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HomeMy WebLinkAboutPermit M98-0216 - PRIMESOURCEvici O2( W City of Tukwila ( Community Development / Public Works • 6300 Southcenter Boulevard, Suite 100 • Tukwila, Washington 98188 MECHANICAL PERMIT Permit No: M98 -0216 Type: B -MECH Category: NRES Address: 355 TRECK DR Location: Parcel #: 022340 -0042 Contractor License No: MACDOM *248J9 TENANT OWNER CONTRACTOR CONTACT *****************************• k**• k************** * * **** ** ** ** * ** * * * * * * * * * Permit Description: INSTALL'1 EXHAUST FAN FOR STORAGE ROOM,'.1 HEAT PUMP, DUCT, DIFFUSERS, T -STATS FOR MEZZANINE` LEVEL. UMC Edition:. 1997 * * * * *' * * * ** PRIMESOURCE 355 TRECK DR, TUKWILA WA 98188 PRIMESOURCE CORP 15 TWINBRIDGE DR, PENNSAUKEN NJ 08110 MACDONALD MILLER CO 7717 DETROIT SW, SEATTLE, WA 98106 DAN MULVIHILL 355,TRECK DR, TUKWILA WA 98188 ** ** * ** * * *•k ** *** *** * * *' ***•k * ** **iii * *•k **** * * * ** Permit Center Aut ori.zed Signature. Signature ,(et w y_ Date Valuation: Total Permit.. Fee: Print Name: __ Title: 431 -3670 Status: ISSUED Issued: 12/07/1998 Expires: 06/05/1999 Phone: (206)575 -1500 Phone: 206 763 -9400 Phone: 206- 362 -7227 10,068.00 56.94 I hereby certify that I have read and examined this; permit and know the same:: to be true and correct. All provisions of law and ordinances governing this work will be complied with, whether specified herein or not The granting of this permit does not presume to give authority to violate or cancel the provisions of any other state o'' local laws regulating construction or the performance .gf work. .I am authorized to sign for and obtain this building permit Date: This permit shall become null. -and voidthe work is not commenced within 180 days from the date of i'ssuance', .or if the work is suspended or abandoned for a period of 180 days from the last inspection. Project NameO Want: 0 �� Description of work to be done: /0 X N P7 fb7 50 d2 / /,(^k /000710 1),x* 1 r -es' - / ' ' Will there be storage of flammable /combustible hazardous material in the building? Et. yes ❑ no Attach list of materials and storage location on se•arate 8 1/2 X 11 .a.erindicating quantities & Material Safety Data Sheets Value of Construction: 0 Site Address: City State/ Zip: x `755 I fe L —�C_X- ' /G? / v;(wf// , Tax Parcel Numbe p 7z 3 �/d D D Property Owner: a� C_ /'� g _ J�J` Q Phone: 9 / � ? Ph no(0 _3)-2---. 2 , Z^ / Street Address: City State /Zip: Fax #: Contact Person: vp./v M v VIA ; // 0 Sewer 0 Metro Phone: zoo 3roz - Z."7 Street Address: ` �� 2 � / City State /Zip: Fax #: Contractor: P A I / � 7 * c [ U L / /�/ 4 / / `� Phone: � 6 ,� �� � Street Address: ,�► Le' /� sew .. ' City St -te /Zi : —C��id Fax # - ZG �6; 9 � Architect: Phone: Street Address: I City State /Zip: Fax #: Engineer: Phone: Street Address: City State /Zip: Fax #: MISCELLANEOUS PERMIT REVIEW AND. APPROVAL REQUESTED :. (TO BE FILLED OUT BY APPLICANT) Description of work to be done: /0 X N P7 fb7 50 d2 / /,(^k /000710 1),x* 1 r -es' - / ' ' Will there be storage of flammable /combustible hazardous material in the building? Et. yes ❑ no Attach list of materials and storage location on se•arate 8 1/2 X 11 .a.erindicating quantities & Material Safety Data Sheets ■ Above Ground Tanks ■ Antennas /Satellite Dishes ■ Bulkhead /Docks ❑ Commercial Reroof ❑ Demolition El Fence ❑ Mechanical El Manufactured Housing - Replacement only ❑ Parking Lots El Retaining Walls ❑ Temporary Pedestrian Protection /Exit Systems ❑ Temporary Facilities ❑ Tree Cutting MONTHLY SERVICE BILLINGS .TO: .. Name: Phone: Address: City /State /Zip: 0 Water 0 Sewer 0 Metro 0 Standby Miscellaneous Permit Application APPLICANT REQUEST FOR MISCELLANEOUS PUBLIC WORKS PERMITS El Curb cut/Access /Sidewalk El Fire Loop /Hydrant (main to vault) #: Size(s): ❑ Land Altering: 0 Cut cubic yards 0 Fill cubic yards 0 sq. ft.grading /clearing El Sanitary Side Sewer #: ❑ Sewer Main Extension 0 Private 0 Public El Street Use ❑ Water Main Extension 0 Private Size(s): Size(s): Size(s): Est. quantity: ❑ Miscellaneous ❑ Moving Oversized Load/Hauling ❑ Channelization /Striping El Flood Control Zone ❑ Landscape Irrigation El Storm Drainage El Water Meter /Exempt it ❑ Water Meter /Permanent # ❑ Water Meter Temp # 0 Deduct gal O Public O Water Only Schedule: WATER METER DEPOSIT /REFUND BILLING: Name: Address: Value of Construction - In all cases, a value of construction amount should be entered by the applicant. This figure will be reviewed and is subject to possible revision by the Permit Center to comply with current foe schedules. Expiration of Plan Review - Applications for which no permit is issued within 180 days following the date of application shall expire by limitation. The building official may extend the time for action by the applicant for a period not exceeding 180 days upon written request by the applicant as defined in Section 107.4 of the Uniform Building Code (current edition). No application shall be extended more than once. Date application accepted: CITY OF^TUKWILA Permit Center 6300 Southcenter Boulevard, Suite 100 Tukwila, WA 98188 (206) 431 -3670 Application and plans must be complete in order to be accepted for plan review. Applications will not be accepted through the mail or facsimile. MISCPM'T.DOC 7/11/96 Date application expires: 5...- --9r Phone: City /State /Zip: Applicat/o/ftken by: (initials) . . BUILDING OWNER OR AUTHORIZED 'AGEN SUBMIT APPLICATION AND REQUIRED CHECKLISTS FOR Above Ground Tanks/Water.Tanks - Supported directly upon grade exceeding 5,000 gallons and a ratio of height to diameter or width which exceeds 2:1 Signature: L f d�l % e � Y J Date: //_ a -- Print name: ���J Bulkhead/Dock 4 I C� in Phone: o!o z £s -3w7 Fax #:768.-70, -- r0 -IlG( Address: 7170, in ireBr'T �Gi// Q71:/A„, zygk,Eity /State /Zip: ALL MISCELLANEOUS PEP' APPLICATIONS MUST BE SUBMI D WITH THE FOLLOWING: ➢ ALL DRAWINGS SHALL BE AT A LEGIBLE SCALE AND NEATLY DRAWN ➢ BUILDING SlrE PLANS AND UTILITY PLANS ARE TO BE COMBINED ➢ ARCHITECTURAL DRAWINGS REQUIRE STAMP BY WASHINGTON LICENSED ARCHITECT ➢ STRUCTURAL CALCULATIONS AND DRAWINGS REQUIRE STAMP BY WASHINGTON LICENSED STRUCTURAL ENGINEER ➢ CIVIL/SITE PLAN DRAWINGS REQUIRE STAMP BY WASHINGTON LICENSED CIVIL ENGINEER (P.E.) ▪ Copy of Washington State Department of Labor and Industries Valid Contractor's License. If not available at the time of application, a copy of this license will be required before the permit is issued, unless the homeowner will be the builder OR submit Form H -4, "Affidavit in Lieu of Contractor Registration ". Building Owner /Authorized Agent If the applicant is other. than the owner, registered architect/ engineer;; or; contractor:licensed• by the State of Washington, a notarized letter from the property ownei authorizing the agent to submit this permit application and" obtain the permit will be required as part of this submittal. I HEREBY CERTIFY THAT 1 HAVE READ AND EXAMINED THIS APPLICATION AND KNOW THE SAME TO BE TRUE UNDER PENALTY OF PERJURY BY THE LAWS OF THE STATE OF WASHINGTON, AND I AM AUTHORIZED TO APPLY FOR THIS PERMIT. MISCPMT.DOC 7/11/96 SUBMIT APPLICATION AND REQUIRED CHECKLISTS FOR Above Ground Tanks/Water.Tanks - Supported directly upon grade exceeding 5,000 gallons and a ratio of height to diameter or width which exceeds 2:1 PERMIT REVIEW Submit checklist. No:. M -9 Antennas /Satellite Dishes Submit checklist No M-1. J Awnings /Canopies - No signage Cbmmercial'Tenant Improvement Permit : < . Bulkhead/Dock Submit checklist . No M-10 in Commercial Reroof Submit checklist .: No:.M-6..' El Demolition. Submit checklist Not : M 3, M -3a in Fences - Over 6 feet in Height Submit checklist No: M -9 in Land Aitering/Grading /Preloads Submit checklist No: M •2 in Loading Docks Commercial Tenant:Improvement Permit. Subrriiit'checklist No: H -17 0 Mechanical (Residential & Commercial) Submit' checklist` No, M-8,., Residential 'only - .H -6, H -16 , 71 Miscellaneous Public Works Permits Submit checklist H -9 i n Manufactured Housing (RED INSIGNIA ONLY) : Submit checklist No M=5 0 Moving Oversized Load /Hauling Submit checklist •� No M -5' 0 Parking Lots Submit checklist No: M -4 0 Residential Reroof - Exempt with following exception: If roof structure to be repaired or replaced . Residential Building Permit Submit checklist °.. No: M -6. in Retaining Walls - Over 4 feet in height Submit checklist : ' o: M -1: Ei Temporary Facilities Submit checklist'' No: M-7 ` in Temporary Pedestrian'Protection/Exit 'Systems Submit ' checklist : No:.M-4 in Tree Cutting Submit checklist No M =2' ALL MISCELLANEOUS PEP' APPLICATIONS MUST BE SUBMI D WITH THE FOLLOWING: ➢ ALL DRAWINGS SHALL BE AT A LEGIBLE SCALE AND NEATLY DRAWN ➢ BUILDING SlrE PLANS AND UTILITY PLANS ARE TO BE COMBINED ➢ ARCHITECTURAL DRAWINGS REQUIRE STAMP BY WASHINGTON LICENSED ARCHITECT ➢ STRUCTURAL CALCULATIONS AND DRAWINGS REQUIRE STAMP BY WASHINGTON LICENSED STRUCTURAL ENGINEER ➢ CIVIL/SITE PLAN DRAWINGS REQUIRE STAMP BY WASHINGTON LICENSED CIVIL ENGINEER (P.E.) ▪ Copy of Washington State Department of Labor and Industries Valid Contractor's License. If not available at the time of application, a copy of this license will be required before the permit is issued, unless the homeowner will be the builder OR submit Form H -4, "Affidavit in Lieu of Contractor Registration ". Building Owner /Authorized Agent If the applicant is other. than the owner, registered architect/ engineer;; or; contractor:licensed• by the State of Washington, a notarized letter from the property ownei authorizing the agent to submit this permit application and" obtain the permit will be required as part of this submittal. I HEREBY CERTIFY THAT 1 HAVE READ AND EXAMINED THIS APPLICATION AND KNOW THE SAME TO BE TRUE UNDER PENALTY OF PERJURY BY THE LAWS OF THE STATE OF WASHINGTON, AND I AM AUTHORIZED TO APPLY FOR THIS PERMIT. MISCPMT.DOC 7/11/96 .11 Address: 355 TRECK'DR Permit No: M98-02I6 Suite: Tenant: PRIMESOURCE Status: ISSUED Type: B-MECH Applied: 11103/1998 Parcel #: 022340-0042 Issued: 12/07/1998 *k****k** Permit Conditions: 3. No changes will be made to the plans unless approved by the Architect or Engineer and the Tukwila Building Division. 2. All permits, inspection recordsand,:approved plans shall be available at the lob site prior - tO the start of any con- struction. These,,;:documents are tope maintained and avail- able until final inspection ,a0proVi1 is granted. All construction' to 6e done in conformance approved plans and regUirements of the Uniform BuildingCode,j1997 Edition) aS:amended, Uniform llechanical Cud (]997 Edition), and Washington State Energy Code (1997 Edition):,, 4. Validity ,Of Permit. The issuanoe of a permit or approvaof plans,'specificattons, an,doomputations shall'notbe con-; struedto be a permit for',' or an approval of, any violation of anY:of' the provisions of the ,building code or of any other. or of the:jurisdiction, No per mie pres'uming to give , authority :to violate or cancel the provisions' of tigls code-Shall'be valid , 5. MANUFACTURERS INSTALLATION , INSTRUQTIONS REQUIRED ON -SITE FOR THE BUILDING INSPECTORSREVIEW; ' 6, Electri'oalpermits shalt be:obtaine&-throUgh the Washington State Divtsion of Labor, and,:InduStries'andall elec:triCal, - work:,w111- be insptte6 by that .(248-6630). ' 7. Readily accessible' acc.6a.,s 'to 1 . f reciptred. B. VENTILATIuN FOR ALLINIEWROOMS_AND.:-SPACES oF-!0NEW.'", A OR OcISTING BUILDINGS IN CONFORMANCE WITH THE/UNIFORtC, BUILDING CODE AND THE WASHINGTON: ANr- INDOORAIR QUALITY CODE, CHAPTEW 51-18 WAC. CITY OF TURWIL • ei. ACTIVITY NUMBER: M98 -0216 DATE: 11 -3 -98 PROJECT NAME: PRIMESOURCE XX Original Plan Submittal Response to Incomplete. Letter Response to Correction Letter # Revision # After Permit Is Issued DEPARTMENTS: B 'il li"ng Division 55 Pu lic WorksL, ) Complete C Comments: TUES /THURS ROUTING: Please Route Approved \PR•ROUTE.DOC 6/98 PLTN REVIEV'V /ROUf SLIP OT F're rrevention r /- �- � S ructura )t6._ C Planning Dion Permit Coordinator DETERMINATION OF COMPLETENESS: (Tues, Thurs) DUE DATE: 11 - - 98 Incomplete ❑ Not Applicable El Routed by Staff El (if routed by staff, make copy to master file and enter into Sierra) No further Review Required 0 REVIEWERS INITIALS: DATE: APPROVALS OR CORRECTIONS: (ten days) DUE DATE: 12 - - 98 Approved El Approved with Conditions Ell Not Approved (attach comments) El REVIEWERS INITIALS: DATE. CORRECTION DETERMINATION: DUE DATE: Approved with Conditions LI Not Approved (attach comments) LJ REVIEWERS INITIALS: DATE. Proi pe spection: Addr s: „- _ w /i �:..G,..C/C.__ to called: Special instructions: Date wanted: a.m. p.m. Requester �f Pho e: INSPECTION NO. CITY OF TUKWILA BUILDING DIVISION 6300 Southcenter Blvd, #100, Tukwila, WA 98188 COMMENTS: Approved per applicable codes. INSPECTION RECCK Retain a copy with p( ,ft • PERMIT NOC,,Y (206)431 -3670 Corrections required prior to approval. C $47.00 REINSPECTION FEE REQUIRED. Prior to inspection, fee must be paid , at 6300 Southcenter Blvd., Suite 100. Call to schedule reinspection. Receipt No: Date: COMMENTS: ' Type of Ins )72:7 r Ai'.,-, e Address: ey h,�,f,i -- Date called: r/0/9.-- /(1....",e,.....1 c r J'u Date wanted: Cr' T' ri - / ( ., c £ , 4/0( / 5 l' _..-- ii'p C.r ,, 64/. / 6&1, plc / t / r ` 6i.! 1r. ) ir - 2/ e 4'' •✓' % �rh r' (-Ne 4 e..,.< re.,‘.., - ,h A--(G/ -- -, le-'74 e .� Project: r . Type of Ins )72:7 1l Address: Date called: Speaa instructions `y' �/!� � �A �� r .' U , ' -' Date wanted: 7'.` (/� C� a.m. p.m. Requester: Phone: INSPECTION NO. El Approved per applicable codes. Inspector: '-"r' . ^.wtT '•-v-.-rr+. .. - \' t � INSPECTION RECOr Retain a copy with pe ,,,it CITY OF TUKWILA BUILDING DIVISION 6300 Southcenter Blvd, #100, Tukwila WA 98188 Date: /(7f ?9 / PERMIT NO. (206)431 -3670 Corrections required prior to approval. $47.00 REINSPECTION R EQUIRED. Prior to inspection, fee must be paid at 6300 Southcenter Blvd., Suite 100. Call to schedule reinspection. Receipt No: Date: COMMENTS: TYpg-of lnspecton:,'1/fec / �i f le ( d� / /' Addr s. { Date ca Sp inst ctions: Va , Date wante / , . m Requen/ e F is as, //'... 3 ' ,- -..� ...�.,„ . Alin z", 11 reel k4 , 1- 13/ -- '16/g Project/ J me ., o urc e • TYpg-of lnspecton:,'1/fec / �i f le ( d� / /' Addr s. { Date ca Sp inst ctions: Va , Date wante / , . m Requen/ e F is t Phone r_ rwehs/ : 7 CITY OF TUKWILA BUILDING DIVISION 6300 Southcenter Blvd, #100, Tukwila, WA 98188 INSPECTION NO. Inspector: Approved per applicable codes. INSPECTION REC Retain a copy with Date: • M q ? - t 7 i • PERMIT NO. (206)431-3670 Corrections required prior to approval. 0 $47.00 ' ` SPECTION F ' REQUI ' ED. Prior to inspection, fee must be paid at 6300 Southcenter Blvd., Suite 100. Call to schedule reinspection. C Receipt No: Date: p -ct: i l!" L./ ! Type a tion: /t al i Date called: prior to approval. A: • r s Lk, Special instructions: r----)y Date want�ci; G Reque er: ~ K Approved per applicable codes. . . Corrections required prior to approval. COMMENTS: i u`i c 4 (J?. 4e4) 'A- ioA c.. ,o€ D- zE`7o ,. INSPECTION NO. CITY OF TUKWILA.BUILDING DIVISION 6300 Southcenter Blvd., #100; Tukwila, WA 98188 g••s74'riti - ,'.fi 77,~,+Y'<. :.; d' ice..• "hSF h.;""" - . '} ` :+ `'td ?"l+' .5''iSj t' I Receipt No.: INSPECTION REC Retain a copy with it MAX 02/ (P PERMIT NO. P (206) 431 -3670 42.0 REINSPECTION FEE REQUIRED. Prior to I spection, fee must be paid at 6300 Southcenter Blvd., Suite 100. Call to schedule reinspection. Date: Projec 0 Type of ins. -, tjaA Address: ;s «„ Date called: / k Special instructions: l � A-V&A (/14 -' � u� A 2...J-id .F /au. /td e- 2itt4n, Le. Date wanted: / a ya . p.m. Requester: '�{7 1 Ob l U-1Lua 4y Phone No.: Fs Kf,.;rwv zo. Inspecto INSPECTION RECD Retain a copy with INSPECTION NO. CITY OF TUKWILA BUILDING DIVISION 6300 Southcenter Blvd., #100, Tukwila, WA 98188 Date: q PERMIT NO. (206) 431 -3670 Approved per applicable codes. I Corrections required prior to approval. t A .141 & El $42.00 REINSPECTION FEE* REQUIRED. Prior to inspection, fee must be paid at 6300 Southcenter Blvd., Suite 100. Call to schedule reinspection. Receipt No.: Date: Project Name Address Sprinklers: Fire Alarm: Hood & Duct: Halon: Monitor: Pre-Fire: Permits: City of Tukwila Fire Department ,....2 Retain current inspection schedule f • Needs shift inspection Approved without correction notice Approved with correction notice issued _, 5 wra Authorized Signature. FINALAPP.FRM Rev. 2/19/98 TUKWILA FIRE DEPARTMENT FINAL APPROVAL FORM V -C C-ok CO C L • John W. Rants, Mayor Thomas P. Keefe, Fire Chief Permit No. spc3--032(0 rni)e) 02.1(0 Suite # Date T.F.D. Form F.P. 85 Headquarters Station: 444 Andover Park East • Tukwila, Washington 98188 6 Phone: goo) 575.4404 • Fat poN 575409 ••• ..... .. ( Vin, . St • ! r! ; lYr."'i•. SP 7, 711, i'y "717 7 e't ,,,,„, * *4140 * * * * * / *4k * * * *AA S* ti** 4a** A•*: AAA* k * * * **' * *4 ** * *:4 } * *A *;f: * * * ** CITY OF 'rUt;NILA. Nit TRAta8MI1 ' * *4 * * *A ** * * * * * * *f * * * *4 * ** * *A ** AAA * *4r *r4A k *k * *!r * * * * *A*3*0 * *# * . . is,TRANSMIT Number: R9700878 Amount: 56.94 12'07/78 14:32 Payment Method: CHECK Notation: iarte MACD ONALD MILLER Intl 01:H .. Permit NO: M9E -Q216 Type: EHMECH MECRANtC.'L PERMIT • Parcel No 02234070042 ;Fite Address: 355 T.RE,CK OR Total fees; 'This Payment 5E, r, 94 Total ALL Pmts: 56,4 li. Gt 'I a r1 e »00 its * * ** *•k *. * * *** *** ** * * *•* ** A** * *ii.4*.A * * * * **9:*A ***A *A *AAA * * **,fir** Acc:our t Codr? 000/345, 831) 000/322.1.00' Description • PLAN CHECK. -. NONRES MECHt1NICA1. • N O14W1'S`• • Amour) 45„55 TO; ATTN REF 206- 763 -1950 A 114 TEC CO. FAX 1206) 763 -1950 5701 - 1ST. AVENUE SOUTH MACDONALD MILLER CO SCOTT GROFF YOUR PO#208- 907343 Erik Aploks a:t .ice i•'"''�"y"��y' r''y% -ti' rl ri� r tid ' d`:'�!- w.+..�. G AIR TEC CO. (200 783 -9911 • SEATTLE, WASHINGTON 98108 FAX COVER FAX # j 768 -3903 979 P01 OCT 30 '98 16:23 DATE 7 PAGES 10/30/98 7 Scott, Per Jay, the attached is a submittal for the explosion resistant exhaust fan on the above - mentioned order. It should be ready in about a week. Regards, Erik Aploks CITY OF TUKyva. A Nov ° 3 1998 PERMIT CENTER FAN NO. OTY_ MODEL NO. CEM V^ r SP RPM SONES HP RPM VOLTAGE FN H2 ENCLOSURE ACCESSORIES AND REMARKS 26 29 318 1430¢i5J �f V . //32 `. ,.6 24 1/2 1?' 11 UBCA 16,18 lay EP10 gaiko t) Risc91+07'0 21 5/8 24 1/2 22 23 114 28 112 25 1/4 361/2 UBCA 20 34 43 318 29 7/8 25 112 281/2 26 11 ,ktokAwic,r 32 112 29 i/4 40112 UBC 245 34 43318 34 114 25 1x2 28112 26 27114 321/2 29 114 A) Sze UBC 300 40 51 114 38 f/2 29 112 34 112 32 33 114 381/2 35 114 461/2 UBC 365 46 I. Me) 45 7/8 37112 40 1/2 38 391/4 44 1/2 41 1/4 52 1/2 A -- + _ —f—i- -- Unit Ventilator Dimons ons Roof Curb and Damper Dimensions A B C 0 E F G H J K UBCA 12 - 15 26 29 318 24 1/2 19 114 201/2 18 19114 24 1/2 21 114 3212 UBCA 16,18 30 35 3/8 26 1/2 21 5/8 24 1/2 22 23 114 28 112 25 1/4 361/2 UBCA 20 34 43 318 29 7/8 25 112 281/2 26 27 114 32 112 29 i/4 40112 UBC 245 34 43318 34 114 25 1x2 28112 26 27114 321/2 29 114 40112 UBC 300 40 51 114 38 f/2 29 112 34 112 32 33 114 381/2 35 114 461/2 UBC 365 46 62 5/8 45 7/8 37112 40 1/2 38 391/4 44 1/2 41 1/4 52 1/2 .. : AMERICAN COOLAIR CORPORATION P.O. Box 2300 Jacksonville, Florida 32203 ;- Phone (904) 389 -3646 1: Fax (901) 367 -3449 Standard Fan Features Optional Features • Non -overloading aluminum wheel computer • UL Label for Standard 705 balanced. or Standard 762. . Force ventilated motor compartment - CSA Label. isolated from airstream. • Disconnect switch (loose or . Variable pitch motor pulley. factory mounted and wired). • Single bolt belt tension adjustment. • Backdraft damper (UL 705). • Weatherproof spun aluminum housing. • Roof curb (damper shelf • NEMA Standard frame size motors. optional). • Overlapping wheeUinlet venturi. • Epoxy coating. • Built-in grease and water removal drain. • Birdguard (UL 705). • Heavy duty self- aligning pillow -block • Grease collector (UL 762). bearings with cast iron housing. • Hinged base kit. . AMCA label for air and sound. • Roof handle. Type UBCAIUBC Belt Drive Centrifugal Upblast Power Roof Ventilators DIIDUSTBIES DIVISION PROJECT XS '963 LOCATION amca DERTMED RRTIOGI A rr ovrmrnt Ms COMM Ar'oernTIo0 ItTtRItfnonnt. !MAD AIR MOTOR DATA SUBMITTED BY APPROVED BY C h ack here for UL 705. Q Check here for UL 762. 2 04r3Maron+ to lathes f aa. No Tr6.30.2 [G.gF3 Footed •rtlSA 0 195Y by Amitwwn Cco4• Cnrpuuon m m DATE r DATE m IU 14 TYPE: UBCA AMERICAN COOLAIR CORPORATION Commercial /Industrial Division ILG Industries Division REPRESENTATIVE AIR TEC CO. Phone: 206 -763 -9911 FAX: 206- 763 -1950 Version: 2.04 Fri Oct 30 14:28:21 1998 1.50 1.35- 1.20- 1.05 - 0.90- 0.75 0.60 - 0.45 - 0.30 - O.1S- 0.011 SELECTION ILG INDUSTRIES DIVISION : UPPLAST CENTRIFUGAL POWER ROOF VENTILATORS Model : UBCA Flow 2000 CFM . Sones 9.6 Size . : 15 : SP . 0.250 IN W6 LwA : 71.8 dB Drive : BELT Speed : 1132 RPM dBA @ 5 : 60.3 d13 Blades : 12 Power : 0.32 BHP dBA @ 10: 54.3 cit3 Setting : 43.0 Density: 0.075 LB!FT "3 dBA @ 20: 48.3 dB Temp 70 F Elev 0 FT ALL SPECIFICATIONS.SUBJECT TO CHANGE WITHOUT NOTICE [Copuright 1997 -98 American Coolair Corporation Fan Performance Curves -i ; SYSTE 0 600 1200 1800 2400 Volume flow Rate (CFM) 0.50 0.45 -0.40 -0.35 -0.30 -0.25 0.20 -0.15 -0.10 -0.05 0.00 3000 Suu rd Power (Lw) 63 Hz 7.1.4 dB 125 Hz 74.3 dB 250 Hz 73.1 dH 500 Hz 70.7 dB 1000 Hz 64.4 dB 2000 Hz 62.9 dB 4000 Hz 55.7 dB 8000 Hz 45.0 d8 a m u a U3 c6 Unit Ventilator Dimensions Roof Curb and Damper DlmensIone A B C D S — F G H J K IL UBCA 12, 13, 15 26 29 318 22 318 20 3/8 20 1/2 18 19 114 24112 21 1/4 32 1/2 UBCA 16, 18 30 35 3/8 24 1/2 21 241/2 22 23 1/4 281/2 25 1/4 36 112 UBCA 20 34 43 3/8 27 7/6 24 28 1/2 26 27 114 321/2 29 1/4 40 1/2 UBC 245 34 43 3/8 32 1/4 24 28 1/2 26 27 1/4 32 1/2 28 1/4 40 1/2 UBC 300 40 51 1/4 36 1/2 29 112 341/2 32 33 1/4 38112 35 1/4 46 1/2 UBC 365 46 62 518 43 718 37 1/2 40 1/2 38 38 1/4 441/2 41 1/4 52 1/2 0 206- 763 -1950 A(W TEC CO. UBCA, UBC and Roof Curb Dimensions 8 STD. 1 HEIGHT 1 5/8 1 5/8 K SQ. E SQ. F SQ. G SQ. 0 J I.D. i ! 979 PO4 OCT 30 '98 16:24 1 -1/2 THICK INSULATION 13 2 206 - 763 -1950 All.) TEC CO. 979 P06 OCT 30 '98 16:25 UBCA and UBC Belt Drive Centrifugal Upblast Power Roof Ventilators Applications The UBCA and UBC units are quiet, dependable upblast power roof ventilators for the exhaust of grease -laden air from restaurant range hoods, and general ventilation applications where vertical discharge of exhaust air is required. Applications include virtually all types of commercial and institutional kitchens, such as restaurant and cafeteria, fast food, hospital, hotel and motel, bakery, delicatessen, school and military. UBCA and UBC units are specified where a roof - mounted location is desired to eliminate interference with other equipment or activities in the building. They permit the direct upward venting of overheated air. The ILG Industries USC was the first power roof ventilator to meet the rigorous requirements of Underwriters Laboratories Standard 762 and Is so listed as being suitable for the extraction of grease -laden air and fumes from range exhaust hoods and commercial kitchen exhaust systems. The UBCA and UBC are listed under UL classification YZHW for Power Roof Ventilators for Restaurant Exhaust Systems. When properly Installed, the UBCA and UBC also meet the requirements of National Fire Protection Association Standard NFPA 96. These units are particularly recommended for economical and efficient range hood ventilation where continuous operation under severe conditions may cause other power roof ventilators to fail. Construction Construction of UBCA and UBC units features heavy gauge steel structural support throughout consisting of steel base, motor compartment disc and support pipes, to maintain support and proper alignment of motor, wheel and drive during shipment, installation and operation. The seated spun aluminum motor compartment cover provides protection from weather and contaminated air and is easily removable for complete access to motor and drive. UBCA and UBC models feature a housing of durable spun aluminum for optimum weather protection. The overlapping deep -spun venturi minimizes air turbulence and increases efficiency. The aluminum centrifugal wheel is a non - overloading, backward - inclined type, selected for low noise levels. Backelate fins draw cool air through the motor compartment. The wheels are computer balanced on state -of -the -art equipment. The UBCA wheel is secured to a machined aluminum hub with a line bore, which eliminates the need for bushings. Drive Mechanism The belt driven UBCA and UBC utilize a standard V -belt drive design with a variable pitch cast iron motor pulley for adjusting fan speed. Drive shaft is turned, ground and polished. Motor support features a single bolt adjustment for proper belt tensioning. Motors The standard motor for UBCA and USC models is open drip -proof construction, located out of the airstream. Totally enclosed, energy efficient, two -speed and explosion -proof motors may also be available. All motor brands are recognized and serviced nationwide. Motor enclosure may affect Ut. listing. Bearings Heavy duty pillow -block bearings with cast iron housing are self- aligning and relubricabie. CSA Listing UBCA and UBC models are listed by Canadian Standards Association as certified, CSA File Number LR3391B. (Listing does not apply to models furnished with explosion -proof motors,) AIR MOVEilIEAT AAD COATROI nsvooiATIOA imreni ATIOnat. IRO. amcca come) RATIAGS sounD flip ���r American Coolair Corporation, ILG industries Division certifies that the Type UBCA and UBC PRV's shown herein are licensed to bear the AMCA Seal. The ratings shown are based on tests and procedures performed in accordance with AMCA Publication 211 and AMCA Publication 311 and comply with the requirements of the AMCA Certified Ratings Program. Guide Specifications Upbiast power roof ventilators shall be of the UBCA or UBC centrifugal type as manufactured by ILG Industries Division of American Coolair Corporation (individual models to be listed in fan schedule), Units shall meet UL Standard 705 or 762 as required and shall bear the AMCA Certified Ratings Seal for air and sound performance. Bottom outer housing and venturi inlet shall be one piece heavy gauge spun aluminum, with built In grease drain. Wheel and venturi shall overlap for efficient operation. Motor compartment cover shall be heavy gauge spun aluminum construction and easily removable for access to motor and drive, Base, motor compartment disc and support pipes shall be heavy gauge steel. Drive mechanism shall incorporate a V -belt drive with cast iron motor pulley. Drive shaft shall be turned, ground and polished. The centrifugal wheel shall be heavy gauge aluminum with backward - inclined, non - overloading blades and be computer balanced. Bearings shall be self - aligning and have fittings for relubrication. Motor shall be open drip -proof construction, NEMA design B with minimum service factor of 1.16. Motor compartment shall be cooled by a forced air ventilation system. Adjustable motor pulley shall be provided to allow for field adjustment and system balance. Motor shall be mounted on a adjustable steel mounting bracket. Motor shall be mounted with the shaft up to allow easy access to the cast iron variable pitch drive pulley. (Mounted and wired disconnect switch, epoxy coating, roof curb and other accessories shall be listed in the fan schedule.) CFM at Static Pressure RPM Range 0.00 .125 .250 .375 .500 .750 1.00 1.25 1.80 2.00 Motor HP BHP Sons 2188 0.27 10.1 2280 0.31 10.8 2370 2370 0,35 2462 0.39 12.5 2552 0.44 13.4 2844 0.48 14.3 2736 0,54 15.4 2828 0.69 16.3 2917 0.66 17.4 3009 0.72 18.4 3099 0.76 19.5 3191 0.55 21 3281 0.93 22 SHP Sow 2101 0.29 9.4 21974 0.33 M�, 0.37 10,9 2356 0.41 11.1 0.46 12.7 2574 , 0.60 KM 2668 0.56 2761 0.61 16.6 2864 0.67 2948 . 