING OILS MIXTURE POUR POINT:DEPRESOANT: • TRADE SECRET:.:..., FRICTION MODIFIER TRADE SECRET ANTIFOAM- ADDITIVE DETERGENT /INHIBITOR SYSTEM TRADE SECRET NO NO NO No NO PERCENTAGE MIN MAX 05.00 TO COMPONENT EXPOSURE LIMITS UNITS OSHA PEL NO LIMIT 95.00 ACGIH TLV NO LIMIT .'..:;'OSHA PEL :''::: 1: ; °..: rNO..'CIMIT.!;:.;. c .. :5r00.:: ACOIH.:.TLV:::..;L:' i:.::::;:.i...i:, :'i.NO,>LIMIT., OSHA PEL NO LIMIT c 5.00 ACGIH TLV NO LIMIT OSHA PEL NO LIMIT 'r` 0 .01...:..:...ACGIH TLV':i. ,•.... ..._ NO; LIMIT : OSHA PEL NO LIMIT 5.00 ACGIH TLV NO LIMIT BY: EUIi2OUfl HTAL a SAFETY & HEALTH (113) 546 -6227 EFFECTIVE DATE:: DECEMBER 27,;:' 1991 • OZwCL,INCR OF WARRANTY: Tl; o*ArAT r,JJJJ coJIT 11HEO HEREIN 15 BASED UPON DATA AVAILABLE TO US, AND REFLECTS OUR BEST PROFESSIONAL ' ' rd .1%, THE ACCURACY OF SUCH DATA, THE RESULTS TO BE ODTA/NED FROM THE USE THEREOF. OR THAT ANY .J/fKF v i fF RRJyJIIR�T/,NOL ANY WHICH WE MAY INFORMATION CONTAINED HEREIN ASUME ANYPRESPONSIBILITY CONDITIONS THE Col t�k,( iff5 friWa+d frfl t #u 1QH Of THE INFORMATION OF FURNISHED RIALOFOR HIS PARTICULAR PURPOSE�RSON RECEIVING IT SHALL Myrif [JAr`,f; f till . AFL1Y AHD HEALTH REGULATIONS FOR SHIP REPAIRING, SHIPBUILDING, AND SHIPBREAKING MSOS CODE: 000275 PRODUCT: PENNZOIL U9 MULTI - PURPOSE GEAR LUBRICANT 4096 PAGE 2 OF 6 QN....,....:. .:�.,:.';<•:-::•: <;:::•: ::C h HEALTH..,E� .�:C.: INFORMATI : EYE CONTACT THIS PRODUCT IS PRACTICALLY NON - IRRITATING TO THE EVES UPON DIRECT CONTACT. BASED ON TESTING OF SIMILAR PRODUCTS AND /OR COMPONENTS. SKIN CONTACT BSED CONTACT. I PRODUCT MAY CAUSE SKIN DIRECT ON TESTING OF SMILRPRODUCT AND OROMPONENT.ROLOGED UPON R REPEATED CONTACT MAY RESULT IN CONTACT DERMATITIS WHICH IS CHARACTERIZED BV DRYNESS, CHAPPING, AND REDDENING. THIS CONDITION MAY MAKE THE SKIN MORE SUSCEPTIBLE TO OTHER IRRITANTS. SENSITIZERS. AND DISEASE. PROLONGED OR REPEATED CONTACT MAY RESULT IN OIL ACNE WHICH IS CHARACTERIZED BY BLACKHEADS WITH POSSIBLE SECONDARY INFECTION. SEE HEALTH DATA SECTION BELOW. INHALATION THIS PRODUCT HAS A LOW VAPOR PRESSURE AND IS NOT EXPECTED TO PRESENT AN INHALATION HAZARD AT AMBIENT CONDITIONS. CAUTION SHOULD BE TAKEN TO PREVENT AEROSOLIZATION OR MISTING OF THIS PRODUCT. THE PERMISSABLE EXPOSURE LIMIT (PEL) AND THRESHOLD LIMIT VALUE (TLV) FOR THIS PRODUCT AS OIL MIST IS 5 MG /M3. EXPOSURES BELOW 5 MG /M3 APPEAR TO BE WITHOUT SIGNIFICANT HEALTH RISK. THE SHORT -TERM EXPOSURE LIMIT FOR T1HIS PRODUCT AS AN OIL MIST IS 10 MG /M3. • INGESTION DO NOT INGEST. THIS PRODUCT IS RELATIVELY NON - TOXIC BY INGESTION. THIS PRODUCT HAS LAXATIVE PROPERTIES AND MAY RESULT IN ABDOMINAL CRAMPS AND DIARRHEA. SEE HEALTH DATA SECTION BELOW. D HEALTH DATA DISEASE SUCHSASNCHR NICOLUNG LRMEMATATIOEND ISSUSUALLY OOMAF RESULT OF REPEATED SMALL ASPIRATIONS. SHORTNESS OF BREATH AND COUGH ARE THE MOST COMMON SYMPTOMS. THE INTERNATIONAL AGENCY FOR RESEARCH ON CANCER HAS CONCLUDED THAT HIGHLY REFINED MINERAL OILS ARE GROUP 3'SUBSTANCES, "NOT CLASSIFIABLE AS TO THEIR CARCINOGENICITY TO HUMANS," BASED ON INADEQUATE HUMAN AND INADEQUATE ANIMAL EVIDENCE. THIS SUBSTANCE IS NOT CARCINOGENIC ACCORDING TO THE OSHA HAZARD COMMUNICATION STANDARD. MSDS CODE: 000275 PRODUCT: PENNZOIL() MULTI-PURPOSE GEAR LUBRICANT 4096 PAGE 3 OF 6 ERGENC 4#, • EYE CONTACT /MMEDIATELV FLUSH EVES WITH LARGE AMOUNTS OF WATER AND CONTINUE FLUSHING UNTIL IRRITATION SUBSIDES. IF MATERIAL IS HOT, TREAT FOR THERMAL BURNS AND TAKE VICTIM TO HOSPITAL IMMEDIATELY. SKIN CONTACT . ...:REMOVE'CONTAMINATED.CLOTHING. WASH CONTAMINATED AREA THOROUGHLY WITH SOAP AND WATER..IF REDNESS OR IRRITATION OCCURS, SEEK .MEDICAL ATTENTION :.IF MATERIAL IS HOT,."SUSMERGE INJURED AREA IN COLD WATER. IF VICTIM IS SEVERELY BURNEDr.REMOVETO'AHOSPITALIMMEDIATELY.:: • • • INHALATION THIS MATERIAL.HAS A LOW VAPOR PRESSURE AND ISNOT EXPECTED SXPOSURSAT AMBIENT CONDITIONS. TO PREBENT%AllINHALATION • 1 , • , , • • INGESTION DO NOT:iNDUCE VOMITING. SEEK',MEDICALATTENTION. MSDS CO[SE: 000275 .PERSONA PRODUCT: PENNZOIL@ MULTI - PURPOSE GEAR LUBRICANT 4096 PAGE 4 OF 6 OTEG :TI FORMATE( EYE PROTECTION EYE PROTECTION IS NOT REQUIRED UNDER CONDITIONS OF NORMAL USE. IF MATERIAL IS HANDLED SUCH THAT IT COULD..BE SPLASHED INTO EYES, WEAR PLASTIC FACE SHIELD OR SPLASH -PROOF SAFETY GOGGLES'. SKIN PROTECTION NO SKIN PROTECTION IS REQUIRED FOR SINGLE, SHORT DURATION EXPOSURES. FOR PROLONGED OR REPEATED EXPOSURES, USE IMPERVIOUS CLOTHING (BOOTS. GLOVES. APRONS, ETC.), OVER PARTS OF THE BODY SUBJECT TO EXPOSURE. IF HANDLING HOT MATERIAL, 'USE INSULATED PROTECTIVE CLOTHING (BOOTS. GLOVES. APRONS. ETC.'). LAUNDER SOILED CLOTHES. PROPERLY DISPOSE OF CONTAMINATED LEATHER ARTICLES INCLUDING SHOES, WHICH CANNOT BE OECONTAMINATED, RESPIRATORY PROTECTION .RESPIRATORY PROTECTION IS NOT REQUIRED'UNDER CONDITIONS OF NORMAL USE. IF VAPOR•OR MIST IS GENERATED WHEN THE MATERIAL IS :HEATED OR HANDLED. USE AN ORGANIC VAPOR'RESPIRATORWITH A DUST AND • MIST FILTER. ALL RESPIRATORS MUST. BE NIOSH CERTIFIED. DO NOT USE COMPRESSED • OXYGEN IN HVDROCARBON ATMOSPHERES. VENTILATION iF VAPOR OR MIST IS GENERATED WHEN THE MATERIAL IS HEATED OR HANDLED." ADEQUATE VENTILATION IN ACCORDANCE WITH GOOD ENGINEERING PRACTICE. MUST BE PROVX000 70 MAINTAIN CONCENTRATIONS BELOW THE.SPECIFIED'EXPOSURE OR FLAMMABLE. LIMITS. OTHER • •.CONSUMPTION OF F000 AND BEVERAGE-SHOULD BE.AVOIDED IN WORK AREAS WHERE HYDROCARBONS ARE, PRESENT.:: ALWAYS: WASH. HANDS AND:FACE WITHSOAP:AND:WATER BEFORE. EATING,' DRINKING, OR MSDS CODE: 000275 PRODUCT: PENNZOIL() MULTI- PURPOSE GEAR LUBRICANT 4096 PAGE 5 OF 6 ' <:%' Y is <4 •. �.:•..Ili'�, f 1 •::.. . ,�...,.:: n < •• :l ' i•s : 1 ,;,4.4. . %OTECT O�9 O. f2y. :E E • :i : r.. .. FLASH POINT >30B F TEST METHOD• c.O.c. • AUTOIGNITION TEMPERATURE > Boo F TEST METHOD NO DATA FLAMMABLE LIMITS IN AIR % BY VOL LOWER NO DATA UPPER NO DATA EXTINGUISHING USE DRY CHEMICAL, FOAM, OR CARBON DIOXIDE. MEDIA SPECIAL FIRE WATER MAY BE INEFFECTIVE BUT CAN BE USED TO COOL CONTAINERS EXPOSED TO MEAT FIGHTING CAUTION SHOULD BE EXERCISED WHEN USING WATER OR FOAM AS FROTHING MAY OCCUR, SPRAYED INTO.CONTAINERS OF HOT, BURNING LIQUID. PROCEDURES OR FLAME. ESPECIALLY IF UNUSUAL FIRE DENSE SMOKE MAV BE GENERATED WHILE BURNING. CARBON MONOXIDE, CARBON DIOXIDE, AND EXPLOSIVE OXIDES MAV BE GENERATED AS PRODUCTS OF COMBUSTION. CONDITIONS AND OTHER' :• i i5. .;:Q:�� !;i.' :;:fait `:UI:i:' �REACTIVI:TY:DATA•� ,:. STABILITY STABLE (THERMAL, LIGHT, ETC.) CONDITIONS TO NONE AVOID HAZARDOUS . OT OCCUR POLYMERIZATION CONDITIONS TO NONE AVOID INCOMPATIBILITY MAY REACT WITH STRONG OXIDIZING AGENTS MATERIALS TO AVOID HAZARDOUS DECOMPOSITION NON PRODUCTS MSUS CODE: 000275 PRODUCT: PENNZOIL® MULTI - PURPOSE GEAR LUBRICANT 4096 PAGE 6 OF 6 . �:: V IRO NPE ECA U T O ... .: i :. : :t {.• '•JJ rJ STEPS TO BE CONSULT HEALTH EFFECT INFORMATION IN SECTION III. PERSONAL HEALTH PROTECTION INFORMATION TAKEN IF IN SECTION V, FIRE PROTECTION INFORMATION IN SECTION VI. AND REACTIVITY DATA IN SECTION Vii. NOTIFY APPROPRIATE AUTHORITIES OF SPILL. CONTAIN SPILL IMMEDIATELY. DO NOT ALLOW MATERIAL IS SPILL TO ENTER SEWERS OR WATERCOURSES. REMOVE ALL SOURCES OF IGNITION. ABSORB WITH RELEASED OR APPROPRIATE SUCH CEPRM PICKED SING VACUUM PUMPS, SHOVELS, BUCKETS OR OTHER M ANS AND PLAEDINDUMSOR OTHER SUITABLE SPILLED CONTAINERS. WASTE DISPOSAL ALL DISPOSALS MUST COMPLY WITH FEDERAL, STATE, AND LOCAL REGULATIONS. THE MATERIAL, IF METHOD SPILLED OR DISCARDED, MAY BE A REGULATED WASTE. REFER TO STATE AND LOCAL REGULATIONS. CAUTION! IF REGULATED SOLVENTS ARE USED TO CLEAN UP SPILLED MATERIAL, THE RESULTING WASTE MIXTURE MAV BE REGULATED. DEPARTMENT OF TRANSPORTATION (DOT) REGULATIONS MAV APPLV FOR TRANSPORTING THIS MATERIAL WHEN SPILLED. WASTE MATERIAL MAY BE LANOFILLED OR INCINERATED AT AN APPROVED FACILITY. MATERIALS SHOULD BE RECYCLED IF POSSIBLE. : ✓f Y d: ..4 :SCELL N� U.S� <- • iii:.v. :a o: ">' 4 t .o r•.. •t,•' J t� HANDLING AND DO NOT TRANSFER TO UNMARKED CONTAINERS. STORE IN CLOSED CONTAINERS AWAV FROM HEAT, SPARKS, STORAGE OPEN FLAME. OR OXIDIZING MATERIALS. THIS PRODUCT IS NOT CLASSIFIED AS HAZARDOUS UNDER DOT REGULATIONS. FIRE EXTINGUISHERS SHOULD BE KEPT READILY AVAILABLE. SEE NFPA 30 AND OSHA REQUIREMENTS 1910.106 -- FLAMMABLE AND COMBUSTIBLE LIQUIDS. • ADDITIONAL THIS MIXTURE MAV BE FORMULATED IN PART WITH COMPONENTS PURCHASED FROM OTHER COMPANIES. IN INFORMATION MANY INSTANCES. ESPECIALLY WHEN PROPRIETARY OR TRADE SECRET MATERIALS ARE USED. PENNZOIL COMPANY MUST RELY UPON THE HAZARD EVALUATION OF SUCH COMPONENT SUBMITTED TO PENNZOIL BY THAT PRODUCT'S MANUFACTURER OR IMPORTER. THIS PRODUCT IS NOT KNOWN TO CONTAIN ANY SARA TITLE III, SECTION 313 REPORTABLE CHEMICALS AT OR GREATER THAN 1.0Z (0.1X FOR CARCINOGENS). r. .....,$,.. :J.. , r. . .t. t• M1 J• :y:!. t;7tti ..::.::. ::...PHY.ST'CAL• .}�y! AERTI': BOILING POINT > 800 F PERCENT VOLATILE N/A MELTING POINT - 10 F VAPOR DENSITY (AIR •1) N/A APPEARANCE CLEAR, DARK RED EVAPORATION RATE (EE ■1) N/A ODOR MILD SULFUR ODOR SPECIFIC GRAVITY 0.896 VAPOR PRESSURE N/A MOLECULAR WEIGHT VARIES SOLUBILITY SOLUBLE IN HYDROCARBONS OxyC,Nem. MATERIAL SAFETY DATA SHEET MSDS NUMBER : M7695 MSDS DATE • 06 -21 -89 PRODUCT NAME : MURIATIC ACID 20 COMMERCIAL 24 HOUR EMERGENCY PHONE: (7 16) 278-7021 I. PRODUCT IDENTIFICATION HMIS HAZARD RATINGS HEALTH HAZARD 3 FIRE HAZARD 0 REACTIVITY 2 Based on the National Paint & Coatings Association HMIS rating system. SARA /TITLE III HAZARD CATEGORIES (See Section X) Immediate (ACUTE) Health: YES Delayed (Chronic) Health: NO Fire IHIazard : NO Reactive Hazard : YES Sudden Release of Pressure: NO MANUFACTURER'S: NAME AND ADDRESS Occidental Chemical Corporation Customer Service. Occidental Tower, P 0 Box 809050, Dallas, Texas 75380 Telephone (1- 800 -752 -5 15 1 ) CHEMICAL NAME: Hydrochloric Acid CAS NUMBER: 7647 -01 -0 SYNONYMS /COMMON NAMES: MC1: Aqueous Hydrogen Chloride, Muriatic Acid CHEMICAL FORMULA: MC 1 DOT PROPER SHIPPING NAME: (-Hydrochloric Acid DOT HAZARD CLASS: Corrosive M erial DOT I,D. NUMBER: UN1789 DOT HAZARDOUS SUBSTANCE: Rf35000// II. HEALTH HAZARD INFORMATION EMERGENCY AND FIRST AID PROCEDURES EYES: 0BUECT 1S TO FLUSH MATERIAL OUT IMMEDIATELY TI•IEN SEEK MEDICAL ATTENTION. IMMEDIATELY flush eyes with large amounts of water For at least 15 minutes holding lids apart to ensure flushing of the entire eye surface. Washing eyes within seconds is essential to achieve maximum effectiveness. SEEK MEDICAL ATTENTION IMMEDIATELY. SKIN: IMMEDIATELY wash contaminated areas with plenty of soap and water for at least 15 minutes. A 'soothing ointment may be applied to irritated skin after thorough cleansing. Remove contaminated clothing and footwear and wash clothing before reuse. Discard footwear which cannot be decontaminated. SEEK MEDICAL ATTENTION IMMEDIATELY. CAS • Chemical Abstract S.rvSCO Nunher NO ' • No relevant Information found or not available rill • OSHA Pernlsslble topes ur• time% COMP • Corporate topesure tenet 1tS a •COIN Ihr.fhold limit Value, Currant • • tee Chronic t•Ieels rnform.tl.n N1 • Not applicable INP0al&Nle the Informatlen Pr•senteu heraln 'h% %• not p$•rent..U, vas prepared by competent teuhnlcal personnel and IS true end actor Ate so the best of our t.nowl.d0e. NO w 1r, Oa CUa0ANfr, tNPa0S1 OR IHP1.110 IS NAOS 010ao01N0 HAMC1. SIAS1tIIY, Oa OIN1Aw If1 tnls Inlorm•Ilon 10 not Intended to be •II.InClu$ly• •s le She manner and c.ndltlans el use, nanulin0 anti Stora0e. Otn0r (*C.O.'S nay 11,v•Ive oSher or •,luellen.l art.•.. n. ........... our %.€Intel no • • • . • OCCtDENTAL CHEMICAL MSDS NUMBER: M7695 PRODUCT NAME: MURIATIC ACID 20 COMMERCIAL Page 2 of 9 . 06 -21 -89 H. HEALTH HAZARD INFORMATION (Continued) INHALATION: Remove to fresh air; if breathing is difficult, have trained Person administer oxygen. If respiration stops, give mouth -to -mouth resuscitation. GET MEDICAL ATTENTION. INGESTION: NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water, If available. give several glasses of milk. Keep airway clear. SEEK MEDICAL ATTENTION IMMEDIATELY. ROUTES OF EXPOSURE INHALATION: Inhalation of gas, mist, fog, or spray will cause severe irritation of the upper respiratory tract. resulting in coughing, burning of the throat. and a choking sensation. If inhaled deeply, edema of the lungs may occur-. SKIN: Irritating and corrosive to skin and can cause severe burns if not promptly washed off. Repeated contact of the skin may lead to the development of dermatitis. EYE CONTACT: This product rapidly causes severe irritation of the eyes and eyelids. If the acid is not quickly removed by thorough irrigation with water, there may be prolonged or permanent visual impairment or total loss of sight. Hydrogen chloride gas escaping from the aqueous solution is immediately irritating to the eyes. INGESTION: This product causes severe burns of mucous membranes of the mouth, esophagus, and stomach if swallowed. EFFECTS OF OVEREXPOSURE ACUTE: Strongly irritating and corrosive to the eyes. digestive system. Vapors are irritating to tract: excessive exposure may cause more including pulmonary edema. skin, mouth, and the respiratory severe symptoms The local dermal effect may consist of multiple areas of superficial destruction of the skin or of primary irritant dermatitis. Similarly. inhalation of spray, mist, or vapor may result in varying degrees of irritation or damage to the respiratory tract tissues and an increased susceptibility to respiratory illness. Prolonged or repeated exposure to concentrations in excess of the TLV may cause discoloration and /or erosion of the teeth. CHRONIC: No known chronic health effects. FIEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Any acute or chronic respiratory TOXICOLOGY DATA: (as HC1) Acute Oral Toxicity; Acute Dermal Toxicity: Acute Inhalation Toxicity; Corrosivity: condition. L050 (rat) LD50 .(rabbit) LC50 (rat, 1hr) (rabbit) Corrosivity: (rabbit) 700 (mg/kg >5.01 mg/kg 3 124 ppm 0,01%-15% Concentration Non- Corrosive > 15% Concentration Corrosive • OCCIDENTAL CHEMICAL MSDS NUMBER:. M7695 PRODUCT NAME: MURIATIC ACID 20 COMMERCIAL Page 3 of 9 06 -21 -89 111. IMPORTANT COMPONENTS CAS NUMBER / NAME 7647010 Hydrochloric acid EXPOSURE LIMITS PERCENTAGE PEL =5 ppm; 7 mg /m3, Ceiling VOL 18 -19.60 TLV =5 ppm; 7.5 mg /m3, Ceiling WT 31 -33 COMMON NAMES: HYDROGEN CHLORIDE Listed On(List Legend Below): 0 1 02 13 16 18 7732185 Water EXPOSURE LIMITS PE1_ =Not Established TLV =Not Established COMMON NAMES: Listed On(List Legend Below): 19 PERCENTAGE VOL 80.40 -82 WT 67 -69. 7782505 Chlorine EXPOSURE LIMITS 'PEL =0 . 5 . ppm T.5 mg /m3 TWA. STEL 1 ppm; 3 mg /m3 •LV =0.5ppm; 1.5 mg /m3,TWA ::STEL= 1 ppm: 3 mg/m3 COMMON NAMES: Listed On(List Legend Below): 0 1 02 13 16 18 PERCENTAGE VOL WT 3PPM 100PPM ND See Section II All components of this product. that .are required to be :,.Inventory are listed on. the inventory. Not listed•as carcinogen - 1ARC. NTP, OSHA LIST•LEGEND 1. SARA EXTR HAZ SUB, SECTION 302 13 PA ENVIROMENTAL HAZ•SUBSTANCE. .18 NY.I-IAZARDOUS SUBSTANCES.. on the TSCA 2 SARA TOXIC.CHEM, ".SECTION•313 • 16 NJ. WORKPLACE HAZ- SUBSTANCE LST 19 PA REQUIREMENT- 3% OR. GREATER OCCIDENTAL CHEMICAL MSDS NUMBER: M7695 PRODUCT NAME: MURIATIC ACID 20 COMMERCIAL Page 4 of 9 06 -2 1 -89 IV. FIRE AND EXPLOSION DATA FLASH POINT: NA FLAMMABLE LIMITS IN AIR AUTOIGNITION TEMPERATURE: NA , % BY VOLUME - UPPER: Nonflammable LOWER: Nonflammable EXTINGUISHING MEDIA: Hydrogen chloride is non - combustible. Carbon dioxide, dry chemical and Foam may all be used in areas where hydrogen chloride is stored. SPECIAL FIRE FIGHTING PROCEDURES: Positive pressure. self - contained respiratory protection should be provided for fire fighters in buildings or confined areas where this product is stored. UNUSUAL FIRE AND EXPLOSION HAZARD: This product is nonflammable and nonexplosive under normal conditions of use. At high temperatures, this product can generate toxic and irritating gases. If storage containers are exposed to excessive heat, over - pressurization and rupture of the containers can result. The use of water on this product should be discouraged. Addition of water may cause violent reaction. This product attacks most metals with evolution of explosive hydrogen. V. SPECIAL PROTECTION VENTILATION REQUIREMENTS: Work in well ventilated areas. Use good engineering controls. Use local exhaust ventilation where mist, spray. gas, vapors, or fumes may be generated. SPECIFIC PERSONAL PROTECTIVE EQUIPMENT RESPIRATORY: Use a N I OSI I /MSI•IA approved respirator following manufacturer's recommendation where gas, vapor, fumes, spray, or mist may be generated. EYE: Face shield and chemical goggles should be worn. GLOVES: Impervious gloves should he worn. Natural rubber, neoprene. nitrile or PVC have been suggested. OTHER CLOTHING AND EQUIPMENT: Impervious and chemical' resistant clothing and rubber shoes or boots should be used where any possibility of skin contact exists. Emergency shower and eyewash facility should be in close proximity. MONITORING EXPOSURE PERSONAL /AREA: NLOSH Analytical method number 7903 for inorganic acids. OCCIDENTAL CHEMICAL MSOS NUMBER: M7695 PRODUCT NAME: MURIATIC ACID 20 COMMERCIAL: Page' 5 of 9 06-21-69 VI. PHYSICAL DATA BOILING POINT @ 760 mm Hg: 60 °C (176 °F)C 20 °8e': 60 °C (140. °0 :22 °Be' FREEZING POINT:--45°C (-49.3°F) 20 °Be'; -34 °C (-29.2°F) 22 °Be' VAPOR PRESSURE: 80mm @ 20 °C 22 °Be' SPECIFIC GRAVITY (1-120= l) : 1 . 16 20 °Be' ; t.18 22 °Be.' SOLUBILITY IN H2O °% BY WT: Infinite VAPOR DENSITY (Air =1): 1.3 @20 °C DENSITY 1.16 gm /cc, 9.67 lb /gal 20 °Be' 1 . 18 gm /cc, 9.83 lb /gal 22 °Be' APPEARANCE AND ODOR: Clear to slightly yellow liquid with a sharp irritating odor. pH: 0,2% solution has a pH of -2. All data varies with concentration, VII. REACTIVITY DATA CONDITIONS CONTRIBUTING TO INSTABILITY: Under; normal conditions of use this product.. is stable. - Releases hydrogen chloride gas when heated INCOMPATIBILITY: :Avoid contacting this product with alkalis and alkali or" other.: active metals and certain of,. their.'compounds Do not add water directly to the .product. The product may :be addedto:water with mixing and dilution. Mi.xing with strong 'oxidizers :„ can". yield chlorine... HAZARDOUS DECOMPOSITION PRODUCTS: At high temperatures, this product' generates toxic and irritating gases. Reacts with metals with the:: aVolution of, hydrogen which 'when mixed in air.may result in fire or explosion:. -if ignited. Chiorine gas rmay be released.by mixing with stron,Q oxidizers,. CONDITIONS CONTRIBUTING TO HAZARDOUS POLYMERIZATION :. Material is not known to polymerize. OCCIDENTAL CHEMICAL MSDS NUMBER: M7695 PRODUCT NAME: MURIATIC ACID 20 COMMERCIAL Page 6 of 9 06 -21 -89 VIII. HANDLING AND STORAGE HANDLING AND STORAGE PRECAUTIONS: When handling, wear chemical safety goggles and face shield. gloves and protective clothing. Avoid breathing vapor. use with adequate ventilation - if exposure is likely, wear appropriate respiratory protection. Wash thoroughly after handling. Keep heat, sparks, open flames, pilot lights, and lighted cigarettes away from area of use as toxic. corrosive, and explosive gases may be formed. Keep container tightly closed when not in use. Store in cool, ventilated area away from flammable substances and • oxidizing materials, particularly nitric acid or chlorates. Open container carefully to avoid spurting. DO NOT ADD WATER DIRECTLY TO PRODUCT, and do not mix with alkalies such as sodium hydroxide (caustic soda) or alkali metals, to avoid possible violent reaction. The product may be added to water with mixing and dilution. Do not store in unlined containers. Leaking containers should be removed to outdoors or to an isolated and well ventilated area and contents transferred to a suitable container or disposed in a safe manner. Dike and vent storage tanks. IX. ENVIRONMENTAL PROCEDURES STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Proceed with caution and restrict access to area. Keep unprotected personnel up wind of spill area. Get protective clothing and equipment. Dike and contain spill and prevent from entering sewers and waterways. Contain spill and pump into marked containers for reclamation or disposal. For small spills or residue after pumping, neutralize with soda ash or'dilute caustic soda solution or absorb with compatible substances •much as sand or earth. Clean up material should be removed and placed in approved containers. Spills or releases should be reported. if required, to the appropriate local, state, and federal agencies. WASTE DISPOSAL METHOD: The rnaterials resulting from clean-up operations may be hazardous wastes and, therefore. subject to specific regulations. Package, store. transport. and dispose of all clean -up materials and any contaminated equipment in accordance with all 'applicable federal, state, and local health and environmental regulations. Shipments of waste materials may be subject to manifesting requirements per applicable regulations. Appropriate disposal will depend on the nature of each waste material and should be performed by competent and properly permitted contractors.. Ensure that all responsible federal, state. and local agencies receive proper notification of spill and disposal methods. OCCIDENTAL CHEMICAL MSDS NUMBER: M7695 PRODUCT NAME: MURIATIC ACID 20 COMMERCIAL Page 6 of 9 . 06 -21 -89 VIII. HANDLING AND STORAGE HANDLING AND STORAGE PRECAUTIONS: When handling, wear chemical safety•goggles and face shield, gloves and protective clothing. Avoid breathing vapor. use with adequate ventilation - if exposure is likely, wear appropriate respiratory protection. Wash thoroughly after handling. Keep heat, sparks, open flames, pilot lights. and lighted cigarettes away From area of use as toxic, corrosive, and explosive gases may be Formed. Keep container tightly closed when not in use. Store in cool, ventilated area away from flammable substances and oxidizing materials. particularly nitric acid or chlorates. Open container carefully to avoid spurting. DO NOT ADD WATER DIRECTLY TO PRODUCT, and do not mix with alkalies such as sodium hydroxide (caust is soda) or alkali metals . to avoid possible violent reaction. The product may be added to water with mixing and dilution. Do not store In unlined containers. Leaking containers should be removed to outdoors or to an isolated and well ventilated area and contents transferred to a suitable. container or disposed in a safe manner. Dike and vent storage tanks. IX. ENVIRONMENTAL PROCEDURES STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Proceed with caution and restrict access to area. Keep unprotected personnel up wind of spill area. Get' protective clothing and equipment. Dike and contain spill and prevent from entering sewers and waterways. Contain spill and pump into marked containers for reclamation or disposal. For small spills or residue after pumping, neutralize with soda ash or dilute caustic soda solution or absorb with compatible substances much as sand or earth. Clean up material should be removed and placed in approved containers. Spills or releases should be reported. if required. to the appropriate local, state, and federal agencies. WASTE DISPOSAL METHOD: The materials resulting from clean -up operations may be hazardous wastes and. therefore, subject to specific regulations. Package. store. transport, and dispose of all clean -up materials and any contaminated equipment in accordance with a l l applicable federal, state. and local health and environmental regulations. Shipments of waste materials may be subject to manifesting requirements per applicable regulations. Appropriate disposal will depend on the nature of each waste material and should be performed by competent and properly permitted contractors. Ensure that all responsible federal, state, and local agencies receive proper notification of spill and disposal methods.. • OCCIDENTAL CHEMICAL MSDS NUMBER: M7695 PRODUCT NAME: MURIATIC ACID 20 COMMERCIAL X. ADDITIONAL INFORMATION Page 7 of 9 06-21-89 Sec 311 of the Clean Water Act lists Muriatic Acid as a hazardous substance which. if discharged into or upon water. may required immediate response to mitigate danger to public health. Spills of Muriatic Acid of 5000 or more pounds must be reported to the National Response Center, 1 -800- 424 -8802. Contained on a composite list as required under Sec 101(14) of the Comprehensive Environmental Response., Compensation and Liability Act (Superfund) which includes substances designated pursuant to Sec. 3001 of the Solid Waste Disposal Act (RCRA). Sec. 307 of the Clean Water Act, Sec 112 of the Clean Air Act, Sec 7 of TSCA and Sec 102 of CERCLA. OSHA Standard 29CFR 1910. 1200 requires that information be provided to employees regarding the hazards of chemicals by means of a hazard communication program including labeling. material safety data sheets, training and access to written records. We request that you. and it is your legal duty to, make all information in this Material Safety Data Sheet available to your employees. To aid our customers in complying with regulatory requirements. SARA Title III hazard categories for this product are Indicated in Section I. IF the word "YES" appears net to any category, this product may be reportable by you under the requirements of 40 CFR Part 370. Please consult those regulations for details. • This product contains a toxic chemical or chemicals subject to the reporting requirements of SECTION 313 of TITLE 111 of the SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 and 40 CFR PART 372. (See Section 111,List Legend 02) X1. PREPARATION INFORMATION For additional Non - Emergency health, safety, or.environmental .information telephone (716).286 - 3081, Or write to: Occidental Chemical Corporation Product Stewardship Department Suite 400' 360'Rainbow Boulevard South Niagara Falls, NY 14302 For Emergencies: 24 HOUR EMERGENCY PHONE: (716) 278-7021 This.MSDS replaces MSDS Number M7695 dated 5 /3/88. • OCCIDENTAL CHEMICAL MSDS NUMBER: M7695 PRODUCT NAME: MURIATIC ACID 20 COMMERCIAL Page 8 of 9 , 08-21-89 WARNING LABEL INFORMATION Occidental Chemical Corporation Electrochemicals & Specialty Products Dallas, Texas 75380 In case of CHEMICAL EMERGENCIES - Call (716) 278-7021 (24 hours) CAS Number: 7647 -01 -0 SIGNAL WORD: DANGER! STATEMENT OF HAZARDS: CORROSIVE CAUSES SEVERE BURNS TO EYES, SKIN, AND DIGESTIVE TRACT SEVERELY IRRITATING TO RESPIRATORY TRACT - EXCESSIVE EXPOSURE MAY CAUSE LUNG DAMAGE. MAY CAUSE DISCOLORATION AND EROSION OF TEETH PRECAUTIONARY STATEMENTS: Keep container closed except when transferring material. Do not breathe vapor. Insure adequate ventilation or use an approved respirator. Do not get in eyes, on skin, on clothing. Use goggles, face shield, and rubber shoes. Wear protective clothing and gloves made of vinyl, neoprene, or rubber. Wash thoroughly after handling. Material in contact with metals may liberate toxic and flammable gases. Do not allow entry to sewers or waterways. FIRST AID: IN CASE OF CONTACT: FOR EYES: OBJECT IS TO FLUSH MATERIAL OUT IMMEDIATELY THEN SEEK MEDICAL ATTENTION. IMMEDIATELY Flush eyes with large amounts of water for at least 15 minutes holding lids apart to ensure flushing of the entire eye surface. Washing eyes within seconds is essential to achieve maximum effectiveness, SEEK MEDICAL ATTENTION IMMEDIATELY. FOR SKIN: IMMEDIATELY wash contaminated areas with plenty of soap and water for at least 15 minutes. A soothing ointment may be applied to irritated skin after thorough cleansing. Remove contaminated clothing and footwear and wash clothing before reuse, Discard footwear which cannot be decontaminated. SEEK MEDICAL ATTENTION IMMEDIATELY. IF INHALED Remove to fresh air, If breathing is difficult, trained person administer oxygen. If respiration stops, give mouth -to -mouth resuscitation. GET MEDICAL ATTENTION. IF SWALLOWED: NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. If swallowed. 