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HomeMy WebLinkAboutPermit B93-0210 - KEMPER SYSTEMS - TENANT IMPROVEMENTB93-0210 KEMPER SYSTEMS ulitg \15rEN5 ( coital) carlyler b. fens An 979 john street seattle. wa• 98109 206 882 --8985 _z f rECEIVE;D SEP 1 1993 Mr. Bob Benedicto Senior Plans Examiner Dept. of Community Development, City Of Tukwila 6300 Southcenter Blvd, Tukwila, WA, 98188 ANCELLE IVI6COMI Re: Kemper Systems Inc. Building Permit Application. Dear Mr. Benedicto; As you requested this letter will withdraw our application for a building permit to remodel a tenant space at 4485 S. 134th PL, Permit number 93 -0210. The owners could not make the project work in the Tukwila area. Thank you for your help in reviewing the "plans. Sincerely: • Carlyle Archite Jensen A.I.A. ELOPMENT CITY OF TUKWIL Department of C . nunity Development — Permit Cen 6300 Southcenter Boulevard - #100, Tukwila, WA 98188 (206) 431 -3670 Building Permit Application Tracking PLAN CHECK NUMBER 6cJ3olo PROJECT NAME SITE ADDRESS Km -e r `�tJ, -e►'n s SUITE NO. INSTRUCTIONS TO STAFF • Contacts with applicants or requests for information should be summarized in writing by staff so that the status of the project may be ascertained at any time. • Plan corrections shall be completed and approved prior to sending to the next department. • Any conditions or requirements for the permit shall be noted in the Sierra system or summarized concisely in the form of a formal letter or memo, which will be attached to the permit. • Please fill out your section of the tracking chart completely. Where information requested is not applicable, so note by using "N /A ", date and initial. DEPARTMENTAL REVIEW "X" In box indicates which departments need to review the project. P;ARTME ......................... BUILDING - initial review kf FIRE << >DATE , PROV (vc1 -q3 ROUTED CONSULTANT: Date Sent - . MMEiNL. ..............:...::....... Date Approved - FIRE PROTECTION: Sprinklers Detectors N/A INIT: FIRE DEPT. LETTER DATED: INSPECTOR: O PLANNING O PUBLIC WORKS Alba lopi/73 INIT: INIT: ZONING: TBAR/LAND USE CONDITIONS? )Yes LJ No REFERENCE FILE NOS.: MINIMUM SETBACKS: N- s- UTILITY PERMITS REQUIRED? Yes No E- PUBLIC WORKS LETTER DATED: (4 BUILDING - final review INIT: TYPE OF CONSTRUCTION: CERT. OF OCCUPANCY? Yes D No UBC EDITION (year): k- BUILDING OFFICIAL INIT: REVIEW COMPLETED AMOUNT OWING: cD5b. CONTACTED DATE NOTIFIED BY: (init.) 2nd NOTIFICATION BY: . (init.) 3RD NOTIFICATION BY: .. (init.) 01/08109 CITY OF TUKWILA Department of Community Development - Building Division 6300 Southcenter Boulevard, Tukwila WA 98188 (206) 431 -3670 BUILDIIL PERMIT APPLICATION DESCRIPTION AMOUNT RCPT::# BUILDING PERMIT FEE PLAN CHECK FEE BUILDING SURCHARGE:.: OTHER: TOTAL::.: -5o. SITE ADDRESS SUITE # 1-4SS S. 1 341--4 h VALUE OF CONSTRUCTION - $ 5/ O D PROJECT NAME/TENANT t 8Lc1 I cliricj je -m0cIe I f v Kempe.1- c.���C.m,S a� ASSESSOR ACCOUNT # zip? 3ZO-- oov el— ---00 (commercial) Li Demolition (building) 0 Other: TYPE OF 0 New Building U Addition () Tenant Improvement WORK: 0 Rack Storage 0 Reroof 0 Remodel (residential) DESCRIBE WORK TO BE DONE: L m Do a t_ L— Li A kI -r 1 m P12_0\4/1E1.'7- IIe0 e Ui t..l (;t TO "pL -0) }1 BUILDING USE (office, warehouse, etc.) 14 A- r E. -) -}0 QS E NATURE OF BUSINESS: m..Iv..e_ Ho 1 , e ; ) I`I/4 ( = o e, e OoF I iI Lf `1i•km ,1 kb WILL THERE BE A CHANGE IN USE? CR No 0 Yes If Yes, new building requirements may need to be met. Please explain: SQUARE FOOTAGE - Building: z 7) 000 Tenant Space: Area 1-4- Area of Construction: WILL THERE BE STORAGE OR USE OF FLAMMABLE, COMBUSTIBLE 0 No ®. Yes IF YES, EXPLAIN: 6TO eAG or- F LA m, m ATEZ OR HAZARDOUS MATERIALS IN THE BUILDING? 7E E e r-- A-4) P tF j LE J k1., L P' Eq 3 .- 0 I (e, PROPERTY OWNER Lam" <-- K e i,,,,wCc �vs 7-:Els') PHONE --7Co ) cps---0 ADDRESS -t5-C) S- . M164_1 1 GI ./W 7--f- . �j- . -3A7- Li:L ZIP 9?) (ve CONTRACTOR PHONE ADDRESS ZIP WA. ST. CONTRACTOR'S LICENSE # EXP. DATE ARCHITECT GA -t? L,,-{ L� 3 3 aLi S ELI t wc4- I T` eL T PHONE (d sZ,-e9 0 G- ADDRESS 9 1 �) O 1-11,-4 E,T SEA : .r1 Le v-i A ZIP 9s I o9 I;:HEREBY;CERTIFY T;H��AT I HAV► :READ �qND EXAMINED THIS APP;LICATLOFI AND KfV BE:IRUE AND. :COR 3NAT AND :1 gUTHORIZED TO APPLrEOWTH.IS PERMI,. BUILDING OWNER OR AUTHORIZED AGENT S TU PRINT NA E4,I,� L ADDRES &. - - (73-0 CONTACT PERSON c fA_d_ ( Le 6 ,4 rz-C G4 APPLICATION SUBMITTAL �n order to ensure that your application is accepted for DATE PHONE &&-2a ey'� CITY/ZIP y s2 0 PHONE beyz. 967 a y pp p plan review, please make sure to fill out the application completely and follow the plan submittal checklist on the reverse side of this form. Handouts are available at the Building counter which provide more detailed information on application and plan submittal requirements. Application and plans must be complete in order to be accepted for plan review. VALUATION OF CONSTRUCTION Valuation for new construction and additions are calculated by the Department of Community Development prior to application submittal. Contact the Permit Coordinator at 431 -3670 prior to submitting application. In all cases, a valuation amount should be entered by the applicant. This figure will be reviewed and is subject to possible revision by the Building Division to comply with current fee schedules. BUILDING OWNER / AUTHORIZED AGENT If the applicant is other than the owner, registered architect/engineer, or contractor licensed by the State of Washington, a notarized letter from the property owner authorizing the agent to submit this permit application and obtain the permit will be required as part of this submittal. EXPIRATION OF PLAN REVIEW Applications for which no permit is issued within 180 days following the date of application shall expire by limitations. The building official may extend the time for action by the applicant for a period not exceeding 180 days upon written request by the applicant as defined in Section 304(d) of the Uniform Building Code (current edition). No application shall be extended more than once. If you have any questions about our process or plan submittal requirements, please contact the Department of Community Development Building Division at 431 -3670. DATE APPLICATION ACCEPTED 10- 04-G3 DATE APPLICATION EXPIRES h oa -ct- let COMMERCIAL NEW COMMERCIAL BUILDINGS/ADOITIONp ••• ' • • " . • • :• • : . : . • •., . .„ •.:• , Competed building perrnit'.applleatfon'(Onefor.elicfr.StrUCtUre).,:::;;•:::::„:... •• —; • Assessor Account ' ' : • Two Seti.(2)of the tolloWing.;.:.:: • Speclficat:ons RS • . Structural calCUletions.Stamped Gngineer Soils repOrt"itanigipiti'by. a WashingiOn•••$i*teilCenied 'engineer " ••••• • ' ' • . . SUBMITTAL CHECKLIST I ToOogrephical. su • ..• • • „... Energy. calculations :stamped by'a•Washington:,State•ticensed.....,.., flLegal doSaription:•••:•-•,;;•.:::....:..:•:•.::;:.:•.;:.,•••••::•;-....„'...,.,.,••••.,:•:--:•.••••::•••,...,••. Working 'Clthwingso:•StainCed ,:. • •.• ••• • ''• • ••••:•••••• Me cha nical drawings Etevattons '•••• ....„ •••••....•,•••••.:••:.•.•,-.... • • - g Completed uhiity permit appiication (one for entire project) Six (6) sets • Of civil drawings :•••tioTE-J::See.:'iiiiliiy, permit c4tio n ancichackl,st : '.•submittal:reciLlirerherfts; I ...Building floor pian showing Entiro • space where racks will 69::IciCated ' • Dimensions of all aisles • ; ...• • Tenant space floor plan showing rook storage layout,:aisies,and:'.... exits• • NOTE:. Include dimensions of racks (hoight, 'width and lengtb),.aM10$ ri SirUCtUralcalculationstarriped•by.e:Weihington'Staiii.liCenSed:;,•': . •• ••• :••••••... • •,.• • • • ,..••••••.:•,.:•••••,:•,....:•••••,...: • ... • • .:.•• ."•• .. . • . "•••••" • • ••• • •.• • •••-•••"•••• •• ••• • ••••• •• •-• • .. RESIDENTIAL NEW SINGLE FAMILY .. .. . DWELLINGS/ADDITIONS ri.Completeci, building :pc:401i application (ono tor; eiich;:strUcturej.:.::::..,,-. Completed ............................ • NOTE Bulldsng site plan and kaplai-i in ay..b. a Corn.b!nqcl Se!, wility /join.? irapplica!lon Adthtional loOograPhiCal and sods. mformetionmay.be Ere- iiIred , If unlque site conditions.; •••.• .••:::. ••• • . • . • . • . .. ..:...... • .. . , :-,COMMERCIAL TENANT IMPROVEMENTS :.:.„..„.... 6orhple.iea1:■iiilding:FierOilappiication..(*)0'.for•'eeCilSktOttirtidel;::';•::'....:::::. :.,-,..,.. ,•:. . .'...tenant).,:l.,.,.„ ,....T.sy.Asse:Ogor::.AcC66rit'Nurri...,....,tie:::::.......:::i,i:....:...... 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' : i 0 ill 0: 'sni,ciu i.: c). 1: n .,:t . •• r: 0. ...6 ,'.9.. . : : ...9... :' , k i footage ::,. ,..,. 9 .... ,. ) :' 1‘. .. is ,:,........:„...,, ‘. t (c.Ommo.n..citilriecill).. ..cFio°°6......'i...',.'.1is..‘r'..'.,:.....!;tlte'4.:.''TEO..eNU...rfrii,:ekessi.tailtlrirrwee:.1..0caclici....oliPWh....f...9.1f.,lorilli:°1‘1.11?i..tirnP.a:...,,,a.•...:...°e°8::11:..,..iild1::,......,-.:1,:.:°:....,;.;htn:,,.•.i.n.ww..•,•6:El:,ilfnilt,:g..t,..:',I.::11:1'..6.,..,...!!'.e?......,•.:;.n,•....f...g.......'e.......:6,....:..:.,::‘:°.,.:.,,..,...:.......ri.:.;....-:i..:6.,'..'bel.:.....8.........1Ill...,:....•:;r..:':.°:...,ii:°e.•• td:':::•••••:,:..:,:',..-...'1'.., ... • s•seOt details — wail 011strPOt101.1's......,..;.....‘, ...‘.. , ,;. ‘..... II; ogress alti.:end ,, . ., .... /).197-4:::':gOVOtiiitY.,*9t:/(' • .,. str uq.uC air Cross a.y.. :66 required t :l 6n1 r ss t '..t1 sl PP stamped r:ii....S il structural 9:: tt.irslu ; ..' ) . Wbm•.‘.... a. . 1S. ih 8,:i jr1,.... sj,.,t. .' o°,. 'd n. 1;'e ..' : ... 1:1!rn.. State .' °i.l.t.. 1 6 lil. ii:y. 116 7. p: (2 .. ci: s..... ''' r:;:: :..:. ,. .: " ... :.. .':..: .'. :1.... ..'. ...:.. ... .. .... .. ,. ,.. ,,,. .' .: : .• • ..- •'.::0119...•••.,,Ia,..t:::,....„:„......., 1 .19, al...,ped '1!y: I' oeS!.:t'...'''''''''''''''''''''...:: ' . ie.'''. applicition'and plan.s.::::::::'.,,;:.:;:::.':::::::::.:::.....::;,<::::',::::j:.:.:?.,,;::.:.:•:•:,..,,,.:,,:•.:i.,:•..... .. . be:1d 0179,.. ... .. 61j1ref9 .... ., . Cilmplete0.000164:000:406.0061000:lar.pao::sti-yptyre Assessor A�oljnt Number matorial being •? NcY?E 5A • cortiftcat,on ••••• • • •••••.: . . • ANTENNA,SATEWTE DISHES . . . . . . COrriplotect buiIdingrniitappljcatior • Assessor Account Number Two • (2) sots ot pi :11,i6;:::,,,yhjc.11 include lit k* ** * *ikk*** k• * ** *** *y4 ** * ***h* *** • *** hurt *vt•k•k*sk,k*** *hk* * *k•k** *. CITY OF 1UKWILA, WA TRANSMIT ***• k********** h**** k*k*************** *h *k ** **•h* * ** *** *** * ***** ** 1•R'AN$MIT. Number: 9:30.00724 Amount. 163.80 06/09/93 10:53 Permit No: 13.9x. -0210 Type :. B- BUILD BUILDING :PERM r ,Parcel Na .a 261320.0084 $.,te'Address: 4485 3 134 PL Payment. Method... CHECK: Notut.iornr CARLYLE: 0 ;JEN3EN Irlita 8.L13 ***** **•Fr•k*hy4r•hkdr•k*•kski4• *** ***k ** * ** * ** * ** ***fir * * *** * * * ***** * *•k *** Account Code ileecr i pt i on Paid 000/343.830 PLAN CHECK( -. NONREB; 163.80 Total.. (This Payment): "163.80 GENERA 163.80 TOTAL 163.80 CHECK 163.80 CHANGE. 0.00 1A41A000 15:Q2. Total Fees. Total A11, Payments: Balance. 4 20.30 163 80 256.50. ;SECTION I.- PRODUCT'INFORMATION : .. TRADE NAME: KEMPEROL D PRIMER: COMPONENT A TWO COMPONENT PRIMER CHEMICAL NAME AND SYNONYMS: POLYOL RESIN WITH ADDITIVE PRODUCT USE: ROOFING AND WATERPROOFING PREPARATION DATE: NOVEMBER 30, 1990 MANUFACTURER Kemper Systems, Inc. 550 South Michigan Street Seattle, Washington 98108 Emergency Phone: (800) 541 -5455 Facsimile: (206) 767 -9531 ORDER NUMBERS & PACKAGING: K0013030X 1.31 US GAL (5 KGS workpack) K0013031X .78 US GAL (3 KGS workpack) SECTION II ,- HAZARDOUS INGREDIENTS INGREDIENT Polyoi CAS # Unknown OSHA PEL Not established ACGIH TLV Not established PERCENTAGE 100 TRANSPORTATION REQUIREMENTS D.O.T. ID: UN NUMBER: Not Regulated Under D.O.T. HAZARD CLASS: LABEL: SHIPPING NAME: Diphenylmethane, 4,4' diisocyanate SECTION IV -. FIRE & EXPLOSION DATA Flashpoint (C.O.C. method): No data available. Autoignitlon Temperature: No data available. Flammable Limits: No data available. Extinguishing Media: Dry chemical, carbon dioxide, water spray or foam. For larger fires, use water spray, fog or alcohol foam. Special Fire Fighting Procedures: Move container from fire are If possible. Do not scatter spilled material with more water than needed for fire control. Dike fire control water for later disposal. Avoid breathing hazardous vapors, keep upwind. Unusual Fire & Explosion Hazards: None known. i,,,Sensitivlty to Static Discharge: No data available. SECTION I11 = PHYSICAL DAT Physical State: Odor & Appearance: Odor Threshold (ppm): Vapor Pressure: Vapor Density (Air =1): Evaporation Rate: Bolling Point: Freezing Point: Melting Point: Solubility In Water. Specific Gravity: Viscosity: Liquid Mild odor; cream color No data available <1 mbar (1.3 mm Hg) No data available No data available No data available No data available No data available Not soluble 1.01 Approximately 1,800 mPa SECTION V - REACTIVITY DATA Stability: Stable. Conditions to Avoid: May burn, but does not Ignite readily. Avoid contact with strong oxidizers, excessive heat, sparks, or open flame. Incompatibles (materials to avoid): Strong oxidizers. Hazardous Decomposition Products: Thermal decomposition may release acrid smoke and irritating fumes. Hazardous Polymerization: Hazardous polymeriza- tion has not been reported to occur under normal temperatures and pressures. MSDS- D- P- A- B/06 -91 SECTION VI - HEALTH HAZARD DATAITOXICOLOGICAL. PROPERTIES Emergency First Aid Procedures: Inhalation: Remove from exposure area to fresh air immediately. If breathing has stopped, perform artificial respiration. Keep person warm and at rest. Treat symptomatically and supportively. Get medical attention immediately. Eyes: Remove contact lens(es), If present, and flush Immediately with water for at least 15 minutes, carefully ROUTES OF ENTRY lifting the eyelids to expose the eye to contact with water. Get medical attention If Irritation persists. Skin: Contact with the concentrated solution may cause irritation. Chronic exposure - no data available. Ingestion: Treat symptomatically and supportively. Get medical attention immediately. SKIN CONTACT SKIN ABSORPTION INHALATION No No Unlikely f INGESTION Yes EXPOS. LIMITS IRRITANCY SENSITIZATION Not established Yes No ORAL. LD50 (rat): No data available Threshold Limit Value: Not established. Carcinogenicity: Not listed as a carcinogen by OSHA, NTP or IARC. Medical Conditions Generally Aggravated: None reported. Effects of Acute Exposure to Polyol: No data available. Due to the low degree of volatility of common polyols, no significant health hazard from Inhalation is likely to CARCINOGENICITY No TERATOGENICITY No REPRO. TOXIC, MUTAGENICITY SYNERGISTIC No No No DERMAL LD50 (rat): No SECTION VII - SPILL OR LEAK PROCEDURES. In case material Is released or spilled: Stop leak If you can do so without risk. For small spills, take up with sand or other absorbent material and place Into clean, dry containers for later disposal. Keep unnecessary people away. Isolate hazard area and deny area entry. Waste Disposal Method: This material Is not a hazardous waste and may be disposed of in any approved landfill. Environmental: SARA 313: There are no SARA reportable chemicals In this product. RCRA: This product does not contain any listed hazardous waste. VOC: No VOCs are released by this product. SECTION IX - SPECIAL PRECAUTIONS Special precautions with handling and storing: Store cool and dry In unopened container. Other precautions: No data available. data available INHALATION LC50 (rat): No data available occur at normal room temperatures. Inhalation of generated mist or vapors produced from elevated temperatures may cause Irritation of the mucous membranes. Effects of Chronic Overexposure to Polyol: No data available. SECTION VIII - SPEC. PROTECTION INFORMATION Respiratory Protection: When applying activated primer, only an airline respirator is acceptable. Ventilation: Natural ventilation may be sufficient on unobstructed roof top. If poor air movement or close work required, local exhaust may be required. Protective Gloves: The best protection is supplied by the North Silver Shield Glove. Polyvinyl alcohol also provides good protection. Eye Protection: Employee must wear splash -proof or dust - resistant safety goggles to prevent eye contact with this substance. Emergency Eye Wash: Where there Is any possibility that an employee's eyes may be exposed to this substance, the employer should provide an eye wash fountain within the immediate work area for emergency use. Other Protective Clothing or Equipment: Employee must wear appropriate protective (impervious) clothing and equipment to prevent repeated or prolonged skin contact with this substance. THIS INFORMATION IS GIVEN IN GOOD FAITH, BUT NO WARRANTY, EXPRESS OR IMPLIED, IS MADE. THE PRODUCT IS NOT CLAIMED TO BE MERCHANTABLE OR FIT FOR ANY PARTICULAR PURPOSE. SUITABILITY IS DETERMINED BY USER. FOR INDUSTRIAL USE AND CERTIFIED APPLICATORS ONLY. Prepared from Importer supplied Information by Schumacher & Associates, Inc., Seattle, WA. No claim of completeness or accuracy Is made. KEMPER 7A O 4 • t SECTION I.- PRODUCT INFORMATION TRADE NAME: KEMPEROL D PRIMER: COMPONENT B TWO COMPONENT PRIMER - CATALYST CHEMICAL NAME AND SYNONYMS: POLYURETHANE CATALYST PRODUCT USE: ROOFING AND WATERPROOFING PREPARATION DATE: NOVEMBER 30, 1990 MANUFACTURER Kemper Systems, Inc. 550 South Michigan Street Seattle, Washington 98108 Emergency Phone: (800) 541 -5455 Facsimile: (206) 767 -9531 ORDER NUMBERS & PACKAGING: K0013030X 1.31 US GAL (5 KGS workpack) K0013031X .78 US GAL (3 GAL workpack) SECTION II - HAZARDOUS INGREDIENTS 4,4'-Dlpheny dilsocyanat INGREDIENT % CASN OSHA PEL ACGIH TLV 4,4=Diphenylmethane dilsocyanate (MDI) 35.45 101.681 0.005 ppm 0.005 ppm Diphenylmethane dilsocyanate (2,2;2,4) 1.10 26447.40.5 None established None established Higher oligomers of MDI 30.40 9016.87.9 None established None established Phenyl isocyanate Trace 103-71-9 None established None established TRANRPnRTATIriN n.n.T. In. LIN NUMBER: Not Recelated Under D.O.T. IREMENTS HAZARD CLASS: LABEL: SHIPPING NAME: Diphenylmethane, 4,4' dilsocyanate SECTION IV - FIRE & EXPLOSION DATA Flashpolnt (C.O.C. method): > 453 °F Flammable Limits: None. Autotgnitlon Temperature: 400°C/752°C Extinguishing Media: Dry chemical, CO23 foam, water spray for larger fires. Special Fire Fighting Procedures: Full emergency equipment with self - contained breathing apparatus and full protec- tive clothing should be worn by firefighters. During a fire, MDI vapors and other Irritating, highly toxic gases may be generated by thermal decomposition or combustion. (See Section V.) At temperatures greater than 400 °F (204 °C), polymeric MDI can polymerize and decompose which can cause pressure build -up in closed containers. Explosive rupture is possible. Therefore, use cold water to cool fire - exposed containers. Unusual Fire & Explosion Hazards: None known. Sensitivity to Static Discharge: No data available. SECTION III PHYSICAL DATA Physical State: Odor & Appearance: Odor Threshold (ppm): Vapor Pressure: Vapor Density (Air =1): Evaporation Rate: Bolling Point: Freezing Point: Melting Point: Solubility in Water: Specific Gravity: Viscosity: Volatile: Liquid Earthy odor; dark brown No data available 0.00013 mmHg (MDI) 8.5 No data available 208 °C1408 °F @ 5 mmHg for M v 0°C/32°F for M No data available Not soluble; reacts slowly with water to liberate 1.24 ® 77°F (25°C) 50 mPa Negligible SECTION V - REACTIVITY DATA Stability: Stable. Conditions to Avoid: May burn, but does not Ignite readily. Avoid contact with strong oxidizers, excessive heat, sparks, or open flame. Avoid contamination with water. Incompatibilities (materials to avoid): Strong acids, alcohols, amines, bases and water. This material will corrode copper or aluminum. Hazardous Decomposition Products: Thermal decomposi- tion products may Include very toxic fumes of hydrogen cyanide, toxic oxides of carbon and nitrogen, MDI vapors. Hazardous Polymerization: Polymerization may occur If in contact with moisture or other materials which react with isocyanates. May occur at temperatures over 400 °F (204°C). See Section IV. .-SECTION. VI.