0.74 i�G 3040. 0.80 18,7 3134 0.88 19.$ 3225. 0.95 21: BHP Sons 9.5 2077 0.35 0.39 11.0 2288 0.43 11.8 0.48 12.8 IIEILMIEEIIHIEEall 0.63 13.5 2689 0.58 14.3 2886 0.63 16.3 imam 09 2551 I CI 2976 0.83 18,3 3072 0.90 O 3188 0.98 20 BHP Sone ,,x,( 9.3 , 939 10.1�0.38� 2411 0.40 10.9 2148 0.450E 0.80 12.7 0.55 13.8 2476 0.60 14.5 2583 0.86 15,4 2890 0,72 al 2795 0.75 17. 2906 .86 0 18.3 2998 043 Eau 3098 1.00 20 BHP iir:fro ( 6.6 1635 � 1940 0.42 10.3 2046 0,45 11,3 0.5 12.3 >m3033 2366 0.132 14.4 2460 0.68 15.6 itzramommoug 0,74 mg 2579 0.51 17.6 2768 0,58 18.4 Min 0.95 cc 3004 1,03 El BHP =02 0.33 8.2 1633 166■ 2 0.42 � 1804 0.48 10.5 0.63 11.2 2062 0.69 gl 2170 0.65 13.2 2286 0.71 14.3 0.78 15.6 2495 0.55 18.9 2600 0.92 18.1 2704 1.00 gug 2806 1 .08 E1 Sone ® 0.47 10,0 043 11.1 1787 azi 1923 0.65 13.3 2055 0.72 0.79 2323 0.87 Q J 0.94 18.8 2556 1,03 18.1 2662 1.11 19.4 = Sone �-� Alp a i s mr 1811 0.59 an 1864 0.65 12,4 1802 0.72 13,7 1840 0.79 15.0 2077 0.87 � 0.95 17.0 Ram mi 17.7 2481 1.13 18.6 CU Sone i e�` 1 /1 � ' 1514 a n 14.0 1693 0.79 14.2 0,87 1� 1981 2119 mania 2262 1.12 19,1 BHP +n +n w 1 r 1.-t CrIr: I '.,y, 114q 1186 1212 ,� y vii _ 1259 1305 . . 1352 1399 I _- •- 1445 �� _ a' , L'",',1, ?14 1492 o � � �. ` r t' ' � � ci t • ,... � , • 1686 ��� t' 1632 1790 : L� III , ,:,Y,. 1678 206 - 763 -1950 PIP TEC CO. UBCA15 Performance Data Performance shown Is fpr Typo k free inlet, tree outlet. Porfon once rating* do not Include the effects of appurtenances In the ahotreem. Power ratings (BHP) do. not Include drive )owes. Bearing looses are inaidded. The sound retinas sham ere loudness values In fan sonea at 5 IL (1.5 in) in a hemispherical free field calculated per MICA Standard 501; Values shown are for Installation Type,A; free Intel tan sone levels. 6 _._ .. . :. 17 11E 184 T TO coANOWINIPT PPATIQ 979 P07 OCT 30 '98 16:25 ZONE SUMMARY CALCULATIONS Job Name: PRIMESOURCE MEZZININE Job No.: PRIMEMEZ Evaluated at 48 Degrees North Latitude 74 Deg. F. Cooling Space Temp. 55 Deg. F. Cooling Discharge Temp. 19 Deg. F. Cooling Temp. Diff. Zone Name LARGE ROOM OFFICE 1 EAST OFFICE 2 WEST HALL Total: Btuh Btuh Btuh/ I Total Sens. SHR Sq.Ft. CFM I Btuh 6678 5857 0.88 20 4&4-9° 5641 2551 2267 0.89 20 110 407 2350 2551 2267 0,89 20 110 2350 5235 4830 0.92 16 ,,2341 S.2 5257 17016 15220 10 -29 -1998 70 Deg. F. Heating Space Temp. 110 Deg. F. Heating Discharge Temp. 40 Deg. F. Heating Temp. Diff. COOLING LOAD SUMMARY HEATING LOAD SUMMARY Watts/ KW Sq.Ft. CFM 1.65 4,92 108 0.69 5.30 45 0.69 5.30 45 1.54 4.70 101 738 I 15597 4,57 299 RECEIVED CITY OF TUKWILA NOV - + . PERMIT CENTER 1ASHRAE CLTD /CLR COOLING LOAD CALCULATIONS! PEAK MONTH - JULY OUTSIDE TEMP 85 LATITUDE 48 PEAK HOUR - 1600 INSIDE TEMP 74 WALL SOLAR AND TRANS GAIN TYPE DIR LF HT U 1 N 44.00 X 12.00 X 0.05 X 1 E 21.00 X 12.00 X 0.05 X 2 N 36.00 X 12.00 X 0.05 X 2 S 8.00 X 12.00 X 0.05 X ROOF SOLAR AND TRANS GAIN AREA U TD 924.00 X 0.03 X 62 X 100 % TD 28 34 28 45 INTERNAL GAINS AREA 924 SQ FT PEOPLE 6 X 245 BTUH /PERSON INFIL, 69 CFM X 1,085 X 11 LIGHTS 1109 WATTS X 3.413 X 100 % EQUIP 477 WATTS X 3.413 MISC BTUH TOTAL ROOM SENSIBLE BTUH VENT. 120 CFM X 1.085 X 11 PLENUM LIGHT HEAT PLENUM ROOF HEAT FAN MOTOR HEAT GAIN ( 0.25 HP): LATENT PEOPLE: 6 X 205 STUB /PERSON INFILT. 69 CFM X .68 X 12 VENT. 120 CFM X .68 X 12 GRAND TOTAL BTUH SQ FT /TON: 535.35 0.87 SHR +t * * * ** LOAD CALCULATION FOR ** * ** ** PRIMESOURCE MEZZININE PREPARED BY MACDONALD MILLER COMPANY 10 -29 -1998 SEATTLE WASHINGTON CALCULATIONS FOR UNIT: A . H . U . - 1 • 739.20 • 428.40 • 604.80 • 216.00 • 1718.64 • 1470.00 • 827.10 • 3785.02 1628.00 4300.00 15717.15 1432.20 0.00 0.00 787.50 • 1230.00 • 565.49 • 979.20 20711.54 1.73 TONS HEATING LOAD CALCULATIONSI OUTSIDE TEMP 22 INSIDE TEMP 70 WALL TRANSMISSION LOSS TYPE DIR LF HT U TD 1 N 44.00 X 12.00 X 0.05 X 48 1 E 21.00 X 12.00 X 0.05 X 48 2 N 36.00 X 12.00 X 0.05 X 48 2 S 8.00 X 12.00 X 0.05 X 48 ROOF TRANSMISSION LOSS AREA U TD 924.00 X 0.03 X 48 INFIL. LOSS 69 CFM X 1.085 X 48 VENT. LOSS 120 CFM X 1.085 X 48 SLAB LOSS 0.00 LF X 25 BTUH SPACE HEAT LOSS TOTAL HEAT LOSS WATTS /SQ FT 5.28 • 1267.20 • 604.80 • 1036.80 • 230.40 1330.56. • 3609.14 • 6249.60 • 0.00 14328.50 PICK -UP LOAD = 2310.00 16638,50 4.88 KW DESIGN C R I T E R I A Wa11 aria Glass Sclzedulas - -- Wall - -- --- Glass - -- SCHED. U - -val. Height U -val. S.C. Height 1 0.050 12.000 0.000 0.000 0.000 2 0.050 12.000 0.000 0.000 0.000 Job Name: PRIMESOURCE MEZZININE Job No.: PRIMEMEZ File: PRIMEMEZ 10 -29 -1998 Design conditions at 48 degrees North latitude Grains /Lb diff: 12 SUMMER (Degrees Fahrenheit) Outside Inside Temp. Lvg Air Temp. Temp. Diff. Temp. ZONE: 85 74 11 55 BLOCK: 85 74 11 55 Iriterior Sc11.eaules OCCUPANCY 1 2 SF /Person: 130.00 300.00 Sens /Person: 245.00 245.00 Lat /Person: 205.00 205.00 ELECTRICAL WATTS /SF Lights: 1.20 1.20 Equipment: 0.80 0.00 OUTDOOR AIR Infilt. AC /Hr 0.50 0.50 Vent CFM /Pers: 20.00 20.00 PERCENT TO SPACE Lights: 100.00 100.00 Roof: 100.00 100.00 WINTER (Degrees Fahrenheit) Outside Inside Temp. Lvg Air Temp. Temp. Diff. Temp. 22 70 48 110 22 70 48 110 3 4 5 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0. 00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0. 0.00 0.00 0.00 0.00 0.00 Et JE aria Exp Er 1. cD C3 x ScYicaa i1 fa EXPOSED FLOOR 1 2 3 4 5 U- value: 0.00 0.00 0.00 0.00 0.00 OPAQUE ROOF U- vlaue: 0.03 0.00 0.00 SKYLIGHT U- value: 0.00 0.00 0.00 Shading Coeff: 0.00 0.00 0.00 0.00 0.00 0.00 0. 0.00 0.00 --- Overhang - -- Abv Glass Horiz Dist. 0.00 0.00 0.00 40.00 Familian MACDONALD MILLER SERVICE INC 7707 DETROIT AVE SW SEATTLE, WA 98106 -3998 Bid ID: 5263008 PRIME SOURCE Engineer: JAY Job Name: PRIME SOURSE Submitted BY: DAN KRISCHANO Bid Valid Through: 10/30/99 * *REF 5263008 FAMILIAN NORTHWEST TUKWIL PAGE: 18323 ANDOVER PARK WEST TUKWILA, WA 98188 Telephone: 206 -575 -8971 MACDONALD MILLER SERVICE INC Bid ID: 5263008 PRIME SOURCE FAMILIAN NORTHWEST TUKWIL PAGE: 2 Unit Extended Ouantity Description Price Price. 1 YORK B- HA030A06 2.5T HEAT PMP 208/1 .967.53 EA 967.53 1 YORK 2NH04500706 7KW HP /AC 208/1 61.85 EA 61.85 1 YORK 1FF0114 FILTER FRAME KIT 20.09 EA 20.09 1 YORK 1FA0406 MANUAL ODA DAMPER 38.23 EA 38.23 - End of Bid - 2 Total Pages Bid Total: 1,087.70 • • • DESCRIPTION These packaged heat pumps are designed for outdoor instal- lation. Only utility and duct connections are required at the point of installation. Field- installed electric heater accessories are available to provide electric heat, if required. STANDARD FEATURES / BENEFITS OPERATING EFFICIENCY - All units provide high operating efficiencies of 10 SEER or greater, 3.0 COP or greater and up to 7.0 HSPF. All efficiencies exceed legislated minimum levels. ON SITE FLEXIBILITY - All model sizes share a common, compact design cabinet with a single footprint. The installer has the flexibility of setting one curb or pad and placing the proper tonnage unit on that curb after the internal load has been determined. Field convertible duct connections from side shot to down shot allows the installer to have greater flexibility and needs to carry less inventory. LOWER INSTALLATION COST - Installation time and costs are reduced by easy power and control wiring connections. The small base dimension means less space is required on the ground or roof, plus, the installer can fit this unit between the wheel wells of full size pick -up truck. All models are well under 500 pounds. All units are completely wired, charged with R -22 and tested prior to shipment. Unique test stations using a new state of the art computerized process system are used to insure product quality. Refrigerant charge, and component part numbers are verified via computers at manufacturing point. Vital run test statistics such LIYORIC Champion ® Series SINGLE PACKAGE HEAT PUMPS B1 HA018 THRU 060 1 -1/2 THRU 5 NOMINAL TONS 10 SEER FOR DISTRIBUTION USE ONLY - NOT TO BE USED AT POINT OF RETAIL SALE 511.18 -TG1Y (598) as system pressure, motor currents, air velocity and tempera- ture and unit vibration are monitored and recorded by the system to insure unit performance. Equal size, side supply and return duct connections allows easy hook -up of ducts to match low crawl spaces without transition pieces. UTILITY CONNECTIONS MADE EASY - Electrical utility knockouts are provided through the bottom as well as the side of the unit. Utility connections can be made quickly and with a minimum amount of field labor. A field supplied and field installed electrical disconnect switch must be installed. CONVERTIBLE AIRFLOW DESIGN - The bottom duct open- ings are covered when they leave the factory ready to be used for a side supply / side return application. If a bottom supply / bottom return application is desired, you simply remove the two panels from the bottom of the unit and place them in the side supply / side return duct openings. No panel cutting is required and no accessory panel is necessary. Convertible airflow design allows maximum field flexibility and minimum inventory. CONDENSATE PAN - A non - corrosive, long- lasting, water -tight pan is positioned below the evaporator coil to collect and drain all condensate. Less collection of stagnate condensate will build -up. The condensate pan conforms to ASHRAE 62 -89 standards (Ventilation for Acceptable Indoor Air Quality). CONDENSATE DRAIN -The heavy duty, 3/4 inch NPTI copper connection is more tolerable during installation and is more durable over time, The connection is rigidly mounted to assure proper fit and leak tight seal. 511.18 -TG1Y STANDARD FEATURES and BENEFITS - continued DURABLE FINISH - With a heavy duty cabinet made of powder - painted, galvanized steel the neutral color blends into surrounding areas. The powered paint, provides a better paint to steel bond, which resists corrosion and rust creep. The special primer formulas and glossy earth tone finish insure Tess fading when exposed to sunlight and offers a more attractive on site appearance. This paint finish exceeds ASTM -B117 standards for 750 hours salt spray rating, the highest in the industry. FULL PERIMETER BASE RAILS - The easily removable base rails provide a solid foundation for the entire unit and protects the unit during shipment. The rails provide fork lift access from all sides, and rigging holes are also provided so that an overhead crane can be used to place the units on a roof. On applications when the unit is placed on a pad, the base will keep the unit off the pad to deter corrosion. On applications where height is limited, the 2 inch high base rails may be removed on location. MORE ATTRACTIVE APPEARANCE - A single piece "Water Shed' top cover containing a top discharge condenser fan arrangement requires less square footage on installation and provides a wider variety of installations. The one piece design adds greater water integrity. Rounded corners with water drip edges add to the attractive appearance. The cabinet panels have a non - fibrous insulation that reduces insulation fibers into conditioned area. TOP DISCHARGE - The top discharge condenser fan does not disrupt neighboring areas and does not dry-out vegetation surrounding the unit. The warm air from the top mounted fan is blown up away from the structure and any landscaping. This allows compact location on multi -unit applications. OUTDOOR COIL GRILLE - A multi -piece totally enclosed, rigidly mounted outdoor coil grille provides protection from objects and personal after installation and provides protection during transit and installation. LOW OPERATING SOUND LEVEL - The upward air flow carries the normal operating noise up and away from the living area. The rigid top panel effectively isolates any motor sound. Isolator mounted compressor and the rippled fins of the condenser coil muffle the normal fan motor and compressor operating sounds. The unique formed base pan also aids in sound alterations with it's 'Super-Structure' design. This de- sign strategically places embossments in the pan for optimum strength and rigidity. FAN SYSTEM - All models operate over a wide range of design conditions with a 3 -speed direct -drive fan motor. These units easily match all types of applications and provides greater on site flexibility to match comfort requirement. SIMPLE CONTROL CIRCUIT - A low voltage printed circuit board contains a low voltage terminal strip. The electrical control box is not located in the compressor compartment. All wiring intemal to the unit is color /number coded. CONTROLS - Reliable time - temperature defrost control pro- vides defrost including field selectable time periods between cycles (30, 60 and 90 minutes). factory set at 30 minutes. Defrost control also provides an 'X' terminal to provide a 24 volt signal for room thermostat "LED' indication of unit lockout, plus built in 5 minute anti -short cycle protection. PROTECTED COMPRESSOR -The compressor is intemally protected against high pressure and temperature. This is accomplished by the simultaneous operation of high pressure relief valve and a temperature sensor which protect the com- pressor if undesirable operating conditions occur. EXCLUSIVE COIL DESIGN - Grooved copper tubes and enhanced aluminum fin construction improves heat transfer for maximum efficiency and durability. LOW MAINTENANCE - Long life, permanently lubricated condenser and evaporator fan motor bearings need no annual maintenance adding greater reliability to the unit. Blower assembly can be easily removed for cleaning by the unique 'Slip Track' slide -out blower assembly. SECURED SERVICE ACCESS PORTS - Protected, externally mounted, re- usable service access ports are provided on both the high and low lines for ease of evacuating and charging the system. EASY SERVICE ACCESS - A large, single hinged panel covers the electrical controls and makes servicing easy. The blower compartment has an additional large panel with a built -in handle tab. Removing this panel will allow the blower assembly to slide -out for easy removal for maintenance and ease of trouble shooting. REPLACEMENT PARTS - The Installer has no need to carry an inventory of unique parts or needs special training to replace any of the components parts for these units. All are easily obtained from Source 1 or other major part houses. Description 1 Features and Benefits 1 & 2 Field - installed Accessories 3 Ratings 4 Physical Data 4 Cooling Capacities - BHA018 5 Cooling Capacities - BHA024 6 Cooling Capacities - BHA030 7 Cooling Capacities - BHA036 8 Cooling Capacities - BHA042 9 Cooling Capacities - BHA048 10 Cooling Capacities - BHA060 11 Heating Capacities - BHA018 & 024 12 Heating Capacities - BHA030 & 036 13 Heating Capacities - BHA042 & 048 14 Heating Capacities - BHA060 15 Application Data 15 FIELD- INSTALLED ACCESSORIES . ECONOMIZER DOWN DISCHARGE / SUPPLY KIT - Modu- lating integrated economizer provides simultaneous opera- tion between the mechanical cooling and economizer operation. Independent blade design insures proper control and less than 1% leak rate. Includes hood and mesh bird screen filter integrated into the hood, dry bulb sensor and relief damper. Separate field accessories of single enthalpy and dual enthalpy are also available. SINGLE ENTHALPY SENSOR - Sensor replaces dry bulb sensor standard in economizer kit. Provides improved econo- mizer operation by sensing the dry bulb temperature from outdoors plus the enthalpy content of the outdoor air. DUAL ENTHALPY SENSOR - Additional sensor to single enthalpy sensor. Sensor senses both the return air tempera- ture dry bulb and humidity in conjunction with the single enthalpy to determine the most economical mix. Single En- thalpy sensor also required. UPGRADE PRESSURE PACKAGE - Contains screw in type High pressure, Low Pressure/Loss of Charge switch, freeze protection switch and lockout relay. Switches are placed onto existing scharder ports located in the unit by furnished adapt- ers. When abnormal conditions are sensed through the pres- sure switches, the unit will lock out preventing any further operation until reset or problem is corrected. Package agency approved. HAIL GUARD KiT - Kit contains protected grilles made of expanded aluminum grilles with full perimeter 11/2 inch frame. Sloped hoods are also included to assure maximum protec- tion. • FiLTER / FRAME KIT (Single Phase only) - Kit contains the necessary hardware to field Install return air filters Into the base unit. Pre -cut filter racks and appropriate cleanable standard size filters are shipped in one kit. (1" filter is supplied) This kit is available for single phase horizontal or vertical duct application only. Standard in all 3 Phase models. Unitary Products Group TABLE OF CONTENTS 511.18 - TG1Y MOTORIZED FRESH AIR DAMPER - Designed for duct mounted side supply /return and unit mounted down supply /re- turn applications. Damper capable of providing 0% thru 50% of outdoor air (field supplied). Closes on power loss, includes hood and screen assembly. RECTANGLE TO ROUND ADAPTERS - Kit includes one sup- ply and one return air rectangle to round duct adapter. Adapters are preformed and designed to fit over current duct openings on the base unit. Transition is from15' square to 14° round. ROOF CURBS - NRCA approved curbs provide proper fit to base unit for rooftop installations. Curbs are designed to be assembled through hinge pins in each corner. Kit also pro- vides seal strip to assure a water tight seal. 8 and 14 inch high roof curbs are available. MANUAL OUTDOOR DAMPER - Provides 0% thru 50% outdoor air capability (field adjustable). Designed for duct mounted side supply /return applications. Includes hood and screen assembly. WALL THERMOSTAT - The units are designed to operate with 24 -volt electronic and electro-mechanical thermostats. All units can operate with single stage heat / single stage cool thermostats - with or without the economizer. LOW AMBIENT KIT - Kit provides necessary hardware to convert unit to operate in cooling cycle down to 0° F. Standard unit operation 45° F. TRANSFORMER KIT (Single Phase only) - Kit provides necessary hardware to provide single phase models from factory furnished 40 VA transformer capability to 75 VA trans- former capability. ELECTRIC HEATERS - Each heater package provides easy installation of electric heat strips. Slide in design with plug in harness and agency approved. Heaters are available from 5.0 KW sizes and are designed for single point connection. Additional Static Pressure Resistance 15 Side and Bottom Supply Air Blower Performance 16 Field Wiring Diagram 17 Electrical Data (basic unit) 17 Electrical Data (cooling / electric heat) 18 Unit Dimensions 19 Center of Gravity 20 Clearances 20 Typical Applications 21 Roof Curb Dimensions 22 Roof Curb Application 22 Typical Wiring Diagram (208/230 -1 -60) 23 Typical Wiring Diagram (208/230-3-60) 24 Typical Wiring Diagram (460-3-60 & 575 -3 -60) 25 Typical Wiring Diagram Notes 26 Typical Wiring Diagram Legend 26 Mechanical Specification 27 & 28 3 ..., -, -- . MODEL BHA COOLING CAPACITY 80 / 67 -95 °F HSPF SOUND RATING (dbels) NET HEATING CAPACITY AVAILABLE ELECTRIC HEAT NOMINAL CAPACITY KW @ 47 °F 0 17 °F MBH SEER MBH COP MBH 9.3 COP 2.0 ANGLE PHASE 5.0, 7.5 THEE PHASE N/A 018 18.5 10.2 = 6.6 77 18.5 3.0 024 23.8 11.0 7.0 75 23.8 3.0 12.1 2.0 5.0. 7.5. 10.0 N / A a" 030 29.8 .10,2 7.0 79 29.0 3.0 14.7 2.0 5.0, 7.5, 10.0, 15.0 N / A 036 36.0 10,6 7.0 83 36,0 3.0 19.2 2.0 5.0 7.5, 10.0, 15.0 10.0, 15.0 042 41.0 10.2 7.0 83 41.5 3.0 20.8 2.0 5.0, 7.5, 10.0, 15.0 10.0, 15.0 048 48.0 10.0 7.0 79 47.0 3.0 22.0 2.0 10.0 15.0 20.0 25.0 10.0 15.0 20.0 25.0 060 57.5 10.0 7.0 79 5 8,5 3.0 35.0 2.0 10.0. 15.0.20.0.25.0 1QA.15.0.20.0 MODELS BHA .I : 0 4 a s a as t.'.: 10.0 INDOOR CENTRIFUGAL BLOWER (Dia. x Wd. In.) 9X 6 10X 8 10 X B 10 x 8 11 X 10 11 X10 11 X 10 BLOWER FAN MOTOR HP (Three Speed) 1 /2 t/2 1/2 3 3 3 1 ROWS DEEP 2 2 l 3 3 3 3 3 INDOOR COIL FINS PER INCH 15 13 13 15 15 16 16 FACE AREA (Sq. Ft.) 4.38 4.38 4.38 4.38 4.38 5.62 5.62 PROPELLER DIA. ((n.) 22 22 22 22 22 22 22 OUTDOOR FAN FAN MOTOR HP 1 /4 1 /4 1 /4 1 /4 1 /4 1 /4 1 /4 NOM. CFM TOTAL 1,800 1.800 1,800 2,400 2,400 2,800 2,800 ROWS DEEP 1 1 1 1 1 1 1 OUTDOOR COIL FINS PER INCH 20 20 20 20 20 16 20 FACE AREA (Sq. Ft.) 8.3 11.7 11.7 11.7 11.7 16.4 16.4 CHARGE REFRIGERANT 22 (Ibsioz.) 4/12 5 / 12 7 /8 _ 6/5 5 / 5 9/0 10 / 0 FILTER FACE AREA (Sq. Ft. / Qty. / Size) 4.28 /2 / 14 x22 COMPRESSOR HERMETIC Type, (Qty. = 1) _ 1 1e.procetahg Reaproceting Scroll I Scroll 1 Scroll Scroll I Scroll 511.18•TG1Y 4 RATINGS BACK AND BOTTOM RETURN AIR AND SUPPLY AIR DUCT OPENING HIGH VOLTAGE TERMINAL BLOCK LOW VOLTAGE TERMINAL BLOCK LONG LASTING POWDER PAINT FINISH EARTH TONE COLOR HIGH EFFICIENCY COMPRESSOR RIGIDLY MOUNTED PHYSICAL DATA HIGHLY EFFICIENT ENHANCED COPPER TUBE/ALUMINUM FIN INDOOR COIL 3 -SPEED DIRECT DRIVE BLOWER MOTOR WITH SLIDE -OUT BLOWER ASSEMBLY HEAVY GAUGE REMOVABLE BASE RAILS DIRECT DRIVE CONDENSER FAN MOTOR HIGHLY EFFICIENT ENHANCED COPPER TUBE/ALUMINUM FIN OUTDOOR COIL DECORATIVE PROTECTIVE COIL GUARD SEER - Seasonal Energy Efficiency Ratio • the total coding output In BTU's during a normal annual usage period for cooling chided by the to electric power Input In wet. hours during the same period. COP = Coefficient of Performance - the total heating capadry provided by the refrigeration system, Inducing circulating tan heat but excluding supplementary resistance (BTU's per tour) dulled by the total electric Input (watts) x 3,412. IISPF - Healing Seasonal Pertomhance Factor • the total heating output during a normal annual usage period for heating dvided by the total electric power Input during the same period. (Based on Region IV minimum design healing requirement), Unitary Products Group • Temperature of Air on Outdoor Coil .7267162 Air On Indoor Coil 1 CFM 875 CFM WB °F 1,000 CFM WB °F 1,125 CFM WB °F 1,250 CFM WB °F ... WB °F 32.5 29.3 26.4 57 , 26.0 72 ` 33.4 30.2 62 27.1 57 26.7 ` 72_ 34.4 67 31.1 62 27.9 57 27.5 _ 72 35.7 67 32.3 62 29.0 57.72 28.6 37.1 67 33.5 62 30.1 57 29.7 85 °F Net Cap MBH Total Power Input KW 2.94 2.85 2.76 2.74 3.02 2.93 2.84 2.81 3.11 3.02 2.92 2.89 3.15 3.06 2.96 2.93 3.20 3.10 3.01 2.98 Sensible Capacity] MBHW i aci Dry i�b °F 86 19 .523.926:426.021.4262 ! 7 23. 428 .427.927.525.731.029.028.628.1 33.5 30.1 29.7 83 17. 421. 825. 728. 018, 923. 626. 826. 720. 425. 527. 927. 522 .428.029,028.624.430.430.129.7 80 15.2 19.6 23.5 23.9 16.4 21.1 25.3 25.7 17.5 22.6 27.1 27.5 19.1 24.6 28.6 28.8 20.7 26.7 30.1 29.7 77 13.1 17.5 21.4 21.7 13.9 18.6 22.8 23.2 14.6 19.7 24.2 24.6 15.8 21.3 25,3 25.3 16.9 22.9 26.4 26.0 74 10.9 15.4 19.2 19.6 11.3 16.1 20.2 20.6 11.7 16.8 21.2 21.7 12.5 18.0 22.0 22.0 13.2 19.2 22.7 22.2 71 - 13.2 17.1 17.5 - 13.5 17.7 18.1 - 13.9 18.3 18.8 - 14.7 18.6 18.6 - 15.5 19.0 18.5 1 • 1 - 11 . 