00 NOT INDUCE VOMITING. Give large quantities of water, If available, give several glasses of milk. Keep airway clear. SEEK MEDICAL ATTENTION IMMEDIATELY. .00CIDENTAL CHEM I CAL MSDS NUMBER: M7695 PRODUCT NAME: MURIATIC ACID 20 COMMERCIAL Page 9 of 9 06-21-89 WARNING LABEL INFORMATION (Continued) IN CASE OF: SPILL OR LEAK: Get protective equipment. Contain spill and pump into marked container for reclamation or disposal. Avoid discharges to sewers and streams. Spills of 5000 pounds or more must be reported to the National Response Center, 1-800-424-8802. FIRE: Material will • not burn. Use extinguishing medium as appropriate for surrounding fire. Use self- contained breathing apparatus and full protective equipment fire will liberate toxic gases. ADDITION OF WATER MAY CAUSE VIOLENT REACTION. HANDLING AND STORAGE: Store in a cool, dry, well - ventilated area away from metals and strong alkalies, flammable substances and oxidizing materials. Dike and vent storage tanks. Do not add water directly to product, do not mix with alkalies or alkali metals. Do not store in unlined containers. DISPOSAL: Submit to an approved chemical disposal service for disposal in accordance with government regulations. INFORMATION REQUIRED BY FEDERAL, STATE OR LOCAL REGULATIONS: This product contains: CAS NAME 7647010 Hydrochloric acid 7732185 Water 7782505 Chlorine: HMIS RATING SYSTEM:. HEALTH 3 FLAMMABILITY 0 FOR INDUSTRIAL. USE, ONLY For further information, Request. OCC MSDS M7695 REACTIVITY 2' LABEL 069M7695. The following MSDSs are included in this packet: 002495 CHEVRON Ultra -Duty Grease 2 004455 CHEVRON DELO Heavy Duty Motor Oil SAE 1.OW •004457 CHEVRON DELO Heavy Duty motor Oil SAE-30 004617 CHEVRON Hydraulic Oil AW MV ISO 46 (End of list) Emergency Number (800)457 -2022 or (510)233 -3737 Material Safety Data Sheet Chevron 1001 kW° CHEVRON Ultra -Duty Grease 2 CHEMICAL WASTE MGT ATTN: CHERYL BOXX 19002 72 ND AVE. KENT; WA 98032 Page CPS254600 of 6 Print Date: January 31, 1992 This Material Safety Data Sheet contains environmental, health and toxicology information for your employees. Please make sure this information is given to them. It also contains information to help you meet community right -to- know /emergency response reporting requirements under SARA Title III and many other laws. If you resell this product, this MSDS must be given to the buyer or the information incorporated in your MSDS. Discard any previous edition of this MSDS. Revised to update Section 9 - :Composition. PRODUCT IDENTIFICATION CHEVRON Ultra -Duty Grease 2. A HAZARD WARNING IS NOT REQUIRED FOR. THIS. PRODUCT UNDER:;... OSHA HAZARD COMMUNICATION STANDARD (29'CFR 1910:1200);..' PRODUCT NUMBER(S),: CPS254600 PRODUCT INFORMATION: (800)582 -3835 Revision:" Number: 7 Revision Date: 05/30/90 MSDS: Number:: 002495, NDA. No Data.Available „; NA - . Not ;Applicable;. :Prepared According. to. the. OSHA: Hazard Communication Standard.,'(29 CF0910.1200) by the Chevron Environmental. Health Center, Inc., P.O. Box 4054,., Richmond;' CA 94804. CHEVRON Ultra -Duty Grease 2 Page 2 of 6 2. FIRST AID - EMERGENCY NUMBER (800)457 -2022 OR (510)233 -3737 EYE CONTACT: No first aid procedures are required. However, as a precaution flush eyes with fresh water for 15 minutes. Remove contact lenses if worn. SKIN CONTACT: No first aid procedures are required. As a precaution, wash skin thoroughly with soap and water. Remove and wash contaminated clothing. Note to Physician: Injection under the skin of materials. similar to this product is associated with accidents involving high - pressure equipment. When ejected from this type of equipment, the material can easily penetrate the skin and leave a small, sometimes bloodless, puncture wound. Yet, because of its driving force, material injected into a fingertip can be deposited into the palm of the hand. Within 24 hours, there is usually a great deal of swelling, discoloration, and intense throbbing pain in the affected part. Immediate treatment at surgical emergency center is recommended. INHALATION: Since this material is not expected to be an immediate inhalation problem, no first aid procedures are required. INGESTION: If swallowed, give water or milk to drink and telephone for medical advice. Consult medical personnel before inducing vomiting. If medical advice cannot be obtained, then take the person and product container to the nearest medical emergency treatment center or hospital. 3. IMMEDIATE HEALTH EFFECTS - (ALSO SEE SECTIONS 11 & 12) EYE CONTACT: This substance irritation. SKIN IRRITATION: Prolonged or frequently cracked or dry from the DERMAL TOXICITY: The systemic toxicity of it should be practically non -toxic to internal organs if it gets on the skin. High- Pressure Equipment Information: Accidental high - velocity injection under the skin of materials of this type may result in serious injury. Seek medical attention at once should an accident like this occur. The initial wound at the injection site may not appear to be serious at first; but, if left untreated, could result in disfigurement or amputation of the affected part. RESPIRATORY /INHALATION: The systemic toxicity of this substance has not been determined. However, it should be practically non -toxic to internal organs if inhaled. INGESTION: The systemic toxicity of this substance has not been determined. However, . it should be practically non - toxic to internal organs if swallowed. is not expected to cause prolonged or significant eye repeated contact may cause the skin to become defatting action of this material. this substance has not been determined. However, Revision Number: 7 Revision Date: 05/30/90 MSDS Number: 002495 NDA - No Data Available NA - Not Applicable x— nncno, an _not CHEVRON Ultra -Duty Grease 2 Page 3 of 6 4. PROTECTIVE EQUIPMENT EYE PROTECTION: No special eye protection is usually necessary. SKIN PROTECTION: No special skin protection is usually necessary. Avoid prolonged or frequently repeated skin contact with this material. Skin contact can be minimized by wearing protective clothing. RESPIRATORY PROTECTION: No special respiratory protection is normally required. However, if operating conditions create high airborne concentrations, the use of an approved respirator is recommended. VENTILATION: Use adequate ventilation to keep, the airborne concentrations of this material below the recommended exposure standard. 5. FIRE PROTECTION FLASH POINT: NA AUTOIGNITION: NDA FLAMMABILITY: NA EXTINGUISHING MEDIA: CO2, Dry Chemical, Foam, Water Fog NFPA RATINGS: Health 0; Flammability 1; Reactivity 0; Special NDA; HMIS RATINGS: Health 0; Flammability 1; Reactivity 0; Other NDA; (Least -0, Slight -1, Moderate-2, High -3, Extreme -4). These values are obtained using the guidelines or published evaluations prepared by the National Fire Protection Association or, if applicable, the National. Paint and Coating Association, and do not necessarily reflect the hazard evaluation of the Chevron Environmental Health Center. Read the entire document and label before using this product. FIRE FIGHTING PROCEDURES: For fires involving this material, do not enter any enclosed or confined fire space without proper protective equipment, including self- contained breathing apparatus. COMBUSTION PRODUCTS: Normal combustion forms carbon dioxide, water vapor and may produce oxides of sulfur, nitrogen and phosphorous. Incomplete combustion can produce carbon monoxide. 6. STORAGE, HANDLING, AND REACTIVITY HAZARDOUS DECOMPOSITION PRODUCTS: NDA STABILITY: Stable. HAZARDOUS POLYMERIZATION: Revision Number: 7 Revision Date: 05/30/90 MSDS Number: 002495 NDA - No Data Available NA.- Not Applicable v _nncnni in, on CHEVRON Ultra -Duty Grease 2 Page 4 of 6 Polymerization will not occur. INCOMPATIBILITY: May react with strong oxidizing agents, such as chlorates, nitrates, peroxides, etc. SPECIAL PRECAUTIONS: DO NOT weld, heat or drill container. Residue may ignite with explosive violence if heated sufficiently. CAUTION! Do not use pressure to empty drum or explosion may result. 7. PHYSICAL PROPERTIES SOLUBILITY: Soluble in hydrocarbon solvents; insoluble in water. APPEARANCE: Red grease. BOILING POINT: NA MELTING POINT: NDA EVAPORATION: NA SPECIFIC GRAVITY: NDA VAPOR PRESSURE: NA PERCENT VOLATILE (VOLUME %): NA VAPOR DENSITY (AIR =1): NA VISCOSITY: 22 cSt @ 100C (Min.) 8. ENVIRONMENTAL CONCERNS, SPILL RESPONSE AND DISPOSAL CHEMTREC EMERGENCY PHONE NUMBER: (800) 424 -9300 (24 hour). SPILL /LEAK PRECAUTIONS: This material is not expected to present any environmental problem. Clean up spills immediately, observing precautions in Protective Equipment section. ,DISPOSAL METHODS: Place contaminated materials in disposable containers and dispose of in a manner consistent with applicable regulations. Contact local environmental or health authorities for approved disposal of this material. 9. EXPOSURE STANDARDS, REGULATORY LIMITS AND COMPOSITION COMPOSITION COMMENT: All the components of this material are on the Toxic Substances Control Act Chemical Substances Inventory•. The percent compositions are given to allow for the various ranges of the components present in the whole product and may not equal 100 %. PERCENT /CAS# COMPONENT /REGULATORY LIMITS Revision Number: 7 Revision Date: 05 /30/90 MSDS Number: 002495. NDA - No Data Available NA - Not Applicable v_nncno� mt_aa% c C CHEVRON Ultra -Duty Grease 2 Page 5 of 6 100.0 % CONTAINING > 70.0 % CHEVRON Ultra -Duty Grease 2 LUBRICATING BASE OIL The BASE OIL may be a mixture of any of the following: CAS 64741884, CAS 64741895,CAS 64741964,CAS 64741975,CAS 64742014,CAS 64742525, CAS 64742536,CAS 64742547,CAS 64742627,CAS 64742650,CAS 72623837. < 30.0 % < 0.5 % ADDITIVES INCLUDING THE FOLLOWING SUBSTITUTED BENZOTRIAZOLE TLV - Threshold Limit Value STEL - Short -term Exposure Limit RQ - Reportable Quantity CC - Chevron Chemical Company TWA - Time Weighted Average TPQ - Threshold Planning Quantity CPS - CUSA Product Code CAS - Chemical Abstract Service Number 10. REGULATORY INFORMATION DOT SHIPPING NAME: NOT DESIGNATED AS A HAZARDOUS MATERIAL BY THE FEDERAL DOT DOT HAZARD CLASS: NOT APPLICABLE DOT IDENTIFICATION NUMBER: NOT APPLICABLE SARA 311. CATEGORIES: 1. Immediate (Acute). Health Effects; NO 2. Delayed (Chronic) Health Effects; NO 3. Fire Hazard; NO 4. Sudden Release of Pressure Hazard; NO 5. Reactivity Hazard; NO WHEN A COMPONENT OF THIS MATERIAL IS SHOWN IN THIS SECTION, THE REGULATORY LIST ON WHICH IT APPEARS IS INDICATED. NO COMPONENTS OF THIS MATERIAL ARE FOUNp ON THE REGULATORY LISTS SHOWN BELOW. REGULATORY LISTS SEARCHED: 01 =SARA 313 04 =CA Prop. 65 07 =IARC Group 2A 10 =PA RTK 13 =MN RTK 02 =MASS RTK 05 =MI 406 08 =IARC Group 2B 11 =NJ RTK 14 =ACGIH TLV 16 =ACGIH Calculated TLV 17 =0SHA.TWA 19 =Chevron TLV 20 =EPA Carcinogen 22 =TSCA SECT 5 SNUR 23 =TSCA SECT 6 RULE 25 =TSCA SECT 8A CAIR 26 =TSCA SECT 8D REPORT 28 =Canadian WHMIS 29 =OSHA CEILING 03=NTP Carcinogen 06 =IARC Group 1 09 =SARA 302/304 12 =CERCLA 302.4 15 =ACGIH STEL 18 =OSHA STEL 21 =TSCA SECT 4 24 =TSCA.SECT 12 EXPORT 27 =TSCA SECT 8E Revision Number: 7 Revision Date: 05/30/90 MSDS Number: 002495 NDA - No Data Available NA - Not Applicable CHEVRON Ultra -Duty Grease 2 Page 6 of 6 11. PRODUCT TOXICOLOGY DATA EYE IRRITATION: No product toxicology data available. data from similar materials. SKIN IRRITATION: No product toxicology data available. data from similar materials. DERMAL TOXICITY: No product toxicology data available. data from similar materials. RESPIRATORY /INHALATION: No product toxicology data available. data from similar materials. INGESTION: No product toxicology data available. data from similar materials. The hazard evaluation was based on The hazard evaluation was based on The hazard evaluation was based on The hazard evaluation was based on The hazard evaluation was based on 12. ADDITIONAL HEALTH DATA ADDITIONAL HEALTH DATA COMMENT: This product contains petroleum base oils which may be refined by various processes including severe solvent extraction, severe hydrocracking, or severe hydrotreating. None of the oils requires a cancer warning under the OSHA Hazard Communication Standard (29 CFR 1910.1200). These oils have not been listed in the National Toxicology Program (NTP) Annual Report nor have they been . classified by the International Agency for Research on Cancer (IARC) as; carcinogenic to humans (Group 1), probably carcinogenic to humans (Group 2A), or possibly carcinogenic to humans (Group 25). Experimental evidence indicates that substituted benzotriazole may cause allergic skin reactions. There is no evidence that human exposure to the low levels of the additive in this product will cause such skin reactions. *************************************** * * * * * * * * * * * * * * * * * * * * * * * * * * * * * ** The above information is based on the data of which we are aware and is believed to be correct as of the date hereof. Since the information contained herein may be applied under conditions beyond our control and with which we may be unfamiliar and since data made available subsequent to the date hereof may suggest modification of the information, we do not assume any responsibility for the results of its use. This information is furnished upon condition that the person receiving it shall make his own determination of the suitability of the material for his particular purpose. Revision Number: 7 Revision Date: 05/30/90 NSDS Number: 002495 NDA - No Data Available NA - Not Applicable nnnn.,• ,,,. nnt Emergency Number (800)457 -2022 or (510)233 -3737 Material Safety Data Sheet Chevron. Plag. IVO CHEVRON DELO Heavy Duty Motor Oil SAE 10W •CPS238153 Page 1 of 7 CHEMICAL WASTE MGT .ATTN: CHERYL BOXX' 19002 72 ND AVE. KENT, WA 98032 Print Date: January 311'1992 This Material Safety Data Sheet contains'environmental, health and toxicology information for.your employees. Please make sure this ,information is given to them. It also contains information, to help you meet community right -to- know /emergency response reporting requirements under SARA Title III and many other laws. If you resell this'product, this MSDS must be given to the buyer or the information incorporated in your MSDS. Discard any previous edition of this MSDS. Revised to update Sections 9 (Composition Comment) and 10 (DOT Information). 1. PRODUCT IDENTIFICATION CHEVRON DELO Heavy Duty Motor Oil SAE 10W - A HAZARD WARNING I5 NOT REQUIRED FOR THIS PRODUCT UNDER OSHA HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200)',. PRODUCT NUMBER(S): CPS238153 PRODUCT INFORMATION: (800)582 -3835 Revision: Number : .,1 '::" Revision Date, 12/27/90 NSDS Number: 004555. NDA -.No Data Available NA - Not Applicable Prepared-According to °the OSHA Hazard Communication, Standard (29 CFR 1910..1200) by the'Chevron Environmental. Health'Center, Inc., P.O. Box 4054, Richmond, CA 94804.. CHEVRON DELO Heavy Duty Motor Oil SAE 10W Page 2 of 7 2. FIRST AID - EMERGENCY NUMBER (800)457 -2022 OR (510)233 -3737 EYE CONTACT: No first aid procedures are required. However, as a precaution flush eyes with fresh water for 15 minutes. Remove contact lenses if worn. SKIN CONTACT: No first aid procedures are required. thoroughly with soap and water. Remove INHALATION: Since this material is not expected to no first aid procedures are required. INGESTION: If swallowed, give water or milk to drink and telephone for medical . advice. Consult medical personnel before inducing vomiting. If medical advice cannot be obtained, then take the person and product container to the nearest medical emergency treatment center or hospital. As a precaution, wash skin and wash contaminated clothing. be an immediate inhalation problem, 3. IMMEDIATE HEALTH EFFECTS - (ALSO SEE SECTIONS 11 & 12) EYE CONTACT: This substance is not expected to cause prolonged or significant eye irritation. This hazard evaluation is based on the data from similar materials. SKIN IRRITATION: This substance is not expected to cause prolonged or significant skin irritation. This hazard evaluation is based on data from similar materials. DERMAL TOXICITY: The systemic toxicity of this substance has not been determined. However, . it should be practically non -toxic to internal organs if it gets•on the skin. This hazard evaluation is based on data from similar. materials. RESPIRATORY /INHALATION: The systemic toxicity of this substance has not been determined. However, it should be practically non -toxic to internal organs if inhaled. This hazard evaluation is based on data from similar materials. INGESTION: The systemic toxicity of this substance has not been determined. However, it should be practically non -toxic to internal organs if swallowed. This hazard evaluation is based on data from similar materials. 4. PROTECTIVE EQUIPMENT EYE PROTECTION: No special eye protection is usually necessary. SKIN PROTECTION: No special skin protection is usually necessary. Avoid prolonged or frequently repeated skin contact with this material. Skin contact can be Revision Number: 1 Revision. Date: 12/27/90 MSDS Number: 004455 NDA - No Data Available NA - Not Applicable v ., nneno, ins om CHEVRON DELO Heavy Duty Motor Oil SAE 10W Page 3 of 7 minimized by wearing protective clothing. RESPIRATORY PROTECTION: No special respiratory protection is normally required. However, if operating conditions create airborne concentrations which exceed the recommended exposure standards, the use of an approved respirator is required. VENTILATION: Use adequate ventilation to keep the airborne concentrations of this material below the recommended exposure standard. 5. FIRE PROTECTION FLASH POINT: (COC) 392F' (195C) Min. AUTOIGNITION: NDA FLAMMABILITY LIMITS (% by volume in air): Lower: NA Upper: NA EXTINGUISHING MEDIA: CO2, Dry Chemical, Foam and Water Fog. NFPA RATINGS: Health 0; Flammability 1; Reactivity 0; Special NDA; HMIS RATINGS: Health 0; Flammability 1; Reactivity 0; Other NDA; (Least -0, Slight -1, Moderate -2, High-3, Extreme -4). These values are obtained using the guidelines or published evaluations prepared by the National fire Protection Association or, if applicable, the National Paint and Coating Association, and do not necessarily reflect the hazard evaluation of the Chevron Environmental Health Center. Read the entire document and label before using this product. FIRE FIGHTING PROCEDURES: For fires involving this material, do not enter any enclosed or confined fire space without proper protective equipment, including self - contained breathing apparatus. COMBUSTION PRODUCTS: Normal combustion forms carbon dioxide, water vapor and may produce oxides . of sulfur, nitrogen and phosphorous. Incomplete combustion can produce carbon monoxide. 6. STORAGE, HANDLING, AND REACTIVITY HAZARDOUS DECOMPOSITION PRODUCTS: NDA. STABILITY: Stable. HAZARDOUS POLYMERIZATION: Polymerization will not occur. INCOMPATIBILITY: May react with strong oxidizing agents, such as chlorates, nitrates, peroxides, etc. SPECIAL PRECAUTIONS: CAUTION! Do not use pressure to empty drum or explosion may result. DO. NOT weld, heat or drill container. Residue may ignite with explosive violence if heated sufficiently. Revision Number: 1 Revision Date: 12/27/90 MSDS Number: 004455 NDA - No Data Available NA - Not Applicable v nnonni m+ om CHEVRON DELO Heavy Duty Motor Oil SAE 1OW Page 4 of 7 • NMI 7. PHYSICAL PROPERTIES SOLUBILITY: Soluble in hydrocarbon solvents; insoluble in water. APPEARANCE: Dark brown liquid. BOILING POINT: NA MELTING POINT: NA EVAPORATION: NA SPECIFIC GRAVITY: 0.89 @ 15.6/15.6C VAPOR PRESSURE: NA PERCENT VOLATILE (VOLUME %): NA VAPOR DENSITY (AIR =1): NA VISCOSITY: 45 cSt @ 40C 8. ENVIRONMENTAL CONCERNS, SPILL RESPONSE AND DISPOSAL CHEMTREC EMERGENCY PHONE NUMBER: (800) 424 -9300 (24 hour). SPILL /LEAK PRECAUTIONS: This material is not expected to present any environmental problems other than those associated with oil spills. Stop the source of the leak or release. Clean up releases as soon as possible. Contain liquid to prevent further contamination of soil, surface water or groundwater. Clean up small spills using appropriate techniques such as sorbent materials or pumping. Where feasible and appropriate, remove contaminated soil. Follow prescribed procedures for reporting and responding to larger releases. DISPOSAL METHODS: Place contaminated materials in disposable containers and dispose of in a manner consistent with applicable regulations. Contact local environmental or health authorities for approved disposal of this material. 9. EXPOSURE STANDARDS, REGULATORY LIMITS AND COMPOSITION COMPOSITION COMMENT: All the components of this material are on the Toxic Substances Control Act Chemical Substances Inventory. This product fits the ACGIH definition for mineral oil mist. The ACGIH TLV is 5 mg /m3, the OSHA PEL is 5 mg /m3. The percent compositions are given to allow for the various ranges of the components present in the whole product and may not equal 100 %. PERCENT /CAS# COMPONENT /REGULATORY LIMITS Revision Number: 1 Revision Date: 12/27/90 MSDS Number: • 004455 NDA - No Data Available NA - Not Applicable v_nncn "a ni on CHEVRON DELO Heavy Duty Motor Oil SAE 10W 100.0 % CONTAINING 80.0 % .■e Page 5 of 7 CHEVRON DELO Heavy Duty Motor Oil SAE 10W LUBRICATING BASE OIL The BASE OIL may be a mixture of any of the following: CAS 64741884, CAS 64741895,CAS 64741964,CAS 64741975,CAS 64742014,CAS 64742525, CAS 64742536,CAS 64742547,CAS 64742627,CAS 64742650,CAS 72623837. < 20.0 % ADDITIVES INCLUDING THE FOLLOWING < 2.0 % CAS85687 BUTYL BENZYL PHTHALATE A toxic chemical subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372. CERCLA 302.4 RQ =100 POUNDS < 1.5 % ZINC ALKYL DITHIOPHOSPHATE CAS68649423 A toxic chemical subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372. TLV - Threshold Limit Value STEL - Short -term Exposure Limit RQ - Reportable Quantity CC. - Chevron Chemical Company TWA - Time Weighted Average TPQ - Threshold Planning Quantity CPS - CUSA Product Code CAS - Chemical Abstract Service Number' 10. REGULATORY INFORMATION. DOT SHIPPING NAME: NOT DESIGNATED AS A HAZARDOUS MATERIAL BY THE FEDERAL DOT DOT HAZARD CLASS: NOT. APPLICABLE DOT IDENTIFICATION NUMBER: NOT APPLICABLE SARA 311 CATEGORIES:; 1. Immediate (Acute) Health Effects; NO 2. Delayed (Chronic) Health Effects; NO 3. Fire Hazard; NO 4. Sudden Release of Pressure Hazard; NO 5. Reactivity Hazard; NO The following components of this material are found on the regulatory lists indicated by the number below the component name: ZINC ALKYL DITHIOPHOSPHATE is found on lists: 01,10,11, BUTYL BENZYL PHTHALATE is found on lists: 01,10,11,12,26,2 REGULATORY LISTS SEARCHED: Revision Number: 1. Revision Date: 12/27/90 MSDS Number: 004455 NDA - No Data Available.; NA - Not Applicable CHEVRON DELO Heavy Duty Motor Oil SAE 10W Page 6 of 7 01 =SARA 313 02 =MASS RTK 04 =CA Prop. 65 05 =MI 406 07 =IARC Group 2A 08 =IARC Group 2B 10 =PA RTK 11 =NJ RTK 13 =MN RTK 14 =ACGIH TLV 16 =ACGIH Calculated TLV 17 =OSHA TWA 19 =Chevron TLV 20 =EPA Carcinogen 22 =TSCA Sect 5(a)(e)(f) 23 =TSCA Sect 6 25 =TSCA Sect 8(a) 26 =TSCA Sect 8(d) 28= Canadian WHMIS 29 =OSHA CEILING 03 =NTP Carcinogen 06 =IARC Group 1 09 =SARA 302/304 12 =CERCLA 302.4 15 =ACGIH STEL 18 =OSHA STEL 21 =TSCA Sect 4(e) 24 =TSCA Sect 12(b) 27 =TSCA Sect 8(e) 30'TSCA Sect 8 FYI 11. PRODUCT TOXICOLOGY DATA EYE IRRITATION: No product toxicology data available. The data from similar materials. SKIN IRRITATION: No product toxicology data available. The data from similar materials. DERMAL TOXICITY: No product toxicology data available. The data from similar materials. RESPIRATORY /INHALATION: No product toxicology data available. The data from similar materials. INGESTION: No product toxicology data available. The data from similar materials. hazard hazard hazard hazard hazard evaluation was based on evaluation was based on evaluation was based on evaluation was based on evaluation was based on 12. ADDITIONAL HEALTH DATA ADDITIONAL HEALTH DATA COMMENT: This product contains zinc alkyl dithiophosphates (ZDDPs). Several ZDDPs have been reported to have weak mutagenic activity in cultured mammalian cells but only at concentrations that were toxic to the test cells. We do not believe that there is any mutagenic risk to workers exposed to ZDDPs. This product contains butyl benzyl phthalate. In a cancer bioassay conducted by the National Toxicology Program (NTP), mice and rats were given butyl benzyl phthalate in their diets. All groups of male rats were terminated at six months due to excessive mortality. Female rats showed an increase in cancer but both sexes of mice did not. This study has been declared invalid and is being repeated by NTP. This product contains petroleum base oils which may be refined by various . processes including severe solvent extraction, severe hydrocracking, or severe hydrotreating. None of the oils requires a cancer warning under the OSHA Hazard Communication Standard (29 CFR 1910.1200). These oils have not been listed in the National Toxicology Program (NTP) Annual Report nor have they been classified by the International Agency for Revision Number: 1 Revision Date: 12/27/90 MSDS Number: 004455 NDA - No Data Available NA - Not Applicable �� nnwnn. /n4 nn%. CHEVRON DELO Heavy Duty Motor Oil SAE 1OW Research on Cancer (IARC) as; carcinogenic to humans (Group 1), probably carcinogenic to humans (Group 2A), or possibly carcinogenic to humans (Group 2B). Page 7 of 7 During use in engines, contamination of oil with low levels of cancer - causing combustion products occurs. Used motor oils have been shown to cause skin cancer in mice following repeated application and continuous exposure. Brief or intermittent skin contact with used motor oil is not expected to have serious effects in humans if the oil is thoroughly removed by washing with soap and water. See Chevron. Material Safety Data Sheet No. 1793 for additional information on used motor oil. *************************************** * * * * * * * * * * * * * * * * * * * * * * * * * * * * * ** The above information is based on the data of which we are aware and is believed to be correct as of the date hereof. Since the information contained herein may be applied under conditions beyond our control and with which we may be unfamiliar and since data made available subsequent to the date hereof may suggest modification of the information, we do not assume any responsibility for the results of its use. This information is furnished upon condition that the person receiving it shall make his own determination of the suitability of the material for his particular purpose. Revision Number: 1 Revision Date. 12 /27/90 MSDS Number: NDA - No Data Availablb., NA Not Applicable Emergency Number (800)457 -2022 or (510)233 -3737. Material Safety Data Sheet Chevron /1410 CHEVRON DELO Heavy Duty Motor Oil SAE 30 CHEMICAL WASTE MGT ATTN: CHERYL BOXX 19002 72. ND AVE • KENT, WA 98032 CPS238155 Page 1 of 7 Print Date: January 31, 1992 This Material Safety Data. Sheet contains environmental, health and toxicology information for your employees. Please make sure this information is given to them. It also contains, information to help you meet community right -to- know /emergency response reporting requirements under SARA Title III and many other laws. If you resell this product,. this MSDS must be given to the buyer or the information incorporated in your MSDS. Discard any previous edition of this MSDS.. Revised to update Sections 9 (Composition Comment) and 10" (DOT Information). 1. PRODUCT IDENTIFICATION CHEVRON DELO Heavy Duty Motor Oil SAE .30 - A HAZARD WARNING IS NOT REQUIRED FOR THIS PRODUCT UNDER'' OSHA HAZARD COMMMUNICATION STANDARD (29 CFR 19104200) `` PRODUCT NUMBER(S):'CPS238155 PRODUCT':NFORMATION: (800)582 -3835 Revision Number: 1 Revision Date: 12/27/90 MSDS Number: 004457 Data Available NA - Not Applicable prepared;According to the OSHA Hazard Communication standard (29 CFR 1910.1200) by the Chevron Environmental Health Center, Inc., P.O..Box 4054, Richmond; CA 94804. CHEVRON DELO Heavy Duty Motor Oil SAE 30 Page 2 of 7 2. FIRST AID - EMERGENCY NUMBER (800)457 -2022 OR (510)233 -3737 EYE CONTACT: No first aid procedures are required. However, as a precaution flush eyes with fresh water for 15 minutes. Remove contact lenses if worn. SKIN CONTACT: No first aid procedures are required. As a precaution, wash skin thoroughly with soap and water. Remove and wash contaminated clothing. INHALATION: Since this material is not expected to be an immediate inhalation problem, no first aid procedures are required. INGESTION: If swallowed, give water or milk to drink and telephone for medical advice. Consult medical personnel before inducing vomiting. If medical advice cannot be obtained, then take the person and product container to the nearest medical emergency treatment center or hospital. 3. IMMEDIATE HEALTH EFFECTS - (ALSO SEE SECTIONS 11 & 12) EYE CONTACT: This substance is not expected to cause prolonged or significant eye irritation. This hazard evaluation is based on the data from similar materials. SKIN IRRITATION: This substance is not expected to cause prolonged or significant skin irritation. This hazard evaluation is based on data from similar materials. DERMAL TOXICITY: The systemic toxicity of this substance has not been determined. However, it should be practically non -toxic to internal organs if it gets on the skin. This hazard evaluation is based on data from similar materials. RESPIRATORY /INHALATION: The systemic toxicity of this substance has not been determined. However, it should be practically non -toxic to internal organs if inhaled. This hazard evaluation is based on data from similar materials. INGESTION: The systemic toxicity of this substance has not been determined. However, it should be practically non -toxic to internal organs if swallowed. This hazard evaluation is based on data from similar materials. 