- HEALTH. HAZARDDAT/ Emergency First Aid Procedures: Inhalation: Remove from exposure area t immediately. If breathing has stopped, p respiration. Keep person warm and at res tomatically and supportively. Get medical immediately. Eyes: Remove contact lens(es), if present Immediately with water for at least 15 ml lifting the eyelids to expose the eye to c water. Get medical attention If irritation p Skin: Remove contaminated clothing and immediately. Wash affected area with so detergent and large amounts of water un of chemical remains (approximately 15 -2 medical attention immediately. ingestion: Get medical attention immedi occurs, keep head lower than hips to pre In case material is released or spilled: Eva ventilate spill area; dike spill to prevent system; wear full protective equipment atory equipment during cleanup. (See S Major spill: Call Mobay at (412) 923.180 transportation spill, call CHEMTREC (8 temporary control of isocyanate vapor I blanket of protein foam (available at m ROL D PRIMER: COMPONENT B PONENT PRIMER - CATALYST RETHANE CATALYST NG AND WATERPROOFING BER 30, 1990 NUMBERS & PACKAGING: 30X 1.31 US GAL (5 KGS workpack) 31X .78 US GAL (3 GAL workpack) ECTION III - PHYSICAL DATA Physical State: dor & Appearance: r Threshold (ppm): Vapor Pressure: or Density (AIr =1): Evaporation Rate: Bolling Point: Freezing Point: Melting Point: Solubility In Water. Specific Gravity: Viscosity: Volatile: Liquid Earthy odor; dark brown No data available 0.00013 mmHg (MDI) 8.5 No data available 208 °C /406 °F @ 5 mmHg for M v 0°C/32°F for M No data available Not soluble; reacts slowly with water to liberate 1.24 ia? 77 °F (25°C) 50 mPa Negligible REACTIVITY DATA ally: Jtabte. •litlons to Avoid: May burn, but does not ignite readily. ,id contact with strong oxidizers, excessive heat, arks, or open flame. Avoid contamination with water. mpatibllitles (materials to avoid): Strong acids, alcohols, nines, bases and water. This material will corrode pper or aluminum. rdous Decomposition Products: Thermal decomposi- n products may include very toxic fumes of hydrogen anide, toxic oxides of carbon and nitrogen, MDI vapors. rdous Polymerization: Polymerization may occur If in ntact with moisture or other materials which react with cyanates. May occur at temperatures over 400 °F 04°C). See Section IV. SECTION VI - HEALTH HAZARD DATA /TOXICOLOGICAL PROPERTIES Emergency First Aid Procedures: Inhalation: Remove from exposure area to fresh air Immediately. If breathing has stopped, perform artlfical respiration. Keep person warm and at rest. Treat symp- tomatically and supportively. Get medical attention immediately. Eyes: Remove contact lens(es), if present, and flush immediately with water for at least 15 minutes, carefully lifting the eyelids to expose the eye to contact with water. Get medical attention if irritation persists. Skin: Remove contaminated clothing and shoes immediately. Wash affected area with soap or mild detergent and large amounts of water until no evidence of chemical remains (approximately 15-20 minutes). Get medical attention Immediately. Ingestion: Get medical attention immediately. If vomiting Do not induce vomiting. Give 1 to 2 cups of milk or water to drink. Treat symptomatically and supportively. Note to Physician: Eyes: Stain for evidence of corneal injury. If cornea is burned, instill antibiotic steroid preparation frequently. Workplace vapors have produced reversible corneal epithelial edema impairing vision. Skin: This compound is a known skin sensitizer. Treat symptomatically as for contact determatitls or thermal burns. If burned, treat as thermal burn. Ingestion: Treat symptomatically. There Is no specific antidote. Inducing vomiting is contraindicated because of the Irritating nature of this compound. Respiratory: This compound Is a known pulmonary sensitizer. Treatment is essentially symptomatic. An individual having a skin or pulmonary sensitization reaction to this material should be removed from exposure to any isocyanate. -- ..- •- ...,,,.."N luau ,vvvoi uiaai HIP° w Niovvn1 aONnauuii. TOXOLOGICAL INFORMATION ROUTES OF ENTRY /OTHER DATA 4,4'•Diphenyimethane dlisocyanate Diphenylmethane dlisocyanate Higher oligomers of MDI Phenyl Isocyanate SKIN CONTACT Yes Yes Yes Yes SKIN ABSORPTION No No No No INHALATION Yes No No Yes INGESTION Yes Yes Yes Yes ORAL LD50 (rat) 31,890 mg /kg No data available No data available 940 mg/kg DERMAL L050 (rat) 500 mg /24 hrs No data available No data available No data available INHALATION LC50 (rat) 178 mg /m3 No data available No data available No data available THRESHOLD LIMIT VALUE 0.005 ppm Not established Not established Not established EXPOS. LIMITS IRRITANCY MDI 0.005 PPM TWA Yes SENSITIZATION Yes CARCINOGENICITY TERATOGENICITY No No REPRO. TOXIC. MUTAGENICITY No MDI • Yes Phenyl Iso. • Yes SYNERGISTIC No Carcinogenicity: Not listed as a carcinogen by OSHA, NTP or ARC. Medical Conditions Generally Aggravated: MDi: Asthma and other respiratory disorders, skin allergies and eczema. Diphenylmethane dlisocyanate: None reported. Higher ollgomers of MDI: None reported. Phenyl Isocyanate: None reported. Effects of Acute Exposure to Chemicals In the Product: MDI: Irritant /sensitizer /toxic. 10 ppm immediately dangerous to life or health. Acute exposure may cause Irritation of the nose and throat. Depending on the length of concentrations of exposure (above 0.5 ppm), respiratory symptoms may develop with a latent period of four to eight hours. Symptoms may include coughing and dyspnea, especially prominent in the evenings, with progression of asthmatic bronchitis and wheezing. Other symptoms may include headache, nausea, vomiting, chest pain, pulmonary secretions, pulmonary edema and possible death. A human exposed to 130 ppb for 30 minutes experienced an Increase in Immune response and body temperature. Diphenylmethane Dllsocyanate101igomers of MDI: No data available. Due to the low degree of volatility, no significant health hazard from Inhalation Is likely to occur at normal room temperatures. Inhalation of generated mist or vapors produced from elevated tem- peratures may cause irritation of the mucous membranes. Phenyl Isocyanate: Vapors are extremely irritating to nose and throat. Some isocyanates are capable of inducing pulmonary sensitization. Asthmatic manifesta- tions range from minor breathing difficulties to acute attacks, sometimes accompanied by sudden loss of consciousness. Other respiratory effects may Include rhinitis or rhinopharyngitis, chest tightness, wheezing, coughing and choking (predominantly in the evenings), pulmonary edema, long -term changes in ventilatory capacity, and chemical bronchitis. Effects of Chronic Overexposure to Chemicals In the Product: MDI: After months of exposure, allergic sensitization of the respiratory tract may occur. Symptoms, which Include nocturnal dyspnea, nocturnal cough and asthmatic bronchitis, become progressively more pronounced with continued exposure. Dlphenylmethane Dllsocyanate1011gomers of MDI: There is no health effects data for these substances. Effects could be similar to MDI, above. Phenyl Isocyanate: As with other Isocyanates, repeated and prolonged exposure may elicit hypersensitivity reactions and chronic decrement in pulmonary function. SECTION VII - SPILL OR LEAK PROCEDURES In case material Is released or spilled: Evacuate and ventilate spill area; dike spill to prevent entry into water system; wear full protective equipment including respir- atory equipment during cleanup. (See Section VIII). Major spill: Call Mobay at (412) 923 -1800. If transportation spill, call CHEMTREC (800)424-9300. If temporary control of isocyanate vapor is required, a blanket of protein foam (available at most fire depart- ments) may be placed over the spill. Large quantities may be pumped into closed, but not sealed, container for disposal. Minor spill: Absorb isocyanates with sawdust or other absorbent, shovel Into suitable unsealed containers, transport to well - ventilated area (outside) and treat with neutralizing solution: mixture of water (180 %) with non -Ionic surfactant Tergltol TMN -10 (20 %) or; water (90 %), concentrated ammonia (3-8%) CONTINUED ON NEXT PAGE • and detergent (2 %). Add about 10 parts of neutralizer per part of isocyanate, with mixing. Allow to stand uncovered for 48 hours to let CO2 escape. Cleanup: Decontaminate floor with decontamination solution, letting stand for at least 15 minutes. SECTION VIII -SPEC. PROTECTION INFORMATION Respiratory Protection: The following respirators and maximum use concentrations are recommended by the US Department of Health and Human Services, NIOSH Pocket Guide to Chemical Hazards; NIOSH Criteria Documents or by the US Department of Labor, 29 CFR1910 Subpart Z. The specific respirator selected must be based on contam- ination levels found in the workplace, must not exceed the working limits of the respirator, and be Jointly approved by the National Institute for Occupational Safety and .Health and the Mine Safety and Health Administration (NIOSH•MSHA). 0.2 ppm: Any supplied-air respirator or self-contained breathing apparatus, 0.5 ppm: Any supplied -air respirator operated in a continuous flow mode. 1.0 ppm: Any self-contained breathing apparatus with full faceplece; or any supplied -air respirator with a full faceplece. 10 ppm: Any self-contained breathing apparatus with full faceplece and operated In a pressure demand or other positive pressure mode. Waste Disposal Method: Cure extra catalyst (activator) with Part A until solid, then dispose of as ordinary waste. Always mix in proper proportions. Environmental: SARA 313: MDI Is reportable. The percentage MDI In Kemperol D Primer Catalyst is 35-45%. RCRA: This product does not contain listed waste. VOC: No VOCs are released by this product. Escape: Any air - purifying full faceplece respirator (gas mask) with a high efficiency particulate filter; any appropriate escape-type self-contained breathing apparatus. Ventilation: Provide local exhaust or process enclosure ventilation to meet published exposure limits. Protective Gloves: Employee must wear appropriate protective gloves to prevent contact with this substance. The best protection is supplied by the North Silver Shield Glove. Polyvinyl alcohol also provides good protection. Eye Protection: Employee must wear liquid chemical goggles resistant safety goggles to prevent eye contact with thls substance. Contact lenses should not be worn. Emergency Eye Wash: Where there Is any possibility that an employee's eyes may be exposed to this substance, the employer should provide an eye wash fountain within the Immediate work area for emergency use. Other Protective Clothing or Equipment: Employee must wear appropriate protective (Impervious) clothing and equipment to prevent repeated or prolonged skin contact with this substance. SECTION IX SPECIAL PRECAUTIONS. Special precautions with handling and storing: Storage Temperature: Min: 64 °F (18 °C) Max: 88°F (30 °C) Shelf Life: 6 months Special Sensitivity: If contained is exposed to high heat (400 °F /204 °C), it can be pressurized and possibly rupture. MDI reacts slowly with water to form CO2 gas. This gas can cause sealed containers to expand and possibly rupture. Handling /Storage Precautions: Store in tightly closed containers to prevent moisture contamination. Do not reseal If contamination is sus- pected. Avoid contact with skin and eyes. Do not breathe aerosols or vapors. Other precautions: Warning properties (Irritation of the eyes, nose and throat or odor) are not adequate to prevent chronic overexposure from inhalation. This material can produce asthmatic sensitization upon either a single inhalation exposure to a relatively high concentration, or upon repeated Inhalation exposures to lower concentrations. Exposure to vapors of heated MDI can be extremely dangerous. Employee education and training In the safe use and handling of this compound are required under the OSHA Hazard Communication Standard. THIS INFORMATION IS GIVEN IN GOOD FAITH, BUT NO WARRANTY, EXPRESS OR IMPLIED, IS MADE. THE PRODUCT IS NOT CLAIMED TO BE MERCHANTABLE OR FIT FOR ANY PARTICULAR PURPOSE, SUITABILITY IS DETERMINED BY USER. FOR INDUSTRIAL USE AND CERTIFIED APPLICATORS ONLY. Prepared from Importer supplied Information by Schumacher & Associates, Inc., Seattle, WA. No claim of completeness or accuracy is made. KEMPER 7B Partner for Professional Solutions in 'Roofing and Waterproofing , .SECTION.: I. PRODUCT INPORMAT,ION-.,.; TRADE NAME: KEMPEROL BSF -R, PRIMER MSDS Material Safety Data Sheet ' .. . j Meets OSHA & WHMIS CHEMICAL NAME AND SYNONYMS: WATER BASED ADHESION PRIMER CHEMICAL FAMILY: VINYL RESIN PRODUCT USE: ROOFING AND WATERPROOFING PREPARATION DATE: NOVEMBER 15, 1990 MANUFACTURER Kemper Systems, Inc. 550 South Michigan Street Seattle, Washington 98108 Emergency Phone: (800) 541 -5455 Facsimile: (206) 767 -9531 ORDER NUMBERS & PACKAGING: K0013020X 3.48 US GAL (20 KGS) K0013021X 1.74 US GAL (10 KGS) SECTION II -. HAZARDOUS INGREDIENT NAME INGREDIENTS Water Ethylene -vinyl acetate copolymer CAS # Not established 7732 -18.5 OSHA PEL Not established Not established ACGHIH TLV Not established Not established PERCENTAGE 71* 3 29 t 3 TRANSPORTATION REQUIREMENTS Not regulated by DOT SECTION IV - FIRE & EXPLOSION DATA Flashpolnt (C.O.C. method): No data available. Flammable Limits: No data available. Autoignitlon Temperature: No data available. Extinguishing Media: Water fog, dry chemical, CO2, foam. Special Fire Fighting Procedures: Fight as fuel oII fire, wear self - contained breathing apparatus. Cool containers with water. Unusual Fire & Explosion Hazards: If exposed to elevated temperatures for extended length of time, spontaneous exothermic polymerization may occur yielding violent rupture of packaging container. Sensitivity to Static Discharge: No data available. SECTION III - PHYSICAL DATA Physical State: Odor & Appearance: Odor Threshold (ppm): Vapor Pressure: Vapor Density (Air= 1): Evaporation Rate: Bolling Point: Freezing Point: Melting Point: Solubility In Water: Specific Gravity: Viscosity: Liquid Gray; acid odor No data available 23 mbar (30.3 mm Hg) No data available No data available 212 °F No data available No data available Miscible 1.52 No data available SECTION V - REACTIVITY DATA Stability: Stable. Conditions to Avoid: May burn but will not ignite readily. Avoid contact with strong oxidizers. Incompatibles (materials to avoid): No data available Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, and smoke. Hazardous Polymerization: May occur. MSDS 2 - BSF - R - P / 06-91 'SECTION VI. - HEALTH HAZARD DATA /TOXICOLOGICAL PROPERTIES Emergency First Aid Procedures: Inhalation: Remove to fresh air. If not breathing, give mouth to mouth resuscitation; if breathing is difficult, give oxygen. Call physician immediately. Eyes: Remove contact lens(es), If present, and flush immediately with water for at least 15 minutes, carefully lifting the eyelids to expose the eye to contact with SKIN CONTACT Yes EXPOS. LIMITS Skin: immediately flush skin with ample water for at least 15 minutes; remove and discard contaminated clothing and shoes; If irritation persists, call a physician. Ingestion: DO NOT induce vomiting. Call physician and /or transport to emergency medical facility immediately. ROUTES OF ENTRY - ETHYLENE -VINYL ACETATE COPOLYMER SKIN ABSORPTION No IRRITANCY INHALATION No INGESTION Yes SENSITIZATION CARCINOGENICITY TERATOOENICITY REPRO. TOXIC. MUTAGENICITY SYNERGISTIC Not established Yes No No No No No No ORAL LD50 (rat): No data available DERMAL LD50 (rat): No data available Threshold Limit Value: Not established. Carcinogenicity: Not established. Modica' Conditions Genaraily Aggravated: None are known. SECTION VII .= SPILL OR LEAK PROCEDURES In case material is released or spilled: Extinguish open flames, cut off electrical power to area, dike to prevent run -off Into waterways and sewers, cover spill with absorbent media (Le., peat, vermiculite, etc.), sweep up remaining contamination. Clean up with non- flammable solvent, dispose of cured media as solid waste in closed containers either at an approved landfill or Incinerate at an approved facility. Obey federal, state, county or any other regulations. Waste Disposal Method: Cured catalyzed (resin) may be disposed of at proper landfill and /or incinerated. Obey all pertaining regulations. Excess catalyst should be combined with the correct amount of resin for waste disposal. Unused catalyst must be handled as a hazardous waste. Environmental: SARA 313: There are no SARA reportable chemicals in thls product. RCRA: This products does not contain listed waste. VOC: No VOCs are released by this product. INHALATION LC50 (rat): No data available Effects of Acute Exposure to Ethylene-Vinyl Acetate Copolymer. May cause irritation. Effects of Chronic Overexposure to Ethylene -Vinyl Acetate Copolymer. There are no expected chronic health effects from thls material. SECTION •VIII -SPEC. PROTECTION INFORMATION Respiratory Protection: For some spraying applications, an air purifying respirator is necessary. Ventilation: Unnecessary In outside application, but local exhaust Is recommended inside buildings and structures. Protective Gloves: Neoprene is recommended. Eye Protection: The minimal recommendation is safety glasses with sideshieids. Other Protective Clothing or Equipment: Protective clothing and shoes. SECTION IX - SPECIAL PRECAUTIONS Special precautions with handling and storing: Always store in a cool, dry area. Protect from freezing. Other Precautions: Not usually necessary. THIS INFORMATION IS GIVEN IN GOOD FAITH, BUT NO WARRANTY, EXPRESS OR IMPLIED, IS MADE, THE PRODUCT IS NOT CLAIMED TO BE MERCHANTABLE OR FIT FOR ANY PARTICULAR PURPOSE. SUITABILITY IS DETERMINED BY USER. FOR INDUSTRIAL USE AND CERTIFIED APPLICATORS ONLY. Prepared from Importer supplied Information by Schumacher & Associates, Inc., Seattle, WA. No claim of completeness or accuracy Is made. KEMPER SYSTEMS, INC. 550 S Michigan Street Seattle, WA 98108 206- 767 -9505 FAX: 206- 767 -9531 800 - 541 -5455 , L • . _J ' t J LJ lJ l;J IW�s+o rwws • :Partner for Protessional•Solutions in. and. Waterproofing A TRADE NAME: KEMPEROL ' 12-. COMPONENT A TWO - COMPONENT FLASHING RESIN CHEMICAL NAME AND SYNONYMS: POLYESTER FLASHING RESIN CHEMICAL FAMILY: !UNSATURATED POLYESTER RESIN PRODUCT USE: ROOFING AND WATERPROOFING PREPARATION DATE. NOVEMBER 30, 1990 MANUFACTURER Kemper Systems, Inc. 550 South Michigan Street Seattle, Washington 98108 Emergency Phone: (800) 541-5455 Facsimile: (206) 767 -9531 ORDER NUMBERS & PACKAGING: Com oven A - Black Formulation K011070.2.28 US GAL (10.0 KGS) (measurements include catalyst powder) SECTION II - INGREDIENT NAME HAZARDOUS INGREDIENTS Unsaturated Polyester Resin Styrene CAS # 100-42-5 8011 -97.9 OSHA PEL 50 ppm Not established ACGHIH TLV 100 ppm(STEL) 50 ppm(TWA) Not established PERCENTAGE 27 t 3 Balance TRANSPORTATION REQUIREMENTS DOT ID: UN 1866 HAZ. CLASS: Flammable liquid LABLE: Flammable liquid SHIP. NAME: Resin Solution SECTION IV - FIRE & EXPLOSION DATA Flashpoint (C.O.C. method): 32 °C190 °F Flammable Limits: Lower: 1.1%, Upper: 8% Autolgnitlon Temperature: 490 °C1914 °F Extinguishing Media: Water fog, dry chemical, CO2, foam. Special Fire Fighting Procedures: Fight as fuel oil fire, wear self - contained breathing apparatus. Cool containers with water. Unusual Fire & Explosion Hazards: If exposed to elevated temperatures for extended length of time, spontaneous exothermic polymerization may occur yielding violent rupture of packaging container. Sensitivity to Static Discharge: No data available. SECTION III - PHYSICAL DATA. Physical State: Viscous liquid Odor & Appearance: White Odor Threshold (ppm): No data available Vapor Pressure: ( 020 °C /68 °F): <10 mbar (13.1 mm Hg) (styrene) 3.6 (styrene) No data available 145 °C1298 °F No data available No data available 0.3 g/L (styrene) Approximately 1.16 Approximately 1,500 mPa Vapor Density (Air =1): Evaporation Rate: Bolling Point: Freezing Point: Melting Point: Solubility In Water: Specific Gravity: Viscosity: SECTION V -.REACTIVITY DATA Stability: Stable. Conditions to Avoid: Sunlight, excessive heat, open flames, contamination with oxidizing agents, prolonged storage. >86 °F (30 °C) Incompatibles (materials to avoid): Peroxides and other other oxidizing agents, promoters. Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, low molecular weight hydrocarbons, organic acids. Hazardous Polymerization: May occur if exposed to heat >100 °F /38 °C for prolonged time, open flame, contamination with oxidizer, Improper addition of catalysts and/or promoters. THIS INFORMATION IS GIVEN IN GOOD FAITH, BUT NO WARRANTY, EXPRESS OR IMPLIED, IS MADE. THE PRODUCT IS NOT CLAIMED TO BE MERCHANTABLE OR FIT FOR ANY PARTICULAR PURPOSE. SUITABILITY IS DETERMINED BY USER, FOR INDUSTRIAL USE AND CERTIFIED APPLICATORS ONLY. Prepared from Importer supplied Information by Schumacher & Associates, inc., Seattle, WA. No claim of completeness or accuracy Is made. MSDS 12-. AN A - B / 06 -91 SECTION VII SPILL OR LEAK. PROCEDURES / SECTION VI - HEALTH HAZARD, DATA /TOXICOLOGICAL'PROPERTIES: Emergency First Aid Procedures: Inhalation: Remove to fresh air. If not breathing, give mouth to mouth resuscitation; If breathing is difficult, give oxygen. Call physician Immediately. Eyes: Remove contact lens(es), if present, and flush immediately with water for at least 15 minutes, carefully lifting the eyelids to expose the eye to contact with water. Get medical attention if irritation persists. Skin: immediately flush skin with ample water for at least 15 minutes; remove and discard contaminated clothing and shoes; if irritation persists, call a physician. Ingestion: DO NOT induce vomiting. Call physician and/or transport to emergency medical facility immediately. ROUTES OF ENTRY - STYRENE SKIN CONTACT SKIN ABSORPTION INHALATION INGESTION Yes Yes Yes Yes EXPOS. LIMITS IRRITANCY Styr. 50 PPM TWA Yes ORAL LD50 (rat): 5000 mg /kg SENSITIZATION CARCINOGENICITY TERATOGENICITY No Yes Styr. • Yes DERMAL LD50 (rat): No data available Threshold Limit Value: 100 ppm STEU50 ppm 8 -hour TWA (styrene). Carcinogenicity: Styrene has been identified by the IARC as a 2B carcinogen; limited animal evidence. As of January 1989, OSHA withdrew the carcinogen classification for styrene. Medical Conditions Generally Aggravated: Central nervous system, kidney, liver disorder history. Effects of Acute Exposure to Styrene: May cause irritation of the lungs, throat, and airways, usually accompanied by cough, difficulty in breathing or swallowing, or as sensation of pain or burning in the lungs. May cause headache, disorientation, drowsiness, nausea, vomiting, euphoria, and dizziness. With Increasing exposure, symptoms may include staggering gait, loss of coordination, breathing difficulty, unconsciousness, coma, and death. High exposure can also result in liver In case material Is released or spilled: Extinguish open flames, cut off electrical power to area, dike to prevent run -off into waterways and sewers, cover spill with absorbent media (Le., peat, vermiculite, etc.), sweep up remaining contamination. Clean up with non- flammable solvent, dispose of cured media as solid waste In closed containers either at an approved landfill or incinerate at an approved facility. Obey federal, state, county or any other regulations. Waste Disposal Method: Cured resin (catalyzed) will solidify and may be disposed of at proper landfill and /or incinerated. Obey all pertaining regulations. Unpoly- merized resin should be catalyzed. If you need to dispose of uncatalyzed resin, it must be handled as a hazardous waste. Environmental: SARA 313: Styrene is reportable. Percentage styrene is approx. 26% ± 3. RCRA: EPA waste code for unused resin is 0001 for a flammable liquid. VOC: VOCs are 27.3 grams per gallon. REPRO. TOXIC. MUTAGENICITY SYNERGISTIC Styr. • Yes Styr. - Yes No INHALATION LC50 (rat): 9500 ppm damage and possible liver failure. High exposure can result In kidney damage and possible kidney failure. Effects of Chronic Overexposure to Styrene: Animal studies, and /or human epidemiologic studies, indicate that this chemical may cause or contribute to the devel- opment of cancer. Reproductive hazard: May cause decreased fertility, miscarriage or birth defects. Long- term exposure to concentrations in excess of the PEUTLV may result in chronic bronchitis (cough and production of excess mucus) or chronic obstructive pulmonary disease (shortness of breath). Chronic exposure may result in reversible or irreversible damage to the nervous system resulting In some or all of the following symptoms: fatigue, sleep disturbance, headache, convulsions, nervous excitability, nerve paralysis, hallucinations, delusions, acute psychosis, tremor and Toss or memory. May cause damage to the kidneys, which can result in swelling, increased urinary protein, changes in urine composition, fluid retention, and, in severe cases, kidney failure. SECTION VIII -SPEC. PROTECTION INFORMATION Respiratory Protection: No respiratory protection is needed below 50 ppm. From 50 to 5000 ppm, use a NIOSH- approved half -mask with organic vapor cartridges. From 500 to 5,000 ppm, use a full -face respirator with organic vapor cartridges. Above 5000 ppm, an air - supplied respirator or self - contained breathing apparatus is required. Ventilation: Recommended sufficient to control vapors to below 50 ppm. Natural ventilation may be sufficient on unobstructed roof top. If poor air movement or close work required, local exhaust may be necessary. Protective Gloves: Gauntlet type; polyvinyl alcohol. Eye Protection: Face shield, safety glasses, or chemical goggles. Other Protective Clothing or Equipment: Solvent - resistant shoes, boots, aprons - frequently cleaned to avoid skin contact. Safety showers and eye -wash equipment should be on -site. SECTION .IX SPECIAL PRECAUTIONS Special precautions with handling and storing: Always store dry and cool. Avoid prolonged storage above 80 °F (27°C). Keep away from sunlight. Store and handle as NFPA Class 1 -C. Open containers slowly and carefully to relieve any internal pressure, ground all connections, non - sparking explosion -proof equipment. KEMPER OA Other Precautions: Practice care, precaution and common sense. No smoking, open flames and no consumption of food while handling material. Avoid prolonged contact with skin, avoid breathing vapor. Styrene monomer is uninhibited and may form polymers in vents or flame arrestors of storage tanks, resulting in stoppage of vents. • FLOORS Partner for Professional Solutions in Roofing and Waterproofing SECTION :I PRODUCT INFORMATiON (_ A TRADE NAME: KEMPEROL ' Ik4: COMPONENT B TWO- COMPONENT LASHING RESIN CHEMICAL NAME AND SYNONYMS: POLYESTER FLASHING RESIN CHEMICAL FAMILY: UNSATURATED POLYESTER RESIN PRODUCT USE: ROOFING AND WATERPROOFING PREPARATION DATE: NOVEMBER 15, 1990 MANUFACTURER Kemper Systems, Inc. 550 South Michigan Street Seattle, Washington 98108 Emergency Phone: (800) 541-5455 Facsimile: (206) 767-9531 ORDER NUMBERS & PACKAGING: Com on B - White Formulation KO trA 2.28 US GAL (10.0 KGS) o Naltl'�I. [rta�• INGREDIENT STYRENE UNSATURATED POLYESTER RESIN DIMETHYLANILINE CAS # 100.42.5 8011-97-9 121 -69.7 OSHA PEL 50 ppm Not established 5 ppm TWA 10 ppm STEL ACGIH TLV 50 ppm/TWA 100 ppm /STEL Not established 5 ppm TWA 10 ppm /STEL PERCENTAGE 27 ± 3 Balance 1 TRANSPORTATION REOUIREMENTS DOT ID: UN 866 HAZARD CLASS: Flammable liquid LABEL: Flammable liquid SHIPPING NAME: Resin Solution SECTION IV - FiRE & EXPLOSION DATA Fiashpoint (C.O.C. method): 32 °C190 °F Flammable Limits: Lower: 1.1, Upper: 8 Autoignition Temperature: 490°C/914°F Extinguishing Media: Water fog, dry chemical, CO2, foam Special Fire Fighting Procedures: Fight as fuel oil fire, wear self - contained breathing apparatus. Cool containers with water. Unusual Fire & Explosion Hazards: If exposed to elevated temperatures for extended length of time, spontaneous exothermic polymerization may occur yielding violent rupture of packaging container. Sensitivity to Static Discharge: No data available. • SECTION III PHYSICAL DATA Physical State: Viscous liquid Odor & Appearance: White Odor Threshold (ppm): No data available Vapor Pressure (p 20 °C /68 °F7: <10 mbar (13.1 mm Hg) (styrene) Vapor Density (Air =1): 3.6 (styrene) Evaporation Rate: No data available Bolling Point: 145 °C/298 °F Freezing Point: No data available Melting Point: No data available Solubility In Water. 0.3 gIL (styrene) Specific Gravity: Approximately 1.16 Viscosity: Approximately 1,500 mPa SECTION V - REACTIVITY. DATA Stability: Stable. Conditions to Avoid: Sunlight, excessive heat, open flames, contamination with oxidizing agents, prolonged storage at temperatures >86 °F (30 °C) Incompatibles (materials to avoid): Peroxides and other oxidizing agents, promoters. Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, low molecular weight hydrocarbons, organic acids. Hazardous Polymerization: May occur if exposed to heat >100 °F /38 °C for prolonged time, open flame, contamination with oxidizer, improper addition of catalysts and /or promoters. THIS INFORMATION IS GIVEN IN GOOD FAITH, BUT NO WARRANTY, EXPRESS OR IMPLIED, IS MADE. THE PRODUCT IS NOT CLAIMED TO BE MERCHANTABLE OR FIT FOR ANY PARTICULAR PURPOSE. SUITABILITY IS DETERMINED BY USER. FOR INDUSTRIAL USE AND CERTIFIED APPLICATORS ONLY. Prepared from Importer supplied Information by Schumacher & Associates, Inc., Seattle, WA. No claim of completeness or accuracy Is made. MSDS 7671 A - B / 06 -91 SECTION VI - .HEALTH HAZARD DATA /TOXICOLOGICAL PROPERTIES- Emergency First AId Procedures: Inhalation: Remove to fresh air. If not breathing, give mouth to mouth resuscitation; If breathing Is difficult, give oxygen. Call physician immediately. Eyes: Remove contact lens(es), If present, and flush imme- diately with water for at least 15 minutes, carefully lifting the eyelids to expose the eye to contact with water. Get medical attention If irritation persists. Skin: Immediately flush skin with ample water for at least 15 minutes; remove and discard contaminated clothing and shoes; if irritation persists, call a physician. Ingestion: DO NOT Induce vomiting. Call physician and/or transport to emergency medical facility immediately. ROUTES OF ENTRY - STYRENE SKIN CONTACT SKIN ABSORPTION INHALATION Yes EXPOS. LIMITS Styr. 50 PPM TWA Yes IRRITANCY Yos SENSITIZATION CARCINOGENICITY Styrene • No Styrone • Yes Yes TERATOGENICITY Styrene • Yes ORAL LD50 (rat): 5000 mg /kg DERMAL LD50 (rat): No data available Threshold Limit Value: 50 ppm 8 -hour TWA/100 ppm STEL (styrene). Carcinogenicity: Styrene has been Identified by the IARC for Research on Cancer as a 28 carcinogen; limited animal evidence. As of January 1989, OSHA withdrew the carcinogen classification for styrene. Medical Conditions Generally Aggravated: Central nervous system, kidney, liver disorder history. Effects of Acute Exposure to Styrene: May cause Irritation of the lungs, throat, and airways, usually accompanied by cough, difficulty In breathing or swallowing, or as sensation of pain or burning In the lungs. May cause headache, disorientation, drowsiness, nausea, vomiting, euphoria, and dizziness. With Increasing exposure, symptoms may Include staggering gait, loss of coordination, breathing difficulty, unconsciousness, coma, and death. High exposure can also result In liver damage and possible liver 'failure. High exposure can result In kidney damage and possible kidney failure. ROUTES OF ENTRY - DI REPRO. TOXIC. Styrene • Yes INGESTION Yes MUTAGENICITY Styrone • Yes SYNERGISTIC No INHALATION LC50 (rat): 9500 ppm Effects of Chronic Overexposure to Styrene: Animal studies, and/or human epldemiologlc studies, indicate that this chemical may cause or contribute to the development of cancer. Reproductive hazard: May cause decreased fertility, miscarriage or birth defects. Long-term exposure to concentrations in excess of the PELJTLV may result in chronic bronchitis (cough and production of excess mucus) or chronic obstructive pulmonary disease (shortness of breath). Chronic exposure may result in reversible or irreversible damage to the nervous system resulting In some or all of the following symptoms: fatigue, sleep disturbance, headache, convulsions, nervous excitability, nerve paralysis, hallucinations, delusions, acute psychosis, tremor and loss or memory. May cause damage to the kidneys, which can result in swelling, Increased urinary protein, changes in urine composition, fluid retention, and, In severe cases, kidney failure. METHYLANILINE SKIN CONTACT Yes SKIN ABSORPTION Unknown INHALATION Yes INGESTION Yes _EXPOS. LIMITS DMA 5 PPM TWA IRRITANCY SENSITIZATION CARCINOGENICITY TERATOOENICITY REPRO. TOXIC. MUTAGENICITY SYNERGISTIC Yes DMA -No DMA -No DMA-No DMA -No DMA-No No ORAL LD50 (rat): 1410 mg /kg INHALATION LC50: No data available DERMAL LD50 (rabbit): 10 mg/24 hr. mild irritation Threshold Limit Value: 5 ppm 8-hour TWA/10 ppm STEL. Carcinogenicity: Dimethylanlllne is not listed as a carcinogen by OSHA, NTP or IARC. Target Organs: Central nervous system, liver, kidneys, blood. Effects of Acute Exposure to Dimethylanlllne: Inhalation of SECTION VII - SPILL OR LEAK PROCEDURES In Case Material Is Released or Spilled: Extinguish open flames, cut off electrical power to area, dike to prevent runoff Into waterways and sewers, cover spill with absorbent media (Le., peat, vermiculite, etc.), sweep up remaining contamination. Clean up with non-flammable solvent, dispose of cured media as solid waste in closed containers either at an approved landfill or incin- erate at an approved facility. Obey federal, state, county or any other regulations. Waste Disposal Method: Cured resin (catalyzed) may be disposed of at proper landfill and /or Incinerated. Obey all pertaining regulations. Unpolymerized resin should be catalyzed. If you need to dispose of uncatalyzod resin, it must be handled as a hazardous waste. Environmental: SARA 313: Styreno and dimethylaniline (DMA) are both reportable. Percentage styrene Is approx. 27% u:3. Percentage DMA is 1. RCRA: EPA waste code for unused resin Is D001 for a flammable liquid, VOC: VOCs are 27.3 grams per gallon. SECTION IX - SPECIAL PRECAUTIONS Special precautions with handling and storing: Always store dry and cool. Avoid prolonged storage above 80 °F (27 °C). Keep away from sunlight. Store and handle as NFPA Class 1•C. Open containers slowly and carefully to relieve any Internal pressure, ground all connections, non - sparking explosion - proof equipment. KEMPER 9B unmeasured concentrations may cause headache, dizziness, labored breathing, methemoglobinemia, cyanosis, and anemia. Severe exposures may cause visual disturbances, unconsciousness, and liver and kidney damage. Effects of Chronic Overexposure to Dimethylaniline: Repeated or prolonged exposure may affect the central nervous system. SECTION VIII -SPEC. PROTECTION INFORMATION Respiratory Protection: No respiratory protection is needed below 50 ppm. From 50 to 5000 ppm, use a NIOSH - approved half -mask with organic vapor cartridges. From 500 to 5,000 ppm, use a full - face respirator with organic vapor cartridges. Above 5000 ppm, an air-supplied respirator or self-contained breathing apparatus Is required. Ventilation: Recommended sufficient to control vapors to below 50 ppm. Natural ventilation may be sufficient on unobstructed roof top. If poor alr movement or close work required, local exhaust may be necessary. Protective Gloves: Gauntlet type; polyvinyl alcohol. Eye Protection: Face shield, safety glasses, or chemical goggles. Other Protective Clothing or Equipment: Solvent•reslstant shoes, boots, aprons - frequently cleaned to avoid skin contact, safety showers and eyewash equipment should be on -site. Other Precautions: Practice care, precaution and common sense. No smoking, open flames and no consumption of food '! Partner for Professional Solutions in.Roofiny and Waterproofing. SECTION. i = :PRODUCT INFORMATION: TRADE NAME: KEMPEROL S 210: COMPONENT A TWO COMPONENT RESIN - UL LISTED CHEMICAL NAME AND SYNONYMS: CHEMICAL FAMILY: PRODUCT USE: PREPARATION DATE: POLYESTER RESIN UNSATURATED POLYESTER RESIN ROOFING AND WATERPROOFING NOVEMBER 30, 1990 MANUFACTURER Kemper Systems, Inc. 550 South Michigan Street Seattle, Washington 98108 Emergency Phone: (800) 541 -5455 Facsimile: (206) 767 -9531 ORDER NUMBERS & PACKAGING: Component A - Black Formulation: K012110A 5.46 US GAL (25.0 KGS) K012111A 2.18 US GAL (10.0 KGS) K012112A 0.50 US GAL (2.3 KGS) (measurements include catalyst powder) SECTION II - INGREDIENT NAME HAZARDOUS INGREDIENTS Unsaturated Polyester Resin Styrene CAS # 100-42-5 8011-97-9 OSHA PEL 50 ppm Not established ACGIH TLV 100 ppm(STEL) Not established 50 ppm(TWA) PERCENTAGE 27±3 Balance TRANSPORTATION REQUIREMENTS DOT ID: UN 1866 HAZARD CLASS: Flammable liquid LABEL: Flammable liquid SHIP. NAME: Resin Solution SECTION IV - FIRE & EXPLOSION DATA Flashpoint (C.O.C. method): 32 °C190 °F Flammable Limits: Lower: 1.1, Upper: 8 Autoignitlon Temperature: 490 °C1914 °F Extinguishing Media: Water fog, dry chemical, CO2, foam. Special Fire Fighting Procedures: Fight as fuel oil fire, wear self - contained breathing apparatus. Cool containers with water. Unusual Fire & Explosion Hazards: If exposed to elevated temperatures for extended length of time, spontaneous exothermic polymerization may occur yielding violent rupture of packaging container. Sensitivity to Static Discharge: No data available. SECTION III - PHYSICAL DATA. Physical State: Viscous liquid Odor & Appearance: Black Odor Threshold (ppm): No data available Vapor Pressure: (020°C/68°F): <10 mbar (13.1 mm Hg) (styrene) Vapor Density (Air =1): 3.6 (styrene) Evaporation Rate: No data available Bolling Point: 145 °C/298 °F Freezing Point: No data available Melting Point: No data available Solubility In Water: 0.3 g/L (styrene) Specific Gravity: Approximately 1.21 Viscosity: Approximately 1,500 mPa SECTION V - REACTIVITY DATA Stability: Stable. Conditions to Avoid: Sunlight, excessive heat, open flames, contamination with oxidizing agents, prolonged storage >86 °F (30 °C) Incompatibilities (materials to avoid): Peroxides and other oxidizing agents, promoters. Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, low molecular weight hydrocarbons, organic acids. Hazardous Polymerization: May occur if exposed to heat >100 °F/38 °C for prolonged time, open flame, contamination with oxidizer, Improper addition of catalysts and/or promoters. THIS INFORMATION IS GIVEN IN GOOD FAITH, BUT NO WARRANTY, EXPRESS OR IMPLIED, IS MADE. THE PRODUCT IS NOT CLAIMED TO BE MERCHANTABLE OR FIT FOR ANY PARTICULAR PURPOSE. SUITABILITY IS DETERMINED BY USER. FOR INDUSTRIAL USE AND CERTIFIED APPLICATORS ONLY. Prepared from Importer supplied Information by Schumacher & Associates, Inc., Seattle, WA. No claim of completeness or accuracy le made. MSDS - S 210 - A - B / 06-91 SECTION VI.- HEALTH HAZARD DATA/TOXICOLOGICAL PROPERTIES Emergency First Aid Procedures: Inhalation: Remove to fresh air. If not breathing, give mouth to mouth resuscitation; if breathing is difficult, give oxygen and call physician. Eyes: Remove contact lens(es), if present, and flush immediately with water for at least 15 minutes, carefully lifting the eyelids to expose the eye to contact with ROUTES OF ENTRY - STYRENE water. Get medical attention if irritation persists. Skin: immediately flush skin with soap and water for at least 15 minutes; remove and discard contaminated clothing and shoes; if irritation persists, call a physician. Ingestion: DO NOT induce vomiting. Call physician and /or transport to emergency medical facility immediately. SKIN CONTACT SKIN ABSORPTION INHALATION INGESTION Yes Yes Yes Yes EXPOS. LIMITS IRRITANCY SENSITIZATION CARCINOGENICITY TERATOGENICITY REPRO. TOXIC. MUTAGENICITY SYNERGISTIC Styr. 50 PPM TWA Yos No Styrene • Yes Styreno - Yes Styrene • Yes Styreno • Yes No Oral LD50 (rat): 5000mg /kg Dermal LD50 (rat): Threshold Limit Value: 100 ppm STEU50 ppm 8 -hour TWA (styrene). Carcinogenicity: Styrene has been identified by the IARC as a 2B carcinogen; limited animal evidence. As of January 1989, OSHA withdrew the carcinogen classification for styrene. Medical Conditions Generally Aggravated: Central nervous system, kidney, liver disorder history. Effects of Acute Exposure to Styrene: May cause irritation of the lungs, throat, and airways, usually accompanied by cough, difficulty in breathing or swallowing, or as sensation of pain or burning in the lungs. May cause headache, disorientation, drowsiness, nausea, vomiting, euphoria, and dizziness. With Increasing exposure, symptoms may include staggering gait, loss of coordin- ation, breathing difficulty, unconsciousness, coma, and death. High exposure can also result in liver damage and possible liver failure. High exposure can result in kidney damage and possible kidney failure. SECT! • N 'VII SPILL OR LEAK PROCEDURES In case material is released or spilled: Extinguish open flames, cut off electrical power to area, dike to prevent run -off Into waterways and sewers, cover spill with absorbent media (i.e. peat, vermiculite, etc.), sweep up remaining contamination. Clean up with non - flammable solvent, dispose of cured media as solid waste In closed containers either at an approved landfill or incinerate at an approved facility. Obey federal, state, county or any other regulations. Waste Disposal Method: Cured resin (catalyzed) will solidify and may be disposed of at proper landfill and /or incinerated. Obey all pertaining regulations. Unpolymerized resin should be catalyzed. If you need to dispose of uncatalyzed resin, it must be handled as a hazarous waste. Environmental: SARA 313: Styrene is reportable. Percentage styrene is approx. 