1 . - 1. • 1 4 1 • • - 11 1 1 - 11 1 14.8 95 °F Net Cap MBH 30.9 27.3 24.3 24.5 31.7 27.9 24.9 25.1 32.4 28.6 25.5 25.7 33.0 29.2 26.0 26,2 33.7 29.7 26.5 26.7 Total Power Input KW 3.14 3.02 2.92 2.94 3.22 3.09 3.00 3.01 329 3.17 3.07 3.09 3.36 3.23 3.13 3.15 3.43 3.30 3.19 3.21 Sensible Capacity MBH m ring Dry ulb °F 86 18.4 23.0 24:3 24.5 20.3 25.3 24.9 25.1 222 27.5 25.5 25.7 24.2 28.6 26.0 26.2 26.2 29.7 26.5 26.7 83 16.3 20.9 24.2 24.3 17.8 22.7. 24.9 25.0 19.3 24.6 25.5 25.7 20.9 26.6 26.0 26.2 22.5 28.5 26.5 26.7 80 14.2 18.7 22.0 22.2 15.3 20.2 23.8 23.9 16.4 21.7 25.5 25.7 17.6 23.3 26.0 26.2 18.8 24.8 26.5 26.7 77 12.0 16.6 19.9 20.1 12.8 17.7 21.3 21.4 13.5 18.8 22.6 22.8 14.3 19.9 22.7 22.9 15.1 21.1 22.8 22.9 74 9.9 14.5 17.8 17.9 10.2 15.2 18.7 18.9 10.6 15.9 19.7 19.9 11.0 16.6 19.4 19.5 11.3 17.4 19.0 19.2 71 - 12.3 15.6 15.8 - 12.6 16.2 16.4 - 12.9 16.8 17.0 - 13.3 16.1 16.2 - 13.6 15,3 15.5 - . 13 1 • - 10 1 1 7 1 . - • I 1 • 14 • - 1110 1 7 12 9 - 9,9 11,6 11.8 105 °F Net Cap MBH 28.5 24.8 22.5 22.6 29.1 25.3 23.0 23.0 29.7 25.9 23.5 23.5 30.3 26.4 23,9 24.0, 30.8 26.9 24,4 24.4 Total Power input KW 3.31 3.17 3,08 3.10 3.40 325 3,16 3.17 3.48 3.33 3.23 3.25 3.54 3.39 3.29 3.31 3.60 3.44 3.35 3,36 Sensible Capacity MBH Bring Dry ulb°E 86 17.6 21.9 22.5 22.8 19.5 23.6 23.0 23:0 21.5 25.3 23.5 23.5 23.5 26.1 23.9 24.0 25.5 26:9 24.4 24.4 83 15. 519. 822. 222. 317. 021 .722.822.918.523.523 - 523.520.1 24.9 23.9 24.0 21.7 26.3 24.4 24.4 80 13.4 17.6 20.1 20.1 14.5 19.1 21.8 21.8 15.6 20.6 23:5 23.5 16.8 22.2 23.9 24.0 18.0 23.8 24A 24.4 77 11.2 15.5 17.9 18.0 12.0 16.6 19.2 19.3 12.7 17.7 20.6 20.6 13.5 18.9 20.6 20.6 14.3 20.0 20.6 20.7 74 9.1 13.4 15.8 15.8 9.4 14.1 16.7 16.8 9.8 14.8 17.6 17.7 10.2 15.6 17.3 17.3 10.6 16.3 16.9 17.0 71 - 11.2 13.7 13.7 • 11.6 14.2 14.2 - 11.9 14.7 14.8 - 12,2 14.0 14.0 - 12.6 13.2 13.2 68 - • 1 11 11.. •.0 11 7 11.7 - • • 11 : 11 • - - • 1. • 1..7 - • 9 5 115 °F Net Cap MBH 26.1 22.4 20.7 20.6 26.5 22.7 21.1 21.0 27.0 23.1 21.4 21.3 27.5 23.6 21.8 21.8 28.0 24.0 22.2 22.2 Total Power Input KW 3.49 3.32 3.24 3.25 157 3.40 3.32 3.33 3.66 3.48 3.40 3.41 3.71 3.54 3.45 3.46 3.77 3.59 3.50 3.51 Sensible Capacity MBHOO raring Dry ulb °F_ 86 16.8 20.8 20.7 20.6 18.7 22.0 211 21:0 20.7 23.1 21.4 21.3 22.7 23.6 21.8 21.8 24.7 24.0 22.2 22.2 83 14.7 18.7 20.2 20.2 16.2 20.6 20.8 20.8 17.8 22.5 21.4 21.3 19.4 23.2 21.8 21.8 20.9 24.0 22.2 22.2 80 12.5 16.5 18.1 18.0 13.7 18.1 19.8 19.7 14.8 19.6 21.4 21.3 16.0 21.1 21.8 21.8 17.2 22,7 22.2 222 77 10.4 14.4 16.0 15.9 11.2 15.5 17.2 17.2 11.9 16.7 18.5 18.4 12.7 17.8 18.5 18.4 13.5 19.0 18.5 18.4 74 8.3 12.3 13.8 13.8 8.6 13.0 14.7 14.6 9.0 13.7 15.6 15.5 9.4 14.5 15.2 15.1 9.8 15.3 14.8 14.7 71 - 10.1 11.7 11.6 - 10.5 12.2 12.1 - 10.8 12.7 12.6 - 11,2 11.9 11.8 - 11.5 11.1 11.0 68 - , 8.0 9,6 9.5 I 7.9 9,6 9,6 . - 7.9 9,7 9.7 - 7.9 8,5 8,5 7.8 7,3 7,3 125 °F Net Cap MBH 23.7 19.9 18.9 18.7 24.0 20.1 19.1 18.9 242 20.4 19.4 192 24.7 20.8 19.7 19.5 25.2 21,2 20.1 19.9 Total Power Input KW 3,7 3.5 3.4 3.4 3.8 3.6 3.5 3.5 3.8 3,6 3.6 3.6 3.9 3.7 3.6 3.6 3.9 31 3.7 3.7 Sensible Capacity MBH wring Dry ulb °F 86 160 19.7 18.9 18.7 17.9 20.3 19.1 18.9 19.9 20.9 19.4 19.2 21.9 21.1 19.7 19.5 23.9 21.2 20.1 19.9 83 13. 917. 618. 318. 115. 419. 518. 818. 617. 021. 4 19, 419. 2 18 .621.6 19.719.5 20.221.7 20.119.9 80 11.7 15.5 16.1 16.0 12,9 17.0 17.7 17.6 14.0 18.5 19.4 192 15.2 20.1 19.7 19.5 16.4 21.7 20.1 19.9 77 9.6 13.3 14.0 13.8 10.4 14.5 15.2 15.0 11.1 15.6 16.4 16.2 11.9 16.8 16.4 16.2 12.7 17.9 16.4 16.2 74 7.5 11.2 11.9 11.7 7.8 11.9 12.7 12.5 8.2 12.7 13.5 13.3 8.6 13.4 13,1 12.9 9.0 14.2 12.6 12.4 71 9.0 9.7 9.6 - 9.4 10.2 10.0 - 9.8 10.6 10.4 - 10.1 9.8 9.6 - 10.5 8.9 8.7 68 - 6.9 7.6 , 7.4 ;, • 6.9 7.6 7.5 - 6.8 7.7 7.5 - 6.8 6.4 6.2 . - 6.8 5.2 0 • • • COOLING CAPACITIES - 2 - 1/2 TON (BHA030 m - Those capaobes are net capacities • Indoor tan heat deducted. Unitary Products Group ALL SENSIBLE CAPACITY 511.18 -TG 1 Y 7 CFM RETURN AIR °F CAP & KW OUTDOOR AIR TEMPERATURE °F {72% RH -10 0 10 _ 20 30 40 50 I 60 750 55 MBH KW 8.239 1.515 10.151 1.673 12.469 1.832 15.280 1.990 18.687 2.148 22.817 2.306 27.824 2.465 33.893 2.623 70 MBH KW 7.038 1.690 8.950 1.848 11.268 2.007 14.079 2.165 17.486 2.323 21.616 2.481 26.623 2.640 32.692 2.798 80 MBH KW 5.302 1.802 7.214 1.960 9.532 2.119 12.343 2.277 15.750 2.435 19.880 2.593 24.887 2.752 30.956 2.910 1,000 55 MBH KW 10.209 1.530 12.121 1.688 14.439 1.847 17.250 2.005 20.657 2.163 24,787 2.321 29.794 2.480 35.863 2.638 70 MBH KW 9.008 1.705 10.920 1.863 13.238 2.022 16.049 2.180 19.456 2.338 23.586 2.496 28.593 2.655 34.662 2.813 80 MBH KW 7.272 1.817 9.184 1.975 11.502 2.134 14.313 2.292 17.720 2.450 21.850 2.608 26.857 2.767 32.926 2.925 35.635 1,250 55 MBH KW 11.402 1.552 13.314 1.710 15.632 1.869 18.443 2.027 21.850 2.185 25.980 2.343 30.987 2.502 37.056 2.660 70 MBH KW 10.201 1.727 12.113 1.885 14.431 2.044 17.242 2.202 20.649 2.360 24.779 2.518 29.786 2.677 35.855 2.835 80 MBH KW 8.465 _.839 10.377 1.997 12.695 2.156 15.506 2,314 18.913 2,472 23.043 2.630 28.050 2,789 34.119 2.947 HEATING - 3 TON (BHA036) / CFM RETURN AIR' °F ., QA P & KW-- OUTDOOR AIR TEMPERATUR • F (72% RH) -10 0 10 20 /10 40 50 60 55 MBH 9:14 ' 11.465 14.209 17.452 '' 21.284 25.814 31.167 37.494 KW 2.186 `• . 2.314 2.442 2.570' 2.698 2.826 2.955 3.083 900 70 MBH 8.834 11155 13.899 47.142 20.974 25.504 30.857 37.184 KW 2.451 2.579' . 2.707 •' 2.835 2.963 3.091 3.220 3.348 80 MBH 7.285 9,606 '4235 15.593 19.425 23.955 29.308 35.635 KW 2.596 2.724 . 2.852 2.980 3.108 3.236 3.365 3.493 55 MBH 13.075 15.396 18.14 ••• •,• 21.383 25.215 29.745 35.098 41.425 KW 2.156 2.284 2.412 2,540 2.668 2.796 2.925 3.053 1,200 70 MBH 12.765 15.086 17.83 21.079 24.905 29.435 34.788 41.115 KW 2.421 2.549 2.677 2.805 � 2.933 3.061 3.190 3.318 80 MBH 11.216 13.537 16.281 19.524 23:356 27.886 33.239 39.566 KW ,2.566 2.694 2.822 2.950 3.078`. 3.206 3.335 3.463 55 MBH , 15.343 17.664 20.408 23.651 27.483 • '`32.013 37.366 43.693 KW 2.156 2.284 2.412 2.540 2.668 2.796 2.925 3.053 1,500 70 -MBH 15.033 17.354 20.098 23.341 27.173 31,703` 37.056 43.383 KW 2.421 2.549 ' 2.677 2.805 2.933 3.061 N 3.190 3.318 .•' 'MBH 13.484 15.805 18.549 21.792 25.624 30.154 35.507, 41.834 -19ti - 2.566 2194 9. 822 9 950 3 078 1.208 3.335 3,463 • HEATING CAPACITIES - 2 -1/2 TON (BHA030) ° These eepodtles en nN awled • M bulbar motor Mat has been add. These power Inputs are total power Inputs • the Indoor motor watts have been added. Unitary Products Group 511.18 -TG1Y 13 CFM RETURN AIR °F CAP & KW OUTDOOR AIR TEMPERATURE, °F (72% RH) -10 0 10 20 30 40 50 60 1,500 55 MBH KW 19.316 3.57 23.261 3.829 27.902 4.088 33.364 4.347 39.79 4.606 47.351 4.865 56.247 5.124 66.714 5.383 70 MBH KW 18.491 4.061 22.436 4.32 27.077 4.579 32.539 4.838 38.965 5.097 46.526 5.356 55.422 5.615 65.889 5.874 80 MBH KW 15.362 4.358 19.307 4.617 23.948 4.876 29.41 5.135 35.836 5.394 43.397 5.653 52.293 5.912 62.76 6.171 2,000 55 MBH KW 23.164 3.624 27.109 3.883 31.75 4.142 37.212 4.401 43.638 4.66 51.199 4.919 60.095 5.178 70.562 5.437 70 MBH KW 22.339 4.115 26.284 4.374 30.925 4.633 36.387 4.892 42.813 5.151 50.374 5.41 59.27 5.669 69.737 5.928 80 MBH KW 19.21 4.412 23.155 4.671 27.796 4.93 33.258 5.189 39.684 5.448 47.245 5.707 56.141 5.966 66.608 6.225 2,500 55 MBH KW 24.796 3.754 28.741 4.013 33.382 4.272 38.844 4.531 45.27 4.79 52.831 5.049 61.727 5.308 72.194 5.567 70 MBH KW 23.971 4.245 27.916 4.504 32.557 4.763 38.019 5.022 44.445 5.281 52.006 5.54 60.902 5.799 71.369 6.058 80 MBH KW 20.842 4,542_ .24.787 4.601 29.428 5,06 34.89 5,319 41.316 • 5.578 48.877 5,837 57.773 6.096 68.24 6.355 MODEL BHA 018 024 030 036 042 048 060 MINIMUM AIR FLOW (CFM) COOLING 450 600 750 900 1,050 1,200 1,500 HEATING 450 600 750 900 1,050 1,200 1,500 MAXIMUM AIR FLOW (CFM) COOLING 750 1,000 1,250 1,500 1,750 2,000 2,500 HEATING 750 1,000 1250 1.500 1,750 2,000 2,500 MINIMUM OPERATING TEMPERATURE IN COOLING MODE (AMBIENT, °F) 45 45 45 45 45 45 45 MINIMUM MIXED AIR IN COOLING MODE (RETURN AIR, DB °F/WB °F) 68/57 68/57 68/ 57 68/57 68/57 68/57 68/57 MINIMUM MIXED AIR IN HEATING MODE (RETURN AIR, °F) 55 55 55 55 55 55 55 DISCRIPTION RESISTANCE, IWG CFM 500 600 700 800 900 1,000 1,100 1,200 1,300 1,400 1,500 1,600 1,700 1,800 1,900 2,000 Wet Indoor coil 0.01 0.01 0.01 0.02 0.02 0.03 0.03 0.04 0.04 0,04 0.04 0.04 0.05 0.05 0.06 0.07 Economizer 0.00 0.00 0.00 0.01 0.01 0.01 0,01 0.02 0,03 0.04 0.05 0.06 0.07 0.07 0.08 0.08 Filter /Frame Kit 0.01 0,02 0.02 0.02 0.02 0.02 0.03 0.03 0.03 0.03 0,04 0.05 0.05 0.06 0.06 0.07 Electric Heat 0.02 0.03 0.03 0,03 0.04 0.04 0.05 0.06 0.07 0.08 0.09 0.10 0.01 0.11 0,11 0.12 6 • HEATING CAPACITIES - 5 TON (BHA06 APPLICATION DATA ADDITIONAL STATIC PRESSURE RESISTANCE 511.1 8 -TG 1 Y NOTE: 1. Deduct these resistance values from the available external static pressure shown In the respective Blower Performance Table. 2. The pressure thru the economizer Is greater for 100% outdoor air then for 100% return air. If the resistance of the return air duct system Is leu then 025 IWO, the unit will delNer less CFM during full economizer operation. Unitary Products Group 15 MODEL NO. BHA MOTOR SPEED EXTERNAL STATIC PRESSURE - IWG .10 .20 .30 .40 .50 .60 .70 I .80 .90 1.00 1.10 WJ3 I S11VM WJO l S11 I wd3 SLLVM r Wd3 I I Si1VM [ WAO [ S11VM , I I Wd3 I SLLVM I Wd0 SLLVM WJ3 I SLLVM Wd9 S11VM WJ° I SUVM I WHO S11VM HI - - - - - - • - - 689 401 652 386 - - - - - - - - 018 MED - - - - - - • 654 233 231 209 - - - - - - - - - - - LOW - LOW - - 702 220 641 206 536 183 577 - - - - - - - - - - - HI - - HI - - - - - - - - - - 987 507 873 493 760 480 - - 024 MED - - - - - - - - 935 338 961 720 351 219 800 304 733 286 867 268 - 274 - - - - - LOW 900 290 850 287 800 243 760 220 697 238 - - - - - - - - - - - HI - - - - - - - - - 1021 341 1100 620 987 507 873 493 760 480 - - 030 MED 1200 390 1134 397 1068 368 100 367 936 339 8 766 800 304 - - - - - - - - - LOW 900 280 850 267 800 243 • - - - - - - - - - - - - - 530 1097 HI 1004 912 456 - - 1414 617 1317 688 1219 660 1116 533 1013 910 480 - - 036 MED 952 911 392 348 - - 1472 647 13 626 1297 495 1199 465 1102 435 985 397 - • 1728 725 1633 - 1527 LOW 1422 526 1400 506 1337 486 127 467 1167 440 1100 414 1012 387 042 MED • • 1674 614 1590 590 - 567 HI t - 1296 - - 470 - 1697 740 1580 1463 672 1339 640 1216 608 1092 576 - - 042 MED - - - - - 1093 1673 830 1566 594 1439 In 1322 522 1182 476 - - - - - - 1939 850 LOW - - 1680 607 1608 770 1630 660 1425 528 1320 707 1214 464 1050 420 - 048 MED f0 690 1662 673 HI - - - - - - 1947 882 18671 857 1786 832 1706 807 1637 782 1569 757 1500 732 - - ' 048 MED 1876 792 1829 772 1783 753 1736 733 166 706 1599 680 1531 653 1434 622 1337 591 1240 560 - - LOW 1544 620 1508 610 1472 600 1436 590 137 573 1313 557 1252 540 - - - - - - 060 - 233911702275111822111067214710152083 Hl - - - - - 24991290 123322831177'21751120 2019 912 1955 860 067108019581040 824 1753 788 11000 1 17 - - - 060 MED - - 245411632387111723201070 1772 830 1720 110232137 rs N 0 D 1667 977 2046 930 1950 887 1854 843 800 - - LQW 2242109022011053216110172,120 980 _ t7 1 : :7 1:_: : 0 1797 7:7 1711 7 e - - MODEL NO, BHA MOTOR SPEED EXTERNAL STATIC PRESSURE - IWG .10 .20 .30 .40 .50 .60 .70 .80 .90 1.00 1.10 WA9 I S1LVM I WA9 I S11VM I Wd° S11VM I I I SLLVM vin I S11VM I WHO I SLLVM I WHO I S11VM I ■33 I S11VM 1 Wd3I I SiJVM I WAO I S1LVM I I WdO I [sum I HI - - - - - - • • 689 374 593 361 497 347 - - - • - - - 018 MED - - - - - • 690 231 659 210 487 188 • - - - - - - - - - LOW 741 226 686 212 632 198 577 185 453 165 - - - - - - - - - - HI - - - - - - - - 990 468 888 456 786 432 - - 024 MED LOW 810 - 261 - 765 - 240 961 720 351 219 902 675 321 198 841 627 305 215 751 - 290 - 720 - 274 - 660 257 - - - - - - - HI - - - - - - 1171 1080 980 468 888 786 - - - 030 MED 1080 351 1021 341 961 331 902 321 841 781 S - - - - - - - LOW 810 261 766 240 - - - • - - - - - - - HI - - - 14.40 1381 581 1273 656 1185 530 1097 604 1004 912 456 - - - 036 MED LOW 1465 1316 631 473 1395 1260 512 455 1325 1204 1255 1148 473 420 1167 1069+396 446 1079 990 419 372 952 911 392 348 - - - - - - - - - - - - HI - - • 1728 725 1633 697 1527 666 1422 1317 606 1205 676 1094 547 - - 042 MED • • 1674 614 1590 590 1506 567 1400 636 1296 1190 470 1063 428 LOW 1679 867 1612 646 1449 526 1377 504 1282 476 1188 1093 418 - HI - 1982 870 1939 850 1897 830 1813 800 1728 770 1644 740 1559 707 1474 673 1389 - - 048 MED f0 690 1662 673 1629 657 1597 640 1542 623 1486 607 1431 590 1336 563 1240 537 - • - LOW 1 520 1349 510 1312 500 1276 490 1235 480 - - - - - - - - HI - - 24501213236611652282111721981066721141020 1993 1864 967 .752 CD 940 - • 060 MED 233911702275111822111067214710152083 963 2019 912 1955 860 , Co m 824 1753 788 • - ____,J, OW 1929940 16771903 1824.867 1772 830 1720 793 1667 757 1615 720 i_ 706 1557 691 • 577 • 511.18 -TG 1 Y SIDE AND BOTTOM SUPPLY AIR BLOWER PERFORMANCE 230/460/575 volts NOTE: Above data Includes allowances for a dry Indoor coil and no Mors. For additional pressure drops, refer to the •Add boned Static Pressure Resistance* table. 208 volts NOT Above data includes allowances for a dry indoor coil and no filers. For addtorW pressure drops, raker to the 'AIJdDOn l 9taac Prasaue Rraatance table. 16 Unitary Products Group MODEL BHA POWER SUPPLY VOLTAGE LIMITATIONS O COMPRESSOR OUTDOOR FAN MOTOR, FLA SUPPLY AIR BLOWER MOTOR, FLA MINIMUM CIRCUIT AMPACITY MAX. FUSE SIZE, AMPS m MAX. HACK BREAKER SIZE, AMPS UNIT POWER FACTOR TRANSFORMER SIZE (VA) MIN. MAX. RLA LRA , 018 208/230-1-60 187 253 9.0 48.0 1.1 2.6 14.9 20 , 20 .96 40 024 208/230 -1-60 187 253 11.2 60.0 1.1 2.6 17.7 25 25 .96 40 ► 030 208/230 -1-60 187 253 12.0 73.0 1.1 2.6 18.7 25 25 .96 40 036 208/230 -1-60 187 253 17.3 94.0 1.1 3.5 26.2 35 35 .96 40 042 208/230 -1-60 187 253 20.5 120.0 1.1 3.5 30.2 40 40 .96 40 048 208/230-1-60 187 253 24.4 140.0 1.5 4.0 36.0 50 50 .96 40 060 208/230 -1 -60 187 253 28.9 165.0 1.5 7.0 44.6 60 60 .96 40 036 208/230 -3-60 187 253 10.9 78.0 1.1 3.5 18.2 25 25 .96 75 042 208/230 -3-60 187 253 14.1 110.0 1.1 3.5 22.2 30 30 .96 75 048 208/230 -3.60 187 253 14.1 105.0 1.5 4.0 23.1 30 30 .96 75 060 208/230 -3-60 187 253 16.0 125.0 1.5 7.0 28.5 40 40 .96 75 036 460-3-60 414 504 5.8 40.0 0.6 1.8 9.6 , 15 15 .96 75 _ 042 460 -3 -60 414 504 7.1 54.0 0.6 1.8 11.2 _ 15 15 .96 75 048 460 -3 -60 414 504 7.1 55.0 0.8 2.0 11.7 15 15 .96 75 060 460 -3 -60 414 504 8.0 67.0 0.8 3.5 14.3 20 20 .96 75 036 575-3-60 518 630 4.5 32.0 0.4 1.5 7.6 15 15 .96 75 042 575-3-60 518 630 5.8 44.0 0.4 1.5 9.1 15 15 .96 75 04.8 575 -3 -60 518 630 5.6 44.0 0.6 1.6 9.3 15 15 .96 75 060 575 -3 -60 518 630 6.4 50,0 0.6 2.8 11.4 15 15 .96 75 e • FIELD WIRING DIAGRAM THERMOSTAT UNIT TERMINAL STRIP " = Minimum wire size of 18 AWG wire shuold be used for all field installed 24 volt wire. CONTACTOR POWER WIRING PROGRAMABLE THERMOSTAT ONLY • = Only required on units with supplemental electric heal ELECTRICAL DATA (BASIC UNIT) 0 - 24 VOLT TRANSFORMER CAUTION: Label all wires prior to disconnection when servicing controls. Wiring errors can cause improper and dangerous operation. Verify proper operation after servicing. CONTROL WIRING CONTACTOR NOTE: HEAT ANTICIPATOR SHOULD BE SET AT 025 AMPS FOR ALL MODELS. 511.18 -TG 1 Y --- FIELD-SUPPLIED = Y FIELD-SUPPLIED DISCONNECT DISCONNECT T r -1 SINGLE �� Q CT r - i L ' - I - i - - O' -rp - - r - PHASE __i_.. - i - , THREE PHASE I- -0- 0- -� POWER = L - „� �r -��F_ GROUND REFER TO EL DATA L SUPPLY GROUND L ,0-J- 0- _ L .- POWER LUG TABLES TO SIZE THE DIS- LUG REFER TO ELECTRICAL DATA L SUPPLY CONNECT TABLES TO SIZE THE DIS CONNECT m. Utillzatlon Rant?) 'A' in accordance with ARI Standard 110. Unitary Products Group m. Dual element, lime delay type. 17 . 511.18 -TG 1Y ELECTRICAL DATA (HEAT PUMP / ELECT RAC HEAT) ELECTRIC HEAT CORRECTION FACTORS NOMINAL VOLTAGE VOLTAGE KW CAP. _NULTIELIER .75 .92 240 208 230 480 s�75 . 9 I m w O POWER COMPRESSOR OUTDOOR FAN MOTOR FLA SUPPLY AIR ELECTRIC HEAT ACCESSORY MINIMUM CIRCUIT AMPACITY MAX. FUSE SIZE, 0) AMPS MAX. HACK at) BREAKER SIZE SUPPLY RLA LRA MOTOR, FLA MODEL NO. w H Cl) KW AMPS 018 208/230 -1 -60 9.0 48.0 1.1 2,6 2NH04500506 2NH04500706 2NH04500506 2NH04500706 2NH04501006 2NH04500506 04500706„ 1 2 1 2 2 I CMI C NI rHN CM 3.8/5.0 • 5.6/7.5 • 3.8/5.0 • 5.6/7.5 " 7.5/10.0 • 3.8/5.0 • 5. 5 7. • 11.3/15.0 • 18.1/20.8 27.1/31.3 18.1/20.8 27.1/31.3 36.1/41.7 18.1/20.8 27.3/31.3 36.1/41.7 54.2/62.5 37.5/41.0 48.8/54.0 40.7/44.2 52.0/57.2 63.3170.2 44.7/48.2 56.0/61.2 67.3/74.2 89.8/100.3 40/4.5 50/60 45/50 60/60 70/80 50/50 60/70 70/80 90/110 40/45 50/60 45/50 60/60 70/80 50/50 60/70 70/80 90/110 024 208/230 -1 -60 11.2 60.0 1.1 2.6 . 030 208/230-1-60 12.0 73.0 1.1 ( 2.6 • 64501006 2NH04501506 036 208/230-1-60 17,3 94.0 1.1 3.5 2NH04500506 2NH04500706 2NH04501006 04501506 2NH04500506 2NH04500706 2NH04501006 2NH04501506 r N N N r N N N CCpO tO CCOLpD C COLD CD 0 O^ON 0 88888888 1111 _ = _ _ zzzz zzzz N N N N N N N N 3.8/5.0 • 5.6/7.5 • 7.5/10.0 • 11.3/15.0 • 3.8/5.0 • 5.6/7.5 • 7.5/10.0 • 11.3/15.0 • 18.1/20.8 27.1/31.3 36.1/41.7 54.2/62.5 18.1/20.8 27.1/31.3 36.1/41.7 54.2/62.5 48.8/52.3 60.1/65.3 71.4/78.3 93.9/104.4 52.8/56.3 64.1/69.3 75.4/82.3 97.9/108.4 60/60 70/70 80/80 100/110 60/70 70/80 80/90 100/110 60/60 70/70 80 /80 100/110 60/70 70/80 80/90 100/110 042 208/230-1-60 20.5 120.0 1.1 3.5 048 208/230-1-60 24.4 140.0 1.5 4.0 04501006 2NH04501506 2NH04502006 2NH04502506 N N N N 0000 0000 0000 0 0 0000 0000 8888 __ == zzzz N N N N 7.5/10.0 ' 11.3/15.0 • 15.0/20.0 ' 18.8/25.0 • 36.1/41.7 54.2/62.5 72.2/83.3 90.3/104.2 81.1/88.1 103.7/114.1 126.3/140.2 148.8/166.2 90/100 110/125 150/150 150/175 90/100 110/125 150/150 150/175 060 208/230-1-60 28.9 165.0 1.5 7.0 04501006 2NH04501506 04502006 2NH04502506 N NN CM CMM p r N p N 8080 =Ix zzzz N N NN 7.5/10.0 • 11.3/15.0 • 15.0/20.0 • 18.8/25.0 • 36.1/41.7 54.2/62.5 72.2/83.3 90.3/104.2 89.8/96.7 112.3/122.8 134.9/148.8 157.5/174.8 100/110 125/125 150/150 175/175 100/110 125/125 150/150 175/175 036 208/230-3-60 10.9 78.0 1.1 3.5 - 04501025 2NH04501525 0 0 N N 0121 O O 0 to mm zz NN 7.5/10.0 ' 11.3/15.0 * 20.8/24.1 31.3/36.1 44.3/48.3 57.3/63.3 45/50 60/70 45/50 60/70 042 208/230 -3-60 14.1 110.0 1.1 3.5 2NH04501025 2NH04501525 0 0 N N O O $S zz N N 7.5/10.0 • 11.3/15.0 • 20.8/24.1 31.3/36.1 48.3/57.3 61.3/67.3 50/60 70/70 50/60 70/70 048 208/230-3-60 14.1 105.0 1.5 4.0 2NH04501025 2NH04501525 04502025 04502525 r r N N O O 0 O ' N N N N O O 0 0 r N N 0000 NOO tf) 8888 zzzz N N N N 7.5/10.0 • 11.3/15.0 • 15.0/20.0 18.8/25.0 ' 20.8/24.1 31.3/36.1 41.7/48.1 52.1/60.1 49.2/53.2 62.2/68.2 75.3/83.3 88.3/98.3 50/60 70/70 80/90 90/100 50/60 70/70 80/90 90 /100 060 208/230-3-60 16.0 125.0 1.5 7.0 2NH04501025 04501525 ..... /04502025 2NH04 02 r r N O tt) O O N N N N 00 O • r- N N 0 O O O 0 0 0 0 Saga III' zzzz N N NN I 7.5/10.0 • 11.3/15.0 " 15.0/20.0 • 18.: 50 • 20.8/24.1 31.3/36.1 41.7/48.1 .1/60.1 54.6/58.6 67.6/73.6 80.7/88.7 : 71.37 60/60 70/80 90/90 10e/111 60/60 70/80 90/90 10. 110 036 460 -3 -60 5.8 40.0 0.6 1.8 2NH04501046 2NH04501546 CO CD 8 0 O O O __ zz N N 10.0 •• 15.0 " 12.8 18.0 24.6 32.2 25 35 25 35 042 460-3-60 7.1 54.0 0.6 1,8 2NH04501046 2NH04501546 • —' N 10.0 ** 15.0 10.0 '" 15.0 " 20.0 •• 25.0 '" 12.0 18.0 12.0 18.0 24.1 30.1 26.2 33.8 26.7 34.2 41.7 49.3 30 35 30 35 45 50 30 35 30 35 45 50 048 460.3 -60 7.1 55.0 0.8 2.0 2NH04501046 2NH04501546 2NH04502046 2NH04502546 060 460-3-60 8.0 67.0 0.8 3.5 1.5 2NH04501046 2NH04501546 2NH04502046 NH04502546 2NH04501058 2NH04501558 .-r NN CD tO COLD mm �_�� ow, r N 000 00 00 CO MX __ ZZZ zZ N NN NN, 10.0 " 15.0 " 20.0 '" 25.0 " 10.0 •" 15.0 "' 12.0 18.0 24.1 30.1 9.6 14.4 29.4 36.9 44.4 51.9, 19.6 25.6 30 40 45 60 20 30 30 40 45 60 20 30 036 575-3-60 4.5 32.0 0.4 042 575.3 -60 5.8 44.0 0.4 1.5 2NH04501058 2NH04501558 co Q) ss 0 O O 0 a8 __ zz N N ' 10.0 "" 15.0 ••• 9.6 14.4 21.1 27.2 25 30 25 30 048 575 -3-60 5.6 44.0 0.6 1.6 2NH04501058 2NH04501558 2NH04502058 2NH04502558 r r N N CD CD C CO in 000 CO o • r N N' 8885 __ == zzzz N N N N 10.0 "" 15.0 •• 20.0 ••" 25.0 •• 9.6 14,4 19.2 24.1 21.3 27.3 33.3 39.3 25 30 35 40 25 30 35 40 060 575 3-60 6.4 50.0 0.6 2.8 2NH04501058 2NH04501558 2NH04502058 NH s . r N 222 000 Val aaa = =z= zzzz N N N 10.0 "" 15.0 •" 20.0 • "" .s •" 9,6 14.4 19.2 41 23.4 29.5 35.5 4 25 30 40 4 25 30 40 4 m - Dual element. time delay type. Z - Standard orwit breakers may be used in Canada and on applications over 60 amps *Pent V* beaters are separately fused. 18 • ■ Kw wand I for 240 volts use table at lop of paps Ior206 or 230 volt - Kw ll:t.d is fa 400 volts, use hole al lop of papa for 460 volts. •"• - KW Meted is for 600 volts. use table at top of paps for 575 volts. Unitary Products Group • • • • • UNIT DIMENSIONS HIGH VOLTAGE CONN. 1 DIA. KNOCKOUT LOW VOLTAGE CONN. 1 /e" DIA. KNOCKOUT SIDE SUPPLY AIR OPENING SIDE RETURN AIR OPENING LOW VOLTAGE CONN. 1/4" DIA. KNOCKOUT 43/2.40 Unitary Products Group HIGH VOLTAGE CONN. %/e D1k KNOCKOUT 49 (OVERALL) 6 CONDENSATE DRAIN 3 /4" NPTI 2 221 FRONT 3 22 OUTDOOR COIL BOTTOM SUPPLY AIR OPENING 1 1'/2 UNIT CONDENSATE 4 CONNECTION 3/4' NPTI (TRAP REQUIRED) HIGH VOLTAGE CONN. 1 x %' DIA. KNOCKOUT 15 FRONT COMPRESSOR SERVICE ACCESS COMPARTMENT PANEL "A" (OVERALL) 14'/2 13'4 471 (OVERALL) SIDE SUPPLY AIR OPENING 28% UNIT SIZE 018.042 048 - 060 REFRIGERANT CONNECTIONS ELECTRICAUFILTER SERVICE ACCESS COMPARTMENT PANEL HIGH VOLTAGE CONN. 1 DIA KNOCKOUT All dimensions are in inches. They are subject to change without notice. Certified dimensions will be provided upon request. 14Y 511.1 8 -TG 1 Y DIMENSION "A" BACK 3 33 411/2 SIDE RETURN AIR OPENING 31/2 \ BOTTOM RETURN AIR OPENING 19 B1HA UNIT SIZE SHIPPING WEIGHT OPERATING WEIGHT CORNER WEIGHTS A B C D 018 350 345 103 92 73 82 024 350 345 95 92 80 83 • 030 360 355 98 94 82 85 036 367 362 100 96 84 87 042 394 389 107 103 90 93 048 445 440 121 117 102 105 060 490 485 133 129 112 116 minimum Front 12" Back 0" Left Side (Filter Access) 24" Right Side 24" Below Unit CD 0" Above Unit O 36" (For Condenser Air Discharge) 511.1 8•TG 1 Y CENTER OF GRAVITY FRONT OF UNIT 49 25 CLEARANCES UNIT CLEARANCES 22 47r/a m Units may be installed on combustible Moors made from wood or dass A B or C roof covering material. to Units must be Installed outdoors, Overhanging structures or shrubs should not obstruct outdoor air dscharge outlet NOTE: FOR UNITS APPLIED WITH A ROOF CURB, THE MINIMUM CLEARANCE MAY BE REDUCED FROM 1 INCH TO 1/2 INCH BETWEEN COMBUSTIBLE ROOF CURB MATERIAL AND THE SUPPLY DUCT. 20 CENTER OF GRAVITY FLEXIBLE DUCT COLLAR MINIMUM CLEARANCE OF 1' ALL SIDES FOR THE FIRST 3' OF DUCT FOR 20 & 25 KW. ZERO INCHES THEREAF- TER. FOR ALL OTHER HEATERS. ZERO INCH CLEARANCE ALL SIDES FOR ENTIRE LENGTH OF DUCT • • • TYPICAL APPLICATIONS TYPICAL SLAB ON GROUND INSTALLATION SUPPLY AIR DUCT RETURN AIR DUCT FIELD SUPPLIED DISCONNECT SWITCH LOCATED TO REAR OF UNIT TO POWER SUPPLY CONTROL WIRING TO INDOOR THERMOSTAT FIELD SUPPLIED DISCONNECT SWITCH MOUNTED ON UNIT ROOF CURB INSTALLATION REAR DUCT Unitary Products Group TO POWER SUPPLY CONTROL WIRIN TO INDOOR THERMOSTAT ROOF CURB INSTALLATION BOTTOM DUCT TYPICAL ROOF CURB INSTALLATION 0 RETURN AIR DUCT SLAB ON GROUND INSTALLATION SUPPLY AIR DUCT 511.1 B -TG 1 Y 21 22 • 511.18-TG1Y ROOF CURB DIMENSIONS (8" roof curb also available) OPENING FOR RETURN AIR DUCT 14 42 40 FRONT INSULATED PANELS ROOF CURB APPLICATION 3 x 1" WIDE GASKETING FOR CURB FRAME AND ALL DUCT SUPPORT SURFACES UNIT BASE WOOD NAILER 8" MIN. ABOVE FINISHED ROOF CURB FRAME INSULATION RECOMMENDED DUCT SIZE SUPPLY AIR DUCT 17 x 21 RETURN AIR DUCT 17 x 16 4 45 WOOD NAILER UNIT BASE RAIL COUNTERFLASHING CANT STRIP NSULATION AND ROOFING MATERIAL ROOF DECK AND ROOFING MATERIAL Unitary Products Group • 511.18 -TG1Y TYPICAL WIRING DIAGRAM (208/230.1 -60 POWER SUPPLY) • A I B ( C 1 0 1 E I I 0 f H ELEMENTARY DIAGRAM POWER SUPPLY WITH ELEC HEAT 208/230 -1 -00 use COPPER CDaCTORS ONLY • • 34 35 38 37 •®• 218/BK SEE NOTE 7 RVS Unitary Products Group ELU 222/Y 220/0 114/BK 201/BR 221/BR COIN RELAY O I 203/BR PRESS SV 101 PI 709 /BKi O— - q CIM FAN �OFST U © S1 A1 DEFROST CONTROL I- T'STAP 0- OEF © I O MI -I •- I- Np BL F — Qw.wQ- co KS 7 n r No B O H TR w p� — FS HT 4 �7BK C10 ND -QwvwQ KO HER 3 5_ 71 - BK N0 RED PR 108/BK 120/BK 216/2 215/0 217/0/ 216/V POWER SUPPLY V/UJT ELEC MEAT 200/230 160 USE COPPER CONCLCTORS ONLY F3 703 K3 r--, 704 HTR 2 705 BK s CO Q-� R 214/98 I 701" L_ R _. <i_© C3 -0 (4 =ftei P3 S3 F24 CID 2I / BR I - - -- L 00 FAN BEN MOTOR 1 1. PTtP A 4 -I L KI K2 112 /92 CINTRL LTAiIC L } S RC2 PTCR RCI T 24V 2. BY • 230/ 10B/PR FAN CCHTKEL I BOARD ?05/4 P2 2 0. I ) ®s 2 ®■• ® -4 ) (fp. B12/T'B ®4w 0 B10/BL I"0— L J L. 1 111 )/PR 0 MI -2 213/4 129/PR TH1 204/64 SEA NOTE B 000/0 © TH • 0PJ F2 BID ON FAN I05/R Y /ALT CAPAC. ONLY EM NT (0501 16 /O 813 1M2 ANT I 014 017 /BL /0 4L IM0 0 THI /TC1 ANT Cril OM - W' CFA HEAT p EM HT/ O A 0 150 130 230, 200 7C, 7F ROOM THERMOSTAT O 23 511.16 -TG 1 Y TYPICAL WIRING DIAGRAM NOTES (See page 23, 24 and 25) CB CIRCUIT BREAKER, 3 AMP CCH CRANKCASE HEATER COMPR COMPRESSOR OS DEFROST SENSOR, CLOSES a 31 ° F, OPENS e 55 ° F. F1, F2 FUSES, LINE VOLTAGE - 60 AMP (5, 7.5, 10, & 15 KW ELEC HEAT) F3, F4 FUSES, LINE VOLTAGE - 3D AMP (7.5, 10, & 15 KW ELEC HEAT) F5, F6 FUSES, LINE VOLTAGE - 30 AMP (15 KW ELEC HEAT) F24 FUSE 24V SECONDARY, 5 AMP FS FREEZESTAT SWITCH (OPTIONAL ACCESSORY) OPEN a 26 °F HP HIGH PRESSURE SNITCH (OPTIONAL ACCESSORY) OPENS a 380 PSIG HTR 1 ELECTRIC HEATER (OPT. ACCSSRY: 5, 7.5, 10, & 15 KW ELEC HEAT) HTR 2 ELECTRIC HEATER (OPT. ACCSSRY: 7.5, 10, & 15 KW ELEC HEAT) HTR 3 ELECTRIC HEATER (OPT. ACCSSRY: 15 KW ELEC HEAT) K1 RELAY INDOOR FAN MOTOR K2 RELAY ELECTRIC HEATER K3 RELAY ELECTRIC HEATER, 24 VOC COIL (7.5, ID, & 35 KW ELEC HEAT) K4 RELAY ELECTRIC HEATER, 24 VOC COIL (15 KW ELEC HEAT) LP LOW PRESSURE SWITCH (OPTIONAL ACCESSORY) OPEN e 7 PSIG LS LIMIT SWITCH, ELECTRIC HEAT (PART OF ELEC HEAT ACCESSORY) M1 CONTACTOR, COMPRESSOR & OUTDOOR FAN M2 CONTACTOR, INDOOR BLOWER MOTOR M3 CONTACTOR, OUTDOOR FAN MOTOR RC1/RC2 COMPRESSOR & OUTDOOR FAN RUN CAPACITOR RCI COMPRESSOR RUN CAPACITOR (ALTERNATE) RC2 OUTDOOR FAN RUN CAPACITOR (ALTERNATE) RC3 INDOOR FAN RUN CAPACITOR RVS REVERSING VALVE SOLENOID S2/P2 SOCKET/PLUG CONNECTION ON FAN CONTROL BOARD, LOW VOLTAGE S3/P3 SOCKET/PLUG CONNECTION ON FAN CONTROL BOARD, LINE VOLTAGE T1 TRANSFORMER, 24V, 40 VA IDENTIFIED TERMINAL ON RUN CAPACITOR A ROOM THERMOSTAT 24V CONNECTIONS 0 TOt ON FAN/ELEC HEAT CONTROL BOARD FACTORY WIRING AND DEVICES -- OPTIONAL WIRING AND DEVICES — — — — FIELD WIRING TYPICAL WIRING DIAGRAM LEGEND (See page 23, 24 and 25) I ALL FIELD WIRING TO BE ACCOMPLISHED FOLLOWING CITY, LOCAL AND /OR NATIONAL CODES IN EFFECT AT TIME OF INSTALLATION OF THIS UNIT. 2. CAUTI ❑N: LABEL ALL WIRES PRIOR TO DISCONNECTION WHEN SERVICING CONTROLS. WIRING ERRORS CAN CAUSE IMPROPER AND DANGEROUS OPERATION. IF ANY OF THE WIRE AS SUPPLIED WITH THIS UNIT MUST BE REMOVED, IT MUST SE REPLACED WITH TYPE 105' C, 600V WIRE OR EQUIVALENT CLEARLY RENUMBERED FOR IDENTIFICATION. VERIFY PROPER OPERATION AFTER SERVICING. 