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Permit D13-234 - NORMED - TENANT IMPROVEMENT
NORMED 4320 S 131 PL EXPIRED 05/06/14 D13-234 wq City o!Tukwila Department of Community Development 6300 Southcenter Boulevard, Suite #100 Tukwila, Washington 98188 Phone: 206431-3670 Inspection Request Line: 206-431-2451 Web site: http://www.TukwilaWA.gov Parcel No.: 7349200095 Address: 4320 S 131 PL TUKW Suite No: Project Name: NORMED DEVELOPMENT PERMIT Permit Number: D13-234 Issue Date: 08/22/2013 Permit Expires On: 02/09/2014 Owner: Name: NORMED SHAW PTN Address: PO BOX 3644 , SEATTLE WA 98124 Contact Person: Name: LIESA KOLONICS Address: 4310 S 131 PL , TUKVVILA WA 98168 Phone: 206-242-8228 Contractor: Name: TCL PARTNERS CORPORATION Phone: 425-316-3500 Address: 16000 MILL CREEK BLVD SUITE 103 , MILL CREEK WA 98012 Contractor License No: TCLPAPC919QD Expiration Date: 07/10/2015 Lender: Name: SELF FUNDED - NORMED Address: DESCRIPTION OF WORK: INSTALL RACKING Value of Construction: $0.00 Fees Collected: $1,666.34 Type of Fire Protection: SPRINKLERS/AFA International Building Code Edition: 2012 Type of Construction: III -B Occupancy per IBC: 0024 Electrical Service Provided by: SEATTLE CITY LIGHT **continued on next page** doc: IBC -7/10 D13-234 Printed: 08-22-2013 Public Works Activities: Channelization / Striping: N Curb Cut / Access / Sidewalk / CSS: N Fire Loop Hydrant: N Number: 0 Flood Control Zone: Hauling: N Start Time: End Time: Land Altering: Volumes: Cut 0 c.y. Fill 0 c.y. Landscape Irrigation: Moving Oversize Load: Start Time: End Time: Size (Inches): 0 Sanitary Side Sewer: Sewer Main Extension: Private: Public: Storm Drainage: Street Use: Profit: N Non -Profit: Water Main Extension: Private: Public: Water Meter: N Permit Center Authorized Signature: Date: vr/dal/ 3 I hereby certify that I have read and examined this permit and know the same to be true and correct. All provisions of law and ordinances governing this work will be complied with, whether specified herein or not. The granting of this permit does not presume to give authority to violate or cancel the provisions of any other state or local laws regulating construction or the performance of work. I am authorized to sign and obtain this development permit and agree to the conditions attached to this permit. Signature: Print Name: S Lle5' 0. Dl cru CS Date: S. 1.2-i i3 This permit shall become null and void if the work is not commenced within 180 days from the date of issuance, or if the work is suspended or abandoned for a period of 180 days from the last inspection. PERMIT CONDITIONS: 1: ***BUILDING DEPARTMENT CONDITIONS*** 2: No changes shall be made to the approved plans unless approved by the design professional in responsible charge and the Building Official. 3: All permits, inspection records, and approved plans shall be at the job site and available to the inspectors prior to start of any construction. These documents shall be maintained and made available until final inspection approval is granted. 4: When special inspection is required, either the owner or the registered design professional in responsible charge, shall employ a special inspection agency and notify the Building Official of the appointment prior to the first building inspection. The special inspector shall furnish inspection reports to the Building Official in a timely manner. 5: A final report documenting required special inspections and correction of any discrepancies noted in the inspections shall be submitted to the Building Official. The final inspection report shall be prepared by the approved special inspection agency and shall be submitted to the Building Official prior to and as a condition of final inspection approval. doc: IBC -7/10 D13-234 Printed: 08-22-2013 6: All construction shall be done in conforms with the approved plans and the requireme f the International Building Code or International Residential Co�lnternational Mechanical Code, Washington a Energy Code. 7: All rack storage requires a separate permit issued through the City of Tukwila Permit Center. Rack storage over 8 -feet in height shall be anchored or braced to prevent overturning or displacement during seismic events. The design and calculations for the anchorage or bracing shall be prepared by a registered professional engineer licensed in the State of Washington. 8: Manufacturers installation instructions shall be available on the job site at the time of inspection. 9: All electrical work shall be inspected and approved under a separate permit issued by the City of Tukwila Building Department (206-431-3670). 10: VALIDITY OF PERMIT: The issuance or granting of a permit shall not be construed to be a permit for, or an approval of, any violation of any of the provisions of the building code or of any other ordinances of the City of Tukwila. Permits presuming to give authority to violate or cancel the provisions of the code or other ordinances of the City of Tukwila shall not be valid. The issuance of a permit based on construction documents and other data shall not prevent the Building Official from requiring the correction of errors in the construction documents and other data. 11: ***FIRE DEPARTMENT CONDITIONS*** 12: The attached set of building plans have been reviewed by the Fire Prevention Bureau and are acceptable with the following concerns: 13: The total number of fire extinguishers required for an extra hazard occupancy with Class A fire hazards is calculated at one extinguisher for each 1,000 sq. ft. of area. The extinguisher(s) should be of the "all purpose" (4A 40 B:C) dry chemical type. The travel distance to any extinguisher must be 75' or less. (IFC 906.3) (NFPA 10, 3-2.1) 14: Portable fire extinguishers, not housed in cabinets, shall be installed on the hangers or brackets supplied. Hangers or brackets shall be securely anchored to the mounting surface in accordance with the manufacturer's installation instructions. Portable fire extinguishers having a gross weight not exceeding 40 pounds (18 kg) shall be installed so that its top is not more than 5 feet (1524 mm) above the floor. Hand-held portable fire extinguishers having a gross weight exceeding 40 pounds (18 kg) shall be installed so that its top is not more than 3.5 feet (1067 mm) above the floor. The clearance between the floor and the bottom of the installed hand-held extinguishers shall not be less than 4 inches (102 mm). (IFC 906.7 and IFC 906.9) 15: Fire extinguishers shall not be obstructed or obscured from view. In rooms or areas in which visual obstruction cannot be completely avoided, means shall be provided to indicate the locations of the extinguishers. (IFC 906.6) 16: Extinguishers shall be located in conspicuous locations where they will be readily accessible and immediately available for use. These locations shall be along normal paths of travel, unless the fire code official determines that the hazard posed