4. PROTECTIVE EQUIPMENT EYE PROTECTION: No special eye protection is usually necessary. SKIN PROTECTION: No special skin protection is usually necessary. Avoid prolonged or frequently repeated skin contact with this material. Skin contact can be. Revision Number: 1 Revision Date: 12/27/90 MSDS Number: 004457 NDA - No Data Available NA - Not Applicable ,. f.f\nnn• In. nn. CHEVRON DELO Heavy Duty Motor Oil SAE 30 Page 3 of 7 minimized by wearing protective clothing. RESPIRATORY PROTECTION: No special respiratory protection is normally required. However, if operating conditions create airborne concentrations which exceed the recommended exposure standards, the use of an approved respirator is required. VENTILATION: Use adequate ventilation to keep the airborne concentrations of this material below the recommended exposure standard. 5. FIRE PROTECTION FLASH POINT: (COC) 419F (210C) Min. AUTOIGNITION: NDA FLAMMABILITY LIMITS (% by volume in air): Lower: NA Upper: NA EXTINGUISHING MEDIA: CO2, Dry Chemical, Foam and Water Fog. NFPA RATINGS: Health 0; Flammability 1; Reactivity 0; Special NDA; HMIS RATINGS: Health 0; Flammability 1; Reactivity 0; Other NDA; (Least -0, Slight -1, Moderate -2, High -3, Extreme -4). These values are obtained using the guidelines or published evaluations prepared by the National Fire Protection Association or, if applicable, the National Paint and Coating Association, and do not necessarily reflect the hazard evaluation of the Chevron Environmental Health Center. Read the entire document and label before using this product. FIRE FIGHTING PROCEDURES: For fires involving this material, do not enter any enclosed or confined fire space without proper protective equipment, including self- contained breathing apparatus. COMBUSTION PRODUCTS: Normal combustion forms carbon dioxide, water vapor and may produce oxides of sulfur, nitrogen and phosphorous. Incomplete combustion can produce carbon monoxide. 6. STORAGE, HANDLING, AND REACTIVITY HAZARDOUS DECOMPOSITION PRODUCTS: NDA. STABILITY: Stable. HAZARDOUS POLYMERIZATION: Polymerization will not occur. INCOMPATIBILITY: May react with strong oxidizing. agents, such as chlorates, nitrates, peroxides, etc. SPECIAL PRECAUTIONS: CAUTION! Do not use pressure to empty drum or explosion may result. DO NOT weld, heat or drill container. Residue may ignite with explosive violence if heated sufficiently. Revision Numbar: 1 Revision Date: 12/27/90 MSDS Number: 004457 NDA - No Data Available NA - Not Applicable CHEVRON DEL.O Heavy Duty Motor Oil SAE 30 Page 4 of 7 7. PHYSICAL PROPERTIES SOLUBILITY: Soluble in hydrocarbon solvents; insoluble in water. APPEARANCE: Dark brown liquid. BOILING POINT: NA MELTING POINT: NA EVAPORATION: NA SPECIFIC GRAVITY: 0.88 @ 15.6/15.6C VAPOR PRESSURE: NA PERCENT VOLATILE (VOLUME %): NA VAPOR DENSITY (AIR =1): NA VISCOSITY: 10.6 cSt @ 100C (Min.) 8. ENVIRONMENTAL CONCERNS, SPILL RESPONSE AND DISPOSAL CHEMTREC EMERGENCY PHONE NUMBER: (800) 424 -9300 (24 hour). SPILL /LEAK PRECAUTIONS: This material is not expected to present any environmental problems other than those associated with oil spills. Stop the source of the leak or release. Clean up releases as soon as possible. Contain liquid to prevent further contamination of soil, surface water or groundwater. Clean up small spills using appropriate techniques such as sorbent materials or pumping. Where feasible and appropriate, remove contaminated soil. Follow prescribed procedures for reporting and responding to larger releases. DISPOSAL METHODS: Place contaminated materials in disposable containers and dispose of in a manner consistent with applicable regulations. Contact local environmental or health authorities for approved disposal of this material. 9. EXPOSURE STANDARDS, REGULATORY LIMITS AND COMPOSITION COMPOSITION COMMENT: All the components of this material are on the Toxic Substances Control Act Chemical Substances Inventory. This product fits the ACGIH definition for mineral oil mist. The ACGIH TLV is 5 mg /m3, the OSHA PEL is 5 mg /m3. The percent compositions are given to allow for the various ranges of the components present in the whole product and may not equal 100 %. PERCENT /CAS# COMPONENT /REGULATORY LIMITS Revision Number: 1 Revision Date: 12/27/90 MSDS Number: 004457 NDA - No Data Available NA - Not Applicable v_nncm� m+ om CHEVRON DELO Heavy Duty Motor Oil SAE 30 Page 5 of 7 100.0 % CONTAINING > 80.0 % CHEVRON DELO Heavy Duty Motor Oil SAE 30. LUBRICATING BASE OIL The BASE OIL may be a mixture of any of the following: CAS 64741884, . CAS 64741895,CAS 64741964,CAS 64741975,CAS 64742014,CAS 64742525, . CAS 64742536,CAS 64742547,CAS 64742627,CAS 64742650,CAS 72623837. < 20.0 % ADDITIVES INCLUDING THE FOLLOWING < 2.0 % BUTYL BENZYL PHTHALATE CAS85687 A toxic chemical subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments'and Reauthorization Act of 1986 and 40 CFR Part 372. CERCLA 302.4 RQ =100 POUNDS < 1.5 %, ZINC ALKYL DITHIOPHOSPHATE CAS68649423 A toxic chemical subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372. TLV - Threshold Limit Value STEL - Short -term Exposure Limit RQ - Reportable Quantity CC - Chevron Chemical Company TWA - Time Weighted Average TPQ - Threshold Planning Quantity CPS - CUSA Product Code CAS - Chemical Abstract Service Number, 10. REGULATORY INFORMATION DOT SHIPPING NAME: NOT DESIGNATED AS A HAZARDOUS MATERIAL BY THE FEDERAL DOT DOT HAZARD CLASS: NOT APPLICABLE DOT IDENTIFICATION NUMBER: NOT APPLICABLE - SARA 311 CATEGORIES:' 1. Immediate (Acute) Health Effects; NO 2. Delayed (Chronic) Health Effects; NO 3. Fire Hazard; NO 4. Sudden'Release of-Pressure Hazard; NO 5. Reactivity Hazard; NO The following components of this material are found on the regulatory, lists indicated by the number below the 'component name: ZINC ALKYL DITHIOPHOSPHATE is found on lists: 01,10,11, BUTYL BENZYL PHTHALATE is found on lists: 01,10,11',12,26,28, REGULATORY LISTS SEARCHED: Revision Number: 3. Revision. Date: 12/27/90 MSDS Number: 004457 NDA - No Data Available NA - Not Applicable CHEVRON DELO Heavy Duty Motor Oil SAE 30 Page 6 of 7 01 =SARA 313 02 =MASS RTK 04 =CA Prop. 65 05 =MI 406 07 =IARC Group 2A 08 =IARC Group 28 10 =PA RTK 11 =NJ RTK 13 =MN RTK 14 =ACGIH TLV 16 =ACGIH Calculated TLV 17 =OSHA TWA 19 =Chevron TLV 20 =EPA Carcinogen 22 =TSCA Sect 5(a)(e)(f) 23 =TSCA Sect 6 25 =TSCA Sect 8(a) 26 =TSCA Sect 8(d) 28 =Canadian WHMIS 29 =OSHA CEILING 03 =NTP Carcinogen 06 =IARC Group 1 09 =SARA 302/304 12 =CERCLA 302.4 15 =ACGIH STEL 18 =OSHA STEL 21 =TSCA Sect 4(e) 24 =TSCA Sect 12(b) 27 =TSCA Sect 8(e) 30 =TSCA Sect 8 FYI 11. PRODUCT TOXICOLOGY DATA EYE IRRITATION: No product toxicology data available. data from similar materials. SKIN IRRITATION: No product toxicology data available. data from similar materials. DERMAL TOXICITY: No product toxicology data available. data from similar materials. RESPIRATORY /INHALATION: No product toxicology data available. data from similar materials. INGESTION: No product toxicology data available. data from similar materials. The The The The The hazard hazard hazard hazard hazard evaluation evaluation evaluation evaluation evaluation was based on was based on was based on was based on was based on 12. ADDITIONAL HEALTH DATA ADDITIONAL HEALTH DATA COMMENT: This product contains zinc alkyl dithiophosphates (ZDDPs). Several ZDDPs have been reported to have weak mutagenic activity in cultured mammalian cells but only at concentrations that were toxic to the test cells. We do . not believe that there is any mutagenic risk to workers exposed to ZDDPs. This product contains butyl benzyl phthalate. In a cancer bioassay conducted by the National Toxicology Program (NTP), mice and rats were given butyl benzyl phthalate in their diets. All groups of male rats were terminated at six months due to excessive mortality. Female rats showed an increase in cancer but both sexes of mice did not. This study has been . declared invalid and is being repeated by NTP. This product contains petroleum base oils which may be refined by various processes including severe solvent extraction, severe hydrocracking, or severe hydrotreating. None of the oils requires a cancer warning under the OSHA Hazard Communication Standard (29 CFR 1910.1200). These oils have not been listed in the National Toxicology Program (NTP) Annual Report nor have they been classified by the International Agency for Revision Number: 1 Revision Date: 12/27/90 MSDS Number: 004457 NDA - No Data Available NA - Not Applicable x..nnem1 mi_Rgi CHEVRON DELO Heavy Duty Motor Oil SAE 30 Page of 7 Research on Cancer (IARC) as; carcinogenic to humans (Group 1), probably carcinogenic to humans (Group 2A), or possibly carcinogenic to humans (Group 2B). During use in engines, contamination of oil with low levels of cancer - causing combustion products occurs. Used motor oils have been shown to cause skin cancer in mice following repeated application and continuous exposure. Brief or intermittent skin contact with used motor oil is not expected to have serious effects in humans if the oil is thoroughly removed by washing with soap and water. See Chevron Material Safety Data Sheet No. 1793 for additional information on used motor oil. *************************************** * * * * * * * * * * * * * * * * * * * * * * * * * * * * * ** The above information is based on the data of which we are aware and is believed to be correct as of the date hereof. Since the information contained herein may be applied under conditions beyond our control and with which we may be unfamiliar and since data made available subsequent to the date hereof may suggest modification of the information, we do not assume any responsibility for the results of its use. This information is furnished upon condition that the person receiving it shall make his own determination of the suitability of the material for his particular purpose. Revision Number: 1 Revision•Date: 12/27/90 :MSDS Number. 004457 NDA - 'No`Data Available NA - Not Applicable •Mnnn ,1. /M :nN c Emergency Number (800)457 -2022 or (510)233 -3737 Material Safety Data Sheet Chevron 1410 %.1 CHEVRON Hydraulic Oil AW MV ISO 46 CHEMICAL WASTE MGT ATTN: CHERYL BOXX 19002 72 ND AVE. KENT, WA 98032 CPS255679 Page 1 of 6 • Print Date: January 31, 1992 This Material Safety Data Sheet contains environmental, health and toxicology information for your employees. Please make sure this information is given to them. It also contains information to help you meet community right -to- know /emergency response reporting requirements under SARA Title 1I1 and many other laws. If you resell . this product, this MSDS must be given to the buyer or the information incorporated in your MSDS. Discard any previous edition of this MSDS. Revised to update Section 5 (Flash Point), 7 (Physical Properties), 8 (Composition). 1. PRODUCT IDENTIFICATION CHEVRON Hydraulic Oil AW MV ISO 46 - A HAZARD WARNING IS NOT REQUIRED FOR THIS PRODUCT UNDER OSHA HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200) PRODUCT NUMBER(S): CPS255679 PRODUCT .INFORMATION: (800)582 -3835 Revision Number. 1 ' Revision Date: 03/28/91 MSDS Number 004617 NDA - .,No.Data Available • NA - Not Applicable PreparedAccording to the OSHA Hazard Communication Standard (29 CFR 1910.1200) by the Chevron Environmental Health Center,.inc., P.O. Box 4054, Richmond, CA, 94804. CHEVRON Hydraulic Oil AW MV ISO 46 Page 2 of 6 2. FIRST AID — EMERGENCY NUMBER (800)457 -2022 OR (510)233 -3737 EYE CONTACT: No first aid procedures are required. However, as a precaution flush eyes with fresh water for 15 minutes. Remove contact lenses if worn. SKIN CONTACT: No first aid procedures are required. As a precaution, wash skin thoroughly with soap and water. Remove and wash contaminated clothing. Note to Physician: Injection under the skin of materials similar to this product is associated with accidents involving high - pressure equipment. When ejected from this type of equipment, the material can easily penetrate the skin and leave a small, sometimes bloodless, puncture wound. Yet, because of its driving force, material injected into a fingertip can be deposited into the palm of the hand. Within 24 hours, there is usually a great deal of swelling, discoloration, and intense throbbing pain in the affected part. Immediate treatment at surgical emergency center is recommended. INHALATION: Since this material is not expected to be an immediate inhalation problem, no first aid procedures are required. INGESTION: If swallowed, give water or milk to drink and telephone for medical advice. Consult medical personnel before inducing vomiting. If medical advice cannot be obtained, then take the person and product container to the nearest medical emergency treatment center or hospital. 3. IMMEDIATE HEALTH EFFECTS - (ALSO SEE SECTIONS 11 &•12) EYE CONTACT: This substance is not expected to cause prolonged or significant eye irritation. This hazard evaluation is based on the data from similar materials. SKIN IRRITATION: This substance is not expected to cause prolonged or significant skin irritation. This hazard evaluation is based on data from similar materials. DERMAL TOXICITY: The systemic toxicity of this substance has not been determined. However, it should be practically non -toxic to internal organs if it gets on the skin. This hazard evaluation is based on data from similar materials. RESPIRATORY /INHALATION: The systemic toxicity of this substance has not been determined. However, it should be practically non -toxic to internal organs if. inhaled. This hazard evaluation is based on data from similar materials. INGESTION: The systemic toxicity of this substance has not been determined. However, it should be practically non -toxic to internal organs if swallowed. This hazard evaluation is based on data from similar materials. Revision Number: 1 Revision Date: 03/28/91 MSDS Number: 004617 NDA - No Data Available NA - Not Applicable c CHEVRON Hydraulic Oil AW MV ISO 46 Page 3 of 6 ■•■•••11111111•1=11111■ 4. PROTECTIVE EQUIPMENT EYE PROTECTION: No special eye protection is usually necessary. SKIN PROTECTION: No special skin protection is usually necessary. Avoid prolonged or frequently repeated skin contact with this material. Skin contact can be minimized by wearing protective clothing. RESPIRATORY PROTECTION: No special respiratory protection is normally required. However, if operating conditions create airborne concentrations which exceed the recommended exposure standards, the use of an approved respirator is required. VENTILATION: Use adequate ventilation to keep the airborne concentrations of this material below the recommended exposure standard. 5. FIRE PROTECTION FLASH POINT: (COC) 366.8F (186C) Min. AUTOIGNITION: NDA FLAMMABILITY LIMITS (% by volume in air): Lower: NDA Upper: NDA EXTINGUISHING MEDIA: CO2, Dry Chemical, Foam and Water Fog. NFPA RATINGS: Health 0; Flammability 1; Reactivity 0; Special NDA; (Least -0, Slight -1, Moderate -2, High -3, Extreme -4). These values are obtained using the guidelines or published evaluations prepared by the National Fire Protection Association or, if applicable, the National Paint and Coating Association, and do not necessarily reflect the hazard evaluation of the Chevron Environmental Health Center. Read the entire document and label before using this product. FIRE FIGHTING PROCEDURES: For fires involving this material, do not enter any enclosed or confined fire space without proper protective equipment, including self - contained breathing apparatus. COMBUSTION PRODUCTS: Normal combustion forms carbon dioxide and water vapor and may produce oxides of sulfur and phosphorus. Incomplete combustion can produce carbon monoxide. 6. STORAGE, HANDLING, AND REACTIVITY HAZARDOUS DECOMPOSITION PRODUCTS: NDA. STABILITY: Stable. HAZARDOUS POLYMERIZATION: Revision Number: 1 Revision Date: 03 /28/91 MSDS Number: 004617 NDA - No Data Available NA - Not Applicable CHEVRON Hydraulic Oil AW MV ISO 46 Page 4 of 6 Polymerization will not occur. INCOMPATIBILITY: May react with strong oxidizing agents, such as chlorates, nitrates, peroxides, etc. SPECIAL PRECAUTIONS: CAUTION! Do not use pressure to empty drum or explosion may result. DO NOT weld, heat or drill container. Replace cap or bung. Emptied container still contains hazardous material which may ignite with explosive violence if heated sufficiently. 7. PHYSICAL PROPERTIES SOLUBILITY: Soluble in hydrocarbon solvents; insoluble in water. APPEARANCE: Pale yellow liquid. BOILING POINT: NA MELTING POINT: NA EVAPORATION: NA SPECIFIC GRAVITY: 0.87 @ 15.6/15.6C VAPOR PRESSURE: NA PERCENT VOLATILE (VOLUME %): NA VAPOR DENSITY (AIR =1): NA VISCOSITY: 41.4 cSt @ 40C (Min.) 8. ENVIRONMENTAL CONCERNS, SPILL RESPONSE AND DISPOSAL CHEMTREC EMERGENCY PHONE NUMBER: (800) 424 -9300 (24 hour). SPILL /LEAK PRECAUTIONS: This material is not expected to present any environmental problems other than those associated with oil spills. Stop the source of the leak or release. Clean up releases as soon as possible. Contain liquid to prevent further contamination of soil, . surface water or groundwater. Clean up small spills using appropriate techniques such as sorbent materials or pumping. Where feasible and appropriate, remove contaminated soil. Follow prescribed procedures for reporting and responding to larger releases. DISPOSAL METHODS: Place contaminated materials in disposable containers and dispose of in a manner consistent with applicable regulations. Contact local environmental or health authorities for approved disposal of this material. 9. EXPOSURE STANDARDS, REGULATORY LIMITS AND COMPOSITION COMPOSITION COMMENT: All the components of this material are on the Toxic Substances Control 1•■■ 4R 1 Revision Number: 1 Revision Date: 03/28/91 MSDS Number: 004617 NDA - No Data Available NA - Not Applicable v_nncr»i im._ann CHEVRON Hydraulic Oil AW MV ISO 46 Page 5of6 Act Chemical Substances Inventory. This product fits the ACGIH definition for mineral oil mist. The ACGIH TLV is 5 mg /m3, the OSHA PEL is 5 mg /m3. The percent compositions are given to allow for the various ranges of the components present in the whole product and may not equal 100 %. PERCENT /CAS# COMPONENT /REGULATORY LIMITS 100.0 % CHEVRON Hydraulic Oil AW MV ISO 46 CONTAINING > 94.0 % DISTILLATES, HYDROTREATED HEAVY PARAFFINIC CAS64742547 < 6.0 % ADDITIVES TLV - Threshold Limit Value STEL - Short -term Exposure Limit RQ - Reportable Quantity CC •- Chevron Chemical Company TWA - Time Weighted Average TPQ - Threshold Planning. Quantity CPS - CUSA Product Code CAS - Chemical Abstract Service Number 10. REGULATORY INFORMATION DOT SHIPPING NAME: NOT DESIGNATED AS A HAZARDOUS MATERIAL BY THE FEDERAL DOT DOT HAZARD CLASS: NOT APPLICABLE DOT IDENTIFICATION NUMBER: NOT APPLICABLE SARA 311 CATEGORIES: Immediate (Acute) Health Effects; NO Delayed (Chronic) Health Effects; N0. Fire Hazard; NO Sudden Release of Pressure Hazard; NO.. Reactivity Hazard; NO None of the components of this material are found on the regulatory . lists shown below. REGULATORY LISTS SEARCHED: O1 =SARA 313 04 =CA Prop. 65 07 =IARC Group 2A• 10 =PA RTK 13 =MN RTK 16=ACGIH Calculated TLV 19= Chevron TLV 22 =TSCA Sect 5(a)(e)(f) 25 =TSCA Sect 5(a) 29 =OSHA CEILING 02 =MASS RTK 05 =MI 406:. 08 =IARC Group 2B 11 =N4 RTK 14 =ACGIH TLV 17 =OSHA TWA 20 =EPA Carcinogen 23 =TSCA Sect 6. 26 =TSCA Sect 5(d) 03 =NTP Carcinogen 06 =IARC Group 1 09 =SARA302 /304 '12 =CERCLA 302.4 15 =ACGIH STEL 18 =OSHA STEL 21=TSCA Sect 4(e) 24 =TSCA Sect 12(b) 28 =Canadian WHMIS Revision Number: 1 Revision Date: 03 /28/91' MSDS Number:. 004617' NDA - No Data Available NA -lMot Applicable CHEVRON Hydraulic Oil AW MV ISO 46 Page 6 of 6 11. PRODUCT TOXICOLOGY DATA EYE IRRITATION: No product toxicology data available. The hazard evaluation was based on data from similar materials. SKIN IRRITATION: No product toxicology data available. The hazard evaluation was based on data from similar materials. DERMAL TOXICITY: No product toxicology data available. The hazard evaluation was based on data from similar materials. RESPIRATORY /INHALATION: No product toxicology data available. The hazard evaluation was based on data from similar materials. INGESTION: No product toxicology data available. The hazard evaluation was based on data from similar materials. 12. ADDITIONAL HEALTH DATA ADDITIONAL HEALTH DATA COMMENT: This product contains petroleum base oils which may be refined by various processes including severe solvent extraction, severe hydrocracking, or severe hydrotreating. None of the oils requires a cancer warning under the OSHA Hazard Communication Standard (29 CFR 1910.1200). These oils have not been listed in the National Toxicology Program (NTP) Annual Report nor have they been classified by the International Agency for Research on Cancer (IARC) as; carcinogenic to humans (Group 1), probably carcinogenic to humans (Group 2A), or possibly carcinogenic to humans (Group 2B). *************************************** * * * * * * * ** * * * * * * * * *** ** * * * * * * * ** The above information is based on the data of which we are aware and is believed to be correct as of the date hereof. Since this information may be applied under conditions beyond our control and with which we may be unfamiliar and since data made available subsequent to the date hereof may suggest modification of the information, we do not assume any responsibil- ity for the results of its use. This information is furnished upon condition that the person receiving it shall make his own determination of the suitability of the material for his particular purpose. Revision Number: 1 Revision Date: 03/28/91 MSDS Number: 004617 NDA - No Data Available NA - Not Applicable nnn nn. ,n• nn, ,•w Oxygen Material Safety Data Sheet Industrial Ges Division Air Products and Chemicals. Inc. Allentown, PA 18195 Tel, (215) 481.4911 TWX 510.651.3686 Cable•AIRPROD • Telex 847416 Fax (215) 481.5900 AIR PRO®VC73 t £YRNE SPECIALTY GASES, INC 118 SO. MEAD ST. SEATTLE. WA 98108 '?fiat 164463. EMERGENCY PHONE; 800-- 523.9374 IN PENNSYLVANIA: 800 - 322.9092 ISSUE DATE Issued: 13 April 1977 REVISIONS Rev: 1 June 1990 TRADE NAME AND SYNONYMS Oxygen, LOX (Liquid only), GOX (Gas only) FORMULA 02 MW: 32.00 CHEMICAL NAME AND SYNONYMS Oxygen ! CHEMICAL FAMILY Oxidizing gas CAS#7782 -44 -7 HEALTH HAZARD DATA EXPOSURE LIMITS OSHA and ACGIH: None established. Oxygen is not listed as a carcinogen by NTP, IARC, or OSHA. SYMPTOMS IF INGESTED, CONTACTED WITH SKIN, OR VAPOR INHALED Oxygen is nontoxic under most conditions of use and is necessary to support life. Liquid oxygen or cold gas will freeze tissues and can cause severe cryogenic (extremely low temperature) burns. TOXICOLOGICAL PROPERTIES Oxygen is nontoxic under usual conditions of use. Breathing pure oxygen at one atmosphere, however, may produce cough and chest pains within 8 -24 hours. Concentrations of 60% may produce these symptoms in several days. At two atmospheres symptoms occur in 2 -3 hours. Partial pressure of oxygen in excess of two atmospheres may produce a variety of central nervous system manifestations including tingling of fingers and toes, visual and hearing disturbances, abnormal sensations, impaired coordination, confusion, muscle twitching, and seizures resembling those of epilepsy. Severe hazards may be present when confusion and impaired Judgment lead to operational errors. Infants exposed to oxygen levels In excess of 35-40% may suffer permanent visual impairment or blindness due to retrolental fibroplasia, RECOMMENDED FIRST AID TREATMENT If cryogenic liquid or cold boil -off gas contacts a worker's skin or eyes, frozen tissues should be flooded or soaked with tepid water (105 -115F; 41 -46C). DO NOT USE HOT WATER. Burns which result in blistering or deeper tissue freezing should be seen promptly by a physician. FIRE AND EXPLOSION HAZARD DATA FLASH POINT (Method used) , AUTO IGNITION TEMP N/A 1 N/A FLAMMABLE LIMITS N/A LEL N/A UEL N/A EXTINGUISHING MEDIA i ELECTRICAL CLASSIFICATION N/A I GROUP N/A SPECIAL FIRE FIGH'ING PROCEDURES Oxygen is nonflammable, but supports and VIGOROUSLY ACCELERATES COMBUSTION of flammables. To fight fires, shut off sources of oxygen and fight like conventional fire. UNUSUAL FIRE AND EXPLOSION HAZARDS Oxygen is nonflammable, but supports and VIGOROUSLY ACCELERATES COMBUSTION of flammables. Some materials which are noncombustible in air will burn in the presence of oxygen. PHYSICAL DATA BOILING POINT ( *F , FREEZING POINT ('F) @ 1 atm - 297.3F (- 183,0C) , ® 1 atm - 361.8F (- 218.8C) VAPOR PRESSURE .os.a1 N/A SOLUBILITY IN WATER ® 77F (25C), 1 atm 3.16% by volume VAPOR DENSITY (Ib:tu 11) ® 70F (21.1C), 1 atm 0.08279 SPECIFIC GRAVITY (AIR. 1) @ 68F (200), 1 atm 1.10 LIQUID DENSITY (Ibieu (t) @ boiling point, 1 atm 71.23 SPECIFIC GRAVITY (H=O.1) @ boiling point, 1 atm 1.14 APPEARANCE AND ODOR Gaseous oxygen is colorless and odorless. Liquid oxygen is pale blue and odorless. nA1r PrnrinMq and RhPmfr.al¢ Inr' 1QRn Orinlorl In 11 C A 11A. r17 Me.. R lnrl% REACTIVITY DATA STABILITY JNSTABLE STABLE CONDITIONS r0 AiOID Materials which burn in air will burn violently in atmosphere richer than approx. X ' 25% oxygen. Some materials will burn in pure oxygen which are nonflammable in ' air. INCOMPATIBILITY I Materials Io a.olet All flammables, especially petroleum products, asphalt, other volatile flammables. HAZARDOUS DECOMPOSITION PRODUCTS None HAZARDOUS POLYMERIZATION MAY OCCUR WILL NOT OCCUR CONDITIONS TO AvoID X i None SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Prevent liquid oxygen from contacting grease, oil, asphalt or combustibles. Ventilate area to evaporate and disperse oxygen. Flush area with large quantities of water. DO NOT ENTER areas of high oxygen concentration, which can saturate clothing and increase its flammability. Avoid smoking and contact with sources of ignition after exposure to concentration of oxygen higher than the normal atmosphere. WASTE DISPOSAL METHOD Allow liquid oxygen to evaporate In a well ventilated outdoor area, Vent oxygen gas to outside location. Disposal site should be remote from work areas, open flames or sources of Ignition and combustibles. Flushing with water will Increase the vaporization rate of the liquid. Do not attempt to dispose of residual oxygen in compressed gas cylinders. Return cylinders to Air Products with residual pressure, the cylinder valve tightly closed and valve cap in place, SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION (Specify type) N/A VENTILATION Prevent accumulation with natural or forced air. LOCAL EXHAUST SPECIAL As necessary None normally required MECHANICAL (General) OTHER As necessary Vents should be situated to avoid higher than nor- mal concentration of oxygen in work areas. PROTECTIVE GLOVES (Liquid) Loose-fitting gloves of impermeable material, such as leather. (Gas) Leather work gloves are recommended when handling mpressed gas cylinders. PROTECTION (Liquid) Chemical goggles or safety glasses. (Gas) Safety glasses are recommended when handling high-pressure cylinders. OTHER PROTECTIVE EQUIPMENT N/A SPECIAL PRECAUTIONS* SPECIAL LAUELING•INFORMA'.ON DOT Shipping Name: Oxygen, or Oxygen Compressed; (Liquid) Oxygen, refrigerated liquid. DOT Hazard Class: Nonflammable Gas. DOT Shipping Label: Oxidizer. I.D. Number: UN 1072, SPECIAL HANDLING RECOMMENDATIONS Prevent contact of liquid oxygen with exposed skin. Prevent entrapment of liquid in closed systems. Use only in well ventilated areas. Cleanliness and compatibility of materials in contact with oxygen are essential especially internal parts of piping systems. Some elastomers (o-rings, valve seats, etc.) are not compatible with oxygen. Open oxygen valves slowly. Compressed gas cylinders contain oxygen at extremely high pressure and should be handled with care. Use a pressure reducing regulator when connecting to lower pressure pip- ing systems. Secure cylinders when in use. Never use direct flame to heat a compressed gas cylinder. Use a check valve to prevent back flow into storeg'e containers. Avoid dragging, rolling, or sliding cylinders, even for a short distance. Use a suitable hand truck. For additional handling recommendations on compressed gas cylinders, consult Compressed Gas Association Pamphlet 12-1 . SPECIAL STORAGE RECOMMENDATIONS Store liquid containers and cylinders in well ventilated areas. Do not store cylinders of oxygen within 20 ft. of flammable or combustible materials, especially oil or grease. Keep cylinders away from source of heat. Storage should not be in heavy traffic areas to prevent accidental knocking over or damage from passing or falling objects. Valve caps should remain on cylinders not connected for use. Never lubricate valves or cylinder caps. Segregate full and empty cylinders. Storage areas should be free of combustible material. Avoid exposure to areas where salt or other corrosive chemicals are present. See Compressed Gas Association Pamphlet P -1 for addi- tional storage recommendations. SPECIAL PACKAGING RECOMMENDATIONS Gaseous oxygen containers meet DOT specifications or American Society of Mechanical Engineers (ASME) codes. Liquid oxygen Is stored In vacuum-Insulated containers meeting DOT specifications or ASME codes. OTHER RECOMMENDATIONS OR PRECAUTIONS Oxygen is not to be used as a substitute for compressed air. Applications such as cleaning, dusting, powering pneumatic tools, etc., are not safe due to lubricating oils and other materials present. Use only with equipment specifically designed and cleaned for oxygen service. Consult Compressed Gas Association Pamphlet G•4.1, "Cleaning Equipment for Oxygen Service," for details. Liquid oxygen is cryogenic liquid. Materials of construction must be selected tor compatibility with extremely low temperatures. Avoid use of carbon ( lel and other materials which become brittle at low temperatures. Compressed gas cylinders should not be refilled except by qualified 1. oducers of compressed gases. Shipment of a compressed gas cylinder filled without the permission of the owner is a violation of Federal Law. If oxygen concentrations exceeding 25% are suspected or can occur, use oxygen monitoring equipment to test for oxygen - enriched atmospheres. 