3. MOTORS ARE INHERENTLY PROTECTED. 4. UNIT FACTORY WIRED FOR 230 VOLT OPERATION. FOR 208 VOLT OPERATION MOVE '10B/PR' WIRE FROM 240V TO 20BV ON TRANSFORMER T1. 5. SEE UNIT NAMEPLATE FOR MAXIMUM FUSE SIZE AND MINIMUM CIRCUIT AMPACITY. 6. SELECT INDOOR BLOWER SPEED TO OBTAIN APPROX 400 CFM/TON IN COOLING. 7. IF OPTIONAL SAFETY SWITCH KIT IS INSTALLED, WIRE 219/BK IS REMOVED. 26 B. VIRE 204/2R IS REMOVED WHEN ELECTRIC HEAT IS INSTALLED. CAUTION — OPEN ALL DISCONNECTS BEFORE SERVICING THIS UNIT Unitary Products Group • • • 511.18 -TG 1 Y TYPICAL WIRING DIAGRAM NOTES (See page 23, Nand 25) CB CIRCUIT BREAKER, 3 AMP CCH CRANKCASE HEATER COMPR COMPRESSOR OS DEFROST SENSOR, CLOSES e 31 °F, OPENS a 55 ° F. Fl, F2 FUSES, LINE VOLTAGE - 60 AMP (5, 7.5, 10, & 15 KW ELEC HEAT) F3, F4 FUSES, LINE VOLTAGE - 30 AMP (7.5, 10, & 15 KW ELEC HEAT) F5, F6 FUSES, LINE VOLTAGE - 30 AMP (15 KW ELEC HEAT) F24 FUSE 24V SECONDARY, 5 AMP FS FREEZESTAT SWITCH (OPTIONAL ACCESSORY) OPEN e 26 °F HP HIGH PRESSURE SNITCH (OPTIONAL ACCESSORY) OPENS a 380 PSIG HTR l ELECTRIC HEATER (OPT. ACCSSRY: 5, 7.5, 10, & 15 KW ELEC HEAT) HTR 2 ELECTRIC HEATER (OPT. ACCSSRY: 7.5, 10, & 15 KW ELEC HEAT) HTR 3 ELECTRIC HEATER (OPT. ACCSSRY: 15 KW ELEC HEAT) K1 RELAY INDOOR FAN MOTOR K2 RELAY ELECTRIC HEATER K3 RELAY ELECTRIC HEATER, 24 VOC COIL (7,5, 10, & 35 KW ELEC HEAT) K4 RELAY ELECTRIC HEATER, 24 VOC COIL (15 KW ELEC HEAT) LP LOW PRESSURE SWITCH (OPTIONAL ACCESSORY) OPEN e 7 PSIG LS LIMIT SNITCH, ELECTRIC HEAT (PART OF ELEC HEAT ACCESSORY) M1 CONTACTOR, COMPRESSOR & OUTDOOR FAN M2 CONTACTOR, INDOOR BLOWER MOTOR M3 CONTACTOR, OUTDOOR FAN MOTOR RCl/RC2 COMPRESSOR & OUTDOOR FAN RUN CAPACITOR RCI COMPRESSOR RUN CAPACITOR (ALTERNATE) RC2 OUTDOOR FAN RUN CAPACITOR (ALTERNATE) RC3 INDOOR FAN RUN CAPACITOR RVS REVERSING VALVE SOLENOID S2/P2 SOCKET/PLUG CONNECTION ON FAN CONTROL BOARD, LOW VOLTAGE S3/P3 SOCKET/PLUG CONNECTION ON FAN CONTROL BOARD, LINE VOLTAGE T1 TRANSFORMER, 24V, 40 VA ® IDENTIFIED TERMINAL ON RUN CAPACITOR 6 ROOM THERMOSTAT 24V CONNECTIONS O TBI ON FAN/ELEC HEAT CONTROL BOARD FACTORY WIRING AND DEVICES OPTIONAL WIRING ANO DEVICES — — — — FIELD WIRING TYPICAL WIRING DIAGRAM LEGEND (See page 23, 24 and 25) 1 ALL FIELD WIRING TO BE ACCOMPLISHED FOLLOWING CITY, LOCAL AND/OR NATIONAL CODES IN EFFECT AT TIME OF INSTALLATION OF THIS UNIT. 2. CAUTION: LABEL ALL WIRES PRIOR TO DISCONNECTION WHEN SERVICING CONTROLS. WIRING ERRORS CAN CAUSE IMPROPER AND DANGEROUS OPERATION. IF ANY OF THE WIRE AS SUPPLIED WITH THIS UNIT MUST BE REMOVED, IT MUST BE REPLACED WITH TYPE 105' C, 500V WIRE DR EQUIVALENT CLEARLY RENUMBEREO FOR IDENTIFICATION. VERIFY PROPER OPERATION AFTER SERVICING. 3. MOTORS ARE INHERENTLY PROTECTED. 4. UNIT FACTORY WIREO FOR 230 VOLT OPERATION. FOR 208 VOLT OPERATION MOVE '108/PR' WIRE FROM 240V TO 20BV ON TRANSFORMER 71. 5. SEE UNIT NAMEPLATE FOR MAXIMUM FUSE SIZE AND MINIMUM CIRCUIT AMPACITY. 6. SELECT INDO ❑R BLOWER SPEED TO OBTAIN APPROX 400 CFM/TDN IN COOLING. 7. IF OPTIONAL SAFETY SWITCH KIT IS INSTALLED, WIRE 219/8K IS REMOVED. 26 B. WIRE 204/BR IS REMOVED WHEN ELECTRIC HEAT IS INSTALLED. CAUTION - OPEN ALL DISCONNECTS BEFORE SERVICING THIS UNIT Unitary Products Group • MECHANICAL SPECIFICATIONS • GENERAL DESCRIPTION • Units shall be factory- assembled, single packaged, Heat Pumps, designed for outdoor mounted installation. Units shall have minimum SEER ratings of 10.0. They shall have built in, equal size, field convertible duct connections for down dis- charge supply /return or horizontal discharge supply /return. The units shall be factory wired, piped, charged with R -22 refrigerant and factory tested prior to shipment. All unit wiring shall be both numbered and color coded. All units shall be manufactured in a facility certified to ISO 9001 standards, and the cooling performance shall be rated in accordance with DOE and ARt test procedures. Units shall be certified to UL 1995 /CAN /CSA C22.2 No. 236 standards. UNiT CABINET 1. Unit cabinet shall be constructed of G90 galvanized steel, with exterior surfaces coated with •a non - chalking, pow- ered paint finish, certified at 750 hours salt spray test per ASTM -B117 standards. 2. The unit top shall be a single piece "Water Shed" design, with drip edges and no-seam corners to provide optimum water integrity. 3. Unit shall have a rigidly mounted condenser coil guard to provide protection from objects and personnel after instal- lation. 4. Indoor blower section shall be insulated with up to 3/4" thick, aluminum, foil faced insulation, fastened to prevent insulation from entering the air stream. 5. Cabinet panels shall be "large" size, easily removable for servicing and maintenance, with built -in lift handles. 6. Unit shall be built on a formed, "Super- Structure" design base pan, with embossments at critical points to add strength, rigidity and aid in minimizing sound. 7. Full perimeter base rails shall be provided to assure reliable transit of equipment, overhead rigging, fork truck access and proper sealing on roof curb applications. Base rails shall be removable, when required, to Iower unit height. 8. Filters shall be furnished and be accessible through a removable access door, sealed air tight. (Single phase models - accessory kit available. Three phase models - standard from factory.) 9. Units vertical discharge and return duct configuration shall be designed to fit between standard 24" O.C. beams without modification to building structure, duct work and base unit. 10. Condensate pan shall be internally sloped and conform to ASHARE 62 -89 self- draining standards, with 3 /4" NPTI copper, ridged mount connection. 511.18 - TG1Y INDOOR (SUPPLY) FAN ASSEMBLY 1. Fan shall be direct drive, multi -speed design. Job site selected (BHP) brake horse power shall not exceed the motors nameplate horse power rating. 2. Fan wheel shall be double -inlet type with forward -curved blades, dynamically balanced to operate smoothly throughout the entire range of operation. Airflow design shall be constant air volume. 3. Bearings shall be sealed and permanently lubricated for longer life and no maintenance. 4. Fan assembly shall be "Slip Track" (slide -out) design for easy removal and cleaning. OUTDOOR FAN ASSEMBLY 1. The outdoor fan shall be of the direct - driven propeller type, discharge air vertically, have aluminum blades riveted to corrosion resistant steel spider bracket and shall be stati- cally balanced for smooth operation. 2. The outdoor fan motor shall be totally enclosed with permanently lubricated bearings and internally protected against overload conditions. REFRIGERANT COMPONENTS 1. Compressors: A. Shall be fully hermetic type, direct drive, internally protected with internal high- pressure relief and over temperature protection. The hermetic motor shall be suction gas cooled and have a voltage range of + or - 10% of the unit nameplate voltage. B. Shall have Internal isolation and sound muffling to minimize vibration and noise, and be externally iso- lated on a dedicated, independent mounting. 2. Coils: A. Evaporator and condenser coils shall have aluminum plate fins mechanically bonded to seamless internally - enhanced copper tubes with all joints brazed. B. Evaporator and Condenser coils shall be of the direct expansion, blow -thru design. 3. Refrigerant Circuit and Refrigerant Safety Components shall include: A. Independent fixed - orifice expansion devices. B. Filter /strainer to eliminate any foreign matter. C. Accessible service gage connections on both suction and discharge lines to charge, evacuate, and measure refrigerant pressure during any necessary servicing or troubleshooting, without losing charge and without disrupting condenser or evaporator air flow. D. The refrigeration system shall provide at least 10° F of liquid sub - cooling at design conditions. E. Unit shall have a suction line accumulator and auto- matic reversing valve. Unitary Products Group 27 z 4. Unit Controls: A. Unit shall contain a large, low voltage Terminal Board for easy connection of field low voltage wiring. B. Controls shall be mounted in a largo control box with tilt -out, hinged access door, allowing easy access fortrouble shooting and maintenance without affecting the normal system operation pressures. C. Unit shall contain a reliable time - temperature defrost control to provide defrost, including field selectable time periods between cycles (30, 60 and 90 minutes), factory set at 60 minutes. The defrost control shall also have an "X" terminal to provide a 24 volt signal for room termostat "LED" indication of unit lockout, plus built in 5 minute anti -short cycle protection. D. Unit shall have large, easily removable panels, cover- ing electrical controls and compressor, allowing easy access for any necessary maintenance or servicing. ELECTRIC HEATING SECTION 1. An electric heating section, with nickel chromium ele- ments, shall be provided in a range of 5 thru 25 KW, offering two stages of capacity - 7 KW and above on single phase heaters, and one 20 KW and above on three phase heaters. L1YORK Heating and Air Conditioning Unitary Products Group P.O. Box 1692, York Pennsylvania USA 17406.1592 Subject to change without notice. Printed In U.S.A. Copyright 0 by York International Corporation 1998. All rights reserved. RPC 12M 598 1.54 2. The heating section shall have a primary limit control(s) and automatic reset, to prevent the heating element sys- tem from operating at an excessive temperature. 3. The heating section assembly shall slide out of the unit for easy maintenance and service. 4. Units with electric heating sections shall be wired for a single point power supply, with branch circuit fusing (where required). UNIT OPERATING CHARACTERISTICS 1. Unit shall be capable of starting and running at 125° F outdoor temperature, exceeding maximum load criteria of ARI Standard 210/240. 2. The compressor, with standard controls, shall be capable of operation down to 45° Foutdoortemperature. Accessory low ambient kit shall be available for operation to 0° F. ELECTRICAL REQUIREMENTS All unit power wiring shall enter unit cabinet at a single factory provided location and be capable of side or bottom entry, to minimize roof penetrations and avoid unit field modifications. Separate side and bottom openings shall be provided for the control wiring. Codes: EBY, EGY 's 9001 CIIt TIP1a0 USA Q9$ Pawl Sponsor 01 IM 199E U.S. 01ympC Turn XuSC]W 511,18 -TGIY Supersedes: 511.184G1Y (597) • • 07.10.98 MATERIAL AND QUANTITY ESTIMATES FOR H -ROOM STORAGE 1,4- DIOXANE ACETONE ACETONITRILE ALCOHOL ETHYL ACETATE ETHYL ETHER HEXANE ISOPROPYL ALCOHOL METHANOL N,N- DIMETHYLFORMAMIDE PENTANE TETRAHYDROFURAN TOLUENE XYLENE TOTAL ESTIMATE 1486 DUE TO THE CHANGING NATURE OF OUR CUSTOMERS' REQUIREMENTS, MATERIALS AND QUANTITIES ARE ESTIMATES AND ARE SUBJECT TO CHANGE. ALL CHANGE IN MATERIALS WOULD BE SIMILAR IN CLASS TO THOSE ABOVE. 8 179 299 14 63 14 253 184 409 20 4 28 24 g < R ECEIVED CITY OF TUKWILA ' - ; 1998 i'ERMIT CENTER BURDICK & JACKSON, INC. 1953 SOUTH HARVEY STREET MUSKEGON, MI 49442 USA MATERIAL SAFETY DATA SHEET INFORMATION /EMERGENCY TELEPHONE NUMBER 616.726.3171 CHEMTREC TELEPHONE NUMBER 800.424.9300 CANADIAN EMERGENCY TELEPHONE NUMBER 613,996.6666 I. IDENTIFICATION CHEMICAL NAME: 1,4- DIOXANE MOLECULAR WEIGHT: 88.11 CHEMICAL FAMILY: CYCLIC ETHER FORMULA: C4H802 SYNONYMS: DIOXANE, DIETHYLENE DIOXIDE, DIETHYLENE ETHER DOT PROPER SHIPPING NAME: DIOXANE DOT HAZARD CLASS: FLAMMABLE LIQUID, HAZARD CLASS 3, P.G. II DOT IDENTIFICATION NUMBER: UN1165 CAS NUMBER: 123-91-1 II. PHYSICAL AND CHEMICAL DATA BOILING POINT, 760 MM HG: VAPOR PRESSURE AT 20 C: X VOLATILES BY VOLUME: FREEZING POINT: VAPOR DENSITY (AIR =1): SPECIFIC GRAVITY (H20 =1): EVAPORATION RATE: SOLUBILITY IN WATER: STABILITY: HAZARDOUS POLYMERIZATION: APPEARANCE AND ODOR: CONDITIONS TO AVOID: MATERIALS TO AVOID: HAZARDOUS DECOMPOSITION PRODUCTS: III. FIRE AND EXPLOSION HAZARD DATA 1,4- DJOXANE REVISION DATE: DECEMBER, 1993 REVISION NO: 1 101.32 C 29 MM HG CA 100 11.8 C 3.0 @ 20 C 1.034 (BUAC =1) CA 3 @ 20 C COMPLETE STABLE NOT EXPECTED TO OCCUR. CLEAR, COLORLESS LIQUID WITH A SLIGHT ETHER -LIKE ODOR. HEAT, SPARKS, OPEN FLAME, OPEN CONTAINERS, AND POOR VENTILATION. • OXIDIZING AGENTS AND STRONG ACIDS AND BASES. INCOMPLETE COMBUSTION CAN GENERATE CARBON MONOXIDE AND OTHER TOXIC VAPORS. EXPLOSIVE PEROXIDES CAN FORM AFTER STANDING OR UPON EXPOSURE TO AIR OR DIRECT SUNLIGHT. FLASH POINT(TEST METHOD): 12 C(TAG CLOSED CUP) AUTO IGNITION TEMPERATURE: 180 C FLAMMABLE LIMITS IN AIR X BY VOLUME: LOWER LIMIT 1.97 UPPER LIMIT: 22.5 UNUSUAL FIRE AND EXPLOSION HAZARDS: VOLATILE AND FLAMMABLE. CAN FORM HEAT SENSITIVE PEROXIDES WHICH COULD EXPLODE DURING CONCENTRATION OR EVAPORATION. PAGE 1 EXTINGUISHING MEDIA: SPECIAL FIRE FIGHTING PROCEDURES: IV. HAZARDOUS COMPONENTS CARBON DIOXIDE, DRY CHEMICAL, ALCOHOL FOAM, WATER MIST OR FOG, WEAR FULL PROTECTIVE CLOTHING AND SELF - CONTAINED BREATHING APPARATUS. HEAT WILL BUILD PRESSURE AND MAY RUPTURE CLOSED STORAGE CONTAINERS. KEEP FIRE - EXPOSED CONTAINERS COOL WITH WATER SPRAY. 1,4- DIOXANE WT.X CA 100 TLV 25 PPM (SKIN) CAS NO. 123 -91 -1 V. HEALTH HAZARDS OCCUPATIONAL EXPOSURE LIMITS CONCENTRATION IMMEDIATELY DANGEROUS TO HEALTH OSHA TWA 25 PPM STEL NOT LISTED OSHA /NIOSH 2,000 CEILING NOT LISTED ODOR THRESHOLD ACGIH TLV -TWA 25 PPM (SKIN) TLV -STEL NOT LISTED NSC 150 PPM NIOSH 2.7 -170 PPM NIOSH TLV -TWA NOT LISTED 30- MIN.CEILING 1 PPM CARCINOGENIC DATA 1,4- DIOXANE IS LISTED AS A PROVEN ANIMAL CARCINOGEN BY IARC, AND NIP. 1,4- DIOXANE IS LISTED BY ACGIH AS A SUSPECT HUMAN CARCINOGEN. PRIMARY ROUTES OF ENTRY 1,4- DIOXANE MAY EXERT ITS EFFECTS THROUGH INHALATION, SKIN ABSORPTION, AND INGESTION. INDUSTRIAL EXPOSURE: ROUTE OF EXPOSURE /SIGNS AND SYMPTOMS INHALATION: EXPOSURE CAN CAUSE IRRITATION, HEADACHE, DIZZINESS, DROWSI- NESS, AND NAUSEA. 1,4-DIOXANE IS EASILY ABSORBED THROUGH LUNGS AND CAN CAUSE DAMAGE TO THE LIVER, KIDNEYS, AND CENTRAL NERVOUS SYSTEM. EYE CONTACT: LIQUID AND HIGH VAPOR CONCENTRATION CAN CAUSE IRRITATION. SKIN CONTACT: PROLONGED OR REPEATED SKIN CONTACT CAN CAUSE IRRITATION AND DERMATITIS THROUGH DEFATTING OF SKIN. ABSORPTION THROUGH THE SKIN CAN PRODUCE TOXIC EFFECTS, INGESTION: CAN CAUSE GASTROINTESTINAL TRACT DISCOMFORT, NAUSEA, AND BLOOD DISORDERS, EFFECTS OF OVEREXPOSURE 1,4- DIOXANE IS AN EYE AND MUCOUS MEMBRANE IRRITANT, PRIMARY SKIN IRRITANT, AND CENTRAL NERVOUS SYSTEM DEPRESSANT, NEPHROTOXIN, AND HEPATOTOXIN. ACUTE EXPOSURE CAUSES IRRITATION, HEADACHE, DIZZINESS, AND NARCOSIS. CHRONIC INHALATION EXPOSURE CAN PRODUCE DAMAGE TO THE LIVER AND KIDNEYS, AND BLOOD DISORDERS. PAGE 2 MEDICAL CONDITION AGGRAVATED BY EXPOSURE PRECLUDE FROM EXPOSURE THOSE INDIVIDUALS WITH DISEASE OF THE BLOOD, LIVER, KIDNEYS, CENTRAL NERVOUS SYSTEM, AND THOSE SUSCEPTIBLE TO DERMATITIS. EMERGENCY FIRST AID INHALATION: IMMEDIATELY REMOVE TO FRESH AIR. IF NOT BREATHING, ADMINISTER MOUTH -TO -MOUTH RESCUE BREATHING. IF THERE IS NO PULSE, ADMINISTER CARDIOPULMONARY RESUSCITATION (CPR). CONTACT PHYSICIAN IMMEDIATELY. EYE CONTACT: RINSE WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. GET EMERGENCY MEDICAL ASSISTANCE. SKIN CONTACT: FLUSH THOROUGHLY FOR AT LEAST 15 MINUTES. WASH AFFECTED SKIN WITH SOAP AND WATER, REMOVE CONTAMINATED CLOTHING AND SHOES. WASH CLOTHING BEFORE RE -USE, AND DISCARD CONTAMINATED SHOES. GET EMERGENCY MEDICAL ASSISTANCE. INGESTION: CALL. LOCAL POISON CONTROL CENTER FOR ASSISTANCE. CONTACT PHYSICIAN IMMEDIATELY. NEVER INDUCE VOMITING OR GIVE ANYTHING BY MOUTH TO A VICTIM UNCONSCIOUS OR HAVING CONVULSIONS. VI. SAFETY MEASURES AND EQUIPMENT VENTILATION: ADEQUATE VENTILATION IS REQUIRED TO PROTECT PERSONNEL FROM EXPOSURE TO CHEMICAL. VAPORS EXCEEDING THE PEL AND TO MINIMIZE FIRE HAZARDS. THE CHOICE OF VENTILATION EQUIPMENT, EITHER LOCAL OR GENERAL, WILL DEPEND ON THE CONDITIONS OF USE, QUANTITY OF MATERIAL, AND OTHER OPERATING PARAMETERS. RESPIRATORY: USE APPROVED RESPIRATOR EQUIPMENT. FOLLOW NIOSH AND EQUIPMENT MANUFACTURER'S RECOMMENDATIONS TO DETERMINE APPROPRIATE EQUIP- MENT (AIR - PURIFYING, AIR - SUPPLIED, OR SELF - CONTAINED BREATHING APPARATUS). EYES: SAFETY GLASSES ARE CONSIDERED MINIMUM PROTECTION. GOGGLES OR FACE SHIELD MAY BE NECESSARY DEPENDING ON QUANTITY OF MATERIAL AND CONDITIONS OF USE. SKIN: PROTECTIVE GLOVES AND CLOTHING ARE RECOMMENDED. THE CHOICE OF MATERIAL MUST BE BASED ON CHEMICAL RESISTANCE AND OTHER USER REQUIREMENTS.. GENERALLY, NEOPRENE OFFERS ACCEPTABLE CHEMICAL RESISTANCE. INDIVIDUALS WHO ARE ACUTELY AND SPECIFICALLY SENSITIVE TO 1,4- DIOXANE MAY REQUIRE ADDITIONAL PROTECTIVE EQUIPMENT. PAGE 3 STORAGE: OTHER: 1,4- DIOXANE SHOULD BE PROTECTED FROM TEMPERATURE EXTREMES AND DIRECT SUNLIGHT. PROPER STORAGE OF 1,4- DIOXANE MUST BE DETERMINED BASED ON OTHER MATERIALS STORED AND THEIR HAZARDS AND POTENTIAL CHEMICAL INCOMPATIBILITY. IN GENERAL, 1,4- DIOXANE SHOULD BE STORED IN AN ACCEPTABLY PROTECTED AND SECURE FLAMMABLE LIQUID STORAGE ROOM. CHECK PERIODICALLY FOR PEROXIDES IN STORED MATERIAL AND PRIOR TO USE, ESPECIALLY • BEFORE CONCENTRATING OR HEATING. DO NOT OPEN CONTAINER IF PEROXIDE CRYSTALS FORM IN LIQUID OR AROUND CLOSURE, DO NOT CONCENTRATE IF PEROXIDE CONCENTRATIONS EXCEED 0.01% OR 100 PPM. CONTACT'THE MANUFACTURER FOR APPROPRIATE PEROXIDE TREATMENT AND HANDLING METHODS. EMERGENCY EYEWASH FOUNTAINS AND SAFETY SHOWERS SHOULD BE AVAILABLE IN THE VICINITY OF ANY POTENTIAL EXPOSURE. GROUND AND BOND METAL CONTAINERS TO MINIMIZE STATIC SPARKS. VII. SPILL AND DISPOSAL DATA SPILL CONTROL: PROTECT FROM IGNITION. WEAR PROTECTIVE CLOTHING AND USE APPROVED RESPIRATOR EQUIPMENT. ADSORB SPILLED MATERIAL IN AN ABSORBENT RECOMMENDED FOR SOLVENT SPILLS AND REMOVE TO A SAFE LOCATION FOR DISPOSAL BY APPROVED METHODS. IF RELEASED TO THE ENVIRONMENT, COMPLY WITH ALL REGULATORY NOTIFICATION REQUIRE- MENTS. CERCLA REPORTABLE QUANTITY: 100 POUNDS. WASTE DISPOSAL: DISPOSE OF 1,4- DIOXANE AS AN EPA HAZARDOUS WASTE. CONTACT STATE ENVIRONMENTAL_ AGENCY FOR LISTING OF LICENSED HAZARDOUS WASTE DISPOSAL FACILITIES AND APPLICABLE REGULATIONS. HAZARDOUS WASTE NUMBER: 0108 (TOXIC); D001 (IGNITABLE). VIII. SARA /TITLE III DATA HAZARD CLASSIFICATION CHEMICAL LISTINGS IMMEDIATE HEALTH: YES (IRRITANT) EXTREMELY HAZARDOUS SUBSTANCES: NO DELAYED HEALTH: YES CERCLA HAZARDOUS SUBSTANCES: YES FIRE: YES TOXIC CHEMICALS: YES SUDDEN RELEASE: NO REACTIVE: NO 1,4- DIOXANE IS SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA) AND 40CFR PART 372. THIS PRODUCT DOES NOT CONTAIN ANY OTHER TOXIC CHEMICAL ABOVE 1% CONCENTRATION OR A CARCINOGEN ABOVE 0.1% CONCENTRATION. KEY CA APPROXIMATELY NA NOT APPLICABLE C CEILING STEL SHORT TERM EXPOSURE LEVEL (15 MINUTES) TLV THRESHOLD LIMIT VALUE TWA TIME WEIGHTED AVERAGE BUAC BUTYL ACETATE CERCLA COMPREHENSIVE ENVIRONMENTAL_ RESPONSE, COMPENSATION AND LIABILITY ACT OF 1980 MSC NATIONAL SAFETY COUNCIL ( "FUNDAMENTALS OF INDUSTRIAL HYGIENE," 3RD ED., 1988) PAGE 4 BURDICK & JACKSON'S DISCLAIMER: THE INFORMATION AND RECOMMENDATIONS PRESENTED .'IN THIS MATERIAL SAFETY DATA SHEET ARE BASED ON SOURCES BELIEVED TO BE RELIABLE ON THE DATE HEREOF. BURDICK & JACKSON MAKES NO REPRESENTATION ON ITS COMPLET €NESS OR ACCURACY. IT IS THE USER'S RESPONSIBILITY TO DETERMINE THE _:.. PRODUCT S SUITABILITY FOR ITS INTENDED USE, THE PRODUCT'S SAFE USE, AND THE . PRODUCT'S PROPER DISPOSAL. NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR OF ANY OTHER NATURE ARE MADE WITH RESPECT TO THE INFORMATION PROVIDED IN THIS MATERIAL SAFETY DATA SHEET OR TO THE PRODUCT TO WHICH SUCH INFORMATION REFERS. BURDICK & JACKSON NEITHER ASSUMES NOR AUTHORIZES ANY OTHER PERSON TO ASSUME FOR IT, ANY OTHER OR ADDITIONAL LIABILITY OR RESPONSIBILITY RESULTING FROM THE USE OF, OR RELIANCE UPON, THIS INFORMATION. PAGE 5 (LAST PAGE) "ISSUED BY VWR 07/09/98" BURDICK & JACKSON, INC. 1953 SOUTH HARVEY STREET MUSKEGON, MI 49442 USA MATERIAL SAFETY DATA SHEET INFORMATION /EMERGENCY TELEPHONE NUMBER CHEMTREC TELEPHONE NUMBER CANADIAN EMERGENCY TELEPHONE NUMBER I. IDENTIFICATION CHEMICAL NAME: CHEMICAL FAMILY: SYNONYMS: DOT PROPER SHIPPING NAME: DOT HAZARD CLASS: DOT IDENTIFICATION NUMBER: II. PHYSICAL AND CHEMICAL DATA BOILING POINT, 760 MM HG: VAPOR PRESSURE AT 20 C: X VOLATILES BY VOLUME: FREEZING POINT: VAPOR DENSITY: SPECIFIC GRAVITY (H20 =1): EVAPORATION RATE: SOLUBIL.ITY IN WATER: STABILITY: HAZARDOUS POLYMERIZATION: APPEARANCE AND ODOR: CONDITIONS TO AVOID: MATERIALS TO AVOID: HAZARDOUS DECOMPOSITION PRODUCTS: III. FIRE AND EXPLOSION HAZARD DATA ACETONE REVISION DATE: DECEMBER, 1993 REVISION NO: 1 616.726.3171 800.424.9300 613.996.6666 ACETONE MOLECULAR WEIGHT: 58.08 KETONE FORMULA: C3H60 DIMETHYL KETONE ACETONE FLAMMABLE LIQUID, HAZARD CLASS 3, P.G. II UN1090 CAS NUMBER; 67 -64 -1 56.29 C 184.5 MM HG CA 100 -94.7 2.0 C� 20 C 0.79 (BUAC =1) CA 12 • 2Q C COMPLETE STABLE NOT EXPECTED TO OCCUR. CLEAR, COLORLESS LIQUID WITH A PENETRATING, SWEET ODOR. HEAT, SPARKS, OPEN FLAME, OPEN CONTAINERS, AND POOR VENTILATION. STRONG OXIDIZING AGENTS AND STRONG ACIDS AND BASES. INCOMPLETE COMBUSTION CAN GENERATE CARBON MONOXIDE AND OTHER TOXIC VAPORS. FLASH POINT (TEST METHOD): -18 C (TAG CLOSED CUP) AUTO IGNITION TEMPERATURE: 465 C FLAMMABLE LIMITS IN AIR % BY VOLUME: LOUER LIMIT .2.6 UPPER LIMIT: 12.8 UNUSUAL FIRE AND EXPLOSION HAZARDS: VERY VOLATILE AND EXTREMELY FLAMMABLE; MIXTURES WITH WATER CAN BE FLAMMABLE FXTTNr,IITRNTtIR MrilTA! rnpprm nrnwrnr- nry rurMrrnr Al rnrrrn SPECIAL FIRE FIGHTING PROCEDURES: IV. HAZARDOUS COMPONENTS ...ETONE WT. X CA 100 V. HEALTH HAZARDS OCCUPATIONAL EXPOSURE LIMITS OSHA TWA 750 PPM STEL 1,000 PPM CEILING NOT LISTED ACGIH TLV -TWA 750 PPM TLV -STEL 1,000 PPM NIOSH 10 -HOUR TWA 250 PPM CARCINOGENIC DATA ACETONE IS NOT LISTED AS A CARCINOGEN BY IARC, NTt', OSHA, OR ACGIH. PRIMARY ROUTES OF ENTRY ACETONE MAY EXERT ITS EFFECTS THROUGH INHALATION, SKIN ABSORPTION, AND INGESTION. EYE CONTACT: SKIN CONTACT: INGESTION: WEAR FULLY PROTECTIVE CLOTHING AND SELF- CONTAINED BREATHING APPARATUS. HEAT WILL BUILD PRESSURE AND MAY RUPTURE CLOSED STORAGE CONTAINERS. KEEP FIRE - EXPOSED CONTAINERS COOL WITH WATER SPRAY. PAGE 2 TLV 750 PPM CAS NO, 67 -64 -1 CONCENTRATION IMMEDIATELY DANGEROUS TO HEALTH OSHA /NIOSH 20,000 PPM ODOR THRESHOLD NSC NIOSH INDUSTRIAL EXPOSURE: ROUTE OF EXPOSURE /SIGNS AND SYMPTOMS INHALATION: EXPOSURE CAN CAUSE EYE, NOSE, AND THROAT IRRITATION, HEADACHE, NAUSEA, DIZZINESS AND NARCOSIS. LIQUID ANO HIGH VAPOR CONCENTRATION CAN CAUSE IRRITATION. PROLONGED OR REPEATED SKIN CONTACT CAN CAUSE IRRITATION AND DERMATITIS THROUGH DEFATTING OF SKIN. SYMPTOM INFORMATION IS INADEQUATE /UNKNOWN. 