indicates the need for placement away from normal paths of travel. (IFC 906.5) 17: Fire extinguishers require monthly and yearly inspections. They must have a tag or label securely attached that indicates the month and year that the inspection was performed and shall identify the company or person performing the service. Every six years stored pressure extinguishers shall be emptied and subjected to the applicable recharge procedures. If the required monthly and yearly inspections of the fire extinguisher(s) are not accomplished or the inspection tag is not completed, a reputable fire extinguisher service company will be required to conduct these required surveys. (NFPA 10, 4-3, 4-4) 18: Maintain fire alarm system audible/visual notification. Addition/relocation of walls or partitions may require relocation and/or addition of audible/visual notification devices. (City Ordinance #2328) 19: All new fire alarm systems or modifications to existing systems shall have the written approval of The Tukwila Fire Prevention Bureau. No work shall commence until a fire department permit has been obtained. (City Ordinance #2328) (IFC 104.2) 20: Clearance between ignition sources, such as light fixtures, heaters and flame -producing devices, and combustible materials shall be maintained in an approved manner. (IFC 305.1) 21: Storage shall be maintained 2 feet or more below the ceiling in nonsprinklered areas of buildings or a minimum of 18 inches below sprinkler head deflectors in sprinklered areas of buildings. (IFC 315.2.1) 22: Flue spaces shall be provided in accordance with International Fire Code Table 2308.3. Required flue spaces shall be maintained. 23: Exits and exit access doors shall be marked by an approved exit sign readily visible from any direction of egress travel. Access to exits shall be marked by readily visible exit signs in cases where the exit or the path of egress doc: IBC -7/10 D13-234 Printed: 08-22-2013 travel is not immediately visible to the occup . Exit sign placement shall be such that no p tin an exit access corridor is more than 100 feet (30,480 mm) o listed viewing distance for the sign, which 's less, from the nearest visible exit sign. (IFC 1011.1) 24: Every exit sign and directional exit sign shall have plainly legible letters not less than 6 inches (152 mm) high with the principal strokes of the letters not less than 0.75 inch (19.1 mm) wide. The word "EXIT" shall have letters having a width not less than 2 inches (51 mm) wide except the letter "I", and the minimum spacing between letters shall not be less than 0.375 inch (9.5 mm). Signs larger than the minimum established in section 1011.5.1 of the International Fire Code shall have letter widths, strokes and spacing in proportion to their height. The word "EXIT" shall be in high contrast with the background and shall be clearly discernible when the exit sign illumination means is or is not energized. If an arrow is provided as part of the exit sign, the construction shall be such that the arrow direction cannot be readily changed. (IFC 1011.5.1) 25: Exit signs shall be illuminated at all times. To ensure continued illumination for a duration of not less than 90 minutes in case of primary power loss, the sign illumination means shall be connected to an emergency power system provided from storage batteries, unit equipment or on-site generator. (IFC 1006.1, 1006.2, 1006.3) 26: Emergency lighting facilities shall be arranged to provide initial illumination that is at least an average of 1 Foot-candle (11 lux) and a minimum at any point of 0.1 foot-candle (1 lux) measured along the path of egress at floor level. Illumination levels shall be permitted to decline to 0.6 foot-candle (6 lux) average and a minimum at any point of 0.06 foot-candle (0.6 lux) at the end of the emergency lighting time duration. A maximum -to -minimum illumination uniformity ratio of 40 to 1 shall not be exceeded. (IFC 1006.4) 27: Contact The Tukwila Fire Prevention Bureau to witness all required inspections and tests. (City Ordinances #2327 and 1#2328) 28: Any overlooked hazardous condition and/or violation of the adopted Fire or Building Codes does not imply approval of such condition or violation. 29: These plans were reviewed by Inspector 511. If you have any questions, please call Tukwila Fire Prevention Bureau at (206)575-4407. ioc: IBC -7/10 D13-234 Printed: 08-22-2013 CITY OF TUKWILA Community Development Department Public Works Department Permit Center 6300 Soutlicenter Blvd., Suite 100 Tukwila, IVA 98188 http://www.TukwilaWA.gov Building Permit No. Project No. Date Application Accepted: —7 I 7--'I Date Application Expires: "(For office use only) CONSTRUCTION PERMIT APPLICATION Applications and plans must be complete in order to be accepted for plan review. Applications will not be accepted through the mail or by fax. **Please Print** SITE LOCATION Site Address: y 320 S ' 13 I5+ ..c"(RCe King Co Assessor's Tax No.: Tenant Name: I vOri"1ec Suite Number: Floor: PROPERTY OWNER '/ ` ,, l Name: I ' eSG. ,I�OI Ot'11CS- (N o f L�) Address: L4 310 S 131st- el City: T, . 1, „I 1 a State: wA Zip:9 14, Name: IDC ,e,8, Email: ` CAblr kCS 01'lOrYyle8, . C -UM Tukwila Business License No.: 1-.G Gi I qa� Email: ityvaAM 5Cc 1 C\c. (ne-k-- Address:143m 5 . 13151..- P I City: i6,_v'.V\j l \ a State: j (\ Zipgg Q CONTACT PERSON — person receiving all project communication '/ ` ,, l Name: I ' eSG. ,I�OI Ot'11CS- (N o f L�) Address: L4 310 S 131st- el City: T, . 1, „I 1 a State: wA Zip:9 14, Phone: cgcyo_a4a 2226 Fax: +D-G(o^oZ40 _5.5 Is Email: ` CAblr kCS 01'lOrYyle8, . C -UM GENERAL CONTRACTOR INFORMATION Company Name: Tc L `-p . c,-5 Address: I k, cot) tyY t. orae.% IN ici City: rnl l \ ueek, State: W A Zip: ? o(2... Phone: L 5_ 31(0-30 ax: `,2.5 _320_ N0(,' Contr Reg No.:T(fkeCet rixp Date: -1 (lo (is__ Tukwila Business License No.: 1-.G Gi I qa� H:\Applications\Forms-Applications On Line\2011 Applications\Permit Application Revised - 8-9-I l.docx Revised: August 2011 bh New Tenant: 12 Yes ..No ARCHITECT OF RECORD Company Name: (,aeetve lr Ar ( Architect Name: pc„ l Gt,.�, d kocce,r Address: \ L_Iut �-In N v,� -4- s ( 0 City: SecikIt State: W N Zip:99101 Phone: gtio'mgGa_9(oZZ Fax: 2-0(o`a(o21.—CjSO`7 Email: Pa wecivex_ lrCin e c.„rn U ENGINEER OF RECORD Company Name:Skx-uthurai exylve Ewe Engineer Name: A ("l fko ( h as n ( Address: 1 aco j� �- ren S* t C J 1 AC1 J City: I-�sYv0. rte 1 wk. State: C. Zip: ./ 2�—j Phone:. 