27% ± 3. RCRA: EPA waste code for unused resin is D001 for a flammable liquid. VOC: VOCs are 27.3 grams per gallon. No data available Inhalation LC50 (rat): 9500 ppm Effects of Chronic Overexposure to Styrene: Animal studies, and /or human epidemiologic studies, indicate that this chemical may cause or contribute to the development of cancer. Reproductive hazard: May cause decreased fertility, miscarriage or birth defects. Long- term exposure to concentrations in excess of the PEUTLV may result in chronic bronchitis (cough and production of excess mucus) or chronic obstructive pulmonary disease (shortness of breath). Chronic exposure may result in reversible or irreversible damage to the nervous system resulting in some or all of the following symptoms: fatigue, sleep disturbance, headache, convulsions, nervous excitability, nerve paralysis, hallucinations, delusions, acute psychosis, tremor and loss of memory. May cause damage to the kidneys, which can result in swelling, increased urinary protein, changes in urine composition, fluid retention, and, In severe cases, kidney failure. SECTION VIII -SPEC. PROTECTION INFORMATION Respiratory Protection: No respiratory protection is needed below 50 ppm. From 50 to 500 ppm, use a NIOSH- approved half -mask with organic vapor cartridges. From 500 to 5,000 ppm, use a full -face respirator with organic vapor cartridges. Above 5,000 ppm, an air - supplied respirator or self - contained breathing apparatus is required. Ventilation: Recommended sufficient to control vapors to below 50 ppm. Natural ventilation may be sufficient on unobstructed roof top. If poor air movement or close work required, local exhaust may be necessary. Protective Gloves: Gauntlet type; polyvinyl alcohol. Eye Protection: Face shield, safety glasses, or chemical goggles. Other Protective Clothing or Equipment: Solvent - resistant shoes, boots, aprons - frequently cleaned to avoid skin contact. Safety showers and eye -wash equipment should be on -site. SECTION IX .- SPECIAL PRECAUTIONS Special precautions with handling and storing: Always store dry and cool. Avoid prolonged storage above 80 °F (27 °C). Keep away from sunlight. Store and handle as NFPA Class 1 -C. Open containers slowly and carefully to relieve any internal pressure, ground all connections, use non - sparking explosion -proof equipment. KEMPER 4A Other precautions: Practice care, precaution and common sense. No smoking, open flames and no consumption of food while handling material. Avoid prolonged contact with skin, avoid breathing vapor. Styrene monomer is uninhibited and may form polymers in vents or flame arrestors of storage tanks, resulting in stoppage of vents. Partner for Professional Solutions in Ro ng'and Waterproofing;: SECTION I - :PRODUCT.INFORMATION. Meets OSHA & WHMIS° TRADE NAME: KEMPEROL S 210: COMPONENT B TWO COMPONENT RESIN - UI. RATED CHEMICAL NAME AND SYNONYMS: CHEMICAL FAMILY: PRODUCT USE: PREPARATION DATE: POLYESTER RESIN UNSATURATED POLYESTER RESIN ROOFING AND WATERPROOFING NOVEMBER 30, 1990 MANUFACTURER Kemper Systems, Inc. 550 South Michigan Street Seattle, Washington 98108 Emergency Phone: (800) 541-5455 Facsimile: (206) 767 -9531 ORDER NUMBERS & PACKAGING: Component B - White Formulation: K012110/B 5.46 US GAL (25.0 KGS) K012111/B 2.18 US GAL (10.0 KGS) K012112/B 0.50 US GAL (2.3 KGS) SECTION. 11 - HAZARDOUS INGREDIENTS INGREDIENT STYRENE POLYESATUR TEDIN DIMETHYLANILINE CAS # 100.42.5 8011.97.9 121.69.7 OSHA PEL 50 ppm Not established 5 ppm TWA 10 ppm STEL ACGIH TLV 50 ppmfrWA 100 ppm/STEL Not established 5 ppm TWA 10 ppm STEL PERCENTAGE 27 *3 Balance 1 TRANSPORTATION REQUIREMENTS DOT ID NUMBER: UN 1856 HAZARD CLASS: Flammable liquid LABEL: Flammable liquid SHIPPING NAME: Resin Solution SECTION IV - FIRE & EXPLOSION DATA Flashpolnt (C.O.C. method): 32 °C190 °F Flammable Limits: Lower: 1.1%, Upper: 8% Autolgnition Temperature: 490 °C1914 °F Extinguishing Media: Water fog, dry chemical, CO2, foam. Special Fire Fighting Procedures: Fight as fuel oil fire, wear self - contained breathing apparatus. Cool containers with water. Unusual Fire & Explosion Hazards: If exposed to elevated temperatures for extended length of time, spontaneous exothermic polymerization may occur yielding violent rupture of packaging container. Sensitivity to Static Discharge: No data available. SECTION 111 - PHYSICAL DATA Physical State: Odor & Appearance: Odor Threshold (ppm): Vapor Pressure ( ®20°C/68°F): Vapor Density (Air =1): Evaporation Rate: Boiling Point: Freezing Point: Melting Point: Solubility In Water. Specific Gravity: Viscosity: Viscous liquid White No data available <10 mbar (13.1 mm Hg) (styrene) 3.6 (styrene) No data available 145 °C1298 °F No data available No data available 0.3 gIL (styrene) Approximately 1.16 Approximately 1,500 mPa SECTION V - REACTIVITY DATA Stability: Stable. Conditions to Avoid: Sunlight, excessive heat, open flames, contamination with oxidizing agents, prolonged storage at temperatures >86 °F (30 °C) Incompatibilities (materials to avoid): Peroxides and other oxidizing agents, promoters. Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, low molecular weight hydrocarbons, organic acids. Hazardous Polymerization: May occur if exposed to heat >100 °F /38 °C for prolonged time, open flame, contamination with oxidizer, Improper addition of catalysts and/or promoters. THIS INFORMATION IS GIVEN IN GOOD FAITH, BUT NO WARRANTY, EXPRESS OR IMPLIED, IS MADE. THE PRODUCT IS NOT CLAIMED TO BE MERCHANTABLE OR FIT FOR ANY PARTICULAR PURPOSE. SUITABILITY IS DETERMINED BY USER. FOR INDUSTRIAL USE AND CERTIFIED APPLICATORS ONLY. Prepared from Importer supplled Information by Schumacher & Associates, Inc., Seattle, WA. No claim of completeness or accuracy Is made. KEMPER 40 MSDS - S 210 - A - B / 06 -91 SECTION VI - HEALTH. HAZARD DATA /TOXICOLOGICAL PROPERTIES First Aid Procedures: Inhalation: Remove to fresh alr. If not breathing, give mouth to mouth resuscitation; If breathing is difficult, give oxygen. Call physician Immediately. Eyes: Remove contact lens(es), If present, and flush imme- diately with water for at least 15 minutes, carefully lifting the eyelids to expose the eye to contact with water. Get medical SKIN CONTACT Yes SKIN ABSORPTION Yes EXPOS. LIMITS IRRITANCY SENSITIZATION Styr. 50 PPM TWA Yes Styrene - No ORAL LD50 (rat): 5000 mg /kg attention if irritation persists. Skin: Immediately flush skin with soap and water for at least 15 minutes; remove and discard contaminated clothing and shoes; If irritation persists, call physician. Ingestion: DO NOT Induce vomiting. Call physician and/or transport to emergency medical facility immediately. ROUTES OF ENTRY - STYRENE INHALATION Yes INGESTION Yes CARCINOGENICITY TERATOGENICITY Styrene - Yes Styrene - Yes DERMAL LD50: No data available Threshold Limit Value: 50 ppm 8•hour TWA/100 ppm STEL (styrene) Carcinogenicity: Styrene has been identified by the IARC as a 2B carcinogen; limited animal evidence. As of January 1989, OSHA withdrew the carcinogen classification for styrene. Medical Conditions Generally Aggravated: Central nervous system, kidney, liver disorder history. Effects of Acute Exposure to Styrene: May cause irritation of the lungs, throat, and airways, usually accompanied by cough, diffi- culty in breathing or swallowing, or as sensation of pain or burning In the lungs. May cause headache, disorientation, drowsi- ness, nausea, vomiting, euphoria, and dizziness. With increasing exposure, symptoms may include staggering gait, loss of coordination, breathing difficulty, unconsciousness, coma, and death. High exposure can also result in liver damage and possible liver failure. High exposure can result In kidney damage and possible kidney failure. SKIN CONTACT Yes REPRO. TOXIC. MUTAGENICITY Styrene • Yes Styrene - Yes SYNERGISTIC No INHALATION LC50: 9500 ppm Effects of Chronic Overexposure to Styrene: Animal studies, and /or human epidemiologic studies, indicate that this chemical may cause or contribute to the development of cancer. Reproduc- tive hazard: May cause decreased fertility, miscarriage or birth defects. Long-term exposure to concentrations in excess of the PELJTLV may result in chronic bronchitis (cough and production of excess mucus) or chronic obstructive pulmonary disease (shortness of breath). Chronic exposure may result in reversible or irreversible damage to the nervous system resulting in some or all of the following symptoms: fatigue, sleep disturbance, headache, convulsions, nervous excitability, nerve paralysis, hallucinations, delusions, acute psychosis, tremor and loss of memory. May cause damage to the kidneys, which can result In swelling, Increased urinary protein, changes in urine composition, fluid retention, and, in severe cases, kidney failure. ROUTES OF ENTRY - DIMETHYLANILINE SKIN ABSORPTION Unknown INHALATION Yes EXPOS. LIMITS IRRITANCY DMA 50 PPM TWA Yes SENSITIZATION CARCINOGENICITY TERATOGENICITY DMA • Yes DMA - No DMA - No J REPRO. TOXIC. DMA No INGESTION Yes MUTAGENICITY DMA - No SYNERGISTIC No ORAL LD50 (rat): 1410 mg/kg DERMAL LD50 (rabbit): 10 mg/24 hr. mild irritation INHALATION LC50: No data available Threshold Limit Value: 5 ppm 8•hour TWA/10 ppm STEL. Carcinogenicity: Dimethylaniline is not listed as a carcinogen by OSHA, NTP or IARC. Target Organs /Symptoms: Central nervous system, liver, kidney, blood. Effects of Acute Exposure to Dimethylanillne: Inhalation of unmeasured concentrations may cause headache, dizziness, SECTION VII - SPILL OR LEAK PROCEDURES In case material Is released or spilled: Extinguish open flames, cut off electrical power to area, dike to prevent run-off Into waterways and sewers, cover spill with absorbent media (i.e. peat, vermiculite, etc.), sweep up remaining contamination. Clean up with non-flammable solvent, dispose of cured media as solid waste In closed containers either at an approved landfill or incin- erate at an approved facility. Obey federal, state, county or any other regulations. Waste Disposal Method: Cured resin (catalyzed) may be disposed of at proper landfill and /or incinerated. Obey all pertaining regulations. Unpolymerized resin should be catalyzed. If you need to dispose of uncatalyzed resin, it must be handled as a hazarous waste. Environmental: SARA 313: Styrene 2nd dimethylanillne (DMA) are both reportable. Percentage styrene Is approx. 27% ±3. Percentage DMA is 1. RCRA: EPA waste code for unused resin is D001 for a flammable liquid. VOC: VOCs are 27.3 grams per gallon. labored breathing, methemogiobinema, cyanosis, and anemia. Severe exposure may cause visual disturbances, unconscious- ness, and liver and kidney damage. Effects of Chronic Overexposure to Dimethylanillne: Repeated or prolonged exposure may affect the central nervous system. SECTION VIII -SPEC. PROTECTION INFORMATION Respiratory Protection: No respiratory protection Is needed below 50 ppm. From 50 to 500 ppm, use a NIOSH- approved half -mask with organic vapor cartridges. From 500 to 5,000 ppm, use a full - face respirator with organic vapor cartridges. Above 5,000 ppm, an air - supplied respirator or self-contained breathing apparatus is required. Ventilation: Recommended sufficient to control vapors to below 50 ppm. Natural ventilation may be sufficient on unobstructed rooftop. If poor air movement or close work required, local exhaust may be necessary. Protective Gloves: Gauntlet type; polyvinyl alcohol. Eye Protection: Face shield, safety glasses, or chemical goggles. Other Protective Clothing or Equipment Solvent - resistant shoes, boots, aprons - frequently cleaned to avoid skin contact. Safety showers and eye-wash equipment should be on -site. SECTION IX - SPECIAL PRECAUTIONS Special precautions with handling and storing: Always store dry and cool. Avoid prolonged storage above 80 °F (27°C). Keep away from sunlight. Store and handle as National Protective Association Class 1 -C. Open containers slowly and carefully to relieve any internal pressure, ground all connections, non - sparking explosion -proof equipment is to be used. Other precautions: Practice care, precaution and common sense. No smoking, open flames and no consumption of food while handling material. Avoid prolonged contact with skin, avoid breathing vapor. Styrene monomer Is uninhibited and may form polymers In vents or flame arrestors of storage tanks, resulting In stoppage of vents. • • • Partner forProfesiional Solutions in Roofing and Waterproofing SECTION `.1 - `,PRODUCT INFORMATION. -' MSDS Material Safety Data.Sheet.' Meets OSHA & WHMIS TRADE NAME: KEMPEROL V 210: COMPONENT B TWO COMPONENT RESIN CHEMICAL NAME AND SYNONYMS: POLYESTER RESIN CHEMICAL FAMILY: UNSATURATED POLYESTER RESIN PRODUCT USE: ROOFING AND WATERPROOFING PREPARATION DATE: NOVEMBER 30, 1990 MANUFACTURER Kemper Systems, Inc. 550 South Michigan Street Seattle, Washington 98108 Emergency Phone: (800) 541 -5455 Facsimile: (206) 767 -9531 ORDER NUMBERS & PACKAGING: Component B - White Formulation: K012010/B 5.69 US GAL (25.0 KGS) K012011/B 2.28 US GAL (10.0 KGS) K012012 /B .50 US GAL (2.2 KGS) SECTION Ii - HAZARDOUS INGREDIENTS UNSATURATED POLYESTER RESIN • DIMETHYLANILINE INGREDIENT NAME: STYRENE CAS if 100.42.5 8011.97.9 121-69-7 OSHA PEL 50 ppm Not established 5 ppm TWA 10 ppm STEL ACGIH TLV 50 ppm/TWA 100 ppm /STEL Not established 5 ppm TWA 10 ppm /STEL PERCENTAGE 27 t 3 Balance 1 TRANSPORTATION REQUIREMENTS DOT ID NUMBER: UN 1866 HAZARD CLASS: Flammable liquid LABEL: Flammable liquid SHIPPING NAME: Resin Solution SECTION IV - FIRE & EXPLOSION DATA Flashpoint (C.O.C. method): 32°C/90°F Flammable Limits: Lower: 1.1%, Upper: 8% Autolgnition Temperature: 490°C/914°F Extinguishing Media: Water fog, dry chemical, CO2, foam. Special Fire Fighting Procedures: Fight as fuel oil fire, wear self- contained breathing apparatus. Cool containers with water. Unusual Fire & Explosion Hazards: If exposed to elevated temperatures for extended length of time, spontaneous exothermic polymerization may occur yielding violent rupture of packaging container. Sensitivity to Static Discharge: No data available. SECTION I11 - 'PHYSICAL DATA Physical State: Odor & Appearance: Odor Threshold (ppm): Vapor Pressure ( ®20 °C /68 °F): Vapor Density (Air =1): Evaporation Rate: Bolling Point: Freezing Point: Melting Point: Solubility in Water. Specific Gravity: Viscosity: Viscous liquid White No data available <10 mbar (13.1 mm Hg) (styrene) 3.6 (styrene) No data available 145 °C /298 °F No data available No data available 0.3 grams per liter (styrene) Approximately 1.16 Approximately 1,500 mPa SECTION 1/ - REACTIVITY DATA Stability: Stable. Conditions to Avoid: Sunlight, excessive heat, open flames, contamination with oxidizing agents, prolonged storage at temperatures > 86°F (30°C). Incompatibles (materials to avoid): Peroxides and other oxidizing agents, promoters. Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, low molecular weight hydrocarbons, organic acids. Hazardous Polymerization: May occur if exposed to heat> 100 °F /38 °C for prolonged time, open flame, contamination with oxidizer, improper addition of catalysts and/or promoters. MSDS - V 210 - A - B / 06-91 SECTION VI HEALTH HAZARD DATA/TOXICOLOGICAL PROPERTIES Emergency First Aid Procedures: Inhalation: Remove to fresh air. If not breathing, give mouth to attention If Irritation persists. mouth resuscitation; if breathing Is difficult, give oxygen. Call Skin: Immediately flush skin with soap and water for at least 15 physician immediately. minutes; remove and discard contaminated clothing and shoes; if Eyes: Remove contact lens(es), if present, and flush imme- irritation persists, call a physician. dlately with water for at least 15 minutes, carefully lifting the Ingestion: DO NOT induce vomiting. Call physician and/or eyelids to expose the eye to contact with water. Get medical transport to emergency medical facility immediately. ROUTES OF ENTRY - STYRENE SKIN CONTACT SKIN ABSORPTION INHALATION Yes Yes Yes INGESTION Yes EXPOS. LIMITS IRRITANCY SENSITIZATION Styr. 50 PPM TWA Yes Styrene - No CARCINOGENICITY TERATOGENICITY Styrene - Yes Styrene • Yes ORAL LD50 (rat): 5000 mg /kg DERMAL LD50 (rat): No data available Threshold Limit Value: 50 ppm 8 -hour TWA/100 ppm STEL (styrene) Carcinogenicity: Styrene has been identified by the IARC as a 2B carcinogen; limited animal evidence. As of January 1989, OSHA withdrew the carcinogen classification for styrene. Medical Conditions Generally Aggravated: Central nervous system, kidney, liver disorder history. Effects of Acute Exposure to Styrene: May cause irritation of the lungs, throat, and airways, usually accompanied by cough, difficulty in breathing or swallowing, or as sensation of pain or burning in the lungs. May cause headache, disorientation, drowsiness, nausea, vomiting, euphoria, and dizziness. With increasing exposure, symptoms may Include staggering gait, loss of coordination, breathing difficulty, unconsciousness, coma, and death. High exposure can result in liver damage and possible liver failure. High exposure can also result in kidney damage and possible kidney failure. ROUTES OF ENTRY - REPRO. TOXIC. MUTAOENICITY SYNERGISTIC Styrene • Yes Styrene - Yes No INHALATION LC50 (rat): 9500 ppm Effects of Chronic Overexposure to Styrene: Animal studies, and /or human epidemiologlc studies, Indicate that this chemical may cause or contribute to the development of cancer. Reproductive hazard: May cause decreased fertility, miscarriage or birth defects. Long-term exposure to concentrations in excess of the PEL/TLV may result In chronic bronchitis (cough and production of excess mucus) or chronic obstructive pulmonary disease (shortness of breath). Chronic exposure may result In reversible or Irreversible damage to the nervous system resulting In some or all of the following symptoms: fatigue, sleep disturbance, headache, convulsions, nervous excitability, nerve paralysis, hallucinations, delusions, acute psychosis, tremor and loss of memory. May cause damage to the kidneys, which can result in swelling, Increased urinary protein, changes In urine composition, fluid retention, and, in severe cases, kidney failure. DIMETHYLANILINE SKIN CONTACT SKIN ABSORPTION INHALATION INGESTION Yes Unknown Yes Yes EXPOS. LIMITS IRRITANCY SENSITIZATION CARCINOGENICITY TERATOGENICITY REPRO. TOXIC. MUTAOENICITY SYNERGISTIC DMA 50 PPM TWA DMA • No ORAL LD 50 (rat): 1410 mg /KG DERMAL LD 50 (rabbit): 10 mg/24 hr. mild irritation INHALATION LC 50 (rat): No data available Threshold Limit Value: 5 ppm 8 -hour TWA/10 ppm STEL Target Organs: Central nervous system, liver, kidneys, blood. Effects of Acute Exposure to Dimethylanlline: Inhalation of unmeasured concentrations may cause headache, dizziness, DMA-Yes DMA-No DMA -No DMA -No DMA -No No SECTION VII - SPILL OR LEAK PROCEDURES In case material Is released or spilled: Extinguish open flames, cut off electrical power to area, dike to prevent run-off into waterways and sewers, cover spill with absorbent media (i.e., peat, vermiculite, etc.), sweep up remaining contamination. Clean up with non-flammable solvent, dispose of cured media as solid waste in closed containers either at an approved landfill or incinerate at an approved facility. Obey federal, state, county or any other regulations. Waste Disposal Method: Cured resin (catalyzed) may be disposed at proper landfill and /or incinerated. Obey all pertaining regulations. Unpolymerized resin should be catalyzed. If you need to dispose uncatalyzed resin, It must be handled as a hazardous waste. Environmental: SARA 313: Styrene and dimethylaniline (DMA) are both reportable. Percentage styrene is approx. 