'Various Government agencies (i.e., Department of Transportation, Occupational Safety and Health Administration, Food and Drug Administration and others) may have specific regulations concerning the transportation handling, storage or use of this product which will not be reflected in this data sheet. The customer should review these regulations to ensure that s /he is in full compliance. OHSITY918 MATERIAL SAFETY DATA SHEET OCCUPATIONAL HEALTH SERVICES, INC. 11 WEST 42ND STREET,'12TH FLOOR NEW YORK, NEW:YORK•10036 1- 800 - 445 -MSDS ."(1- 800 - 445 -6737) OR 1- 212 - 789 -3535 FOR EMERGENCY SOURCE INFORMATION CONTACT: 1 -615- 366 -2000 SUBSTANCE IDENTIFICATION SUBSTANCE:: PAINT STRIPPER TRADE NAMES /SYNONYMS:' T20997; OHSITY918 CHEMICAL FAMILY:.. :.MIXTURE . CERCLA RATINGS (SCALE 073): HEALTH -3 FIRE -3 REACTIVITY.° PERSISTENCE -1 NFPA RATINGS'.(SCALE'.0 -4):: HEALTH -2 FIRE -3' REACTIVITY -0 COMPONENTS. AND. CONTAMINANTS COMPONENT: .DICHLOROMETHANE CAS #.75 -09 -2 COMPONENT:.' PROPANE' CAS# 74- 98-6::.. COMPONENT: . • ISOBUTANE CAS# 75 -28 -5 PERCENT: 70.0 -75.6 'PERCENT: 15.0-20.0 - 'PERCENT: :7.0 - 10.'0, COMPONENT:.:. 'PERCENT; 1.0-5.0' METHYL ALCOHOL C67- 56 -1., SURE LIMITS: DICHLOROMETHANE ,(METHYLENE•CHLORIDE): :.. 500 PPM.OSHA'.TWA: 1000• PPM,OSHA'CEILINO:._2000 PPM /5 MIN :IN'2 HOURS OSHA PEAK. 50 PPM (174 MG /M3) ACGIH.TWA 'ACGIH A2- ..SUSPECTED HUMAN CARCINOGEN LOWEST FEASIBLE LIMIT`NIOSHRECOMMENDED EXPOSURE CRITERIA,. 100'PPM.(360.M0 /M3) DFG,MAK TWA: 500 PPM (1800 MG /M3) DFG MAK,30,MINUTE 'PEAK,' AVERAGE VALUE„ 2 TIMES /SHIFT MEASUREMENT METHOD:' CHARCOAL.TUBE..(2)1: CARBON' DISULFIDEt ..GAS.,CHROMATOGRAPHY'°_.. WITH FLAME IONIZATION, DETECTION;. (NIOSH VOL. III: #'1005). 1000 POUNDS CERCLA SECTION 103, REPORTABLE QUANTITY. SUBJECT TO `BARA`SECTION 313 .'ANNUAIi'TOXIC CHEMICAL, RELEASE; REPORTING'?"',`.: SUBJECT TO 'CALIFORNIA PROPOSITION:65 :CANCER AND /OR REPRODUCTIVE - TOXICITY WARNING AND RELE'ASEiREQUIREMENTS- (APRIL•1,'1988) PROPANE: OHSITY918 PAGE 002 OF 013 000 PPM (1800 MG /M3) OSHA TWA 1171 00.PPM (1800 MO /M3) NIOSH RECOMMENDED TWA ,)00 PPM (1800 M0 /M3) DFO MAK TWA," . 2000 PPM (3600 MU /M3) DFG MAK 60 MINUTE PEAK, MOMENTARY VALUE, 3 TIMES /SHIFT MEASUREMENT METHOD: COMBUSTIBLE GAS METER: (NIOSH VOL: II(2) # S87), LIQUIFIED. PETROLEUM GAS ALPO): . . 1000 PPM (1800 MU /M3) OSHA TWA 1000.PPM.(1800 M0 /M3) NIOSH RECOMMENDED TWA , MEASUREMENT. METHOD: COMBUSTIBLE GAS METER; (NIOSH•VOL. ISOBUTANEi 800.PPM'(1900 M0 /M3)•ACGIH.TWA METHYL ALCOHOL (METHANOL):.- . 200 PPM (262 140 /M3) OSHA TWA (SKIN);.250 PPM (328 M0 /M3) OSHA STEL 200 PPM (262 M0 /M3) ACGIH TWA"(SKIN); 250 PPM (328.M0/M3) ACGIH STEL 200.PPM (262 M0 /M3):NIOSH RECOMMENDED TWA,(SKIN)1 •250 PPM (328:MG/M3) NIOSH RECOMMENDED STEL 200 PPM.(262.M0 /M3) DFO,MAK.TWA-(SKIN);; '. .. 400 PPM (524 MO /M3)1)FG MAK.30 MINUTE PEAK, AVERAGE VALUE, 4 TIMES /SHIF.T .MEASUREMENT METHOD:, SILICA GEL TUBE; WATER; GAS CHROMATOGRAPHY WITH FLAME IONIZATION DETECTION; (NIOSH VOL. III .# 2000, METHANOL). ' ' 5000 POUNDS. CERCLA SECTION 103 REPORTABLE QUANTITY., SUBJECT .TO SARA SECTION 313 ANNUAL.TOXIC CHEMICAL RELEASE REPORTING **OSHA LIMITS ADOPTED JANUARY'19,.1989 ARE SUBJECT. TO THE DECISION'09 THE 11TH CIRCUIT COURT OF APPEALS (AFL- CIO'V. OSHA) AS OF JULY 7, 1992,** I1(2) # S93). PHYSICAL DATA. DESCRIPTION: CLEAR .GAS WITH A PUNGENT ODOR. BOILING POINT: IFICGRAVITY: 1.3 'VAPOR PRESSURE: 380 MMHO'O 22 C i,UBILITY.IN WATERS BLIGHT VAPOR DENSITY: 2.9 V.O.C; 50.2% 100 F (38.C) FIRE AND` EXPLOSION,: DATA • FIRE AND EXPLOSION HAZARD:' • ' • DANGEROUS. FIRE '"HAZARD•.WHEN;EXPOSED.TO.HEAT OR FLAME.' VAPORS ARE HEAVIER' THAN.•AIR'AND.MAY TRAVEL A CONSIDERABLE DISTANCE 10..A SOURCE OF IGNITION AND FLASH GAS -AIR MIXTURES ARE EXPLOSIVE FLASH POINT: ,99 F. (9 C) (TOC)`(PROPELLANT) UPPER EXPLOSIVE' LIMIT; 10 -36% LOWER EXPLOSIVE LIMIT: 2=12 t, OHSITY918 PAGE 003 OF 013 EFIGHTING MEDIAN 'CHEMICAL OR CARBON DIOXIDE =90 EMERGENCY RESPONSE GUIDEBOOK, DOT P 5800.5). FOR LARGER FIRES, USE WATER SPRAY OR FOG (1990 EMERGENCY RESPONSE GUIDEBOOK, DOT P 5800.5). • FIREFIGHTING: MOVE CONTAINER FROM FIRE AREA IF YOU CAN DO IT WITHOUT, RISK. APPLY COOLING WATER TO 'SIDES OF CONTAINERS THAT ARE EXPOSED TO FLAMES UNTIL WELL AFTER FIRE IS'OITf. STAY AWAY FROM ENDS OF TANKS. FOR MASSIVE FIRE IN CARGO AREA, USE UNMANNED HOLDER OR MONITOR NOZZLES, IF THIS IS IMPOSSIBLE, WITHDRAW FROM AREA AND LET FIRE BURN. WITHDRAW IMMEDIATELY IN CASE OF RISING SOUND FROM VENTING SAFETY DEVICE,OR ANY DISCOLORATION OF TANK DUE TO FIRE. LET TANK, TANK CAR OR TANK TRUCK BURN.UNLESS'LEAK CAN BE STOPPED: WITH SMALLER TANKS OR CYLINDERS, EXTINGUISH /ISOLATE FROM OTHER FLAMMABLES. ISOLATE FOR 1/2 MILE IN ALL DIRECTIONS IF TANK, RAIL' CAR OR TANK TRUCK IS INVOLVED IN FIRE (1990. EMERGENCY RESPONSE GUIDEBOOK, DOT P 5800.5, GUIDE PAGE 22). EXTINGUISH ONLY•IF'GAS`FLOW CAN BE STOPPED. USE,FLOODING AMOUNTS OF WATER AS FOG. COOL CYLINDERS WITH FLOODING 'AMOUNTS OF WATER FROM AS FAR A DISTANCE AS POSSIBLE. AVOID.BREATHING.VAPORS, KEEP UPWIND. IF FIRE IS UNCONTROLLABLE OR. . CYLINDERS ARE EXPOSED TO FIRE; EVACUATE FOR A RADIUS OF 1500 FEET. CONSIDER . EVACUATION OF DOWNWIND AREA IF MATERIAL .IS LEAKING. • TRANSPORTATION DATA DEPARTMENT OF TRANSPORTATION HAZARD CLASSIFICATION 49 -CFR 172.101: FLAMMABLE GAS ' DEPARTMENT OF TRANSPORTATION LABELING REQUIREMENTS 49 -CFR 172.101 AND SUBPART Es • FLAMMABLE GAS DEPARTMENT OF TRANSPORTATION PACKAGING REQUIREMENTS:'49 —CFR 173.119 EXCEPTIONSi 49 -CFR 173,110. AL RULE ON HAZARDOUS MATERIALS REGULATIONS (HMR, 49 CFR PARTS 171 -180), .ET NUMBERS HM -181, HM- 1B1A,•HM -1818, HM -1810, HM-181D AND HM -204.. FECTIVE DATE OCTOBER. 1,'1491. HOWEVER, COMPLIANCE WITH THE REGULATIONS' I8 AUTHORIZED -ON AND,AFTER JANUARY 1, 1991, (55 FR 52402, 12/21/90) EXCEPT FOR EXPLOSIVES, INHALATION HAZARDS, AND INFECTIOUS SUBSTANCES,..THE EFFECTIVE ;DATE,FOR HAZARD'COtMtUNICATION REQUIREMENTS IS EXTENDED TO '• OCTOBER..1, 1993,'(56 FR 47158, 09/18/91)' .' U.S, DEPARTMENT.OF TRANSPORTATION SHIPPING NAME -ID NUMBER, 49 CFR 172.1011. AEROSOLS, FLAMMABLE, 1,1,0.8,4-UN 19E0 U.B. DEPARTMENT OF. TRANSPORTATION HAZARD 2.1 - FLAMMABLE GAS.: U.B. DEPARTMENT OF TRANSPORTATION LABELING REQUIREMENTS,' 49 CFR 172.101 AND SUBPART. E: FLAMMABLE GAS U.S, DEPARTMENT OF TRANSPORTATION QUANTITY LIMITATIONS.49 CFR 172.101, OHSITY918 PAGE 004 OF 013 SENGER AIRCRAFT OR RAILCAR: 75 KG 0 AIRCRAFT ONLY: 150.K0 TOXICITY DICHLOROMETHANE (METHYLENE CHLORIDE) :: IRRITATION DATA: 162 MO. EYE- RABBIT.MODERATEJ 10 MG EYE - RABBIT MILD :. ' 500 M0/24 HOURS EYE - RABBIT MILD; 810 M0/24 HOURS SKIN - RABBIT SEVERE, .100 MG /24 HOURS'SKIN- RABBIT MODERATE; •. TOXICITY DATA: .500 PPM /1 YEAR- INTERMITTENT.INHALATION -HUMAN TCLO; 500 PPM /8 HOURS INHALATION -HUMAN TCL01 88000 MG /M3/30 MINUTES INHALATION -RAT LC50j 552 PPM /6 HOURS /5 DAY INTERMITTENT INHALATION -RAT TCLO; 14400'PPM /7,HOURS INHALATION -MOUSE LC50; 10000 PPM /7 HOURS INHALATION- RABBIT LCL01 LCLOt.5000 PPM /2 HOURS INHALATION - GUINEA PIG LCLOt.14108 PPM /7 HOURS INHALATION- DOG;LCL0143400 M0/M3/4,5 HOURS INHALATION= CAT,LCLO: 357 MG /KG ' ORAL -HUMAN LULOj 1600 M0 /KG.ORAL -RAT LD501.1900 MG /KG ORAL- RABBIT LDLO; 3-GM/KG 'ORAL-DOG. LDLO1 6460 WW1 SUBCUTANEOUS-MOUSE LD501 2700 "MG /KG SUBCUTANEOUS- RABBIT LDLOI 200 MG /KG INTRAVENOUS -DOG LDLO1 916 MG/KG.' INTRAPERITONEAL- RAT. L0501.437'MG /K0.INTRAPERITONEAL -MOUSE LD501 950 MG /K0• INTRAPERITONEAL -D00 LDL0: 4770 MO /KG UNREPORTED -MOUSE LD501 MUTAGENIC DATA (RTECS) REPRODUCTIVE EFFECTS DATA (RTECS)1.TUMORIGENIC DATA (RTECS).` . CARCINOGEN STATUSt ANTICIPATED :HUMAN CARCINOGEN (NTP)j•HUMAN.INADEQUATE . EVIDENCE, ANIMAL•SUFFICIENT.EVIDENCE (IARC GROUP -213). EXPOSURE BY'INHALATION • INCREASED THE INCIDENCE OF BENIGN AND MALIONANT.LUNO AND LIVER TUMORS IN MICE OF EACH SEX AND THE INCIDENCE OR MULTIPLICITY OF.BENION MAMMARY TUMORS IN RATS OF EACH SEX:.IN'MALE RATS,AN INCREASED INCIDENCE OF SARCOMAS , ' LOCATED IN THE NECK WAS ALSO OBSERVED.: . LOCAL EFFECTSt•IRRITANT- INHALATION, SKIN,- EYE. ACUTE'TOXICITY LEVELt•MODERATELY TOXIC BY INHALATION,AND INGESTION. TARGET,.EFFECTSt CENTRAL' NERVOUS SYSTEM DEPRESSANT: CHEMICAL ASPHYXIANT. . POISONING MAY AFFECT THE BL00D, LIVER AND KIDNEYS. AT INCREASED RISK FROM EXPOSURE:. PERSONS, WITH.SKIN,, LIVER,. KIDNEY, CARDIOVASCULAR'DISEASE OR ANEMIA. . ADDITIONAL DATA: CONCURRENT • EXPOSURE TO OTHER SOURCES .OF CARBON MONOXIDE,.' SMOKING, OR PHYSICAL ACTIVITY MAY INCREASE THE LEVEL OF. CARBOXYHEMOGLOBIN ' IN THE BLOOD RESULTING IN ADDITIVE EFFECfS,'.ALCOHOL MAY ENHANCE THE TOXIC EFFECTS, STIMULANTS SUCH AS EPINEPHRINE MAY INDUCE CARDIAC 'RHYTHMIAS. ONE.STUDY INDICATED,THAT CHRONIC EXPOSURE. MAY BE ASSOCIATED TH AN INCREASED RISK OF: SPONTANEOUS ABORTION :'DICHLOROMETHANE CROSSES HE PLACENTA AND' IS EXCRETED.IN BREAST MILK. . PROPANE: CARCINOGEN STATUS=• NONE.., • ACUTE TOXICITY LEVEL, „NO DATA AVAILABLE.... . TARGET EFFECTSt'CENTRAL'NERVOUB SYSTEM DEPRESSANT: SIMPLE ASPHYXIANT. ADDITIONAL DATA:.'.STIMULANTS:SUCHAS' EPINEPHRINE.MAY INDUCE VENTRICULAR FIBRILLATION.' ISOBUTANE; •TOXICITY.DATA; 57,PPH/15' MINUTES.. INHALATION -RAT LC501- 1041,GM/M3/2 HOURS • INHALATION•MOUSE•LCL01; 52 MG /KG /1 HOUR INHALATION - MOUSE, LC50:(38MKAJ)`. ',. CARCINOGEN STATUSi,NONE; , LOCAL EFFECTS:` IRRITANT- :INHALATION: ACUTE TOXICITY LEVEL: RELATIVELY NON -TOXIC BY.INHALATION:. . TARGET EFFECTS: CENTRAL NERVOUS'SYSTEM DEPRESSANTI•SIMPLE ASPHYXIANT. ADDITIONAL DATA: STIMULANTS SUCH AS EPINEPHRINE MAY'. INDUCE VENTRICULAR . FIBRILLATION. OHSITY918 PAGE 005 OF 013 YI ALCOHOL (METHANOL):• 2TATION DATAi`20 MG /24 HOURS SKIN- RABBIT MODERATE; 40 MG EYE - RABBIT. MODERATE;' 100 MG /24 HOURS EYE - RABBIT MODERATE. TOXICITY DATA 86,000 MG/M3. INHALATION-HUMAN TCLO; 300 PPM INHALATION - HUMAN' TCLO; ,64,000 PPM /4 HOURS INHALATION -RAT LC50; 1000'PPM INHALATION - MONKEY LCLO; 50 GM /M3 /2.HOURS :INHALATION -MOUSE LCLO; 44,000 MG /M3/6 HOURS INHALATION -CAT LCLO; ,15,800.MG/KG SKIN- RABBIT•LD50; 393 MG /KG SKIN- MONKEY LDLO; 428 MG /KG ORAL -HUMAN LDLO ;.143.MG /KG ORAL -HUMAN LDLO; 6422 MG /KG ORAL -MAN LDLO; 3429 MG /KG ORAL- MAN. TDL0 ;•4 GM /KG ORAL -WOMAN TDLO; 7 GM /KG ORAL- MONKEY•LD50; 5628.MG /KG ORAL -RAT LDSO; 7300 MG /KG ORAL -MOUSE LD50; 14,200 MG /KG •ORAL- RABBIT LD50; 7500 MO /KG ORAL -DOG LDLO; 9800 MG /KG • SUBCUTANEOUS -MOUSE LD50; 2131.MG /KG.INTRAVENOUS -RAT LD50; 4710 MO /KG • INTRAVENOUS -MOUSE LD50; 8907 MG /KG INTRAVENOUS- RABBIT L050; 4641 MG /KG.' INTRAVENOUS-CAT .LDLO ;•7529 MO /KG INTRAPERITONEAL -RAT LD50 ;'10,765 MG /KG INTRAPERITONEAL -MOUSE LD50; 1826 MG /KG INTRAPERITONEAL- RABBIT LD50; 3556 MG /KG INTRAPERITONEAL - GUINEA PIG LD5O; 8555.MG /KG INTRAPERITONEAL- HAMSTER'LDS0; 868 MO /KO UNREPORTED -MAN LDLO; MUTAGENIC DATA (RTECS)1 REPRODUCTIVE EFFECTS DATA (RTECS). CARCINOGEN' STATUS:' NONE. LOCAL EFFECTS:. IRRITANT- SKIN, EYE :., ACUTE TOXICITY LEVEL) SLIGHTLY TOXIC BY DERMAL "ABSORPTION AND INGESTION; RELATIVELY, NON -TOXIC BY: INHALATION.. TARGET EFFECTS:' CENTRAL NERVOUS SYSTEM DEPRESSANT; NEUROTOXIN.,. AT INCREASED:RISK PROM EXPOSURE: PERSONS WITH KIDNEY, EYE'OR SKIN DISORDERS.. HEALTH EFFECTS AND FIRST AID' INHALATION :. . DICHLOROMETHANE (METHYLENE CHLORIDE),: IRRITANT %NARCOTIC /CHEMICAL ASPHYXIANT /CARCINOGEN. ACUTE EXPOSURE-HUMAN EXPOSURE TO 100 PPM.HAS RESULTED IN UPPER'RESPIRATORY TRACT IRRITATION ;, CONCENTRATIONS AS•.LOW AS 200 PPM.HAVE PRODUCED TEMPORARY. NEUROBEHAVIOURAL ..EFFECTS1.500- 1000'PPM FOR 1 -2 HOURS HAS CAUSED LIGHTHEADEDNESS AND ELEVATED CARBOXYHEMOGLOBIN .LEVEL 1,2300 PPM .FOR .30 MINUTES HAS CAUSED'NAUSEA AND NARCOSIB1'5000 PPM•MAO •CAUSED HEADACHE, • FATIGUE, NEURASTHENIC DISORDERS AND DIGESTIVE DISTURBANCES.• OTHER. ' SYMPTOMS MAY, INCLUDE DIZZINESS, TINGLING, NUMBNESS.OF THE,EXTREMITIEB, A SENBATION.OF'HEAT, A SENSATION OF.FULLNE88 IN, THE, HEAD,. DRUNKENNESS,.' STUPOR, DULLNESS; AND MENTAL CONFUSION., MASSIVE :EXPOSURE MAY CAUSE ,''' PHARYNGEAL. EROSION, PULMONARY EDEMA,; STAGGERING,. HEMOLYSIS.WITH GROSS HEMATURIA,. RAPID UNCONSCIOUSNESS AND DEATH:, RECOVERY. IS GENERALLY COMPLETE :IF•EXPOSURE.18. TERMINATED BEFORE ANESTHETIC DEATH. EXPOSURE TO HIGH LEVELS .MAY ALSO CAUSE. CARDIAC ARRHYTHMIAS..•., CHRONIC ,EXPOSURE- ',MORE:THAN 100 WORKERS EXPOSED TO LEVELS BELOW '500 PPM HAVE ,, • DEVELOPED HEALTH PROBLEMS•INCLUDING'SIGNIFICANT UPPER RESPIRATORY'``, IRRITATIONEXACERBATION•OF CORONARY ARTERY DISEASE, AND;.A.HIGH'INCIDENCE . OF.NEUROTOXICITY/ INCREASED COMPLAINTS OF CHEST PAINS WERE :REPORTED' AT : CONCENTRATIONS pF 30 TO 35 PPM. REPEATED HUMAN.EXPOSURE.T0.500 -3600 PPM . HAS CAUSED :8IGN8.OF.TOXIC,ENCEPHALOPATHY WITH ACOUSTICAL'AND OPTICAL •, DELUSIONS AND HALLUCINATIONS. A.CASE OF:SERIOUS CEREBRAL'DETERIORATION WAS OBSERVED IWAN INDIVIDUAL EXPOSED FORSEVERAL YEARS T0" DICHLOROMETHANE. IN'A MORTALITY STUDY OF.TWO GROUPS OF'WORKERS,,ONE .EXPOSED'TO,.ACETONE,AND THE 'THER,TO DICHLOROMETHANE.AND•ACETONE,. A• STATISTICALLY SIGNIFICANT DIFFERENCE..IN DEATHS FROM DISEASES.08.1THE .. CIRCULATORY SYSTEM AND FROM ISCF(EMIC HEART DISEASE, WORE REPORTED.FROM THE DICHLOROMETHANE AND ;ACETONE GROUP: IN. ANOTHER MORTALITY'.,BTUDY,:OF,; OHSITY918 PAGE 006 OF 013 • WORKERS EXPOSED TO DICHLOROMETHANE, A SIGNIFICANT INCREASE IN HYPERTENSIVE 117 DISEASE AND A "SUGGESTIVE EXCESS" OF PANCREATIC CANCER WERE REPORTED. ' LIVER DISEASE HAS BEEN REPORTED IN WORKERS. IN ONE STUDY, AN INCREASE IN SERUM'BILIRUBIN.WAS OBSERVED•IN EXPOSED WORKERS, BUT NO OTHER SIGN OF'LIVER INJURY OR HEMOLYSIS WAS REPORTED: ADVERSE LIVER EFFECTS WERE OBSERVED 'IN • SEVERAL ANIMAL SPECIES CHEMICALLY EXPOSED. TESTICULAR ATROPHY WAS REPORTED' IN MICE EXPOSED TO 9000 PPM OVER 2•YEARS. REPEATED INHALATION BY RODENTS PRIOR TO•AND /OR DURING GESTATION CAUSED FETAL SKELETAL ABNORMALITIES AND BEHAVIORAL EFFECTS IN NEWBORN .OFFSPRING. REPEATED •INHALATION.INCREASED'THE INCIDENCE OF BENIGN AND MALIGNANT LUNG ' AND LIVER TUMORS IN•MICE OF EACH SEX AND THE INCIDENCE OR MULTIPLICITY 'OF BENIGN MAMMARY TUMORS IN RATS OF EACH SEX/ IN MALE RATS, AN INCREASED INCIDENCE'OF SARCOMAS LOCATED.IN THE NECK WAS ALSO OBSERVED. PROPANE: NARCOTIC /SIMPLE ASPHYXIANT. 20,000 PPM IMMEDIATELY DANGEROUS TO LIFE OR HEALTH ACUTE EXPOSURE- BRIEF•EXPOSURE TO.10,000 PPM CAUSED NO SYMPTOMS IN HUMAN.' SUBJECTS / 100,000 PPM.PRODUCED SLIGHT DIZZINESS IN A FEW MINUTES BUT WAS NOT NOTICEABLY IRRITATING TO THE NOSE OR RESPIRATORY TRACT. HIGH LEVELS MAY• PRODUCE DISORIENTATION,. EXCITATION, EXCESSIVE SALIVATION, HEADACHE' AND VOMITING. 'IN PRIMATES, 100,000 PPM PRODUCED•SOME MYOCARDIAL EFFECTS AND AT•200,000 PPM AGGRAVATION OF' THESE PARAMETERS.AND RESPIRATORY DEPRESSION,- CONCENTATIONS OF 100,000. PPM IN MICE.AND 150,000. PPM . • IN DOGS APPEAR TO.PRODUCE NO ARRHYTHMIA BUT WEAK'CARDIAC SENSITIZATION: SIMPLE ASPHYXIANTS AT CONCENTRATIONS OF 33% MAY CAUSE RAPID RESPIRATION, DYSPNEA AND REDUCED, MENTAL ALERTNESS.AND MUSCLE COORDINATION. CONCENTRATIONS OF 75% MAY.PRODUCE NAUSEA, VOMITING, PROSTRATION, UNCONSCIOUSNESS, CONVULSIONS, DEEP COMA AND DEATH. CHRONIC EXPOSURE- REPEATED CONTACT MAY RESULT IN SYMPTOMS AS DESCRIBED IN, ACUTE EXPOSURE. ISOBUTANE: IRRITANT /NARCOTIC /SIMPLE ASPHYXIANT.' 19,000'PPM (LIQUIFIED PETROLEUM GAS) IMMEDIATELY DANGEROUS TO LIFE OR HEALTH. ACUTE EXPOSURE- VAPORS MAY BE IRRITATING TO THE MUCOUS MEMBRANES. HUMANS EXPOSED TO 250 -1000 PPM FORT MINUTE TO 8.HOURS DID NOT EXHIBIT ANY • ADVERSEEFFECTS:.HIGHER CONCENTRATIONS MAY CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION AND ASPHYXIATION. SYMPTOMS MAY INCLUDE DIZZINESS, DIFFICULTY IN .BREATHING, ;LOSS OP CONSCIOUSNESS, MUSCULAR INCOORDINATION, HEADACHE, WEAKNESS, -EMOTIONAL INSTABILITY, NAUSEA,.VOMITING,'PROSTRATION, CONVULSIONS,COMA,'AND DEATH. ANIMALS, EXPOSED TO,NEAR LETHAL LEVELS EXHIBITED CENTRAL NERVOUS SYSTEM DEPRESSION,.RAPID AND.SHALLOW . RESPIRATION,' AND:APNEA. CARDIAC SENSITIZATION HAS BEEN:REPORTED IN', ' ANIMALS.. .. CHRONIC EXPOSURE -'.NO ADVERSE.EFFECTS'HAVE BEEN REPORTED FROM'HUMAN EXPOSURE TO 500 PPM FOR 1 -8 HOURS /DAY FOR 10.DAYS.'. ' METHYL ALCOHOL (METHANOL): NARCOTIC /NEUROTOXIN, :25,000 PPM IMMEDIATELY :DANGEROUS TO.LIFE OR HEALTH. ACUTE EXPOSURE- MAY CAUSE IRRITATION OF`.THE MUCOUS; MEMBRANES,. COUGHING,. OPPRESSION IN THE CHEST,' TRACHEITIS ,.BRONCHITIS,TINNITUS,' UNSTEADY ' GAIT,. TWITCHING,.. COLIC; CONSTIPATION,.NYSTAGMUS, AND BLEPHAROSPASM, SYMPTOMS FROM OCCUPATIONAL EXPOSURE'.INCLUDE PARESTHESIAS, NUMBNESS :AND SHOOTING PAINS IN THE HANDS AND FOREARMS. METABOLIC ACIDOSIS, AND, EFFECTS` ON THE EYES AND - CENTRAL NERVOUS SYSTEM MAY OCCUR AS'DETAILED IN ACUTE ' INGESTION. CHRONIC EXPOSURE- REPEATED,OR:PROLONOED'EXPOSURE MAY CAUSE EFFECTS AS IN OHSHY918 . • PAGE 007 OF 013 ACUTE INGESTION. REPEATED EXPOSURE TO 200 -275 PPM CAUSED RECURRENT lc' HEADACHES IN WORKERS. EXPOSURE FOR 4 YEARS TO 1200 -8000 PPM RESULTED IN • MARKED DIMINUTION OF VISION AND. ENLARGEMENT OF THE LIVER IN A WORKMAN. REPRODUCTIVE EFFECTS HAVE BEEN REPORTED IN ANIMALS: FIRST AID- REMOVE FROM ,EXPOSURE AREA TO FRESH AIR IMMEDIATELY. IF BREATHING HAS.STOPPED, GIVE ARTIFICIAL RESPIRATION. MAINTAIN AIRWAY AND BLOOD . PRESSURE AND ADMINISTER'OXYGEN IF AVAILABLE. KEEP AFFECTED PERSON WARM AND AT REST:' TREAT•SYMPTOMATICALLY AND SUPPORTIVELY. ADMINISTRATION OF OXYGEN SHOULD BE PERFORMED BY QUALIFIED PERSONNEL. GET MEDICAL ATTENTION • ..IMMEDIATELY. . SKIN CONTACT: DICHLOROMETHANE (METHYLENE CHLORIDE): IRRITANT. '. . • ACUTE EXPOSURE -'MAY CAUSE EFFECTS RANGING FROM MILD IRRITATION TO•SEVERE PAIN,.PARESTHESIAS; AND POSSIBLY'BURNS,,'DEPENDING•ON THE INTENSITY OF. .. CONTACT: ,.. . CHRONIC EXPOSURE - 'PROLONGED OR REPEATED CONTACT MAY CAUSE A DRY, SCALY AND FISSURED DERMATITIS DUE;TO DEFATTING.ACTION OF LIQUID ON SKIN. PROPANE: , ACUTE EXPOSURE- NO ADVERSE EFFECTS HAVE BEEN REPORTED FROM THE GAS. DUE TO RAPID EVAPORATION, THE LIQUID MAY CAUSE FROSTBITE. WITH REDNESS, TINGLING • AND PAIN OR NUMBNESS. IN MORE SEVERE CASES, THE.SKIN MAY BECOME HARD AND WHITE AND DEVELOP BLISTERS. .CHRONIC EXPOSURE- NO. ADVERSE EFFECTS•REPORTED. • ISOSUTANEs . ACUTE .EXPOSURE - NO.ADVERSE EFFECTS HAVE BEEN REPORTED FROM THE GAS. DUE TO • RAPID EVAPORATION, THE LIQUID MAY'CAUSE•FROSTBITE WITH REDNESS, TINGLING . AND'PAIN OR NUMBNESS. IN.MORE SEVERE CASES, THE SKIN MAY,BECOME HARD AND WHITE AND DEVELOP BLISTERS. ' CHRONIC EXPOSURE- NO EFFECTS•HAVE BEEN REPORTED. METHYL ALCOHOL"(METHANOL):. IRRITANT /NARCOTIC /NEUROTOXIN.. ACUTE EXPOSURE- CONTACT WITH LIQUID.MAY CAUSE IRRITATION, SKIN ABSORPTION • MAY OCCUR AND. CAUSE METABOLIC' ACIDOSIS AND EFFECTS 'ON THE.EYES AND'CENTRAL NERVOUS SYSTEM AS DETAILED IN ACUTE INGESTION... 'HRONIC EXPOSURE - REPEATED.OR PROLONOED'CONTACT :WITH THE LIQUID'MAY CAUSE, DEFATTING OF•THE SKIN RESULTING IN ERYTHEMA, SCALING,'AND.ECZEMATOID , ' DERMATITIS., CHRONIC•AB80RPTION'MAY RESULT IN METABOLIC ACIDOSIS AND EFFECTS. AS DETAILED,IN ACUTE - INGESTION. FIRST AID- REMOVE CONTAMINATED. CLOTHING AND SHOES IMMEDIATELY. WASH AFFECTED AREA WITH'ROAP OR MILD DETERGENT,AND.LARGE AMOUNTS OF WATER"UNTIL'NO ' ; - EVIDENCE OF- CHEMICAL.REMAINS (APPROXIMATELY :15 -20 MINUTES)'. GET MEDICAL:.. ATTENTION "IMMEDIATELY,:. EYE CONTACT: DICHLOROMETHANE (METHYLENE' CHLORIDE): -• ACUTE EXPOSURE- VAPOR CONCENTRATIONS ABOVE 2000 PPM•,MAY CAUSEIRRITATION, 'DIRECT-CONTACT MAY CAUSE PAIN AND',•EXTREME-IRRITATION, BUT.IT I8 NOT. LIKELY TO CAUSE SERIOUS INJURY.••10,MG APPLIED TO:RABBIT EYES PRODUCED KERATITIS,IRITIS, INCREASED :CORNEAL THICKNESS, AND INFLAMMATION. OF THE CONJUNCTIVA' AND EYELIDS WITH SOME. EFFECTS` LASTING'UP.TO TWO WEEKS.' OHSHY918 PAGE 008 OF 013 RONIC EXPOSURE- REPEATED OR PROLONGED EXPOSURE TO IRRITANTS MAY CAUSE CCONJUNCTIVITIS. PROPANE: ACUTE EXPOSURE- VAPOR CONCENTRATIONB'OF 100,000 PPM WERE NOT NOTICEABLY IRRITATING TO THE EYES. DUE TO RAPID EVAPORATION, THE LIQUID MAY CAUSE FROSTBITE WITH.REDNESS, PAIN AND BLURRED VISION. CHRONIC EXPOSURE- NO DATA AVAILABLE. :ISOBUTANE: • ACUTE- EXPOSURE -.NO ADVERSE EFFECTS HAVE.BEEN REPORTED.FROM THE GAS. DUE TO RAPID :EVAPORATION, THE LIQUID'MAY CAUSE FROSTBITE WITH REDNESS,. PAIN, AND BLURRED VISION. CHRONIC EXPOSURE-NO DATA.AVAILABLE.• METHYL ALCOHOL:,(METHANOL): IRRITANT. ACUTE EXPOSURE - :VAPORS MAY.CAUSE IRRITATION ..HIGH'CONCENTRATIONS'HAVE BEEN REPORTED TO CAUSE VIOLENT'.INFLAMMATION OF THE CONJUNCTIVA AND-'. EPITHELIAL DETECTS ON THE CORNEA'. MILD IRRITATION MAY. OCCUR WITH DILUTE SOLUTIONS; ,THE. UNDILUTED LIQUID HAS PRODUCED MODERATE CORNEAL • OPACITY AND CONJUNCTIVAL :REDNESS,IN.RABBITS. APPLICATION.OF A DROP OF METHANOL IN RABBIT EYES CAUSED A• MILD REVERSIBLE REACTION, GRADED 3 ON'A SCALE 0F1-10 AFTER 24 HOURS: • CHRONIC EXPOSURR - REPEATED OR PROLONGED CONTACT MAY CAUSE CONJUNCTIVITIS. FIRST AID- IMMEDIATELY WASH THE EYES WITH•LARGE AMOUNTS OF WATER, OCCASIONALLY. LIFTING UPPER AND LOWER LIDS, UNTIL NO EVIDENCE OF CHEMICAL REMAINS (APPROXIMATELY 15 -20 MINUTES). IF FROSTBITE IS PRESENT, WARM WATER, MAY BE PREFERRED. GET MEDICAL ATTENTION IMMEDIATELY:•., • INGESTION: DICHLOROMETHANE ,(METHYLENE CHLORIDE): NARCOTIC /CHEMICAL ASPHYXIANT. . ACUTE. EXPOSURE; MAY CAUSE 'RAPID,' THEN SLOWED RESPIRATION, GLOTTAL AND • PHARYNOEAL'EDEMA,. INTRAVABCULAR HEMOLYSIS WITH GROSB•HEMATURIA, GASTROINTESTINAL ULCERATION. AND HEMORRHAGE, AND CARBOXYHEMOGLOBINEMIA THESE,SYMPTOMS.MAY PROGRESS: RAPIDLY TO UNCONSCIOUSNESS AND'LACK OF RESPONSE. TO. PAINFUL: STIMULI. PHARYNGEAL • EROSIONS MAY DISTURB.THE SWALLOWING MECHANISM.RESULTING,IN' ASPIRATION .PNEUMONIA.'IN.ADDITION,. . SYMPTOMS OF CENTRAL NERVOUS.SYSTEM DEPRESSION MAY OCCUR FOLLOWED BY. CONVULSIONS AND_PARESTHESIA DF.THE EXTREMITIES: LARGE'DOSES,MAY CAUSE LIVER AND 'KIDNEY,DAMAGE..THE.ESTIMATED. LETHAL DOSE FOR AN.ADULT.IS'25 GRAMS. CHRONIC EXPOSURE- :REPEATED INGESTION BY RATS AND MICE RESULTED:IN , HISTOMORPHOLOGICAL,CHANGES IN THE'LIVER. PROPANE: ACUTE EXPOSURE-':INGESTION FROSTBITE_DAMAOE.OF THE CHRONIC EXPOSURE - NO DATA ISOBUTANE: ACUTE EXPOSURE-. INGESTION FROSTBITE DAMAGE`OF.THE CHRONIC EXPOSURE - NO DATA OF A GA8.I8 UNLIKELY. IF THELIQUID'I5 SWALLOWED,; LIPS, MOUTH AND MUCOUS.MEMBR , AVAILABLE:.,, OF A GAS I8'UNLIKELY, IF, THE LIQUID I8, SWALLOWED, LIPS, MOUTH AND MUCOUS.MEMBRANES'MAY OCCUR, AVAILABLE,' OHSITY918 PAGE 009 OF 013 YL ALCOHOL (METHANOL):. OTIC /NEUROTOXIN. ',:JUTE EXPOSURE - MAY CAUSE MILD AND TRANSIENT INEBRIATION AND SUBSEQUENT DROWSINESS FOLLOWED BY AN ASYMPTOMATIC PERIOD LASTING 8 -48 HOURS. FOLLOWING THE DELAY, COUGHING, DYSPNEA, HEADACHE, DULLNESS, WEAKNESS, VERTIGO OR DIZZINESS,.NAUSEA, VOMITING, OCCASIONAL DIARRHEA, ANOREXIA, . VIOLENT PAIN IN THE BACK,:ABOOMEN, AND• EXTREMITIES, RESTLESSNESS,' APATHY OR DELIRIUM,. AND RARELY,, EXCITEMENT AND MANIA MAY•OCCUR. RAPID, 'SHALLOW RESPIRATION DUE TO METABOLIC, ACIDOSIS, COLD AND CLAMMY SKIN,, HYPOTENSION, CYANOSIS, OPIBTHOTONOS, CONVULSIONS, MILD TACHYCARDIA, CARDIAC DEPRESSION, PERIPHERAL NEURITIS; CEREBRAL AND PULMONARY EDEMA,' UNCONSCIOUSNESS, AND. .COMA ARE, POSSIBLE.' EFFECTS ON THE EYE MAY INCLUDE OPTIC NEURITIS, BLURRED .. OR DIMMED,VISION, DILATED,,UNRESPONSIVE PUPILS, PTOBIS, EYE'PAIN, CONCENTRIC CONSTRICTION ,OF VISUAL FIELDS, DIPLOPIA, CHANGE IN COLOR • PERCEPTION;,PHOTOPHOBIA, AND OPTIC NERVE :ATROPHY. PARTIAL BLINDNESS OR- POSSIBLY-DELAYED TRANSIENT OR'PERMANENT BLINDNESS MAY OCCUR. BILATERAL SENSORINEURAL.DEAFNESS HAS BEEN REPORTED IN A SINGLE CASE. LIVER, KIDNEY, HEART,' STOMACH,. INTESTINAL AND :PANCREATIC DAMAGE MAY'ALSO OCCUR. DEATH . • MAYBE DUE TO RESPIRATORY FAILURE OR'RARELY.FROM CIRCULATORY COLLAPSE. . AS LITTLE AS 15.ML HAS CAUSED BLINDNESS; THE USUAL'FATAL DOSE I8 60 -240 Mt.. PROLONGED ASTHENIA'AND IRREVERSIBLE EFFECTS ON THE NERVOUS SYSTEM INCLUDING DIFFICULTY IN SPEECH,' MOTOR DYSFUNCTION WITH RIGIDITY, SPASTICITY, AND HYPOKINESIS HAVE BEEN REPORTED. . CHRONIC EXPOSURE - REPEATED INGESTION MAY CAUSE VISUAL IMPAIRMENT AND'.,., BLINDNESS AND OTHER SYSTEMIC EFFECTS AS DETAILED IN.ACUTE INGESTION.. REPRODUCTIVE EFFECTS HAVE BEEN REPORTED IN ANIMALS. FIRST AID- SEEK MEDICAL ATTENTION' IMMEDIATELY.•TREAT SYMPTOMATICALLY AND SUPPORTIVELY. MAINTAIN AIRWAY AND. RESPIRATION..,IF VOMITING. OCCURS, KEEP HEAD BELOW HIPS TO PREVENT.ASPIRATION. IF A POISONOUS SUBSTANCE HAS:BEEN • INGESTED, REMOVAL BY,EMESIS.OR GASTRIC,LAVAGE WITH APPROPRIATE PRECAUTIONS TO PREVENT ASPIRATION IS RECOMMENDED ,PROVIDED'THE'PATIENT IS CONSCIOUS,'NOT.CONVULSING AND THERE IS'NO SIGN OF CORROSIVE INJURY. ONLY QUALIFIED MEDICAL PERSONNEL SHOULD PERFORM GASTRIC LAVAGE. IF A CORROSIVE SUBSTANCE HAS BEEN INGESTED, DILUTION BY RINSING.THE MOUTH.AND GIVING•WATER OR MILK TO DRINK I8. GENERALLY'RECOMMENDED. IF PERFORATION HAS OCCURRED OR' • THE VICTIM I8 UNCONSCIOUS,, THE. VICTIM. SHOULD NOT BE GIVEN ANYTHING TO'DRINK. C REACTIVITY REACTIVITY: STABLE UNDER NORMAL TEMPERATURES AND' PRESSURES.,_, INCOMPATIBILITIES; DICHLOROMETHANE ,(METHYLENE:CHLORIDE);•: ALKALI METALS : :40SSIBLE EXPLOSIVE REACTION..., ALUMINUM: VIOLENT ,'.UNCONTROLLABLE.REACTION ABOVE 95'C.', CAUSTICS ( STRONG); VIGOROUS;.POS0IBLY VIOLENT. REACTION:., . COPPER: MAY CORRODE AT ELEVATED :TEMPERATURES IN•THE PRESENCE OF MOISTURE,, DINITROGEN:PENTOXIDE: POSSIBLE.EXPLOSION. • DINITROGEN TETROXIDE: "FORMS SHOCK - SENSITIVE. MIXTURE. IRON: MAY CORRODE AT, ELEVATED. TEMPERATURES. IN. THE PRESENCE 0F: MOISTURE:•: LITHIUM: FORMS „SHOCK - SENSITIVE :MIXTURE.'- . MAGNESIUMt'POSSIBLE EXPLOSION..' NICKEL: MAY CORRODE, AT '..ELEVATED TEMPERATURES IN THE. PRESENCE, OF. MOISTURE.: NITRIC ACID:: EXOTHERMICEACTION YIELDING. DETONABLE SOLUTION:.. OXIDIZERS _(STRONG) {;'_FIRE_AND,EXPLOSION HAZARD.. ., • OHSITY91B C XYGEN (LIQUID): EXPLOSIVE REACTION ON IGNITION. ASTICB,,RUBBER, AND COATINGS: MAY BE ATTACKED. jTASSIUM::EXPLOSIVE REACTION . POTASSIUM HYDROXIDE + N- METHYL— N-NITROSO UREA: POSSIBLE POTASSIUM TERT- BUTOXIDE: IGNITION REACTION.. SODIUM: FORMS SHOCK- SENSITIVE'MIXTURE.. SODIUM - POTASSIUM ALLOY:. FORMS SHOCK- SENSITIVE MIXTURE.. STAINLESS STEEL: MAY CORRODE AT ELEVATED TEMPERATURES.IN'•THE MOISTURE. • TITANIUM: POBBIBLE VIOLENT REACTION.. ZINC: POSSIBLE. VIOLENT REACTION.. PROPANE: BARIUM PEROXIDE: VIOLENT. EXOTHERMIC REACTION.. CHLORINE DIOXIDE: SPONTANEOUS EXPLOSION. PLASTICS, RUBBER, COATINGS: ATTACKED .BY'LIQUID PROPANE. , OXIDIZERS .(STRONG): FIRE AND EXPLOSION HAZARD. ISOBUTANE:' OXIDIZERS: FIRE AND EXPLOSION HAZARD. METHYL ALCOHOL (METHANOL):• ACETYL BROMIDE ::VIOLENT :REACTION WITH. FORMATION OF HYDROGEN BROMIDE. ALKYLALUMINUM .SOLUTIONS:'.VIOLENT REACTION. ALUMINUM:. CORRODES', : BARIUM PERCHLORATE:' DISTILLATION' YIELDS HIGHLY EXPLOSIVE ALKYL PERCHLORATE. BERYLLIUM HYDRIDE: VIOLENT.REACTION,'EVEN AT - 196.C. BROMINE: VIGOROUSLY EXOTHERMIC REACTION. CALCIUM CARBIDE:,' VIOLENT REACTION.. CHLORINE: POSSIBLE IGNITION AND•EXPLOSION HAZARD.' CHLOROFORM,AND,SODIUM HYDROXIDE:, EXPLOSIVE REACTION, CHROMIUM, TRIOXIDE (CHROMIC'ANHYDRIDE): POSSIBLE.IGNITION.. CYANURIC CHLORIDE:'VIOLENT'REACTION. .. DICHLOROMETHANE:,POSSIBLE IGNITION AND EXPLOSION.. DIETHYL ZINC;.POSSIBLE'IGNITION AND °EXPLOSION. HYDROGEN. PEROXIDE.