14 .. (P32 _-7330Fax:lj`f- (032 11 tp5 Email: ityvaAM 5Cc 1 C\c. (ne-k-- LEN, DER/BONDISSUED (required for projects $5,000 or greater per RCW"19.27.095) Name: Opt.I'Cte Address: 143(b s, 1 t l 31 S4"" p I City:—Ti ( (a State: WA Zip: tlg1LS Page I of 4 BUILDING PERMIT INFORMATION— 206-431-3670 Valuation of Project (contractor's bid price): $ Describe the scope of work (please provide detailed information): ' Qn 1 `CSC r Will there be new rack storage? Yes Existing Building Valuation: $ ❑.. No If yes, a separate permit and plan submittal will be required. Provide All Building Areas in Square Footage Below PLANNING DIVISION: Single family building footprint (area of the foundation of all structures, plus any decks over 18 inches and overhangs greater than 18 inches) *For an Accessory dwelling, provide the following: Lot Area (sq ft): Floor area of principal dwelling: Floor area of accessory dwelling: *Provide documentation that shows that the principal owner lives in one of the dwellings as his or her primary residence. Number of Parking Stalls Provided: Standard: Compact: Handicap: Will there be a change in use? 0 Yes ❑ No If "yes", explain: FIRE PROTECTION/HAZARDOUS MATERIALS: Sprinklers Automatic Fire Alarm ❑ None ❑ Other (specify) Will there be storage or use of flammable, combustible or hazardous materials in the building? Yes 0 No If "yes', attach list of materials and storage locations on a separate 8-1/2" x l 1" paper including quantities and Material Safety Data Sheets. SEPTIC SYSTEM ❑ On-site Septic System — For on-site septic system, provide 2 copies of a current septic design approved by King County Health Department. H:\Applications\Forms-Applications On Line\2011 Applications\Permit Application Revised - 8-9-I I.docx Revised: August 2011 bh Page 2 of 4 Existing Interior Remodel Addition to Existing Structure New Type of Construction per IBC Type of Occupancy per IBC lst Floor 2nd Floor 3rd Floor Floors thru Basement Accessory Structure* Attached Garage Detached Garage Attached Carport Detached Carport Covered Deck Uncovered Deck PLANNING DIVISION: Single family building footprint (area of the foundation of all structures, plus any decks over 18 inches and overhangs greater than 18 inches) *For an Accessory dwelling, provide the following: Lot Area (sq ft): Floor area of principal dwelling: Floor area of accessory dwelling: *Provide documentation that shows that the principal owner lives in one of the dwellings as his or her primary residence. Number of Parking Stalls Provided: Standard: Compact: Handicap: Will there be a change in use? 0 Yes ❑ No If "yes", explain: FIRE PROTECTION/HAZARDOUS MATERIALS: Sprinklers Automatic Fire Alarm ❑ None ❑ Other (specify) Will there be storage or use of flammable, combustible or hazardous materials in the building? Yes 0 No If "yes', attach list of materials and storage locations on a separate 8-1/2" x l 1" paper including quantities and Material Safety Data Sheets. SEPTIC SYSTEM ❑ On-site Septic System — For on-site septic system, provide 2 copies of a current septic design approved by King County Health Department. H:\Applications\Forms-Applications On Line\2011 Applications\Permit Application Revised - 8-9-I I.docx Revised: August 2011 bh Page 2 of 4 PERMITAPPLICATION NOTES Value of Construction — In all cases, a value of construction amount should be entered by the applicant. This figure will be reviewed and is subject to possible revision by the Permit Center to comply with current fee schedules. Expiration of Plan Review — Applications for which no permit is issued within 180 days following the date of application shall expire by limitation. The Building Official may grant one or more extensions of time for additional periods not exceeding 90 days each. The extension shall be requested in writing and justifiable cause demonstrated. Section 105.3.2 International Building Code (current edition). I HEREBY CERTIFY THAT I HAVE READ AND EXAMINED THIS APPLICATION AND KNOW THE SAME TO BE TRUE UNDER PENALTY OF PERJURY BY THE LAWS OF THE STATE OF WASHINGTON, AND I AM AUTHORIZED TO APPLY FOR THIS PERMIT. BUILDING OWNER Signature: Print Name: - - _Sha Day Telephone: vQi(p ^ ��- 8-02-2 kUTHORIZ D GENT: Date: 1 I l3 Mailing Address: P.0 . 60< (o4" -f H:\Applications\Forms-Applications On Line\2011 Applications\Permit Application Revised - 8-9-I I.docx Revised: August 2011 bh Secd—H e wA qq 124 - 3%4q City State Zip Page 4 of 4 • • City of Tukwila of �Z Department of Community Development 6300 Southcenter Boulevard, Suite #100 Tukwila, Washington 98188 Phone: 206-431-3670 Fax: 206-431-3665 Web site: http://www.TukwilaWA.g,ov Parcel No.: 7349200095 Address: 4320 S 131 PL TUKW Suite No: Applicant: NORMED .RECEIPT Permit Number: D13-234 Status: APPROVED Applied Date: 07/12/2013 Issue Date: Receipt No.: R13-02430 Initials: User ID: LAW 1632 Payment Amount: $834.40 Payment Date: 08/22/2013 02:07 PM Balance: $0.00 Payee: NORMED TRANSACTION LIST: Type Method Descriptio Amount Payment Check 165750 834.40 Authorization No. ACCOUNT ITEM LIST: Description Account.Code Current Pmts BUILDING - NONRES STATE BUILDING SURCHARGE 000.322.100 640.237.114 Total: $834.40 829.90 4.50 Printari• (1R-22-7013 City of Tukwila Department of Community Development 6300 Southcenter Boulevard, Suite #100 Tukwila, Washington 98188 Phone: 206-431-3670 Fax: 206-431-3665 Web site: http://www.TukwilaWA.gov Parcel No.: 7349200095 Address: 4320 S 131 PL TUKW Suite No: Applicant: NORMED 'RECEIPT Permit Number: D13-234 Status: PENDING Applied Date: 07/12/2013 Issue Date: Receipt No.: R13-02339 Initials: JEM User ID: 1165 Payment Amount: $.45 Payment Date: 08/12/2013 01:19 PM Balance: $834.40 Payee: NORMED TRANSACTION LIST: Type Method Descriptio Amount Payment Cash Authorization No. ACCOUNT ITEM LIST: .45 Description Account Code Current Pmts BUILDING INVESTIGATION 000.322.800 .45 Total: $.45 crnrod• na_19_9n1l • • City of Tukwila Department of Community Development 6300 Southcenter Boulevard, Suite #100 Tukwila, Washington 98188 Phone: 206-431-3670 Fax: 206-431-3665 Web site: http://www.TukwilaWA.gov Parcel No.: 7349200095 Address: 4320 S 131 PL TUKW Suite No: Applicant: NORMED RECEIPT Permit Number: D13-234 Status: PENDING Applied Date: 07/12/2013 Issue Date: Receipt No.: R13-02338 Payment Amount: $292.05 Initials: JEM Payment Date: 08/12/2013 01:18 PM User ID: 1165 Balance: $834.85 Payee: NORMED TRANSACTION LIST: Type Method Descriptio Amount Payment Check 165938 292.05 Authorization No. ACCOUNT ITEM LIST: Description Account Code Current Pmts BUILDING INVESTIGATION 000.322.800 292.05 Total: $292.05 rinr• [7 o, int_nR Printed: 08-12-2013 • City of Tukwila Department of Community Development 6300 Southcenter Boulevard, Suite #100 Tukwila, Washington 98188 Phone: 206-431-3670 Fax: 206-431-3665 Web site: http://www.TukwilaWA.gov Parcel No.: 7349200095 Address: 4320 S 131 PL TUKW Suite No: Applicant: NORMED RECEIPT Permit Number: D13-234 Status: PENDING Applied Date: 07/12/2013 Issue Date: Receipt No.: R13-02119 Initials: User ID: WER 1655 Payment Amount: $539.44 Payment Date: 07/12/2013 09:16 AM Balance: $834.40 Payee: NORMED TRANSACTION LIST: Type Method Descriptio Amount Payment Check 165715 539.44 Authorization No. ACCOUNT ITEM LIST: Description Account Code Current Pmts PLAN CHECK - NONRES 000.345.830 539.44 Total: $539.44 rinr• Recaint-116 Printed: 07-12-2013 INSPECTION NO. INSPECTION RECORD Retain a copy with permit I3 23h1 PERMIT N0. CITY OF TUKWILA BUILDING DIVISION 6300 Southcenter Blvd., #100, Tukwila. WA 98188 (206) 431-3670 Permit Inspection Request Line (206) 431-2451 Project: /N OZ. r\r\� n Type of Ins a ion: ��� `�`Lc� 'LI_Lie 11-11\-( Address: %-\ 22 '3t t--- Date Called: , Special Instructions: DateWanted t: / / aim. 1 (7 : ((2j PIT?.? Requester: Phone No: „..Q.:7-'\ 2 t Z- * 3 22n Approved per applicable codes. Corrections required prior to approval. COMMENTS: (L I e.