27% ±3. Percentage DMA Is t VOCs: VOCs are 27.3 grams per gallon. RCRA: EPA waste code for unused resin Is D001 for a flammable liquid. SECTION IX - SPECIAL PRECAUTIONS Special precautions with handling and storing: Always store dry and cool. Avoid prolonged storage above 80 °F (27 °C). Keep away from sunlight. Store and handle as NPAC Class 1-0. Open containers slowly and carefully to relieve any • labored breathing, methemoglobinemia, cyanosis, and anemia. Severe exposures may cause visual disturbances, unconscious- ness, and liver and kidney damage. Effects of Chronic Overexposure to Dimethylanlline: Repeated or prolonged exposure may affect the central nervous system. SECTION VIII -SPEC. PROTECTION INFORMATION Respiratory Protection: No respiratory protection Is needed below 50 ppm. From 50 to 500 ppm, use a NIOSH•approved half -mask with organic vapor cartridges. From 500 to 5,000 ppm, use a full- face respirator with organic vapor cartridges. Above 5,000 ppm, an air-supplied respirator or self-contained breathing apparatus Is required. Ventilation: Recommended sufficient to control vapors to below 50 ppm. Natural ventilation may be sufficient on unobstructed roof top. If poor air movement or close work required, local exhaust may be necessary. Protective Gloves: Gauntlet type; polyvinyl alcohol. Eye Protection: Face shield, safety glasses, or chemical goggles. Other Protective Clothing or Equipment: Solvent - resistant shoes, boots, aprons - frequently cleaned to avoid skin contact. Safety showers and eye-wash equipment should be on -site. Internal pressure, ground all connections, non - sparking explosion - proof equipment Is to be used. Other precautions: Practice care, precaution and common sense. No smoking, open flames and no consumption of food while handling material. Avoid prolonged contact with skin, avoid breathing vapor. Styrene monomer Is uninhibited and may form THIS INFORMATION IS GIVEN IN GOOD FAITH, BUT NO WARRANTY, EXPRESS OR IMPLIED, IS MADE. THE PRODUCT IS NOT CLAIMED TO BE MERCHANTABLE OR FIT FOR ANY PARTICULAR PURPOSE. SUITABILITY IS DETERMINED BY USER. FOR INDUSTRIAL USE AND CERTIFIED APPLICATORS ONLY. Prepared from Importer supplied Information by Schumacher & Associates, Inc., Seattle, WA. No claim of completeness or accuracy Is made. KEMPER•3B .Partner'for Professional Solutions in Roofing aind Waterproofing SECTION I - *PRODUCT INFORMATION TRADE NAME: KEMPEROL V 210: COMPONENT A TWO - COMPONENT RESIN CHEMICAL NAME AND SYNONYMS: CHEMICAL FAMILY: PRODUCT USE: PREPARATION DATE: POLYESTER RESIN UNSATURATED POLYESTER RESiN ROOFING AND WATERPROOFING NOVEMBER 30, 1990 MANUFACTURER Kemper Systems, inc. 550 South Michigan Street Seattle, Washington 98108 Emergency Phone: (800) 541 -5455 Facsimile: (206) 767-9531 ORDER NUMBERS & PACKAGING: Component A - Black Formulation: K012010A 5.69 US GAL (25.0 KGS) K012011A 2.28 US GAL (10.0 KGS) K012012A 0.50 US GAL (2.2 KGS) (measurements include catalyst powder) SECTION II. - HAZARDOUS INGREDIENTS INGREDIENT NAME Styrene Unsaturated Polyester Resin CAS # 100 -42.5 8011 -97 -9 OSHA PEL 50 ppm Not established ACGIH TLV 100 ppm /STEL Not established 50 ppm /TWA PERCENTAGE 27 ± 3 Balance TRANSPORTATION REQUIREMENTS DOT ID: UN 1866 Hazard Class: Flammable liquid Label: Flammable liquid Ship. Name: Resin Solution SECTION IV - FIRE & EXPLOSION DATA Flashpoint (C.O.C. method): 32 °C /90 °F Flammable Limits: Lower: 1.1%, Upper: 8% Autoignition Temperature: 490 °C1914 °F Extinguishing Media: Water fog, dry chemical, CO2, foam. Special Fire Fighting Procedures: Fight as fuel oil fire, wear self- contained breathing apparatus. Cool containers with water. Unusual Fire & Explosion Hazards: If exposed to elevated temperatures for extended length of time, spontaneous exothermic polymerization may occur yielding violent rupture of packaging container. Sensitivity to Static Discharge: No data available. SECTION III - PHYSICAL DATA Physical State: Odor & Appearance: Odor Threshold (ppm): Vapor Pressure: ( ®20°C/68°F): Vapor Density (Air =1): Evaporation Rate: Boiling Point: Freezing Point: Melting Point: Solubility In Water: Specific Gravity: Viscosity: Viscous liquid Black No data available <10 mbar (13.1mm Hg) (styrene) 3.6 (styrene) No data available 145 °C/298 °F No data available No data available 0.3 gIL (styrene) Approximately 1.16 Approximately 1,500 mPa SECTION V -. REACTIVITY DATA Stability: Stable. Conditions to Avoid: Sunlight, excessive heat, open flames, contamination with oxidizing agents, prolonged storage at temperatures> 86 °F (30 °C). Incompatibles (materials to avoid): Peroxides and other oxidizing agents, promoters. Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, low molecular weight hydrocarbons, organic acids. Hazardous Polymerization: May occur if exposed to heat >100 °F /38 °C for prolonged time, open flame, contamination with oxidizer, improper addition of catalysts and /or promoters. MSDS- V210- A- B/06 -91 SECTION. VI - HEALTH :HAZARD DATAITOXICOLOGICAL PROPERTIES Emorgency First Aid Procedures: Inhalation: Remove to fresh air. If not breathing, give mouth to mouth resuscitation; If breathing is difficult, give oxygen. Call physician immediately. Eyes: Remove contact lens(es), if present, and flush immediately with water for at least 15 minutes, carefully ROUTES OF ENTRY - STYRENE lifting the eyelids to expose the eye to contact with water. Get medical attention if irritation persists. Skin: Immediately flush skin with soap and water for at least 15 minutes; remove and discard contaminated clothing and shoes; if irritation persists, call a physician. Ingestion: DO NOT induce vomiting. Call physician and/or transport to emergency medical facility immediately. SKIN CONTACT SKIN ABSORPTION INHALATION INGESTION Yes Yes Yes Yes EXPOS. LIMITS IRRITANCY Styr. 50 PPM TWA Yes SENSITIZATION No CARCINOGENICITY Styrene • Yes TERATOGENICITY Styrene • Yes REPRO. TOXIC. MUTAGENICITY Styrene • Yes Styrene • Yes SYNERGISTIC No ORAL LD50 (rat): 5000 /mg /kg DERMAL LD50 (rat): No data available. INHALATION LC50 (rat): 9500 ppm Threshold Limit Value: 100 ppm STEU50 ppm 8 -hour TWA (styrene). Carcinogenicity: Styrene has been Identified by the IARC as a 2B carcinogen; limited animal evidence. As of January 1989, OSHA withdrew the carcinogen classi- fication for styrene. Medical Conditions Generally Aggravated: Central nervous system, kidney, liver disorder history. Effects of Acute Exposure to Styrene: May cause irritation of the lungs, throat, and airways, usually accompanied by cough, difficulty in breathing or swallowing, or as sensation of pain or burning in the lungs. May cause headache, disorientation, drowsiness, nausea, vomiting, euphoria, and dizziness. With increasing exposure, symptoms may include staggering gait, loss of coordin- ation, breathing difficulty, unconsciousness, coma, and death. High exposure can also result in liver damage and possible liver failure. High exposure can result in kidney damage and possible kidney failure. SECTION VII - SPILL OR LEAK PROCEDURES Effects of Chronic Overexposure to Styrene: Animal studies, and/or human epidemlologic studies, indicate that this chemical may cause or contribute to the development of cancer. Reproductive hazard: May cause decreased fertility, miscarriage or birth defects. Long -term exposure to concentrations in excess of the PEUTLV may result in chronic bronchitis (cough and production of excess mucus) or chronic obstructive pulmonary disease (short- ness of breath). Chronic exposure may result in reversible or irreversible damage to the nervous system resulting In some or all of the following symptoms: fatigue, sleep disturbance, headache, convulsions, nervous excitability, nerve paralysis, hallucinations, delusions, acute psychosis, tremor and loss of memory. May cause damage to the kidneys, which can result in swelling, increased urinary protein, changes in urine composition, fluid retention, and, in severe cases, kidney failure. In case material Is released or spilled: Extinguish open flames, cut off electrical power to area, dike to prevent run -off into waterways and sewers, cover spill with absorb- ent media (i.e. peat, vermiculite, etc.), sweep up remaining contamination. Clean up with non - flammable solvent, dis- pose of cured media as solid waste in closed containers either at an approved landfill or incinerate at an approved facility. Obey federal, state, county or any other regulations. Waste Disposal Method: Cured resin (catalyzed) will solidify and may be disposed of at proper landfill and /or incinerated. Obey all pertaining regulations. Unpolymerized resin should be catalyzed. If you need to dispose of uncatalyzed resin, It must be handled as a hazardous waste. Environmental: SARA 313: Styrene Is reportable. Percentage styrene is approx. 27% ± 3. RCRA: EPA waste code for unused resin is D001 for a flammable liquid. VOCs: VOCs are 27.3 grams per gallon. SECTION IX - SPECIAL PRECAUTIONS Special precautions with handling and storing: Always store dry and cool. Avoid prolonged storage above 80 °F (27 °C). Keep away from sunlight. Store and handle as NFPA Class 1 -C. Open containers slowly and carefully SECTION VIII - SPEC. PROTECTION INFORMATION. Respiratory Protection: No respiratory protection is needed below 50 ppm. From 50 to 500 ppm, use a NIOSH- approved half-mask with organic vapor cartridges. From 500 to 5,000 ppm, use a full -face respirator with organic vapor cartridges. Above 5,000 ppm, an air - supplied respirator or self - contained breathing apparatus is required. Ventilation: Recommended sufficient to control vapors to below 50 ppm. Natural ventilation may be sufficient on unobstructed rooftop. If poor air movement or close work required, local exhaust may be necessary. Protective Gloves: Gauntlet type; polyvinyl alcohol. Eye Protection: Face shield, safety glasses, or chemical goggles. Other Protective Clothing or Equipment: Solvent - resistant shoes, boots, aprons - frequently cleaned to avoid skin contact. Safety showers and eye -wash equipment should be on-site. to relieve any Internal pressure, ground all connections, non-sparking explosion-proof equipment Is to be used. Other precautions: Practice care, precaution and common sense. No smoking, open flames and no consumption of food while handling material. Avoid prolonged contact with skin, avoid breathing vapor. Styrene monomer is uninhibited and may form polymers in vents or flame arrestors of storage tanks, resulting in stoppage of vents. THIS INFORMATION IS GIVEN IN GOOD FAITH, BUT NO WARRANTY, EXPRESS OR IMPLIED, IS MADE. THE PRODUCT IS NOT CLAIMED TO BE MERCHANTABLE OR FIT FOR ANY PARTICULAR PURPOSE. SUITABILITY IS DETERMINED BY USER. FOR INDUSTRIAL USE AND CERTIFIED APPLICATORS ONLY. Prepared from Importer supplied Information by Schumacher & Associates, Inc., Seattle, WA. No claim of completeness or accuracy Is made. KEMPER -3A • Partner for Professional Solutions hi Roofing and Waterproofing. . SECTION I,- PRODUCT:IN.FORMATION .: TRADE NAME: KEMPERDUR SAND BINDER RESIN CHEMICAL NAME AND SYNONYMS: PRODUCT USE: PREPARATION DATE: 1,6- Hexamethylene Diisocyanate Based Polyisocyanate, Polymeric Hexamethylene Diisocyanate TRAFFIC SURFACE FINISH APRIL 8, 1991 MANUFACTURER Kemper Systems, Inc. 550 South Michigan Street Seattle, Washington 98108 Emergency Phone: (800) 541 -5455 Facsimile: (206) 767 -9531 ORDER NUMBERS & PACKAGING: K0045702Y 4.4 LBS (2.0 KGS) SECTION 1I - HAZARDOUS INGREDIENTS INGREDIENT Homopolymer of HDI Hexamethylene Dlisocya CAS N 28182.81 -2 822.06.0 OSHA PEL Not established Not established ACGIH TLV Not established 0.005 ppm (TWA) NIOSH EXP. LIMIT RECOMMENDATIONS Not establised 0.005 ppm (TWA) 0.02 ppm (10 -min. ceiling) OTHER EXP. LIMITS (MOBAY GO. LEVS.) 0.5 mg/m3 (TWA) 1.0 mg /m3 TEL) 0.02 ppm (ceiling PERCENTAGE Essentially 100 v 0.2 based on resin solids /time of manuf. TRANSPORTATION HAZARD CLASS; LABEL: DOT SHIP. NAME: TECH. SHIP. NAME: �"fs!111 as Non - Regulated • r, Non - Regulated a �, None Polyisocyanate SECTION IV. - FIRE & EXPLOSION DATA Fiashpolnt (Setaflash): 460 °F (237.7 °C) Autoignition Temperature: 860 °F (460 °C) Extinguishing Media: Dry Chemical, Carbon Dioxide, Foam; Water Spray for larger fires. Special Fire Fighting Procedures: Full emergency equipment with self-contained breathing apparatus and full protective clothing should be worn by firefighters. Unusual Fire & Explosion Hazards: During a fire, HDI vapors and other irritating or highly toxic gases may be generated by thermal decomposition or combustion (see Section V). Closed container may explode when exposed to extreme heat or may burst when contaminated with water (CO2 evolved). Sensitivity to Static Discharge: No data available. SECTION IH - PHYSICAL DATA Physical State: Odor & Appearance: Odor Threshold (ppm): Vapor Pressure (mmlHg): Vapor Density (Air =1): Evaporation Rate: Bolling Point: Freezing Point: Melting Point: Solubility In Water: Specific Gravity: Viscosity: Bulk Density: Liquid Slight odor; clear pale yellow No data available Approximately 0.000075 @ 20 °C (poiyisocyanate) No data available No data available Approximately 446 °F (230 °C) Not established Not established Insoluble; reacts slowly with water to liberate 002 1.17 68 °F (20 °C) No data available 9.76 lb/gal SECTION V -. REACTIVITY DATA Stability: Stable. Conditions to Avoid: None known. Incompatibilities (materials to avoid): Water, amines, strong bases, alcohols, metal compounds and surface active materials. Hazardous Decomposition Products: By heat and fire: carbon dioxide, carbon monoxide, oxides of nitrpgen, hydrogen cyanide, HDI. Hazardous Polymerization: May occur. Contact with moisture or other materials which react with isocyanates or tem- peratures 400 °F (204C) may cause polymerization. MSDS- S- B- R/06 -91 SECTION VI - HEALTH HAZARD :DATA /TOXICOLOGICAL PROPERTIES Emergency First Aid Procedures: Inhalation: Remove to fresh air. Administer oxygen or artificial respiration as needed. Obtain medical attention. Asthmatic -type symptoms may develop and may be Imme- diate or delayed up to several hours. Treatment is esentially symptomatic. Eyes: Remove contact lens(es), if present, and flush immediately with water for at least 15 minutes, carefully lifting the eyelids to expose the eye to contact with water. Refer individual to physician or ophthalmologist for immediate follow -up. SKIN CONTACT EYE CONTACT Yes Yes ROUTES SKIN ABSORPTION No Skin: Remove contaminated clothing and shoes Immedi- ately. Wash affected area with soap or mild detergent and large amounts of water until no evidence of chemical remains (approximately 15-20 minutes). For severe exposures, get under safety shower after removing clothing, then get medical attention. For lesser exposures, seek medical attention if Irritation develops or persists. Ingestion: Do not induce vomiting. Give 1 to 2 cups milk or water to drink. Do not give anything by mouth to an unconscious or convulsing person. Get medical attention immediately. OF ENTRY INHALATION INGESTION Yes Yes ORAL LD50 (rat): 10,000 mg /kg (Mobay MSDS) Inhalation LC50: Pulmonary irritant. Mobay MSDS reports that LC50 values of 137 -1,150 mg /m3 were obtained in rats exposed (4 hrs) to aerosols. Threshold Limit Value: Not established for product as a whole. Refer to Section II for exposure limits of hazardous constituents. The Mobay Guideline Levels are based on limited data; they are guides pending the review of future data. Carcinogenicity: Not listed as a carcinogen by OSHA, NTP or IARC. Medical Conditions Generally Aggravated: Asthma and other respiratory disorders (bronchitis, emphysema, hyperreac- tivity), skin allergies, eczema. Effects of Acute Exposure to the Product (Mobay MSDS): Inhalation: HDI vapors or mist at concentrations above the TLV or MGL (Mobay Guideline Level) can irritate the mucous membranes in the nose, throat and lungs causing runny nose, sore throat, coughing, chest discomfort, shortness of breath and reduced lung function (breathing obstruction). Persons with a preexisting, nonspecific bronchial hyperreactivity can respond to concentrations below the TLV or MGL with similar symptoms as well as an asthma attack. Exposure well above the TLV or MGL may lead to bronchitis, brochial spasm and pulmonary edema (fluid In lungs). These effects are usually reversible. Chemical or hypersensitive pneumonitis, with flu -like symptoms (e.g., fever, chills) has also been reported. Skin Contact: isocyanates react with skin protein and moisture and can cause irritation. Symptoms of skin irritation may be reddening, swelling, rash, scaling or blistering. Some persons may develop skin sensitization from skin contact. Cured material Is difficult to remove. Eye Contact: Liquid aerosols and vapors of this product are irritation and can cause pain, tearing, reddening and swelling accompanied by a stinging sensation and/or a feeling like that of fine dust in the eyes. Ingestion: Can result in irritation and possible corrosive action in the mouth, stomach tissue and digestive tract. DERMAL LD50 (rabbit): 5,000 mg /kg (Mobay MSDS) Effects of Chronic Exposure to the Product (Mobay MSDS): Inhalation: As a result of previous repeated overexposures or a single large dose, certain individuals will develop isocyanate sensitization (chemical asthma) which will cause them to react to a later exposure to isocyanate at levels well below the TLV or MGL. These symptoms, which Include: chest tightness, wheezing, cough, shortness of breath or asthmatic attack, could be Immediate or delayed up to several hours after exposure. Similar to many non - specific asthmatic responses, there are reports that once sensitized, an individual can experience these symptoms upon exposure to dust, cold air or other irritants. This Increased lung sensitivity can persist for weeks and in severe cases for several years. Chronic overexposure to isocyanates has also been reported to cause lung damage, including decrease in lung function, which may be permanent. Sensitization may be either temporary or permanent. Skin Contact: Prolonged contact with the isocyanate can cause reddening, swelling, rash, scaling or blistering. In those who have developed a skin sensitization, these symptoms can develop as a result of contact with very srnall amounts of liquid material or even as a result of vapor -only exposure. Eye Contact: May result in corneal opacity (clouding of the eye surface). Ingestion: No data available. Notes of Physicians: Eyes: Stain for evidence of corneal Injury. If cornea Is burned, instill antibiotic /steroid preparation frequently. Workplace vapors could produce reversible corneal epithelial edema impairing vision. Skin: This product is a known skin sensitizer. Treat symptomatically as for contact dermatitis or thermal burn. Ingestion: Treat symptomatically. There Is no specific antidote. Inducing vomiting is contraindicated because of the irritating nature of the product. Inhalation: This product Is a known pulmonary sensitizer. Treatment is essentially symptomatic. An individual having a dermal or pulmonary senstization reaction to this material must be removed from any further exposure to any isocyanate. SECTION VII - SPILL OR LEAK PROCEDURES In case material Is released or spilled: Evacuate nonessen- tial personnel. Notify appropriate authorities If necessary. Put on personal protective equipment (see Section VIII). Dike or Impound spilled material and control further spillage If feasible. Cover the spill with sawdust, vermiculite, Fuller's earth or other absorbent material. Pour decontamination solution over spill area and allow to react for at (east 10 minutes. Collect material In open containers and add further amounts of decontamination solution. Remove containers to a safe place, cover loosely, and allow to stand for 24 to 48 hours. Wash down spill area with decontamination solutions. Decontamina- tion solutions: nonionic surfactant Union Carbide's Tergitol TMN -10 (20 %) and water (80 %). • • Waste Disposal Method: Waste must be disposed of In accordance with federal, state and local environmental control regulations. Incineration is the preferred method. Empty containers must be handled with care due to product :SECTION .VIII -SPEC. PROTECTION INFORMATION residue. Decontaminate containers prior to disposal. DO NOT TREAT OR CUT EMPTY CONTAINER WITH ELECTRIC OR GAS TORCH. (See Sections IV and V). Respiratory protection: Precautions must be taken so that persons handling this product do not breathe the vapors. Consider type of application and workplace concentrations when choosing a respirator. Observe OSHA regulations for respirator use (29 CFR 1910.134): Spray Application: Use a positive pressure supplied -air respirator. Non -Spray Operations: Even during non -spray operations, it is possible to be exposed to airborne Isocyanate vapors. A positive pressure supplied -air respirator must be worn when: • the airborne concentrations are unknown; or • the airborne concentrations of HDI exceed the TLV or MGL; or . SECTION IX - SPECIAL PRECAUTIONS Protective gloves: Employees must wear appropriate protective gloves to prevent contact with this substance. The best protection is supplied by the North Silver Shield Glove. Polyvinyl alcohol also provides good protection. Eye protection: Employees must wear safety glasses, splash goggles or face shield to prevent eye contact with this substance. Contact lenses should not be worn. Other protective clothing or equipment: Employees must wear appropriate (Impervious) clothing and equipment to prevent repeated or prolonged skin contact with this substance. Medical Surveillance: Medical supervision of all employees who handle or come In contact with this product is recommended. This should Include preemployment and periodic medical examinations with respiratory function tests (FEV, FVC as a minimum). Persons with asthma -type conditions, chronic bronchitis, other chronic respiratory diseases or recurrent skin eczema or sensitization should be excluded from working with isocyanates. Once a person Is diagnosed as sensitized to an Isocyanate, no further exposure can be permitted. • operations are performed in a confined space or in an area with limited ventilation. If the airborne concentration of HDI Is below the TLV or MGL, a respirator is optional. An air - purifying respirator is not recommended. Ventilation: Exhaust ventilation sufficient to keep the airborne concentrations of HDI and poiyisocyanate below their respective TLVs and MGLs must be used. Exhaust air may need to be cleaned by scrubbers or filters to reduce environmental contamination. Emergency Eye Wash: Where there Is any possibility that an employee's eyes may be exposed to this substance, the employer should provide an eye wash fountain within the immediate work area for emergency use. Special precautions with handling and storage: Store in tightly closed containers to prevent moisture contamination. Do not reseal if contamination Is suspected. At maximum storage temperatures noted, material may slowly polymerize without hazard. Ideal storage temperature range for ease of handling is 50.81 °F (10-27°C), Avoid contact with skin and eyes. Employee education and training in the safe use and handling of this product are required under the OSHA Hazard Communication Standard. Other precautions: Storage temperature (minimax): -30°F ( -34 °C)1122 °F (50°C) Shelf life: 6 months @ 77 °F (25°C) after receipt of material by customer. Special sensitivity: If container is exposed to high heat, it can be pressurized and possibly rupture explosively. HDI reacts slowly with water to form CO2 gas. This gas can cause sealed containers to expand and possibly rupture explosively. Environmental: SARA 313: There are no SARA reportable chemicals in this product. RCRA: This product (if discarded in its purchased form) does not contain listed waste. VOC: No VOCs are released by this product. THIS INFORMATION IS GIVEN IN GOOD FAITH, BUT NO WARRANTY, EXPRESS OR IMPLIED, IS MADE. THE PRODUCT IS NOT CLAIMED TO BE MERCHANTABLE OR FIT FOR ANY PARTICULAR PURPOSE. SUITABILITY IS DETERMINED BY USER. FOR INDUSTRIAL USE AND CERTIFIED APPLICATORS ONLY. Prepared from Importer supplied Information by Schumacher & Associates, Inc., Seattle, WA. No claim of completeness or accuracy Is made. KEMPER SYSTEMS, INC: 550 S Michigan Street Seattle, `WA 98108. 