+ WATER':.EXPLOSION'HAZARD.' IODINE + 'ETHANOL + MERCURIC OXIDE:' EXPLOSION'HAZARD.. LEAD:. CORRODES. °AD PERCHLORATEs'EXPLOSION HAZARD. .,,3NESIUM:'VIOLENT REACTION,. r:AGNESIUM (POWDERED): M75XTURES :ARE CAPABLE OF DETONATION, METALS: INCOMPATIBLE.. NICKEL: :POSSIBLE:IGNITION IN:THE.PRE$ENCE OF'NICKEL CATALYST;.'', NITRIC ACID -(CONCENTRATED }:,MIXTURES OF GREATER THAN 25% ACID.MAY DECOMPOSE ': VIOLENTLY. OXIDIZERS (STRONG).: FIRE'AND.EXPLOSION HAZARD.:. PERCHLORIC ACID:'EXPLOSION`HAZARD , ": PHOSPHOROUS TRIOXIDE; .'POSSIBLE VIOLENT. REACTION AND IGNITION.: PLASTICS, RUBBER ,`COATINGS :.MAY., DE' ATTACKED,' POTASSIUMs,POSSIBLE DANQEROUS ;REACTION.: POTASSIUM HYDROXIDE` +'CHLOROFORM:' EXOTHERMIC REACTION,' POTASSIUM ,TERT- BUTOXIDEs;,FIRE AND EXPLOSION'HAZARD. SODIUM + .CHLOROFORMi:POS$IBLE'EXPLOSION SODIUM HYPOCHLORITE {;EXPLOSION HAZARD:. SODIUM METHOXIDE.+ CHLOROFORMs'VIOLENT•REACTION.' SULFURIC'ACID: FIRE AND EXPLOSION HAZARD. `.": ZINC: EXPLOSION.HAZARD. OHSITY918 PAGE 011 OF 013 CMPOSITION: 4AL DECOMPOSITION MAY RELEASE TOXIC AND /OR HAZARDOUS GASES. POLYMERIZATION: HAZARDOUS POLYMERIZATION HAS NOT BEEN REPORTED TO OCCUR UNDER NORMAL TEMPERATURES AND PRESSURES. STORAGE AND DISPOSAL OBSERVE ALL FEDERAL, STATE AND LOCAL REGULATIONS WHEN STORING OR DISPOSING OF THIS SUBSTANCE. FOR ASSISTANCE, CONTACT THE DISTRICT DIRECTOR OP THE ENVIRONMENTAL PROTECTION AGENCY. * *STORAGE ** STORE IN ACCORDANCE WITH 29 CFR 1910.101. BONDING AND GROUNDING: SUBSTANCES WITH LOW ELECTROCONDUCTIVITY, WHICH MAY BE IGNITED.BY ELECTROSTATIC SPARKS, SHOULD BE'STORED IN CONTAINERS WHICH MEET THE'BONDING AND GROUNDING GUIDELINES SPECIFIED.IN NFPA 77 -1983, RECOMMENDED PRACTICE ON STATIC ELECTRICITY. STORE AWAY FROM•INCOMPATIBLE SUBSTANCES. DISPOSAL MUST BE IN ACCORDANCE WITH STANDARDS APPLICABLE TO GENERATORS OF HAZARDOUS WASTE, 40 CFR 262. EPA HAZARDOUS WASTE'.NUMBER D001. 100 POUND CERCLA SECTION,103_REPORTABLE QUANTITY. CONDITIONS AVOID CONTACT WITH HEAT, SPARKS, FLAMES BE EXPLOSIVE, DO'NOT ALLOW CONTACT WITH CONTENTS ARE UNDER PRESSURE; CONTAINERS CONSIDERABLE DISTANCE, C TO AVOID OR OTHER IGNITION SOURCES. VAPORS MAY SKIN; MATERIAL MAY CAUSE FROSTBITE. MAY RUPTURE VIOLENTLY AND TRAVEL A SPILL AND LEAK PROCEDURES WATER SPILL; THE CALIFORNIA SAFE DRINKING WATER AND TOXIC (PROPOSITION ,65)' PROHIBITS. CONTAMZNATING ANY WITH SUBSTANCES TO CAUSE CANCER AND /OR • ENFORCEMENT ACT OF 1986. KNOWN SOURCE'OF DRINKING WATER REPRODUCTIVE TOXICITY.., OCCUPATIONAL SPILL: SHUT OFF IGNITION SOURCES. DO NOT TOUCH SPILLED MATERIAL, STOP LEAK IF YOU CAN DO IT WITHOUT RISK. USE WATER SPRAY TO REDUCE VAPORS, ISOLATE AREA UNTIL GAS HAS DISPERSED. N0 SMOKING, FLANES OK FLARES IN HAZARD AREA! KEEP UNNECESSARY PEOPLE AWAY; ISOLATE HAZARD AREA AND DENY. ENTRY. VENTILATE CLOSED SPACES BEFORE. ENTERING, QUANTITY (RQ): THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT. (SARA)'SECTION 304 REQUIRES THAT A RELEASE EQUAL TO OR GREATER THAN THE, REPORTABLE QUANTITY. ESTABLISHED. FOR THAT SUBSTANCE BE IMMEDIATELY REPORTED TO THE LOCAL EMERGENCY PLANNING AND THE STATE EMERGENCY RESPONSE COMMISSION (40 CFR 355.40). IF THE OHSITY918 PAGE 012 OF 013 C EASE OF THIS SUBSTANCE I8 REPORTABLE UNDER CERCLA SETION 103, THE NATIONAL )NSE CENTER MUST BE NOTIFIED IMMEDIATELYAT..(800424 -8802. OR ;.) 426 -2675 IN THE METROPOILITAN WASHINGTON, D.C. AREA (40 CFR 302.6)., PROTECTIVE EQUIPMENT VENTILATION: PROVIDE LOCAL EXHAUST OR PROCESS ENCLOSURE VENTILATION TO MEET PUBLISHED EXPOSURE LIMITS. RESPIRATOR: THE FOLLOWING RESPIRATORS ARE RECOMMENDED BASED ON INFORMATION POUND IN THE PHYSICAL DATA, TOXICITY AND HEALTH EFFECTS SECTIONS.' THEY ARE.RANKED IN ORDER.FROM MINIMUM TO MAXIMUM RESPIRATORY PROTECTION.. THE SPECIFIC RESPIRATOR SELECTED MUST BE BASED ON CONTAMINATION LEVELS FOUND IN THE WORK PLACE, :MUST BE BASED ON THE SPECIFIC OPERATION, MUST NOT EXCEED THE. WORKING LIMITS OF THE RESPIRATOR AND MUST. BE JOINTLY APPROVED BY.THE NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY AND HEALTH AND THE MINE SAFETY AND HEALTH ADMINISTRATION (NIOSH- MSHA). ANY TYPE 'C'. SUPPLIED -AIR RESPIRATOR WITH.A.FULL FACEPIECE OPERATED IN . PRESSURE- DEMAND'OR OTHER POSITIVE'PRESSURE.MODE OR WITH A FULL FACEPIECE, HELMET OR HOOD OPERATED IN CONTINUOUS -FLOW MODE. ANY SELF- CONTAINED BREATHING APPARATUS WITH A FULL FACEPIECE OPERATED IN PRESSURE- DEMAND OR OTHER POSITIVE PRESSURE MODE, FOR FIREFIGHTING AND OTHER IMMEDIATELY. DANGEROUS TO LIFE OR HEALTH CONDITIONS: ANY SELF - CONTAINED BREATHING'APPARATUS THAT'HAS A FULL'FACEPIECE AND IS OPERATED IN A PRESSURE- DEMAND OR OTHER POSITIVE - PRESSURE MODE. • ANY SUPPLIED -AIR RESPIRATOR THAT,HAS A.FULL'FACEPIECE AND IS.OPERATED IN PRESSURE - DEMAND OR•OTHER POSITIVE- PRESSURE MODE IN COMBINATION WITH AN AUXILIARY SELF- CONTAINED,BREATHING APPARATUS OPERATED IN PRESSURE - DEMAND , OR OTHER POSITIVE- PRESSURE MODE. c 0 3IN0:.. eLOYEE MUST WEAR APPROPRIATE'PROTECTIVE (IMPERVIOUS) CLOTHING AND. EQUIPMENT . TO PREVENT REPEATED.OR PROLONGED SKIN CONTACT WITH THIS SUBSTANCE; GLOVES: . EMPLOYEE MUST WEAR` APPROPRIATE PROTECTIVE.OLOVES TO PREVENT CONTACT WITH THIS - SUBSTANCE. .. EYE PROTECTION: ... ; . EMPLOYEE MUST WEAR SPLASH - PROOF :OR'DUBT - RESISTANT SAFETY000OLES :AND A .'. FACESHIELD TO. PREVENT. CONTACT WITH'THIS SUBSTANCE." ., • EMERGENCY WASH FACILITIES: WHERE THERE IS.ANY POSSIBILITY, THAT AN.EMPLOYEEIS EYES AND /OR'SKIN MAYBE • EXPOSED TO THIS SUBSTANCE, 'THE EMPLOYER, SHOULD PROVIDE AN EYE. WASH FOUNTAIN'. AND QUICK DRENCH SHOWER WITHIN. THE IMMEDIATE WORK AREA•FOR EMERGENCY USE: :,'. OHSITY91B PAGE 013 OF 013 OPYRIGHT 1993 OCCUPATIONAL HEALTH SERVICES, INC.. ALL RIGHTS RESERVED. .. CREATION DATE: 06/30/92 REVISION DATE: 12/04/92 . PROPANE PRP Common 5ynonyn s Ownelnykm11m4ne .w10+1 comresIed L01000111 00110.11010v "04.1' '„/ ,..um uw1 41810,1 :0le0 110111 441 4.0.14 44 *elm f .,1,4,41•01.4 .44.444 44004 _■14.41 1 :1(114[411 '. D .1.V4 014. ' :,ASSA4' • 1.0 L4'9N,: 1.4' ^cal r" •J''C" S'44..4S 4^.7 :a '4.'1404" '.' 'AA, 040m•.' 44.1 '.10 *air X/1,'1 •400' •'0101 1.)44 "41.18 and 0,1.1.00 .0 •t1• l4'") :.S Fire rtAMMABLE '.4mane11 mar 400 004 0 44 • 0 411b1t1 long 4a014 11044 "'ay CCC0 11004 may 1140008 4 ynny: n 48 80Cbled yea 'x100 1108 0' pis 4 0080.111 '.004 4400004 0001410440 a'C 0.01001 urn 00••01.1v1 S00I.00 14911 *1101 .41104 040 :ALL FCR MECICA. l' VAPOR 401 imam, t0 111. n4N Of 71,041 4 ■444440. w01 cause b724Mts 0,41044 breading of 011 01 conv.cus.noss VOVO 10 '8.11 40 Ye11lvn0 AS 8'70000 7,4 4' 10414espra'4r' ' 44eatni g 6 74004 304 :0.700 LIQUID May cause NOttb4. • •An &neve° atom *O M 0wh O' *aim .73 NOT 440 4F054'. 4=545 INIMMONI Exposure Water Pollution Na harmful to .o.cic We 1. RESPONSE TO DISCHARGE Moe Rospo eo Methods 111041 wwm}ngln ttamma0:ty Handbooal 2. LABEL 2.1 Category: F4nwnaa. gas 2.2 Class: 2 Re10,01 access EvaCwls MN 3. CHEMICAL DESIGNATIONS 3.1 CO Colnp.Ue/Ry Close: PoeHn 3.2 Formic CMICo',CH, 3.3 1140/1102 01.494bon: 2 041975 3.4 DOT ID Ho: *ill 3.5 CAS Registry No.: 14.96.0 4. OBSERVABLE CHARACTERISTICS 4.1 Physical State (es sMpp.d0 Los6r0 cam0011100 9P6 4.2 Coen. Coion.0 4.3 Odor. Font gassy S. HEALTH HAZARDS' 5.1 Personal Pro1101481 G4u4me41t S.II.0001an03 0.141nn9 070a /Out tor Nun concentrations of 941 5.2 Symptoms Following Exposurr: V$ponneg nab may cause 110slale. Concenultona in ar grate than 10%. cause OISbOVY M a 144 OvnuN/ I'S. C000,n01e041 901114 same effect In 10 min Mon ca1CMb1W00 0*001 1101)tat44 5.3 Trestnrnt of Elpoours: Rommel 10 open W I vlcun is overcome by gas, apply artificial revile /1100 0.drd against 64441.1', 4 contused S.4 Tlwvahoki Lase VMS: Asonnanl 5.5 5ho41 Term Inhalation LAME Data no 14ae:v. it Toxlcty by Ingestelt Not pertinent 5.7 Late Toxlclty. Noe 51 Vapor IDae) brt6M0 Ch4ractene ce VU7a1 04.0 nonentaar9 10 Ins ores and ihr0al. S 1 Uauld or 5060 WWI Chara:ts,elles: ND 4.•a.clab4 1U1442 P•pc4c411y 144041015 40 Ire Nn 6104414* 4 1IIDaees coca,. 5.10 0008 ThweMOMt 5 000.20.000 0014 5.11 IDLN Value X 300 p0m s 1 6 2 6 3 4 4 6 (IRE HAZARDS nosh Point - 4441'T r• •' rlMwn8N Limns In A0 114,4 5♦ Firs Eltn uishi g Aeon& 5,00 hew cat 4■1 Tw Small Ives 404 wy cmrmwa11 Ul oaacent areas •e" 44110 10,44 0 ,. E.ttngulmnwq Agents Hcl low Used: Waver 10. HAZARD ASSESSMENT CODE 1510 Heard A.naament Hs,ldbooa) A•B•C•O'E•F43 I1 HAZARD CLASSIFICATIONS 6 5 504smal 4101eW of Combustion 11.1 Cods of FedWal Regulations: Pr001104 : 7404 pMlnem F.amma• 946 9 6 Botevi0r M Fine: Conlon.% 414v 4401004 11 2 HAS Wree R•tlrg 40' BWa WNW 111X1 Is 0141184 than 48 400 may 1,W44 a T1anp0/bMOrt: 0n0 0,040C1110 a sours 04 4)40140n orb Ca•gvy Reline "ash 11400 Foe 4 6 7 Ignition Temperature. 612'0 moon 6.1 ENetneal Hazard: Class Stout: 0 • Vapor innate 0 61 Burning Rale 82 mmlmr 14700 Or So84 tn41n1 . . 0 6 10 Adiabatic Flame Temporalure 2440 (E611 Poison .. . . 0 Wets, Poanbn Human Toxicity .. 0 (CunA•hed) Aquae/ Tonuty .. .. .. . 0 7. CHEMICAL REACTIVITY ReOCbnty 7 1 RelcM ty With Water. No teactw7n Oho Cherrrcals ...... ...... 0 7 2 Reactivity with Connor! Meeta4a: No W4is, ......... .. .... ...... 0 •eacl0n Soli Reacba1 . ... 0 7.3 Staaety During Transport Stab., 11.] NPPA Maud aasiReOUOm 7 4 Heutra1zl g Aponte for Apes and Category Cbnitication Caw06y Not pMnlnl 1/1044110 Itais,d MOO ......... ....... I 7.5 Polymerisation: Not pertinent ;hm naoiry (Red) ..........• ..... 4 7.6 Inhibitor of Polymerttsf10ft '401 pe11en1 7.7 Molar 4116o (Reactant 10 Product: Data not avwtao4 7.1 RuctIvfy oioue 31 12. PHYSICAL MO CHEMICAL PROPERTIES 12.1 Phyel0al SSW 01 11'C and 1 aim Gas 12.2 14e2nlds, 9415245 44.09 12.3 Soling Point M 1 Obew -47 s,'0 . -421'C • 231.1'1( 12.4 Flossing Port B. WATER POLLUTION - 3059'F . - 447.7'P - 655'K 12.5 Cr1BSal Tempenber, 6 t Oust* Toxicity. 2060'F . 96.67'C . 369.6174 Nr0r1. 12.6 CrIBaal PrMMlee 1.2 Watortowl Toxe0y: Nor 616.5 po0 . 41.94 Om • 4.240 5.3 Biological Oxygen Demand (0001 MN /m1 None 12.1 80044416 Ore.By: 1.4 Food Chain ConoenY /eon Pofsntlet 0.690 al -50'C (road) None 12.4 LqW 1Rwfae. Tondos 16 drnear m . 0.016 Nlm al •47'C 12.9 Liquid Water Inter5a0W Twelon, (rat 1 50 0141•14/ CM . 0.05 Wm at -50'C 12.10 Viper (Owl SMeMc 020yity: 1.5 12.11 Rage of Noah: Heels at Vapor (Clasp 1.130 12.12 Latent Hat el VaPOrte tort 163.2 84/15 • 101.6 cai/g . 4.262 0 10, Drag 12.13 140.2 of Conboadi.0 - 10,762 Btullo . 9. SHIPPING INFORMATION - 10.990 ogre • -460 13 0 101 Jag 12.14 Heat of Dooseepeeltlet Not pertinent 9.1 Oradea 0f hr0y: Research. net/went. Or 12.15 Nw/ Of $eG1Bs,t Not peratrnl Pun: 05135. 'r Tecrwecal 97 50 1. 12.11 Nose of PW7OnrIOBUC 1101 perhron1 9.2 Stooge T.mpWMHO: Amore 12.21 NW of Poem Doe not avaNbe 9.3 Inert Almo.phem: No roommate 12.29 LJr4Nlq Vol um Data not anlable 9.4 Venting Safety IoW( 12.27 ROB V•Or Presire: 110 M 6. FIRE HAZARDS (C*hA*.sd) 6.11 SIoehlorti,lnc Mt l0 Fuse Rine: 1560 (Est.) 6 12 Flame TempMlt.e: Data '71 avolsb4 JUNE 1985 PRP PROPANE 12.17 SATURATED LIOUID DENSITY Temperature Pounds per cubic (degrees F) loot 12.18 LIQUID HEAT CAPACITY Temperature British thermal unit (degrees F) per pouno•F 12.19 LIQUID THERMAL CONDUCTIVITY Temperature British thermal (degrees F) urnl•mch per hour- square loot•F 12.20 LIQUID VISCOSITY Tem Temperature (degrees F) CenUpotse -180 Temperature (degrees F) 41.480 -50 i Pounds per cubic • foot 546 N -145 433 -175 -230 41.290 .00003 • .0 0 -140 ,413 -170 ' .004 41.100 t '. .00007 ' ' T -135 .395 -165 -210 40.910 -210 • ,00015 -130 .378 • -160 40.720 ,019 -200 P -125 .362 -155 .397. 40.530 -190. ,039 -190 E -120 .347 -150 i 40.340 -180 .074 R -115 333 -145 125 40,150 .429 -170 T -110 .321 -140 .00190 39.980 {{ ' :444, I . -105 ' .309 -135 . 39.770 175 j .459, N -100 .297 -130 39.580 ' . .00504 200' E -95 .287 -125 -140 39.390 .00777 ' 225 . N -90 .277 -120 .931 39.190 ' ' ' .01160 T -85 .268 -115 -120 , 39.000 -120 ,01685 -80 .259 -110. ' 38.810 -110 • -75 .251 -105 38.620 -100 .03296 -70 .243 -100 :. 38.430 4,017 -90 -65 .236 -95 .562 38.240 -80 5.480 -80 -60 .229 -90 I' 38.050 -70 7.344 • -70 -55 .222 -85 ' ' 400 37.860 .590 ' -60 1 9.680 i -50 .216 -80 425 37,670 .603 -50 ! 12.570 -50 -45 .210 -75 450 37.480 .617 -40 4 , 16.090 -40 -70 475. 37.290 ,630 1 -30 . 20.340.. , , -30 • -65 ... 500 37.100 ' . .643 .' . -20 25.400 .. -20 -60 525 ' 36.910 .657 -55 550. 38.720 . :669. .. . .575 i .682 1 12.21. SOLUBILITY IN WATER 12.22 SATURATED VAPOR PRESSURE 12.23 SATURATED. VAPOR DENSITY 12.24 IDEAL OAS HEAT CAPACITY Temperature ' Pounds per 100 (degrees F) pounds 01 water Temperature (degrees F) . Pounds per square inch ' Temperature (degrees F) i Pounds per cubic • foot Temperature . (degrees F) . British thermal unit ' per pound•F mrm.CrOCAAZ - -230 ' .002 -230 .00003 • .0 .349' -220 ' . . ' .004 -220 ' t .00007 ' ' . 25 ,385 -210 .009 -210 • ,00015 50 . ..381 -200 ,019 -200 .00031 75 , . .397. -190. ,039 -190 .00060 100 i . .413. -180 .074 -180 .00109 125 .429 -170 .134 -170 .00190 150 {{ ' :444, -160 .230 -160 . •00315 175 1 .459, -150 .380 -150 .00504 200' .474 -140. ' .805 -140 .00777 ' 225 . f.. .489 -130 .931 -130 , ' ' ' .01160 250 ' . ..504 -120 , • 1.393 -120 ,01685 275 ' .519 -110 2.029 -110 .02384 300 . ' .. '.533• -100 2.886 -100 .03296 325 I .548 :. -90 4,017 -90 .04463. 350 .562 : ' -80 5.480 -80 .05929 375 I' ' .576 -70 7.344 • -70 ' .07741 400 .590 -60 1 9.680 -60 . .09948 : ' 425 .603 -50 ! 12.570 -50 .12600 450 i .617 -40 4 , 16.090 -40 .15750 475. ,630 -30 . 20.340.. , , -30 • .19440 ', 500 ' . .643 .' . -20 25.400 .. -20 .23730 ' 525 ' ' .657 . 550. i . :669. .. . .575 i .682 600 r . .695 . . MATERIAL SAFETY DATA SHEET Radiator Specialty Company 1400 W. INDEPENDENCE BLVD. • CHARLOTTE, N.C. 28208 • 704 - 377 -6555 SECTION 1 GENERAL INFORMATION M 1 I PRODUCT NAME PUNCTURE SEAL (AEROSOL) PART NUMBERS MI 1 -J 9 - 16., -24 CHEMICAL DESCRIPTION Latex Dispersion FORMULA • SECTION II HAZARDOUS COMPONENTS CAS NUMBER COMPONENT % TLV 107 -21 -1 _ Ethylene Glycol Propane /1soButane Propellant 1 -10 20 -35 50 ppm N/A * Components not 'dentilied are non - hazardous accordin. to 29 CFR 1910.1200 SECTION III PHYSICAL DATA BOILING POINT ____N /� __.. °F SPECIFIC GRAVITY (H70 =1) NLA FLASH POINT — C __ °F VOLATILE BY WT. .:> `J_ gib EVAPORATION RATE 11/A SOLUBILITY IN WATER ..Miscible..__ .. _ SOLUBILITY IN SOLVENTS ItydrnCarhnna APPEARANCE AND ODOR ._ Millar ..liy.uisl...wiChnuunr�ni;u'n 1 odor. Slightly pH Alkaline SECTION IV FIRE AND EXPLOSION DATA 'XTINCIJISHING MEDIA Water Fog _. , Foarn X . CO! ..?L . Dry Ctremicai X Other SPECIAL FIRE FIGHTING PROCEDURES Wear sell - contained, positive pressure breathing apparatus and , otactive clothing. UNUSUAL FIRE AND EXPLOSION IiF'?ARDS Contents Under Pressure. At elevated Temperatures, Containers may burst:, even violently. SECTION V REACTIVITY INFORMATION (hasud on date lo, undwidual components) STABLE UNSTABLE HAZARDOUS POLYMERIZATION? YES_ NO.X_ 1 CORROSIVE'S MATERIALS TO AVOID Oxidizing agents, Strong Acids. CONDITIONS TO AVOID Temperatures above 120 F. HAZARDOUS DECOMPOSITION PRODUCTS Fire: Normal products of combustion; carbon Nn •. . 1 • • 11 1 1 • . EMERGENCY TELEPHONE NUMBER 704 -377 -6555 This information is presented to comply with tho OSHA Hazard Communication Standard. (_; . H11 , SECTION VI' HEALTH. HAZARD INFORMATION w. f., tlMA MM +Mn'NIYM COM•O!MMi► RECOMMENDED TO OF PRODUCT . , 50 ppm CONSUMER USE. BULK HANDUNG (PROLONGED EXPOSURE) . EYE Irritant. • • Not Required, SKIN Slightly' irritating on 'long exposure. Use i de uate veni�aton • INHALATION May irritate mucous membranes. Avoid Contact . INGESTION Unlikely, Aerosol Product. . N/A Not Required ' OTHER Extremely Flammable. SECTION VII' . EMERGENCY AND FIRST AID PROCEDURES (Based on data for Individual components) EYE CONTACT Flush eye•with water for 15 minutes. If irritation persist, Consult Physician Immediately. SKIN CONTACT : , ' ' Wash with soap and water. INHALATION Move to fresh air. If adverse symptoms persist, Consult Physician Immediate INGESTION Drink water.INDUCE VOMITING. Consult Physician Immediately. SECTION VIII' •; SPECIAL PROTECTION INFORMATION ( Basod on data for t r►dtvidualcomponeft) . CONSUMER USE. BULK HANDUNG (PROLONGED EXPOSURE) . RESPIRATORY PROTECTION, . N/A • Not Required, VENTILATION Use i de uate veni�aton General Ventilation. EYE. PROTECTION. Avoid Contact Wear Goggles PROTECTIVE CLOTHING N/A Not Required ' SECTION IX SPILL OR LEAK PROCEDURES SPILL OR LEAK PROCEDURES N/A Venti Late area. WASTE DISPOSAL METHODS Dispose of In accordance with all applicable government laws and regulations. SECTION °X,:.SPECIAL PRECAUTIONS WEARING CONTACT LENSES IS INADVISABLE.. STORAGE AND HANDUNG PRECAUTIONS Contents Undgr.P.,ressure. Do Not Store at Temperatures over 120�1j �.$'tore'away from oxidizing agents* & acids. OTHER PREC/ATIQNS, DO NOT*NCTURE OR INCINERATE AEROSOL CONTAINERS.• KEEP AWAY FROM CHILDREN. HAZARD INFORMATION LABEL DATA HAZARD CODE 4aExtreme 3EHlph 2•Moderate • .1 =SlIght OaNegUgIWe FLAMMAefuTY REACTWITY • HEALTH sPEc&AL 6 Pre surer;'. While Radiator Specialty Company believes this data Is accurate as of the revision date, we make no warranty with rt'espect to the data and we expressly disclaim all liability for reliance thereon. The data is offered solely fdrybur information, Investigation, and verification. REVISED. September, 1985 KCE /sd 1 y2 -62- 7220 -01 MATERIAL SAFETY DATA SHEET 004420 THIS MSD9 Amami cnem►ca► company DIVISION OP ASHLAND OIL. INC. P. 0. BOX 2219. COLUMBUS. OHIO 43218 • I61.0 889.3333 24 -HOUR EMERGENCY TELEPHONE 16061, 324.1133 900 BICARBONATE USN COAR PW 92 widONIMIft PAGE, 1 COMPLIES WITH 20 CFR *910.1200 (THE HAZARD COMMUNICATION STANDARD) 099969199099600110099 PRODUCT NAME, CAB NUMSER, • 6G B ASHLAND CHEMICAL CO. 955 NORTH COLUMBIA BOULEVARD PORTLAND, OR 97217 ATTN, DISTRICT MANAOER OURS INTERCOMPANY MAIL .59. 11'51 05 109 DATA SHEET NO, 001E596 -001 LATEST REVISION DATE, 05/95 -95136 PRODUCT, 3024901 INVOICE, ACCLOC INVOICE DATE, 12/10/115 TO, SECTION I- PROOUCT IDENTIFICATION GENERAL OR GENERIC ID, ALKALI HAZARD CLASSIFICATION, 199) NOT APPLICABLE SECTION II- HAZARDOUS COMPONENTS INGREDIENT I (BY WT) SODIUM EIIOAR9ONATE >96 PEL 15 •1 1), PEL AND TLV ARE FOR TOTAL NUISANCE PARTICULATES. TLV 10 MO /M3 NOTE t 1) SECTION III - PHYSICAL DATA PROPERTY INITIAL SOILING POINT VAPOR PRESSURE VAPOR DENSITY SPECIFIC GRAVITY REFINEMENT NOT APPLICABLE MEASUREMENT NOT APPLICABLE NOT APPLICABLE 2.200 9 68.00 DEG F t 20.00 DEG 0) PERCENT VOLATILES NOT APPLICABLE EVAPORATION RATE NOT APPLICABLE SECTION I -FIRE ANO EXPLOSION DATA FLASN POINT NOT APPLICABLE E XPLOSIVE LIMtt NOT APPLICABLE EXTINGUISHING MEDIA, UNUSUAL MIRE 1. EXPLOSION HAZARDS, NOT APPLICABLE SECTION V- HEALTH HAZARD DATA P ERMIeSIHLE EXPOSURE LEVEL 16 THRtgHOLt! LIMIT VALUE 10 EFFECTS OF OVEREXPOSURE, FOR PRODUCT MG /M3 MG /M3 EYES - CAN CAUSE IRRITATION. SKIN - MAY CAUSE IRRITATION. 9REATHIND - OF OUST CAN CAUSE IRRITATION OF NASAL AND RESPIRATORY PASSAGES. S WALLOWING - MAY CAUSE • GASTROINTESTINAL IRRITATION. F2fiet AID, IF ON OK2N1 THOROUGHLY WASH EXPOSED AREA WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING. LAUNDER CONTAMINATED CLOTHING BEFORE RE -USE. IF IN EYES, FLUSH WITH LARGE AMOUNTS OF WATER, LIFTING UPPER AND LOWER 1.2138 000ABIONALLV, GET MEDICAL ATTENTION. IF SWALLOWED, IMMEDIATELY DRINK TWO GLASSES OF WATER AND INDUCE VOMITING BY EITHER DIVING IPECAC SYRUP OR BY PLACING FINGER AT BACK OF THROAT. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUB PERSON. GET MEDICAL ATTENTION IMMEDIATELY. SF SREATHEO, REMOVE INDIVIDUAL TO FRESH AIR. SECTION VI- REACTIVITY DATA HAZARDOUS POLYMERIZATION, CANNOT OCCUR ',2- ea- 781'go -o4. MATERIAL SAFETY DATA SHEET 00441(0 Ashland Chemical Company DIVISION OP ASHLAND OIL. INC. P. 0. BOIL 2210. COLUMBUS. OHIO 43218 • 18141 888.3333 24 -HOUR EMERGENCY TELEPHONE 16061324.1133 Akt MIE vSSfir' '"24.-1",,. DOD BICARBONATE UBP COAR PW 02 AINOOkribr AShiand0 1,11110111W c' PAGE' 2 SECTION VI- REACTIVITY DATA (CONTINUED) S TABILITY' STABLE INCOMPATIBILITY' AVOID CONTACT WITH', STRONG MINERAL ACIDS. SECTION VII -SPILL OR LEAK PROCEDURES STEPS TO SE TAKEN IN CASE MATERIAL 20 RELEASED OR SPILLED' S MALL SPILL' SWEEP UP MATERIAL ONTO PAPER. LARGE SPILL' SHOVEL MATERIAL INTO CONTAINERS. THOROUGHLY SWEEP AREA OF SPILL TO CLEAN UP ANY RESIDUAL MATERIAL. WASTE bt0POSAL METHOD' SMALL SPILL' DISPOSE OF IN ACCORDANCE WITH ALL LOCAL, STATE AND FEDERAL REOULATIONB. LARGE SPILL' DISPOSE OF IN ACCORDANCE WITH ALL LOCAL, STATE AND FEDERAL REGULATIONS. SECTION VIII - PROTECTIVE EQUIPMENT TO SE USED RESPIRATORY PROTECTION' IF NEEDED UBE A NIOBH /MBHA JOINTLY APPROVED DUST RESPIRATOR.(ASK YOUR BAFETV EQUIPMENT SUPPLIER) • VENTILAT2ON' PROVIDE SUFFICIENT MECHANICAL (GENERAL AND /OR LOCAL EXHAUST) VENTILATION TO MAINTAIN EXPOSURE BELOW LEVEL OF OVEREXPOSURE (FROM KNOWN, SUSPECTED OR APPARENT ADVERSE EFFECTS). EYE PROTECTION' WEAR SAFETY GLASSES IN COMPLIANCE WITH OSHA REGULATIONS. (CONSULT YOUR SAFETY EQUIPMENT SUPPLIER) OTHER PROTECTIVE EQUIPMENT' NORMAL WORK CLOTHING OOVERXNO ARMS AND LEGS. SECTION IX- SPECIAL PRECAUTIONO OR OTHER COMMENTS CONTAINERS OF THIS MATERIAL MAY OE HAZARDOUS WHEN EMPTTED.SINOE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUES (VAPOR, LIQUID, AND /OR SOLID), ALL HAZARD PRECAUTIONS GIVEN IN THE DATA SHEET MUST. BE OBSERVED. THE INFORMATION ACCUMULATED HEREIN IS BELIEVED TO BE ACCURATE BUT 20 NOT WARRANTED TO BE WHETHER ORIGINATING WITH THE COMPANY OR NOT. RECIPIENTS ARE ADVISED TO CONFIRM IN ADVANCE OF NEED THAT THE INFORMATION XS CURRENT, APPLICABLE, AND SUITABLE TO THEIR CIRCUMSTANCES. • MORTON THIOKOL. INC. PAGE 1 Ventron Products I' l ANDOVER STREET • ANVERS, MA 01923 1I;11GENCY INFORMATION: ChemTtec.1.800.424.9300 PnOOUCT CODE: 15105 ISSUE DATE: Nov. 1985 r1EVISED DATE: FOR INFORMATION CONTACT: VENTRON HEALTH AND SAFETY DEPT. (617) 774.3100 0 • • . IDENTIFICATION I'NUUUCI NAME: "VenPur13 ** So luEion- ':rtl(11IVIMi None NitkIIITEMNIgil INGREDIENTS (n 1t11 ni A nppncially formulated aqueous solution of.: cnsr: /: • PEL. TLV,— ACGWH:. .Sodium 8orohydride :- 16940 -66 -2 5 -12 None * ** ' None***,.. •Soditna:�Hydrexide 1310 -73 -2 '.35 -55 2mg /m3 2mg /m3' CHEMICAL FAMILY: Alkaline Solution of Na804 CAS": See below MOLECULARFORMULA•NnBI4, NeOR, in water 'i; atuaF11RM NIIYSlcb•4 q I% r 11111(1 roue (tROnln, ilnl. )130 C •ri 'Jr lr,t11IAVirem.n., l 1.4 I n',n r 4A111 11 Not applicable VOLATILES 0.5 SOLUBILITY IN WATER (!b wn 100x fnEF.21b1Ol1AELTINB Pr)INii >13 C EVAPORATION BATE: None wort PfESSURE (mm Hq al ?O'CT No data (OUTYL ACETA IE : 1) n1 11I �'II)otir'n Off white clear liquid; may have slight hydrocarbon odor „ 111 r vt.scosity: 79 centipoine (23• C) 4.3TilIBMPOPP IPI r tIEOD pxPLOSIO� DATA 1 1 !,•,11 I'UII1111.1IiIllODUSF.DI None . ". •F FLAMMABLE LIMITS(!; BY VOLUME): None LEI; -!one ,III(,lmi,IIIuUll II'MI(EIIAkUnr None -. . 1 ituo 1P,11111(1Mt111n. Not applicable ' .1 111.1 v,111IIlr rnr r :rtlIIRF Will evolve :flammable hydrogen gas in contact with strong acids, or if .diluted..with large ! amounts of water i. J • MATERIAL SAFETY DATA SHEET Pnoouct cook5105 un,lll, m rg/fe ni sodium hyiltnzide mise — - r— ACOIIii1 yr mg /m3 as sodium Fiydroxide mist tllll.AI 1(1.1,•It•V . c PAGE 2 Oral(rat) 500- 1000mg /kg;Dernu1(rabbit) 100- 500mg /kg for NaBH1r solution intrnperitoneal (mouse)) /JDm k g for (Na0H) Not established None Corrosive to digestive tract - alkali burns ( Causes alkali burns . Severe. irritation Irritation of respiratory system /alkali burns 9 , ••'11 , +.I„ /.+{r•NAVA I t n (1Y 1113' x:111 (v1U.61 None known ,,,vvlm None known . u•, +nl•; 11 111inr • • '.1'I,n• 1 I I 2'41$ r • 1 • None known 1 None known •,• n ( None known . Nona known Skin and eyes ,•I,Due to severely irritating acute effects, it is unlikely that chronic (long term) effects will be observed. • I v "Il N,'Y AND FIn6T Alp P11Odinijn S .' . ._....�. • ., 0:01 Drink at least three glasses of wafer ilmiie`dIately`tio` not Induce vom(;Ein-g: �Gal�'physlc�an ana trnnsfec patient to a medical'facility Immediately. •I,,II Remove contaminated clothing. Wash affected area immediately with water. If burns are evident, seek.medical attention.. t Flush immediately with running water for fifteen minutes including under eyelids. Call physician. Examination by an opthamologist is strongly recommended. „ii •.11 .11 Remove from site to fresh air. Rinse mouth with water. Call physician. MATERIAL SAFETY Y DATA SHEET PnOnUCTC0015105 PAGE 3 INr,Mrntlnu,lty; Acids`, olciaizers, ransition metals. a urninum roes nN, nuuldr; urcomilmmnnNPnonylr;TS•Hydrogen gas when in contact with water, acids or incompatible materials. • I•rJInhI n..IfAvoln: Do not store below 12 "C or above 40•C IIy. Stable 1 None known NAZAnD0US rol.VMEnIZAIION: Will'not occur t LvialIi111111 NI ERkililoillA RTAt111 €3RIATlals '1• 'm ran' D002 I. Cn IIEnIS EnEn: Yea •111 nY 1111 MIF;Anrpnrr,F MINES: Absorb on sand /dolomite; keep from entering drains. If 'permitted by regulatory agencies, hydrolyze and neutralize waste streams on site, providing ventilation or dispose of as described in Section 11. 1111' 11•;L If regulatory agencies permit, hydrolyze and neutralize waste 'streams with large excess of water followed by Slow addition s of dilute acetic acid; provide ventilation (flammable hydrogen gas released) or as described in Section 11. 11717Wr0i,l 11OTECTICN IUFONMATtON 1.11111A11,I MroUINEMENrs Use ventilation adequate to maintain airborne concentrations below PEL /TLV or irritating levels. " 1'11•111A If Ilre PIIOIECnoN: If PEL /TLV of components is exceeded, use NIOSH approved corrosive mist respirator. 11• „1rr.l nn ta.nvrs: Rubber 11 1 rl'niii.Nrni Goggles, face shield I miT nTriawargT € IAL'P UirlitiNS 1111..11P,,ANI)RIrIAGE•• Skin protection required. Do not store near acids, oxidizers or transition metals. Do not store in aluminum or glass containers or glass lined tanks. Store in dry, well - ventilated area. p1•u,N rnv:AUrll g; Allow 102 free volume .in all closed containers. Long -term storage in sealed containers may result in ressure buiie up - check and vent container monthly. For industrial use only. • r•lIR1;R1 inAMPTS TrTiioillA oniaAnon . tl.s. D,o.T, .''• t 1 1' ^.111rI•IIIC; NAME: Sodium Hydroxide Solution, R. Q. "Am, • IA':';NIr,A11f11• Corrosive Material 1824 "FsIFIZA11,111111PomMENIs Put material into nn approved container. Dispose of at a licensed hazardous waste facility. Your local state or EPA regional office should be contacted to obtain the location of an approved facility. Standard storage and handling procedures for 502 caustic soda solutions apply to this material. Registered trademark of Morton Thiokol, Inc. * *Trademark of Moron Thiokol, Inc. ** *Although no PELITLV has been established, Sodium 8orohydride is a.corrosive liquid. • i• • , .1 ••u' . onr.l.Wlp. 11t. 011,010.11,00 cenllmrd het n 11 1 CrlI.' I All Lluntllrnl. in:1V 111110101 Ilnkn.l0,1 ho AII11101rnuk mml 0100ld IM 1o10$ 0dh r.nutlnn Allhnuph rnllnul Imranan nip descII A.11 hash• we .101,001 QIIAIAIIInh ' . .I ,• .•rl, h:1;,l.11n •01,011 0,00 1'100111/'Inhn,on111.1 01 +u11nh11lly 01 Ilan , hrinlrnl 10 II.0 Onln Ira •nns,hlIIly of the null. Dolls III 7117 cllnlnInel mhn111d AAl lily I11rnmelvos Ihnl Ills COndlllnn1 And 1„olhchle 011100 mA0111e ' ' •. 11 .n mod gnlol, 110 Or'IIEITEN IA 110,19 1111 v7AnrlA11IIEs, I IIIIFII F YrnETIED on IMPI IED. or MEICI1ANIAn4NY. FITNESS Fon A PANTICULAn PUnPOSE on ANY oflIEn NAIUnE ADE MADE IIEIE 1'■ ,y1.1� 111• ,•rl :I IQ 111E IIIrct'MAIION CONTAINED 11Cnt•U1 011 111E cnct.IICAt to WIIICII IIIE INFOMAAIIUN DEFEnS. - .. . t• OCCUPATIONAL HEALTH SERVICES, INC. 11 WEST 42ND STREET, 12TH FLOOR NEW YORK, NEW YORK 10036 1- 800 - 445 -M608 (1- 800 -445 -6737) OR 1 -212 -789 -3535 0H822280 PAGE 001 OF 008 MATERIAL SAFETY DATA SHEET FOR EMERGENCY SOURCE INFORMATION CONTACT: 1- 615 - 366 -2000 SUBSTANCE IDENTIFICATION SUBSTANCE: SULFUR CAS NUMBER: 7704 -34 -9 RTECS NUMBER:.WS4250000 TRADE NAMES /SYNONYMS: . AGRI -SUL; BENSULFOED; COSAN; CRYSTEX; ELOSAL; HEXASUL; KOLO 100; KUMULUS;. SOLFRIL; BUFRAN; BULFEX; SULPHUR; SVOVL; THIOVIT; BRIMSTONE ;. FLOWERS OF SULFUR; SULFUR FLOUR; UN 1350; SUBLIMED SULFUR; 88; 0HS22280 CHEMICAL FAMILY: NON- METALLIC ELEMENT MOLECULAR FORMULA: S8 • MOLECULAR WEIGHT: 256.48 CERCLA RATINGS (SCALE 0 -3):. HEALTH -3 FIRE.1 REACTIVITY.° PERSISTENCE -0 NFPA RATINGS (SCALE 0 -4): 'HEALTH -1 FIRE -1 .REACTIVITY.° COMPONENTS AND CONTAMINANTS COMPONENT: SULFUR CASS 7704 -34 -9 OTHER CONTAMINANTS: NONE EXPOSURE LIMITS: OCCUPATIONAL EXPOSURE LIMITS ESTABLISHED BY OSHA, ACOIN,OR NIOSH. PERCENT: 100.0 PHYSICAL. DATA DESCRIPTION: ODORLESS, TASTELESB, PALE YELLOW SOLID. BOILING POINT: 832'F (445:C)..: MELTING. POINT; SPECIFIC GRAVITY: 2.07. ;VAPOR PRESSURE: 1 MMHG 0 184'C 80LUBIL1TY IN WATERp' INSOLUBLE. SOLVENT SOLUBILITY:' SOLUBLE IN CARBON DISULFIDE, CARBON TETRACHLORIDE,' BENZENE, LIQUID AMMONIA, METHYLENE IODIDE, SLIGHTLY SOLUBLE IN TOLUENE,' ACETONE,, CHLOROFORM, ALCOHOL,. ETHER. HARDNESS .