2 PPM NOT LISTED EFFECTS OF OVEREXPOSURE ACETONE IS A MILD EYE AND MUCOUS MEMBRANE IRRITANT, PRIMARY SKIN IRRITANT, AND CENTRAL NERVOUS SYSTEM DEPRESSANT. ACUTE EXPOSURE IRRITATES THE EYES AND UPPER RESPIRATORY TRACT. DIRECT SKIN CONTACT PRODUCES DERMATITIS „CHARACTERIZED BY DRYNESS AND ERYTHEMA. HIGH CONCENTRATIONS PRODUCE NARCOSIS AND HYPOGLYCEMIA. MEDICAL CONDITION AGGRAVATED BY EXPOSURE PRECLUDE FROM EXPOSURE THOSE INDIVIDUALS SUSCEPTIBLE TO DERMATITIS. EMERGENCY FIRST AID INHALATION: IMMEDIATELY REMOVE TO FRESH AIR, IF NOT BREATHING, ADMINISTER MOUTH -TO -MOUTH RESCUE BREATHING. IF THERE IS NO PULSE, ADMINISTER CARDIOPULMONARY RESUSCITATION (CPR). CONTACT PHYSICIAN IMMEDIATELY. EYE CONTACT: SKIN CONTACT: INGESTION: VI. SAFETY MEASURES AND EQUIPMENT VENTILATION: RESPIRATORY: EYES: SKIN: STORAGE: OTHER: VII. SPILL AND DISPOSAL DATA SPILL CONTROL: RINSE WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. GET EMERGENCY MEDICAL ASSISTANCE. FLUSH THOROUGHLY FOR AT LEAST 15 MINUTES. WASH AFFECTED SKIN WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND SHOES. WASH CLOTHING BEFORE RE -USE, AND DISCARD CONTAMINATED SHOES. GET EMERGENCY MEDICAL ASSISTANCE. CALL LOCAL POISON CONTROL CENTER FOR ASSISTANCE. CONTACT PHYSICIAN IMMEDIATELY. NEVER INDUCE VOMITING OR GIVE ANYTHING BY MOUTH TO A VICTIM UNCONSCIOUS OR HAVING CONVULSIONS. ADEQUATE VENTILATION IS REQUIRED TO PROTECT PERSONNEL FROM EXPOSURE TO CHEMICAL VAPORS EXCEEDING THE PEL AND TO MINIMIZE FIRE HAZARDS. THE CHOICE OF VENTILATION EQUIPMENT, EITHER LOCAL OR GENERAL, WILL DEPEND ON THE CONDITIONS OF USE, QUANTITY OR MATERIAL, AND OTHER OPERATING PARAMETERS. USE APPROVED RESPIRATOR EQUIPMENT. FOLLOW NIOSH AND EQUIPMENT MANUFACTURER'S RECOMMENDATIONS TO DETERMINE APPROPRIATE EQUIPMENT (AIR- PURIFYING, AIR - SUPPLIED, OR SELF- CONTAINED BREATHING APPARATUS). SAFETY GLASSES ARE CONSIDERED MINIMUM PROTECTION. GOGGLES OR FACE SHIELD MAY BE NECESSARY DEPENDING ON QUANTITY OF MATERIAL AND CONDITIONS OF USE. PROTECTIVE GLOVES AND CLOTHING ARE RECOMMENDED. THE CHOICE OF MATERIAL MUST BE BASED ON CHEMICAL. RESISTANCE AND OTHER USER REQUIREMENTS. GENERALLY, NEOPRENE OR RUBBER OFFERS ACCEPTABLE CHEMICAL RESISTANCE. INDIVIDUALS WHO ARE ACUTELY AND SPECIFICALLY SENSITIVE TO ACETONE MAY REQUIRE ADDITIONAL PROTECTIVE EQUIPMENT. ACETONE SHOULD BE PROTECTED FROM TEMPERATURE EXTREMES AND DIRECT SUNLIGHT. PROPER STORAGE or A CETONE MUST RE DETERMINED BASED ON OTHER MATERIALS STORED AND THEIR HAZARDS AND POTENTIAL CHEMICAL INCOMPATIBILITY. IN GENERAL, ACETONE SHOULD BE STORED IN AN ACCEPTABLY PROTECTED AND SECURE FLAMMABLE LIQUID STORAGE ROOM. EMERGENCY EYEWASH FOUNTAINS AND SAFETY SHOWERS SHOULD BE AVAILABLE IN THE VICINITY OF ANY POTENTIAL QXPOSURE. GROUND AND BOND METAL CONTAINERS TO MINIMIZE STATIC SPARKS. PROTECT FROM IGNITION. WEAR PROTECTIVE CLOTHING AND USE APPROVED RESPIRATOR EQUIPMENT. ABSORB SPILLED MATERIAL IN AN ABSORBENT RECOMMENDED FOR SOLVENT SPILLS AND REMOVE TO A SAFE LOCATION FOR DISPOSAL BY APPROVED METHODS. IF RELEASED TO THE ENVIRONMENT, COMPLY WITH ALL REGULATORY NOTIFICATION REQUIREMENTS. CERCLA REPORTABLE QUANTITY: 5,000 POUNDS. PAGE 3 • e WASTE DISPOSAL: DISPOSE OF ACETONE AS AN EPA HAZARDOUS WASTE. CONTACT STATE ENVIRONMENTAL AGENCY FOR LISTING OF LICENSED HAZARDOUS WASTE DISPOSAL FACILITIES AND APPLICABLE REGULATIONS. HAZARDOUS WASTE NUMBER: 0003 (IGNITABLE, TOXIC); 0001 (IGNITABLE). HAZARD CLASSIFICATION CHEMICAL LISTINGS IMMEDIATE HEALTH: YES (IRRITANT) EXTREMELY HAZARDOUS SUBSTANCES: NO DELAYED HEALTH: NO CERCLA HAZARDOUS SUBSTANCES: YES FIRE: YES TOXIC CHEMICALS: YES SUDDEN RELEASE: NO REACTIVE: NO ACETONE IS SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA) AND 40CFR PART 372. THIS PRODUCT DOES NOT CONTAIN ANY OTHER TOXIC CHEMICAL ABOVE 1% CONCENTRATION OR A CARCINOGEN ABOVE 0.1X CONCENTRATION. KEY CA APPROXIMATELY STEL. SHORT TERM EXPOSURE LEVEL (15 MINUTES) NA NOT APPLICABLE TLV THRESHOLD LIMIT VALUE C CEILING TWA TIME WEIGHTCD AVERAGE BUAC BUTYL ACETATE CERCLA COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION AND LIABILITY ACT OF 1980 NSC NATIONAL SAFETY COUNCIL ( "FUNDAMENTALS OF INDUSTRIAL_ HYGIENE," 3RD ED., 1988) BURDICK & JACKSON'S DISCLAIMER: THE INFORMATION AND RECOMMENDATIONS PRESENTED IN THIS MATERIAL SAFETY DATA SHEET ARE BASED ON SOURCES BELIEVED TO BE RELIABLE ON THE DATE HEREOF. BURDICK & JACKSON MAKES NO REPRESENTATION ON ITS COMPLETENESS OR ACCURACY. IT IS THE USER'S RESPONSIBILITY TO DETERMINE THE PRODUCT'S SUITABILITY FOR ITS INTENDCD USE, THE PRODUCT'S SAFE USE, AND THE PRODUCT'S PROPER DISPOSAL. NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR OF ANY OTHER NATURE ARE MADE WITH RESPECT TO THE INFORMATION PROVIDED IN THIS MATERIAL SAFETY DATA SHEET OR TO THE PRODUCT TO WHICH SUCH INFORMATION REFERS. BURDICK & JACKSON NEITHER ASSUMES NOR AIJTHORIZES ANY OTHER PERSON TO ASSUME FOR IT, ANY OTHER OR ADDITIONAL. LIABILITY OR RESPONSIBILITY RESULTING FROM THE USE OF, OR RELIANCE UPON, THIS INFORMATION. PAGE 4 (LAST PAGE) • "ISSUED BY VWR 07/09/98" BURDICK & JACKSON, INC. 1953 SOUTH HARVEY STREET MUSKEGON, MI 49442 USA INFORMATION /EMERGENCY TELEPHONE NUMBER 616.72.6.3171 CHEMTREC TELEPHONE NUMBER 800.424.9300 CANADIAN EMERGENCY TELEPHONE NUMBER 613.996.6666 I. IDENTIFICATION CHEMICAL NAME CHEMICAL FAMILY SYNONYMS DOT PROPER SHIPPING NAME DOT HAZARD CLASS DOT IDENTIFICATION NUMBER II. PHYSICAL AND CHEMICAL DATA BOILING POINT, 760MM HG VAPOR PRESSURE AT 20 C X VOLATILES BY VOLUME FREEZING POINT VAPOR DENSITY (AIR =1) SPECIFIC GRAVITY (H20 =1) EVAPORATION RATE (BUAC =1) SOLUBILITY IN WATER STABILITY HAZARDOUS POLYMERIZATION 81.6 C 72.8 MM HG CA 100 -43.8 C 1.4 O 20 C 0.78 CA 5 20 C COMPLETE STABLE NOT EXPECTED TO OCCUR MATERIAL SArETY DATA SHEET ACETONITRILE REVISION DATE: DECEMBER, 1993 REVISION NO. 1 ACETONITRILE MOLECULAR WEIGHT 41.05 NITRILE FORMULA C2H3N METHYL CYANIDE, CYANOMETHANE ACETONITRILE FLAMMABLE LIQUID, HAZARD CLASS 3; P.G. II UN1648 CAS NUMBER 75 -05 -8 APPEARANCE AND ODOR CLEAR, COLORLESS LIQUID WITH A SWEET, ETHER -LIKE ODOR CONDITIONS TO AVOID HEAT, SPARKS, OPEN FLAME, OPEN CONTAINERS, AND POOR VENTILATION MATERIALS TO AVOID HAZARDOUS DECOMPOSITION PRODUCTS III. FIRE AND EXPLOSION HAZARD DATA FLASH POINT (TEST METHOD) 5.6 C (CLOSED CUP) AUTO IGNITION:TEMPERATURE 524 C FLAMMABLE LIMITS IN AIR X BY VOLUME: LOWER LIMIT 3.0 UPPER LIMIT 16.0 UNUSUAL FIRE AND EXPLOSION HAZARDS VERY VOLATILE AND EXTREMELY FLAMMABLE EXTINGUISHING MEDIA CARBON DIOXIDE, DRY CHEMICAL, ALCOHOL FOAM, WATER MIST OR FOG SPECIAL FIRE FIGHTING PROCEDURES WEAR FULL PROTECTIVE CLOTHING AND SELF - CONTAINED BREATHING APPARATUS. HEAT WILL BUILD PRESSURE AND RUPTURE CLOSED STORAGE CONTAINERS. WATER SPRAY MAY BE INEF- FECTIVE DIRECTLY ON FIRE, BUT SHOULD BE USED TO COOL FIRE - EXPOSED CONTAINERS. PAGE 1 IV. HAZARDOUS COMPONENTS ACETONITRILE (METHYL CYANIDE) CA 100 TLV 40 PPM (SKIN) CAS NO. 75 -05 -8 -V. HEALTH HAZARDS OCCUPATIONAL EXPOSURE LIMITS OSHA TWA 40 PPM STEL 60 PPM CEILING - MOT LISTED ACGIH ODOR THRESHOLD TLV -TWA 40 PPM (SKIN) TLV -STEL. 60 PPM (SKIN) NSC NOT LISTED NIOSH 40 PPM NIOSH 10 -HOUR TWA 20 PPM CONCENTRATION IMMEDIATELY DANGEROUS TO HEALTH OSHA / NIOSH 4,000 PPM CARCINOGENIC DATA ACETONITRILE IS NOT LISTED AS A CARCINOGENIC BY IARC, NTP, OSHA, OR ACGIH. ANIMAL TESTS HAVE INDICATED TERATOGENIC EFFECTS. RTEC REPORTS TERATOGENIC EFFECTS IN ANIMALS. PRIMARY ROUTES OF ENTRY ACETONITRILE MAY EXERT ITS EFFECTS THROUGH INHALATION, SKIN ABSORPTION, AND INGESTION. INDUSTRIAL EXPOSURE: ROUTE OF EXPOSURE /SIGNS AND SYMPTOMS INHALATION: EXPOSURE CAN CAUSE HEADACHE, WEAKNESS, NAUSEA, REDUCED PULSE RATE AND BLOOD PRESSURE, PALE OR ASHEN SKIN, SUBNORMAL TEMPER- ATURE, SHALLOW RESPIRATION, CONVULSION, COLLAPSE, AND DEATH AT HIGH CONCENTRATIONS. EYE CONTACT: SKIN CONTACT: INGESTION: LIQUID AND HIGH VAPOR CONCENTRATION CAN CAUSE IRRITATION. CAN CAUSE IRRITATION AND THE SAME SYSTEMIC SYMPTOMS AS INHALATION. SWALLOWING MORE THAN 2 OUNCES OF ACETONITRILE CAN HAVE AN ADVERSE EFFECT ON THE CENTRAL NERVOUS SYSTEM. EFFECTS OF OVEREXPOSURE ACETONITRILE IS AN IRRITANT AND A CHEMICAL ASPHYXIANT. ACUTE EXPOSURE THROUGH INHALATION, INGESTION, OR SKIN ABSORPTION CAUSES DIZZINESS, HEADACHE, VOMITING, DROWSINESS, CHEST PAIN, UNCONSCIOUSNESS, SHOCK, AND DEATH. SEVERAL HOURS MAY ELAPSE BETWEEN EXPOSURE AND INITIATION OF SYMPTOMS, DUE TO SLOW RELEASE OF CYANIDE. CHRONIC EXPOSURES CAN PRODUCE DAMAGE TO THE LIVER AND KIDNEYS. MEDICAL CONDITION AGGRAVATED BY EXPOSURE PRECLUDE FROM EXPOSURE THOSE INDIVIDUALS WITH DISEASE OF LIVER, KIDNEYS, SKIN, AND CENTRAL NERVOUS SYSTEM. EMERGENCY FIRST AID INHALATION: IMMEDIATELY REMOVE TO FRESH AIR. IF NOT BREATHING, ADMINISTER MOUTH -TO -MOUTH RESCUE BREATHING. IF THERE IS NO PULSE, ADMINISTER CARDIOPULMONARY RESUSCITATION (CPR). CONTACT PHYSICIAN IMMEDIATELY. PAGE 2 EYE CONTACT: RINSE WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. GET EMERGENCY MEDICAL ASSISTANCE. SKIN CONTACT: FLUSH THOROUGHLY FOR AT LEAST 15 MINUTES. WASH AFFECTED SKIN WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND SHOES. WASH CLOTHING BEFORE RE -USE, AND DISCARD CONTAMINATED SHOES. GET EMERGENCY MEDICAL ASSISTANCE. INGESTION: CALL LOCAL POISON CONTROL CENTER FOR ASSISTANCE. CONTACT PHYSICIAN IMMEDIATELY. NEVER INDUCE VOMITING OR GIVE ANYTHING BY MOUTH TO A VICTIM UNCONSCIOUS OR HAVING CONVULSIONS. NOTE TO PHYSICIAN MAXIMUM ACUTE EFFECTS MAY BE DELAYED SEVERAL HOURS. ANY EXPOSED PERSON SHOULD BE KEPT UNDER SURVEILLANCE. FOR SEVERE EXPOSURE, TREAT AS CYANIDE POISONING. VI. SAFETY MEASURES AND EQUIPMENT VENTILATION; ADEQUATE VENTILATION IS REQUIRED TO PROTECT PERSONNEL FROM EXPOSURE TO CHEMICAL VAPORS EXCEEDING THE PEL AND TO MINIMIZE FIRE HAZARDS. THE CHOICE OF VENTILATION EQUIPMENT, EITHER LOCAL OR GENERAL, WILL DEPEND ON THE CONDITIONS OF USE, QUANTITY OR MATERIAL, AND OTHER OPERATING PARAMETERS. RESPIRATORY: USE APPROVED RESPIRATOR EQUIPMENT. FOLLOW NIOSH AND EQUIPMENT MANUFACTURER'S RECOMMENDATIONS TO DETERMINE APPROPRIATE EQUIP- MENT (AIR - PURIFYING, AIR - SUPPLIED, OR SELF - CONTAINED BREATHING APPARATUS). EYES: SAFETY GLASSES ARE CONSIDERED MINIMUM PROTECTION. GOGGLES OR FACE SHIELD MAY BE NECESSARY DEPENDING ON QUANTITY OF MATERIAL AND CONDITIONS OF USE. SKIN: PROTECTIVE GLOVES AND CLOTHING ARE RECOMMENDED. THE CHOICE OF MATERIAL MUST BE BASED ON CHEMICAL RESISTANCE AND OTHER USER REQUIREMENTS. GENERALLY, NEOPRENE OR RUBBER OFFERS ACCEPTABLE CHEMICAL RESISTANCE. INDIVIDUALS WHO ARE ACUTELY AND SPECI- FICALLY SENSITIVE TO ACETONITRILE MAY REQUIRE ADDITIONAL PROTECTIVE EQUIPMENT. STORAGE: OTHER: ACETONITRILE SHOULD BE PROTECTED FROM TEMPERATURE EXTREMES AND DIRECT SUNLIGHT. PROPER STORAGE OF ACETONITRILE MUST BE DETERMINED BASED ON OTHER MATERIALS STORED AND THEIR HAZARDS AND POTENTIAL CHEMICAL INCOMPATIBILITY. IN GENERAL, ACETONI- TRILE SHOULD BE STORED IN AN ACCEPTABLY PROTECTED AND SECURE FLAMMABLE LIQUID STORAGE ROOM. EMERGENCY EYEWASH FOUNTAINS AND SAFETY SHOWERS SHOULD BE AVAILABLE IN THE VICINITY OF ANY POTENTIAL EXPOSURE. GROUND AND BOND METAL CONTAINERS TO MINIMIZE STATIC SPARKS. PAGE 3 VII. SPILL AND DISPOSAL DATA SPILL CONTROL: PROTECT FROM IGNITION. WEAR PROTECTIVE CLOTHING AND USE APPROVED RESPIRATOR EQUIPMENT. ABSORB SPILLED MATERIAL IN AN ABSORBENT RECOHENDED FOR SOLVENT SPILLS AND REMOVE TO A SAFE LOCATION FOR DISPOSAL BY APPROVED METHODS. IF RELEASED TO THE ENVIRONMENT, COMPLY WITH ALL REGULATORY NOTIFICATION REQUIRE- MENTS. CERCLA REPORTABLE QUANTITY: 5000 POUNDS WASTE DISPOSAL: DISPOSE OF ACETONITRILE AS AN EPA HAZARDOUS WASTE. CONTACT STATE ENVIRONMENTAL AGENCY FOR LISTING OF LICENSED HAZARDOUS WASTE DISPOSAL FACILITIES AND APPLICABLE REGULATIONS. HAZARDOUS WASTE NUMBER: U003 (IGNITABLE, TOXIC): 0001 (IGNITABLE). HAZARD CLASSIFICATION CHEMICAL LISTINGS IMMEDIATE HEALTH YES EXTREMELY HAZARDOUS SUBSTANCES NO DELAYED HEALTH YES CERCLA HAZARDOUS SUBSTANCES YES FIRE YES TOXIC CHEMICALS YES SUDDEN RELEASE NO REACTIVE NO ACETONITRILE IS SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 19136 (SARA) AND 40CFR PART 372. THIS PRODUCT DOES NOT CONTAIN ANY OTHER TOXIC CHEMICAL ABOVE IX CONCENTRATION OR A CARCINOGEN ABOVE 0.1X CONCENTRATION. KEY .. CA APPROXIMATELY NA NOT APPLICABLE C CEILING STEL SHORT TERM EXPOSURE LEVEL (15 MINUTES) TLV THRESHOLD LIMIT VALUE TVA TIME WEIGHTED AVERAGE BUAC BUTYL ACETATE CERCLA COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION AND LIABILITY ACT OF 1980 NSC NATIONAL SAFETY COUNCIL ( "FUNDAMENTALS OF INDUSTRIAL_ HYGIENE," 3RD ED., 1988 BURDICK & JACKSON'S DISCLAIMER: THE INFORMATION AND RECOMMENDATIONS PRESENTED IN THIS MATERIAL SAFETY DATA SHEET ARE BASED ON SOURCES BELIEVED TO BE RELIABLE ON THE DATE HEREOF. BURDICK & JACKSON MAKES NO REPRESENTATION ON ITS COMPLETENESS OR ACCURACY. IT. IS THE USER'S RESPONSIBILITY TO DETERMINE THE PRODUCT'S SUITABILITY FOR IM INTENDED USE, THE PRODUCT'S SAFE USE, AND THE PRODUCT'S PROPER DISPOSAL. NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESSED OR IMPLIED, OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR ANY OTHER NATURE ARE MADE WITH RESPECT TO THE INFORMATION PROVIDED IN THIS MATERIAL SAFETY DATA SHEET OR TO THE PRODUCT TO WHICH SUCH INFORMATION REFERS. BURDICK & JACKSON NEITHER ASSUMES NO AUTHORIZES ANY OTHER PERSON TO ASSUME FOR IT, ANY OTHER OR ADDITIONAL LIABILITY OR RESPONSIBILITY RESULTING FROM THE USE OF, OR RELIANCE UPON, THIS INFORMATION. PAGE 4 (LAST PAGE) "ISSUED BY VLJR 07/09/98" 11. CHEMICAL PRODUCT AND COMPANY MANUFACTURER EM SCIENCE A DIVISION OF EM INDUSTRIES P.O. BOX 70 480 DEMOCRAT RD. GIBBSTOWN, N.J. 08027 CATALOG NUMBER(S): AX0441 AX044tT AX0445 PRODUCT NAME ALCOHOL, REAGENT, ANHYDROUS SYNONYMS ETHYL ALCOHOL; DENATURED ALCOHOL CHEMICAL FAMILY : ALIPHATIC ALCOHOL FORMULA C2H5OH MOLECULAR WEIGHT.: 46.07 ETHYL ALCOHOL METHANOL ISO - PROPYL ALCOHOL MATERIAL SAFETY DATA SHEET EM SCIENCE IDENTIFICATION 2. COMPOSITION / INFORMATION ON INGREDIENTS COMPONENT CAS 4 PREPARATION DATE.: 04/05/95 DATE MSDS PRINTED.: OCT 19, 1995 INFORMATION PHONE NUMBER.: 609 - 423 -6300 HOURS: MON. TO FRI. 8:30 -5 CHEMTREC EMERGENCY NUMBER: 800-424-9300 HOURS: 24 HRS A DAY 64 -17 -5 67 -56 -1 67 -63-0 13, HAZARDS IDENTIFICATION EMERGENCY OVERVIEW FLAMMABLE LIQUID AND VAPOR. VAPOR HARMFUL. MAY BE FATAL OR CAUSE BLINDNESS IF SWALLOWED. CANNOT BE MADE NON - POISONOUS. MAY CAUSE DAMAGE TO LIVER, KIDNEYS, GASTROINTESTINAL TRACT AND CARDIOVASCULAR SYSTEM. MSDS (CONTINUED) - AX0441 PAGE 4 1 APPR Y 90% 5% 5% APPEARANCE COLORLESS LIQUID, CHARACTERISTIC ODOR POTENTIAL HEALTH EFFECTS (ACUTE AND CHRONIC) SYMPTOMS OF EXPOSURE: CAN BE FATAL OR CAUSE BLINDNESS IF SWALLOWED IN QUANTITY. CAUSES HEADACHE, NAUSEA, DIZZINESS, NARCOSIS. CHRONIC OVEREXPOSURE'(INHAL.AT]ON OR INGESTION) CAN CAUSE DAMAGE TO GASTROINTESTINAL TRACT, LIVER, KIDNEYS AND CARDIOVASCULAR SYSTEM. PROLONGED CONTACT CAUSES IRRITATION TO SKIN AND EYES. MEDICAL COND. AGGRAVATED BY EXPOSURE: KIDNEY, LIVER, HEART AND GI CONDITIONS. ROUTES OF ENTRY....... ..... ... : INHALATION, INGESTION SKIN CONTACT. CARCINOGENICITY..... .. � . � .... ... : THE MATERIAL IS NOT LISTED (IARC, NTP, OSHA) AS CANCER CAUSING AGENT. 4. FIRST AID MEASURES EMERGENCY FIRST AID: GET MEDICAL ASSISTANCE FOR ALL CASES OF OVEREXPOSURE. SKIN: WASH THOROUGHLY WITH SOAP AND WATER. EYES: IMMEDIATELY FLUSH THOROUGHLY WITH WATER FOR AT LEAST 15 MINUTES. INHALATION: REMOVE TO FRESH AIR; GIVE ARTIFICIAL RESPIRATION IF BREATHING HAS STOPPED. INGESTION: IF CONSCIOUS, DRINK WATER AND INDUCE VOMITING IMMEDIATELY AS DIRECTED BY MEDICAL PERSONNEL. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. 5. FIRE FIGHTING MEASURES FLASH POINT (F) 54F (CC) FLAMMABLE LIMITS LEL (X).: 3'.30 FLAMMABLE LIMITS UEL (X).: 19.00 EXTINGUISHING MEDIA ALCOHOL" FOAM, CO2, DRY CHEMICAL FIRE FIGHTING PROCEDURES. WEAR SELF - CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING, FIRE & EXPLOSION HAZARDS.: VAPOR CAN TRAVEL DISTANCES TO IGNITION SOURCE AND FLASH BACK. 6. ACCIDENTAL RELEASE MEASURES MSDS (CONTINUED) - AX0441 PAGE # 2 ' SPILL RESPONSE: EVACUATE THE AREA OF ALL UNNECESSARY PERSONNEL. WEAR SUITABLE PROTECTIVE EQUIPMENT LISTED UNDER EXPOSURE / PERSONAL PROTECTION. • ELIMINATE ANY IGNITION SOURCES UNTIL THE AREA IS DETERMINED TO BE ' FREE FROM EXPLOSION OR FIRE HAZARDS. CONTAIN THE RELEASE AND ELIMINATE ITS SOURCE, IF THIS CAN BE DONE WITHOUT RISK. TAKE UP AND CONTAINERIZE FOR PROPER DISPOSAL AS DESCRIBED UNDER DISPOSAL. COMPLY WITH FEDERAL,' STATE, AND LOCAL REGULATIONS ON REPORTING RELEASES. REFER TO REGULATORY INFORMATION FOR REPORTABLE QUANTITY AND OTHER REGULATORY DATA. EM SCIENCE RECOMMENDS SPILL —X ABSORBENT AGENTS FOR VARIOUS TYPES OF SPILLS. ADDITIONAL INFORMATION ON THE SPILL —X PRODUCTS CAN BE PROVIDED THROUGH THE EM SCIENCE TECHNICAL SERVICE DEPARTMENT (609) 354 -9200. THE FOLLOWING EM SCIENCE SPILL —X ABSORBENT IS RECOMMENDED FOR THIS PRODUCT: SX0863 SOLVENT SPILL TREATMENT KIT 7. HANDLING AND STORAGE HANDLING & STORAGE: KEEP CONTAINER CLOSED. STORE IN A COOL AREA AWAY FROM IGNITION SOURCES AND OXIDIZERS. DO NOT BREATHE VAPOR. DO NOT GET IN EYES. AVOID PROLONGED, OR REPEATED, SKIN CONTACT. ELECTRICALLY GROUND ALL EQUIPMENT WHEN HANDLING THIS PRODUCT. RETAINED RESIDUE MAY MAKE EMPTY CONTAINERS HAZARDOUS; USE CAUTION! 8. EXPOSURE CONTROLS / PERSONAL PROTECTION ENGINEERING CONTROLS AND PERSONAL PROTECTIVE EQUIPMENT: VENTILATION, RESPIRATORY PROTECTION, PROTECTIVE CLOTHING, EYE PROTECTION MATERIAL SHOULD BE HANDLED OR TRANSFERRED IN AN APPROVED FUME HOOD OR WITH ADEQUATE VENTILATION. PROTECTIVE GLOVES (NEOPRENE, NITRILE OR EQUIVALENT) SHOULD BE WORN TO PREVENT SKIN CONTACT. SAFETY GLASSES WITH SIDE SHIELDS SHOULD BE WORN AT ALL TIMES. WORK / HYGENIC PRACTICES: WASH THOROUGHLY AFTER HANDLING. DO NOT TAKE INTERNALLY. EYE WASH AND SAFETY EQUIPMENT SHOULD BE READILY AVAILABLE. MSDS (CONTINUED) — AX0441 PAGE 4 3 EXPOSURE GUIDELINES OSHA - PEL: COMPONENT PPM TWA Mr, /M3 PPM STEL CL PPM CL HG /M3 SKIN ETHYL ALCOHOL 1000 1900 METHANOL 200 260 250 325 X ISO - PROPYL ALCOHOL 400 980 500 1225 ACGIH - TLV: TWA STEL CL COMPONENT PPM MG /M3 PPM MG /M3 PPM MG /M3 SKIN ETHYL ALCOHOL 1000 1880 METHANOL 200 262 250 328 X ISO - PROPYL ALCOHOL 400 983 500 1230 9. PHYSICAL AND CHEMICAL PROPERTIES BOILING POINT (C 760 MMHG).: 77C MELTING POINT (C) • ( -144C SPECIFIC GRAVITY (H20 = 1).: 0.79 VAPOR PRESSURE (MM HG).....: 48 20C PERCENT VOLATILE BY VOL (X): 99 +% VAPOR DENSITY (AIR = 1) 1.6 EVAPORATION RATE (BUAC = 1): 3.1 SOLUBILITY IN WATER ( %) MISCIBLE APPEARANCE COLORLESS LIQUID, CHARACTERISTIC ODOR 10. STABILITY AND REACTIVITY STABILITY • YES HAZARDOUS POLYMERIZATION: DOES NOT OCCUR HAZARDOUS DECOMPOSITION.: COX HSDS (CONTINUED) - AX0441 PAGE # 4 CONDITIONS TO AVOID • HEAT; CONTACT WITH IGNITION SOURCES. MATERIALS TO AVOID ( ) WATER ( ) ACIDS ( ) BASES ( ) CORROSIVES (X) OXIDIZERS ( ) OTHER : 11. TOXICOLOGICAL INFORMATION TOXICITY DATA: ORL -HMN LDLO: 1400 MG /KG TOXICOLOGICAL FINDINGS: TESTS ON LABORATORY ANIMALS INDICATE MATERIAL MAY CAUSE TUMORS AND PRODUCE ADVERSE MUTAGENIC AND REPRODUCTIVE EFFECTS. CITED IN. REGISTRY OF TOXIC EFFECTS OF CHEMICAL SUBSTANCES (RTECS) 12. -DISPOSAL CONSIDERATIONS EPA WASTE NUMBERS: 0001 TREATMENT: INCINERATION, FUELS BLENDING OR RECYCLE. CONTACT YOUR LOCAL PERMITTED WASTE DISPOSAL SITE (TSD) FOR PERMISSIBLE TREATMENT SITES. ALWAYS CONTACT A PERMITTED WASTE DISPOSER (TSD) TO ASSURE COMPLIANCE WITH ALL CURRENT LOCAL, STATE AND FEDERAL REGULATIONS. 13. TRANSPORT INFORMATION DOT PROPER SHIPPING NAME...: DENATURED ALCOHOL DOT ID NUMBER NA1986 14. REGULATORY INFORMATION TSCA STATEMENT ... ........: THIS PRODUCT IS A "MIXTURE" THE CAS NUMBERS OF ALL COMPONENTS ARE LISTED ON THE TSCA INVENTORY. MSDS (CONTINUED) - AX0441 PAGE # 5 COMPONENT ' - . ETHYL ALCOHOL METHANOL ISO- PROPYL ALCOHOL SARA SARA CERCLA EHS EHS TPQ RQ (302) (LDS) (LOS) OSHA SARA DEMINIMIS COMPONENT FLOOR LIST 313 FOR SARA 313 (X) ETHYL ALCOHOL METHANOL ISO- PROPYL ALCOHOL 15. OTHER INFORMATION COMMENTS: NONE Y Y 5000 Y Y 1.0 Y 0.1 NFPA HAZARD RATINGS: HEALTH : 0 FLAMMABILITY : 3 REACTIVITY : 0 SPECIAL HAZARDS REVISION HISTORY: 08/01/81 08/01/83 01/17/87 10/27/87 01/20/88 05/26/88 12/15/88 08/28/90 03/01/91 I = REVISED SECTION N/A = NOT AVAILABLE N/E = NONE ESTABLISHED THE STATEMENTS CONTAINED HEREIN ARE OFFERED FOR INFORMATIONAL PURPOSES ONLY AND ARE BASED UPON TECHNICAL DATA THAT EM SCIENCE BELIEVES TO BE ACCURATE. IT IS INTENDED FOR USE ONLY BY PERSONS HAVING THE NECESSARY TECHNICAL SKILL AND AT THEIR OWN DESCRETION AND RISK. SINCE CONDITIONS AND MANNER OF USE ARE OUTSIDE OUR CONTROL, WC MAKE NO WARRANTY, EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS OR OTHERWISE. PORTIONS COPYRIGHT ARIEL RESEARCH CORPORATION, 1993. RESTRICTED USE CONDITIONS APPLY. SELECTED REGULATORY INFORMATION IN EMCIS MSDS (CONTINUED) - AX0441 PAGE # 6 ;EXTINGUISHING MEDIA: CARBON DIOXIDE, DRY CHEMICAL, ALCOHOL FOAM, WATER MIST, OR FOG. 'SPECIAL FIRE FIGHTING PROCEDURES: WEAR FULL PROTECTIVE CLOTHING AND SELF- CONTAINED BREATHING APPARATUS. HEAT WILL BUILD PRESSURE AND MAY RUPTURE CLOSED STORAGE CONTAINERS. KEEP FIRE - EXPOSED CONTAINERS COOL WITH WATER SPRAY. IV. HAZARDOUS COMPONENTS METHANOL UJT.% CA 100 TLV 200 PPM (SKIN) CAS NO. 67 -56 -1 V. HEALTH HAZARDS OCCUPATIONAL EXPOSURE LIMITS OSHA T!JA STEL CEILING ACGIH TLV -TWA TLV -STEL NIOSH. 10 -HOUR TWA STEL 200 PPM (SKIN) 250 PPM OSHA / NIOSH 25,000 PPM NOT LISTED 200 PPM (SKIN) 250 PPM NSC 10 PPM NIOSH 2,000 PPM 200 PPM (SKIN) 250 PPM CONCENTRATION IMMEDIATELY DANGEROUS TO HEALTH ODOR THRESHOLD CARCINOGENIC DATA METHANOL IS NOT LISTED AS A CARCINOGEN BY IARC, NTP, OSHA, OR ACGIH. PRIMARY ROUTES OF ENTRY METHANOL MAY EXERT ITS EFFECTS THROUGH INHALATION, SKIN ABSORPTION, AND INGESTION. INDUSTRIAL EXPOSURE: ROUTE OF EXPOSURE /SIGNS AND SYMPTOMS INHALATION: EXPOSURE CAN CAUSE DROWSINESS AND INTOXICATION, HEADACHE, VISUAL DISTURBANCE LEADING TO BLINDNESS, COUGHING AND SHORTNESS OF BREATH, COLLAPSE AND DEATH AT HIGH CONCENTRATIONS, EYE CONTACT: LIQUID CAN CAUSE MODERATE BURNING, WATERING, SWELLING, AND REDNESS; HIGH VAPOR CONCENTRATION (GREATER THAN 2,000 PPM) MAY CAUSE SAME SYMPTOMS. SKIN CONTACT: THIS SUBSTANCE MAY BE ABSORBED THROUGH INTACT SKIN AND PRODUCE TOXIC EFFECTS. EXTENSIVE, REPEATED AND /OR PROLONGED SKIN CONTACT CAN CAUSE BURNING, ITCHING, REDNESS, OR BLISTERS. INGESTION: CAUSES BURNING OF THE GASTROINTESTINAL TRACT AND TOXIC EFFECTS. SWALLOWING MORE THAN 2 OUNCES OF METHANOL CAN CAUSE DEATH. EFFECTS OF OVEREXPOSURE MILD POISONING IS CHARACTERIZED BY FATIGUE, NAUSEA, HEADACHE, AND DELAYED VISUAL BLURRING. MODERATE INTOXICATION RESULTS IN SEVERE DEPRESSION. TEMPORARY OR PERMANENT BLINDNESS MAY FOLLOW IN 2 -6 DAYS. IN SEVERE POISONING, SYMPTOMS PROGRESS TO RAPID, SHALLOW RESPIRATION, CYANOSIS, COMA, HYPOTENSION, DILATED PUPILS, AND VISUAL DISTURBANCE. DEATH MAY RESULT FROM RESPIRATORY FAILURE. PAGE 2 • MEDICAL CONDITION AGGRAVATED BY EXPOSURE PRECLUDE FROM EXPOSURE THOSE INDIVIDUALS WITH DISEASES OF EYES, LIVER, KIDNEYS, AND LUNGS. EMERGENCY AND FIRST AID INHALATION: IMMEDIATELY REMOVE TO FRESH AIR. IF NOT BREATHING, ADMINISTER MOUTH -TO -MOUTH RESCUE BREATHING. IF THERE IS NO PULSE, ADMINISTER CARDIOPULMONARY RESUSCITATION (CPR). CONTACT PHYSICIAN IMMEDIATELY. EYE CONTACT: RINSE WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. GET EMERGENCY MEDICAL ASSISTANCE. SKIN CONTACT: FLUSH THOROUGHLY FOR AT LEAST 15 MINUTES. WASH AFFECTED SKIN WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND SHOES. WASH CLOTHING BEFORE RE -USE, AND DISCARD CONTAMINATED SHOES. GET EMERGENCY MEDICAL ASSISTANCE. INGESTION: CALL LOCAL POISON CONTROL CENTER FOR ASSISTANCE. CONTACT PHYSICIAN IMMEDIATELY. NEVER INDUCE VOMITING OR GIVE ANYTHING BY MOUTH TO A VICTIM UNCONSCIOUS OR HAVING CONVULSIONS. NOTE TO PHYSICIAN: IN CASE OF INGESTION OR MASSIVE INHALATION, OBSERVE VICTIM AS AN INPATIENT BECAUSE SLOW METABOLISM CAUSES A LATENT PERIOD OF 24 HOURS BETWEEN EXPOSURE AND ACIDOSIS AND BLINDNESS. VI. SAFETY MEASURES AND EQUIPMENT VENTILATION: ADEQUATE VENTILATION IS REQUIRED TO PROTECT PERSONNEL FROM EXPOSURE TO CHEMICAL VAPORS EXCEEDING THE PEL AND TO MINIMIZE FIRE HAZARDS. THE CHOICE OF VENTILATION EQUIPMENT, EITHER LOCAL OR GENERAL, WILL DEPEND ON THE CONDITIONS OF USE, QUANTITY OF MATERIAL, AND OTHER OPERATING PARAMETERS. RESPIRATORY: USE APPROVED RESPIRATOR EQUIPMENT. FOLLOW NIOSH AND EQUIPMENT MANUFACTURER'S RECOMMENDATIONS TO DETERMINE APPROPRIATE EQUIPMENT (AIR - PURIFYING, AIR - SUPPLIED, OR SELF - CONTAINED BREATHING APPARATUS). EYES: SAFETY GLASSES ARE CONSIDERED MINIMUM PROTECTION. GOGGLES OR FACE SHIELD MAY BE NECESSARY DEPENDING ON QUANTITY OF MATERIAL AND CONDITIONS OF USE. SKIN: PROTECTIVE GLOVES AND CLOTHING ARE RECOMMENDED. THE CHOICE OF MATERIAL MUST BE BASED ON CHEMICAL RESISTANCE AND OTHER USER REQUIREMENTS. GENERALLY, NEOPRENE, NITRILE RUBBER, OR RUDDER OFFERS ACCEPTABLE CHEMICAL RESISTANCE. INDIVIDUALS WHO ARE ACUTELY AND SPECIFICALLY SENSITIVE TO METHANOL MAY REQUIRE ADDITIONAL PROTECTIVE EQUIPMENT. STORAGE: METHANOL SHOULD BE PROTECTED FROM TEMPERATURE EXTREMES AND DIRECT SUNLIGHT. PROPER STORAGE OF METHANOL MUST BE DETERMINED BASED ON OTHER MATERIALS STORED AND THEIR HAZARDS AND POTENTIAL CHEMICAL INCOMPATIBILITY. IN GENERAL, METHANOL SHOULD BE STORED IN AN ACCEPTABLY PROTECTED AND SECURE FLAMMABLE LIQUID STORAGE ROOM. OTHER: EMERGENCY EYEWASH FOUNTAINS AND SAFETY SHOWERS SHOULD BE AVAILABLE IN THE VICINITY OF ANY POTENTIAL EXPOSURE. GROUND AND BOND METAL CONTAINERS TO MINIMIZE STATIC SPARKS. PAGE 3 VII. SPILL AND DISPOSAL DATA SPILL CONTROL: PROTECT FROM IGNITION. WEAR PROTECTIVE CLOTHING AND USE APPROVED RESPIRATOR EQUIPMENT. ABSORB SPILLED MATERIAL IN AN ABSORBENT RECOMMENDED FOR SOLVENT SPILLS AND REMOVE TO A SAFE LOCATION FOR DISPOSAL BY APPROVED METHODS. IF RELEASED TO THE ENVIRONMENT, COMPLY WITH ALL REGULATORY NOTIFICATION REQUIREMENTS. CERCLA REPORTABLE QUANTITY: 5,000 POUNDS. WASTE DISPOSAL: DISPOSE OF METHANOL AS AN EPA HAZARDOUS WASTE. CONTACT STATE ENVIRONMENTAL AGENCY FOR LISTING OF LICENSED HAZARDOUS WASTE DISPOSAL FACILITIES AND APPLICABLE REGULATIONS. HAZARDOUS WASTE' NUMBER: U154 (IGNITABLE); F003 (IGNITABLE). HAZARD CLASSIFICATION IMMEDIATE HEALTH: YES DELAYED HEALTH: YES FIRE: YES SUDDEN RELEASE: NO REACTIVE: NO METHANOL IS SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA) AND 40CFR PART 372, THIS PRODUCT DOES NOT CONTAIN ANY OTHER TOXIC CHEMICAL ABOVE 