206. 767 -8606 FAX 206.767.8531 800 - 541 -,5455 • Partner tot Piofessioncii Solutions, in Roofing and Waterproofing • PRODUCT/INFORMATION: TRADE NAME: CHEMICAL NAME AND SYNONYMS: CHEMICAL FAMILY: PRODUCT USE: PREPARATION DATE: KEMPEROL FLEECE 200S OR 165S NON -WOVEN POLYESTER FIBER, FLEECE NOT APPLICABLE ROOFING AND WATERPROOFING NOVEMBER 30, 1990 MANUFACTURER Kemper Systems, Inc. 550 South Michigan Street Seattle, Washington 98108 Emergency Phone: (800) 541-5455 Facsimile: (206) 767-9531 ORDER NUMBERS FLEECE 200S: K0012200a 565 SQ FT (52.500 M2) K0012200b 377 SQ FT (35.000 M2) K0012200c 283 SQ FT (26.250 M2) K0012200d 188 SQ FT (17.500 M2) K0012200e 141 SQ FT (13.125 M2) K0012200f 133 SQ FT (10.500 M2) K0012200g 57 SQ FT (5.250 M2) & PACKAGING: FLEECE 165S: K0012401a 565 SQ K0012401b 377 SQ K0012401c 283 SQ K0012401d 188 SQ K0012401e 141 SQ K0012401f 133 SQ K0012401g 57 SQ FT (52.500 M2) FT (35.000 M2) FT (26.250 M2) FT (17.500 M2) FT (13.125 M2) FT (10,500 M2) FT (5.250 M2) SECTION it - HAZARDOUS INGREDIENT NAME INGREDIENTS Polyester Fiber CAS # Not established OSHA PEL Not established ACGIH TLV Not established PERCENTAGE 100 TRANSPORTATION REQUIREMENTS Not regulated by DOT SECTION. IV - FIRE & EXPLOSION DATA Flashpoint (C.O.C. method): Not applicable. Flammable Limits: Not applicable. Autoignition Temperature: Not applicable. Extinguishing Media: Not applicable. Special Fire Fighting Procedures: Not applicable. Unusual Fire & Explosion Hazards: None. Sensitivity to Static Discharge: Not applicable. SECTION III - PHYSICAL, DATA Physical State: Odor & Appearance: Odor Threshold (ppm): Vapor Pressure: Vapor Density (Air = 1): Evaporation Rate: Bolling Point: Freezing Point: Melting Point: Solubility In Water. Specific Gravity: Viscosity: Solid White non-woven textile Not applicable Not applicable Not applicable Not applicable Not applicable Not applicable Not applicable None No data available Not applicable SECTION V - REACTIVITY DATA Stability: Stable. Conditions to Avoid: None. Incompatibles (materials to avoid): None. Hazardous Decomposition Products: Carbon monoxide and carbon dioxide. Hazardous Polymerization: WIII not occur. KEMPER 6 MSDS - F • 200 S / 06 -91 SECTION VI HEALTH' HAZARD DATA/TOXICOLOGICAL PROPERTIES Emergency First Aid Procedures: Inhalation: This material is not likely to cause a first-aid emergency. Eyes: This material is not likely to cause a first-aid emergency. Skin: This material is not likely to cause a first•ald emergency. Ingestion: This material Is not likely to cause a first -aid emergency. ROUTES OF ENTRY SKIN CONTACT SKIN ABSORPTION INHALATION No No No INGESTION No EXPOS. LIMITS Not established IRRITANCY Yes SENSITIZATION No CARCINOGENICITY No TERATOGENICITY No REPRO. TOXIC No MUTAOENICITY No SYNERGISTIC No ORAL LD50(rat): No data available DERMAL LD50: No Threshold Limit Value: None established. Carcinogenicity: This material Is not listed as a carcinogen by OSHA, NTP or IARC. Medical Conditions Generally Aggravated: None. Effects of Acute Exposure to the Product: This material SECTION VII - "SPILL OR 'LEAK *PROCEDURES In case material Is released or spilled: This Is a solid, non- hazardous non-woven fabric. No special procedures are necessary. Waste Disposal Method: May be disposed of as a non- hazardous material. data available INHALATION LC50: No data available has very low toxicity. There are no known acute health effects. Effects of Chronic Overexposure to the Product: This material has very low toxicity. There are no known chronic health effects. `SECTION VIII -SPEC. PROTECTION INFORMATION Respiratory Protection: Not necessary. Ventilation: Not necessary. Local Exhaust: Not necessary. Special: Not necessary. Mechanical: Not necessary. Protective Gloves: Any glove may be used for protection from mechanical irritation. Eye Protection: Not necessary. Other Protective Clothing or Equipment: None. SECTION IX SPECIAL PREC ' UIIONS Special precautions with handling and storing: Always keep dry and away from any contaminants such as water, oil, dirt, etc. Other precautions: Environmental: SARA 313: There are no SARA reportable chemicals in thls product. RCRA: This product does not contaln listed waste. VOC: No VOCs are released by this product. THIS INFORMATION IS GIVEN IN GOOD FAITH, BUT NO WARRANTY, EXPRESS OR IMPLIED, IS MADE. THE PRODUCT IS NOT CLAIMED TO BE MERCHANTABLE OR FIT FOR ANY PARTICULAR PURPOSE. SUITABILITY IS DETERMINED BY USER. FOR INDUSTRIAL USE AND CERTIFIED APPLICATORS ONLY. Prepared from Importer supplied Information by Schumacher & Associates, Inc., Seattle, WA. No claim of completeness or accuracy Is made. ( SECTION 1 7. PRODUCT INFORMATION TRADE NAME: CHEMICAL NAME AND SYNONYMS: CHEMICAL FAMILY: PRODUCT USE: PREPARATION DATE: KEMPEROL FLEECE 200 OR 165 NON -WOVEN POLYESTER FIBER, FLEECE NOT APPLICABLE ROOFING AND WATERPROOFING NOVEMBER 30, 1990 MANUFACTURER Kemper Systems, Inc. 550 South Michigan Street Seattle, Washington 98108 Emergency Phone: (800) 541 -5455 Facsimile: (206) 767.9531 ORDER NUMBERS & PACKAGING: FLEECE 200: K0012100a 565 SQ FT (52.500 M2) K0012100b 377 SQ FT (35.000 M2) K0012100c 283 SQ FT (26.250 M2) K0012100d 188 SQ FT (17.500 M2) K0012100e 141 SQ FT (13.125 M2) K0012100f 113 SQ FT (10.500 M2) K0012100g 57 SQ FT (5.250 M2) FLEECE 165: K0012301a 65 SQ FT (52.500 M2) K0012301b 377 SQ FT (35.000 M2) K0012301c 283 SQ FT (26.250 M2) K0012301d 188 SQ FT (17.500 M2) K0012301e 141 SQ FT (13.125 M2) K0012301f 113 SQ FT (10.500 M2) K0012301g 57 SQ FT (5.250 M2) NAME INGREDIENT Polyester CAS # Not established OSHA PEL Not established ACGIH TLV Not established PERCENTAGE 100 TRANSPORTATION REQUIREMENTS Not regulated by DOT. SECTION IV - FIRE & EXPLOSION DATA • Flashpoint (C.O.C. method): Not applicable Flammable Limits: Not applicable Autolgnition Temperature: Not applicable Extinguishing Media: Water fog, dry chemical, CO2, foam. Special Fire Fighting Procedures: Use standard fire fighting techniques for combustible materials. Fire fighters should use self - contalned breathing apparatus. Unusual Fire & Explosion Hazards: None Sensitivity to Static Discharge: Not applicable. SECTION III - PHYSICAL DATA Physical State: Solid Odor & Appearance: White non -woven textile Odor Threshold (ppm): Not applicable Vapor Pressure: Not applicable Vapor Density (Air =1): Not applicable Evaporation Rate: Not applicable Boiling Point: Not applicable Freezing Point: Not applicable Melting Point: Not applicable Solubility in Water: None Specific Gravity: No data available Viscosity: Not applicable SECTION V - REACTIVITY DATA Stability: Stable. Conditions to Avoid: Heat, sparks, open flames or other sources of ignition. Incompatibles (materials to avoid): None. Hazardous Decomposition Products: Carbon monoxide and carbon dioxide. Hazardous Polymerization: Will not occur. MSDS - F - 200 / 06 -91 SECTION VI - HEALTH HAZARD DATA /TOXICOLOGICAL PROPERTIES Emergency First Aid Procedures: Inhalation: This material is not likely to cause a first -aid emergency. Eyes: This material is not likely to cause a first -aid emergency. Skin: This material is not likely to cause a first -aid emergency. Ingestion: This material is not likely to cause a first -aid emergency. ROUTES OF ENTRY SKIN CONTACT SKIN ABSORPTION INHALATION INGESTION No No No No EXPOS, LIMITS IRRITANCY SENSITIZATION CARCINOGENICITY TERATOGENICITY REPRO. TOXIC. MUTAGENICITY SYNERGISTIC Not established Yes No No No No No No DERMAL LD50 (rat): No data available. DERMAL LD50 (rat): No data available. INHALATION LC50 (rat): No data available. Threshold Limit Value: None established Carcinogenicity: This material is not listed as a carcinogen by OSHA, NTP or IARC. Medical Conditions Generally Aggravated: None. Effects of Acute Exposure to Styrene: This material has SECTION VII - SPILL'OR LEAK PROCEDURES In case material is released or spilled: This is a solid, non- hazardous nonwoven fabric. No special procedures are necessary. Waste Disposal Method: May be disposed of as a non- hazardous material. very low toxicity. There are no known acute health effects. Effects of Chronic Overexposure to the Product: This material has very low toxicity. There are no known chronic health effects. SECTION :VIII -SPEC. PROTECTION .INFORMATION. Respiratory Protection: Not necessary. Ventilation: Not necessary. Protective Gloves: Any glove may be used for protection from mechanical irritation. Eye Protection: Not necessary. Other Protective Clothing or Equipment: None. SECTION IX - SPECIAL PRECAUTIONS Special precautions with handling and storing: Always keep dry and away from any contaminants such as water, oil, dirt, etc. Other precautions: Nona. Environmental: SARA 313: There are no SARA reportable chemicals In this product. RCRA: This product does not contain listed waste. VOC: No VOCs are released by this product. THIS INFORMATION IS GIVEN IN GOOD FAITH, BUT NO WARRANTY, EXPRESS OR IMPLIED, IS MADE. THE PRODUCT IS NOT CLAIMED TO BE MERCHANTABLE OR FIT FOR ANY PARTICULAR PURPOSE. SUITABILITY IS DETERMINED BY USER. FOR INDUSTRIAL USE AND CERTIFIED APPLICATORS ONLY. Prepared from Importer supplied information by Schumacher & Associates, Inc., Seattle, WA, No claim of completeness or accuracy Is made. KEMPER SYSTEMS, INC. 550 S Michigan Street Seattle, WA 98108 206. 767 -9505 FAX: 206 - 767-9531 800 - 541 -5455 KEMPER 5 Partner for Professional Solutions in Roofing tend Waterproofing. ('. SECTION 1 PRODUCT INFORMATION 9 TRADE NAME: KEMPEROL SEALER CHEMICAL NAME AND SYNONYMS: DIISOCYANATE (HD1° BASED POLYURETHANE Meets OSHA & WHMIS PRODUCT USE: ROOFING AND WATERPROOFING PREPARATION DATE: DECEMBER 20, 1990 MANUFACTURER Kemper Systems, Inc. 550 South Michigan Street Seattle, Washington 98108 Emergency Phone: (800) 541-5455 Facsimile: (206) 767 -9531 ORDER NUMBERS & PACKAGING: K0013120X 2.72 US GAL (10 kgs) K0013121X 1.36 US GAL ( 5 kgs) SECTION. I1 - HAZARDOUS INGREDIENTS. INGREDIENT % CAS # PEL TLV 1,6- Hexamethylene dlisocyanato (HDI) 0.7 822.06.0 Not established 0.0005 ppm Aliphatic polyisocyanate dilsocyanate 53 Not assigned Not established Not established Aromatic 100 40 64742.95.6 No PEL or TLV but Exxon recommends a 50 ppm TWA 1•Methoxy2•Propanol acetate 6 108.65.6 No PEL or TLV but Mobay recommends a 100 ppm STEL TRANSPORTATION REQUIREMENTS: DOT IDENTIFICATION NUMBER: NA1993 HAZARD CLASS: Combustible liquid LABEL: Combustible SHIPPING NAME: Combustible liquid, n.o.s. SECTION IV - FIRE & EXPLOSION DATA Flashpoint (C.O.D. method): v 120 °F Flammable Limits: LEL: 0.6% UEL: 7.5% Autolgnitlon Temperature: Not available Extinguishing Media: Dry chemical, carbon dioxide, water spray or standard foam. For larger fires, use water spray, fog or standard foam. Special Fire Fighting Procedures: Full emergency equipment with self-contained breathing apparatus and full protective clothing should be worn by firefighters. During a fire, HDI vapors and other irritating, highly toxic gases may be generated by thermal decomposition or combustion. (See Section V.) Isolate from heat, electrical equipment, sparks and open flame. Closed container may explode when exposed to extreme heat or burst when contaminated with water (CO2 evolved). Solvent vapors may be heavier than air. Stagnant air may cause vapors to accumulate and travel along the ground to an Ignition source which may result in a flash back to the source of the vapors. Unusual Fire & Explosion Hazards: None known. Sensitivity to Static Discharge: Sparks from static electricity can ignite this material. Grounding Is recommended. MSDS - S - / 06 -91 SECTION ill.- PHYSICAL DATA" Physical State: Odor & Appearance: Odor Threshold (ppm): Vapor Pressure: Vapor Density (Air =1): Evaporation Rate: Bolling Point: Freezing Point: Melting Point: Solubility In Water. Specific Gravity: Viscosity: % Volatile: Liquid Solvent odor; clear yellow No data available Aromatic 100: 6 mm Hg ® 20 °C; Acetate: 3.8 mm Hg @ 25°C 8.5 No data available No data available No data available No data available Not soluble; reacts slowly to liberate CO2 1.05 No data available No data available SECTION V - REACTIVITY DATA Stability: Stable under normal conditions. Conditions to Avoid: May burn, but does not ignite readily. Avoid contact with strong oxidizers, excessive heat, sparks, or open flame. Incompatibilities (materials to avoid): Strong bases, alcohols, surface active materials, amines, and water. This material will corrode copper or aluminum. Hazardous Decomposition Products: Thermal decomposition products may Include very toxic fumes of hydrogen cyanide and toxic oxides of carbon and nitrogen. Hazardous Polymerization: Polymerization may occur slowly, however, it is not hazardous. •SECTION•VI- HEALTH. HAZARD DATA /TOXICOLOGICAL PROPERTIES Emergency First Aid Procedures: Inhalation: Remove from exposure area to fresh air immediately. If breathing has stopped, perform artificial respiration. Keep person warm and at rest. Treat sympto- matically and supportively. Get medical attention immedi- ately. Eyes: Remove contact lens(es), if present, and flush immediately with water for at least 15 minutes, carefully lifting the eyelids to expose the eye to contact with water. Get medical attention immediately. Skin: Remove contaminated clothing and shoes immedi- ately. Wash affected area with soap or mild detergent and large amounts of water until no evidence of chemical remains (approximately 15-20 minutes). Get medical attention Immediately. Ingestion: Treat symptomatically and supportively. Get medical attention immediately. If vomiting occurs, keep head lower than hips to prevent aspiration. NOTE TO PHYSICIAN: Eyes: Stain for evidence of corneal injury. If cornea is burned, Instill antibiotic steroid prepara- tion frequently. Workplace vapors have produced reversi- ble corneal epithelial edema impairing vision. Skin: This compound is a known skin sensitizer. Treat symptomat- ically as for contact dermatitis or thermal burns. If burned, treat as thermal burn. Ingestion: Treat symptomatically. There is no specific antidote. Inducing vomiting is contra- indicated because of the irritating nature of this compound. Respiratory: This compound is a known pulmonary sensitizer. Treatment is essentially sympto- matic. An individual having a skin or pulmonary sensitiza- tion reaction to this material should be removed from future exposure to any isocyanate. TOXOLOGICAL INFORMATION ROUTES OF ENTRY /OTHER DATA 1,8•Hexamethyleno Aliphatic 1•Methoxy2•Propanol dllsocyanate (HDI) dllsocyanate acetate SKIN CONTACT Yes Yes Yes Aromatic 100 Yes SKIN ABSORPTION INHALATION INGESTION ORAL LD50 (rat) DERMAL LD50 (rabbit) INHALATION LC50 THRESHOLD LIMIT No Yes Yes 735 m9 /kg 593 mg /kg 30 mg /m' (mouse) 0.005 ppm No Yes Yes No data available No data available No data available Not established Yes Yes Yes 8,532 mg/kg v5,000 mg/kg/(Dow MSDS) 4,345 ppm /8 hour (rat) 100 ppm TWA (Mobay) Yes Yes Yes v5,000 mg /kg v3,180 mg /kg No data available 50 ppm TWA (Exxon) Carcinogenicity: Not listed as a carcinogen by OSHA, NTP or IARC. Medical Conditions Generally Aggravated: Respiratory, liver, kidneys, and nervous system. Effects of Acute Exposure to Chemicals in the Product: HDI: Irritant /Sensitizer/Toxic. 10 ppm immediately dangerous to life or health. Acute exposure may cause Irritation of the nose and throat. Depending on the length and concentrations of exposure (above 0.5 ppm), respiratory symptoms may develop with a latent period of four to eight hours. Symptoms may Include coughing and dyspnea, especially prominent in the evenings, with progression of asthmatic bronchitis and wheezing. Other symptoms may Include headache, nausea, vomiting, chest pain, pulmonary secretions, pulmonary edema and possible death. A human exposed to 130 ppb for 30 minutes experienced an Increase in Immune response and body temperature. Aliphatic polyisocyanate dllsocyanate: No data available. Due to the low degree of volatility, no significant health hazard from inhalation is likely to occur at normal room temperatures. Inhalation of generated mist or vapors produced from elevated temperatures may cause irritation of the mucous membranes. Aromatic 100: Vapor concentrations v 1,000 ppm may cause irritation of the respiratory tract. Headache, dizziness, and anesthesia and other signs of central nervous system depression may also occur. 1- Methoxy -2- Propanol acetate: May cause irritation of the nose and throat3- Methoxypropyi acetate: May cause irritation of the nose and throat, central nervous system depression with headache, nausea, lightheadedness, drowsiness, Incoordination, and possibly unconsciousness may occur at very high concentrations. Effects of Chronic Overexposure to Chemicals In the Product: HDI: After months of exposure, allergic sensitization of the respiratory tract may occur. Symptoms, which include nocturnal dyspnea, noctural cough and asthmatic bronchitis, become progressively more pronounced with continued exposure. Aliphatic polylsocyanate dllsocyanate: There is no health effects data for these substances. Effects could be similar to HDI, above. Aromatic 100: No data available. 