— 1:-A; 10 - gc51 Lr /e 41c- s F D - 0 Ili 1n/f s i r D&. Date: Io (Ip 3 rei EINSPECTION FEE REQUIRED. Prior to next inspection, fee must be p.i.¢)at 6300 Southcenter Blvd., Suite 100. Call to schedule reinspection. 7�= INSPECTION RECORD Retain a copy with permit INSPECTION NO. PERMIT NO. CITY OF TUKWILA BUILDING DIVISION 6300 Southcenter Blvd., #100, Tukwila. WA 98188 (206) 431-3670 Permit Inspection Request Line (206) 431-2451 bI Project: 0__ l�ni f !, (--A6 P.V) 0 ]— "I- r J K S Si- (Ai"' J j-. 1 SNC 0_5. N PRaPekL ( 1� Type of Inspection. C 2� € nit 4 N cl Li g IAA :N(.7 i e-- 1"" Add ess: �i`3�O 5 /3 / P1..-. Date Called: Special Instructions: Date Wanted: a.m: Requester: ,I. /s 4 Phone No: 06—oZ4/2-22Z& Approved per applicable codes. 0Corrections required prior to approval. COMMENTS: (--A6 P.V) 0 ]— "I- r J K S Si- (Ai"' J j-. 1 SNC 0_5. N PRaPekL ( 1� \ d i ZleD C 2� € nit 4 N cl Li g IAA :N(.7 i e-- 1"" lVP f OIL - t,3�&iP, i73c h4'—ren 041Did s YViInl/Z ASKS 0 D f'ikl0 Ho- et' Date. 6-141— ,, .. SPECTION FEE REQ IRED. P ionto next inspection. fee must be at 6300 Southcenter B vd., Su to 100. Call to schedule reinspection. INSPECTION RECORD Retain a copy with permit INSPECTION NO. -. PERMIT NO. CITY OF TUKWILA BUILDING DIVISION 6300 Southcenter Blvd.,#100, Tukwila. WA 98188 im (206) 431-3670 Permit. Inspection Request Line (206) 431-2451 Project: , ISDfZMe Type of Inspection: j=i(JAL— Addre : ' L ;`' 2O . S 1310 L_- Date Called: Special Instructions: \, Date Wanted- ante,d:;, )0 13/r-2, Requester: Phone No: 253-3(03-I')S5 Approved per applicable codes. Corrections required prior to approval. COMMENTS: D.A0(4s 1`Ia-r ciewkpLeTf L v i oA k e/ vcrw\ j L.A- e its'414, 1-;-qi4N �2'; = `OC -4 b'O fn ctn,dei vJ 14 IA QMr r o. -0C1 -mac 04 4? Insp= t'r: /1/4N1 d D f3/(7) SPECTION tFEE REQU]RED. Prior to next inspection, fee must be at 6300 Southcenter Blvd., Suite 100. Call to schedule reinspection. INSPECTION RECORD ' ' ' ''''' Retain a copy permit ermit D 13 —2-3 4 -II INSPEC ION NO. . PERMIT NO. CITY OF TUKWILA BUILDING DIVISION 6300 Southcenter Blvd., #100, Tukwila. WA 98188 (206) 431-3670 Permit Inspection Request Line (206) 431-2451. Project: NpiZMC__N Type of Inspection: =INA Address: 1479,,C) S k3 1 Pi, Date Called: Special Instructions: Date Wanted: CI _ 2-7—. 1-- a.m. Requester: Phone No: ElApproved per applicable codes. Corrections required prior to approval. COMMENTS: fAt.--`'b/r' O k 77-v•' . �-tre 2 ///11-..7 ' ea/i4 z77-7 «l .00 a Date 7// n REINSPECTION FEE REUIRED.T'rio.r to next inspection,.fee must be paid at 6300 Southcenter Blvd., Suite 100. Call to schedule reinspection. INSPECTION NO. INSPECTION RECORD Retain a copy with permit 1713-Z3 (4 PERMIT NO. CITY OF TUKWILA BUILDING DIVISION 6300 Southcenter Blvd., #100,. Tukwila. WA 98188 (206) 431-3670 Permit Inspection Request Line (206) 431-2451 Project: 00D -OE r) Type of Inspection:. 1° +v ee aca iey_Lici in -4; N ( Date Called: Address: t -132-U s i3 \ PL Special Instructions: - Date Wted:. -)3- -2) p. ab • Requester: Phone No: QQS— EiApproved per applicable codes. CArequired prior to approval. COMMENTS: € A 1:41 Date ra%, I I REINSPECTION FEE REQ IRED. Prior t next inspection. fee must J e pais at 6300 Southcenter lvd.. Suite 10 . Call to schedule reinsp ion. INSPECTION NUMBER INSPECTION RECORD Retain a copy with permit 013-234/ PERMIT NUMBERS CITY OF TUKWILA FIRE DEPARTMENT 444 Andover Park East, Tukwila, Wa. 98188 206-575-4407 Project: iv0tr - d' p Type of Inspection: -7-60 Address: , /Contact Suite #: 1-S2© s i 3 1 p j Person: Special Instructions: ric-- Phone No.: Approved per applicable codes. Corrections required prior to approval. COMMENTS: Sprinklers: Fire Alarm: Hood & Duct: Monitor: Pre -Fire: 1-1 � picot -at ftf ric-- i .mac ror f LI o6 1'i )) /13. Needs Shift Inspection: Sprinklers: Fire Alarm: Hood & Duct: Monitor: Pre -Fire: Permits: Occupancy Type: , Inspector: (X i • f /V -f Date: /f7/L///3 Hrs.: I $100.00 REINSPECTION FEE REQUIRED. You will receive an invoice from the City of Tukwila Finance Department. Call to schedule a reinspection. Billing Address Attn: Company Name: Address: City: State: Zip: Word/Inspection Record Form.Doc 6/11/10 T.F.D. Form F.P. 113 1 INSPECTION NUMBER INSPECTION RECORD Retain a copy with permit Des- z3y PERMIT NUMBERS CITY OF TUKWILA FIRE DEPARTMENT 444 Andover Park East, Tukwila, Wa. 98188 206-575-4407 Proje : D ( o r,v J� Sprinklers: a Type 9f Inspection: �.K. Address: Suite #: 11_37 c s t3 l .J. I P1 Contact Person: Special Instructions: A 6c., w / f 4' 7S--/ c0/ uei l J -)- Phone No.: Approved per applicable codes. Corrections required prior to approval. COMMENTS:.:� Sprinklers: f '"'7,' po,,,,--f, I cr epcoaf 4 r s 4 ea 5-e. l�.G Hood & Duct: ci rc % e`,, p faff/S. -1 r -o sos 7 ' dee 6 i 4-s 4-' �a 3 r �a , s ,J€ee dr lvs I- C. Permits: Occupancy Type: '-'4 PI c)- rnrn cn aidd' rien-r i/ 1 - r im tO 8c A 6c., w / f 4' 7S--/ c0/ uei l J -)- L/— Fire— ALit .14 o it i cot ket9 sr„,s1e,.,..) , -S-o m -e I- E r v c-dlytcrrx e X2_3 21 Needs Shift Inspection: Sprinklers: Fire Alarm: Hood & Duct: Monitor: Pre -Fire: Permits: Occupancy Type: InspectorC FM.5-1/ l/ Date: 7/2, 7fr Hrs.: L $1,100 -REINSPECTION FEE REQUIRED. You will receive an invoice from heCity of Tukwila Finance Department. Call to schedule a reinspection. Billing Address `Attn: Company Name: Address: City: State: Zip: Word/Inspection Record Form.Doc . 