1% CONCENTRATION OR A CARCINOGEN ABOVE 0.1X CONCENTRATION. KEY CA APPROXIMATELY NA NOT APPLICABLE C CEILING CHEMICAL LISTINGS EXTREMELY HAZARDOUS SUBSTANCES: NO CERCLA HAZARDOUS SUBSTANCES: YES TOXIC CHEMICALS: YES STEL SHORT TERM EXPOSURE LEVEL (15 MINUTES) TLV THRESHOLD LIMIT VALUE TWA TIME WEIGHTED AVERAGE BUAC BUTYL ACETATE CERCLA COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION AND LIABILITY ACT OF 1980 NSC NATIONAL SAFETY COUNCIL ( "FUNDAMENTALS OF INDUSTRIAL_ HYGIENE," 3RD ED., 1988) BURDICK & JACKSON'S DISCLAIMER: THE INFORMATION AND RECOMMENDATIONS PRESENTED IN THIS MATERIAL SAFETY DATA SHEET ARE BASED ON SOURCES BELIEVED TO BE RELIABLE ON THE DATE HEREOF. BURDICK & JACKSON MAKES NO REPRESENTATION ON ITS COMPLETENESS OR ACCURACY. IT IS THE USER'S RESPONSIBILITY TO DETERMINE THE PRODUCT'S SUITABILITY FOR ITS INTENDED USE, THE PRODUCT'S SAFE USE, AND THE PRODUCT'S PROPER DISPOSAL. NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR OF ANY OTHER NATURE ARE MADE WITH RESPECT TO THE INFORMATION PROVIDED IN THIS MATERIAL SAFETY DATA SHEET OR TO THE PRODUCT TO WHICH SUCH INFORMATION:REFERS. BURDICK & JACKSON NEITHER ASSUMES NOR AUTHORIZES ANY OTHER PERSON TO ASSUME FOR IT, ANY OTHER OR ADDITIONAL LIABILITY OR RESPONSIBILITY RESULTING FROM THE USE OF, OR RELIANCE UPON, THIS INFORMATION. PAGE 4 (LAST PAGE) "ISSUED BY VWR 07/09/98" BURDICK & JACKSON, INC. 1953 SOUTH HARVEY STREET MUSKEGON, MI 49442 USA MATERIAL SAFETY DATA SHEET INFORMATION /EMERGENCY TELEPHONE NUMBER - CHEMTREC TELEPHONE NUMBER -- CANADIAN EMERGENCY TELEPHONE NUMBER I. IDENTIFICATION CHEMICAL NAME: CHEMICAL FAMILY: SYNONYMS: DOT PROPER SHIPPING NAME: DOT HAZARD CLASS: DOT IDENTIFICATION NUMBER: II. PHYSICAL AND CHEMICAL DATA BOILING POINT, 760 MM HG: VAPOR PRESSURE AT 20 C: X VOLATILES BY VOLUME: FREEZING POINT: VAPOR DENSITY (AIR =1): SPECIFIC GRAVITY (H2O =1): EVAPORATION RATE: SOLUBILITY IN WATER: STABILITY: HAZARDOUS POLYMERIZATION: APPEARANCE AND ODOR: CONDITIONS TO AVOID: MATERIALS TO AVOID: HAZARDOUS DECOMPOSITION PRODUCTS: III. FIRE AND EXPLOSION HAZARD DATA DIMETHYL FORMAMIDE REVISION DATE: DECEMBER, 1993 REVISION NO: 1 616.72.6.3171 800.424.9300 613.996.6666 DIMETHYL FORMAMIDE MOLECULAR WEIGHT: 73.10 ALKYL AMIDE FORMULA: C3H7NO DMF, N,N- DIMETHYLFORMAMIDE N,N DIMETHYLFORMAMIDE FLAMMABLE LIQUID, HAZARD CLASS 3, P.G, III UN2265 CAS NUMBER: 68 -12 -2 153 C 2.7 MM HG CA 100 -60.4 C 2.5 @ 20 C 0.949 (BUAC =1) CA 0.2 @ 20 C COMPLETE STABLE NOT EXPECTED TO OCCUR CLEAR, COLORLESS LIQUID WITH A SLIGHT AMINE -LIKE ODOR. HEAT, SPARKS, OPEN FLAME, OPEN CONTAINERS, AND POOR VENTILATION. STRONG OXIDIZERS, HALOGENATED COMPOUNDS AND IRON, ALKYL ALUMINUMS, INORGANIC NITRATES, AN[1 CARBON TETRACHLORIDE. INCOMPLETE COMBUSTION CAN GENERATE CARBON MONOXIDE, DIMETHYLAMINE, NITROGEN OXIDES, AND OTHER TOXIC VAPORS. THERMAL DECOMPOSITION MAY OCCUR AT TEMPERATURES EXCEEDING 350 C. FLASH POINT(TEST METHOD): 58 C(TAG CLOSED CUP) AUTO IGNITION TEMPERATURE: 445 C FLAMMABLE LIMITS IN AIR X BY VOLUME: LOWER LIMIT 2.2 UPPER LIMIT: 1 UNUSUAL FIRE AND EXPLOSION HAZARDS: NONE, OTHER THAN COMBUSTIBILITY. PAGE 1 EXTINGUISHING MEDIA: CARBON DIOXIDE, DRY CHEMICAL OR ALCOHOL FOAM. SPECIAL FIRE FIGHTING PROCEDURES: IV. HAZARDOUS COMPONENTS OCCUPATIONAL EXPOSURE LIMITS WEAR FULL PROTECTIVE CLOTHING AND SELF - CONTAINED BREATHING APPARATUS. HEAT WILL BUILD PRESSURE AND MAY RUPTURE CLOSED STORAGE CONTAINERS. KEEP FIRE - EXPOSED CONTAINERS COOL WITH WATER SPRAY. DIMETHYL FORMAMIDE WT.X CA 100 TLV 10 PPM (SKIN) CAS NO. 6B -12 -2 V. HEALTH HAZARDS CONCENTRATION IMMEDIATELY DANGEROUS TO HEALTH OSHA TWA 10 PPM (SKIN) STEL NOT LISTED OSHA /NIOSH 3,500 PPM CEILING NOT LISTED ODOR THRESHOLD ACGIH TLV -TWA 10 PPM (SKIN) TLV -STEL NOT LISTED NSC 20 PPM NIOSH 100 PPM NIOSH TWA 10 PPM (SKIN) CARCINOGENIC DATA DIMETHYL FORMAMIDE IS LISTED AS A SUSPECTED CARCINOGEN BY IARC, PRIMARY ROUTES OF ENTRY DIMETHYL FORMAMIDE MAY EXERT ITS EFFECTS THROUGH INHALATION, SKIN ADSORPTION, AND INGESTION. INDUSTRIAL EXPOSURE: ROUTE OF EXPOSURE /SIGNS AND SYMPTOMS INHALATION: EXPOSURE CAN DIZZINESS, HEADACHE, NAUSEA, FLUSHING OF THE FACE, ABDOMINAL SPASMS, AND IRRITATION TO THE UPPER RESPIRATORY TRACT. LIVER AND KIDNEY INJURY IS POSSIBLE FROM REPEATED .OR PROLONGED EXPOSURES. EYE CONTACT: LIQUID AND HIGH VAPOR CONCENTRATION WJILL BE IRRITATING. SKIN CONTACT: PROLONGED OR -REPEATED SKIN CONTACT CAN CAUSE IRRITATION AND DERMATITIS. 'DIMETHYL FORMAMIDE IS READILY ABSORBED THROUGH THE SKIN WITH SYSTEMIC EFFECTS SIMILAR TO INHALATION. INGESTION: CAN CAUSE GASTROINTESTINAL TRACT DISCOMFORT.' SWALLOWING MORE THAN 50 GRAMS OF DIMETHYL FORHAMIDE CAN CAUSE DEATH. EFFECTS OF OVEREXPOSURE DIMETHYL FORMAMIDE IS AN EYE AND MUCOUS MEMBRANE IRRITANT, PRIMARY SKIN IRRITANT, AND HEPATOTOXIN. ACUTE EXPOSURE CAUSES DIZZINESS, NAUSEA, VOMITING, AND SEVERE ABDOMINAL. SPASMS. CHRONIC INHALATION CAN CAUSE LIVER, KIDNEY, AND CARDIOVASCULAR DAMAGE. PAGE 2 MEDICAL CONDITION AGGRAVATED BY EXPOSURE PRECLUDE FROM EXPOSURE THOSE INDIVIDUALS WITH DISEASE OF THE LIVER AND KIDNEY, AND THOSE SUSCEPTIBLE TO DERMATITIS. SIMULTANEOUS EXPOSURE TO DIMETHYL FORMAMIDE AND ALCOHOL CAUSES FACIAL FLUSHING AND PALPITATION. EMERGENCY FIRST AID INHALATION: IMMEDIATELY REMOVE TO FRESH AIR. IF NOT BREATHING, ADMINISTER MOUTH -TO -MOUTH RESCUE BREATHING. IF THERE IS NO PULSE, ADMINISTER CARDIOPULMONARY RESUSCITATION (CPR), CONTACT PHYSICIAN IMMEDIATELY. EYE CONTACT: RINSE WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. GET EMERGENCY MEDICAL ASSISTANCE. SKIN CONTACT: FLUSH THOROUGHLY FOR AT LEAST 15 MINUTES. WASH AFFECTED SKIN WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND SHOES. WASH CLOTHING BEFORE RE -USE, AND DISCARD CONTAMINATED SHOES. GET EMERGENCY MEDICAL ASSISTANCE. INGESTION: CALL LOCAL POISON CONTROL CENTER FOR ASSISTANCE. CONTACT PHYSICIAN IMMEDIATELY. NEVER INDUCE VOMITING OR GIVE ANYTHING BY MOUTH TO A VICTIM UNCONSCIOUS OR HAVING CONVULSIONS. VI. SAFETY MEASURES AND EQUIPMENT VENTILATION: ADEQUATE VENTILATION IS REQUIRED TO PROTECT PERSONNEL FROM EXPOSURE TO CHEMICAL VAPORS EXCEEDING THE PEL AND TO MINIMIZE FIRE HAZARDS. THE CHOICE OF VENTILATION EQUIPMENT, EITHER LOCAL OR GENERAL, WILL DEPEND ON THE CONDITIONS OF USE, QUANTITY OF MATERIAL, AND OTHER OPERATING PARAMETERS. RESPIRATORY: USE APPROVED RESPIRATOR EQUIPMENT. FOLLOW NIOSH AND EQUIPMENT MANUFACTURER'S RECOMMENDATIONS TO DETERMINE APPROPRIATE EQUIP- MENT (AIR- PURIFYING, AIR - SUPPLIED, OR SELF- CONTAINED BREATHING APPARATUS). EYES: SAFETY GLASSES ARE CONSIDERED MINIMUM PROTECTION. GOGGLES OR FACE SHIELD MAY BE NECESSARY DEPENDING ON QUANTITY OF MATERIAL AND CONDITIONS OF USE. SKIN: PROTECTIVE GLOVES AND CLOTHING ARE RECOMMENDED. THE CHOICE OF MATERIAL MUST BE BASED ON CHEMICAL RESISTANCE AND OTHER USER REQUIREMENTS. GENERALLY, BUTYL RUBBER, NATURAL RUBBER, OR NEOPRENE OFFERS ACCEPTABLE CHEMICAL RESISTANCE. INDIVIDUALS WHO ARE ACUTELY AND SPECIFICALLY SENSITIVE TQ DIMETHYL FORMAMIDE MAY REQUIRE ADDITIONAL PROTECTIVE EQUIPMENT. STORAGE: OTHER: DIMETHYL FORMAMIDE SHOULD BE PROTECTED FROM TEMPERATURE EXTREMES AND DIRECT SUNLIGHT. PROPER STORAGE OF DIMETHYL FORMAMIDE MUST BE DETERMINED BASED ON OTHER MATERIALS STORED AND THEIR HAZARDS AND POTENTIAL CHEMICAL INCOMPATIBILITY. IN GENERAL, DIMETHYL FORMAMIDE SHOULD BE STORED IN AN ACCEPTABLY PROTECTED AND SECURE TOXIC STORAGE ROOM. EMERGENCY EYEWASH FOUNTAINS AND SAFETY SHOWERS SHOULD BE AVAILABLE IN THE VICINITY OF ANY POTENTIAL EXPOSURE. GROUND AND BONO METAL CONTAINERS TO MINIMIZE STATIC SPARKS. PAGE 3 VII. SPILL AND DISPOSAL DATA SPILL CONTROL: PROTECT FROM IGNITION. WEAR PROTECTIVE CLOTHING AND USE APPROVED RESPIRATOR EQUIPMENT. ABSORB SPILLED MATERIAL IN AN ABSORBENT RECOMMENDED FOR SOLVENT SPILLS AND REMOVE TO A SAFE LOCATION FOR DISPOSAL BY APPROVED METHODS. IF RELEASED TO THE ENVIRONMENT, COMPLY WITH ALL REGULATORY NOTIFICATION REQUIRE- MENTS. CERCLA REPORTABLE QUANTITY: WASTE DISPOSAL: DISPOSE OF DIMETHYL FORMAMIDE AS AN EPA HAZARDOUS WASTE, CONTACT ENVIRONMENTAL AGENCY FOR LISTING OF LICENSED HAZARDOUS WASTE DISPOSAL FACILITIES AND APPLICABLE REGULATIONS. HAZARDOUS WASTE NUMBER: 0001 (IGNITABLE). HAZARD CLASSIFICATION CHEMICAL LISTINGS IMMEDIATE HEALTH: YES EXTREMELY HAZARDOUS SUBSTANCES: NO DELAYED HEALTH: YES CERCLA HAZARDOUS SUBSTANCES: NO FIRE: YES TOXIC CHEMICALS: NO SUDDEN RELEASE: NO REACTIVE: NO DIMETHYL FORMAMIDE IS SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA) AND 40CFR PART 372. THIS PRODUCT DOES NOT CONTAIN ANY OTHER TOXIC CHEMICAL ABOVE 1X CONCENTRATION OR A CARCINOGEN ABOVE 0.1% CONCENTRATION. KEY CA APPROXIMATELY NA NOT APPLICABLE C CEILING STEL SHORT TERM EXPOSURE LEVEL (15 MINUTES) TLV THRESHOLD LIMIT VALUE TWA TIME WEIGHTED AVERAGE BUAC BUTYL ACETATE CERCLA COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION AND LIABILITY ACT OF 1980 NSC NATIONAL SAFETY COUNCIL ( "FUNDAMENTALS OF INDUSTRIAL HYGIENE," 3RD ED., 1988) BURDICK & JACKSON'S DISCLAIMER: THE INFORMATION AND RECOMMENDATIONS PRESENTED IN THIS MATERIAL SAFETY DATA SHEET ARE BASED ON SOURCES BELIEVED TO BE RELIABLE ON THE DATE HEREOF. BURDICK & JACKSON MAKES NO REPRESENTATION ON ITS COMPLETENESS OR ACCURACY, IT IS THE USER'S RESPONSIBILITY TO DETERMINE THE PRODUCT'S SUITABILITY FOR ITS. INTENDED USE, THE PRODUCT'S SAFE USE, AND THE PRODUCT'S PROPER DISPOSAL. ND REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR OF ANY OTHER NATURE ARE MADE WITH RESPECT TO THE INFORMATION PROVIDED IN THIS MATERIAL SAFETY DATA SHEET OR TO THE PRODUCT TO WHICH SUCH INf ORMATION REFERS. BURDICK & JACKSON NEITHER ASSUMES NOR AUTHORIZES ANY OTHER PERSON TO ASSUME FOR IT, ANY OTHER OR ADDITIONAL LIABILITY OR RESPONSIBILITY RESULTING FROM THE USE OF, OR RELIANCE UPON, THIS INFORMATION. PAGE 4 (LAST PAGE) "ISSUED BY VWR 07/09/98" 11. CHEMICAL PRODUCT AND COMPANY MANUFACTURER . EM SCIENCE A DIVISION OF EM INDUSTRIES P.O. BOX 70 480 DEMOCRAT RD. GIBBSTOWN, N.J. 08027 CATALOG NUMBER(S): 7X0277 TX0278 TX0280P TX0280T TX0284 PRODUCT NAME.....: TETRAHYDROFURAN SYNONYMS THF; OIETHYLENE OXIDE; CHEMICAL FAMILY..: CYCLIC ETHER FORMULA C4H80 MOLECULAR WEIGHT.: 72.11 TETRAHYDROFURAN MATERIAL SAFETY DATA SHEET TX0279 TX0281 EM SCIENCE IDENTIFICATION PREPARATION DATE.: 02/11/97 DATE MSDS PRINTED.: MAY 15, 1997 INFORMATION PHONE NUMBER.: 609 -423 -6300 HOURS: MON. TO FRI. 8:30 -5 CHEMTREC EMERGENCY NUMBER: 800- 424 -9300 HOURS: 24 HRS A DAY TX0279AP TX0282 TETRAMETHYLENE OXIDE 2. COMPOSITION / INFORMATION ON INGREDIENTS COMPONENT CAS # 109 -99 -9 100X 3. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW EXTREMELY FLAMMABLE LIQUID AND VAPOR. TENDS TO FORM EXPLOSIVE PEROXIDES ESPECIALLY WHEN ANHYDROUS. CAUSES IRRITATION OF EYES, NOSE AND THROAT. MAY CAUSE EYE INJURY. MAY CAUSE DAMAGE TO NERVOUS AND RESPIRATORY SYSTEMS, KIDNEYS AND LIVER. APPEARANCE MSDS (CONTINUED) - TX0278 PAGE #.1 TX0280 TX0280A0 TX0282AG TX0282P APPR X COLORLESS LIQUID; ETHEREAL ODOR POTENTIAL HEALTH EFFECTS (ACUTE AND CHRONIC) SYMPTOMS OF EXPOSURE: IRRITATING TO EYES (CAUSING BLURRED VISION), SKIN, RESPIRATORY • TRACT (ANESTHETIC EFFECT, HEADACHE) MAY CAUSE DAMAGE TO NERVOUS AND RESPIRATORY SYSTEMS, KIDNEYS AND LIVER. MAY CAUSE EYE BURNS. MEDICAL COND. AGGRAVATED BY EXPOSURE: PRE - EXISTING SKIN DISORDERS OR EYE PROBLEMS OR IMPAIRED LIVER OR KIDNEY FUNCTIONS. ROUTES OF ENTRY INHALATION, INGESTION CARCINOGENICITY THE MATERIAL IS NOT LISTED (IARC, NTP, OSHA) AS CANCER CAUSING AGENT. 4. FIRST AID MEASURES EMERGENCY FIRST AID: GET MEDICAL ASSISTANCE FOR ALL CASES OF OVEREXPOSURE. SKIN: IMMEDIATELY FLUSH THOROUGHLY WITH LARGE AMOUNTS OF WATER. EYES: IMMEDIATELY FLUSH THOROUGHLY WITH WATER FOR AT LEAST 15 MINUTES. INHALATION; REMOVE TO FRESH AIR; GIVE ARTIFICIAL RESPIRATION IF BREATHING HAS STOPPED. INGESTION: DO NOT INDUCE VOMITING; IF CONSCIOUS, GIVE WATER FREELY AND GET HEDICAL ATTENTION. 15. FIRE FIGHTING MEASURES FLASH POINT (F)..........: 6F (TCC) FLAMMABLE LIMITS LEL (X).: 2• FLAMMABLE LIMITS UEL (X).: 11.8 EXTINGUISHING MEDIA USE CARBON DIOXIDE OR DRY CHEMICAL. USE WATER TO COOL FIRE = EXPOSED CONTAINERS AND DISPERSE VAPORS. FIRE FIGHTING PROCEDURES.: WEAR SELF - CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING. FIRE & EXPLOSION HAZARDS.: DANGEROUS FIRE AND EXPLOSIVE HAZARD. MSDS (CONTINUED) - TX0278 PAGE t 2 EXPLOSIVE PEROXIDES MAY FORM AFTER LONG STORAGE OR EXPOSURE TO AIR AND LIGHT. THF CAN FORM HEAT SENSITIVE PEROXIDE WHICH MAY EXPLODE ON CONCENTRATION BY DISTILLATION OR DRYING. DO NOT DISTILL OR ALLOW THF, OR SOLUTIONS CONTAINING THF, TO DRY IF TESTS SHOW MORE THAN 0.05X THF PEROXIDE PRESENT. TO AVOID A POSSIBLE EXPLOSION, THF SHOULD NEVER BE DISTILLED TO DRYNESS. VAPOR CAN TRAVEL DISTANCES TO IGNITION SOURCE AND FLASH BACK. • 6. ACCIDENTAL RELEASE MEASURES SPILL RESPONSE: EVACUATE THE AREA OF ALL UNNECESSARY PERSONNEL. WEAR SUITABLE PROTECTIVE EQUIPMENT LISTED UNDER EXPOSURE / PERSONAL. PROTECTION. ELIMINATE ANY IGNITION SOURCES UNTIL THE AREA IS DETERMINED TO BE FREE FROM EXPLOSION OR FIRE HAZARDS. CONTAIN THE RELEASE AND ELIMINATE ITS SOURCE, IF THIS CAN BE DONE WITHOUT RISK. TAKE UP AND CONTAINERIZE FOR PROPER DISPOSAL AS DESCRIBED UNDER DISPOSAL. COMPLY WITH FEDERAL, STATE, AND LOCAL. REGULATIONS ON REPORTING RELEASES. REFER TO REGULATORY INFORMATION FOR REPORTABLE QUANTITY AND OTHER REGULATORY DATA. EM SCIENCE RECOMMENDS SPILL -X ABSORBENT AGENTS FOR VARIOUS TYPES OF SPILLS. ADDITIONAL INFORMATION ON THE SPILL -X PRODUCTS CAN BE PROVIDED THROUGH THE EM SCIENCE TECHNICAL SERVICE DEPARTMENT (609) 423 -6300. THE FOLLOWING EM SCIENCE SPILL -X ABSORBENT IS RECOMMENDED FOR THIS PRODUCT: SX0063 SOLVENT SPILL TREATMENT KIT 7. HANDLING AND STORAGE HANDLING & STORAGE: KEEP CONTAINER CLOSED. STORE IN A COOL AREA AWAY FROM IGNITION SOURCES AND OXIDIZERS. CHECK PEROXIDE CONTENT BEFORE HEATING MATERIAL. DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING. DO NOT BREATHE VAPOR. B. EXPOSURE CONTROLS / PERSONAL PROTECTION ENGINEERING CONTROLS AND PERSONAL PROTECTIVE EQUIPMENT: VENTILATION, RESPIRATORY PROTECTION, PROTECTIVE CLOTHING, EYE PROTECTION RESPIRATORY PROTECTION: IF WORKPLACE EXPOSURE LIMIT(S) OF PRODUCT M5DS (CONTINUED) - TX0270 PAGE 1 3 OR ANY COMPONENT IS EXCEEDED (SEE TLV /PEL), A NIOSH /MSHA APPROVED AIR SUPPLIED RESPIRATOR IS ADVISED IN ABSENCE OF PROPER ENVIRONMENTAL CONTROL. OSHA REGULATIONS ALSO PERMIT OTHER NIOSH /MSHA RESPIRATORS (NEGATIVE PRESSURE TYPE) UNDER SPECIFIED CONDITIONS (SEE YOUR SAFETY EQUIPMENT SUPPLIER). ENGINEERING AND /OR ADMINISTRATIVE CONTROLS SHOULD BE IMPLEMENTED TO REDUCE EXPOSURE. MATERIAL SHOULD BE HANDLED OR TRANSFERRED IN AN APPROVED FUME H000 OR WITH ADEQUATE VENTILATION. PROTECTIVE GLOVES (PVA OR EQUIVALENT) SHOULD BE WORN TO PREVENT SKIN CONTACT. COVERALL CHEMICAL SPLASH GOGGLES MUST BE WORN AT ALL TINES. WORK / HYGENIC PRACTICES: WASH THOROUGHLY AFTER HANDLING. DO NOT TAKE INTERNALLY. EYE WASH AND SAFETY EQUIPMENT SHOULD RE READILY AVAILABLE, EXPOSURE GUIDELINES OSHA - PEL: TWA STEL CL COMPONENT PPM MG /M3 PPM MG /M3 PPM MG /M3 SKIN TETRAHYDROFURAN 200 590 250 735 ACGIH - TLV: TWA STEL CL COMPONENT PPM MG /M3 PPM MG /M3 PPM MG /M3 SKIN TETRAHYDROFURAN 200 590 250 737 9, PHYSICAL AND CHEMICAL PROPERTIES BOILING POINT (C 760 MMHG).: 65C MELTING POINT (C) • - 108.5C SPECIFIC GRAVITY (H20 = 1).:•0.888 VAPOR PRESSURE (MM HG)..... :'114 15C PERCENT VOLATILE BY VOL (X): 100X VAPOR DENSITY (AIR = 1) 2,5 EVAPORATION RATE (BUAC = 1): 8.0 SOLUBILITY IN WATER (X)....: SOLUBLE APPEARANCE COLORLESS LIQUID; ETHEREAL ODOR 10. STABILITY AND REACTIVITY MSDS (CONTINUED) - TX0278 PAGE # 4 STABILITY ' YES HAZARDOUS POLYMERIZATION: DOES NOT OCCUR HAZARDOUS DECOMPOSITION.: COX CONDITIONS TO AVOID HEAT; CONTACT WITH IGNITION SOURCES; EVAPORATION TO DRYNESS OR NEAR DRYNESS MATERIALS TO AVOID ( ) WATER ( ) ACIDS ( ) BASES ( ) CORROSIVES ( ) OXIDIZERS (X) OTHER : STRONG OXIDIZERS, SODIUM ALUMINUM HYDRIDE, EXCESS OF STRONG CAUSTIC, LITHIUM ALUMINUM HYDRIDE 11. TOXICOLOGICAL INFORMATION TOXICITY DATA: IHL -HMN TCLO: 25000 PPM ORL -RAT LD50: 1650 MG /KG IHL -RAT LD50: 21000 PPM /3H TOXICOLOGICAL FINDINGS: TESTS ON LABORATORY ANIMALS INDICATE MATERIAL MAY PRODUCE ADVERSE MUTAGENIC AND REPRODUCTIVE EFFECTS. CITED IN REGISTRY OF TOXIC EFFECTS OF CHE1•MICAL SUBSTANCES (RTECS) 12. DISPOSAL CONSIDERATIONS EPA WASTE NUMBERS: U213 D001 TREATMENT: INCINERATION, FUELS BLENDING OR RECYCLE. CONTACT YOUR LOCAL PERMITTED WASTE DISPOSAL SITE (TSO) FOR PERMISSIBLE TREATMENT SITES. ALWAYS CONTACT A PERMITTED WASTE DISPOSER (TSD) TO ASSURE COMPLIANCE WITH ALL CURRENT LOCAL, STATE AND FEDERAL REGULATIONS. 13. TRANSPORT INFORFMATION DOT PROPER SHIPPING NAME...: MSDS (CONTINUED) - TX0278 PAGE # 5 TETRAHYDROFURAN DOT ID NUMBER UN2056 14. REGULATORY INFORMATION TSCA STATEMENT ...., ....,..: THE CAS NUMBER OF THIS PRODUCT TS LISTED ON THE TSCA INVENTORY. COMPONENT TETRAHYDROFURAN OSHA SARA DEMINIMIS COMPONENT FLOOR LIST 313 FOR SARA 313 (X) TETRAHYDROFURAN 15. OTHER INFORMATION COMMENTS: NONE Y NFPA HAZARD RATINGS: HEALTH : 2 FLAMMABILITY : 3 REACTIVITY : 1 SPECIAL HAZARDS : SARA SARA CERCLA EHS EHS TPQ RQ (302) (LBS) (LDS) 1000 REVISION HISTORY: 08/01/81 04/15/86 06/08/87 10/27/89 01/30/91 03/01/91 07/26/94 04/05/95 07/07/95 08/28/95 02/15/96 I = REVISED SECTION N/A = NOT AVAILABLE N/E = NONE ESTABLISHED THE STATEMENTS CONTAINED HEREIN ARE OFFERED FOR INFORMATIONAL PURPOSES ONLY AND ARE BASED UPON TECHNICAL DATA THAT EM SCIENCE BELIEVES TO BE ACCURATE. IT IS INTENDED FOR USE ONLY BY PERSONS HAVING THE NECESSARY TECHNICAL SKILL AND AT THEIR OIJN DESCRETION AND RISK. STNCE CONDITIONS AND MANNER OF USE ARE OUTSIDE OUR CONTROL, WE MAKE NO WARRANTY, EXPRESS MSDS (CONTINUED) - 7X0278 PAGE # 6 . OR IMPLIED, OF MERCHANTABILITY, FITNESS OR OTHERWISE. HSDS - TX0278 PAGE # 7 "ISSUED BY VWR 07709/98" BURDICK & JACKSON, INC. - 1953 SOUTH HARVEY STREET MUSKEGON, MI 49442 USA • MATERIAL SAFETY DATA SHEET INFORMATION /EMERGENCY TELEPHONE NUMBER 616.776.3171 CHEMTREC TELEPHONE NUMBER 800.424.9300 CANADIAN EMERGENCY TELEPHONE NUMBER 613.996.6666 I. IDENTIFICATION II. PHYSICAL AND CHEMICAL DATA III, FIRE AND EXPLOSION HAZARD DATA PAGE 1 TOLUENE REVISION DATE: DECEMBER, 1993 REVISION NO: 1 "CHEMICAL NAME: TOLUENE CHEMICAL FAMILY: AROMATIC HYDROCARBON SYNONYMS: TOLUOL, METHYLBENZENE DOT PROPER SHIPPING NAME: TOLUENE DOT HAZARD CLASS: FLAMMABLE LIQUID, HAZARD CLASS 3, P.G. II DOT IDENTIFICATION.NUMBER: UN1294 MOLECULAR WEIGHT: 92.14 FORMULA: C7H8 CAS NUMBER: 108 -88 -3 BOILING POINT, 760 MM MG: 110.62 C VAPOR PRESSURE AT 20 C: 28.5 MM HG X VOLATILES BY VOLUME: CA 100 FREEZING POINT: -94.99 C VAPOR DENSITY (AIR =1): 3.2 SPECIFIC GRAVITY (H20 =1): G 20 C 0.867 EVAPORATION RATE: (BOAC =1) CA 2 SOLUBILITY IN WATER: 120 C 0.074X STABILITY: STABLE HAZARDOUS POLYMERIZATION: NO EXPECTED TO OCCUR. APPEARANCE AND ODOR: CLEAR, COLORLESS LIQUID WITH A SWEET, PUNGENT ODOR.'" CONDITIONS TO AVOID: HEAT, SPARKS, OPEN FLAME, OPEN CONTAINERS, AND POOR VENTILATION. MATERIALS TO AVOID: STRONG OXIDIZING AGENTS AND STRONG ACIDS. HAZARDOUS DECOMPOSITION PRODUCTS: INCOMPLETE COMBUSTION CAN GENERATE CARBON MONOXIDE AND OTHER TOXIC VAPORS. FLASH POINT (TEST METHOD): 2 C (TAG CLOSED CUP) AUTO IGNITION TEMPERATURE: 480 C FLAMMABLE LIMITS IN AIR X BY VOLUME: LOWER LIMIT: 1.2 UPPER LIMIT: 7.1 UNUSUAL FIRE AND EXPLOSION HAZARDS: VOLATILE AND FLAMMABLE. EXTINGUISHING MEDIA: CARBON DIOXIDE, DRY CHEMICAL, AND FOAM. SPECIAL FIRE FIGHTING PROCEDURES: UATER UILL NOT BE EFFECTIVE IN EXTINGUISHING A FIRE AND MAY SPREAD IT, BUT A WATER SPRAY CAN BE USED TO COOL EXPOSED CONTAINERS. WEAR FULL PROTECTIVE CLOTHING AND SELF - CONTAINED BREATHING APPARATUS. HEAT WILL BUILD PRESSURE AND RUPTURE CLOSED STORAGE CONTAINERS. IV. HAZARDOUS COMPONENTS TOLUENE WT.). CA 100 V. HEALTH HAZARDS OCCUPATIONAL EXPOSURE LIMITS OSHA TWA STEL CEILING ACGIH TLV -TWA TLV -STEL NIOSH 10 -HOUR TWA STEL 100 PPM 150 PPM NOT LISTED TLV 100 PPM CAS NO. 108 -88 -3 CONCENTRATION IMMEDIATELY DANGEROUS TO HEALTH OSHA /NIOSH 2,000 PPM ODOR THRESHOLD 100 PPM 150 PPM NSC 1 PPM NIOSH 10 -15 PPM 100 PPM 150 PPM CARCINOGENIC DATA TOLUENE IS NOT LISTED AS A CARCINOGEN BY IARC, NTP, OSHA, OR ACGIH. RTEC REPORTS MUTAGENIC EFFECTS ON HUMANS AND TERATOGENIC EFFECTS ON ANIMALS. PRIMARY ROUTES OF ENTRY TOLUENE MAY EXERT ITS EFFECTS THROUGH INHALATION, SKIN ABSORPTION, AND INGESTION. INDUSTRIAL EXPOSURE: ROUTE OF EXPOSURE /SIGNS AND SYMPTOMS INHALATION: EXPOSURE CAN CAUSE ANESTHESIA, NAUSEA, DIZZINESS AND RESPIRATORY TRACT IRRITATION. EYE CONTACT: LIQUID AND HIGH VAPOR CONCENTRATION WILL CAUSE IRRITATION AND POSSIBLE CORNEAL DAMAGE. SKIN CONTACT: PROLONGED OR REPEATED SKIN CONTACT CAN CAUSE IRRITATION AND DERMATITIS THROUGH DEFATTING OF SKIN. INGESTION: CAUSES IRRITATION OF THE GASTROINTESTINAL. TRACT AND MAY CAUSE SYSTEMIC EFFECTS FROM ABSORPTION. EFFECTS OF OVEREXPOSURE TOLUENE IS A PRIMARY SKIN IRRITANT AND A CENTRAL NERVOUS SYSTEM DEPRESSANT. ACUTE POISONING AFFECTS THE NERVOUS SYSTEM LEADING TO COMA. CHRONIC EXPOSURE DEPRESSES THE BONE MARROW, BUT WITHOUT THE SEVERE OR FATAL DAMAGE PRESENT IN BENZENE POISONING. LIVER ENLARGEMENT IS ALSO POSSIBLE. DELIBERATE CONCENTRATION AND INHALATION CAN CAUSE LIVER, KIDNEY, AND BRAIN DAMAGE. MEDICAL CONDITION AGGRAVATED BY EXPOSURE PRECLUDE FROM EXPOSURE THOSE INDIVIDUALS WITH DISEASE OF EYES, LIVER, AND CENTRAL NERVOUS SYSTEM; AND THOSE SUSCEPTIBLE TO DERMATITIS. EMERGENCY FIRST AID INHALATION: IMMEDIATELY REMOVE TO FRESH AIR. IF NOT BREATHING, ADMINISTER MOUTH -TO -MOUTH RESCUE BREATHING. IF THERE IS NO PULSE, ADMINISTER CARDIOPULMONARY RESUSCITATION (CPR). CONTACT PHYSICIAN IMMEDIATELY. EYE CONTACT: RINSE WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. GET EMERGENCY MEDICAL ASSISTANCE. PAGE 2 'SKIN CONTACT: FLUSH THOROUGHLY FOR AT LEAST 15 MINUTES. WASH AFFECTED SKIN WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND SHOES. WASH CLOTHING BEFORE RE -USE, AND DISCARD CONTAMINATED SHOES. GET EMERGENCY MEDICAL ASSISTANCE. INGESTION: CALL LOCAL POISON CONTROL CENTER FOR ASSISTANCE. CONTACT PHYSICIAN IMMEDIATELY. ASPIRATION HAZARD - DO NOT INDUCE VOMITING. VI. SAFETY MEASURES AND EQUIPMENT VENTILATION: ADEQUATE'VENTILATION IS REQUIRED TO PROTECT PERSONNEL FROM EXPOSURE TO CHEMICAL VAPORS EXCEEDING THE PEL AND TO MINIMIZE FIRE HAZARDS. THE CHOICE OF VENTILATION EQUIPMENT, EITHER LOCAL OR GENERAL, WILL DEPEND ON THE CONDITIONS OF USE, QUANTITY OF MATERIAL, AND OTHER OPERATING PARAMETERS. RESPIRATORY: USE APPROVED RESPIRATOR EQUIPMENT. FOLLOW NIOSH AND EQUIPMENT MANUFACTURER'S RECOMMENDATIONS TO DETERMINE APPROPRIATE EQUIPMENT (AIR - PURIFYING, AIR - SUPPLIED, OR SELF - CONTAINED BREATHING APPARATUS). EYES: SAFETY GLASSES ARE CONSIDERED MINIMUM PROTECTION. GOGGLES OR FACE SHIELD MAY BE NECESSARY DEPENDING ON QUANTITY OF MATERIAL AND CONDITIONS OF USE. SKIN: PROTECTIVE GLOVES AND CLOTHING ARE RECOMMENDED. THE CHOICE OF MATERIAL MUST BE BASED ON CHEMICAL RESISTANCE AND OTHER USER REQUIREMENTS. GENERALLY, VITON OR NITRILE RUBBER OFFERS ACCEPTABLE CHEMICAL RESISTANCE. INDIVIDUALS WHO ARE ACUTELY AND SPECIFICALLY SENSITIVE TO TOLUENE MAY REQUIRE ADDITIONAL PROTECTIVE EQUIPMENT. STORAGE: TOLUENE SHOULD BE PROTECTED FROM TEMPERATURE EXTREMES AND DIRECT SUNLIGHT. PROPER STORAGE OF TOLUENE MUST BE DETERMINED BASED ON OTHER MATERIALS STORED AND THEIR HAZARDS AND POTENTIAL CHEMICAL INCOMPATIBILITY. IN GENERAL, TOLUENE SHOULD BE STORED IN AN ACCEPTABLY PROTECTED AND SECURE FLAMMABLE LIQUID STORAGE ROOM. OTHER: EMERGENCY EYEWASH FOUNTAINS AND SAFETY SHOWERS SHOULD BE AVAILABLE IN THE VICINITY OF ANY POTENTIAL EXPOSURE. GROUND AND BOND METAL CONTAINERS TO MINIMIZE STATIC SPARKS. VII. SPILL AND DISPOSAL DATA SPILL CONTROL: PROTECT FROM .IGNITION. WEAR PROTECTIVE CLOTHING AND USE APPROVED RESPIRATOR EQUIPMENT. ABSORB SPILLED MATERIAL IN AN ABSORBENT RECOMMENDED FOR SOLVENT SPILLS AND REMOVE TO A SAFE LOCATION FOR DISPOSAL BY APPROVED METHODS. IF RELEASED TO THE ENVIRONMENT, COMPLY WITH ALL REGULATORY NOTIFICATION REQUIREMENTS. CERCLA REPORTABLE QUANTITY: 1,000 POUNDS. WASTE DISPOSAL: DISPOSE OF TOLUENE AS AN EPA HAZARDOUS WASTE. CONTACT STATE ENVIRONMENTAL AGENCY FOR LISTING OF LICENSED HAZARDOUS WASTE DISPOSAL FACILITIES AND APPLICABLE REGULATIONS. HAZARDOUS WASTE NUMBER: U220 (TOXIC); F005 (TOXIC, IGNITABLE). HAZARD CLASSIFICATION CHEMICAL LISTINGS IMMEDIATE HEALTH: YES (IRRITANT) EXTREMELY HAZARDOUS SUBSTANCES: NO DELAYED HEALTH: YES CERCLA HAZARDOUS SUBSTANCES: YES FIRE: YES TOXIC CHEMICALS: YES SUDDEN RELEASE: NO REACTIVE: NO PAGE 3 TOLUENE IS SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA) AND 40CFR PART - 372. THIS PRODUCT DOES NOT CONTAIN ANY OTHER TOXIC CHEMICAL ABOVE 1X CONCENTRATION OR A CARCINOGEN ABOVE 0.1% CONCENTRATION. KEY CA APPROXIMATELY NA NOT APPLICABLE C CEIL.ING STEL SHORT TERM EXPOSURE LEVEL (15 MINUTES) TLV THRESHOLD LIMIT VALUE TWA TIME WEIGHTED AVERAGE BUAC BUTYL ACETATE CERCLA COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION AND LIABILITY ACT OF 1980 NSC NATIONAL SAFETY COUNCIL ( "FUNDAMENTALS OF INDUSTRIAL HYGIENE," 3RD ED., 1988) BURDICK & JACKSON'S DISCLAIMER: THE INFORMATION AND RECOMMENDATIONS PRESENTED IN THIS MATERIAL SAFETY DATA SHEET ARE BASED ON SOURCES BELIEVED TO BE RELIABLE ON THE DATE HEREOF. BURDICK & JACKSON MAKES NO REPRESENTATION ON ITS COMPLETENESS OR ACCURACY. IT IS THE USER'S RESPONSIBILITY TO DETERMINE THE PRODUCT'S SUITABILITY FOR ITS INTENDED USE, THE PRODUCT'S SAFE USE, AND THE PRODUCT'S PROPER DISPOSAL. NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR OF ANY OTHER NATURE ARE MADE WITH RESPECT TO THE INFORMATION PROVIDED IN THIS MATERIAL SAFETY DATA SHEET OR TO THE PRODUCT TO WHICH SUCH INFORMATION REFERS. BURDICK & JACKSON NEITHER ASSUMES NOR AUTHORIZES ANY OTHER PERSON TO ASSUME FOR IT, ANY OTHER OR ADDITIONAL LIABILITY OR RESPONSIBILITY RESULTING FROM THE USE OF, OR RELIANCE UPON, THIS INFORMATION. PAGE 4 (LAST PAGE) "ISSUED BY VWR 07/09/98" ############################################## t# # #t # # # # # # # # # # # # # # # # # # # # #t # # # # ## • # # # # # # # ## # # # # # # # # # # # # ## CA- IDMS /DC 12.0 VERSION 00062 tttttt # #R # # # # # #ttttt # # ## #############################$###### t## t####### t ## # # # # # #$t # # # # # # # # # # # #t # # # # # # ## # # # # # # # # # # # # # # ## USER ID = 005203 # # # # # # # # # # # # # # ## # # # # # # # # # # # # # # ## REPORT ID = PRLS3146 # # # # # # # # # # # # # # ## # # # # # # # # # # # # # # ## LTERM ID = UCLTG002 # # # # # # # # # # # # # # ## • # # # # # # # # # # # # # # ## INFO NAME = SDSCSITS # # # # # # # # # # # # # # ## • # # # # # # # # # # # # # # ## TIME AND DATE OF CREATION = 17:32:49 98.190 # # # # # # # # # # # # # # ## • ####### t######################################## # # # # #t #t # # # # # # # # # # # # # # # # # # # # # ## ####################### t######################## # # # # # # # # # # # # # # # # # # # # # # # # # # # # # ## ################################################ # # # # #t # # # # # # # # # # # # # # # # # # # # # # # ## i1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION MANUFACTURER EM SCIENCE A DIVISION OF EM INDUSTRIES P.O. BOX 70 480 DEMOCRAT RD. GIBBSTOWN, N.J. 00027 CATALOG NUMBER(S): XX0055 XX0055E XX0055P PRODUCT NAME XYLENE - SYNONYMS. ..: XYLOI., QIMETHYLQENZENE CHEMICAL FAMILY..: AROMATIC HYDROCARBON FORMULA C6H4(CH3)2 MOLECULAR WEIGHT.: 106.17 2. COMPOSITION / INFORMATION ON INGREDIENTS COMPONENT CAS # M- XYLENE 0- XYLENE P- XYLENE ETHYLBENZENE 108-38-3 95-47-6 106 -42 -3 100-41-4 XYLENE HAS BEEN ASSIGNED CAS# 1330 -20 -7. 