1- Methoxy -2- Propanol acetate: Repeated, excessive exposure may cause upper respiratory tract irritation and liver and kidney effects. OHS reports that rats exposed to 3,000 ppm of 1- Methoxy -2- Propanol acetate experienced mild transient ataxia, lethargy, central nervous system depression, slight to moderate chromodacryorrhea, hypothermia, Increased liver weights In males, and slight fetotoxicity. SECTION VII - SPILL OR LEAK PROCEDURES In case material Is released or spilled: Extinguish open flames. Cut off electrical power to area. Evacuate and ventilate spill area; dike spill to prevent entry Into water system; wear full protective equipment including respir- atory equipment during cleanup. (See Section VIII) Major spill: If temporary control of Isocyanate vapor is required, a blanket of protein foam (available at most fire departments) may be placed over the spill. Large quantities may be pumped Into closed, but not sealed, container for disposal. Minor spIII: Absorb isocyanates with sawdust or other absorbent, shovel into suitable unsealed containers, transport to well - ventilated area (outside) and treat with neutralizing solution: mixture of water (80 %) with non-ionic surfactant Tergitol TMN -10 (20 %). Add about 10 parts of neutralizer per part of Isocyanate, with mixing. Allow to stand uncovered for 48 hours to let 002 escape. Clean -up: Decontaminate floor with decontamination solution, letting stand for at least 15 minutes. • SECTION VIII - SPEC: PROTECTION INFORMATION Respiratory Protection: The following respirator is recommended by the US Department of Health and Human Services, NIOSH Pocket Guide to Chemical Hazards; NIOSH Criteria Documents or by the US Department of Labor, 29 CFR1910 Subpart Z: any self - contained breathing apparatus with full facepiece and operated in a pressure demand or other positive pressure mode. The specific respirator selected must be based on contamination levels found in the workplace, must not exceed the working.1imits of the respirator, and be jointly approved by the National Institute for Occupational Safety and Health and the Mine Safety and Health Administration (NIOSH - MSHA). Ventilation: Provide local exhaust or process enclosure ventilation to meet published exposure limits. Protective Gloves: Employee must wear appropriate protective gloves to prevent contact with this substance. The best protection is supplied by the North Silver Shield Glove. Polyvinyl alcohol may also provide good protection. SECTION iX SPECIAL PRECAUTIO S Special precautions with handling and storage: Store in tightly closed containers to prevent moisture contamination. Do not reseal if contamination is suspect- ed. Avoid contact with skin and eyes. Do not breathe aerosols or vapors. Other Precautions: Warning properties (irritation of the eyes, nose and throat or odor) are not adequate to prevent chronic overexposure from inhalation. This material can produce asthmatic sensitization upon either a single inhalation exposure to a relatively high concentration, or upon repeated Inhalation exposures to lower concentra- tions. Exposure to vapors of heated HDI can be extremely dangerous. Employee education and training in the safe use and handling of this compound are required under the OSHA Hazard Communication Standard. Eye Protection: Employee must wear liquid chemical goggles to prevent eye contact with this substance. Emergency Eye Wash: Where there Is any possibility that an employee's eyes may be exposed to this substance, the employer should provide an eye wash fountain within the immediate work area for emergency use. Other Protective Clothing or Equipment: Employee must wear appropriate protective (impervious) clothing and equipment to prevent repeated or prolonged skin contact with this substance. Medical Surveillance: Medical supervision of all employees who handle or come in contact with this product is recommended. This should Include preemployment and periodic medical examinations with respiratory function tests (FEV, FVC as a minimum). Persons with asthma -type conditions, chronic bronchitis, other chronic respiratory diseases or recurrent skin eczema or sensitization should be excluded from working with isocyanates. Once a person is diagnosed as sensitized to an lsocyanate, no further exposure can be permitted. Environmental: SARA: There are no SARA reportable chemicals in thls product. RCRA: Using the characteristic of ignitabllity and based on flashpolnt, this material would be designated as dangerous waste number D001. VOC: VOCs are 4.1 lb/gallon. Waste Disposal Method: Cure excess sealer until solid, then dispose of as ordinary waste. Always mix In proper proportions. THIS INFORMATION IS GIVEN IN GOOD FAITH, BUT NO WARRANTY, EXPRESS OR IMPLIED, IS MADE. THE PRODUCT IS NOT CLAIMED TO BE MERCHANTABLE OR FIT FOR ANY PARTICULAR PURPOSE. SUITABILITY iS DETERMINED BY USER. FOR INDUSTRIAL USE AND CERTIFIED APPLICATORS ONLY. Prepared from Importer supplied Information by Schumacher & Associates, Inc., Seattle, WA. No claim of completeness or accuracy Is made. KEMPER SYSTEMS, INC. 550 S Michigan Street Seattle, WA 98108 . 206- 767.9505 FAX 206, =787 -9531 800.541 -5455' Autoignition Temperature: Not applicable. Extinguishing Media: This material is not combustible. Special Fire Fighting Procedures: None necessary. Unusual Fire & Explosion Hazards: None. Sensitivity to Static Discharge: None. SECTION III - PHYSICAL DATA Physical State: Odor & Appearance: Odor Threshold (ppm): Vapor Pressure (mm /Hg): Vapor Density (Air =1): Evaporation Rate: Boiling Point: Freezing Point: Melting Point: Solubility In Water. Specific Gravity: Viscosity: Granular solid Grayish white powder Not applicable Not applicable Not applicable Not applicable Not applicable Not applicable 1,652-1,832°F Insoluble 2.5 Not applicable SECTION V - REACTIVITY DATA Stability: Stable. Conditions to Avoid: None are known. Incompatibles (materials to avoid): None are known. Hazardous Decomposition Products: None. Hazardous Polymerization: Will not occur. MSDS - TP / 06-91 SECTION VI - HEALTH HAZARD DATA /TOXICOLOGiCAL.PROPERTIES Emergency First Aid Procedures: Inhalation: Remove to fresh air. Seek medical attention If Irritation persists. Eyes: Remove contact lens(es), if present, and flush Immediately with water for at least 15 minutes, carefully lifting the eyelids to expose the eye to contact with ROUTES OF ENTRY - TALCUM MAGNESIUM SILICATES water. Get medical attention if irritation persists. Skin: Wash with soap and water. Ingestion: Get medical attention immediately. Do not Induce vomiting. If vomiting occurs, keep head below hips to prevent lung aspiration. SKIN CONTACT Yes SKIN ABSORPTION INHALATION INGESTION No Yes Yes EXPOS. LIMITS IRRITANCY Not established Yes SENSITIZATION CARCINOGENICITY TERATOOENICITY No No No Info avail. ORAL LD50 (rat): No data available DERMAL LD50 (rat): No data available Threshold Limit Value: 2 mg /m' Carcinogenicity: Not listed as a carcinogen by OSHA, NTP or IARC. Medical Conditions Generally Aggravated: Pre - existing respiratory conditions such as bronchitis, asthma or emphysema. Effects of Acute Exposure: Exposure to a large concentration of this material may cause mechanical SECTION VII = SPILL •ORLEAK PROCEDURES In case material is released or spilled: No special precautions are necessary. Waste Disposal Method: May be disposed of as non- hazardous waste. SARA 313: There are no SARA reportable chemicals In this product. RCRA: This product does not contain listed waste. VOC: No VOCs are released by this product. REPRO TOXIC. MUTAGENICITY SYNERGISTIC No No No Info avail. INHALATION LC50 (rat): No data available Irritation of the mucous membranes and respiratory tract. Effects of Chronic Overexposure: Repeated or prolonged inhalation of dust may cause scarring of the lungs (pulmonary fibrosis), with shortness of breath, chronic cough, and heart failure. Recent studies have suggest- ed that asbestos -free material can produce a sympto- matic pheumoconiosis. SECTION VIII -SPEC. PROTECTION INFORMATION; Respiratory Protection: A half -mask respirator with dust /mist cartridge should be adequate in most situations. Ventilation: Not necessary in outdoor application. Protective Gloves: Leather or rubber. Eye Protection: Safety glasses with sideshields are recommended. Other Protective Clothing or Equipment: Not normally necessary. Evaluation by an industrial hygienist or safety professional may be needed In unusual cases. SECTION IX - SPECIAL PRECAUTIONS Special Precautions with Handling and Storing: None. Other Precautions: None. THIS INFORMATION IS GIVEN IN GOOD FAITH, BUT NO. WARRANTY, EXPRESS OR IMPLIED, IS MADE. THE PRODUCT IS NOT CLAIMED TO BE MERCHANTABLE OR FIT FOR ANY PARTICULAR PURPOSE. SUITABILITY IS DETERMINED BY USER. FOR INDUSTRIAL USE AND CERTIFIED APPLICATORS ONLY. Prepared from Importer supplied information by Schumacher & Associates, Inc., Seattle, WA. No claim of completeness or accuracy Is made. KEMPER SYSTEMS, INC. 550 S Michigan Street Seattle, WA 98108 206-767-9505 FAX: 206 - 767 -9531 800 - 541 -5455 SECTION 1. PRODUCT INFORMATION TRADE NAME: KEMPEROL CATALYST POWDER CHEMICAL NAME AND SYNONYMS: PEROXIDE CATALYST SPECIAL RISK CATEGORY APPLIES - SEE PAGE 3.24 OF WHMIS MANUAL CHEMICAL FAMILY: ORGANIC PEROXIDE /DIACYL PEROXIDE PRODUCT USE: CATALYZER OF POLYESTER RESIN PREPARATION DATE: NOVEMBER 15, 1990 MANUFACTURER Kemper Systems, Inc. 550 South Michigan Street Seattle, Washington 98108 Emergency Phone: (800) 541 -5455 Facsimile: (206) 767 -9531 ORDER NUMBERS & PACKAGING: A0053170X 1600 gram plastic container A0053171X 600 gram plastic container A0053172X 148 gram plastic container premeasured for black formulations of: Kemperol V -210, Kemperol PHC -AN, Kemperol S -210, Kemperol PHC -SAN, Kemperol BR SECTION II _ INGREDIENT HAZARDOUS INGREDIENTS Dlbenzoyl Peroxide Phthalate CAS # 94 -36 -0 84 -61 -7 OSHA PEL 5 mg/M3 Not established ACGHIH TLV 5 mg /M3 Not established PERCENTAGE 50 50 TRANSPORTATION DOT ID #: UN 2138g.3 / 0G REQUIREMENTS Hazard Class: Organic peroxide Label: Organic peroxide Ship. Name: Benzoyl Peroxide SECTION IV - FIRE & EXPLOSION DATA Flashpoint (C.O.C. method): Not applicable. Flammable Limits: Not applicable. Autoignition Temperature: Unknown Extinguishing Media: Water fog, dry chemical, CO2, foam. Special Fire Fighting Procedures: Evacuate area and apply water from safe distance. Spray water on peroxide containers to prevent overheating. Unusual Fire & Explosion Hazards: Peroxides and decomposition products are flammable and can ignite with explosive force if combined. Sensitivity to Static Discharge: No data available. MSDS 1 SECTION III - PHYSICAL DATA Physical State: Odor & Appearance: Odor Threshold (ppm): Vapor Pressure: Vapor Density (Air =1): Evaporation Rate: Boiling Point: Melting Point: Solubility In Water. Specific Gravity: Viscosity: Granular White granules with slight odor No data available Not applicable Not applicable Not applicable Not applicable Not applicable Insoluble No data available Not applicable SECTION V - REACTIVITY DATA Stability: Unstable: this may be caused by thermal decomposition or contamination. Conditions to Avoid: Ignition sources or temperatures above 104 °F. Incompatibles (materials to avoid): Strong acids, strong alkalis, strong oxidizers, reducing agents and accelerators. Hazardous Decomposition Products: On decomposition, Kemperol Catalyst Powder can produce flammable and toxic vapors. Biphenyl may be released. Hazardous Polymerization: Will not occur without contact with an appropriate resin material. - C- P/06 -91 SECTION VI HEALTH HAZARD DATA /TOXICOLOGICAL PROPERTIES Emergency First Aid Procedures: Inhalation: Remove to fresh air. If not breathing, give mouth to mouth resuscitation; if breathing is difficult, give oxygen. Call physician Immediately. Eyes: Remove contact lens(es), if present, and flush immediately with water for at least 15 minutes, carefully lifting the eyelids to expose the eye to contact with water. Get medical attention if irritation persists. Skin: Immediately flush skin with soap and water for at least 15 minutes; remove contaminated shoes and clothing and launder before reuse; if irritation persists, call physician. Ingestion: DO NOT Induce vomiting; give plenty of water. Call physician and/or transport to emergency medical facility immediately. ROUTES OF ENTRY /OTHER DATA BENZOYL PEROXIDE DICYCLOHEXYL PHTHALATE SKIN CONTACT Yes No SKIN ABSORPTION Unknown No INHALATION Yes Unlikely INGESTION Yes Yes ORAL LD50 (rat) 6400 mg/kg 30 grams /kg INHALATION LC50 (rat) 24.3 mg /L No data available DERMAL LD50 (rat) Not a primary skin irritant or corrosive hazard to skin (based on rabbit tests with 8% wet BPO). No data available THRESHOLD LIMIT VALUE 5 mg /m' Not established CARCINOGENICITY Benzoyl peroxide has not been shown to be a carcinogen. There Is some evidence of promoter activity on mouse skin. Not listed as a carcinogen by OSHA, NTP or IARC. MEDICAL CONDITIONS GENERALLY AGGRAVATED Respiratory disorders may be aggravated. None reported. EXPOS. LIMITS IRRITANCY Dlb. Per: 5mglm' Yes SENSITIZATION CARCINOGENICITY Yes No Effects of Acute Exposure to the Product: Benzoyl Peroxide: Workers exposed to 12 mg /M3 experienced pronounced irritation of the nose and throat. Inhalation may also cause cough, dyspnea, decreased pulse rate, hypothermia, and stupor. In rats, 24,300 mg /M3 of 78% benzoyl peroxide for four hours caused eye squint, , SECTION VII.- - 'ILL: OR LEAK PROCEDURES In case material Is released or spilled: Dispose of as solid waste In closed containers either at an approved landfill or incinerate at an approved facility. Obey federal, state, county or any other regulations. Waste Disposal Method: Cured resin (catalyzed) may be disposed of at proper landfill and/or Incinerated. Obey all pertaining regulations. If excess catalyst requires disposal, combine with resin to produce a solid, non-hazardous material. If you need to dispose of Kemperol Catalyst Powder, It must be handled as a hazardous waste. Environmental: SARA 313: Dibenzoyl peroxide is reportable. RCRA: This product does not contain listed waste. VOC: No VOCs are released by this product. TERATOGENICITY REPRO. TOXIC. MUTAOENICITY SYNERGISTIC No No Dlb. Per. • Yes No difficult breathing, salivation, and an Increase followed by a decrease in motor activity. Dicyclohexyl Phthalate: may cause some irritation of the respiratory system. Effect of Chronic Overexposure: No data available. SECTION VIII.- SPEC. PROTECTION INFORMATION Respiratory Protection: Use a cartridge-type respirator with organic vapor cartridges. A dust /mist prefilter is advised for spraying application. Use an air-supplied respirator for confined spaces. Ventilation: Recommended sufficient to control airborne concentrations to below 5 mg /m3. Natural ventilation may be sufficient on unobstructed rooftop. If poor air movement or close work required, local exhaust may be necessary. Protective Gloves: Gauntlet type; neoprene. Eye Protection: Face shield, safety glasses, or chemical goggles. SECTION iX SPECIAL PRECAUTIONS Special precautions with handling and storing: Always store dry and cool. Avoid prolonged storage above 80 °F (27 °C). Open containers slowly and carefully to relieve any internal pressure. For more safety data, see Akzo's product data sheets and Bulletin 85-6 "Organic Peroxides Safety and Handling," and NFPA Bulletin 43B, "Storage of Organic Peroxide Formulations." Store in original containers. Select storage areas in accordance with local laws and regulations. Other precautions: Practice care, precaution and common sense. No smoking, open flames and no consumption of food while handling material. Avoid prolonged contact with skin, avoid contact and wash skin after any inadvertent contact. Other protective clothing or equipment: Solvent•resistant shoes, boots, aprons - frequently cleaned to avoid skin contact. Safety showers and eyewash equipment should be on•slte. THIS INFORMATION IS GIVEN IN GOOD FAITH, BUT NO WARRANTY, EXPRESS OR IMPLIED, IS MADE. THE PRODUCT IS NOT CLAIMED TO BE MERCHANTABLE OR FIT FOR ANY PARTICULAR PURPOSE, SUITABILITY IS DETERMINED BY USER. FOR INDUSTRIAL USE AND CERTIFIED APPLICATORS ONLY. Prepared from Importer supplied Information by Schumacher & Associates, Inc., Seattle, WA. No claim of completeness or accuracy is made. KEMPER•1 l Rainer for Professional Solutions:in Roofing and Waterproofing. . • 'SECTION 1 -. PRODUCT INFORMATION TRADE NAME: CHEMICAL NAME AND SYNONYMS: PRODUCT USE: PREPARATION DATE: KEMPEROL C3 INHIBITOR 4- TERT - BUTYLCATECHOL IN DIPHENYL - TOLUYL PHOSPHATES (PLASTICIZERS) POLYMERIZATION INHIBITOR DECEMBER 1, 1990 MANUFACTURER Kemper Systems, Inc. 550 South Michigan Street Seattle, Washington 98108 Emergency Phone: (800) 541 -5455 Facsimile: (206) 767 -9531 ORDER NUMBERS & PACKAGING: K0013250X 600 grams /can K0013251X 240 grams /can SECTION II - HAZARDOUS INGREDIENTS INGREDIENT: Tert- butylcatechol Dplalphensticiyzel•tolrs) uyl•phosphate ( CAS # 98.29.3 Not available OSHA PEL Not established Not established ACGIH TLV Not established Not established PERCENTAGE 3 ±3 92 ±3 TRANSPORTATION REQUIREMENTS UN NUMBER: Not regula ed by DOT. SECTION IV - FIRE & EXPLOSION DATA.. Flashpoint (C.O.C. method): 446 °F Flammable Limits: No data available Autolgnitlon Temperature: 932 °F Extinguishing Media: Water fog, dry chemical, CO2, foam. Special Fire Fighting Procedures: Fight as fuel oil fire, wear self - contained breathing apparatus. Cool containers with water. Unusual Fire & Explosion Hazards: None are known. Sensitivity to Static Discharge: Presents no hazard. SECTION 111 - PHYSICAL DATA Physical State: Odor & Appearance: Odor Threshold (ppm): Vapor Pressure: Vapor Density (Air =1): Evaporation Rate: Boiling Point: Melting Point: Solubility in Water. Specific Gravity: Viscosity: Liquid Yellowish liquid with little odor No data available No data available No data available No data available 385 °C1725 °F 127-136°F Insoluble 1.2 No data available SECTION V - REACTIVITY DATA Stability: Stable. Conditions to Avoid: Contact with water. Incompatibilities (materials to avoid): Organic peroxides. Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, phosphoric acid and smoke. Hazardous Polymerization: Will not occur. SECTION 1/I - HEALTH HAZARD DATA /TOXICOLOGICAL PROPERTIES Emergency First Aid Procedures: Inhalation: Remove to fresh air. If not breathing, give mouth to mouth resuscitation; if breathing Is difficult, give oxygen; call physician Immediately. Eyes: Remove contact lens(es), If present, and flush immediately with water for at least 15 minutes, carefully lifting the eyelids to expose the eye to contact with water. Get medical attention if irritation persists. Skin: Wash thoroughly with soap and water. Obtain medical assistance if irritation persists. Ingestion: Do not induce vomiting. Seek immediate medical attention. Effects of Acute Exposure: There Is no information available. However, it is prudent to assume that all chemicals may be hazardous and should be handled with care. Effects of Chronic Overexposure: There are no known chronic effects. MSDS - C - 3 -1/ 06-91 TOXICOLOGICAL INFORMATION No toxicological information Is available for diphenyl•toluyl•phosphate. ROUTES OF ENTRY /OTHER DATA - Tert•butylcatechol SKIN CONTACT SKIN ABSORPTION INHALATION INGESTION Yes No Unlikely Yes ORAL LD50 (rat): 2820 mg /kg DERMAL LD50 (rabbit): 630 mg /kg INHALATION LC50: No data avail. SECTION VII SPILL OR LEAK. PROCEDURES In case material Is released or spilled: Dike to prevent run-off Into waterways and sewers, cover spill with absorbent media (Le., peat, vermiculite, etc.), sweep up remaining contamination. Clean up with nonflammable solvent, dispose of cured media as solid waste in closed containers either at an approved landfill or Incinerate at an approved facility. Obey federal, state, county or any other regulations. Waste Disposal Method: This material must be disposed of as a hazardous waste. SECTION IX SPECIAL PRECAUTIONS Special precautions with handling and storage: Storage: Always store dry and cool. Avoid prolonged storage above 80 °F (27 °C). Keep away from sunlight. Store and handle as NFPA Class 1•C. Open containers slowly and carefully to relieve any Internal pressure, ground all connections, use non - sparking exploslon•proof equipment. Keep away from organic peroxides. Handling: Avoid direct contact with organic peroxides. SECTION VIII' -SPEC. PROTECTION INFORMATION Respiratory Protection: Respiratory protection would not usually be required. If respiratory protection is required, use an air - purifying respirator with a dust/mist cartridge. Ventilation: Natural ventilation may be sufficient on unobstructed roof top. If poor air movement or close work required, local exhaust may be required. Protective Gloves: Neoprene gloves are recommended. Eye Protection: Safety glasses with side shields. Other Protective Clothing or Equipment: Protective clothing and rubber boots. Other precautions: None. Environmental: SARA 313: There are no SARA reportable chemicals in this product. RCRA: This product does not contain any listed hazardous waste. VOC: No VOCs are released by this product. THIS INFORMATION IS GIVEN IN GOOD FAITH, BUT NO WARRANTY, EXPRESS OR IMPLIED, IS MADE. THE PRODUCT IS NOT CLAIMED TO BE MERCHANTABLE OR FIT FOR ANY PARTICULAR PURPOSE, SUITABILITY IS DETERMINED BY USER. FOR INDUSTRIAL USE AND CERTIFIED APPLICATORS ONLY. Prepared from Importer supplied Information by Schumacher & Associates, Inc., Seattle, WA. No claim of completeness or accuracy Is made. C> % KEMPER SYSTEMS, )NC. 550 S Michigan Street Seattle, WA 98108 2087767 .