(MORS):'1.5 -2.5 OHS22280 PAGE 002 OF 008 C' FIRE AND EXPLOSION DATA FIRE AND EXPLOSION HAZARD: SLIGHT FIRE HAZARD WHEN. EXPOSED TO HEAT OR FLAME. DUST -AIR MIXTURES MAY IGNITE OR EXPLODE. MAY BE IGNITED BY STATIC ELECTRICITY. FLASH POINT:'405 F (207 C) '(CC) UPPER EXPLOSIVE LIMIT: 1400 G /M3 LOWER EXPLOSIVE LIMIT: 35 0 /M3 AUTOIGNITION TEMP.: 450 F (232 C) FIREFIGHTING MEDIAN DRY CHEMICAL, SAND, EARTH, WATER SPRAY OR REGULAR FOAM (1990 EMERGENCY RESPONSE GUIDEBOOK, DOT P 5800.5). FOR LARGER FIRES, USE WATER SPRAY, FOG OR REGULAR FOAM (1990 EMERGENCY RESPONSE GUIDEBOOK, DOT,.P 5800.5). FIREFIGHTING: MOVE CONTAINER PROM FIRE AREA •IF YOU CAN DO IT WITHOUT'RISK. APPLY COOLING .. WATER. TO SIDES OF CONTAINERS THAT. ARE EXPOSED TO FLAMES UNTIL WELL AFTER FIRE •• IS OUT. STAY.AWAY FROM•ENDS.OF TANKS. FOR MASSIVE FIRE..IN CARGO AREA, USE UNMANNED HOSE HOLDER OR MONITOR NOZZLES IF THIS IS IMPOSSIBLE, WITHDRAW•FROM' AREA AND LET FIRE BURN'(1990 EMERGENCY. RESPONSE GUIDEBOOK, DOT P 5800,5, GUIDE PAGE •32). APPLY WATER IN FLOODING QUANTITIES AS A FOG. COOL FIRE - EXPOSED CONTAINERS WITH FLOODING AMOUNTS OF WATER APPLIED FROM AS FAR A DISTANCE.AS POSSIBLE. AVOID BREATHING VAPORS OR DUSTS KEEP UPWIND., TRANSPORTATION'DATA DEPARTMENT OF TRANSPORTATION HAZARD CLASSIFICATION ORM -C iTMENT OF TRANSPORTATION LABELING REQUIREMENTS uPART Ei NONE . DEPARTMENT OF TRANSPORTATION PACKAGING REQUIREMENTS: 49 - 0 CFR 173:108 : EXCEPTIONS: 49 -CFR 173.505. • • FINAL RULE on HAZARDOUS,: MATERIALS'REOULATIONS (HMR, 49 CPR.PARTS•171- 180), • DOCKET,NUMBERS HM- 181 ,:HM,- 181A,•HM- 181B,'HM -1B1C, HM -1810 AND. HM -204. EFFECTIVE DATE OCTOBER 1;• 1991;'HOWEVER, COMPLIANCE WITH..THE REGULATIONS:.IS '.' AUTHORIZED ON.AND AFTER JANUARY 1,.'1991: (55 FR 52402, 12 /21/90)'.,' • EXCEPT FOR EXPLOSIVES, INHALATION HAZARDS,•AND'INFECTIOUS SUBSTANCES,,THE', EFFECTIVE DATE'.FOR•HAZARD.-COMMUNICATION REQUIREMENTS IS-EXTENDED.TO OCTOBER 1, 1993.,(56'FR 47158;.'09/18/91). FOR DOMESTIC SHIPMENTS:,' U.S. DEPARTMENT OF,TRANSPORTATION.SHIPPING NAME -ID NUMBER, '99 CFR 172.101 :. SULFUR -NA 1350 '0H/122280 PAGE 003 OF OF TRANSPORTATION HAZARD CLASS OR DIVISION, 49 CFR 172.101 (DEPARTMENT MISCELLANEOUS HAZARDOUS MATERIAL U.S. DEPARTMENT'OF TRANSPORTATION PACKING GROUP, 49 CFR 172.101: PG III U:S.•DEPARTMENT OF TRANSPORTATION LABELING REQUIREMENTS, 49 CFR 172.101 AND SUBPART CLASS 9 U.S. DEPARTMENT OP TRANSPORTATION PACKAGING EXCEPTIONS: 49 CFR. 173:151'. NON -BULK PACKAOING:..49 CFR-173.213 BULK PACKAGING: .49 CFR 173.240 AUTHORIZATIONS: U.S. DEPARTMENT.00TRANSPORTATION QUANTITY. LIMITATIONS 49 CFR 172.101: PASSENGER AIRCRAFT OR RAILCAR:. 25 K0 CARGO AIRCRAFT ONLY: 100.K0. .. FOR INTERNATIONAL. SHIPMENTS:. U.S. DEPARTMENT,OP TRANSPORTATION SHIPPING NAME- ID,NUMBER, 49 CFR 172.101: SULFUR -UN 1350 • 008 U.S. DEPARTMENT OF TRANSPORTATION HAZARD CLASS OR DIVISION, 49 CFR 172.101:' • ' 4.1 - FLAMMABLE SOLID U.S. DEPARTMENT OP TRANSPORTATION PACKING GROUP, 49 CFR 172.101: PO III U.S.. DEPARTMENT OF•TRANSPORTATION LABELING REQUIREMENTS, 49 CFR 172.101: FLAMMABLE SOLID. U.S. DEPARTMENT OF TRANSPORTATION PACKAGING REQUIREMENTS: EXCEPTIONS: 49,CFR 173.151 ' NON -BULK PACKAGING: 49 CFR 173.213 BULK PACKAGING: 49 CFR:173:240 DEPARTMENT,OF,TRANSPORTATION QUANTITY LIMITATIONS, .49 CFR 172.101: LAGER AIRCRAFT OR RAILCAR: 25 K0 n30 AIRCRAFT. ONLY: 100, KG • TOXICITY SULFUR: IRRITATION DATA: 8 PPM EYE -HUMAN TOXICITY DATA :''175 MG /KOcORAL= RABBIT„LDLO ;, >8437 MG /KG ORAL- RAT'LD;' `. 8 MO /K0 INTRAVENOUS -RAT LDLOj:1.0 Md /KG.';INTRAVENOUS -000 PLO/ 5.M0 /K0 • INTRAVENOUS.-RABBIT,. LDLO j,'55,MO /KO;INTRAPERITONEAL- GUINEA PIG LDLO CARCINOGEN'STATUS:;,NONE LOCAL EFFECTS; ; IRRITANT - INHALATION,:; SKIN, AND ,EYE. ACUTE TOXICITY LEVEL: .INSUFFICIENT DATA: TARGET EFFECTS: POISONING MAY'AFFECTTHE RESPIRATORY` SYSTEM:: '. 0H822280 PAGE 004 OF 008 HEALTH EFFECTS ANDFIRST AID ' INHALATION: SULFUR: . IRRITANT. ACUTE EXPOSURE- INHALATION OF LARGE AMOUNTS OF THE DUST MAY'CAUSE CATARRHAL INFLAMMATION OP THE NASAL MUCOSA WHICH MAY LEAD TO HYPERPLASIA WITH ABUNDANT NASAL SECRETIONS.' TRACHIOBRONCHITIS IS A FREQUENT OCCURRENCE, WITH DYBPNEA,.PERSISTENT COUGH AND EXPECTORATION WHICH MAY SOMETIMES BE STREAKED WITH BLOOD. CHRONIC EXPOSURE- REPEATED OR PROLONGED EXPOSURE TO DUST MAY CAUSE IRRITATION TO THE MUCOUS MEMBRANES. BRONCHOPULMONARY DISEASE MAY OCCUR WHICH, AFTER:SEVERAL YEARS, MAY BE•COMPLICATED BY EMPHYSEMA AND BRONCHIECTASIS. EARLY•SYMPTOMS IN".SULFUR.MINERS OFTEN INCLUDE UPPER RESPIRATORY TRACT. CATARRH, WITH COUGH.AND.EXPECTORATION WHICH IS MUCOID AND MAY EVEN CONTAIN. GRANULES OF SULFUR.. ASTHMA IS.A FREQUENT COMPLICATION. THE MAXILLARY AND FRONTAL SINUSES MAY BE AFFECTED; INVOLVEMENT I8 USUALLY BILATERAL AND PANSINUITIS MAY OCCUR.'PULMONARY FUNCTION MAY BE REDUCED. RADIOLOGICAL EXAMINATIONS'HAVE'REVEALED IRREGULAR OPACITIES IN THE'LUNGS AND OCCASIONALLY NODULATION HAS.HEEN REPORTED, BUT NOT TRUE NODULAR FIBROSIS. FIRST AID- REMOVE FROM EXPOSURE AREA TO FRESH AIR IMMEDIATELY. IF BREATHING HAS STOPPED, PERFORM ARTIFICIAL RESPIRATION.. KEEP PERSON WARM AND AT REST.' TREAT SYMPTOMATICALLY AND SUPPORTIVELY. GET MEDICAL ATTENTION IMMEDIATELY. SKIN CONTACT: SULFUR; IRRITANT. ACUTE EXPOSURE- MAY CAUSE IRRITATION ;'REDNESS, AND PAIN. SENSITIVITY TO SULFUR, PARTICULARLY WHEN USED AS A TOPICAL AGENT, I8 RARE. TWO CASES OF ALLERGIC HYPERSENSITIVITY TO SULFUR HAVE BEEN REPORTED. ABSORPTION OF SULFUR USED TO TREAT SCABIES'AND OTHER SKIN DISORDERS MAY OCCUR AND CAUSE POISONING WITH SHOCK, SYNCOPE,- ,FEVER AND POSSIBLY DEATH. ABSORPTION DEPENDS ON THE DEGREE OF INJURY TO THE SKIN; INTACT SKIN I8 ALMOST_ IMPERVIOUS; CHRONIC EXPOSURE- REPEATED OR PROLONGED CONTACT MAY CAUSE DERMATITIS, -.POSSIBLY WITH ERYTHEMATOUS AND ECZEMATOUS LESIONS AND SIGNS OF ULCERATION. • • FXKST AID- REMOVE CONTAMINATED. CLOTHING AND SHOES IMMEDIATELY. WASH AFFECTED AREA WITH SOAP OR MILD DETERGENT AND LARGE AMOUNTS OF WATER UNTIL NO EVIDENCE OF CHEMICAL REMAINS (APPROXIMATELY,15 -20 MINUTES). GET ATTENTION IMMEDIATELY.' EYE CONTACT:. SULFUR: IRRITANT. ACUTE EXPOSURE - 8 PPM HAS CAUSED IRRITATION OF HUMAN EYES. DUST MAY CAUSE IRRITATION, REDNESS AND PAIN WITH LACRIMATION ,.PHOTOPHOBIA,CONJUNCTIVITIS. AND BLEPHAROCONJUNCTIVITIS .,CASES'OF DAMAGE TO THE CRYSTALLINE LENS HAVE BEEN REPORTED WITH THE FORMATION OF. OPACITIES AND.EVEN CATARACT AND FOCAL ,; CHORIORETINITIB.• . • ' . CHRONIC EXPOSURE- REPEATED.. OR PROLONGED EXPOSURE MAY'CAUSE.CONJUNCTIVITIS.: • FIRST AID- WASH EYES IMMEDIATELY' WITH' LARGE AMOUNTS OF WATER OR NORMAL:SALINE,, OCCASIONALLY' LIFTING UPPER AND LOWER,LIDS, UNTIL NO EVIDENCE OF CHEMICAL REMAINS (APPROXIMATELY 15 -20 "MINUTES). GET MEDICAL ATTENTION IMMEDIATELY. • ITION: ACUTE EXPOSURE- A MAN HAS SURVIVED INGESTION OF 60 GRAMS OF SULFUR OVER A PERIOD OF.•24 HOURS.-LARGE ,DOSES (5 .GRAMS) BY. MOUTH MAY LEAD TO.HYDROGEN SULFIDE PRODUCTION CHIEFLY TO'BACTERIAL ACTION WITHIN THE .COLON. WITH LESSER AMOUNTS•THIS IS'RARE'AND UNLIKELY•IN THE ABSENCE OF MECHANICAL OBSTRUCTION.:, SMALL'PARTICLES•ARE GENERALLY MORE TOXIC.THAN LARGE ONES. '.IN,RABBITS.A DOSE OF -175 MG /KG CAUSED CONVULSIONS1,UNCONSCIOUSNESS, A • HYDROGEN'SULFIDE,ODOR OF,THE BREATH,:. FALL IN BLOOD PRESSURE,.BRADYCARDIA, STIMULATION OF RESPIRATION FOLLOWED•.BY RESPIRATORY ARREST, AND DEATH. PATHOLOGIC FINDINGS INCLUDED PULONARY.EDEMA AND. HEMORRHAGE.. , CHRONIC EXPOSURE - .VOLUNTEERS WHO INGESTED DAILY DOSES OF .500 OR 750 MG OP COLLOIDAL SULFUR.ABSORBED IT COMPLETELY,•TOLERATED IT EASILY, AND EXCRETED MOST OP' IT WITHIN 24 HOURS. FIRST:AID- TREAT SYMPTOMATICALLY AND SUPPORTIVELY. GET MEDICAL ATTENTION IMMEDIATELY .'IF'VOMITING.00CURS,' KEEP'HEAD•LOWER THAN HIPS. TO PREVENT ASPIRATION. ANTIDOTE; NO SPECIFIC ANTIDOTE.. TREAT SYMPTOMATICALLY AND SUPPORTIVELY.." REACTIVITY' REACTIVITY: • STABLE UNDER NORMAL TEMPERATURES AND PRESSURES. ' INCOMPATIBILITIES:. SULFUR: . ALKALI METAL NITRIDESs..FORMS HIGHLY FLAMMABLE MIXTURE WHICH AND HYDROGEN SULFIDE' ON CONTACT WITH WATER. • ' ALUMINUM (POWDER)s'POSBIBLEEXPLOSION.,.' AMMONIA: MAY'FORM EXPLOSIVE SULFUR NITRIDE. .. AMMONIUM NITRATE:, FORMS SHOCK- SENSITIVE MIXTURE. BORON: INCANDESCENT. REACTION ABOVE 600.C,,' BROMATES: CONTACT MAY RESULT IN IGNITION OR AN EXPLOSION. OMIUM: EXPLOSIVE:REACTION. 1i,CIUMs EXPLODES ON. IGNITION. CALCIUM'HYPOCHLORITE; EXPLOSIVE REACTION ON HEATING'IN A CALCIUM PHOSPHIDE :INCANDESCES AT 300 C. CARBON (ACTIVATED): MAY IGNITE SPONTANEOUSLY.' • CHLORATES; CONTACT MAY RESULT_IN IGNITION OR•AN;EXPLOSION.- ' CHLORINE DIOXIDE: IGNITION 'WITH'POSSIBLE'EXPLOSION.':' CHLORINE MONOXIDE;..VIOLENT,EXPLOSION. CHLORINE TRIOXIDE; VIOLENT REACTION.:., CHROMIC ANHYDRIDE::IGNITION ON'HEATING, POSSIBLE EXPLOSION.:: CHROMYL CHLORIDEi''IGNITES COPPER :POWDER): IGNITION; ON .WARMING. FLUORINEC IGNITION AT�'AMBIENT,.TEMPERATUREB. GADOLINIUM;.POSSIBLE EXPLOSION: ;.;.;: HEPTASILVER NITRATE OCTAOXIDEs :EXPLOSION,ONIIMPACT.,. HYDROCARBONS ; MAY.FORM EXPLOSIVE. CONCENTRATIONS. OF. HYDROGEN, SULFIDE AND CARBON DISULFIDE, INDIUM; IGNITION AND INCANDESCENCE ON HEATING.'.. INTERHALOGENSt'IGNITION.WITH POSSIBLE INCANDESCENCE. IODATES; CONTACT MAY'RESULT IN IGNITION OR AN :EXPLOSION.'. 0HS22280 PAGE 006 OF 008 CADNE PENTOXIDEt EXPLOSIVE REACTION ON WARMING. )N: INCANDESCENT REACTION ON HEATING. . CHLORITEt.EXPLODES. LEAD CHROMATE:. FORMS PYROPHORIC,MIXTURE. LEAD; DIOXIDE: EXPLODER. LITHIUM: VIOLENT,. "POSSIBLY EXPLOSIVE REACTION. MAGNESIUM: EXOTHERMIC REACTION.. MERCURIC NITRATE: "EXPLOSIVE REACTION.. MERCURIC 'OXIDE :.VIOLENT. EXPLOSION: MERCUROUS OXIDE :.IGNITION ON LIGHT IMPACT. MERCURY:. EXOTHERMIC REACTION: `. , .' METAL'ACETYLIDES: CONTACT MAY RESULT IN IGNITION AND POSSIBLE INCANDESCENCE.. METAL' CARBIDES: CONTACT MAY`RESULT'IN IGNITION AND POSSIBLE INCANDESCENCE. METAL:OXIDES: POSSIBLE IGNITION OR EXPLOSION. METALS: POSSIBLE IGNITION OR' EXPLOSION..: NICKEL.(POWDER)*,IGNITES,WITH INCANDESCENCE WITH BOILING ,SULFUR.' NITROGEN DIOXIDE:'BURNS,VIGOROUSLY. . OSMIUM'(POWDER)t IGNITES WITH INCANDESCENCE IN BOILING SULFUR., OXIDIZERS (STRONG) FXRE •AND•EXPLOSION HAZARD: " PALLADIUM:. IGNITES WITH INCANDESCENCE ON HEATING. PERCHLORATES:•FORMS SHOCK. SENSITIVE MIXTURES... PHOSPHORUS:' IGNITION, OR. EXPLOSION WHEM'WARMED. PHOSPHORUS: TRIOXIDE: VIOLENT REACTION. , . POTASSIUM: VIOLENT REACTION ON WARMING. ' •,POTASSIUM + STANNIC..IODIDE: EXPLOSIVE MIXTURE. • POTASSIUM CHLORITE :, VIOLENT REACTION. POTASSIUM NITRATE -1- ARSENIC TRISULFIDE:.:FORMS EXPLOSIVE MIXTURE. POTASSIUM PERMANGANATE: POSSIBLE. EXPLOSION. WITH FRICTION'OK HEATING. RHODIUM: IGNITION AND INCANDESCENCE ON HEATING.' RUBIDIUM (MOLTEN); IGNITES INTHE VAPOR: SELENIUM: IGNITION WITH INCANDESCENCE.., . SILVER' CHLORITE :'EXPLODES 'WITH FRICTION. . • SILVER. NITRATE: VIOLENT'EXPLOSION ON IMPACT.' SILVER OXIDE* IGNITES ON FRICTION. SODIUM: VIOLENT OR EXPLOSIVE REACTION WITH HEAT OR. FRICTION., SODIUM +- STANNIC.'IODIDE:'IMPACT SENSITIVE. MIXTURE. SODIUM CHLORITE: IGNITES.WITH MOISTURE., . SODIUM HYDRIDE: VIGOROUS REACTION WITH SULFUR VAPOR. • )IUM.NITRATE'+ CHARCOAL:. EXPLOSIVE REACTION. '• .)IUM PEROXIDE: FORMS EXPLOSIVE MIXTURE. . • TANTALUM: POSSIBLE EXPLOSION. TETRAPHENYLLEAD :,,;POSSIBLE.EXPLOSION. ," TETRAPHOSPHORUS HEXOXIDE: VIOLENT., REACTION•f 160 C, . THALLIC OXIDE: EXPLODEB.:WITH "FRICTION.' ' THORIUM: IGNITION AND' INCANDESCENCE WITH,HEATING , TIN: VIGOROUS, REACTION, WITH INCANDESCENCE' AND' IGNITION. ON HEATING .. URANIUM: INCANDESCENCE AND'.IGNITION WITH BOILING. SULFUR. ' VANADIUM (V) OXIDE, „WATER: IGNITION;.''. , '' ZINC (POWDER)'; EXPLOSIVE REACTION WHEN'WARMED..; • . DECOMPOSITION:. • THERMAL DECOMPOSITION' PRODUCTS_ MAY• INCLUDE:TOXIC OXIDES OF,SULPUR POLYMERIZATION: . ., HAZARDOUS POLYNERIZATIONHAS NOT BEEN' REPORTED TO. OCCUR. UNDER' NORMAL „. TEMPERATURES AND. PRESSURES. STORAGE AND DISPOSAL OHS22280 PAGE 007 OF 008 OBSERVE ALL FEDERAL, STATE AND LOCAL REGULATIONS WHEN STORING OR DISPOSING OF.THIS SUBSTANCE. FOR ASSISTANCE,.CONTACT THE DISTRICT DIRECTOR OF THE ENVIRONMENTAL PROTECTION AGENCY. r' * *STORAGE ** STORE AWAY FROM INCOMPATIBLE SUBSTANCES, CONDITIONS TO AVOID AVOID CONTACT WITH HEAT, SPARKS,. FLAMES OR OTHER SOURCES OF'IONITION. MATERIAL IS EXTREMELY FLAMMABLE AND MAY BURN RAPIDLY WITH FLARE- BURNINO. EFFECT. •. SPILL ..AND LEAK-PROCEDURES' OCCUPATIONAL SPILL: SHUT OFF IGNITION .SOURCES: DO NOT TOUCH, SPILLED MATERIAL'. FOR SMALL SPILLS, WITH CLEAN SHOVEL, PLACE MATERIAL INTO CLEAN, 'DRY CONTAINER AND COVER; MOVE CONTAINERS FROM SPILL AREA. FOR LARGER SPILLS,,WET DOWN WITH WATER AND DIKE FOR LATER DISPOSAL. NO SMOKING, FLAMES OR FLARES IN HAZARD AREA. KEEP UNNECESSARY PEOPLE AWAY. .ISOLATE HAZARD AREA AND DENY ENTRY, PROTECTIVE EQUIPMENT VENTILATION: PROVIDE LOCAL EXHAUST_ VENTILATION. VENTILATION EQUIPMENT MUST BE EXPLOSION TROOP. RESPIRATOR: • . THE FOLLOWING RESPIRATORS' ARE RECOMMENDED BASED ON INFORMATION FOUND IN THE .. . PHYSICAL DATA, TOXICITY AND HEALTH EFFECTS SECTIONS: THEY ARE RANKED IN ' " `DER FROM MINIMUM TD MAXIMUM,RESPIRATORY PROTECTION,, iY.3PECIFIC RESPIRATOR SELECTED MUST 58 SASED 014 CONTAMINATION LEVELS FOUND IN THE WORK PLACE,.MUST BE.BASED :DN THE SPECIFIC OPERATION,' MUST.NOTEXCEED ' THE WORKINO,LIMITS OF THE RESPIRATOR AND MUST.BE,JOINTLY APPROVED BY THE, , NATIONAL, INSTITUTE. FOR:000UPATIONAL .A .SAFETY.ND HEALTH' AND,THE.MINE.SAPETY AND. HEALTH: ADMINISTRATION , -_(NIO8H- MBHA).. ANY DUST AND MIST,REBPIRATOR.., • ANY'AIR- PURIFYING REBPIRATOR.WITH A HIGH- EFFICIENCY PARTICULATE FILTER:- ANY POWERED AIR- PURIFYINQ RESPIRATOR WITH: A DUST -AND MIST. FILTER. :,. ANY POWERED AIR- PURIFYINQ-RESPIRATOR WITH'AHIGH - EFFICIENCY PARTICULATE FILTER. ANY TYPE 'C' BUPPLIEDcAIR•RESPIRATOR OPERATED IN THE PRESSURE - DEMAND OR , • OTHER POSITIVE „PRESSURE OR CONTINUOUS -FLAW MODE.`,: OHS22280 PAGE 008 OF 008 NY SELF - CONTAINED BREATHING APPARATUS. 41:R FIREFIGHTING AND OTHER IMMEDIATELY DANGEROUS TO LIFE OR HEALTH CONDITIONS: ANY SELF - CONTAINED.. BREATHING APPARATUS THAT HAS A FULL PACEPIECE AND IS • OPERATED IN A PRESSURE - DEMAND OR OTHER POSITIVE - PRESSURE MODE. ANY SUPPLIED -AIR RESPIRATOR THAT HAS A FULL FACEPIECE AND IS OPERATED IN A PRESSURE- DEMAND OR OTHER POSITIVE- PRESSURE MODE IN COMBINATION WITH AN AUXILIARY SELF - CONTAINED BREATHING APPARATUS :OPERATED IN,PRESSURE- DEMAND, OR OTHER POSITIVE = PRESSURE MODE. . CLOTHINO': ` EMPLOYEE MUST WEAR APPROPRIATE PROTECTIVE (IMPERVIOUS) CLOTHING AND EQUIPMENT TO PREVENT REPEATED OR. PROLONGED SKIN CONTACT WITH THIS SUBSTANCE. GLOVES: EMPLOYEE MUST WEAR .. APPROPRIATE PROTECTIVE GLOVES TO PREVENT CONTACT WITH THIS ' SUBSTANCE. EYE PROTECTION: EMPI.OYEE'MUST.WEAR SPLASH -PROOF OR DUST - RESISTANT SAFETY GOGGLES TO PREVENT EYE,CONTACP.WITH THIS'SUBSTANCE. EMERGENCY EYE WASH: WHERE THERE IS ANY POSSIBILITY THAT AN EMPLOYEE'S EYES MAY BE EXPOSED TO THIS SUBSTANCE, THE EMPLOYER SHOULD PROVIDE AN EYEWASH FOUNTAIN WITHIN THE' XMMEDIATE WORK AREA FOR EMERGENCY USE..' • COPYRIGHT :1993 OCCUPATIONAL HEALTH SERVICES, INC.. ALL RIGHTS RESERVED. CREATION DATE: 01/03/85 REVISION DATE: 12/30/92 Product Safety Information 9 �tittr�ll IC ACID This Product Safety Information Sheet is rprinclpally directed to managerial, safety, hygiene and medical personnel. The description of physical, chemical and toxicological properties and handling advice is based on experimental results and past experience. It is Intended as a starting point for the development of health and safety procedures. Synonym: 011 of Vitriol CAS Registry Number: 7664 -93 -9 1. PHYSICAL AND CHEMICAL PROPERTIES Formula: H2SO4 Formula Weight: 98.08 Physical State /Description: Clear, colorless to cloudy liquid. Bolling Point: 78% = 380°F (193°C) 93% = 529°F (276° C) Flash Point: Not applicable Melting Point: 78 %= 11.6 °F (- 11.3 °C) 93% = -20°F (- 28.9° C) 98%30°F (- 1.1 °C) Odor: None pH: Less than 1 (1% aqueous solution) Specific Gravity: 78% = 1.7 (water = 1) 82 -100% = 1.8 (water = 1) Vapor Density: 3.4 (air = 1 at boiling point of sulfuric acid) Vapor Pressure: 78% to 100% = Less than 1 mmHg at 100° F (37.8° C) Water Solubility: Soluble In all proportions. 11. CHEMICAL REACTIVITY Reacts with many metals. This reaction will evolve flam- mable and potentially explosive hydrogen gas. In Its concentrated form, sulfuric acid Is a strong oxidizing agent and may cause Ignition on contact with organic materials and chemicals such as nitrates, carbides, chlo- rates, etc. It will also react exothermically with water. IN CASE OF SUSPECTED POISONING, REFER TO THE INFORMATION IN SECTION VII: HUMAN HEALTH AND THE PROCEDURE AND EMERGENCY CONTACTS IN SECTION VIII: FIRST AID. IN CASE OF SPILLAGE, REFER TO THE PROCEDURE AND EMERGENCY CONTACTS iN SECTION X: SPILL HANDLING OR CALL CHEMTREC (800) 424 -9300. 111. STABILITY Stable at ambient temperatures and atmospheric pressure. Do not add water to the acid -- as large amounts of heat will be produced, and localized boiling and spattering may occur. When diluting, always add the acid slowly to water. IV. FIRE HAZARD The acid Itself is not flammable. However, higher concen- trations may cause nearby combustible liquids and solids to Ignite upon contact. Contact with common metals will evolve flammable and potentially explosive hydrogen gas. The rate of hydrogen generation increases with decreasing acid concentration. V. FIREFIGHTING TECHNIQUE Concentrated vapors of sulfuric acid are extremely Irri- tating to the respiratory tract and may cause breathing difficulty and pulmonary edema. , Prevent human exposure to fire, smoke, fumes, or products of combustion. Evacuate nonessential personnel from the fire area. Maintain a sate distance from the fire and storage area because excessive heat may cause tank to rupture. Wear full -face, sett - contained breathing apparatus and Impervious clothing (such as gloves, hoods, suits and rubber boots). Use water spray, dry chemicals, foam or carbon dioxide. If tank Is not leaking, keep cooled using a fog spray nozzle to minimize the reactivity of water and acid. Under no circumstances should water or other liquid be Introduced Into acid tanks, Take care not to Ignite hydrogen gas which can accumulate inside metal tanks containing acid. VI. TOXICOLOGY Ingestion Ttie acute oral LD50 is 2,140 mg /kg in rats.(I) Skin Contact Corrosive to skin.12) Eye Contact Corrosive to eyes.t2) Inhalation The LC50 of mist of 1- micron particle size for an 8 -hour exposure was 50 mg /m' for 18 -month old guinea pigs and 18 mg /m' for young (1 -2 month) animals.tai Exposure of guinea pigs to 2 mg /m' for one hour caused an increase In pulmonary airway resistance from reflex bronchoconstriction,(4) VII. HUMAN HEALTH Sulfuric acid is corrosive to all body tissues. Inhalation of mist in excessive amount may cause serious lung damage. Contact with the eyes may result in total loss of vision. St in contact may produce severe necrosis. Ingestion r' ry cause severe injury and death. Frequent skin contact with dilute solutions has caused dermatltis,t2) tr) AM.IND.HYO.ASSOC,J.,30:470 -476 (1979) (2) Merck and Company, Inc., (1903). THE MERCK INDEX, 10th EDITION, Merck and Company: Rahway, NJ 13) AMA ARCii.IND.HYG.00CUP..MED., 5:318 -329 (1952) (4) ARCH.IND.HEALTH, 18:407 -414 (1958) All INpm.IIon It allied In good NM, w4houl gwnntee of obligation la the accaecy a sufficiency Meted, a Ina 10101 obl$ned, end It accepted et utele 1104 TM ueet 1e10110d 10 u• to dw pwpote dluatutlon only ueel should Inrettigele and establish the suilah.tdv n1 urh ,...u4 o .,..,,, -... .I -Iti3M A...,- • . I CIn„fr,..1 STAUFFER CHEMICAL COMPANY S,UI-FURIC ACID VIII. FIRST AID CALL A POISON CENTER OR A PHYSICIAN IMMEDIATELY If a known exposure occurs or is suspected, Immediately start the recommended procedures below. Simultaneously contact a Poison Center, a physician or the nearest hospital. Inform the person contacted of the type and extent of exposure, describe the victim's symptoms, and follow the advice given. FOR ADDITIONAL MEDICAL OR TOXICOLOGICAL INFORMATION, CALL COLLECT, DAY OR NIGHT, STAUFFER CHEMICAL COMPANY, (203) 226 -6602 OR CHEMTREC (800) 424 -9300. Ingestion II swallowed, Immediately give several glasses of water but do not Induce vomiting. This material is corrosive. If vomiting does occur, give fluids again. Have a physician determine if condition of patient will permit induction of vomiting or evacuation of stomach. Do not give anything by mouth to an unconscious or convulsing person. Skin Contact Using a dry cloth, immediately wipe away excess material from the skin and remove all contaminated clothing and shoes. Under a safety shower, flush all offectod areas thoroughly with large amounts of running water tor at least 15 minutes: Do not attempt to neutralize with chemical agents. Get medical attention Immediately. Discard con- taminated clothing and shoes, Eye Contact immediately flush the eyes with large quantities of running water for a minimum o115 minutes. Hold the eyelids apart during the flushing to ensure rinsing of the entire surface of the Dye and Ilds with water. Do not attempt to neutralize with chemical agents. Obtain medical attention as soon as possible. Oils or ointments should not be used at this time. Continue the flushing for an additional 15 minutes II a physician Is not immediately available. Inhalation if inhaled, remove to fresh air. If not breathing, clear victim's airway and start mouth -to -mouth artificial respira- tion, which may be supplemented by the use of a bagmask respirator or manually triggered oxygen supply capable of delivering one liter per second or more. If victim Is breathing, oxygen may be given from a demand -type or continuous -flow Inhaler, preferably with a physician's ad- vice. Get medical attention Immediately. IX. INDUSTRIAL HYGIENE The recommendations described In this section are pro- vided as general guidance for minimizing exposure when handling this product. Because use conditions will vary depending upon customer applications, specific sale handling procedures should be developed by a person knowledgeable of the Intended use conditions and equip- ment. During the development of safe handling pro- cedures, consideration should be given to the need tor cleaning of equipment and piping systems to render them nonhazardous before maintenance and repair activities are performed. Engineering Controls In those cases where engineering controls are Indicated by the use conditions, the following traditional exposure control techniques may be used to effectively minimize employee exposure: local exhaust ventilation, enclosed system design, or process isolation and remote control In combination with appropriate use of personal protective equipment, Ingestion All food should be kept In a separate area away from the storage /use location. Eating, drinking and smoking should he prohibited In areas where there Is a potential for significant exposure to this material. Before eating, hands and face should be thoroughly washed. Skin Contact Skin contact with liquid or its aerosol must be prevented through the use of protective clothing, gloves and footwear selected with regard for use condition exposure potential. Safety showers — with quick opening valves which stay open, ::Mould be readily available In all areas where the material is handled or stored. Water should be supplied through insulated and heat - traced lines to prevent freeze ups in cold weather. Eye Contact Eye contact with liquid or aerosol must be prevented through the use of chemical safety glasses, goggles or a face shield selected with regard for use condition exposure potential. Eye wash fountains -- or other means of washing the eyes with a gentle flow of lap water should be readily available In all areas where this material Is handled or stored. Water should be supplied through insulated and heat- traced lines to prevent freeze ups In cold weather. Inhalation This material must be handled In an open (e.g., outdoor) or well ventilated area. Where adequate ventilation is not available and use conditions could generate acid mist. Inhalation must be prevented through the use of NIOSH- approved mist filter, acid gas cartridge respirators to reduce potential for exposure under the use conditions. Where exposure potential under the use conditions neces- sitates a higher level of protection, use a positive- pressure, air- supplied respirator. Either hall -face respirators in combination with chemical goggles or full -lace respirators may be required In certain use conditions to prevent eye contact or irritation. Exposure Limits The Federal OSHA Permissible Exposure Limit (PEL) is an 8 -hour time - weighted average of 1 mg /m3 for sulfuric acid.ts) The American Conference of Governmental Industrial Hygienists (ACGIH) has recommended a Threshold Limit Value TLV) of 1 mg /m3 as an 8 -hour time - weighted average for sulfuric acid.(S) X. SPILL HANDLING Make sure all personnel Involved In the spill cleanup follow good industrial hygiene practices (refer to SECTION IX: INDUSTRIAL HYGIENE). Any person entering Dither a significant spill area or an unknown concentration of a vapor or mist, should use a positive- pressure, self - contained breathing apparatus or a positive- pressure, supplied -air respirator with escape pack. Small spills can be handled routinely. Use adequate ventilation and /or wear a NIOSH- approved respirator to prevent inhalation exposure. Wear protective clothing to prevent skin and eye contact. Use the following pro- cedures: to) 29 CFR 1910.1000 t$) The American Conference of Governmental Industrial Hyglen- Ists (ACGIH), (1983). Threshold Limit Values for Chemical Substances and Physical Agents In the Workroom Environment and Biological Exposure indices with Intended Changes tor 1984.85. ACRIH' r InrInnell rlhI' SULFURIC ACiD •• Any leak occurring In pipelines or equipment should be cdnsidered an acid leak and treated with extreme caution until the leak Is proven not to be an acid leak. All contam- inated areas should be Immediately zoned off to avoid personnel exposure to the acid spray or stream. Adjust all appropriate valves to isolate the system and stop further leakage. The contaminated area should be covered with sodium bicarbonate, soda ash, or lime, taking care to avoid any foaming or splattering that may occur from the neutraliza- tion reaction of the acid with these materials. Diking may be advisable to help contain the liquid spill. Make sure all liquid has been thoroughly contacted and absorbed by the. dry materials. Transfer absorbed spill material and any contaminated underlying soil to a suitable chemical waste container. Dispose of container and contents In an environmentally acceptable way (refer to SECTION Xfll: DISPOSAL OF UNUSED MATERIAL). Washing down of spills with water is not recommended, as this tends to spread the contamination and increases the likelihood of percolating the acid down through the soil and /or of uncontrolled flow of acid Into sewers, streams, or other waters. Sulfuric acid leaks, spills, or drainings must not come In contact with any acld soluble sulfide wastes (such as sewers) because of the danger of evolving hydro -. gen sulfide gas: Large spills should be handled according to a predeter- mined plan. For assistance in developing a plan, contact the Basic Products Group, Stautler Chemical Company, Westport, CT 06881. IN CASE OF SPILL EMERGENCY, DAY OR NIGHT, CALL (800) 424 -9300 CHEMTREC. XI. CORROSIVITY TO MATERIALS OF CONSTRUCTION Weaker strengths of sulfuric acid, particularly below 55° Baumd (70% H, SO4), are highly corrosive to most metals with evolution of highly flammable and potentially explo- sive hydrogen gas. Within certain limitations of velocity, both Iron and steel can be used in commercial strength acid at ambient temperature. XII. STORAGE REQUIREMENTS Containers should be stored in a cool, dry, well ventilated . area away from flammable materials and sources of heat or flame. Store away from foodstuffs or animal feed. Exer- cise due caution to prevent damage to or leakage from the container. Sulfuric acid may be safely stored In properly designed bulk storage tanks. Contact the Technical Service Depart- ment, Basic Products Group, Stauffer Chemical Company, Westport, CT 06881 for specific recommendations. XIII. DISPOSAL OF UNUSED MATERIAL Material that cannot be used or chemically reprocessed should be disposed of at an approved facility in accord- ance with any applicable regulations under the Resource Conservation and Recovery Act. Note: State and local regulations may be more stringent than Federal. XIV. DISPOSAL OF CONTAINER Dispose of empty containers according to any applicable regulations under the Resource Conservation and Recov- ery Act. Note: State and local regulations may be more stringent than Federal. XV. PRECAUTIONARY STATEMENTS DANGER( Causes severe bums. Contents may be under pressure of explosive hydrogen gas. Keep away from heat, sparks and flames. • Do not get in eyes, on skin, on clothing • Avoid breathing vapor and mist • Keep container closed • Use with adequate ventilation • When handling, wear. NIOSH- approved respirator, lace shield, rubber gloves and appropriate protective clothing • Wash thoroughly alter handling • Do not allow water to get Into container because of, violent reaction FOR NON - EMERGENCY HANDLING INFORMATION, CONTACT THE BASIC PRODUCTS GROUP, STAUFFER CHEMICAL COMPANY, WESTPORT, CT 06881 OR PHONE (203) 222 - 3000. New Issue 10/84 Supercedes Issue Dated 4/79 SULFURIC ACID 96% 0 E o v u A a u 9 L -c.0 C >.;10 co 0 �? t o 5 .. A u a y ►i p 0 L. • 1-..., r _ � T = $ c o p• o e o e E E . � t £ m E 1 a * ar % -, 15 la =e" * U i = c ug _ g° V' = am °Y E Z u = U a C -r u Y G C p c , T p E Q y C 1 E y .y 0 0 V Id 111 PO p Q � V Y In a 10 g .2 , . N Y am, ow c• C" ,eG. o w c o pi.E i� R w E S Ear a st'u $ E •v 6 0 a= O c y:8 npp Yy c •OL a . aV•1 0 G O.Y,• C Y•FO 1 Y1'� cnv., SF ° X0s x3 .53 o E C CS' a K. 0. .t . o e V .0 Y.,. IS = 4 3 A x s e �a, : �, E 0 . O E m 4E r0= u Is' 4 E eo a .c IN C Lr p Oe0 p u eo •00 •2 ° v c t .5 �0 ° c a U" " E E A Q E t+ E a V` Y_ U U ._ O 4 •ii f0 y a.ti Pr ��rr //,�� uu = 00 • W O •,y C !