3. HAZARDS IDENTIFICATION MATERIAL SAFETY- DATA SHEET EM SCIENCE PREPARATION DATE.; 10/10/95 DATE MSOS PRINTED.: DEC 18, 1995 INFORMATION PRONE NUMBER.: 609- 423.6300 HOURS: MON. TO FRI. 8:30 -5 CI-IGMTREC EMERGENCY NUMBER: 800- 424-•9300 HOURS: 24 MRS A DAY - XX0055S XX0057 XX0060 APPR 42X. 19% 18X 21% FLAMMABLE LIQUID AND VAPOR, VAPOR HARMFUL. MAY CAUSE DAMAGE TO LUNGS, THORAX, OR SENSE ORGANS. IRRITATING TO SKIN, EYES AND MUCOUS MEMBRANES. APPEARANCE COLORLESS LIQUID; AROMATIC ODOR . POTENTIAL HEALTH EFFECTS (ACUTE AND CHRONIC) SYMPTOMS OF EXPOSURE: HARMFUL OR FATAL IF SWALLOWED. VAPOR HARMFUL. CAUSES TEARING, BLURRED VISION, DIZZINESS, FATIGUE, LOSS OF APPETITE, NAUSEA, IRRITATION OF MUCOUS MEMBRANES. NARCOTIC AT HIGH CONCENTRATIONS. IRRITATING TO SKIN ON PROLONGED CONTACT CAUSING FLAKY DERMATITIS AND DEFATTING. LIQUID AND VAPOR IRRITATING TO EYES. MEDICAL CONO. AGGRAVATED BY EXPOSURE: DATA NOT AVAILABLE. ROUTES OF ENTRY INHALATION, INGESTION CARCINOGENICITY THE MATERIAL IS NOT LISTED (IARC, NTP, OSHA) AS CANCER CAUSING AGENT. 4. FIRST AID MEASURES EMERGENCY FIRST AID: GET MEDICAL ASSISTANCE FOR ALL CASES OF OVEREXPOSURE. SKIN: WASH THOROUGHLY WITH SOAP AND WATER. EYES: IMMEDIATELY FLUSH THOROUGHLY WITH WATER FOR AT LEAST 15 MINUTES. INHALATION: REMOVE TO FRESH AIR; GIVE ARTIFICIAL_ RESPIRATION IF BREATHING HAS STOPPED. INGESTION: CALL A PHYSICIAN IMMEDIATELY. ONLY INDUCE VOMITING AT THE INSTRUCTIONS OF A PHYSICIAN. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. REMOVE CONTAMINATED CLOTHING AND WASH BEFORE REUSE. 5. FIRE FIGHTING MEASURES FLASH POINT (F)..........: 85F (CC) FLAMMABLE LIMITS LEL (X),: 1.00 FLAMMABLE LIMITS UEL (X),: 7.00 MSDS (CONTINUED) - XX0055 PAGE 4 2 EXTINGUISHING MEDIA FOAM, DRY CHEMICAL, CO2 ; WATER SPRAY TO COOL FIRE - EXPOSED CONTAINERS. FIRE FIGHTING PROCEDURES.: WEAR SELF - CONTAINED BREATHING APPARATUS. FIRE & EXPLOSION HAZARDS.: VAPOR CAN TRAVEL DISTANCES TO IGNITION SOURCE AND FLASH BACK. 6. ACCIDENTAL RELEASE MEASURES SPILL RESPONSE: EVACUATE THE AREA OF ALL UNNECESSARY PERSONNEL. WEAR SUITABLE PROTECTIVE EQUIPMENT LISTED UNDER EXPOSURE / PERSONAL PROTECTION. ELIMINATE ANY IGNITION SOURCES UNTIL THE AREA IS DETERMINED TO BE FREE FROM EXPLOSION OR FIRE HAZARDS. CONTAIN THE RELEASE AND ELIMINATE ITS SOURCE, IF THIS CAN BE DONE WITHOUT RISK. TAKE UP AND CONTAINERIZE FOR PROPER DISPOSAL AS DESCRIBED UNDER DISPOSAL. COMPLY WITH FEDERAL, STATE, AND LOCAL REGULATIONS ON REPORTING RELEASES. REFER TO REGULATORY INFORMATION FOR REPORTABLE QUANTITY AND OTHER REGULATORY DATA. EM SCIENCE RECOMMENDS SPILL -X ABSORBENT AGENTS FOR VARIOUS TYPES OF SPILLS. ADDITIONAL INFORMATION ON THE SPILL -X PRODUCTS CAN BE PROVIDED THROUGH THE EM SCIENCE TECHNICAL SERVICE DEPARTMENT (609) 354 -9200. THE FOLLOWING EM SCIENCE SPILL -X ABSORBENT IS RECOMMENDED FOR THIS PRODUCT: SX0863 SOLVENT sr m. TREATMENT KIT 7. HANDLING AND STORAGE HANDLING & STORAGE: KEEP CONTAINER TIGHTLY CLOSED. STORE IN A COOL, WELL - VENTILATED AREA AWAY FROM IGNITION SOURCES AND OXIDIZERS. DO NOT BREATHE VAPOR. DO NOT GET IN EYES, ON SKIN OR ON CLOTHING NEVER USE WELDING OR CUTTING TORCH ON OR NEAR DRUM (EVEN EMPTY) BECAUSE PRODUCT (OR RESIDUE) MAY IGNITE EXPLOSIVELY. ELECTRICALLY GROUND ALL EQUIPMENT WHEN HANDLING THIS PRODUCT. RETAINED RESIDUE MAY MAKE EMPTY CONTAINERS HAZARDOUS; USE CAUTION! 8. EXPOSURE CONTROLS / PERSONAL PROTECTION MSDS (CONTINUED) - XX0055 PAGE # 3 ' .ENGINEERING CONTROLS AND PERSONAL PROTECTIVE EQUIPMENT: • VENTILATION RESPIRATORY PROTECTION, PROTECTIVE CLOTHING, EYE PROTECTION RESPIRATORY PROTECTION: IF WORKPLACE EXPOSURE LIMIT(S) OF PRODUCT OR ANY COMPONENT IS EXCEEDED (SEE TLV /PEL), A NIOSH /MSHA APPROVED AIR SUPPLIED RESPIRATOR IS ADVISED IN ABSENCE OF PROPER ENVIRONMENTAL CONTROL. OSHA REGULATIONS ALSO PERMIT OTHER NIOSH /MSHA RESPIRATORS (NEGATIVE PRESSURE TYPE) UNDER SPECIFIED CONDITIONS (SEE YOUR SAFETY EQUIPMENT SUPPLIER). ENGINEERING AND /OR ADMINISTRATIVE CONTROLS SHOULD BE IMPLEMENTED TO REDUCE EXPOSURE. MATERIAL MUST BE HANDLED OR TRANSFERRED IN AN APPROVED FUME HOOD OR WITH ADEQUATE VENTILATION PROTECTIVE GLOVES (PVA, VITON OR EQUIVALENT) SHOULD BE WORN TO PREVENT SKIN CONTACT. SAFETY GLASSES WITH SIDE SHIELDS MUST BE WORN AT ALL TIMES. WORK / HYGENIC PRACTICES: WASH THOROUGHLY AFTER HANDLING. DO NOT TAKE INTERNALLY. EYE WASH AND SAFETY EQUIPMENT SHOULD BE READILY AVAILABLE. EXPOSURE GUIDELINES OSHA - PEL: TWA STEL CL COMPONENT PPM MG /M3 PPM MG /M3 PPM MG /M3 SKIN M- XYLENE O- XYLENE P- XYLENE ETHYLBENZENE M- XYLENE • O- XYLENE P- XYLENE ETHYLBENZENE 100 435 150 655 100 435 150 655 100 435 150 655 100 435 125 545 ACGIH - TLV: TWA STEL CL COMPONENT PPM MG /M3 PPM MG /M3 PPM MG /M3 SKIN 100 434 150 651 100 434 150 651 100 434 150 651 100 434 125 543 9. PHYSICAL AND CHEMICAL PROPERTIES MSDS (CONTINUED) - XX0055 PAGE t 4 BOILING POINT (C 760 MMHG) : 138C MELTING POINT (C) : N/A SPECIFIC GRAVITY (H20 = 1) : 0.872 VAPOR PRESSURE (MM HG) : 5.1 20C PERCENT VOLATILE BY VOL (X): 99 +X VAPOR DENSITY (AIR = 1) : 3.6 EVAPORATION RATE (BOAC = 1): 0.61 SOLUBILITY IN WATER (X) • 0.02X APPEARANCE COLORLESS LIQUID; AROMATIC ODOR 10. STABILITY AND REACTIVITY STABILITY YES HAZARDOUS POLYMERIZATION: DOES NOT OCCUR HAZARDOUS DECOMPOSITION.: COX AND VARIOUS HYDROCARBONS CONDITIONS TO AVOID HEAT, CONTACT WITH IGNITION SOURCE MATERIALS TO AVOID ( ) WATER ( ) ACIDS ( ) BASES ( ) CORROSIVES (X) OXIDIZERS ( ) OTHER : 11. TOXICOLOGICAL INFORMATION TOXICITY DATA: ORL -RAT L050: 4300 MG /KG IHL -HMN TCL.O: 200 PPM TOXICOLOGICAL FINDINGS: TESTS ON LABORATORY ANIMALS INDICATE MATERIAL MAY PRODUCE ADVERSE MUTAGENIC EFFECTS. CITED IN REGISTRY OF TOXIC EFFECTS OF CHEMICAL SUBSTANCES (RTECS) 12. DISPOSAL CONSIDERATIONS EPA WASTE NUMBERS: 0001 U239 TREATMENT: INCINERATION, FUELS BLENDING OR RECYCLE. CONTACT YOUR LOCAL MSDS (CONTINUED) - XX0055 PAGE # 5 PERMITTED WASTE DISPOSAL SITE (TSD) FOR PERMISSIBLE TREATMENT SITES. ALWAYS CONTACT A PERMITTED WASTE DISPOSER (TSD) TO ASSURE COMPLIANCE WITH ALL CURRENT LOCAL, STATE AND FEDERAL REGULATIONS. 113. TRANSPORT INFORMATION DOT PROPER SHIPPING NAME : XYLENES DOT ID NUMBER UN1307 14. REGULATORY INFORMATION TSCA STATEMENT ...... ......: THIS PRODUCT IS A "MIXTURE ". THE CAS NUMBERS OF ALL COMPONENTS ARE LISTED ON THE TSCA INVENTORY. COMPONENT M- XYLENE O- XYLENE P- XYLENE ETHYLBENZENE SARA SARA CERCLA EHS EHS TPQ RQ (302) (IBS) (LBS) 1000 1000 100 1000 OSHA SARA DEHINIHIS COMPONENT FLOOR LIST 313 FOR SARA 313 (X) M- XYLENE O- XYLENE P- XYLENE ETHYLBENZENE Y Y 1.0 Y Y 1.0 Y Y 1.0 Y Y 1.0 15. OTHER INFORMATION MSDS (CONTINUED) - XX0055 PAGE # 6 COMMENTS: NONE NFPA HAZARD RATINGS: HEALTH : 2 FLAMMABILITY : 3 REACTIVITY : 0 SPECIAL HAZARDS REVISION HISTORY: 03/01/78 03/07/86 12/08/86 06/09/87 10/27/87 08/25/88 03/01/91 07/15/91 09/08/95 I = REVISED SECTION N/A = NOT AVAILABLE N/E = NONE ESTABLISHED THE STATEMENTS CONTAINED HEREIN ARE OFFERED FOR INFORMATIONAL_ PURPOSES ONLY AND ARE BASED UPON TECHNICAL DATA THAT EM SCIENCE BELIEVES TO BE ACCURATE. IT IS INTENDED FOR USE ONLY BY PERSONS HAVING THE NECESSARY TECHNICAL SKILL AND AT THEIR OWN DESCRETION AND RISK. SINCE CONDITIONS AND MANNER OF USE ARE OUTSIDE OUR CONTROL, WE MAKE NO WARRANTY, EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS OR OTHERWISE. MSDS - XX0055 PAGE # 7 "ISSUED BY VWR 07709/98" HAS BEEN DERIVED FROM AP.IEL RESEARCH CORP'S. INTERNATIONAL CHEMICAL REGULATORY MONITORING SYSTEM (ICRMS). USE OF THIS DATA IS SUBJECT TO THE TERMS OF A LICENSE AGREEMENT BETWEEN EM INDUSTRIES AND ARIEL RESEARCH CORP. FURTHER DISTRIBUTION WITHOUT AUTHORIZATION IS PROHIBITED. MSDS - AX0441 PAGE # 7 "ISSUED BY VWR 07/09/98" BURDICK 6 JACKSON, INC. 1953 SOUTH HARVEY STREET MUSKEGON, MI 49442 USA MATERIAL SAFETY DATA SHEET INFORMATION /EMERGENCY TELEPHONE NUMBER 616.726.3171 CHEMTREC TELEPHONE NUMBER 800.424.9300 CANADIAN EMERGENCY TELEPHONE NUMBER 613.996.6666 I. IDENTIFICATION CHEMICAL NAME: ETHYL ACETATE MOLECULAR WEIGHT: 88.11 CHEMICAL FAMILY: ESTER FORMULA: C411802 SYNONYMS: ETHYL ETIIANOATE, ACETIC ACID ETHYL ESTER DOT PROPER SHIPPING NAME: ETHYL ACETATE DOT HAZARD CLASS: FLAMMABLE LIQUID, HAZARD CLASS 3, P.G. II DOT IDENTIFICATION NUMBER: UN1173 CAS NUMBER: 141 -78 -6 II. PHYSICAL AND CHEMICAL DATA BOILING POINT, 760 MM HG: VAPOR PRESSURE AT 20 C: X VOLATILES BY VOLUME: FREEZING POINT: VAPOR DENSITY (AIR =1): SPECIFIC GRAVITY (H20 =1): EVAPORATION RATE: SOLUBILITY IN WATER: STABILITY: HAZARDOUS POLYMERIZATION: APPEARANCE AND ODOR: CONDITIONS TO AVOID: MATERIALS TO AVOID: HAZARDOUS DECOMPOSITION PRODUCTS: PAGE 1 ETHYL ACETATE REVISION DATE: JANUARY, 1995 REVISION NO: 1 77.11 C C 73.0 MM HG CA 100 -83.97 C 3.0 - e 20 C 0.901 (BUAC =1) CA 5 @ 20 C 8.7X STABLE NOT EXPECTED TO OCCUR CLEAR, COLORLESS LIQUID WITH A CHARACTERISTIC FRUITY ODOR HEAT, SPARKS, OPEN FLAME, OPEN CONTAINERS, AND POOR VENTILATION STRONG OXIDIZING AGENTS AND STRONG ACIDS AND BASES INCOMPLETE COMBUSTION CAN GENERATE CARBON MONOXIDE AND OTHER TOXIC VAPORS III. FIRE AND EXPLOSION HAZARD DATA FLASH POINT(TEST METHOD): -4 C(TAG CLOSED CUP) AUTO IGNITION TEMPERATURE: 426 C FLAMMABLE LIMITS IN AIR X BY VOLUME: LOWER LIMIT 2.2 UPPER LIMIT: 11.5 UNUSUAL FIRE AND EXPLOSION HAZARDS: VOLATILE AND FLAMMABLE EXTINGUISHING MEDIA: CARBON DIOXIDE, DRY CHEMICAL, OR ALCOHOL FOAM SPECIAL FIRE FIGHTING PROCEDURES: WEAR FULL PROTECTIVE CLOTHING AND SELF - CONTAINED BREATHING APPARATUS. HEAT WILL BUILD PRESSURE AND RUPTURE CLOSED STORAGE CONTAINERS. KEEP FIRE - EXPOSED CONTAINERS COOL WITH WATER SPRAY. IV. HAZARDOUS COMPONENTS ETHYL ACETATE V. HEALTH HAZARDS WT.% CA 100 TLV 400 PPM CAS NO. 141 -78 -6 OCCUPATIONAL EXPOSURE LIMITS CONCENTRATION IMMEDIATELY DANGEROUS TO HEALTH OSHA TWA 400 PPM STEL NOT LISTED OSIIA /NIOSU 10,000 PPM CEILING NOT - LISTED ACGIH TLV -TWA 400 PPM TLV -STEL NOT LISTED CARCINOGENIC DATA ETHYL ACETATE IS NOT LISTED AS A CARCINOGEN BY IARC, NTP, OSHA, OR ACGIH. PRIMARY ROUTES OF ENTRY ETHYL ACETATE MAY EXERT ITS EFFECTS THROUGH INHALATION, SKIN ADSORPTION, AND INGESTION. INDUSTRIAL EXPOSURE: ROUTE OF EXPOSURE /SIGNS AND SYMPTOMS INHALATION: EXPOSURE CAN CAUSE RESPIRATORY IRRITATION, HEADACHE, NAUSEA, LIVER AND KIDNEY DAMAGE, AND PULMONARY EDEMA. EYE CONTACT: LIQUID AND HIGH VAPOR CONCENTRATION CAN CAUSE IRRITATION, CONJUNCTIVITIS, AND CORNEAL CLOUDING. SKIN CONTACT: PROLONGED OR REPEATED SKIN CONTACT CAN CAUSE IRRITATION AND DERMATITIS THROUGH DEFATTING OF SKIN. INGESTION: CAN CAUSE IRRITATION OF GASTROINTESTINAL TRACT. EFFECTS OF OVEREXPOSURE ETHYL ACETATE IS A MILD EYE AND MUCOUS MEMBRANE IRRITANT, PRIMARY SKIN IRRITANT, AND CENTRAL NERVOUS SYSTEM DEPRESSANT. REPEATED CONTACT WITH ETHYL ACETATE PRODUCES ECZEMATOUS AND SENSITIZATION DERMATITIS. ACUTE INHALATION MAY PRODUCE NARCOSIS, ANEMIA, LIVER AND KIDNEY DAMAGE, AND PULMONARY EDEMA. MEDICAL CONDITION AGGRAVATED BY EXPOSURE PRECLUDE FROM EXPOSURE THOSE INDIVIDUALS WITH DISEASES OF EYES, LIVER, KIDNEYS, LUNGS, AND THOSE SUSCEPTIBLE TO DERMATITIS. EMERGENCY FIRST AID INHALATION: IMMEDIATELY REMOVE TO FRESH AIR. IF NOT BREATHING, ADMINISTER MOUTH -TO- MOUTH RESCUE BREATHING. IF THERE IS NO PULSE, ADMINISTER CARDIOPULMONARY RESUSCITATION (CPR). CONTACT PHYSICIAN IMMEDIATELY. EYE CONTACT: RINSE WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. GET EMERGENCY MEDICAL ASSISTANCE. PAGE 2 ODOR THRESHOLD NSC 10 PPM NIOSH 50 PPM SKIN CONTACT: FLUSH THOROUGHLY FOR Al LEAST 15 MINUTES. WASH AFFECTED SKIN WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND SHOES. WASH CLOTHING BEFORE RE -USE, AND DISCARD CONTAMINATED SHOES. GET EMERGENCY MEDICAL ASSISTANCE_. INGESTION: CALL LOCAL POISON CONTROL CENTER FOR ASSISTANCE. CONTACT PHYSICIAN IMMEDIATELY. NEVER INDUCE VOMITING OR GIVE ANYTHING BY MOUTH TO A VICTIM UNCONSCIOUS OR HAVING CONVULSIONS. VI. SAFETY MEASURES AND EQUIPMENT VENTILATION: ADEQUATE VENTILATION IS REQUIRED TO PROTECT PERSONNEL FROM EXPOSURE TO CHEMICAL VAPORS EXCEEDING TILE PEL AND TO MINIMIZE FIRE HAZARDS. THE CHOICE OF VENTILATION EQUIPMENT, EITHER LOCAL OR GENERAL, WILL DEPEND ON THE CONDITIONS OF USE, QUANTITY OF MATERIAL, AND OTHER OPERATING PARAMETERS. RESPIRATORY: USE APPROVED RESPIRATOR EQUIPMENT. FOLLOW NIOSII AND EQUIPMENT MANUFACTURER'S RECOMMENDATIONS TO DETERMINE APPROPRIATE EQUIPMENT (AIR - PURIFYING, AIR - SUPPLIED, OR SELF- CONTAINED BREATHING APPARATUS). EYES: SAFETY GLASSES ARE CONSIDERED MINIMUM PROTECTION. GOGGLES OR FACE SHIELD MAY BE NECESSARY DEPENDING ON QUANTITY OF MATERIAL AND CONDITIONS OF USE. SKIN: PROTECTIVE GLOVES AND CLOTHING ARE RECOMMENDED. TILE CHOICE OF MATERIAL MUST BE BASED ON CHEMICAL RESISTANCE AND OTHER USER REQUIREMENTS. GENERALLY, NEOPRENE OR NATURAL RUBBER OFFERS ACCEPTABLE CHEMICAL RESISTANCE. INDIVIDUALS WHO ARE ACUTELY AND SPECIFICALLY SENSITIVE TO ETHYL ACETATE MAY REQUIRE ADDITIONAL_ PROTECTIVE EQUIPMENT, STORAGE: ETHYL ACETATE SHOULD BE PROTECTED FROM TEMPERATURE EXTREMES AND DIRECT SUNLIGHT. PROPER STORAGE OF ETHYL ACETATE MUST BE DETERMINED BASED ON OTHER MATERIALS STORED AND THEIR HAZARDS AND POTENTIAL CHEMICAL INCOMPATIBILITY. IN GENERAL, ETHYL ACETATE SHOULD BE STORED IN AN ACCEPTABLY PROTECTED AND SECURE FLAMMABLE LIQUID STORAGE ROOM. OTHER: EMERGENCY EYEWASH FOUNTAINS AND SAFETY SHOWERS SHOULD BE AVAILABLE IN THE VICINITY OF ANY POTENTIAL EXPOSURE. GROUND AND BOND METAL CONTAINERS TO MINIMIZE STATIC SPARKS. VII. SPILL AND DISPOSAL DATA SPILL CONTROL: PROTECT FROM IGNITION. WEAR PROTECTIVE CLOTHING AND USE APPROVED RESPIRATOR EQUIPMENT. ADSORB SPILLED MA1ERIAL_ IN AN ABSORBENT RECOMMENDED FOR SOLVENT SPILLS AND REMOVE TO A SAFE LOCATION FOR DISPOSAL BY APPROVED METHODS. IF RELEASED TO THE ENVIRONMENT, COMPLY WITH ALL REGULATORY NOTIFICATION REQUIRE- MENTS. CERCLA REPORTABLE QUANTITY: 5,000 POUNDS. PAGE 3 WASTE DISPOSAL: DISPOSE OF ETHYL ACETATE AS AN EPA HAZARDOUS WASTE. CONTACT STATE ENVIRONMENTAL AGENCY FOR LISTING OF LICENSED HAZARDOUS WASTE DISPOSAL FACILITIES AND APPLICABLE- REGULATIONS. HAZARDOUS WASTE NUMBER: U112 (IGNITABLE); D001 (IGNITABLE); F003 (IGNITABLE). VIII. SARA /TITLE III DATA HAZARD CLASSIFICATION CHEMICAL LISTINGS IMMEDIATE HEALTH: YES (IRRITANT) EXTREMELY HAZARDOUS SUBSTANCES: NO DELAYED HEALTH: 'NO CERCLA HAZARDOUS SUBSTANCES: YES FIRE: YES TOXIC CHEMICALS: YES SUDDEN RELEASE: NO REACTIVE: NO ETHYL ACETATE IS SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA) AND 40CFR PART 372. THIS PRODUCT DOES NOT CONTAIN ANY OTHER TOXIC CHEMICAL ABOVE 1% CONCENTRATION OR A CARCINOGEN ABOVE 0.1% CONCENTRATION. KEY CA APPROXIMATELY NA NOT APPLICABLE C CEILING STEL SHORT TERM EXPOSURE LEVEL (15 MINUTES) TLV THRESHOLD LIMIT VALUE TWA TIME WEIGHTED AVERAGE BUAC BUTYL ACETATE CERCLA COMPREHENSIVE ENVIRONMENTAL. RESPONSE, COMPENSATION AND LIABILITY ACT OF 1980 NSC NATIONAL SAFETY COUNCIL ( "FUNDAMENTALS OF INDUSTRIAL. HYGIENE," 3RD ED., 1988) BURDICK & JACKSON'S DISCLAIMER: THE INFORMATION AND RECOMMENDATIONS PRESENTED IN THIS MATERIAL SAFETY DATA SHEET ARE BASED ON SOURCES BELIEVED TO BE RELIABLE ON THE DATE HEREOF. BURDICK & JACKSON MAKES NO REPRESENTATION ON ITS COMPLETENESS OR ACCURACY. IT IS THE USER'S RESPONSIBILITY TO DETERMINE THE PRODUCT'S SUITABILITY FOR ITS INTENDED USE, THE PRODUCT'S SAFE USE, AND THE PRODUCT'S PROPER DISPOSAL. NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR OF ANY OTHER NATURE ARE MADE WITH RESPECT TO THE INFORMATION PROVIDED IN THIS MATERIAL SAFETY DATA SHEET OR TO THE PRODUCT TO WHICH SUCH INFORMATION REFERS. BURDICK & JACKSON NEITHER ASSUMES NOR AUTHORIZES ANY OTHER PERSON TO ASSUME FOR IT, ANY OTHER OR ADDITIONAL LIABILITY OR RESPONSIBILITY RESULTING FROM THE USE OF, OR RELIANCE UPON, THIS INFORMATION. PAGE 4 (LAST PAGE) "ISSUED BY VLJR 07/09/98" BURDICK & JACKSON, INC. 1953 SOUTH HARVEY STREET MUSKEGON, MI 49442 USA MATERIAL SAFETY DATA SHEET INFORMATION /EMERGENCY TELEPHONE NUMBER 616.726.3171 CHEMTREC TELEPHONE NUMBER 800.424.9300 CANADIAN EMERGENCY TELEPHONE NUMBER 613.996.6666 I. IDENTIFICATION CHEMICAL NAME: ETHYL ETHER CHEMICAL FAMILY: ETHER SYNONYMS: DIETHYL ETHER, ETHER, ETHOXYETHANE DOT PROPER SHIPPING NAME: ETHYL ETHER DOT HAZARD CLASS: FLAMMABLE LIQUID, HAZARD CLASS 3, P.G. I DOT IDENTIFICATION NUMBER: UN1155 MOLECULAR WEIGHT: 74.12 FORMULA: C4H100 CAS NUMBER: 60 -29 -7 II. PHYSICAL AND CHEMICAL DATA BOILING POINT, 760 MM HG: 34.55 C VAPOR PRESSURE AT 20 C: 442 Mil HG X VOLATILES BY VOLUME: CA 100 FREEZING POINT: -117.4 C VAPOR DENSITY (AIR =1): 2.6 SPECIFIC GRAVITY (H20 =1): @ 20 C 0.713 EVAPORATION RATE: (BUAC =1) > 10 SOLUBILITY IN WATER: @ 20 C 6.89X STABILITY: UNSTABLE HAZARDOUS POLYMERIZATION: NOT EXPECTED TO OCCUR. APPEARANCE AND ODOR: CLEAR, COLORLESS LIQUID WITH A SWEET, PUNGENT ODOR. CONDITIONS TO AVOID: HEAT, SPARKS, OPEN FLAME, OPEN CONTAINERS, AND POOR VENTILATION MATERIALS TO AVOID: OXIDIZING AGENTS AND STRONG ACIDS HAZARDOUS DECOMPOSITION PRODUCTS: INCOMPLETE COMBUSTION CAN GENERATE CARBON MONOXIDE AND OTHER TOXIC VAPORS. EXPLOSIVE PEROXIDES CAN FORM AFTER STANDING OR UPON EXPOSURE TO AIR OR DIRECT SUNLIGHT. III. FIRE AND EXPLOSION HAZARD DATA FLASH POINT (TEST METHOD): -45 C (TAG CLOSED CUP) AUTO IGNITION TEMPERATURE: 160 C FLAMMABLE LIMITS IN AIR X BY VOLUME: LOWER LIMIT: 1.8 UPPER LIMIT: 48.0 UNUSUAL FIRE AND EXPLOSION HAZARDS: EXTREMELY VOLATILE AND EXTREMELY FLAMMABLE. CAN FORM HEAT- SENSITIVE PEROXIDES WIIICH MAY EXPLODE ON CONCENTRATING OR EVAPORATING. STORAGE UNDER HOT CONDITIONS 034.6 C) WILL CAUSE BOILING. COOL CONTENTS TO ROOM TEMPERATURE (22 C) BEFORE OPENING CONTAINERS. PAGE 1 ETHYL ETHER REVISION DATE: DECEMBER, 1993 REVISION NO: 1 EXTINGUISHING MEDIA: CARBON DIOXIDE, DRY CHEMICAL OR FOAM. SPECIAL FIRE FIGHTING PROCEDURES: WEAR FULL PROTECTIVE CLOTHING AND SELF- ~ CONTAINED BREATHING APPARATUS. HEAT WILL BUILD PRESSURE AND MAY RUPTURE CLOSED STORAGE CONTAINERS. KEEP FIRE - EXPOSED CONTAINERS COOL WITH WATER SPRAY. TREAT AS FLAMMABLE GAS. SURROUNDINGS MUST BE KEPT COOLED BELOW 160 C TO EXTINGUISH AN ETHER FIRE AND PREVENT REIGNITION. IV. HAZARDOUS COMPONENTS ETHYL ETHER WT.X' CA 100 V. HEALTH HAZARDS PAGE 2 TLV 400 PPM CAS NO. 60 -29 -7 OCCUPATIONAL EXPOSURE LIMITS CONCENTRATION IMMEDIATELY DANGEROUS TO HEALTH OSHA TWA 400 PPM STEL 500 PPM OSHA /NIOSH 19,000 PPM CEILING NOT LISTED ODOR THRESHOLD ACGIN TLV -TWA 400 PPM TLV -STEL 500 PPM NSC 1.0 PPM NIOSH 0.33 PPM CARCINOGENIC DATA ETHYL ETHER IS NOT LISTED AS A CARCINOGEN BY IARC, NIP, OSHA, OR ACGIH. PRIMARY ROUTES OF ENTRY ETHYL ETHER MAY EXERT ITS EFFECTS THROUGH INHALATION, SKIN ABSORPTION, AND INGESTION. INDUSTRIAL EXPOSURE: ROUTE OF EXPOSURE /SIGNS AND SYMPTOMS INHALATION: EXPOSURE CAN CAUSE HEADACHE, NAUSEA, VOMITING, LOSS OF CONSCIOUSNESS, AND, IN VERY HIGH CONCENTRATIONS, DEATH DUE TO RESPIRATORY PARALYSIS. EYE CONTACT: LIQUID AND HIGH VAPOR CONCENTRATION CAN CAUSE IRRITATION. SKIN CONTACT: PROLONGED OR REPEATED SKIN CONTACT CAN CAUSE IRRITATION AND DERMATITIS THROUGH DEFATTING OF SKIN. INGESTION: SYMPTOM INFORMATION IS INADEQUATE /UNKNOWN. EFFECTS OF OVEREXPOSURE ETHYL ETHER IS A MILD EYE AND MUCOUS MEMBRANE IRRITANT, PRIMARY SKIN IRRITANT, AND CENTRAL NERVOUS SYSTEM DEPRESSANT. ACUTE EXPOSURE CAN CAUSE ANESTHETIC EFFECTS SUCH AS VOMITING, EXCITEMENT, UNCONSCIOUSNESS, COMA, RESPIRATORY PARALYSIS, AND DEATH. CHRONIC EXPOSURES MAY PRODUCE CENTRAL NERVOUS SYSTEM DISTURBANCES. MEDICAL CONDITION AGGRAVATED BY EXPOSURE PRECLUDE FROM EXPOSURE THOSE INDIVIDUALS SUSCEPTIBLE TO DERMATITIS. EMERGENCY FIRST AID INHALATION: IMMEDIATELY REMOVE TO FRESH AIR. IF NOT BREATHING, ADMINISTER MOUTH -TO -MOUTH RESCUE BREATHING. IF THERE IS NO PULSE, ADMINISTER CARDIOPULMONARY RESUSCITATION (CPR). CONTACT PHYSICIAN IMMEDIATELY. EYE CONTACT: RINSE WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. GET EMERGENCY MEDICAL ASSISTANCE. SKIN CONTACT: FLUSH THOROUGHLY FOR AT LEAST 15 MINUTES. WASH AFFECTED SKIN WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND SHOES. WASH CLOTHING BEFORE RE -USE, AND DISCARD CONTAMINATED SHOES. GET EMERGENCY MEDICAL ASSISTANCE. INGESTION: CALL LOCAL POISON! CONTROL CENTER FOR ASSISTANCE. CONTACT PHYSICIAN IMMEDIATELY. NEVER INDUCE VOMITING OR GIVE ANYTHING BY MOUTH TO A VICTIM UNCONSCIOUS OR HAVING CONVULSIONS. VI. SAFETY MEASURES AND EQUIPMENT VENTILATION: ADEQUATE VENTILATION IS REQUIRED TO PROTECT PERSONNEL FROM EXPOSURE TO CHEMICAL VAPORS EXCEEDING THE PEL AND TO MINIMIZE FIRE HAZARDS. THE CHOICE OF VENTILATION EQUIPMENT, EITHER LOCAL OR GENERAL, WILL DEPEND ON THE CONDITIONS OF USE, QUANTITY OF MATERIAL, AND OTHER OPERATING PARAMETERS. RESPIRATORY: USE APPROVED RESPIRATOR EQUIPMENT. FOLLOW NIOSH AND EQUIPMENT MANUFACTURER'S RECOMMENDATIONS TO DETERMINE APPROPRIATE EQUIPMENT (AIR - PURIFYING, AIR - SUPPLIED, OR SELF- - CONTAINED BREATHING APPARATUS). EYES: SAFETY GLASSES ARE CONSIDERED MINIMUM PROTECTION. GOGGLES OR FACE SHIELD MAY BE NECESSARY DEPENDING ON QUANTITY OF MATERIAL AND CONDITIONS OF USE. SKIN: PROTECTIVE GLOVES AND CLOTHING ARE RECOMMENDED. THE CHOICE OF MATERIAL MUST BE BASED ON CHEMICAL RESISTANCE AND OTHER USER REQUIREMENTS. GENERALLY NEOPRENE OR NITRILE RUBBER OFFERS ACCEPTABLE CHEMICAL RESISTANCE. INDIVIDUALS WHO ARE ACUTELY AND SPECIFICALLY SENSITIVE TO ETHYL ETHER MAY REQUIRE ADDITIONAL PROTECTIVE EQUIPMENT. STORAGE: ETHYL ETHER SHOULD BE PROTECTED FROM TEMPERATURE EXTREMES AND DIRECT SUNLIGHT. PROPER STORAGE OF ETHYL ETHER MUST BE DETERMINED BASED ON OTHER MATERIALS STORED AND THEIR HAZARDS AND POTENTIAL CHEMICAL INCOMPATIBILITY. IN GENERAL, ETHYL ETHER SHOULD BE STORED IN AN ACCEPTABLY PROTECTED AND SECURE FLAMMABLE LIQUID STORAGE ROOM. DO NOT OPEN CONTAINER IF PEROXIDE CRYSTALS FORM IN LIQUID OR AROUND CLOSURE. DO NOT CONCENTRATE IF PEROXIDE CONCENTRATIONS EXCEED 0.01% OR 100 PPM. CONTACT THE MANUFACTURER FOR APPROPRIATE PEROXIDE TREATMENT AND HANDLING METHODS. STORAGE OF ETHYL ETHER UNDER HOT CONDITIONS () 34 C) WILL CAUSE THE LIQUID TO BOIL. IF THE CONTAINER IS OPENED BEFORE ALLOWING TO COOL TO ROOM TEMPERATURE (22 C), THE LIQUID COULD BOIL OVER OUT OF THE CONTAINER. OTHER: EMERGENCY EYEWASH FOUNTAINS AND SAFETY SHOWERS SHOULD DE AVAILABLE IN THE VICINITY OF ANY POTENTIAL EXPOSURE. GROUND AND BOND METAL CONTAINERS TO MINIMIZE STATIC SPARKS. VII. SPILL AND DISPOSAL DATA SPILL CONTROL: PROTECT FROM IGNITION. WEAR PROTECTIVE CLOTHING AND USE APPROVED RESPIRATOR EQUIPMENT. ADSORB SPILLED MATERIAL. IN AN ADSORBENT RECOMMENDED FOR SOLVENT SPILLS AND REMOVE TO A SAFE LOCATION FOR DISPOSAL BY APPROVED METHODS. IF RELEASED TO THE ENVIRONMENT, COMPLY WITH ALL REGULATORY NOTIFICATION REQUIREMENTS. CERCLA REPORTABLE QUANTITY: 100 POUNDS. PAGE 3 WASTE DISPOSAL: DISPOSE OF ETHYL. ETHER AS AN EPA HAZARDOUS WASTE. CONTACT STATE ENVIRONMENTAL AGENCY FOR LISTING OF LICENSED HAZARDOUS WASTE DISPOSAL FACILITIES AND APPL.ICABLE REGULATIONS. HAZARDOUS WASTE NUMBER: U117 (IGNITABLE); F003 (IGNITABLE). HAZARD CLASSIFICATION IMMEDIATE HEALTH: YES (IRRITANT) DELAYED HEALTH: NO FIRE: YES SUDDEN RELEASE: NO REACTIVE: NO KEY CA APPROXIMATELY NA NOT APPLICABLE C CEILING CHEMICAL LISTINGS EXTREMELY HAZARDOUS SUBSTANCES: NO CERCLA HAZARDOUS SUBSTANCES: YES TOXIC CHEMICALS: NO ETHYL ETHER IS SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA) AND 40CFR PART 372. THIS PRODUCT DOES NOT CONTAIN ANY OTHER TOXIC CHEMICAL ABOVE IX CONCENTRATION OR A CARCINOGEN ABOVE 0.1X CONCENTRATION. STEL SHORT TERM EXPOSURE LEVEL (15 MINUTES) TLV THRESHOLD LIMIT VALUE TWA TIME WEIGHTED