-9505 FAX: 206- 767 -9531 800 =541 -5455 KEMPER 15 SECTION :1 - PRODUCT INFORMATION .. TRADE NAME: KEMPEROL COLD ACTIVATOR CHEMICAL NAME AND SYNONYMS: N,N- DIMETHYL -P- TOLUDINES IN DIPHENYL- TOLUYL- PHOSPHATES (PLASTICIZERS) CHEMICAL FAMILY: PLASTICIZER PRODUCT USE: USED TO ASSURE PROPER CURING OF POLYESTER RESINS IN COLD TEMPERATURES PREPARATION DATE: NOVEMBER 15, 1990 MANUFACTURER Kemper Systems, Inc. 550 South Michigan Street Seattle, Washington 98108 Emergency Phone: (800) 541 -5455 Facsimile: (206) 767-9531 ORDER NUMBERS & PACKAGING: K0013260X 500 grams K0013261X 200 grams SECTION II - HAZARDOUS INGREDIENTS INGREDIENT N,N- dimethyl -p- toluidine (DMT) Diphenyl- cresyl phosphate CAS # 99-97-8 Not available OSHA PEL Not Established Not Established ACGIH TLV Not Established Not Established PERCENTAGE 20 80 TRANSPORTATION REQUIREMENTS DOT ID NUMBER: UN 1760 HAZ. CLASS: Corrosive Iiq., n.o.s. LABEL: Corrosive SHIP. NAME: Corrosive ilq., n.o.s. SECTION IV - FIRE & EXPLOSION DATA Flashpolnt (C.O.C. method): No data available. Flammable Limits: No data available. Autoignition Temperature: No data available. Extinguishing Media: Water fog, dry chemical, CO2, foam. Special Fire Fighting Procedures: Fight as fuel oil fire, wear self-contained breathing apparatus. Cool containers with water. Unusual Fire & Explosion Hazards: if exposed to elevated temperatures for extended length of time, spon- taneous exothermic polymerization may occur yielding violent rupture of packaging container. Sensitivity to Static Discharge: No data available. SECTION I11 - PHYSICAL DATA Physical State: Odor & Appearance: Odor Threshold (ppm): Vapor Pressure: Vapor Density (Air =1): Evaporation Rate: Boiling Point: Freezing Point: Melting Point: Solubility In Water. Specific Gravity: Viscosity: Liquid Yellow brown liquid, smells like aniline No data available 0.01 mbar No data available No data available 215 °C1419 °F No data available No data available 0.1 gIL 1.1 to 1.2 g /mL No data available SECTION V - REACTIVITY DATA Stability: Stable, except as noted under conditions to avoid a hazardous polymerization. Conditions to Avoid: Sunlight, excessive heat, open flames, contamination with oxidizing agents, prolonged storage v 86°F (30°C) Incompatibilities (materials to avoid): Peroxides and other oxidizing agents, promoters. Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, low molecular weight hydrocarbons, organic acids. Hazardous Polymerization: May occur If exposed to heat v100 °F /38 °C for prolonged time, open flame, contamina- tion with oxidizer, Improper addition of catalysts and/or promoters. MSDS - C - A / 06.91 SECTION. VI - .HEALTH HAZARD DATA /TOXICOLOGICAL PROPERTIES' Emergency First Aid Procedures: Inhalation: Remove to fresh air. If not breathing, give mouth to mouth resuscitation; if breathing is difficult, give oxygen and call physician. Eyes: Remove contact lens(es), if present, and flush immediately with water for at least 15 minutes, carefully lifting the eyelids to expose the eye to contact with water. Get medical attention immediately. TOXOLOGICAL INFORMATION N,N•Dimethyl- P- Toluldine Yes Yes Yes Yes (Mouse) 212 mglkg No data available No data available Not established This substance Is not listed as a carcinogen by OSHA, NTP or IARC MEDICAL CONDITIONS GENERALLY Central nervous system, kidney, liver disorder history ROUTES OF ENTRY /OTHER DATA SKIN CONTACT SKIN ABSORPTION INHALATION INGESTION ORAL LD50 DERMAL LD50 INHALATION LC50 THRESHOLD LIMIT VALUE CARCINOGENICITY Skin: Immediately flush skin with ample water for at least 15 minutes; remove and discard contaminated clothing � ) and shoes; if irritation persists, call physician. Ingestion: DO NOT induce vomiting. Call physician and/or transport to emergency medical facility immediately. AGGRAVATED Diphenyl cresyl phosphate No data available No data available No data available No data available No data available No data available No data available Not established This substance Is not listed as a carcinogen by OSHA, NTP or IARC No data available Effects of Acute Exposure to Chemicals in the Product: DMT: No specific information was available for acute exposure to this chemical. However, amine compounds generally are strong chemical irritants causing irritation of the nose, throat and eyes. Amines also combine directly with hemoglobin in the blood forming methemoglobins, which reduce the oxygen capacity of the blood and can cause liver and kidney damage. Diphenyl- cresyl SECTION VII - SPILL OR LEAK .PROCEDURES. In case material is released or spilled: Extinguish open flames, cut off electrical power to area, dike to prevent run-off Into waterways and sewers, cover spill with absorbent media (Le. peat, vermiculite, etc.), sweep up remaining contamination. Clean up with nonflammable solvent, dispose of cured media as solid waste In closed containers either at an approved landfill or incinerate at an approved facility. Obey federal, state, county or any other regulations. Waste Disposal Method: Cured catalyzed (resin) may be disposed of at proper landfill and /or incinerated. Obey all pertaining regulations. Excess catalyst should be combined with the correct amount of resin for waste disposal. Unused catalyst must be handled as a hazard- ous waste. phosphate: No data available. Effects of Chronic Overexposure to Chemicals in the Product: DMT: Amines can cause allergic sensitization in a small number of individuals. Symptoms include conditions similar to asthma, or skin rashes typical of many allergies. Diphenyl - cresyl phosphate: No data available. SECTION Vlll -SPEC: PROTECTION INFORMATION Respiratory Protection: Use an airline respirator if there is any significant airborne concentration to prevent health effects or symptoms. Ventilation: Natural ventilation may be sufficient on unobstructed roof top. If poor air movement or close work necessary, local exhaust may be required. Protective Gloves: Gauntlet type; neoprene. Eye Protection: Face shield, safety glasses, or chemical goggles. Other Protective Clothing or Equipment: Solvent-resistant shoes, boots, aprons - frequent cleaned to avoid skin contact. Safety showers and eye -wash equipment should be on-site. SECTION IX - SPECIAL PRECAUTIONS Special precautions with handling and storage: Always store dry and cool. Avoid prolonged storage above 80 °F (27 °C). Keep away from sunlight. Store and handle as NFPA Class 1 -C. Open containers slowly and carefully to relieve any internal pressure, ground all connections, use non - sparking explosion -proof equipment. Other precautions: Practice care, precaution and common sense. No smoking, open flames and no consumption of food while handling material. Avoid prolonged contact with skin, avoid breathing vapor. Environmental: SARA 313: There are no SARA reportable chemicals in this product. RCRA: Using the characteristic of corrosivity (If pH Is -2 or - 12.5), this material would be designated as dangerous waste number D002. VOC: VOCs are released by this product. THIS INFORMATION IS GIVEN IN GOOD FAITH, BUT NO WARRANTY, EXPRESS OR IMPLIED, IS MADE. THE PRODUCT IS NOT CLAIMED TO BE MERCHANTABLE OR FIT FOR ANY PARTICULAR PURPOSE. SUITABILITY IS DETERMINED BY USER. FOR INDUSTRIAL USE AND CERTIFIED APPLICATORS ONLY. Prepared from Importer supplied Information by Schumacher & Associates, Inc., Seattle, WA. No claim of completeness or accuracy Is made. KEMPER SYSTEMS, INC. 550 S Michigan Street Seattle, WA 98108 206 -767 -9505 FAX: 206 - 767 -9531 800 - 541 -5455 KEMPER 13 CITY(' F TUKWILA Department of Community Development FAX T S ITTAL FAX NUMBER: (206) 431 -3665 TO: Ogg //''-_ r DATE: 7//a /g TITLE: FROM: • COMPANY: TITLE: DEPARTMENT: . DEPARTMENT: Ll// Z7 /A/4 � ::.: :......•.::.: :.::.: • : ^.:::.:.: :::..:.. •.:..:.. ::. :. :..:...::. - - .. ��� r..r� �: GGfwSGri :::.: ':wti<iri'SnG:iwiriGiif "w:w4n:i: Ki /i<iiSi:witrV2<v:2ti 1.4,4,4:4,:::44,: ��;::::. .<IN<M< \N'rrvK<4;:; w)F.N�.h:Yw:K.rvNVmn.<v:Kw:; :i∎iNk• s;::: vnw.'4:06::4:r: << iLt irtiS Sw: 4[ �SWi .:4n4wW:i44'v;t4:(wn'.4;x4:5∎; :i4{G� "S'.'i$ :, : :• •r.SV:':•.\'S'<S .v wh,, FAX NO. CALLED: 20 &% 6g2- eCte& NUMBER OF PAGES TRANSMITTED, INCL. 2 THIS COVER SHEET: SENT BY (INITIALS) : r r r nry n rv....'i::: "f..... ; % "''ii 'i' }2::' " tih ` ";! : }'. ` :4< "'v' v!n'f':vi:: Ri <' ':Fi'iiY. GL ' Svn•iii h • 4:::• n'}' i5 'ri4n4S:lir }}:tiiiir.4.h'iK>!:% rig:: 4l i:: vi' i+: Ji: 4i i}: ti}+ 5' rr}}:•::... i<•:•: ti4} i}: v:}:•>i rii}:•} �i r: Ji) isisti: t:•'! i' in{ 4i:' Yi} Sn�} �:v.4n`•:4iY:4ii:4:•::t: "�'• %:" :}......i::. r. . •.n mn r...rr.. rri •....2 . w m r r . • SUBJECT:' 9.3 -- o2 o COMMENTS /MESSAGE: IH: 41r: 1KK• iAN:< I}, 4:'%: trl: Jfii'}: 4:< J%: YiLLJ: NVI/: hVIYWI}:< tii)'< J. LVII% 1: Y}: W% I} J. GY%: 4: iV:< V:\<\'! r': Y::< i<Kt<4YIr:<':«4}}ntil{'FSJ:J }:<Y e4 :'✓�Y:V:h:<J:<N :V}:Ji %:':<4iiYY�J:G<ti• %rA'}:W IYr% N}}: 14:` i91:\ VIIAIi SY( Yf YN} h41JINHXY: 4: Y: J:: i' nrri< Svvial 'J:<WTiivi<•ih<<t4i<Jn'iw: IF THIS COMMUNICATION IS NOT CLEARLY RECEIVED, PLEASE CALL: 31 -3co70 i Dr.vrNrmw.11,rnq?mrfiYH; rri iiik;604iiint .:if WkS:4•AW.aro :4:i�nonn..iuv114,%Z Nv rvf swrnZ»iM,Sveimiw..v >rr4.fii nh - i.n,.iii F.SSrnv'r}.:V ;'''' r: a• 4iw:i a.)< w: a,»' rH: wu; 4; 4�{• N; Ynti) 14}i4 ;{jri.v {' %,yY<i';)h;<ti4i�il <ti:fw41'ir4H)Jh1N:{ti�Sgf DEPARTMENT OF COMMUNITY DEVELOPMENT !7 Office: (206) 431-3670 6300 Sntl1'hrpntnr Rni,1pi,nrr1 T i1rit,iln 'jr A no 1RO M E M O iNNIM City of Tukwila John W. Rants, Mayor Department of Community Development Rick Beeler, Director DATE TO Mr. Carlyle Jensen, Architect FROM Bob Benedicto SUBJECT Kemper Systems, Inc. B93 -0210 # OF PAGES 1 7/6/93 I have reviewed your letter, the Case laboratory reports, and the letter from Buckie Taft of Kemper Systems, Inc. and based upon this information the specific construction requirements for an H -3 flammable liquid storage will not be required. The existing Group B, Divison 2 occupancy may continue with the Kemper Systems, Inc. tenant provided that other requirements are accomplished. ' The V -210, S -210 and BR products remain Toxic, Irritants, Sensitizers and other health hazards (by Kemper Systems, Inc. MSDS). To store these products in a Group B, Divison 2 occupancy the following requirements are applicable: 1. The maximum amount of EACH product that may be stored in a control area is 1000 gals. (per Table 9 -B, UBC). 2. In order to store 1000 Gals. of each product, a control area for each quantity must be identified on the plan. 3. , Each control area must provide a 1 -hr occupancy separation from all other areas and all other control areas. Openings to control areas must be protected by an assembly which provides a 1 -hr fire protective rating. The above noted requirements are in addition to all other Code requirements that apply to this application and are based upon the new information submitted. Please incorporated same in your revisions. If you have any questions or feel that these requirements are not applicable please call me. Robert Benedicto, Plans Examiner 6300 Southcenter Boulevard, Suite #100 • Tukwila, Washington 98188 • (206313670 • Fax (206) 431-3665 M E M O DATE 7/6/93 TO Mr. Carlyle Jensen, Architect FROM Bob Benedicto SUBJECT Kemper Systems, Inc. B93 -0210 #'OF PAGES 1 I have reviewed your letter, the Case laboratory reports, and the letter from Buckie Taft of Kemper Systems, Inc. and based upon this information the specific construction requirements for an H -3 flammable liquid storage will not be required. The existing Group B, Divison 2 occupancy may continue with the Kemper Systems, Inc. tenant provided that other requirements are accomplished. The V -210, S -210 and BR other health hazards (by in a Group B, Divison 2 1. The maximum amount is 1000 gals. (per Table products remain Toxic, Irritants, Sensitizers and Kemper Systems, Inc. MSDS). To store these products occupancy the following requirements are applicable: of EACH product that may be stored in a control area 9 -B, UBC). 2. In order to store 1000 Gals. of each product, a control area for each quantity must be identified on the plan. 3. Each control area must provide a 1 -hr occupancy separation from all other areas and all other control areas. Openings to control areas must be protected by an assembly which provides a 1 -hr fire protective rating. The above noted requirements are in addition to all other Code requirements that apply to this application and are based upon the new information submitted. Please incorporated same in your revisions. If you have any questions or feel that these requirements are not applicable . please call me. Robert Benedicto, Plans Examiner a9rtner for Profeaolonal solution; to Flnhfirl$ and Waterproofing CARLYLE B.JENSEN ARCH. City of Tukwila Building Department Tukwila, Washington Gentlemen: 206 682 8986 P.04 July 1, 1993 Please be advised that the flashpoints for our S210 and BR unsaturated polyester resins are the skune as for our V210, which is indicated on the test reports from Case Consulting Laboratories, Inc., dated June 28, 1993, copies enclosed. All other products which we store and distribute have flashpoints in excess of 120 degrees F or do not have listed flashpoints. In the warehouse from which we intend to distribute, located at 4285 S. 134th Place In Tukwila, we will not have any other products other than those under discussion. Please . advise if you have any questions. Very truly yours, KEMPER SYSTEMS, INC. ti Taft KEMPER SYSTEMS. INC 550 S MIahlAan $tret Seattle, WA 98108 PhOne (800) 841.6455 - (208) 767.9505 FAX (208) 797.9531 Y1 8°,4 oar Iv! o b. is r)9e )7E john stroot 2 cattI9. wry, 96109 CArRLYLE 13.JENSEN ARCH. 206 682 8986 c P. 01 1 t 1cl! Bob Benedict° Senior Plans Examiner Dept. of Community Development City of Tukwila Tukwila, WA. ) Re: Kemper Systems Plans. Dear Mr. Benedicto; Enclosed is a letter from the Kemper System People explaining the Product as we discussed, The material was determined to be not hazardous upon our submittal of the MSDS sheet to Assistant Fire Marshal Mike Alderson. and by the new testing they are not now considdered Flammable, Please review these items and let me know of any problems that these people would have in moving in immediately: Siucerel RECEIVED JUL 0 21993 COMMUNITY DEVELOPMENT CARLYLE B.JENSEN ARCH. 206 692 9996 Case Consulting Laboratories, Inc. P. 02 622 ROUTE TEN WHIPFANY, VIEW J.RSEY 07981 1 ) June 28, 1993 XCemper Systems, Inc. 550 s. Michigan Street Seattle, washington 98108 Ateention: Mr. Rolf W. Eicke.nann FxoM: L. Mr c kow' yak Rroject No.: 04501 SUb.ject: 2eas pod r1ash poin Determination We were a>akhorizad to determine the tag open, cup flash point of an as-receiVed sample identified as v210 Unsaturated Polyester RISin. Flash Point+ ytt' le 'Xa(x p an cup_ (ASTM�a -1318 V210 Unsaturated Polyester Rosin 250k' Respectfully submitted, _rLJ �"' • ' ' L. i ackoWiak CASE C©WSULTrN LASORATORXES, INC Vice President Post-1tr.' brand fax transmittal memo 7671 [rot pages ► From � ° Pc_/ (.�; ,�nJct v �! T! 7 Co. OD� 6U�*"► • phone • ra4r • CARLYLE B.JENSEN.ARCH. 206 562'8986 Ca ,9e Consulting Laboratories, Inc. Attention P. 03 • 622 f1ourE TEN • WHiPPih iy, New JERSEY 079131 • (2 ) 428.8468 •.4:utie 28, .993 Kemper Systems, Inc. 550 S. Michigan Street Seattle, Washington 98103 Mr. Rolf W. Eicke.lmann L. Liackowi,ak Projet;t N .: 04501 Spa i.ePfw: TT alwed c,;,;�: r'l,l�h PA,i.. 7gterrrtiriation 1 �+ .e der0 a.uthoris:�?d to ,4r.;.-;-...._; e. *;�;,� r..�vj CJ.o5c3d flash: pOi ,A1 V/. iii. r ♦l-i.:, �w ..C�p.�.Y l as- rC�C4?i47et,� :;c� ,,� .4 _ ,r... :�� y kc-a icy t'e4nosi.n: _i :i r� '!a�0 .unsd ura ed l:ks".)VJ TS f.4'nnr.n•ANw.. .. �.r..TU....w.LArV...,✓ V21:6 Unsat∎.tz; a uea Po].ye ,ter . Resin 11. Mackawiak 'Zl.ce: :President I4b:. flash up to 2124F. 17,es ElcrfUtlLy Submitted, ." • _• ' • • CASE .Co SULT/NG ::.ASORAT'URXES, : INC.. +Avio "flizr.M : 47/3=1-/ct d. c>100,,vv6ttr,,_ frsor nreJa_w_t_votA z,. occop_wA..c_cti -T-o_kr-_-_6e.irLiciAsr-Arztom Creaor '‘ColAr_vs)i Ox.e.06" oaAci iei ComootAs oC hcotcis e 5icovc.41 liACAck, ?ev- LA.C,To1/46teel-A Jt Crakka o Q tcwvumck6e. trict _610Natc.x0ows_AAAtck_____ iikuiclattotobt-o rate_ oirr__Mne-___0,_ moo_v_vks_oc7__91AwkowoloktikbOvis _ _ tActica,4dAA-__ was_ouwt,__ok rerlowcwevas_ _ _ c*ovv_ekikuL Locks _ %atm) atkvApi- 4-AAR-deocAoevor...Ak_____ 0 R. AA__0.6l.e.,_Atvi. _cLIkomustjc..._rdokv,.. _deo feto_v_cm..os.r4s___ColnkolvA, 1.___Nitowt__Ikt tire uie.A1-+ -6 0, clAcv_■■■.c-3c_114._c_cir-__QADINm.c_m__Sost__:117Ws__Yos____"17:_7_-3/4-ntgL__ A-kt. cc_ (4e,icti_b_e_co.ose 44- Flays.6._Wo..o.a.lactue. AseA...R.616S__ON.Kce_6d4PktswiltA Qkev_tx.410Ak_____4-1/tak. (Ait( pit f\Lo _n:VMAite- X-tramAg-___CAS citScoSsa41 Or__Clectek‘roAl DATE 6/23/93. TO FILE B93 -0210 RSB FROM SUBJECT INITIAL PLAN REVIEW COMMENTS # OF PAGES 1 •1., HAZ MAT STORAGE ROOM IS DESIGNATED AS AN.H -2 STORAGE ROOM. THIS INDICATES (BY DEFINITION AND PROPOSED MATERIALS ON HAND) THAT FLAMMABLE MATERIALS ARE TO'BE USED•IN OPEN CONTAINERS . IF THIS IS THE CASE, THEN THE ROOM IS OVER AREA PER UBC 901(x). IF THIS IS NOT THE CASE, THEN THE. ROOM SHOULD BE CLASSIFIED AS. A GROUP H, DIVISION 3 OCCUPANCY, AND'THE REQUIRMENTS OF A LIQUID STORAGE ROOM WILL BE APPLICABLE. 2. THE H -3 FL AREA EXCEEDS 1000 SF THEREFORE A MINIMUM SEPARATION OF 30 FEET IS QUIRED FROM H -3 EXTERIOR WALLS TO PROPERTY LINES. UBC TABLE 9 ITEM 2.4 3. EXTERIOR DOOR HAS NOT.BEEN PROVIDED PER UBC 3319. 4.. PANIC HARDWARE REQMT NOT NOTED.: 5. SPILL CONTROL AND DRAINAGE CONTROL IS NOT 'SHOWN... VENTILATION REQUIRED. 7. ELECTRICAL PANEL AND TRANSFORMER MAY. NOT BE LOCATED UNLESS CONDITIONS. OF THE WASHINGTON.STATE ELECTRICAL. CODE .KEMPER SYSTEMS PROPOSED HAZARDOUS MATERIALS TO BE STORED: POLYESTER RESINS 1201 GAL BR = 1203 GAL V210 = 1370 GAL S210 = 3774 GAL TOTAL CLASS I -C, (I -C = F.P CLASS I -C, (I -C = F.P CLASS I -C, (I -C = F.P FLAMMABLE LIQUID F.P. = 90F . = OR > 73F AND < 100F ) FLAMMABLE LIQUID F.P. = 90F . = OR > 73F AND < 100F ) FLAMMABLE LIQUID F.P. = 90F . = OR > 73F AND < 100F ) ***************************** * * * * * * * * * * * * * * * * * * * * * * * * * * * * * ** EXEMPT AMOUNTS OF CLASS I -C FLAMMABLE LIQUIDS PER U.B.C. TABLE 9 -A. " IN STORAGE" BASIC 90 GALS. 100% INCR. FOR STOR. IN APPROVED STOR. CABINETS . . . 90 GALS. TOTAL EXEMPT AMOUNT 180 GALS. PER CONTROL AREA AND WITH STORAGE IN APPROVED STORAGE CABINETS. FOOTNOTE 1, TABLE 9 -A ... "CONTROL AREA IS A SPACE BOUNDED BY NOT LESS THAN A ONE HOUR FIRE RESISTIVE OCCUPANCY SEPARATION WITHIN WHICH THE EXEMPTED AMOUNTS OF HAZARDOUS MATERIALS MAY. BE STORED, DISPENSED, HANDLED OR USED. THE NUMBER OR CONTROL AREAS WITHIN A BUILDING USED FOR RETAIL AND WHOLESALE STORES SHALL NOT EXCEED TWO. tHE NUMBER OF CONTROL AREAS IN BUILDINGS WITH OTHER USES SHALL NOT EXCEED FOUR." "CONTROL AREA" DEFINED IN THE U.F.C. PER TABLE SEC. 80 -108. (a) REPEATS THE DEFINITION ABOVE i.e. A ONE HOUR OCCUPANCY SEPARATION IS REQUIRED TO DEFINE THE CONTROL AREA. OCCUPANCY SEPARATIONS ARE DEFINED IN THE BUILDING CODE. KEMPER SYSTEMS PAGE 2 U.F.C. EXEMPT AMOUNT PER CONTROL AREA " STORED" FLAMMABLE LIQUIDS ARE LISTED IN TABLE 79.202 -A. AS FOLLOWS: CLASS I -C FLAMMABLE 90 GALS BASIC 100% INCREASE FOR APPROVED STOR CAB. 90 GALS FOOTNOTE 4 100% INCREASE FOR APPROVED AUTO SPRKS. 90 GALS FOOTNOTE 5 TOTAL ALLOWED 270 GALS OR IN BLDGS USED FOR WHOLESALE & RETAIL SALES WHICH ARE PROTECTED BY AN APPROVED AUTO SPRINKLER SYSTEM THE AGGREGATE QUANTITIES PER CONTROL AREA ACCESSIBLE TO THE PUBLIC ARE ALLOWED TO INCREASE TO A DENSITY OF ONE GALLON PER SQUARE FOOT FOR THE AREA ACTUALLY BEING USED FOR STORAGE ... AND SHALL NOT EXCEED AN AGGREGATE AREA OF 1500 SQUARE FEET. IN THIS CASE FOOTNOTES 4 & 5 SHALL NOT APPLY. TOTAL ALLOWED 1500 GALS. UNIFORM BUILDING CODE REQUIREMENTS FOR PROPOSED STORAGE OF FLAMMABLE LIQUIDS INDICATED AS CLASS I -C FLAMMABLE LIQUIDS. 1. QUANTITIES PROPOSED TO BE STORED EXCEED THE EXEMPT AMOUNTS AS LISTED IN TABLE 9 -A AND ARTICLE 79.202 -A CONSEQUENTLY, THE LIQUID STORAGE ROOM MUST BE CLASSIFIED AS A GROUP H, DIVISION 3 OCCUPANCY. BASED UPON THE DEFINITION: " OCCUPANCIES WITH A QUANTITY OF MATERIAL IN THE BUILDING IN EXCESS OF THOSE LISTED IN TABLE NO 9 -A WHICH PRESENT A HIGH FIRE OR PHUYSICAL HAZARD, INCLUDING BUT NOT LIMITED TO: 3. CLASS I, II, OR III -A FLAMMABLE LIQUIDS OR COMBUSTIBLE LIQUIDS WHICH ARE UTILIZED OR STORED IN NORMALLY CLOSED CONTAINERS OR SYSTEMS AND CONTAINERS PRESSURIZED AT 15 POUNDS PER SQUARE INCH GAUGE OR LESS AND AREOSOLS. KEMPER SYSTEMS PAGE 3. . HAZARDOUS STORAGE AREA MUST MEET THE REQUIREMENTS OF A LIQUID STORAGE ROOM AS DEFINED IN UBC SEC 901 (d) CONSTRUCTION IN ACCORDANCE WITH THE REQUIREMENTS OF GROUP H, DIVISION 3 OCCUPANCIES. UBC 901 (d) & UFC.79.203 (a) ALL PORTIONS OF A ROOM IN H -3 OCCUPANCY SHALL BE WITHIN 75 FEET OF AN EXIT DOOR. UBC 3319 EXIT DOORS PROVIDED WITH LATCH OR LOCK SHALL BE PANIC HARDWARE. UBC 3319 TWO EXITS ARE REQUIRED FOR THIS ROOM ( >200SF). UBC 3319 ONE EXTERIOR DOOR APPROVED FOR FIRE DEPT ACCESS. UBC 901(d)1 TWO HOUR OCCUPANCY SEPARATION REQUIRED. ( >150SF) UBC 901(d)2 * REQUIRED BY UFC 79.203(d) THEREFORE UBC 902 (a,b,c & d) WILL BE REQUIRED. FLOORS LIQUID TIGHT NON COMB. REQUIRED. SPILL CONTROL : RECESS FLOOR 4- INCHES OR PROVIDE RAISED SILL 4 -INCES HIGH & LIQUID TIGHT. DRAINAGE : ROOM SHALL BE PROVIDED WITH A DRAINAGE SYSTEM TO DIRECT THE FLOW OF LIQUIDS TO.AN APPROVED LOCATION, OR THE ROOM SHALL BE DESIGNED TO PROVIDE SECONDARY CONTAINMENT. FOR THE HAZARDOUS MATERIALS AND FIRE PROTECTION WATER. (ALSO REFER DRAINAGE CONTROL REQMT UFC 79.115.) SMOKE AND HEAT VENTS - NO REQMT. 25% OF PERIMETER WALL SHALL BE ON THE EXTERIOR OF BUILDING- O.K. VENTILATION IS REQUIRED PER FIRE CODE / MECHANICAL CODE UBC 905 (a).