6/11/10 T.F.D. Form F.P. 113 Field Report Report #: 059909 Client: Mr. Racks 500 S.W. 16th St. Renton, WA 98057 Contact: Carey Ferguson Project Number: 13, Permit #: Project Name: Normed Address: 4320 S. 131st Place Inspection Performed: Proprietary Anchors Date: 9/26/2013 Time: Temperature: Anchor bolts for pallet racks per drawing 2. Verified installation of Simpson Strong bolt 2 anchors, 1/2 x 4 3/4 with 3 1/4" embed, torqued to 60 ft./lbs. This is a partial inspection as marked on sheet 2, (77) total bays. CITY OF UK C WILq OCT 14 2ic;3 PERMIT CENTER Distribution: Distribute Client ❑ Distribute Contractor Li Distribute Engineer I ! Distribute Owner (Jl Distribute Municipality LI Distribute Other Ei Distribute Architect ❑ Distribute Other Inspector: Trow, Michael Reviewed by: Mike Blackwell All reports are considered confidential and are the property of the client and A.A.R. Testing Laboratory, Inc. Reproduction except in full without the written consent of A.A.R. Testing is strictly forbidden Client: Mr. Racks 500 S.W. 18th St. Renton, WA 98057 Contact: Carey Ferguson Field Report Report #: 059909 Project Number: 13-578 Permit #: D13-234 Project Name: Normed Address: 4320 S. 131st Place Inspection Performed: Proprietary Anchors Date: 9/26/2013 Time: Temperature: Anchor bolts for pallet racks per drawing 2. Verified installation of Simpson Strong bolt 2 anchors, 1/2 x 4 3/4 with 3 1/4" embed, torqued to 60 ft./lbs. This is a partial inspection as marked on sheet 2, (77) total bays. REC CITY OFTUKD W►Lq OCT 152013 PERMIT CENTER Distribution: Li Distribute Client ❑ Distribute Contractor LI Distribute Engineer [1 Distribute Owner [ Distribute Municipality Li Distribute Other ❑ Distribute Architect ❑ Distribute Other Inspector: Trow, Michael Reviewed by: Mike Blackwell All reports are considered confidential and are the property of the client and A.A.R. Testing Laboratory, Inc. Reproduction except in full without the written consent of A.A.R. Testing is strictly forbidden Client: Mr. Racks 500 S.W. 16th St. Renton, WA 98057 Contact: Carey Ferguson Field Report Report #: 059998 Project Number: 13.578 Permit#: D13-234 Project Name: Normed Address: 4320 S. 131st Place Inspection Performed: Proprietary Anchors Date: 10/3/2013 Time: Temperature: Anchor bolts for pallet racks. Verified installation of Simpson Strongbolt 2 anchors, 1/2" x 4 3/4" with 3 1/4" embedment, torqued to 60 ft. lbs. All bays/rows complete per sheet 2. Note: One (1) row of 8 bays deleted in east side. All placed per plan. This is a final inspection. Distribution: J Distribute Client Distribute Engineer LI Distribute Contractor Distribute Owner l j Distribute Municipality ❑ Distribute Other El Distribute Architect U Distribute Other Inspector: Trow, Michael Reviewed by: Mike Blackwell All reports are considered confidential and are the property of the client and A.A.R. Testing Laboratory, Inc. Reproduction except in full without the written consent of A.A.R. Testing is strictly forbidden ‘..X0r1 pi ctural .er""14C°PY oncepts ngineering Project Name : NORMED Project Number : N-002613-4 Date : 07/08/13 Street Address : 4320 S 131ST PLAGE City/State : TUCKWILA, WA .98168 Scope of Work : SELECTIVE RACK 1200 N. Jefferson St, Suite F Anaheim, CA 92807 Tel: 714.632.7330 Fax: 714.632.7763 e-mail: mail@sceinc.net REVIEWED FOR CODE COMPLIANCE APPROVED AUG 2 1 2013 City of Tukwila BUILDING DIVISION EXPIRES 10/25/ ja 08 2D13 RECEIVED CITY OF TUKWILA JUL 1 2 2013 PERMIT CENTER Str tural oncepts Engineering 1200 N. Jefferson Ste. Ste F Anaheim.CA 92807 Tel: 714.632.7330 Fax: 714.632.7763 By: RPL Project: NORMED Project #: N-062613-4 TABLE OF CONTENTS Title Page 1 Table of Contents 2 Design Data and Definition of Components 3 Critical Configuration 4 Seismic Loads 5 to 6 Column 7 Beam and Connector 8 to 9 Bracing 10 Anchors 11 Base Plate 12 Slab on Grade 13 Other Configurations 14 ' ib 15 NORMED -TYPE I Page ' of I 7/8/2013 Str tural Loncepts Engineering 1200 N. Jefferson Ste. Ste F Anaheim. CA 92807 Tel: 714.632.7330 Fax: 714.632.7763 By: RPL Project: NORMED Project #: N-062613-4 Design Data 1) The analyses conforms to the requirements of the 2009 IBC and the 2008 RMI/ANSI MH 16.1 Rack Design Manual Steel Storage Racks (RMI) and the ASCE 7-05, section 15.5.3 2) Transverse braced frame steel conforms to ASTM A570, Gr.42, with minimum strength, Fy=42 ksi Longitudinal frame beam and connector steel conforms to ASTM A570, Gr.42, with minimum yield, Fy=42 ksi All other steel conforms to ASTM A36, Gr. 36 with minimum yield, Fy= 36 ksi 3) Anchor bolts shall be provided by installer per ICC reference on plans and calculations herein. 4) All welds shall conform to AWS procedures, utilizing E70xoc electrodes or similar. All such welds shall be performed in shop, with no field welding allowed other than those supervised by a licensed deputy inspector. 5) The slab on grade is 6" thick with minimum 2500 psi compressive strength. Soil bearing capacity is 1000 psf. Definition of Components Frame Height A . Beam Product Beam Spacing Beam Length Front View: Down Aisle (Longitudinal) Frame Column Beam to Column Connector Base Plate and Anchors Panel Height Frame Depth Section A: Cross Aisle (Transverse) Frame Horizontal Brace Diagonal Brace NORMED -TYPE 1 Page 3 of ( 7 7/8/2013 Structural Concepts Engineering 1200 N. Jefferson Ste. Ste F Anaheim. CA 92807 Tel: 714.632.7330 Fax: 714.632.7763 By: RPL Project: NORMED Project#: N-062613-4 Configuration & Summary: TYPE 1 SELECTIVE RACK D/R 180" 86„ 84" 10" 96" 180" 14" 24" 24" 4- 24" 4- 24" 4- 24" 'f--- 42" 4-4`— 42" **RACK COLUMN REACTIONS ASD LOADS AXIAL DL= 150 /b AXIAL LL= 4,800 /b SEISMIC AXIAL Ps=+/- 3,536 lb BASE MOMENT= 5,000 in -1b Seismic Criteria # Bm Lvls Frame Depth Frame Height # Diagonals Beam Length Frame Type Ss=1.501, Fa=1 3 42 in 180.0 in 6 96 in Single Row Component Description STRESS Column Fy=42 ksi 3x3x14ga P=3300 lb, M=12804 in -lb 0.97-0K Column & Backer None None None N/A Beam Fy=42 ksi StepBeam 4"x2.5"x0.06 " Lu=96 in Capacity: 3844 lb/pr 0.83-0K Beam Connector Fy=42 ksi Lvl 1: 3 pin OK I Mconn=7660 in -lb Mcap=12691 in -lb 0.6-0K Brace -Diagonal Fy=42 ksi I -Type 1-1/2x7/8x14ga 0.21-0K Base Plate Fy=36 ksi 8 in x 5 in x 0.375 in I Fixity= 1106 in -lb 0.46-0K Anchor 2 per Base 0.5" x 3.25" Embed POWER STUD SD2 ESR 2502 Inspection Reqd (Net Seismic Uplift=2354 lb) 0.908 - OK Slab & Soil 6" thk x 2500 psi slab on grade. 1000 psf Soil Bearing Pressure 0.54-0K Level Load Per Level Beam Spcg Brace Story Force Transv Story Force Longit. Column Axial Column Moment Conn. Moment Beam Connector 1 3,200 lb 10.0 in 24.0 in 40 lb 22 lb 4,950 lb 1,106 "# 7,660 "# 3 pin OK 2 3,200 lb 84.0 in 24.0 in 3 3,200 lb 86.0 in 24.0 in 24.0 in 24.0 in 14.0 in 373 lb 209 lb 3,300 lb 12,804 "# 10,475 "# 3 pin OK 715 lb 401 lb 1,650 lb 8,611 "# 5,673 "# 3 pin OK Total: 1,128 lb 632 lb Notes NORMED -TYPE Page yof / 7/8/20 13 Str tura) oncepts Engineering 1200 N. Jefferson Ste. Ste F Anaheim. CA 92807 Tel: 714.632.7330 Fax: 714.632.7763 By: RPL Project: NORMED Project #: N-062613-4 Seismic Forces Configuration: TYPE 1 SELECTIVE RACK D/R Lateral analysis is performed with regard to the 2009 IBC Sec. 2208.1, 2008 RMI/ANSI MH 16.1 Sec 2.6 & ASCE 7-05 sec 15.5.3 Transverse (Cross Aisle) Seismic Load V= Csl= Cs2= Cs3= Cs -max= Cs*Ip*Ws=Cs*Ip*(0.67*LL*PLrf+DL) [Sds/R] * 0.67 0.67 factorper RPP commentary S 2.1 14 5 2.1 unrS C/Ma,llwl erAWLam, 0.1676 0.14*Sds*0.67 0.0939 [0.5*S1/R] * 0.67 0.0434 0.1676 Base Shear Coeff=Cs= 0.1676 ASD format Loads Cs -max * Ip= 0.1676 Vmin= 0.015 Eff Base Shear=Cs= 0.1676 Ws= Level PRODUC LOAD/LVL,PL PL*0.67*PLrf 1 3,200 lb 2,144 lb 2 3,200 lb 2,144 lb 3 3,200 lb 2,144 lb (0.67*PL,1 * PL)+DL 6,732 lb Vtransv=Vt= 0.1676 * (300 lb + 6432 Ib) EL= 1,128 lb ASD Level Transverse seismic shear per upright DL 100 lb 100 lb 100 lb hi 10 in 94 in 180 in wi*hi 22,440 210,936 403,920 Ss= 1.501 