� C 1111 b 0 h to V c '� Wo ter z x �o cc�E+e m .- ri d -it t Y w 2ISg „E sE ~ c c$ C 5C �Fg a a, ycJ c c. Y a c a E.13 a es g gC fsi Y •Lo O G — .Q C O •ii p (ii •c� 1. W N _ Q . CI 2 1> > E .z0...QR. wzo. izol v�szaa c • a N Le yO rryy Y Y u. a:. y wn to C I. u 0 tD G e O' w F L'... ° x c z © eam2g o 7t O. Y Ili it it D Vi a .G i c ° O ;] _ y 4 LL Z w O O • ••∎ t ° , gRg c a° "" ' U u ` c � a • — .. r Q .1' 3: r% •a V a o 0 0 1 g �t Cr `v RC �C x Y'���z 9 °� W Y O 3 d Q z a _w Q.a V` O° E C . 8 p d u, o V 8 boa= p•ajS4 az e.w W 0 g •� E W V 1 Si Vi rt G O s Lei .� N E., Rar v>� a e� � SSia3 a. U2 .c.c VEE� C SULFURIC ACID 96% SULFURIC ACID 96*11 N K . u b _ u E 0 i. u ` V Eso2:u >° , g el• f▪ , ...guy, e 3 Q. o �. 7 o C g.' u a s CE k a s a ups • t.g 3 d < u'q 02 9 ` Q= E 8 t p u �Q i U 1. A (A L MO y V :21 . 7 E' 4 C t' E• E 9 Io u u ... }j!j p, C4 y Q BP MvAaI p 9 2!W o o a qv v L u x 131.8 e a., ti c a v �` E o g °- E g u .gg' yt f4 ;G H i _o u g..4.0 am = V v a p 1) .�0.. O V 9. �. E v w Qy OO F •- .13 c Z' a `� a Ei. _ S o O i� EER. p, u c ao R' c u 6 E E �+ a= c Ri A a. mob. • o _ 25:i4 1 C ,p gt, c a LI'a§ 1 1 . � 8.0.., eL 8 0; w 0 • I a, a Ns 11 i a o V a 1 iii Jh 4 �y jiff .! Vatg firi aft 24/ .. 1' 4 g bo p BE z This Addendum Must Not Be etached from the MSDS (Chem.Key: SUF96) O v g E U 1 E z O z IA 7 N 6. M r. en O M L.L. r a C tr. II `r J © d r U 7 v cc c 3 115 c . 0 `c v u to 3 . R.: ° c c el i° c .. c ° co co vi 1.' z ` °' ' C c " 4 C M Ur • ,c 0 ez ct 6.1 V . c R c .. a cti y M •e w V � � C � v, vs 'o i U: u C u �i c`ua _ C C l. v ri d N y .. '33 ecv E E r, a 'o .u. Q ; V h O ._ 40 �N .. c ° 3 h c 1. ees N° o'ce co A Z .0 u.I. .1 Y o N c u { C 0. o c G u 0 v E : i 7 G for io E u Llu G 'E o U w G u 2 c E o 0 0 0 F,:E. t ti a,.. IN C ' v Q A � E' c ,I .0 w v C C .O 7 td . c E 7 to co d c • o` 0 Eo u c. o O ? u C c r .c C O C4 c4'4' 0 G g 74 v,H E E . o W 0 u 'u W E U U v Nu�14i Ei eM f ery M ^ V. 0 0 = cc u c.a A. N 3 3u V v LX et < go < Lt) 'a U cd SULFURIC ACID 96% : 10 -21 -86 Supersedes 09 -05 -85 ;F A}tWE;:;T PAINT MANUFACTURING CO. 4522 S. 133RD ST. TUKWILA, WA 9816: DATE OF PREPARATION: FEBRUARY 9, 1989 1 SECTON I PRODUCT IDENTIFICATION 1 PRODUCT NUMBER: A05 1 PRODUCT NAME: SYNTHETIC: THINNER 1 PRODUCT CLASS: AROMATIC: SOLVENT 1 MATERIAL SAFETY DATA SHEET FOR COATINGS AND RELATED MATERIALS 24 HOURS EMERGENCY ASSISTANCE EMERGENCY (206) 941 -1619 INFORMATION (206) 244 -8844 HAZARD RATING 1 THIS PRODUCT 0 LOWEST HEALTH :;1 1 1 FLAMMABILITY 2 1 REACTIVITY :1;; 1 PERSONAL. :0 4 EXTREME PROTEC :TION E0 1 SECTION I I HAZARDOUS INGREDIENTS 1 INGREDIENT PERCENT OCCUPATIONAL: . VAPOR . (by volume) EXPOSURE LIMITS PRESSURE TLV PEL :SOLVENT: XYLENE,XYLOL CAS # 1030-20-7 0 -20 -7 100PPM 10 ;:PPM 5. 10MHC@6i F Technical pradc XY1Ene contains 18 -20% EthYl Benzene. Eth••r1 Benzene has a PEL of 100 PPM and a TLV of 100 PPM (125 PPM - :E:TEL) "Pursuant to• Title. III of the SupCrfund •Ammendments and Reauthorization Act of 1986 ( :SARA) and 40 C :FR Fart , :372, This Prc'duct . :'ntains •car ma•,• • coritain a toxic chemical in a 9uantit•Y s.ub,lc:ct to -the r cpurtine' requirements under Section 013." 1 SECTION III PHYSICAL DATA BOILING RANGE: 279F VAPOR DEN :ITY: HEAVIER THAN AIR XX._ LIGHTER THAN AIR EVAPORATION RATE: FASTER THAN ETHER ____ SLOWER THAN ETHER : _XX_ VOLATILE BY VOLUME: 100% SOLUBILITY IN WATER: NIL_ REACTIVITY IN WATER: NIL_ WT /GAL: 7.25 APPEARANCE ?c ODOR: CLEAR, WATER WHITE LIQUID WITH MILD, SWEET AROMATIC ODOR SEC:TICIN IV FIRE AND EXPLOSION HAZARD DATA FLAMMABILITY CLASSIFICATION: OSHA FLAMMABLE L I ! a FLASH Pr_I I NT : _ 3OF TC_:C: LMT FLAMMABLE ____ TC:r_: EXTINGUISHING MELIIAL: FOAM :XX____ DRY CHEMICAL: _XX___ "ALCOHOL" FOAM : WATER FOG :_XX___ CO2 :XXOTHER UNUSUAL FIRE AND EXPLOSION HAZARDS : NEVER USE NEAR OR AROUND WELDERS OR CUTTING TORCHES. DRUM (EVEN EMPTY) BECAUSE PRODUCT (EVEN JUST RESIDUE) CAN IGNITE EXPLOSIVELY. SPECIAL FIREFIGHTING PROCEDURES: SELF—CONTAINED BREATHING APPARATUS WITH A FULL FACEP I ECE OPERATED IN PRESSURE—DEMAND OR OTHER POSITIVE PRESSURE MODE. SECTION V HEALTH HAZARD DATA EFFECT:_; OF OVEREXPOSURE: EYES—CAN CAUSE SEVERE IRRITATION, REDNESS, TEARING, BLURRED VISION. SKIN — PROLONGED OR REPEATED . CONTACT CAN CAUSE MODERATE IRRITATION, DEFATT I NI i, DERMATITIS. BREATHING—EXCESSIVE INHALATION OF VAPORS CAN CAUSE NASAL AND RESPIRATORY IRRITATION, D I Z Z I NESS, WEAKNESS, FATIGUE, NAUSEA, , HEADACHE, POSSIBLE UNCONSCIOUSNESS, AND EVEN ASPHYXIATION. SWALLOWING—CAN CAUSE: GASTROINTESTINAL IRRITATION, NAUSEA, VOMITING, AND DIARRHEA. ASPIRATION OF MATERIAL INTO THE LUNGS CAN CAUSE CHEMICAL PNEUMON I T I S WHICH CAN BE FATAL. MELTICAL CONDITIONS PRONE TO AGGRAVATION BY EXPOSURE: OVEREXPOSURE TO THIS MATERIAL (CIR ITS COMPONENTS) HAS APPARENTLY BEEN FOUND TO CAUSE THE FOLLOWING EFFECTS IN LABORATORY ANIMALS: ANEMIA, LIVER ABNORMALITIES, KIDNEY DAMAGE, EYE DAMAGE. OVEREXPOSURE TO THIS MATERIAL (OR ITS COMPONENTS) HAS BEEN SUGGESTED E =';TELI AS A CAUSE THE FOLLOWING EFFEC :TS IN HUMANS: CARDIAC ABNORMALITY. PRIMARY ROUTE(S) OF ENTRY: DERMAL XX_ INHALATION XX_ INGESTION ___ EMERGENCY AND FIRST AID PROCEDURES: SKIN: THOROUGHLY WASH EXPOSED AREA WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING. LAUNDER CONTAMINATED CLOTHING BEFORE RE—USE. EYES: FLUSH WITH LARGE AMOUNTS OF WATER, LIFTING UPPER AND LOWER LIDS OCCASIONALLY, I GET MEDIC :AL ATTENTION. SWALLOWING: DO NOT INDUCE VOMITING, KEEP PERSON WARM, I !IJ I ET, AND GET MEDICAL ATTENTION. ASPIRATION OF MATERIAL INTO THE LUNGS DUE TO VOMITING CAN CAUSE CHEMICAL PNEUMONITIS WHICH CAN BE FATAL. INHALATION: IF AFFECTED, REMOVE INDIVIDUAL TO FRESH AIR. IF BREATHING IS. DIFFICULT, ADMINISTER OXYGEN. IF BREATHING HAS STOPPED, GIVE ARTIFIC :IAL RESPIRATION. kEEF' PERSON, ► !U I ET AND /GET MEDICAL ATTENTION. SECTION VI REACTIVITY DATA STABILITY: UNSTABLE ____ STABLE XX__ HAZARDOUS POLYMERIZATION: MAY OCCUR ____ WILL NOT OCCUR XX_— HAZARDOUS DEC :OMF'OSITION PRODUCTS: CONDITIONS TCI AVOID: KEEP AWAY FROM OPEN FLAMES, SPARKS, AND HEAT. DO NOT WELD NEAR OR AROUND PRODUCT. INCOMPATIBILITY (MATER I ALS TO AVOID): AVOID CONTACT WITH STRONG OXIDIZING AGENTS. . | SECTION VII SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: SMALL SPILL: ABSORB LIQUID ON PAPER, VERMICULITE, FLOOR ABSORBENT, OR OTHER 3SORBENT MATERIAL AND TRANSFER TO HOOD. LARGE SPILL: ELIMINATE ALL IGNITION SOURCES (FLARES, FLAMES INCLUDING PILOT LIGHTS, ELECTRICAL SPARKS). PERSONS NOT WEARING PROTECTIVE EQUIPMENT SHOULD BE EXCLUDED FROM AREA OF SPILL UNTIL CLEAN—UP HAS BEEN COMPLETED. STOP SPILL AT SOURCE, DIKE AREA OF SPILL TO PREVENT SPREADING, PUMP LIQUID TO SALVAGE TANK. REMAINING LIQUID MAY BE TAKEN UP ON SAND, CLAY, EARTH, FLOOR ABSORBENT, OR OTHER ABSORBENT MATERIAL. PREVENT RUN—OFF TO SEWERS, STREAMS, OR OTHER BODIES OF WATER. IF RUN—OFF OCCURS, NOTIFY PROPER AUTHORITIES AS REQUIRED, THAT A SPILL HAS OCCURED. WASTE DISPOSAL: DESTROY BY LIQUID INCINERATION. CONTAMINATED ABSORBENT MAY BE DEPOSITED IN A LANDFILL IN ACCORDANCE WITH LOCAL, STATE, AND FEDERAL REGULATIONS. 1 SECTION VIII SAFE HANDLING AND USE INFORMATION RESPIRATORY PROTECTION: IF TLV OF THE PRODUCT OR ANY COMPONENT IS EXCEEDED, A NIOSH/MSHA JOINTLY APPROVED AIR SUPPLIED RESPIRATOR IS ADVISED IN ABSENCE OF PROPER ENVIRONMENTAL CONTROL. OSHA REGULATIONS ALSO PERMIT OTHER NIOGH/MSHA RESPIRATORS UNDER SPECIFIED CONDITIONS. (SEE YOUR SAFETY EQUIPMENMT SUPPLIER). ENGINEERING OR ADMINISTRATIVE CONTROLS SHOULD BE IMPLEMENTED TO REDUCE EXPOSURE. /ENTILATION: PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL EXHAUST) vENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S) PROTECTIVE GLOVES: WEAR RESISTANT GLOVES SUCH AS:, NITRILE RUBBER EYE PROTECTION: CHEMICAL SPLASH GOGGLES IN COMPLIANCE WITH OSHA REGULATIONS ARE ADVISED, HOWEVER, OSHA REGULATIONS ALSO PERMIT OTHER TYPE SAFETY GLASSES. (CONSULT OUR SAFETY EQUIPMENT SUPPLIER). OTHER PROTECTIVE EQUIPMENT: TO PREVENT REPEATED OR PROLONGED SKIN CONTACT, WEAR IMPERVIOUS CLOTHING AND BOOTS. HYGIENIC PRACTICES: KEEP WORK AREA CLEAN AND FREE FROM LEAKS, AND SPILLS. ALWAYS WASH HANDS THOROUGHLY WITH SOAP AND WATER BEFORE HANDLING FOOD AND DRINK. 1 SECTION IX SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: CONTAINEERS OF THIS MATERIAL MAY BE HAZARDOUS WHEN EMPTIED, SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUES (VAPOR, LIQUID, AND/OR SOLID), ALL HAZARD PRECAUTIONS GIVEN IN THE DATA SHEET MUST BE OBSERVED. THE INFORMATION SUPPLIED IN THIS DATA SHEET IS BELIEVED TO BE ACCURATE AND TRUE AT THE TIME OF PREPARATION OF THIS DOCUMENT. THIS IS IN NO WAY A WARRANTY OR PRODUCT SPECIFICATION. IT IS THE RESPONSIBILITY OF THE END USER OF THIS PRODUCT TO VERIFY IN ADVANCE THAT THE INFORMATION IN THIS SHEET IS CURRENT, APPLICABLE, AND SUITABLE TO THEIR CIRCUMSTANCES. ./u/farwest/msds/605.ms imptox The Clorox Company 7200 Johnson Drive Pleasanton. California 94566 ��TeL (415) 847.6100 CLOROX -HMIS HEALTH 2* Material Safety FLAMMABILITY Data Sheet REACTIVITY 1 Poona Flotation 9 I Chemical Identification NAME: TILEX CAS no. N/A DESCRIPTION: FAINT YELLOW LIQUID WITH FRAGRANCEO ODOR RTECS no. N/A Other Designations Mildew Stain Remover Clean Scent Formula Tilex Manufacturer Emergency Procedure The Clorox Company 1221 Broadway Oakland, CA 94612 11 Health Hazard Data "Moderate eve irritant. May irritate skin. May cause nausea and vomiting if ingested. Exposure to vapor or mist may irritate nose, throat and lungs. The following medical conditions may be aggra3ated by exposure to high concentrations of vapor or mist: heart conditions or chronic respiratory problems such as asthma, chronic bronchitis or obstructive lung disease. Under normal consumer use conditions the likelihood of any adverse health effects are low. FIRST AID: EYE CONTACT: Flush eyes thoroughly with water. If irritation persists, see a doctor. SKIN CONTACT: Remove contaminated clothing. Wash exposed area with water. INHALATION: If breathing problems develop remove to fresh air. INGESTION: Drink a glassful of water and call a phi sic an— 1 Notify your Supervisor Call your local poison control center or Rocky Mountain Poison Center (303) 573 -1014 111 Hazardous Ingredients In.redient Concentration worker Ex osuit Sodium hydroxide 0.5 -2% m - re Lim CAS 1 1310 -73 -2 Sodium hypochlorite 2 -5% not established CAS I! 7681 -52 -9 None of the ingredients in this product are on the IARC, NTP or OSHA carcinogen lists. TLV-C= Threshold Limit Value - Ceiling. The worker exposure limit should not be exceeded at any time. Source: ACGIH. Occasional clinical reports suggest a low potential for sensitization upon exaggerated exposure to sodium hypochlorite if skin damage (eg. irritation) occurs during exposure. Routine clinical tests conducted on intact skin with Tilex found no sensitization in the test subjects. IV Special Protection Information V Special Precautions Hygienic Practices: Wear safety glasses. With repeated or prolonged use, wear gloves. Engineering Controls: Use general ventilation to minimize exposure to vapor or mist. Work Practices: Avoid eye and skin contact and inhalation of vapor or mist. VI Spill or Leak Procedures Small quantities of less than 5 gallons may be flushed down drain. For larger quantities wine w with an absorbent material or moo and dispose of in accordance with local, state and federal regulations. Dilute with water to minimize oxidizing effect on spilled surface. VIII Fire and Explosion Data Not flammable or explosive. In a fire, cool containers to prevent rw ture aria the release of sodium chlorate. Keeo out of reach of children. Use only in well ventilated area. Open windows and turn on fans before use. Avoid prolonged breathing of vapor. If fumes bother you leave the room. Avoid prolonged contact with metal and porcelain as Tilex can react with these materials and leave a "rusty" Th6E. Do not use on wood or painted surfaces unless you plan to refinish or paint them. Avoid contact with clothes, fabrics or pacer sufraces as they will discolor. Oo not use bottle or spray with other products. VII Reactivity Data Stable under normal use and storage conditions. Strong • oxidizing argent. Reacts with other household chemicals such as toilet bowl cleaners, rust removers, vinegar, acids or ammonia containing products to produce hazardous gases, such as chlorine and other chlorinated species. Prolonged contact with metal may cause pitting or discoloration. IX Physical Data Boiling point approx. 2120F/100°C Evaporation Rate (H20 =1) anprox. 1 Solubility in Water complete pH 12.4 - 12.8 0361m 41983 THE CLOROX COMPANY DATE PREPARED 10 /89 DATA SUPPLIED 1S FOR USE ONLY IN CONNECTION WITH OCCUPATIONAL SAFETY AND HEALTH. L'HIH IRODUCTS INC TEL No.2066568319 Material Safety Data Sheet Meg be usaa a Conegy won 08MA'a tea.tard Comnxincenon Standard. 29 CM 1810.1200 elondera mud be comb ied tar *peal* regr.darnaree. 10dNT11Y tAa Lend On tad end taa Jan 9,92 14:57 No.005 P.02 U .S. Department of Labor Osa 0800at.l !buoy and Woo o Aglesi Nlrmum (NonManwaodlr km, NM& Ski 116e01r w astir Marrraadd M NW earn M not q 1% ar AD A08016100 it awaklls. er►mite NW Ota ateava le Wale P. SAdtlmn tl —∎ Hazardous ingr.dbrttslldwtlty 11110fraatIon V. 1 A r is !teat n Ca Solvents Silica Cas. #7431 -864 Silesian Hama ishyallCaUUC straCal GMrstouladca Bn vapar VApOr tAIA , 11 54 4.1.,rl►WSW 4044110011 1114 oust S$*tlan IY -- Fire and Expiosion Hazard Deus Insoluble wsltes.Ajtrir. Chem six Shcs Fr. rrgr Procwrrrs- ..._._ �,._._.�.�.. None unowt An, me £1*'g ton tiaMOS MIA 14e.51pl 10e5 DATA PRODUCTS INC TEL No.2066568319 Section V Rase* Data Jan 9,92 14:57 No.005 P.03 l0000terteit4y lMaten,M to ArOrd) team lovw Clocompewoon or eyproclooto None None Not A. li able in normal handlin and use. �'�tAay ocwr Palymernatert fiction VI teanM) of - Henteh Hazatd Data fie" in normal handlin : and use. Conaelaa a Apoio Not Applicable Bent og0000nt Malan t AMM (PA IM Moalth hazard is minimal being neither irritating, corrosive nor toxic. Thera is no health hazard in normal use condition. Carcinogenic .A tARC Aieonogrrc+l+rt and Syrop rns d Erlpcswa M.*4N CostOAeru nod tstOina poky WO Fite s'° Pr000dotooContact iith akin: Normal washing with soap and water, s Tr o r or Flush out with e e dto a. Inhalation: Remove from ex re Section VII •• Pt+ae autlona for Sala Nand ing and Ilia asps eo $e Twin M Cass Newel Is MaIwwo a If Ap tiled e veep up or pick up by vacut cleaner. r i two D,spoW Whoa Dis.oaal should conform to 1oca1 re :ulation. PIbcaulionsi to ee Talton w Kendbnp Arta ' np Reap containers cloned. Store in a cool dry place. colsr Prt+cemms Do not handle in areas where the wind blows flying powder may enter into es. Avoid :inhalation of dust. SectIon VIII Control Mansur** Reoptiloy rol.cIOA 1Spscfy T»;I) None. needed moomincsidomm4 Adequate ventilation rye °"* ".cis" wuanq or Egwtn+ pm _.. not required weeb y@. rtietrs tiloeho r Pops XEROX Material Safety Data Sheet MSDS No.: A -0072 Date: 3/16/88 Revision: 3/22/91 Manufacturer: Xerox Corporation Rochester, N.Y. 14644 Emergency Tel. No. : Information Tel. No. : Transportation Emergency Telephone No.: 716 422 -2177 800 828 -6571 (716) 422 -1230 Section I - Product Identification Trade Names /Synonyms: 1012/5012/5014 Dry Ink Cartridge Chemical Name: None Ingredients Styrene /acrylate polymer (45 -50 %) Iron oxide (45-50°A) Polypropylene wax (1 -5 %) Amorrphousammonium i 0)alt(1 -3 %) Part No. : 6R257, 6R275, 6R456; XLG: 6R259; XCI: 6R557, 6R558 CAS No. 25767 -47 -9 1309 -38-2 9003 -07 -0 102561-46-6 7631 -86 -9 Eyes: Skin: Inhalation: Ingestion: Primary Route of Entry: Symptoms of Overexposure: Medical Conditions Generally Aggravated by Exposure: Additional Information: Section II - Emergency and First Aid Flush with water. Wash with soap and water. Remove from exposure. Dilute stomach contents with several glasses of water. Inhalation Minimal respiratory tract irritation may occur as with exposure to large amounts of any non -toxic dust. None when used as described by product literature. See Sections V and VII. Further information on file in Poisindex. Section III - Toxicology and Health Information This material has been evaluated by Xerox Corporation. Oral LD5D: Dermal LDso: Inhalation LCso: Eye Irritation: Skin Sensitization: Skin Irritation: Human Patch: >5 g /kg (Rats) practically non- toxic.1 >2 g /kg (Rats) practically non- toxic.1 >5 mg /I (Rats) practically non- toxic..1,2 Non - irritating Not a sensitizer.1 Not an irritant.1 Non - irritating, non - sensitizing Mutagenicity: No mutagenicity detected in Ames Assay. Carcinogens: None present Aquatic LCso: Not tested Additional Information: Some of the information noted above is based on toxicity data for similar toners. In a Xerox sponsored chronic inhalation study in rats using a special test toner, there were no lung changes at all in the lowest exposure level (1 mg /m3), the most relevant level to potential human exposures. A very slight degree of fibrosis was noted in 25 % of the animals at the middle exposure level (4 mg /m3) while a slight degree of fibrosis was observed at the highest exposure level (16 mg /m3) in all animals. These findings are attributed to "lung overloading," a generic response to excessive amounts of any dust retained in the lungs for a prolonged interval. The special test toner was ten times more respirable than commercially available Xerox toner to comply with EPA testing protocol and would not function properly in Xerox equipment. TLV: 10 mg/m3(Total Dust) PEL: 15 mg /m3 (Total Dust) 5 mg /m3 (Respirable Dust) STEL: None established Ceiling: None established XEL3: 2.5 mg /m3 (Total Dust) 0.4 mg /m3 (Respirable Dust) 1Data from testing of similar materials. 2Nottested to the highest dose or concentration 3XEL -Xerox Exposure Limit (1) We, MATERIAL SAFETY DATA SHEET I. PRODUCT IDENTIFICATION NP1fA 1 Manufacturer: Address: WD-40 Company 1061 Cudahy Place (92110) P.O. Box 80607 San Diego, California 92138»9021 Telephone: Emergency Only: Information: Chemical Name: Made Name: 1 (CHEMTREC) 9300 (819) 275-1400 Organic Mixture WD-40 Aerosol 11. HAZARDOUS INGREDIENTS Chemical Name Aliphatic Petroleum Distillates A•70 Hydrocarbon Propellant Petroleum Base Oil Non - hazardous Ingredients CAS. Number 8052-41.3 68476-85-7 64742.65.0 50 25 >15 <10 ACGJH/OSHAt 100 plain (PEL) 1000 ppm (PEL) 5 mg/Ma (TWA) III. PHYSICAL DATA Bolling Point: Vapor Density (air =1): Solubility in Water: Specific Gravity (Hz0.1): Percent Volatile (volume): IV. FIRE AND EXPLOSION NA Greater than 1, Insoluble • .710 @ 70°F 80% Evaporation Rate: Vapor Pressure: Appearance: Odor: Flash Point: Flammable Limits: Extinguishing Media: Special Fire Fighting Procedures: Unusual Fire and Explosion Hazards: Not determined 5565 PSI @ 70 °F Light amber Characteristic odor NA :fp: ae /Osol cans, (propellant portion) (I.el) 1.8% (UM 9.5% COs. D y •Chemical; Foam None Considered "extremely flammable" under Consumer Product Safety Commission .regulations. V. HEALTH HAZARD / ROUTE(S) OF ENTRY Threshold Limit Value Aliphatic Petroleum Distillates (Stoddard solvent) Iowest.TLV (ACGIH 100 ppm.) Symptoms of Overexposure Inhalation (Breathing): May cause anesthesia, headache, dizziness, nausea and upper respiratory irritation. Skin Contact: May cause drying of skin and or irritation. ' Eye Contact: May cause irritation, tearing and redness. Ingestion (Swallowed): May cause Irritation, nausea, vomiting and diarrhea. `• First Aid Emergency Procedures ingestion (Swallowed): Do not Induce vomiting, seek medical attention. Eye Contact: Immediately flush ayes with, lard amounts of water for 15 minutes. Skin Contact: Wash with soap and water. • • - Inhalartion (Breathing): Remove to fresh air. Give ariiiicaal•raspiratton if necessary. 11 breathing is difficult, give oxygen. DANGER! Aspiration Hazard: If swallowed can enter lungs and may cause chemical pneurnonitfa. Do not induce vomiting. Call Physician immediately. Suspected Cancer Agent Yes No X The components in this mixture have been found to be noncarcinogenic by NTP, IARO and OSHA. pact , anHd ANHdwn'1 MO-rTM I.in?i. 1n:Gt .R. R2 mF-Ir VI. REACTIVITY DATA Stability: Conditions to avoid: Incompatability: Hazardous decomposition products: Hazardous polymerization: (2) Stable •X Unstable NA Strong oxiifizirig materials Thermal decomposition may yield carton monoxide and/or carbon dioxide.. • May occur. Will not occur X VII. SPILL OR LEAK PROCEDURES Spill Response Procedures Spill unlikely from aerosol cans. Leaking cans should be placed in plastic bag or open pail until pressure has dissipated. Waste Disposal Method Empty aerosol cans should not be punctured or incinerated; bury in land fill. Uquid should be incinerated or buried in land fill. Dispose of In accordance with local, state and federal regulations. VIII. SPECIAL HANDLING INFORMATION Ventilation: Sufficient to keep solvent vapor Tess than TLV. Respiratory Protection: Advised when concentrations exceed TLV, Protective Gloves: Advised to prevent possible skin irritation. Eye Protection: Approved eye protection to safeguard against potential eye contact, Irritation or injury. Other Protective Equipment: None required. J IX. SPECIAL PRECAUTIONS Keep from sources of ignition, do not take internally. Avoid excessive inhalation of spray particles. Do not puncture. incinerate or store container above 120 °F.:koep from children, X. TRANSPORTATION DATA Domestic Surface Description; • Consumer Commodity Hazard Class: ORM-D ID No,: NONE Label Required: Consumer Commodity (ORM -D) Domestic Air Description: Consumer Commodity (Flammable Gas- Aerosol products) Hazard Class: ORM -D ID No: NONE Label R auired: Consumer Commodity (ORM.D.AIR) SIGNATURE: A. Miles TITLE: Technical Dira for REVISION DATE: March 1990 SUPERSEDES: ,January 1988 NA az Not applicable NDA = No data available < w Less than > in More than We believe Ole statements, technical information and recommaneationtricont iinod bream are roaeble. Howerw, the data Is pmarlded without warranty expressed or Imi,lled, It Is the users responsibility both to determine We conditions for tee of this product end assume Lois, damage or expanse, direct or consequential, arising from Its use. t lsoro using prodUct.rsaWihtti, ' ANH,IWA1 Mt► -am WAN -I 1 R t q t PR, RR WHr f'.RR • goHri MATE ( 3) Ftre Aeaetivey HMi IAL SAFETY DATA SHEET NASpec,at S 1. PRODUCT iDENTiFIQ'ATION Manufacturer: Address: WD -40 Company 1061 Cudahy Place (92110) P.O. Box 80607 San Diego, Califomia 92138-9021 Telephone: Emergency Only: information: Chemical Name: Trade Name: 1 (800) 424-9300 (CHEMTREC) (619) 275.1400 Organic Mixture WD-40 Bulk Liquid IIi. HAZARDOUS INGREDIENTS Chemical Name Aliphatic Petroleum Distillates Petroleum Base 011 Non - hazardous Ingredients CAS Number 8062 -41-3 64742 -65.0 Exposure SHAt 70 100 ppm (PEL) 6 mg1M3 (TWA) ? 20 <10 11I. PHYSICAL DATA Boiling Point: Vapor Density (air -1): Solubility in Water: Specific Gravity (H20.1): Percent Volatile (volume): 300°F (minimum) Greater than 1 Insoluble .800 70'3F 74% Evaporation Rate: Vapor Pressure: Appearance: Odor VOC: Not determined Not determined Cloudy light amber Characteristic odor 568grams per liter IV. FIRE AND EXPLOSION Flash Palrtt: Flammable Limits: Extinguishing Media: Special Fire Fighting Procedures: Unusual Fire and Explosion Hazards: Tag Open Cup 110 °F (minimum) (solvent portion) (Leif 1.0% Niel] 6,0% CO2, Dry Chemical, Foam None None V. HEALTH HAZARD / ROUTE(S) OF ENTRY Threshold Limit Value Aliphatic etroleum Distillates (Stoddard solvent) lowest TLV (ACGtH 100 ppm.) • Symptom of Overexposure Inhalation (Breathing): May cause anesthesia, headache, dizziness, nausea and upper respiratory Irritation. Skin Contact: May cause drying of skin and or irritation. Eye Contact: May cause irritation, tearing and redness. Ingestion (Swallowed): May cause irritation, nausea, vomiting and diarrhea. First Aid Emergency Procedures Ingestion (Swallowed): Do not induce vomiting, seek medical attention. Eye Contact: Immediately flush eyes with large amounts of water for 15 minutes. Skin Contact: Wash with soap and water. Inhalation (Breathing): Remove to fresh air. Give artificial respiration if necessary. If breathing Is difficult, give oxygen. DANGER! Aspiration Hazard: If swallowed can enter lungs and may cause chemical pneumonids, Do not.induce vomiting. Call Physician immediately. Suspected Cancer Agent Yes No X The components in this; rrtl,t6re• have been found to be noncercinogenle by NTP, !ARC and OSHA. roe • 39Hd ANddWOD 0t' -QM WO21 d 80 : S t P8 , AR NHr (4) Vt. REACTIVITY DATA Stability: Conditions to avoid: Incompatabiiity: Hazardous decomposition products: Hazardous polymerization: Stable X NA Strong oxidizing materials 'Thermal dec:ompoettion may yleld carbon monoxide and/or ce bon dioxide. May occur Unstable not occur X VII. SPILL OR LEAK PROCEDURES Spill Response Procedures Absorb small quantities with sand, earth, sawdust. Large quantities pump into tank. Waste Disposal Method Incinerate liquid, bury saturated absorbent in land fill. Dispose of in accordance with local, state and federal regulations. • VIII. SPECIAL HANDLING INFORMATION Ventilation: Respiratory Protection: Protective Gloves: Eye Protection: Other Protective Equipment: Sufficient to keep solvent valor less than TLV. Advised when concentrations exceed .TLV. Advised to prevent possible skin irritation. Approved eye protection to safeguard against potential eye contact, irritation or injury. None required. IX. SPECIAL PRECAUTIONS Keep from open flame, do not take internally. Avoid excessive inhalation of spray particles. Keep from children. X. TRANSPORTATION DATA Domestic Surface Description: Hazard Class: ID No.: Label Required: Domestic Air Description: Hazard Class: Label Required: Petroleum Distillate Mixture Combustible Liquid UN 1268 NONE, for containers less than 100 Gallons Petroleum Distillate Mixture Combustible Liquid • NONE, for containers lass than 110 Gallons SIGNATURE: R. Miles REVISION DATE: NA = Not applicable TITLE: Technical_ Director March 1990 • SUPERSEDES: January 1989 NDA ,s No data available < Lass than > = More than We believe the statements. technical information and recanmr ndation wOhred herein are reliable. However, the data le wadded without warranty, expressed or 'Theft 11 ie the users respoheibilky both to de termnlnd sb : dtlons lOr use of MO, product sad assume toes, damage et expense, diroa or cone uential, arising from its use. Betore using prodect,..ro4 14b01. WD-4OETechrilct1 Data. Physical Characteristics APPEARANCE COLOR ODOR SPECIFIC GRAVITY VISCOSITY Clear ortightly cloudy light ember Very shark .000 = .020a172'P. 2TS t 1.0 sec. Uri 1 at7rF. RASH POINT (MINIMUM) 110'F. open cup PERCENT NON- VOLATILE 22%bywoight Properties PeRCETTVOLATILE POUR POINT LOW CC ERAGE NOUNS POINT (04rrIAL) WEICOM applied coaling 711%hyweighl aliphatic petroleuMdatitb teasIhaa- 100'F. Bodoni 000b 11000aq.ft per colon 300' F (vnM mum) 3.4x1O4bsls it .0001 b MCC inch CORROSION PROTECTION: I.JJa CA1IION: Dynamic, ooefACant of fdo ion (on fres by sanded mild sheet panels) EXPOSURE Humidity (JAN- H•792) Belt Spray (FED STD 151) Soh Spray FED STD 151) NE5ULTS No rust after 1002houre No rust after 50 hours • Rust beginning alter 100 hours Under actual conditions the duretion of protoodon obtained the type Ol mabelaiing protected a w conditions o f e � i posure. G e n e r a l l y , on m a the protecdbn under various conditions WI be approxatately as follows: 1. Covered or indoor storage 1 year Dr anger 2. Protect edoxbtlor clomp 6months to 1 year 3. Norma! anterior exposers 30 to 80 days 4. Severe exterior exposuro 15 to 30 days (on or near the beach, Bulled to high humidity. salt spray end ash fog) If Songar protectbn is decked, Wd-40 should he $ hay reapplied w11en necessary. Effect on Materials SEARING .PRESSURE 100pgi 'woo poi 2000 pi 9000 psi 4000 pal COEFFICIENT 0.112 0.114 0.129 0.138 0.146 TEST NW toad X1340steel Whnoenolfl Mal adds fNm agranetifetel lubricated walIWD40 ELECTRICAL, Dielectric strength AfTM D e7712,000 V. per 0.100111. Contact resislaroe eAli TM 8-182 waled BARS wt CONTACT *MATED me CONTACTS CONTACTS nomn before cycling 0.0068 0.00113ai .h 0.0017dun after cycles 0.0007 0.0066oIan 0.0018 ohm aRcr100cycles 0.0050 0.0006ohmt 0.0017ohm der t000oyolee 0.0074 0.006501m 0.0011 trim idler20.000cycee 0.0063 0.0001/ohm 0.0018ohm GENERAL: Nearly all materials react to WD-40 ao they world to high glade eaphatic petroleum epirih with Ile suns exposure. I.e., eprey, gthck rap Or ptdon0ed immersion. WD-40 Onntakls no siiaon, tenon or RUDDER: No visible effects on surfao09 of verbustypas rubber sprayed with WI] -40. Curtain typos of lubberwdlia►Ner upon prolonged Immersion in WD-40. MOH STRENGTH STEELS (far hydrogen embriherrwrd): Certified SAFE according to the L mnce Hydrogen Eift*lonTeat FABRICS: The following fabrics were exposed to WD-40 with no effect. except alight staining width wee readily removed with naphtha or dry cleaning solvent: Nybn. Orion, Waal, Dacron, Cotton. Application PAMFJOSURFACES: Many types cApairtanvarious surfaces hew been exposed to WD 40 with no effect Was polishes and certain egmecostings may be edtenad by WD-40. PLASTICS: The ptasice were Immersed In WD-40 for 156 hourswflh no *die effects: Pdyethybno Formica Epee/ 17eirh Arnie Vinyl T� Polyoctar Nylon Clear pdyctubon8te and polystyrene may Obese craze or crack h =toot WD-40. NOTE Appliadian d =Best malts eel be obtained when ties r:ac etoGinned. Linesalspirit6, lacquer dinner, vapor timesaving oraWilns dewier are suitable. DANGER; COMBUSTIBLE HARMFUL OR FATAL IF SWALLOWED. Codeine petroleum ctetlgessa. If mimed. do eat induce yarning. Call physician. Keep barn chldren. WD-40 COMPANY,1061 Cudahy Plena, Ban DNgo. CalilOnsia 02110 ( 818)275.1400,1 AX'.