AVERAGE BUAC BUTYL ACETATE CERCLA COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION AND LIABILITY ACT OF 1980 NSC NATIONAL SAFETY COUNCIL ("FUNDAMENTALS OF INDUSTRIAL HYGIENE," 3RD ED., 1988 BURDICK & JACKSON'S DISCLAIMER: THE INFORMATION AND RECOMMENDATIONS PRESENTED IN THIS MATERIAL SAFETY DATA SHEET ARE 9ASED ON SOURCES BELIEVED TO BE RELIABLE ON THE DATE HEREOF. BURDICK & JACKSON MAKES NO REPRESENTATION ON ITS COMPLETENESS OR ACCURACY. IT IS THE USER'S RESPONSIBILITY TO DETERMINE THE PRODUCT'S SUITABILITY FOR ITS INTENDED USE, THE PRODUCT'S SAFE USE, AND THE PRODUCT'S PROPER DISPOSAL. NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR OF ANY OTHER NATURE ARE MADE WITH RESPECT TO THE INFORMATION PROVIDED IN THIS MATERIAL SAFETY DATA SHEET OR TO THE PRODUCT TO WHICH SUCH INFORMATION REFERS. BURDICK & JACKSON NEITHER ASSUMES NOR AUTHORIZES ANY OTHER PERSON TO ASSUME FOR IT, ANY OTHER OR ADDITIONAL LIABILITY OR RESPONSIBILITY RESULTING FROM THE USE OF, OR RELIANCE UPON, THIS INFORMATION. PAGE 4 (LAST PAGE) "ISSUED BY VUR 07/09/98" BURDICK & JACKSON, INC. 1953 SOUTH HARVEY STREET < MUSKEGON, MI 49442 USA MATERIAL SAFETY DATA SHEET INFORMATION /EMERGENCY TELEPHONE NUMBER 616.726.3171 CHEMTREC TELEPHONE NUMBER 800.424.9300 CANADIAN EMERGENCY TELEPHONE NUMBER 613.996.6666 I. IDENTIFICATION CHEMICAL NAME: HEXANE CHEMICAL FAMILY: ALIPHATIC HYDROCARBON SYNONYMS: N- HEXANE DOT PROPER SHIPPING NAME: HEXANE DOT HAZARD CLASS: FLAMMABLE LIQUID, HAZARD CLASS 3, P.G. II. DOT IDENTIFICATION NUMBER: UN1208 MOLECULAR WEIGHT: 86.18 FORMULA: C6H14 CAS NUMBER: 110 -54 -3 II. PHYSICAL AND CHEMICAL DATA BOILING POINT, 760 MM HG: 68.7 C VAPOR PRESSURE AT 20 C: 124 MM HG X VOLATILES BY VOLUME: CA 100 FREEZING POINT: -95.3 C VAPOR DENSITY (AIR =1): 3.0 SPECIFIC GRAVITY (H20 =1): e 20 C 0.659 EVAPORATION RATE: (BUAC =1) CA 16 SOLUBILITY IN WATER: @ 20 C 0.014X STABILITY: STABLE HAZARDOUS POLYMERIZATION: NOT EXPECTED TO OCCUR. APPEARANCE AND ODOR: CLEAR, COLORLESS LIQUID WITH A MILD HYDROCARBON ODOR. CONDITIONS TO AVOID: HEAT, SPARKS, OPEN FLAME, OPEN CONTAINERS, AND POOR VENTILATION. MATERIALS TO AVOID: STRONG OXIDIZING AGENTS. HAZARDOUS DECOMPOSITION PRODUCTS: INCOMPLETE COMBUSTION CAN GENERATE CARBON MONOXIDE AND OTHER TOXIC VAPORS. III. FIRE AND EXPLOSION HAZARD DATA HEXANE FLASH POINT (TEST METHOD): -26 C (TAG CLOSED CUP) AUTO IGNITION TEMPERATURE: 225 C REVISION DATE: DECEMBER, 1993 REVISION NO: 1 . FLAMMABLE LIMITS IN AIR X BY VOLUME: LOWER LIMIT: 1.1 UPPER LIMIT: 7.5 UNUSUAL FIRE AND EXPLOSION HAZARDS: VERY VOLATILE AND EXTREMELY FLAMMABLE. EXTINGUISHING MEDIA: CARBON DIOXIDE, DRY CHEMICAL. OR FOAM. PAGE 1 SPECIAL FIRE FIGHTING PROCEDURES: WATER WILL NOT DE EFFECTIVE IN EXTINGUISHING A FIRE AND MAY SPREAD IT, BUT A WATER SPRAY CAN BE USED TO COOL EXPOSED CONTAINERS. WEAR FULL PROTECTIVE CLOTHING AND SELF - CONTAINED BREATHING APPARATUS. HEAT WILL BUILD PRESSURE AND MAY RUPTURE CLOSED STORAGE CONTAINERS. IV. HAZARDOUS COMPONENTS HEXANE & ISOMERS V. HEALTH HAZARDS CWT . X CA 100 TLV 50 PPM CAS NO. 110 -54 -3 OCCUPATIONAL EXPOSURE LIMITS CONCENTRATION IMMEDIATELY DANGEROUS TO HEALTH OSHA TWA 50 PPM OSHA /NIOSH 5,000 PPM STEL NOT LISTED CEILING NOT LISTED ODOR THRESHOLD ACGIH TLV -TWA 50 PPM TLV -STEL NOT LISTED NSC NOT LISTED NIOSH NOT LISTED NIOSH- 10 -HOUR TWA 50 PPM CEILING HOT LISTED CARCINOGENIC DATA HEXANE IS NOT LISTED AS A CARCINOGEN BY IARC, NTP, OSHA, OR ACGIH. PRIMARY ROUTES OF ENTRY HEXANE MAY EXERT ITS EFFECTS THROUGH INHALATION, SKIN ABSORPTION, AND INGESTION. INDUSTRIAL EXPOSURE: ROUTES OF EXPOSURE /SIGNS AND SYMPTOMS INHALATION: EXPOSURE CAN CAUSE DIZZINESS, NUMBNESS OF EXTREMITIES, AND INTOXICATION. EYE CONTACT: LIQUID AND HIGH VAPOR CONCENTRATION CAN CAUSE IRRITATION. SKIN CONTACT: PROLONGED OR REPEATED SKIN CONTACT CAN CAUSE IRRITATION AND DERMATITIS THROUGH DEFATTING OF SKIN. INGESTION: CAN CAUSE GASTROINTESTINAL TRACT DISCOMFORT. EFFECTS OF OVEREXPOSURE HEXANE IS A MILD EYE AND MUCOUS MEMBRANE IRRITANT, PRIMARY SKIN IRRITANT, AND CENTRAL NERVOUS SYSTEM DEPRESSANT AND NEUROTOXIN. ACUTE EXPOSURE CAUSES IRRITATION, NARCOSIS, AND GASTROINTESTINAL_ TRACT IRRITATION. CHRONIC INHALATION CAUSES PERIPHERAL NEUROPATHY. NO SYSTEMIC TOXICITY HAS BEEN REPORTED. MEDICAL CONDITION AGGRAVATED BY EXPOSURE PRECLUDE FROM EXPOSURE THOSE INDIVIDUALS SUSCEPTIBLE TO DERMATITIS. EMERGENCY FIRST AID INHALATION: IMMEDIATELY REMOVE TO FRESH AIR. IF NOT BREATHING, ADMINISTER MOUTH -TO -MOUTH RESCUE BREATHING. IF THERE IS NO PULSE, ADMINISTER CARDIOPULMONARY RESUSCITATION (CPR). CONTACT PHYSICIAN IMMEDIATELY. EYE CONTACT: RINSE WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. GET EMERGENCY MEDICAL ASSISTANCE. PAGE 2 SKIN CONTACT: FLUSH THOROUGHLY FOR AT LEAST 15 MINUTES. WASH AFFECTED SKIN - WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND SHOES. WAS!! CLOTHING BEFORE RE -USE, AND DISCARD CONTAMINATED SHOES. GET EMERGENCY MEDICAL ASSISTANCE. INGESTION: CALL LOCAL POISON CONTROL CENTER FOR ASSISTANCE. CONTACT PHYSICIAN IMMEDIATELY. ASPIRATION HAZARD - DO NOT INDUCE VOMITING. VI. SAFETY MEASURES AND EQUIPMENT VENTILATION: ADEQUATE VENTILATION IS REQUIRED TO PROTECT PERSONNEL FROM EXPOSURE TO CHEMICAL VAPORS EXCEEDING THE PEL AND TO MINIMIZE FIRE HAZARDS. THE CHOICE OF VENTILATION EQUIPMENT, EITHER LOCAL OR GENERAL, WILL DEPEND ON THE CONDITIONS OF USE, QUANTITY OF MATERIAL., AND OTHER OPERATING PARAMETERS. RESPIRATORY: USE APPROVED RESPIRATOR EQUIPMENT. FOLLOW NIOSH AND EQUIPMENT MANUFACTURER'S RECOMMENDATIONS TO DETERMINE APPROPRIATE EQUIPMENT (AIR - PURIFYING, AIR - SUPPLIED, OR SELF - CONTAINED BREATHING APPARATUS). EYES: SAFETY GLASSES ARE CONSIDERED MINIMUM PROTECTION. GOGGLES OR FACE SHIELD MAY BE NECESSARY DEPENDING ON QUANTITY OF MATERIAL AND CONDITIONS OF USE. SKIN: PROTECTIVE GLOVES AND CLOTHING ARE RECOMMENDED. THE CHOICE OF MATERIAL MUST BE BASED ON CHEMICAL_ RESISTANCE AND OTHER USER REQUIREMENTS. GENERALLY, NEOPRENE OR NITRILE RUBBER OFFERS ACCEPTABLE CHEMICAL RESISTANCE. INDIVIDUALS WHO ARE ACUTELY AND SPECIFICALLY SENSITIVE TO HEXANE MAY REQUIRE ADDITIONAL PROTECTIVE EQUIPMENT. STORAGE: HEXANE SHOULD BE PROTECTED FROM TEMPERATURE EXTREMES AND DIRECT SUNLIGHT. PROPER STORAGE OF HEXANE IIUST BE DETERMINED BASED ON OTHER iMATERIALS STORED AND THEIR HAZARDS AND POTENTIAL_ CHEMICAL_ INCOMPATIBILITY. IN GENERAL, HEXANE SHOULD BE STORED IN AN ACCEPTABLY PROTECTED AND SECURE FLAMMABLE LIQUID STORAGE ROOM. OTHER: EMERGENCY EYEWASH FOUNTAINS AND SAFETY SHOWERS SHOULD BE AVAILABLE IN THE VICINITY OF ANY POTENTIAL EXPOSURE. GROUND AND BOND METAL CONTAINERS TO MINIMIZE STATIC SPARKS. VII. SPILL AND DISPOSAL DATA SPILL CONTROL: PROTECT FROM IGNITION. WEAR PROTECTIVE CLOTHING AND USE APPROVED RESPIRATOR EQUIPMENT: ABSORB SPILLED MATERIAL_ IN AN ABSORBENT RECOMMENDED FOR SOLVENT SPILLS AND REMOVE TO A SAFE LOCATION FOR DISPOSAL BY APPROVED METHODS. IF RELEASED TO THE ENVIRONMENT, COMPLY WITH ALL REGULATORY NOTIFICATION REQUIREMENTS. CERCLA REPORTABLE QUANTITY: NONE. WASTE DISPOSAL: DISPOSE OF HEXANE AS AN EPA HAZARDOUS WASTE. CONTACT STATE ENVIRONMENTAL AGENCY FOR LISTING OF LICENSED HAZARDOUS WASTE DISPOSAL FACILITIES AND APPLICABLE REGULATIONS. HAZARDOUS WASTE NUMBER: D001 (IGNITABLE). HAZARD CLASSIFICATION IMMEDIATE HEALTH: YES (IRRITANT) DELAYED HEALTH: YES FIRE: YES SUDDEN RELEASE: NO REACTIVE: NO PAGE 3 CHEMICAL LISTINGS EXTREHELY HAZARDOUS SUBSTANCES: NO CERCLA HAZARDOUS SUBSTANCES: NO TOXIC CHEMICALS: NO HEXANE IS NOT SUBJECT TO THE REPORTING REQUIREMENTS Of SECTION 313 OF TITLE III - OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA) AND 40CFR PART 372. THIS PRODUCT DOES NOT CONTAIN ANY OTHER TOXIC CHEMICAL ABOVE 1% CONCENTRATION OR A CARCINOGEN ABOVE 0.1% CONCENTRATION. KEY CA APPROXIMATELY NA NOT APPLICABLE C CEILING STEL SHORT TERM EXPOSURE LEVEL (15 MINUTES) TLV THRESHOLD LIMIT VALUE TWA TIME WEIGHTED AVERAGE BUAC BUTYL ACETATE CERCLA COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION AND LIABILITY ACT OF 1980 NSC NATIONAL SAFETY COUNCIL ( "FUNDAMENTALS OF INDUSTRIAL HYGIENE," 3R0 ED., 1988) BURDICK & JACKSON'S DISCLAIMER: THE INFORMATION AND RECOMMENDATIONS PRESENTED IN THIS MATERIAL SAFETY DATA SHEET ARE BASED ON SOURCES BELIEVED TO DE RELIABLE HE DATE HEREOF. BURDICK & JACKSON MAKES NO REPRESENTATION ON ITS COMPLETENESS OR ACCURACY. IT IS THE USER'S RESPONSIBILITY TO DETERMINE THE PRODUCT'S SUITABILITY FOR ITS INTENDED USE, THE PRODUCT'S SAFE USE, AND THE PRODUCT'S PROPER DISPOSAL. NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR OF ANY OTHER NATURE ARE MADE WITH RESPECT TO THE INFORMATION PROVIDED IN THIS MATERIAL SAFETY DATA SHEET OR TO THE PRODUCT TO WHICH SUCH INFORMATION REFERS. BURDICK & JACKSON NEITHER ASSUMES NOR AUTHORIZES ANY OTHER PERSON TO ASSUME FOR IT, ANY OTHER OR ADDITIONAL LIABILITY OR RESPONSIBILITY RESULTING FROM THE USE OF, OR RELIANCE UPON, THIS INFORMATION. PAGE 4 (LAST PAGE) "ISSUED BY VUR 07/09/98" BURDICK & JACKSON, INC. - 1953 SOUTH HARVEY STREET . MUSKEGON, MI 49442 USA MATERIAL SAFETY DATA SHEET INFORMATION /EMERGENCY TELEPHONE NUMBER 616.726.3171 CHEMTREC TELEPHONE NUMBER • 800.424.9300 CANADIAN EMERGENCY TELEPHONE NUMBER 613.996.6666 I. IDENTIFICATION II. PHYSICAL AND CHEMICAL DATA III. FIRE AND EXPLOSION HAZARD DATA ISOPROPYL ALCOHOL REVISION DATE: JUNE, 1995 REVISION NO: 2 CHEMICAL NAME: ISOPROPYL ALCOHOL CHEMICAL. FAMILY: ALCOHOL SYNONYMS: 2- PROPANOL, ISOPROPANOL, LACTOL DOT PROPER SHIPPING NAME: ISOPROPANOL DOT HAZARD CLASS: FLAMMABLE LIQUID, HAZARD CLASS 3, P.G. II DOT IDENTIFICATION NUMBER: UN1219 MOLECULAR WEIGHT: 60.09 FORMULA: C3H80 CAS NUMBER: 67 -63 -0 BOILING POINT, 760 MM HG: 82.26 C VAPOR PRESSURE AT 20 C: 32.4 MM HG X VOLATILES BY VOLUME: CA 100 FREEZING POINT: -88.0 C VAPOR DENSITY (AIR =1): 2.1 SPECIFIC GRAVITY (H20 =1): 8 20 C 0.785 EVAPORATION RATE: (BUAC =1) CA 3 SOLUBILITY IN WATER: 20 C COMPLETE STABILITY: STABLE HAZARDOUS POLYMERIZATION: NOT EXPECTED TO OCCUR. APPEARANCE AND ODOR: CLEAR, COLORLESS LIQUID WITH A SLIGHT ALCOHOLIC ODOR. CONDITIONS TO AVOID: HEAT, SPARKS, OPEN FLAME, OPEN CONTAINERS, AND POOR VENTILATION. MATERIALS TO AVOID: STRONG OXIDIZING AGENTS, STRONG ACIDS, AND REACTIVE METALS, INCLUDING ALUMINUM, WHICH WILL DISPLACE HYDROGEN. HAZARDOUS DECOMPOSITION PRODUCTS: INCOMPLETE COMBUSTION CAN GENERATE CARBON MONOXIDE AND OTHER TOXIC VAPORS. FLASH POINT (TEST METHOD): 12 C (TAG CLOSED CUP) AUTO IGNITION TEMPERATURE: 399 C FLAMMABLE LIMITS IN AIR X BY VOLUME: LOWER LIMIT: 2.0 UPPER LIMIT: 12.0 UNUSUAL FIRE AND EXPLOSION HAZARDS: VOLATILE AND FLAMMABLE. EXTINGUISHING MEDIA: CARBON DIOXIDE, DRY CHEMICAL, ALCOHOL FOAM, WATER MIST OR FOG. PAGE 1 SPECIAL FIRE FIGHTING PROCEDURES: WEAR FULL PROTECTIVE CLOTHING AND SELF- : CONTAINED BREATHING APPARATUS. HEAT WILL B3UILD PRESSURE AND RUPTURE CLOSED STORAGE CONTAINERS. KEEP FIRE - EXPOSED CONTAINERS COOL WITH WATER SPRAY. IV. HAZARDOUS COMPONENTS ISOPROPYL ALCOHOL V. HEALTH HAZARDS WT.X CA 100 TLV 400 PPM CAS NO. 67 -63 -0 OCCUPATIONAL EXPOSURE LIMITS CONCENTRATION IMMEDIATELY DANGEROUS TO HEALTH OSHA TWA 400 PPM STEL 500 PPM OSHA / NIOSH 12,000 PPM CEILING NOT LISTED PAGE 2 ODOR THRESHOLD ACGIH TLV -TWA 400 PPM TLV -STEL 500 PPM NSC 50 PPM NIOSH 10 -HOUR TWA 400 PPM STEL 500 PPM CARCINOGENIC DATA ISOPROPYL ALCOHOL IS NOT LISTED AS A CARCINOGEN BY IARC, NTP, OSHA, OR ACGIH. PRIMARY ROUTES OF ENTRY ISOPROPYL ALCOHOL MAY EXERT ITS EFFECTS THROUGH INHALATION, SKIN ABSORPTION, AND INGESTION. INDUSTRIAL EXPOSURE: ROUTE OF EXPOSURE /SIGNS AND SYMPTOMS INHALATION: EXPOSURE CAN CAUSE COUGHING, SHORTNESS OF BREATH, DIZZINESS, AND INTOXICATION. EYE CONTACT: LIQUID AND HIGH VAPOR CONCENTRATION CAN CAUSE MODERATE BURNING, WATERING, SWELLING, AND REDNESS. SKIN CONTACT: EXTENSIVE, REPEATED AND /OR PROLONGED SKIN CONTACT CAN CAUSE BURNING, ITCHING, REDNESS, AND DERMATITIS. INGESTION: CAUSES BURNING OF THE GASTROINTESTINAL TRACT AND TOXIC EFFECTS. SWALLOWING MORE THAN 250 ML OF ISOPROPYL ALCOHOL CAN CAUSE DEATH. EFFECTS OF OVEREXPOSURE ISOPROPYL ALCOHOL IS A MILD EYE AND MUCOUS MEMBRANE IRRITANT, PRIMARY SKIN IRRITANT, AND CENTRAL NERVOUS SYSTEM DEPRESSANT. ACUTE EXPOSURE CAN CAUSE GASTROINTESTINAL TRACT UPSET AND NARCOSIS. MEDICAL CONDITION AGGRAVATED BY EXPOSURE PRECLUDE FROM EXPOSURE THOSE INDIVIDUALS SUSCEPTIBLE TO DERMATITIS. EMERGENCY FIRST AID INHALATION: IMMEDIATELY REMOVE TO FRESH AIR. IF NOT BREATHING, ADMINISTER MOUTH -TO -MOUTH RESCUE BREATHING. IF THERE IS NO PULSE, ADMINISTER CARDIOPULMONARY RESUSCITATION (CPR). CONTACT PHYSICIAN IMMEDIATELY. EYE CONTACT: RINSE WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. GET EMERGENCY MEDICAL ASSISTANCE. - SKIN CONTACT: FLUSH THOROUGHLY FOR AT LEAST 15 MINUTES. WASH AFFECTED SKIN - WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND SHOES. WASH CLOTHING < BEFORE RE -USE, AND DISCARD CONTAMINATED SHOES. GET EMERGENCY MEDICAL ASSISTANCE. INGESTION: CALL LOCAL POISON CONTROL CENTER FOR ASSISTANCE. CONTACT PHYSICIAN IMMEDIATELY. NEVER INDUCE VOMITING OR GIVE ANYTHING BY MOUTH TO A VICTIM UNCONSCIOUS OR HAVING CONVULSIONS. VI. SAFETY MEASURES AND EQUIPMENT VENTILATION: ADEQUATE VENTILATION IS REQUIRED TO PROTECT PERSONNEL FROM EXPOSURE TO CHEMICAL. VAPORS EXCEEDING THE PEI_ AND TO MINIMIZE FIRE HAZARDS. THE CHOICE OF VENTIL.ATION EQUIPMENT, EITHER LOCAL OR GENERAL, WILL DEPEND ON THE CONDITIONS OF USE, QUANTITY OF MATERIAL, AND OTHER OPERATING PARAMETERS. RESPIRATORY: USE APPROVED RESPIRATOR EQUIPMENT. FOLLOW NIOSH AND EQUIPMENT MANUFACTURER'S RECOMMENDATIONS TO DETERMINE APPROPRIATE EQUIPMENT (AIR - PURIFYING, AIR - SUPPLIED, OR SELF- CONTAINED BREATHING APPARATUS). EYES: SAFETY GLASSES ARE CONSIDERED MINIMUM PROTECTION. GOGGLES OR FACE SHIELD MAY BE NECESSARY DEPENDING ON QUANTITY OF MATERIAL AND CONDITIONS OF USE. SKIN: PROTECTIVE GLOVES AND CLOTHING ARE RECOMMENDED. THE CHOICE OF MATERIAL MUST BE BASED ON CHEMICAL RESISTANCE AND OTHER USER REQUIREMENTS. GENERALLY, NEOPRENE, NITRILE RUBBER, OR NATURAL RUBBER OFFERS ACCEPTABLE CHEMICAL RESISTANCE. INDIVIDUALS WHO ARE ACUTELY AND SPECIFICALLY SENSITIVE TO ISOPROPYL ALCOHOL MAY REQUIRE ADDITIONAL PROTECTIVE EQUIPMENT. STORAGE: ISOPROPYL ALCOHOL SHOULD BE PROTECTED FROM TEMPERATURE EXTREMES AND DIRECT SUNLIGHT. PROPER STORAGE OF ISOPROPYL ALCOHOL MUST DE DETERMINED BASED ON OTHER MATERIALS STORED AND THEIR HAZARDS AND POTENTIAL CHEMICAL INCOMPATIBILITY. IN GENERAL, ISOPROPYL. ALCOHOL SHOULD BE STORED IN AN ACCEPTABLY PROTECTED AND SECURE FLAMMABLE LIQUID STORAGE ROOM. OTHER: EMERGENCY EYEWASH FOUNTAINS AND SAFETY SHOWERS SHOULD DE AVAILABLE IN THE VICINITY OF ANY POTENTIAL EXPOSURE. GROUND AND BOND METAL CONTAINERS TO MINIMIZE STATIC SPARKS. VII. SPILL AND DISPOSAL DATA SPILL CONTROL: PROTECT FROM IGNITION. WEAR PROTECTIVE CLOTHING AND USE APPROVED RESPIRATOR EQUIPMENT. ADSORB SPILLED MATERIAL. IN AN ABSORBENT RECOMMENDED FOR SOLVENT SPILLS AND REMOVE TO A SAFE LOCATION FOR DISPOSAL BY APPROVED METHODS. IF RELEASED TO THE ENVIRONMENT, COMPLY WITH AIL REGULATORY NOTIFICATION REQUIREMENTS. CERCLA REPORTABLE QUANTITY: NONE. WASTE DISPOSAL: DISPOSE OF ISOPROPYL ALCOHOL AS AN EPA HAZARDOUS WASTE. CONTACT STATE ENVIRONMENTAL AGENCY FOR LISTING OF LICENSED HAZARDOUS WASTE DISPOSAL FACILITIES AND APPLICABLE REGULATIONS. HAZARDOUS WASTE NUMBER: D001 (IGNITABLE). PAGE 3 HAZARD CLASSIFICATION CHEMICAL LISTINGS IMMEDIATE HEALTH: YES (IRRITANT) EXTREMELY HAZARDOUS SUBSTANCES: NO DELAYED HEALTH: NO CERCLA HAZARDOUS SUBSTANCES: NO FIRE: YES TOXIC CHEMICALS: NO SUDDEN RELEASE: NO REACTIVE: NO ISOPROPYL ALCOHOL IS NOT SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA) AND 40CFR PART 372. THIS PRODUCT DOES NOT CONTAIN ANY OTHER TOXIC CHEMICAL ABOVE 1X CONCENTRATION OR A CARCINOGEN ABOVE 0.1X CONCENTRATION. KEY CA APPROXIMATELY STEL SHORT TERM EXPOSURE LEVEL (15 MINUTES) NA NOT APPLICABLE TLV THRESHOLD LIMIT VALUE C CEILING TWA TIME WEIGHTED AVERAGE BUAC BUTYL ACETATE CERCLA COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION AND LIABILITY ACT OF 1980 NSC NATIONAL SAFETY COUNCIL ("FUNDAMENTALS OF INDUSTRIAL HYGIENE," 3RD ED., 1988) BURDICK & JACKSON'S DISCLAIMER: THE INFORMATION AND RECOMMENDATIONS PRESENTED IN THIS MATERIAL SAFETY DATA SHEET ARE BASED ON SOURCES BELIEVED TO BE RELIABLE ON THE DATE HEREOF. BURDICK & JACKSON MAKES NO REPRESENTATION ON ITS COMPLETENESS OR ACCURACY. IT IS THE USER'S RESPONSIBILITY TO DETERMINE THE PRODUCT'S SUITABILITY FOR ITS INTENDED USE, THE PRODUCT'S SAFE USE, AND THE PRODUCT'S PROPER DISPOSAL. NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR OF ANY OTHER NATURE ARE MADE WITH RESPECT TO THE INFORMATION PROVIDED IN THIS MATERIAL SAFETY DATA SHEET OR TO THE PRODUCT TO WHICH SUCH INFORMATION REFERS. BURDICK & JACKSON NEITHER ASSUMES NOR AUTHORIZES ANY OTHER PERSON TO ASSUME FOR IT, ANY OTHER OR ADDITIONAL LIABILITY OR RESPONSIBILITY RESULTING FROM THE USE OF, OR RELIANCE UPON, THIS INFORMATION. PAGE 4 (LAST PAGE) "ISSUED BY VWR 07/09/98" . BURDICK & JACKSON, INC. 1953 SOUTH HARVEY STREET MUSKEGON, MI 49442 USA MATERIAL SAFETY DATA SHEET INFORMATION /EMERGENCY TELEPHONE NUMBER 616.726.3171 CHEMTREC TELEPHONE NUMBER 800.424.9300 CANADIAN EMERGENCY TELEPHONE NUMBER 613.996.6666 I. IDENTIFICATION II. PHYSICAL AND CHEMICAL DATA III. FIRE AND EXPLOSION HAZARD DATA METHANOL PAGE 1 REVISION DATE: DECEMBER, 1993 REVISION NO: 1 CHEMICAL NAME: METHANOL CHEMICAL FAMILY: ALCOHOL SYNONYMS: CARBINOL, METHYL ALCOHOL, WOOD ALCOHOL DOT PROPER SHIPPING NAME: METHANOL DOT HAZARD CLASS: FLAMMABLE LIQUID, HAZARD CLASS 3, P.G. II DOT IDENTIFICATION NUMBER: UN1230 MOLECULAR WEIGHT: 32.04 FORMULA: CH40 CAS NUMBER: 67 -56 -1 BOILING POINT, 760 MM HG: 64.7 C VAPOR PRESSURE AT 20 C: 97 MM HG X VOLATILES BY VOLUME: CA 100 FREEZING POINT: -97.7 C VAPOR DENSITY (AIR =1): 1.11 SPECIFIC GRAVITY (H20 =1): C 20 C 0.792 EVAPORATION RATE: (BUAC =1) CA 5 SOLUBILITY IN WATER: @ 20 C COMPLETE STABILITY: STABLE HAZARDOUS POLYMERIZATION: NOT EXPECTED TO OCCUR. APPEARANCE AND ODOR: A CLEAR, COLORLESS LIQUID WITH A SLIGHT ALCOHOLIC ODOR. CONDITIONS TO AVOID: HEAT, SPARKS, OPEN FLAME, OPEN CONTAINERS, AND POOR VENTILATION. MATERIALS TO AVOID: STRONG OXIDIZING AGENTS AND REACTIVE METALS WHICH WILL DISPLACE HYDROGEN. HAZARDOUS DECOMPOSITION PRODUCTS: INCOMPLETE COMBUSTION CAN GENERATE CARBON MONOXIDE AND OTHER TOXIC VAPORS SUCH AS FORMALDEHYDE. FLASH POINT (TEST METHOD): 12 C (TAG CLOSED CUP) AUTO IGNITION TEMPERATURE: 385 C FLAMMABLE LIMITS IN AIR X BY VOLUME: LOWER LIMIT: 6.0 UPPER LIMIT: 36.5 UNUSUAL FIRE AND EXPLOSION HAZARDS: MAY BURN WITH AN INVISIBLE FLAME. MIXTURES WITH WATER AS LOW AS 21% BY VOLUME ARE STILL FLAMMABLE (FLASH POINT BELOW 37.8 C). UNDER SOME CIRCUMSTANCES CAN CORRODE CERTAIN METALS, INCLUDING ALUMINUM AND ZINC, AND GENERATE HYDROGEN GAS. City of Tukwila Fire Department Fire Department Review Control #M98 -0216 (510) Re: Prime Source - 355 Treck Drive Dear Sir: November 10, 1998 The attached set of mechanical plans have been reviewed by the Fire Prevention Bureau and are acceptable with the following concerns: 1. H.V.A.C. systems supplying air in excess of 2,000 cubic feet per minute to enclosed spaces within buildings shall be equipped with an automatic shutoff. Automatic shutoff shall be accomplished by interrupting the power source of the air- moving equipment upon detection of smoke in the main supply- duct served by such equipment. Smoke detectors shal be labeled by an approved agency for air -duct installati nd si�all be installed in accordance with the man facture ' i tallation instructions. (UMC 608) H. au se cen Ord ct sm• e deter ors shall be capable of being reset om the alarm p nel. (City Ordinance # 742) .C. nits rated at ar own devices. ra zoned in the a ral s`ation supervisi nance #1742) m require devices panel U.L. is requ ._ ►. (City Dedicated fire alarm system circuit breaker(s) shall be equipped with a mechanical lockout device. (NFPA 72 (1- 5.2.8.2)) 2. Ventilation for the flammable liquids room shall meet 1997 U.F.C. 8003.1.4. Any overlooked hazardous condition and /or violation of the John W. Rants, Mayor Thomas P. Keefe, Fire Chief Headquarters Station: 444 Andover Park East • Tukwila, Washington 98188 • Phone: (206) 575.4404 • Fax (206) .57.5-4439 City of Tukwila Fire Department Page number 2 adopted Fire or Building Codes does not imply approval of such condition or violation. Yours truly, 5 The Tukwila Fire Prevention Bureau cc: TFD file ncd John W. Rants, Mayor Thomas P. Keefe, Fire Chief Headquarters Station: 444 Andover Park East • Tukwila, Washington 98188 • Phone (206) S754404 Fax (206) 57544139 F62541524M MO! Wadi And Display Cell:int:air DEPARTMENT OF LABOR AND INDUSTRIES REGISTERED AS PROVIDED BY LAW AS CONST CONT GENERAL REGIST. # EXP. DATE CCO1 MACDOM*248J9 08/01/1999 EFFECTIVE DATE 04/29/1976 MACDONALD MILLER CO 7717 DETROIT AVE SW SEATTLE WA 98106 DI.1,11.11 And Display Celli liutt. 'LLJT 'LLD —TI SD O .X 1ST I NG 1 EZZ,p,t J I NE - FLA.IJ 8 °4 4' M 1E pl•cg 11 sGFCGFrN. �X15T11� CGT'JG. SLO$ RepL.E.TED GAIL It4G PL�ar.1 ' /e; I I -S ' .A CRC. STA, as To IvIATGH EXf5T11J4 FLT MMIA6L.g, 5 r .G.E Rczf,1el e4' IId �x ISTI hl izcz2T ATI-II TRIG • sT) FF V B ITS e "S X I'EHK M. Goa.. 2x¢ AY-IN LAYERON ` rIFfz 1 X • P, O TWO I -(21IZ WALL 3':.I Lo 2 LAM0 - r10S- x aYr 15P- 6A.WI err" 0i,4U 1 6R JT 501A 1I / T1-1P-FA I 120P - Won"( INTO WyXIOO11N GONG 5443 Io1e;X 4 1101∎1171 A0Fz1 .1T TWO I- 1C;Lig. VVAL L.e � - O' X r t t , low $ Hum -1 6MavN LINK FE /4P 2 - 3= 6SCIS.S ee/B S HI ToP 1?.pa11P'S S RS PIKVX I 0 • 1-1 vi/ NTL- EXHAUST FAN SCHEDULE BMT NO. EF-I EF -2 MANEFACTURER A Mt. &GLOUBCA15 TYPE UPBLAST CFM 2000 ESP .25' VOLT/PH;, 12011 1/2 ODD NO WTABS 50 NOTES NEW 1 -3 NOTES 1. MOTOR STARTERS AND DISCONNECTS TO BE SUPPLIED BY E.C. IF REQUIRED. 2 FANTO OPERA 7 -DAYS /WEEK 3. EXHAUST FAN IS SPARK RESISTANT WITH EXPLOSION PROOF MOTOR. Q ROOFTOP PACKAGED HEATPUMP SDULE THAT NO. HP -1 S AREA ERVED MEZZANINE YORK MODEL# B1HA030A06 Total COOL 30.0 SENS. COOL 24 HEAT BTUH 20.00 HSPF COP 7.0 CFM 1000 FAN HP 1/3 OSA CFM 100 ELECTRICAL EE IGI Volt/ph ;HTR,KWI STG:' MCA tED/I 20811 5.6 2 56.0 VYr'. LOS: 390 NOTES NEW 1,2,3,4,5 NOTES: 1. ELECTRICAL TO PROVIDE DISCONNECT. 2 MCA LISTED IS TOTAL MCA (W/ ELECTRIC HEAT). 3. WITH ROOF CURB. 4. WITH (0-25%) MANUAL OUTSIDE AIR DAMPER. 5. CONTROLLED BY HONEYWELL T 7300A1005 WITH SUBBASE MA 0730001006 COLOR CODE LEGEND =NEW WORK = RELOCATE .. =NOTES J FILE � noV uno , soblem Ip .. plans dee adopted c a actor's pat.,. 1= x PXI•TI r•-• riAL4 To Rct'F 0 NNO F %H4 A6T GONG • 4TP+F' To vy.Y� ✓c X tWT1T.l SEPARATE PERMIT REQUIRED FOR: ❑ MECHANICAL ELECTRICAL )2k PLUMBING PIPING CITY OF TUKWILA BUILDING DIVISION &1TYOFTUK I I APPROVED NOV 1 2 1998 ' B.JII DING DIVISION RECEIVED CITY OF TUKWILA 1100 - 3 1998 PERMOCENTER MacDonald Miller Company, Inc. 7717 Detroit Ave. S.W. Seattle, Wa 98106-1503 Phone: (206) 703 -9400 Fox: (200) 767-6773 Wash Lip No 223- O1- M4- CD- OM -245J5 REVISIONS: TM-1 DATE ADD IiPI 70 AI T40LE SfORK,E PP f ME5OURCE 3E5 TRECK DRIVE TUICWILLA , WA e MEUANINE - HVAG a FLAMMABLE 5TOR -E- Ht/AG J IPIr1 10 -30 -98 KarIM 09 -22 -9B WJE KLUEIM NOT ISSUED FOR CONSTRUCTION II i -- H r rt I — i I ' ' y 1 d 'LLJT 'LLD —TI SD O .X 1ST I NG 1 EZZ,p,t J I NE - FLA.IJ 8 °4 4' M 1E pl•cg 11 sGFCGFrN. �X15T11� CGT'JG. SLO$ RepL.E.TED GAIL It4G PL�ar.1 ' /e; I I -S ' .A CRC. STA, as To IvIATGH EXf5T11J4 FLT MMIA6L.g, 5 r .G.E Rczf,1el e4' IId �x ISTI hl izcz2T ATI-II TRIG • sT) FF V B ITS e "S X I'EHK M. Goa.. 2x¢ AY-IN LAYERON ` rIFfz 1 X • P, O TWO I -(21IZ WALL 3':.I Lo 2 LAM0 - r10S- x aYr 15P- 6A.WI err" 0i,4U 1 6R JT 501A 1I / T1-1P-FA I 120P - Won"( INTO WyXIOO11N GONG 5443 Io1e;X 4 1101∎1171 A0Fz1 .1T TWO I- 1C;Lig. VVAL L.e � - O' X r t t , low $ Hum -1 6MavN LINK FE /4P 2 - 3= 6SCIS.S ee/B S HI ToP 1?.pa11P'S S RS PIKVX I 0 • 1-1 vi/ NTL- EXHAUST FAN SCHEDULE BMT NO. EF-I EF -2 MANEFACTURER A Mt. &GLOUBCA15 TYPE UPBLAST CFM 2000 ESP .25' VOLT/PH;, 12011 1/2 ODD NO WTABS 50 NOTES NEW 1 -3 NOTES 1. MOTOR STARTERS AND DISCONNECTS TO BE SUPPLIED BY E.C. IF REQUIRED. 2 FANTO OPERA 7 -DAYS /WEEK 3. EXHAUST FAN IS SPARK RESISTANT WITH EXPLOSION PROOF MOTOR. Q ROOFTOP PACKAGED HEATPUMP SDULE THAT NO. HP -1 S AREA ERVED MEZZANINE YORK MODEL# B1HA030A06 Total COOL 30.0 SENS. COOL 24 HEAT BTUH 20.00 HSPF COP 7.0 CFM 1000 FAN HP 1/3 OSA CFM 100 ELECTRICAL EE IGI Volt/ph ;HTR,KWI STG:' MCA tED/I 20811 5.6 2 56.0 VYr'. LOS: 390 NOTES NEW 1,2,3,4,5 NOTES: 1. ELECTRICAL TO PROVIDE DISCONNECT. 2 MCA LISTED IS TOTAL MCA (W/ ELECTRIC HEAT). 3. WITH ROOF CURB. 4. WITH (0-25%) MANUAL OUTSIDE AIR DAMPER. 5. CONTROLLED BY HONEYWELL T 7300A1005 WITH SUBBASE MA 0730001006 COLOR CODE LEGEND =NEW WORK = RELOCATE .. =NOTES J FILE � noV uno , soblem Ip .. plans dee adopted c a actor's pat.,. 1= x PXI•TI r•-• riAL4 To Rct'F 0 NNO F %H4 A6T GONG • 4TP+F' To vy.Y� ✓c X tWT1T.l SEPARATE PERMIT REQUIRED FOR: ❑ MECHANICAL ELECTRICAL )2k PLUMBING PIPING CITY OF TUKWILA BUILDING DIVISION &1TYOFTUK I I APPROVED NOV 1 2 1998 ' B.JII DING DIVISION RECEIVED CITY OF TUKWILA 1100 - 3 1998 PERMOCENTER MacDonald Miller Company, Inc. 7717 Detroit Ave. S.W. Seattle, Wa 98106-1503 Phone: (206) 703 -9400 Fox: (200) 767-6773 Wash Lip No 223- O1- M4- CD- OM -245J5 REVISIONS: TM-1 DATE ADD IiPI 70 AI T40LE SfORK,E PP f ME5OURCE 3E5 TRECK DRIVE TUICWILLA , WA e MEUANINE - HVAG a FLAMMABLE 5TOR -E- Ht/AG J IPIr1 10 -30 -98 KarIM 09 -22 -9B WJE KLUEIM NOT ISSUED FOR CONSTRUCTION