S1= 0.518 Fa= 1.000 Fv= 1.500 Sds=2/3*Ss*Fa= 1.001 Sd1=2/3*S1*Fv= 0.518 Ca=0.4*2/3*Ss*Fa= 0.4003 (Transverse, Braced Frame Dir.) R= 4.0 Ip= 1.0 PL/F1= 1.0 Pallet Height=hp= 60.0 in DL per Beam LvI= 100 lb Fi Fi*(hi+hp/2) 39.7 lb 1,588-# 373.4 lb 46,302-# 714.9 lb 150,129-# sum: 9,600 lb 6,432 lb Longitudinal (Downaisle) Seismic (Similarly for longitudinal seismic loads, using R=6.0 Cs1=Sd1/(T*R)= Cs2= Cs3= Cs -max= Level 1 2 3 0.0578 0.0939 0.0289 0.0939 300 lb W=6732 lb 637,296 1,128 lb E=198,019 Ws= (0.67 * PLS * PL) + DL PLS= = 6,732 lb (Longitudinal, Unbraced Dir.) R= Cs=Cs-max*Ip= 0.0939 r= 1.0 (,ws1 Eig rr hw1 b.0 Eel s 1.00 sec Vlong= 0.0939 * (300 lb + 6432 lb) EL= 632 lb ASD Level Longit seismic shear per uptight N""1 pwq F9 PRODUC LOAD/LVL,PL PL*0.67*PLrf 3,200 lb 2,144 lb 3,200 lb 2,144 lb 3,200 lb 2,144 lb DL 100 lb 100 lb 100 lb hi 10 in 94 in 180 in wi*hi 22,440 210,936 403,920 Fi 22.3 lb 209.2 lb 400.6 lb wont view sum: NORMED -TYPE I 6,432 lb 300 lb W=6732 lb 637,296 632 lb Page 1, of / 1 7/8/2013 Sttura) rL.oncepts Engineering 1200 N. Jefferson Ste. Ste F Anaheim. CA 92807 Tel: 714.632.7330 Fax: 714.632.7763 By: RPL Project: NORMED Project #: N-062613-4 Downaisle Seismic Loads Configuration: TYPE 1 SELECTIVE RACK D/R Determine the story moments by applying portal analysis. The base plate is assumed to provide partial fixity. Seismic Story Forces Vlong= 632 lb Vcol=Vlong/2= 316 lb F1= 22 lb F2= 209 lb F3= 401 lb Seismic Story Moments �\4 Typical frame made Tributary area of two columns of rack frame \\ 4 \\\ f 14— 96 \\\ J Front View Side View Conceptual System Typical Frame made of two columns \\`I \NN. Top View Mbase-max= 5,000 in -lb <=== Default capacity Mbase-v= (Vcol*hleff)/2 = 1,106 in -lb <=== Moment going to base Mbase-eff= Minimum of Mbase-max and Mbase-v = 1,106 in -lb M 1-1= [Vcol * hleff]-Mbase-eff M 2-2= [Vcol-(F1)/2] * h2 = (316 lb * 7 in) -1106 in -lb = [316 lb -104.6 lb]*84 in/2 = 1,106 in -lb = 12,804 in -lb hl-eff= hi - beam clip height/2 = 7 to Vcol Mseis= (Mupper+Mlower)/2 Mseis(1-1)= (1106 in -lb + 12804 in-lb)/2 Mseis(2-2)= (12804 in -lb + 8611 in-lb)/2 = 6,955 in -lb = 10,707 in -lb Beam to Column Elevation Summary of Forces LEVEL 1 2 3 hi 10 in 84 in 86 in Axial Load 4,950 lb 3,300 lb 1,650 lb Column Moment 1,106 in -lb 12,804 in -lb 8,611 in -lb Mseismic Mend -fixity Mconn** 6,955 in -lb 3,259 in -lb 7,660 in -lb 10,707 in -lb 3,259 in -lb 10,475 in -lb 4,305 in -lb 3,259 in -lb 5,673 in -lb Beam Connector 3 pin OK 3 pin OK 3 pin OK Mconn= (Mseismic + Mend-fixity)*0.75 Mconn-allow(3 Pin)= 12,691 in -lb NORMED -TYPE i Page tF' of ( / 7/8/2013 Str ` tural Joncepts Engineering 1200 N. Jefferson Ste. Ste F Anaheim. CA 92807 Tel: 714.632.7330 Fax: 714.632.7763 By: RPL Project: NORMED Project #: N-062613-4 Column (Longitudinal Loads) Configuration: TYPE 1 SELECTIVE RACK D/R Conforms to the requirements of Chapter C5 of the AISI Cold Formed Steel Design Manual for combined bending and axial loads. Section Properties Section: 3x3x14ga Aeff = 0.643 in^2 Ix = 1.130 in^4 Sx = 0.753 in^3 rx = 1.326 in S2f= 1.67 E= 29,500 ksi Loads Iy = 0.749 in^4 Sy = 0.493 in^3 ry= 1.080 in Fy= 42 ksi Cmx= 0.85 Kx = 1.7 Lx = 82.0 in Ky = 1.0 Ly = 24.0 in Cb= 1.0 t 3.000 in 3.000 in Li0.075 in Considers loads at level 2 Critical load case RMI Sec 1.1, item 4: (1 +0.11Sds)DL + (1 +0.14SDS)PL *0.75+EL *0.75 <= 1.0, ASD Method COLUMN DL= 100 lb COLUMN PL= 3,200 lb Mcol= 12,803 in -lb 0.11Sds= 0.110077 0.14Sds= 0.140098 Axial Analysis Axial Load= p= (1.110077*100 Ib)+(1.140098*3200 Ib*0.75) = 2,847 lb Moment=Mx= Mcol*0.75 = 12803 in -lb * 0.75 = 9,602 in -lb KxLx/rx = 1.7*82"/1.326" = 105.1 Fe= n^2E/(KL/r)max^2 = 26.3ksi Pn= Aeff*Fn = 16,242 lb P/Pa= 0.34 > 0.15 Bending Analysis KyLy/ry = 1*24"/1.08" = 22.2 Fy/2= 21.0 ksi S2c= 1.92 Fe > Fy/2 Fn= Fy(1-Fy/4Fe) = 42 ksi*[1-42 ksi/(4*26.3 ksi)] = 25.3 ksi Pa= Pn/Qc = 16242lb/1.92 = 8,459 lb Check: P/Pa + (Cmx*Mx)/(Max*px) <_ 1.0 P/Pao + Mx/Max 5 1.0 Pno= Ae*Fy = 0.643 in^2 *42000 psi = 27,006 lb Max= My/S2f = 31626 in-lb/1.67 = 18,938 in -lb px= {1/[1-(Qc*P/Pcr)]}^-1 = {1/[1-(1.92*2847 lb/16931 Ib)11^-1 = 0.68 Combined Stresses Pao= Pno/S2c = 270061b/1.92 = 14,066 lb Myield=My= Sx*Fy = 0.753 in^3 * 42000 psi = 31,626 in -lb Pcr= n^2EI/(KL)max^2 = n^2*29500 ksi/(1.7*82 in)^2 = 16,931 lb (2847 lb/8459 Ib) + (0.85*9602 in-lb)/(18938 in-Ib*0.68) = (2847 lb/14066 lb) + (9602 in-lb/18938 in -lb) = 0.97 < 1.0, OK (EQ C5-1) 0.71 < 1.0, OK (EQ C5-2) NORMED -TYPE I Page 7 of ( 7 7/8/2013 Strjiturai onEis � n V- gineering 1200 N. Jefferson Ste, Ste F Anaheim, CA 92807 Tel: 714.632.7330 Fax: 714.632.7763 By: RPL Project: NORMED Project #: N-062613-4 BEAM Contiguration: TYPE 1 SELECTIVE RACK D/R DETERMINE ALLOWABLE MOMENT CAPACITY A) Check compression flange for local buckling (B2.1) w= c - 2*t -2*r = 1.75 in - 2*0.06 in - 2*0.06 in = 1.510 in w/t= 25.17 1=lambda= [1.052/(k)^0.5] * (w/t) * (Fy/E)^0.5 = [1.052/(4)^0.5] * 25.17 * (42/29500)^0.5 = 0.5 < 0.673, Flange is fully effective B) check web for local buckling per section b2.3 fl(comp)= Fy*(y3/y2)= 38.29 ksi f2(tension)= Fy*(y1/y2)= 77.82 ksi Y= f2/f1 Eq. B2.3-5 = -2.032 k= 4 + 2*(1-Y)^3 + 2*(1-Y) Eq. B2.3-4 = 65.81 flat depth=w= yl+y3 = 3.760 in w/t= 62.66666667 OK 1=lambda= [1.052/(k)^0.51* (w/t) * (f1/E)^0.5 = [1.052/(65.81)^0.5] * 3.76 * (38.29/29500)^0.5 = 0.293 < 0.673 be=w= 3.760 in b2= be/2 b1= be(3-Y) = 1.88 in = 0.747 b1+b2= 2.627 in > 1.24 in, Web is fully effective Determine effect of cold working on steel yield point (Fva) per section A7.2 Fya= C*Fyc + (1-C)*Fy (EQ A7.2-1) Lcomer=Lc= (p/2) * (r + t/2) 0.141 in C= 2*Lc/(Lf+2*Lc) Lflange-top=Lf= 1.510 in = 0.157 in m= 0.192*(Fu/Fy) - 0.068 (EQ A7.2-4) = 0.2290 • Bc= 3.69*(Fu/Fy) - 0.819*(Fu/Fy)^2 - 1.79 = 1.959 since fu/Fv= 1.55 > 1.2 OK and r/t= 1 < 7 OK then Fyc= Bc * Fy/(R/t)^m (EQ A7.2-2) = 82.278 ksi Thus, Fya-top= 48.34 ksi (tension stress at top) Fya-bottom= Fya*Ycg/(depth -Ycg) = 93.83 ksi (tension stress at bottom) Check allowable tension stress for bottom flange Lflange-bot=Lfb= Lbottom - 2*r*-2*t = 2.260 in Cbottom=Cb= 2*Lc/(Lfb+2*Lc) = 0.111 Fy-bottom=Fyb= Cb*Fyc + (1-Cb)*Fyf = 46.47 ksi Fya= (Fya-top)*(Fyb/Fya-bottom) = 23.94 ksi if F= 0.95 Then F*Mn=F*Fya*Sx=I 16.58 in -k Eq. B2.1-4 Eq. B2.1-1 Eq 62.3-2 (EQ A7.2-3) i 4.000 in 2.50 in 1.75 in Beam= StepBeam 4"x2.5"x0.06 " Ix= Sx= Ycg= t= Bend Radius=r= Fy=Fyv= Fu=Fuv= E= top flange=b= bottom flange= Web depth= depth V tt(comp) 1.534 in^4 0.729 in^3 2.640 in 0.060 in 0.060 in 42.00 ksi 65.00 ksi 29500 ksi 1.750 in 2.500 in 4.000 in Fy y3 1 yl Ycg @(tension) yl= Ycg-t-r= 2.520 in y2= depth-Ycg= 1.360 in y3= y2 -t -r= 1.240 in Striurai on is �n gineering 1200 N. Jefferson Ste, Ste F Anaheim, CA 92807 Tel: 714.632.7330 Fax: 714.632.7763 By: RPL Project: NORMED Project #: N-062613-4 BEAM Contiguration: TYPE 1 SELECTIVE RACK D/R RMI Section 5.2, PT II Section Beam= StepBeam 4"x2.5"x0.06 " Ix=Ib= 1.534 