(61f1)^+78.602.9 IP16 ** L00' 30 d 34101 ** • WD -40's Five Basic Functions. DispAgeqs Moisture. isformulated for ultra -high surface attraction to metal. It completely covers surfaces, Including g micro - sc epic irregularities, even in the presence of triWtue, In fact, WD-40 g under surface moisture and establishes a protective barrier between the moisture and the parent metal. WD-40 is a of electricity and quiddy eliminates moisture - induced short circuits. Penetrates. WD -40's ultra -high surface attraction results in a super penetrating action that loosens rust-to-metal bonds and frees stuck, frozen, or rusted metal parts. The lubri- cating properties of WD-40 then keep these parts working freely. Protects. WD-40 deposits corrosion - resistant ingredients over the entire surface area, including microscopic•ir lar- ities. This protective barrier shields against moisture and ent otter corrosive elements. WD-40s capability also preludes the possi , bilityof a srrill moisture pocket causing future problems. Cleans. WD -40's ultra -high surface attraction enables itto get under dirt, grime, caked grease, and oil to clean the surface at the same time it form a corrosion- resistant barrier. It also dissolves most adhesives, allowing for tie easy re- moval of labels and excess bonding materials. Lubricates. WD -40's ultra -high surface attraction assures the lubricating ingredients in WD-40 will be widely dispersed and tenaciously held to all moving parts. WD-40 contains no silicone or other additives that attract dust and dirt causing a buildup of gummy, greasy residues. • MtMA GENERAL NOTES 1. The Contractor shaall be governed by all conditions as indicated In the Construction Drawings and Specifications. 2. All work, shall conform to the applicable building codes and ordinances. In case of any conflict where the method or standards of installation or the materials specified do not equal or exceed the requirements of the laws or ordinances, the laws or ordinances shall govern. 3. The Contractor shall be responsible for safety Ir. the area of work in accordance with all applicable safety codes. 4. The Contractor shall indemnify and hold the joiner /Architect/Engineer harmless for injury or death to persons or for damage to property caused by the negligence of the Contractor, his agents, employees or subcontractors. Each Contractor is responsible for any damage to adjacent work and is responsible for the repair of said damage at his own expense. Workmanship shall be first class and to accepted standards recognized within each state or trade. 7. Structural, plumbing, mechanical, electrical and fire protection drawings are supplementary to these drawings. The Contractor shall coordinate the work of each consulting engineer and shall notify the Architect of all discrepancies. . . All information shown on the drawings relative to existing conditions is given as the best present knowledge. Contractor shall field verify existing conditions and dimensions and shall notify the Architect of any discrepancies. Do not scale drawings. 9. Unless otherwise indicated, dimensions for all new work are measured from face of stud and dimensions of existing work are measured from - face of existing finish. 1 0. Doors and cased openings without location dimensions are to be six inches from the face of the adjacent partition or centered between partitions. 11. Locate walls that are not dimensioned toe flush and square with the existing structure or on the centerline of a window mullion. The Contractor shall investigate and verify locations of structural, mechanical, and electrical elements and other existing conditions prior to drilling or cutting of slabs or structural members. . 12. 13. The Contractor shall be responsible for providing all wall blocking as required for all wall and ceiling mounted items. ABBREVIATIONS AC ACT Adj Alt Alum Arch C Bldg B!k'9 B/S Cab Clr Cig CL Clos CWL Const Cont Ct Det Dia Dim Dn Dr Dwg Ea EL Elec Eiev Eq Fin FH Fir Fluor Ft FTIC Furn Get GI GWB HCW Hdw Dior HWL HM Ht Air Conditioning Acoustical Ceiling Tile Adjustable /Adjacent Alternate Aluminum Architectural At Building Blocking Building Standard Cabinet Clear or Clearance Ceiling Centerline Closet Cold Water Line Construction Continuous Carpet Detaii Diameter Dimension Down Door Drawing East Each Elevation (height) ' Electrical Elevation (view) Equal Finish Full Height Floor Fluorescent Foot'Feet Furnished by Tenant Installed by Contractor Furnish /Furnishing Gauge Glass Gypsum Wall Board Hollow Core Wood Hardware Horizontal Hot Water Line Hollow Metal Height In lnca.n incl J Jt Kit Lam LF Ltg Mach Mat Max Mech Mfr. Msc. Mtd Mtl N N/A WC. No Nom Non Comb NTS OC Opng PpLa - m P lwd Pr Pt RB Req'd Rev fpm R0 Schod Seal Sect Sht Sim Sq Std Stl Stg Inch Incandescent Include Junction Box Joint Kitchen Laminate Lineal Foot Lighting Machine Material Maximum Mechanical Manufacturer Miscellaneous Mounted Material /Metal North Not Applicable Not in Contract Number Nominal Non Combustible Not to Scale On Center Opening Opposite Plastic Laminate Plywood Pair Paint Radius Rubber Base Required Revision /Reverse Room Rough Opening South gehudujn Solid Core Wood Sealant Section Sheet Similar Square Standard Steel Storage 14. All construction shall be stabilized against lateral movement in accordance with the requirements of the latest adopted edition of the UBC in the local jurisdiction. 15. . Ceiling heights, where indicated, are from concrete to bottom of ceiling •, grid or other finished surface. 16. Mechanical work shall be conducted under separate permit. 7. There shall be no ;:••posed pipe, conduits, ducts, vents, etc. All such lines shall be concealed or furred and finished, unless noted as exposed construction on drawings. 18. Provide galvanic insulation between dissimilar metals. 19. The Carpet Contractor shall furnish and install rubber reducer strip at locations where carpet and resilient flooring meet. Provide color samples for approval. 20. Electrical/Telephone outlets will be mounted vertically at +12" unless otherwise noted. All wail mounted receptacles 1cx ateel in casework are to be mounted horizontally. Special heights are noted adjacent to the outlet. 21. Asbestos: It is the Contractor's responsibility to insure asbestos inspections have been completed and forms submitted to the governing agency prior to commencing work of any kind. 22. Throughout the plans are abbreviations which are common use. The list of abbreviations'proyided is not intended to be complete or representative of conditions.or materials actually in use on the project. The architect Will define the intent of any in question. 23. Contractor shall verify;slzes and !-cations of an openings for and electrical et- 44111eht With Mechannigal and electrical contractors, as well as shop drawings appl=i3vetl by iirchltect before proceeding with work. • 24. Provide tlr dampers and'access panels for ducts and AlO fixtures when passing through a fire rated enclosure. Provided'fire'dampers at all supply air and return air cutlets or inlets penetrating fire rated assemblies, enclosures, and surfaces and as required by the Fire Department code. Class Ili flame spread required on interior finished and materials. All wood blocking to be fire treated. All batt insulation, including facing, shall have a flame spread rated not to exceed FS 25. All exit doors shall be openable from the inside without the use of key or any special knowledge t.;i effort. All thresholds are 1/2" el. change max. A11 exit signs shall have letters six (6) inches high min., and s.hafl conform with applicable codes. fir Susp Tel Ternp Typ Var V Grid. vein Vert W W/ we Wd Suspended Telephone Tempered Typical Varies Vinyl Cornposition Tile Veneer Vertical West/Watt/Width With Without Wallcovering Wood SYMBOLS DIRECTORY Owner: Caroline and Donald Leuthold 7275 West Mercer Way. Mercer Island, WA 98040 (206) 236-6129 Donald W. Leuthold Tenant: Chemical Waste Management, Inc. 19002 72nd Aveuue South Kent, WA 98032 (206) 251-6227 Robert Mitchell Contractor: Seattle Construction Resources, Inc. 413 3rd West Seattle, WA 98119 (206) 282 -7500 Michael J. Sloate /AGENCY NOTES ZONE FIRE ZONE OCCUPANCY CONSTRUCTION TYPE BUILDING AREA SITE AREA LEGAL DESCRIPTION C-M 111 B -2 III N SPRINKLERED 23300 SQ.FT. 52370 SQ,FT. Parcel A: That portion cif the Southeast of the Southeast ':, of Section 26, Township 23 .North, Range . 4 East W.M., described as follows: Beginning at the Southeast corner of said subdivision; thence North 8Z °44'08" West along the South line of said subdivision 166.46 feet; thence North 1'47'29" East 213.76 feet to the true point of beginning; thence North 88 °12'31" West 253 feet to the East line. of street conveyed to the City of Tukwila by instrument recorded under Auditor's File No. 6375442; thence North 147'29" East 107 feet; thence South 8$ 12'31" East 253 feet; thence South 1'47'29" West 107 feet to the true point of beginning. Parcel 13: That portion of the Southeast .i of the Southeast '., of Section 26, Township 23 North, Range 4 East W.M., described as follows: Beginning at t4 Southeast corner of said subdivision; thence North 87'44'08' West along the South line of said subdivision 166.46 feet; thence North 1 °47'29" East 320.76 feet to the true point of beginning; thence North 88 1'!'31" West 253 feet to the East line of street conveyed to the City of Tukwila by instrument recorded under Auditor's File No. 6375442; thence North 1°47'29" East 100 feet; thence South 8r12'31" East 253 feet; thence Soutt' 1'47'29" West 100 feet to the true point of beginning. CITY OF TUKWILA APPROVED 'm Of 0 Baal IVISION /:1 to a< �I 1 111111111111111 1111111 VIII 111111111 Ili ;1111i1 0 e TH3 INCH 1 2 fr3 • It -,s1 (II' + 1i11 I If I`; 'I l f 11 III 4._... 6....,.., .._ . ,, NOS: If the iicvofilmed document is base clear than this notice, it is due to the quality of U4e original document, 0C 6E r 12 9Z GE tE (CZ z? tIIe OG 111 IIIIII�Iili111I1111111111I111111111111111111I11I11111111111 41 11114lllt llllMiUl�illl ?d,7; " 11111111 111111 !ill II 1111 111111111111 10 11• NAOEINGERwm 12. DRAWING INDEX T -1 TITLE SHEET A -1 PARTITION /ELECTRICAL. PLAN A-2 REFLECTED CEILING PLAN S -1 SITE PLAN S-2 RAMP DETAILS .. -.. 1'/Vil N NAAP Emick Howard Nelson & _Seibert, Inc. 119 Pine Street Suite 30^ S••eattle, WA 98 1 0 1 ( 2.0 6) 2 2 3 - 4 9 9 9 OR A W I N E . DRAWN: CHECKED: D A T E : 413*-- •,•....tY4b8:CHl1 :NS OE T.+ REVsSI0NS NO. DATE DESCRIPTiON BY C L! F k T APPP0Vf'_ APPROVED: DATE- APPROVED: DATE: 1427.103 tmastratand that Om Pim Chock mixovels we to oppmva1 of does 864 seibleati akttott of any Oft et elent sr S E F T I T L E TITLE SHEET ZWITTZWITEV P R O J k C T T 1 T 1. E r z co a 11-- 0 te% run= had .3J3qJ ({jam Eft,11,76 (a) el: RECEIVED CITY OF TUKWILA MAY 7 t99'3 PERMIT CENTER c emtki tbrvril z (.1) fre S H E E• N O. SA.A stel r,I 4 EL.ECTJIC,A► . NOTES ALL WALL MOUNTED TELEPHONE AND ELE.CTRICAL OUTLETS TO BE INSTALLED 12" ABOVE FLOOR UNLESS OTHERWISE: NOTED. ALL CORE DRILL LOCATIONS SMALL BE VERIFIED WITH DESIGNER PRIOR TO - DRILLING. ALL UNUSED CORE DRILLS SHALL BE PLUGGED 8 CAPPED AS REQUIRED TO MAINTAIN FLOOR FIRE RATING. ALL TELEPHONE AND COMPUTER WIRES SHAD. BE PULLED BY TENANTS CONTRACTOR. ELECTRICAL CONTRACTOR SHALL PROVIDE PULL WIRES AND BOXES AT EACH LOCATION. ' • egxrr -rc SuRe ..- Al7pNCa 91-v" oe. w /21,12' MTL.�fiJl?S oee ca. t I Its Ye row 7Pt.Q t t.tr) IV:Tkp mere iu uur. t• Ftra,. T,ctn Y /nrrA �W4'rj11IIxv+106A. fRAC< w/t 1'10 Sca,EUf. a 24•0.c. __ -- - -1'h` ► t� ct. LAY. Sit. out:, 2'• d o.C. AL eliAKET --- Sra'rIU AATAD mu .L 6o ° (out stout coNSYReCn4N° 15 4 Darer. ,ter A' t% Wit att. 4. via. - ton k5 f.7.. LktY. Sn. Ragtag. CA MiEEL - AualoQtD TO /LOW. s ram, pre :rATAP i1 1171AI AT frPUttC SECT. @ BUILDING STANDARD PARTITION • Q fT N T'[ `• E ND DUPLEX RECEPTACLE OUTLET FLOOR MOUNTED DUPLEX RECEPTACLE OUTLET DUPLEX RECEPTACLE OUTLET - DEDICATED CIRCUIT 120V, 20A FOURPLEX RECEPTACLE OUTLET FLOOR MOUNTED FOURPLEX RECEPTACLE OUTLET FOURPLEX RECEPTACLE OUTLET - DEDICATED CIRCUIT 120V, 20A SIMPLEX RECEPTACLE - DEDICATED CIRCUIT 120V, 20A WALL MOUNTED TELEPHONE OUTLET DEDICATED TELEPHONE LINE WALL MOUNTED COMBINATION TELEPHONE /CRT CABLE OUTLET FLOOR MOUNTED TELEPHONE OUTLET FLOOR MOUNTED COMBINATION TELEPHONE /CRT CABLE W,611 MOUNTED CRT CABLE RECEPTACLE OUTLET FLOOR MOUNTED CRT CABLE RECEPTACLE OUTLET ,I BOX TIMER NEW NOTE: ALL OUTLETS EXISTING UNLESS OTHERWISE INDICATED PARTITION NOTES THERE SHALL BE NO EXPOSED PIPE, CONDUIT, DUCTS, VENTS, ETC. ALL SUCH LINES SHALL BE CONCEALED OR FURRED AND FINISHED, UNLESS OTHERWISE NOTED AS EXPOSED CONSTRUCTION ON DRAWINGS. ' OFFSET STUDS WHERE REQUIRED, SO THAT FINISH WALL SURFACE WILL BE FLUSH, UNLESS OTHERWISE NOTED. PROVIDE FURRING AT EXISTING WALLS AS REQUIRED TO INSTALL ELECTRICAL ITEMS AS INDICATED ON THE DRAWINGS. DOOR AND CASED OPENINGS WITHOUT LOCATION DIMENSIONS ARE TO BE SIX INCHES FROM FACE OR ADJACENT WALL OR CENTERED BETWEEN WALLS: ALL WOOD USED ON THE JOB SHALL BE FIRE-TREATED. ALL EXIT DOORS SHALL BE OPENABLE FROM THE INSIDE WITHOUT USE OF KEY OR ANY SPECIAL KNOWLEDGE OR EFFORT. PROVIDE SHEET METAL REINFORCING Or HORIZONTALLY MOUNTED STRIP OF 20 GA. GALVANIZED SHEET METAL) IN PARTITIONS FOR INSTALLATION OF WALL HUNG CABINET WORK AND PANELING WHERE INDICATED ON DRAWING AND ALL OWNER PROVIDED ITEMS. ALL PARTITIONS, UNLESS OTHERWISE NOTED, SHALL BE CONSTRUCTED WITH 2 1/2" METAL S-UDS AT 24" O.C. WITH 5/8" TYPE "X" GYPSUM WALLBOARD EACH SDI. a" RItIANt I rt11 �'1T10lVGEN litigAMMAZEN EXISTING PARTITION EXISTING PARTITION TO BE REMOVED BIS TENANT PARTITION 5/8" TYPE "X" GWB BOTH SIDES EXISTING MS TENANT DEMISING PARTITION - TO STRUCTURE ABOVE — BUILT -IN CABINETRY zRY1 Su CORRIDOR CONSTRUCTION DOOR SCHEDULE DOOR NUMBER 'TYPE OF DOOR .►I • <' .ti4 • - #tfiani X911 ik ' I I. yawn OTHERWME B/S 2' -8" x 6' -8" H.. 0. WOOD POOR ,s B/8 WOOOD! .FRAME. > 3/ 3' -0" x ti', ' S. C. 20 MIN LABEL WOOD DOOR Mb FicIAME ASSET ftY. B/S 3' -0" x T.8". HOLLOW MET-Af DOOR IN HOLLOW METAL F,�' E. E X , t 2 1 O REMAIN. Bib l.00'I T ANO ct* WAREHOUSE f HQ. t::co t T`A'B doo Y \V/ 1.CCe4e1- G y , I611GL E; HCP R 14exv rIXii•IFRra \ GONFOIZM �f $2r.7(Aleemet -tra \t OFFICE WORK ROOM OFFICE a 4L4 OFFICE -F11 / ° —.,... 1120VIt2t : Eli LAM. -now It ....gaF lc� 1VOR14 -ivp w 2 E DI'3. 050. 01Vi2,, i >ci l-C tVR, E'er. 1 f'e5,461L. Pm Z,; Kite t :hG lsuG / FAO OFFICE OFFICE OFFICE OFFICE • ,1 /8 "ffi 1--0" RECEPTION 101 i-reoeiLotore aswis ezep • LIFt,CQFIR:pETAIL • OFFICE CITY OF TUKWILA APPROVED rt ti AS ' BUIL IN DI-- SON"....,.. • i ilia /. ,. '!4IJ'. JY•�fuKL:�' .. 11i'l'i11'i1111111111 0 1d THS INCH '� 11 11 �3 4 tU)TE: �ii111II,lill'I'I'll 2 06 61? 86 Le 9? GZ 47? E' 111111141101111111! 11111! 11111111111 !111111h11111i111111111111111 6 7 8 if ythe microfilmed document is Less clear than this notice, it is due to the quality of the original do'2ui ent. a ZZ tZ OZ 6L Bl Ll 91. Sl lit I r J, ' 71. El el • IA 41, 6 e L 9 s 7 E Z t" 0 1111 1 (i.1ll,141111hl11 101 1111 1.1 i11j �ijiiliii %li�� il91111 C Mick HOWARD NgthoN SBT, INC. . 139 }Maa'3fr 9wI 3 $ *NU. Wsoisingke 90101 I0 ,..A....w......". Mark Nvlaan, AIA CoFCKED API. 1f =ED I S$ U E 0 REVISIONS C L I E N T A P P R O V A L ;) A S fi E F T T 1 1. L E. PARTITION/ ELECTRICAL PLAN P R O d E g 1 1427.103 T I T L E ., t1. CITY C7FT Ut: „ Klytt.,, MAY 1 2 933 . PERMIT CENTER ■ • Pray.tct A.ddr s:...:,.. -, Qa'e.of this Application' 13;tikting Project No Hultding Permit NO - EIeobrgltPormIt No.: Per an new construction and new lighting systems, cOr pleie € its teyth, For remodeling of existing buildings, complete this form Unless one of the' foliowing s;atoments is chocked and Sighed: I certify that no changes are being made to the ligMing:: r 1 certify that c ling Is being done to existing lighting and the existing installed lighting wattage Is being ,�, Maintained a , or (b) a nett, Willi eyster is bofrig i.%%talft4 in ten than. an entire floor or an entire tenant Space, and the existing Installed lighting a>•attapa rdak ,ed , ` � .: ,�. , • . " (pcint, name) LIGHTING LEG,P EXISTING RELOCATED 2 X 4 FLUORESCENT UGHT FIXTURE EXISTING 2 X 4 FLUORESCENT LIGHT FIXTURE TO REMAIN EXISTING 2X2 FLUORESCENT LIGHT FIXTURE REMAIN LIGHT SWITCH CEILING FAN EXISTING 13/S WALL MOUNTED INCANDESCENT LIGHT FIXTURE EXISTING 131S INCANDESCENT DOWN UGHT NEW b Ng_ NOTES PROVIDE FIRE DAMPERS AT ALL SUPPLY AND RETURN AIR. OUTLETS, INLETS, OR DUCTS P.E AND FIRE RATED ASSEMBLIES,'ENCLOSUAES,'WALLS, FLOORS, OR SURFACES, AND AS REQUIRED BY FIRE DEPARTMENT. CONTRACTOR SHALL OBTAIN APPROVAL FROM DESIGNER OF ALL THERMOSTAT LOCATIONS. ALL REWIRED EXIT SIGNS SHALL HAVE LETTERS SIX INCHES HIGH MINIMUM AND SHALL CONFORM WITH APPLICABLE CODES. CEILING HEIGHTS ARE FROM SLAB TO FINISHED C[ ILINO. LIGHT SWITCHES INSTALLED AT 48" HIGH. MULTIPLE SWITCHES SHOW .D'BE GANGED TOG. ETHER UNLESS OTHERWISE SPECFIED. r. • (company hame) ' .. WAREHOUSR ti OFFICE 4 • 2 X 4.MI011E$C0NT LIGHT FIXTURE 2 X 2 FLUoRE CENT ton—. FIXTURE INCANDESCE LIGHT FIXTURE • WORK ROOM . OFFICE. RECEPTION. oF JP. 2 7 i ?J i 2 XX4 FLUORESCENT LIGHT FIXTURE. »X 2 FLUORESCENT LIGHfT FIXTURE i iNCANDES( JT UGHT FIXTURE • PICA: c:ry or TUKI 'ILA APPi0VE1 93 • 8 2ND FLOOPI i Cen* i t o 0 16111S INCH 1 2 111111111 1111:1111141-4 Ill11 Y 11111 I L`I ,�I I i 1il 3 4 OC 6Z ee zz 9z sz I111111111111111111111111111111111111111111111101 111111111 • I 11 NJ I 11 NOTE: If the microfilmed document is less clear than this notice, it is due to the quality of the original document. IIIIIIIIIIIIIIIIIIIIIIIII IIIIIII 10 11 WME IN GERMM11 12 { iz oe 6L E11 41 91 sr 'ii £t zi « p 6 111411, I111 .11.101411i iii I , ml„i II iII ii,Ii i U11111 lei tlt 1,Iiiini G 9 S ri £ z L ww 0 11111111 i► I��,ifiii�ili,i�,llilli 1 h! lln111 iili1 Ii! llllni,i iitI I EMICI' HOWARD NELSON SEIBERT, INC 119 Pine Strut, Suite 303 Seattle, Washington 96101 206-223 -4999 Mark Ne /sort, Al REGISTERED ARCHITECT MARK L, NELSON` STALE OF WASHINGTON DRAWN CHECKED DATE F31!. NO DATE DESCRIPTION L .> )Z•q3 "APPROVED APPROVED • • D R A B! R A ISSUED REVISION: BY ,c L t E R T ' APPROVAL. DATE DATE 3 10 1 E T r T 1 T L P R O J E C T NIENNIMMIaa T I T L E on Lu z CO sk < 14.414* mut/ < ui cri du co < co a. 4ifEEttr RAJ.... RECEIVED ow OFTUKW'IL.A �-' NAY 1 2 1993 PERMIT CENTER hw GENERAL ALL •MATERIALS AND WORKMANSHIP SHALL . CONFORM. TO THE CONTRACT DRAWINGS. 2 . DURING . THE CONSTRUCTION PERIOD THE CONTRACTOR 31IAL1. RE RL'`S1?ONpIBLE FOR THE SAFETY OF THE BUILDING. THE CONTRACTOR SHALL PROVIDE ADEQUATE SIHOR:CNO, BRACIN', APO GUYS IN ACCORDANCE WITH ALL NATIONAL, STATE AND I O C, r. SAFETY ORDINANCES. ANY DEVIATION MUST BE APPROVED PRIOR TO ERECTION. 1 ALL ERECTION PROCEDURES SHALL CONFORM TO OSHA STANDARDS. ANY DEVIATION MUST BE APPROVED BY 0E1E1 PRIOR TO ERECTION. 4. "SHE CONTRACTOR SHALL BE SOLELY RESPONSIBLE FOR ALL CONSTRUCTION PROCEDURES INCLUDING LAGGING, SHORING n °'n PROTECTION OF ADJACENT PROPERTY, STRUCTURES, STRT'l;T:, AND UTILITIES IN ACCORDANCE WITH ALL NATIONAL, STATE AND LOCAL SAFETY ORDINANCES. 5. THE cONTRACTGR SHALL BE RESPONSIBLE FOR COOT DINAT7:''G THE WORK OF ALL TRADES AND SHALL CHECK ALL DIMENSTC' "S ALL DISCREPANCIES SHALL BE CALLED TO THE ATTENTION f71' THE ENGINEER AND BE RESOLVED BEFORE PROCEEDING WTT'1 Tun WORK. 6. SHOP DRAWINGS FOR REINFORCING STEEL SHALL BE SUBMIT 1't E TO THE ENGINEER FOR REVIEW PRIOR TO FABRICATION. 7. DRAWINGS INDICATE GENERAL AND TYPICAL DETAILS OF CONSTRUCTION. WHERE CONDITIONS ARE NOT SPECIFICALLY INDICATED BUT ARE OF .SIMILAR CHARACTER TO DETAILS SHOWN, SIMILAR DETAILS OF CONSTRUCTION SHALL BE USED SUBJECT TO REVIEW BY THE ENGINEER. 8. A:f.L DETAILS DESIGNATED AS STANDARD OR TYPICAL SHALT, OCCUR IN ADDITION TO ANY OTHER SPECIFIC DETAIL CALLED OUT. 9. COORDINATE WITH MECHANICAL, PLUMBING, AND ELECTRICAL DRAWINGS FOR SIZE AND LOCATION OF ALL OPENINGS REOTTrRt'D FOR DUCTS -, PIPES, PIPE SLEEVES, ELECTRICAL CONDUITS, AND OTHER ITEMS TO BE EMBEDDED IN CONCRETE OR OT1!EP1'TrE INCORPORATED IN STRUCTURAL WORK. 10. PROVIDE OPENINGS AND SUPPORTS, AS REQUIRED PER S'f A'1f)11Pf DETAILS FOR HEATERS, MECHANICAL EQUIPMENT, VENTS, DUCTS, PIPING, ETC. ALL SUSPENDED MECHANICAL EQ'TIrnENT SHALL BE SWAY OR LATERALLY BRACED, DESIGN CRITERIA . 1. BUILDING CODE: 1991 UNIFORM BUTLDXNG CODE. 2. VERTICAL LOADS ROOF FLOOR SNOW LOAD 25 PSF LIVE LOAD 100 P- Sr DEAD 'LOAD 15 PSF ACTUAf.I 3. LATERAL LOAD FORCES TRANSMITTEDI B'( DIAPHRAGM ) CTSO'T TO SHEAR WALLS ARD THENCE TO FOUNDATIONS WHERE DISPLACEMENT IS RESISTED BY PASSIVE PRESSURE AND SLIDING FRICTION OF EARTH. 4 . LATERAL WIND LOADS: 80 M.P.H. EXPOSURE "B" 5, LATERAL SEISMIC LOADS (ZONE 3) V E, ZICW /Rw (BAST ZAs0.30 C2.75 Rwt8.0 WNDEAD LOAD s1 ! r:;''.R ) T'oONDAT.i'IjNs . 3 . THE FOUNDATION DESIGN IS BASED ON THE RECOMMENDA.TToO TN THE UNIFORM WILDING CODE TABLE 2913. FOUNDATION R'E'; STALL' TE PERFORMED IN ACCORDANCE WITH CHAPTER 29 f'' THXS CODE. „ 2. THE FOUNDATION DESIGN 1$ BASED ON THE FOLLOWING VA1.C1„fi : ALLOW. SOIL BEARING 2000 PSF SOIL FRICTION O.35 EQUIV. FLUID PRESSURES ACTIVE PRESSURE TEE PCF PASSIVE PRESSURE 200 PCF ( *WALLS RESTRAINED AGAINST ROTATION SHALL BE DESIGNED FOR AN 1QUIV+'. FLUID PRESSURE OF 50 Per.) 3. ALL FOOTINGS SHALL BE FOUNDED AT LEAST 18 "s BELOW t +^"r.ST ADJACENT GRADE OR FINISH FLOOR, WHT,CHEVER IS LOW1P. ALL FOOTINGS SHALL BE FOUNDED ON COMPACTED FILL (M UNDISTURBED NATURAL GRADE UNLESS OTHERWISE NOTED. 4. COMPACTION: MATERIAL FOR PILLING AND NACKFILLING SUAT.L CONSIST OF THE EXCAVATED MATERIAL AND /OR IMPORTED BORROW AND SHALL BE FREE OF ORGANIC MATTER, TRASH, LUMBER OR OTHER DEBRIS. ALL WALLS SHALL BE ADEQUATELY BRACED PRIOR TO BACKFILLXNG. FILL AND BACKFILL SnALT, BE DEPOSITED IN LAYERS NOT TO EXCEED 8 INCHES TITICK, PROPERLY MOISTENED TO APPROXIMATE OPTIMUM REQUIPEtii?P7T AND THOROUGHLY ROLLED OR COMPACTED WITH APPROVED EQUIPMENT IN SUCH A HARPER AND EXTENT AS TO PRODUCE A RELATIVE COMPACTION OF 90% OF MAXIMUM POSSIBLE DENSITY AS 13ETER.41XNED BY ASTM D1557. HAND TRIPPERS SHALL V!'1(741 AT 'LEAST 90 POUNDS EACH AND SHALL HAVE A FACE AREA 14OT IN ,EXCESS OF 64 SQUARE INCHES. HAND TAMPERS MAY }'r,; OPERATED EITHER MANUALLY OR MECHANICALLY AND SHALL RE YSEb WHERE LARGER POWER DRIVEN COMPACTION EQ_UIPMt;E T CANNOT BE USED. y ., r,•••. -+..1 hw„1w.- .. - r. n•• ua ...- �,- ,a.•--- •.•••••..••v.e.. • - w•.r.... p yyyy:XI VOII4G $ E L 1. ALL REINp`O tCXNG STEEL L SHALL CONFORM TO ASTM A615 CRAPE ';5O"" '47LES'b, OTHEtasnA'NoTyp ., .. . 2.. ALL,` R T FORCING STEEL SHALL BE LAPPED AS NOTED OR T}1?E IMAM. WHERP; 'LAP OR SPLICE LOCATIONS ARE NOT SPECIFICALLY INDICATED ON THE CONSTRUCTION DOCUTi' nT , LAPS AND /OR SPLICES SHALL 'BE WELL STAGGERED. 3. COMPLETE REINFORCING PLACEMENT DRAWINGS PREPARED T -N A.Cf ORDANQE WXTH ACT 315 SHALL Dr REVIEWED BY THE ENGINEER AND AVAILABLE ON THE JOB SITE PRIOR W TW3 PLACING OF CONCRETE. 4. WELDED Wf'1 E 'FABRIC SHALL CONFORM B TO ASTM A82 AND Ail '5 AND SHALL DE 12X12 W2.9/W2.9 UNLESS OTHERWISE TTOT7= ;). LAP REINFORCEMENT 12" MINIMUM. 5; • ANCHOR .FIOLTS, DOWELS AND OTHER EMBEDDED ITEMS StiALL BE SECURELY TIER IN PLACE BEFORE CONCRETE IS POURED. ' h+ 4.' CO CT ?r:.TE '1' , 1. ALL CONCRETr. 'Tt}L,s± SS OTHERWISE ?, ^TED WtXGIIT HARD) Eflc'K TYPE ;150 / /on') . ArlGnEGATES SHALL CONFORM TC) A'""11 C'33 WITH 'PRO`.' +'`l ;11I2UNE :AGE CTHIRACTI:IZ:C S'T' 1 CE OF LESS THAN °. n ,%, 2. CONCRETE CC'!t "PEI ETVE STRENGTH $!1ALL BE: SLAB OiI GRADE: CONTINU0HS FOOTINGS: PAD FT_!C)'1'TNGS: 28 DAYS (f 'c) 2000 PSI 2000 PSI 2000 PSI 3. CEMENT SPAT.T., COi'IFORM TO ASTM C'1.50, 'TYPE I, CSA NORMAL, 4, MAXIMUM SETTEE SHALL NOT EXCET'^ 4 INCITES IN FLA'1'WORH., PLACEMENT OF CONCRETE SHALL T. F TN CONFORMANCE WITf\ `CI 5 - 3 01 . 6. CONCRET1?. : �ll7+T,T.1 BE MAINTAINE') Is A MOIST CONDITION FOR • "A MTNI:MUM OF r 7 VT' (5) DAYS AF%'''1Z PLACEMENT. ALTERNATE itETHOOS W1 LE }'E APPROVED IF ST,''TSE CTORY PERFORMANCE CAH BE AJEPET:i./ 7. KEYED CONSTPTJCTION JOINTS SHALL BE USED IN ALL CASES. ALL CONSTRUCT ION JOINTS SHALL, BE THOROUGHLY CLEANED AND ALL LAITANC }E S}U\LL BE REMOVED. ALL VERTICAI, JOINTS SHALL DE 'I'} ;or(OUSHLY WETTED ARO S:LUSHEi) WITH A COAT OF NEAT CEMrr1'1' r.MMEDIATEL.Y BEFORE PLACING NEW CONCRETE. 8. ALL CONCRr'Tf WITH A DESIGNATED COMPRESSIVE STRENGTH EXCEEDING 2500 PSI SHALL. REQUTRE SPECIAL INSPECTION BY AN INSPEC'T'OR APPROVED BY TEE }''UILDING DEPARTMENT AND THE ENG.T.ITEES . 9. SUBMIT LOCATION OF POUR JOINT PRIOR TO PLACEMENT POUR JOINTS Slit! L,r, BE LOCATED TO MINIMIZE EFFECTS OF SHRINKAGE 7 ;(; WELL AS PLACED AT POINTS OF LOW STRESS.• 10. MINIMUM CONCRETE COVERAGE OF PEINFORCING STEEL FOR FORMED WORK SHALL BE AS FOLL01•►S : INTERIOR WALL 3 /4" EXTERIOR T•'ALL S, EXPOSED TO 1.1?.ATIIER . . . . O . . . ..1°1/2" EXTERIOR WT\r,L, NOT EXPOSE() TO WEATHER 3/4" EXPOSED To rAP.TH 011 WEATHT'n 05 OR SMALLER)1 -1/2" EXPOSED TO EARTH OR WEATIT T. (p(!C: OR LARGER) ....'... 2" SUPPORTED SLABS 3/4" *NOTE: CONCPETE CAST AGAINST GEOUND SHALL HAVE 3" MINIMUM COV''T>AGE PIPES OT}1ER THAN ELECTRICAL CONDUITS SHALL NOT- 13E EMBEDDED IN rTRUCTURAL CONCRETE EXCEPT WHERE SPECIFICALLY APPROVED. . • I2. MINIMUM PJEP *4T S SIDLE CEMENT Cnl'TENT FOR CONCRETE O.B.C. TABLE NO. 25--A (WHEN STR :NG'T'1T DATA FROM TRIAL BATCHES OR FIELD EXrrRTENCE ARE NOT T ILAI3L1 ) CEMENT Cr' T E *iT Li3S /CDTETC YARD SACKS PER CUHTC YARD Esc (PSI) (11TNIMT.TT") (MINIMUM)" _- - l;ELT =sumRR'Atmm 2000(no special insnr_c-e ton) SEE TJc'rt^, A 2000 2.500 3000 4000 SEE Po-'E B 470 423 470 517 611 5 4 1/2 5 5 1/2 '81/2 MIXES SRAEL DE PROPORTIONED TO PRODUCE A SLUMP OF 5" OR LESS. NO P'^RE THAN A 1" PLUS TOLERANCE SHALL BE ALLOWED. A) WHERE SPI.c:'TAL INSPECTION IS NOT REQUIRED UNDER SECTION 306(A) OF TEE U. Y3. C. , CONCRETE SHALL HAVE A MINIMUM CEMENT COLT 11T OF 5 SACKS PER CiJBIC YARD OF CONCRETE. B) FOR STRENGTUS ABOVE 4 000 PSI, PROPORTIONS SHALL BE ESTABLISHED BY THE METHODS SPECIFIED IN SUBSECTIONS 2604(D) OR ( }) OF THE U.B.C. C) DESIGN MIX (OTHER THAN AS SPECIFIED IN THIS TABLE) SHALL BE SUBMITTED T7-THE.._ BUrr, 7ENG- OFF:i;CTlk%..,,T)'r9- I,FgI6s ti PR OR,,,.1'O_JE7 T5: P USE . 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