in^4 Sx= 0.729 inA3 t= 0.060 in Fy=Fyv= 42 ksi Fu=Fuv= 65 ksi Fya= 48.3 ksi Bending E= 29500 ksi F= 150.0 L= 96 in Mcenter=F*Mn= W*L*W*Rm/8 W=LRFD Load Factor= 1.2*DL + 1.4*PL+1.4*(0.125)*PL RMI 2.2,item 5 FOR DL=2% of PL, W= 1.599 Rm= 1 - [(2*F*L)/(6*E*Ib + 3*F*L)] 1- (2*150*96 in)/[(6*29500 ksi*1.534 in^3)+(3*150*96 in)] = 0.908 if F= 0.95 Then F*Mn=F*Fya*Sx= 33.48 in -k Thus, allowable load per beam pair=W= F*Mn*8*(# of beams)/(L*Rm*W) = 33.48 in -k * 8 * 2/(96in * 0.908 * 1.599) = 3,844 lb/pair Mend= W*L*(1-Rm)/8 = (3844 lb/2) * 96 in * (1-0.908)/8 = 2,122 in -lb Deflection 4.000 in 2.50 in 1.75 in ,l Dmax= Dss*Rd Rd= 1 - (4*F*L)/(5*F*L + 10*E*Ib) = 1 - (4*150*96 in)/[(5*150*96 in)+(10*29500 ksi*1.534 inA4)] = 0.890 in if Dmax= L/180 and Dss= 5*W*L^3/(384*E*Ib) L/180= 5*W*L^3*Rd/(384*E*Ib*# of beams) solving for W yields, W= 384*E*I*2/(180*5*L^2*Rd) = 384*1.534 in^4*2/[180*5*(96 in)^2*0.89) = 4,708 lb/pair Allowable load= 3,844 lb/pair 7 a Z ngineering 1200 N. Jefferson Ste, Ste F Anaheim, CA 92807 Tel: 714.632.7330 Fax: 714.632.7763 By: RPL Project: NORMED Project #: N-062613-4 3 Pin Beam to Column Connection TYPE 1 SELECTIVE RACK D/R I he beam end moments shown herein show the result of the maximum induced fixed end monents form seismic + static loads and the code mandated minimum value of 1.5%(DL+PL) Mconn max= (Mseismic + Mend-fixity)*0.75 = 7,660 in -lb Load at level 1 Shear Capacity of Pin O O P1 1^ P2 2" 11. 2" P3 0 r " 1/2 C X12^ Connector Type= 3 Pin Pin Diam= 0.44 in Fy= 42,000 psi Ashear= (0.438 in)^2 * Pi/4 = 0.1507 in^2 Pshear= 0.4 * Fy * Ashear = 0.4 * 42000 psi * 0.1507in^2 = 2,532 lb Bearing Capacity of Pin tcol= 0.075 in Omega= 2.22 Fu= 65,000 psi a= 2.22 Pbearing= alpha * Fu * diam * tcol/Omega = 2.22 * 65000 psi * 0.438 in * 0.075 in/2.22 = 2,135 lb < 2532 lb Moment Capacity of Bracket Edge Distance=E= 1.00 in Pin Spacing= 2.0 in Fy= 42,000 psi C= P1+P2+P3 tclip= 0.18 in = P1+P1*(2.5"/4.5")+P1*(0.5"/4.5") = 1.667 * P1 Mcap= Sclip * Fbending = 0.127 in^3*0.66*Fy = 3,520 in -lb Pclip= Mcap/(1.667 * d) = 3520.44 in-lb/(1.667 * 0.5 in) = 4,224 lb C*d= Mcap = 1.667 Thus, P1= 2,135 lb Mconn-allow=[P1*4.5"+P1*(2.5"/4.5")*2.5"+P1*(0.5"/4.5")*0.51 = 2135 LB*[4.5"+(2.5"/4.5")*2.5"+ (0.5"/4.5")*0.5') = 12,691 in -lb > Mconn max, OK Sclip= 0.127 in^3 d= E/2 = 0.50 in NORMED -TYPE I Page / of / 1 7/8/2013 Str ' tural oncepts Engineering 1200 N. Jefferson Ste. Ste F Anaheim. CA 92807 Tel: 714.632.7330 Fax: 714.632.7763 By: RPL Project: NORMED Project #: N-062613-4 Transverse Brace Configuration: TYPE 1 SELECTIVE RACK D/R Section Properties Diagonal Member= I -Type 1-1/2x7/8x14ga Area= 0.278 in^2 r min= 0.405 in Fy= 42,000 psi K= 1.0 Qc= 1.92 Frame Dimensions 0.25 in 1 0.575 in i46— 42.0 in —►I Bottom Panel Height=H= 24.0 in Frame Depth=D= 42.0 in Column Width=B= 3.0 in Diagonal Member Clear Depth=D-B*2= 36.0 in X Brace= NO Critical load case RMI Sec 2.1, item 4: (14-0.11Sds)DL + (1 +0.14SDS)PL *0.75+EL *0.75 <= 1.0, ASD Method, DL=PL=0 for upright brace members Vb=Vtransv= 1,128 lb Ldiag= [(D-B*2)^2 + (H-6")^2]^1/2 = 40.2 in Pmax= V*(Ldiag/D) * 0.75 = 810 lb Pn= AREA*Fn = 0.278 inA2 * 27065 psi = 7,524 lb Pallow= Pn/O = 7524 lb /1.92 = 3,919 lb Pn/Pallow= 0.21 <= 1.0 OK (kl/r)= (k * Ldiag)/r min = (1 x 40.2 in /0.405 in ) = 99.3 in Fe= pi^2*E/(kl/r)^2 = 29,527 psi SINCE Fe>Fy/2, Fn= Fy*(1-fy/4fe) = 27,065 psi Typical Panel Configuration Check End Weld Lweld= 2.5 in Fu= 65 ksi tmin= 0.075 in Weld Capacity= 0.75 * tmin * L * Fu/2.5 = 3,656 lb OK NORMED -TYPE I Page / IP-) of ( 7/8/2013 Sttural rLoncepts Engineering 1200 N. Jefferson Ste. Ste F Anaheim. CA 92807 Tel: 714.632.7330 Fax: 714.632.7763 By: RPL Project: NORMED Project #: N-062613-4 Single Row Frame Overturning Configuration: TYPE 1 SELECTIVE RACK D/R Loads Load case per RMI Sec 2.1, item 3: (0.6-0.11Sds)DL + (0.6-0.14Sds)PLapp*0.75 - EL*0.75 Vtrans=V= 1,128 lb DEAD LOAD PER UPRIGHT=DL= 300 lb PL PER UPRIGHT=PL= 9,600 lb PLapp=PL*0.67= 6,432 lb lst=(0.489923*DL+0.459902*PLapp*0.75)= 2,365 lb PL @ TOP= 3,200 lb DL/Lvl= 100 lb E(Fi*hi)= 198,019 in -lb Total Dead Load per Bay=DL= 300 lb Load Case 1: Fully Loaded rack (0.6-0.11Sds)= 0.4899 (0.6-0.14Sds)= 0.4599 Frame Depth=D= 42.0 in Htop-Iv1=H= 180.0 in # Levels= 3 # Anchors/Base= 2 h= 210.0 in hp= 60.0 in I.D-1 SIDE ELEVATION Vtrans= 1,128 lb Movt= E(Fi*hi)*0.75 = 148,514 in -lb Load Case 2: Top Level Loaded Only Mst= Wst * D/2 = 2365 lb * 42 in/2 = 49,665 in -lb T= (Movt-Mst)/D = (148514 in -lb - 49665 in-lb)/42 in = 2,354 lb Net Uplift per column Qtical.Level= 3 V1=Vtop= Cs * Ip * Ws = 0.1676 * (3200 Ib) = 536 lb V2=VDL= Cs*Ip*DL = 50 lb Mst= (0.489923*DL+0.459902*PL*0.75) * D/2 = (100 lb*3 * 0.489923 + 3200 lb*0.459902*0.75)*42 in/2 = 26,266 in -lb Anchor Partially Fixed Base h= 210.0 in Movt= [V1*h + V2 * H/2]*0.75 = [536 lb*210 in +50 lb*180 in/2]*0.75 = 87,795 in -lb T= (Movt-Mst)/D = (87795 in -lb - 26266 in-lb)/42 in = 1,465 lb Net Uplift per column Check (2) 0.5" x 3.25" Embed POWER STUD SD2 anchor(s) per base plate. Special inspection is required per ESR 2502. Pullout Capacity=Tcap= 1,250 lb Shear Capacity=Vcap= 1,856 lb Tcap*Phi= 1,250 lb Vcap*Phi= 1,856 lb (1177 Ib/1250 Ib)^1 + (282 Ib/1856 Ib)^1 = (733 Ib/1250 Ib)^1 + (134 Ib/1856 Ib)^1 = Fully Loaded: Top Level Loaded: L.A. City Jurisdiction? NO Phi= 1 1.09 <= 1.2 OK 0.66 <= 1.2 OK NORMED -TYPE I Page /7 of ( 7 7/8/2013 Str A tural oncepts Engineering 1200 N. Jefferson Ste. Ste F Anaheim. CA92807 Tel: 714 &32.7330 Fax: 714.632.7763 By: RPL Project: NORMED Project #: N-062613-4 Base Plate Configuration: TYPE 1 SELECTIVE RACK D/R Section Baseplate= 8 in x 5 in x 0.375 in Eff Width=W = 6.00 in a = 2.00 in Eff Depth=D = 5.00 in Anchor c.c. =2*a=d = 4.00 in Column Width=b = 3.00 in N=# Anchor/Base= 2 Column Depth=dc = 3.00 in Fy = 36,000 psi L= 1.50 in Plate Thickness=t = 0.375 in Downaisle Elevation Down Aisle Loads Critical load case RMI Sec 2.1, item 4: (1+0.11Sds)DL + (1+0.145D5)PL*0.75+EL*0.75 <= 1.0, ASD Method COLUMN DL= 150 lb COLUMN PL= 4,800 lb Base Moment= 5,000 in -lb 0.11Sds= 0.110077 0.14Sds= 0.140098 Axial=p= (1.110077x150 Ib)+(1.140098*4800 Ib*0.75) = 4,271 lb Mb= Base Moment*0.75 = 5000 in -lb * 0.' = 3,750 in -lb Effec. Effec. E Axial Load P = 4,271 lb Mbase=Mb = 3,750 in -lb Axial stress=fa = P/A = P/(D*W) = 142 psi Moment Stress=fb = M/S = 6*Mb/[(D*B^2] = 125.0 psi Moment Stress=fbl = fb-fb2 = 62.5 psi (1/2)*fb2*L*(2/3)*L = (1/3)*fb2*L^2 47 in -lb (1)(t^2)/6 0.023 inA3/in Mtotal/[(S-plate)(Fb)] 0.44 OK (Mb-(PLapp*0.75*0.46)(a))/[(d)* N/2] -245 lb No Tension Git a/kaadcaseRMtSec2.1, Item 9: (1+allSds)DL+(1#0.19505)AC'0.75+EL'0.75 1.q ASV Method M3 = S -plate = fb/Fb = Tanchor = Cross Aisle Loads M1= Moment Stress=fb2 = M2= Mtotal = Fb = F'p= Tallow= wL^2/2= fa*L^2/2 160 in -lb 2*fb*UW 62.5 psi fb1*L^2)/2 70 in -lb M1+M2+M3 277 in-lb/in 0.75*Fy 27,000 psi 0.7*F'c 1,750 psi OK 1,250 lb OK Check uplift load on Baseplate PF Pstatic= 4,271 lb Movt*0.75= 148,514 in -lb Frame Depth= 42.0 in P=Pstatic+Pseismic= 7,807 lb b =Column Depth= 3.00 in L =Base Plate Depth -Col Depth= 1.50 in fa = P/A = P/(D*W) = 260 psi Sbase/in = (1)(t^2)/6 = 0.023 inA3/in fb/Fb = M/[(S-plate)(Fb)] = 0.46 OK NORMED -TYPE I Pseismic= Movt/Frame Depth = 3,536 lb M= wL^2/2= fa*L^2/2 = 293 in-lb/in Fbase = 0.75*Fy = 27,000 psi Page /2--- f Check uplift forces on baseplate with 2 or more anchors per RMI 7.2.2. hen the base plate configuration consists of two anchor bolls located on either side f the column and a net uplift force edsts, the minimum base plate thickness all be determined based on a design bending moment in the plate equal o the uplift force on one anchor times 1/2 the distance from e centerline of the anchor to the nearest edge of the rack column" T I4 -c► Ta Mu b Elevation Uplift per Column= 2,354 lb Qty Anchor per BP= 2 Net Tension per anchor=Ta= 1,177 lb c= 1.50 in Mu=Moment on Baseplate due to uplift= Ta*c/2 = 883 in -lb Splate= 0.117 inA3 [fb/Fb]*0.75= 0.209 OK 7/8/2013 Str tural oncepts Engineering 1200 N. Jefferson Ste. Ste F Anaheim. CA 92807 Tel: 714.632.7330 Fax: 714.632.7763 By: RPL Project: NORMED Project #: N-062613-4 Slab on Grade Configuration: TYPE 1 SELECTIVE RACK D/R 75 1111111111111111111111111111111111111111111 SLAB ELEVATION Base Plate Effec. Baseplate width=B= 6.00 in Effec. Baseplate Depth=D= 5.00 in Column Loads width=a= 3.00 in depth=b= 3.00 in Baseplate Plan View Concrete fc= 2,500 psi tslab=t= 6.0 in teff= 6.0 in phi=0= 0.6 Soil fsoil= 1,000 psf Movt= 148,514 in -lb Frame depth= 42.0 in Sds= 1.001 0.2*Sds= 0.200 midway dist face of column to edge of plate=c= 4.50 in midway dist face of column to edge of plate=e= 4.00 in DEAD LOAD=DL= 150 lb per column Load Case 1) (1.2+0.2Sds*DL) + (0.85+0.2Sds*PL) + 1.5*EL RMI SEC 2.2 EQTN 5 unfactored ASO load = 1.40014*150 lb + 1.05014*4800 lb + 1.5*3536 lb PRODUCT LOAD=PL= 4,800 lb per column = 10,555 lb unfactored ASD load Load Case 2) (0.9-0.2Sds)DL + (0.9-0.2Sds)*PLapp + 1.5EL RMI SEC 2.2 EQTN 6 P-seismic=EL= (Movt/Frame depth) = (0.69986*150 Ib) + (0.69986*3216 Ib) + (1.5*3536 Ib) = 3,536 lb per column = 7,660 lb unfactored ASD load Load Case 3) 1.2*DL + 1.4*PL RMI SEC 2.2 EQTN 2 = 1.2*150 lb + 1.4*4800 lb = 6,900 lb Effective Column Load=Pu= 10,555 lb per column Puncture Apunct= [(c+t)+(e+t)]*2*t = 246.0 in^2 Slab Bending Fpunct= 2.66*phi*sqrt(fc) = 79.8 psi fv/Fv= Pu/(Apunct*Fpunct) = 0.538 < 1 OK Pse=DL+PL+E= 10,555 lb Asoil= (Pse*144)/(fsoil) = 1,520 in^2 x= (L -y)/2 = 11.4 in Fb= 5*(phi)*(fc)^0.5 = 150. psi L= (Asoil)^0.5 = 38.99 in M= w*x^2/2 = (fsoil*x^2)/(144*2) = 449.1 in -lb y= (c*e)^0.5 + 2*t = 16.2 in S -slab= 1*teff^2/6 = 6.0 in^3 fb/Fb= M/(S-slab*Fb) = 0.499 < 1, OK NORMED -TYPE I Page (3 of ( % 7/8/2013 Structural Concepts Engineering 1200 N. Jefferson Ste. Ste F Anaheim. CA 92807 Tel: 714.632.7330 Fax: 714.632.7763 By: RPL Project: NORMED Project #: N-062613-4 Configuration & Summary: TYPE 2 SELECTIVE RACK D/R 180" Y 54" 10' or 180" 14" 24" 24" 24" 24" 42" 4' 42" **RACK COLUMN REACTIONS ASO LOADS AXIAL DL= 200 /b AXIAL LL= 5,600/b SEISMIC AXIAL Ps=+/- 3,810 lb BASE MOMENT= 0 in -/b Seismic Criteria # Bm Lvls Frame Depth Frame Height # Diagonals Beam Length Frame Type Ss=1.501, Fa=1 4 42 in 180.0 in 6 96 in Single Row Component Description STRESS Column Fy=42 ksi 3x3x14ga P=4350 lb, M=9742 in -lb 0.71-0K Column & Backer None None None N/A Beam Fy=42 ksi StepBeam 4"x2.5"x0.06 " Lu=96 in Capacity: 3844 lb/pr 0.73-0K Beam Connector Fy=42 ksi Lvl 1: 3 pin OK I Mconn=6771 in -lb Mcap=12691 in -lb 0.53-0K Brace -Diagonal Fy=42 ksi I -Type 1-1/2x1-1/4x14ga 0.24-0K Base Plate Fy=36 ksi 8 in x 5 in x 0.375 in I Fixity= 0 in -lb 0.8-0K Anchor 2 per Base 0.5" x 3.25" Embed POWER STUD SD2 ESR 2502 Inspection Reqd (Net Seismic Uplift=2419 lb) 0.958 - OK Slab & Soil 6" thk x 2500 psi slab on grade. 1000 psf Soil Bearing Pressure 0.6-0K Level Load Per Level Beam Spcg Brace Story Force Transv Story Force Longit. Column Axial _ Column Moment Conn. Moment Beam Connector 1 2,800 lb 10.0 in 24.0 in 36 lb 20 lb 5,800 lb 2,597 "# 6,771 "# 3 pin OK 2 2,800 lb 3 2,800 lb 4 2,800 lb 54.0 in 54.0 in 54.0 in 24.0 in 24.0 in 24.0 in 24.0 in 14.0 in 233 lb 430 lb 626 lb 131 lb 241 lb 351 lb 4,350 lb 2,900 lb 1,450 lb 9,742 "# 7,980 "# 4,733 "# 8,790 "# 6,912 "# 3,919 "# 3 pin OK 3 pin OK 3 pin OK Notes Total: 1,325 lb 742 lb NORM ED -TYPE 2 Page f 9 of ( 7 7/5/2013 Structural Concepts Engineering 1200 N. Jefferson Ste. Ste F Anaheim. CA 92807 Tel: 714.632.7330 Fax: 714.632.7763 By: RPL Project: NORMED Project ft: N.062613-4 Configuration & Summary: TYPE 3 SELECTIVE RACK D/R -94" & 96" BAY 180" 42" 42" 42" 42" 10" * -I- 180" 14" 24" 24" 24" 24" 24" 42" 42" �( **RACK COLUMN REACTIONS ASD LOADS AXIAL DL= 250 /b AXIAL LL= 5,500 /b SEISMIC AXIAL Ps= +/- 3,804 lb BASE MOMENT= 0 in -lb Seismic Criteria # Bm Lvls Frame Depth Frame Height # Diagonals Beam Length Frame Type Ss=1.501, Fa=1 5 42 in 180.0 in 6 96 in Single Row Component Description STRESS Column Fy=42 ksi 3x3x14ga P=4600 lb, M=7595 in -lb 0.6 -OK Column & Backer None None None N/A Beam Fy=42 ksi StepBeam 4"x2.5"x0.06 " Lu=96 in Capacity: 3844 lb/pr 0.57 -OK Beam Connector Fy=42 ksi Lvi 1: 3 pin OK ( Mconn=5513 in -lb Mcap=12691 in -lb 0.43 -OK Brace -Diagonal Fy=42 ksi I -Type 1-1/2x1-1/4x14ga 0.24 -OK Base Plate Fy=36 ksi 8 in x 5 in x 0.375 in Fixity= 0 in -lb 0.52 -OK Anchor 2 per Base 0.5" x 3.25" Embed POWER STUD SD2 ESR 2502 Inspection Reqd (Net Seismic Uplift=2411 Ib) 0.95 - OK Slab & Soil 6" thk x 2500 psi slab on grade. 1000 psf Soil Bearing Pressure 0.6 -OK Level Load Per Level Beam Spcg Brace Story Force Transv Story Force Longit. Column Axial Column Moment Conn. Moment Beam Connector 1 2,200 lb 10.0 in 24.0 in 28 lb 16 lb 5,750 lb 2,587 "# 5,513 "# 3 pin OK 2 3 4 5 2,200 lb 2,200 lb 2,200 lb 2,200 lb 42.0 in 42.0 in 42.0 in 42.0 in 24.0 in 24.0 in 24.0 in 24.0 in 14.0 in 146 lb 264 lb 382 lb 500 lb 82 lb 148 lb 214 lb 280 lb 4,600 lb 3,450 lb 2,300 lb 1,150 lb 7,595 "# 6,736 "# 5,184 "# 2,939 "# 7,069 "# 6,165 "# 4,741 "# 2,797 "# 3 pin OK 3 pin OK 3 pin OK 3 pin OK Notes Total: 1,319 lb 739 lb BAY 94" IS OK BY INSPECTION. NORMED -TYPE 3 Page f: of /7 7/8/2013 Structural Concepts Engineering 1200 N. Jefferson Ste. Ste F Anaheim. CA 92807 Tel: 714.632.7330 Fax: 714.632.7763 By: RPL Project: NORMED Project #: 14-062613-4 Configuration & Summary: TYPE 4 SELECTIVE RACK D/R -TUNNEL BAY 96" 180" 14" 24" 24" 24" 24" 24" 42' 4 42" 4 **RACK COLUMN REACTIONS ASD LOADS AXIAL DL= 250 /b AXIAL LL= 4,650 /b SEISMIC AXIAL Ps=+/- 3,302 /b BASE MOMENT= 0 in -lb Seismic Criteria # Bm Lvls Frame Depth Frame Height # Diagonals Beam Length Frame Type Ss=1.501, Fa=1 5 42 in 180.0 in 6 96 in Single Row Component Description STRESS Column Fy=42 ksi 3x3x14ga P=4300 lb, M=6559 in -lb 0.54-0K Column & Backer None None None N/A Beam Fy=42 ksi StepBeam 4"x2.5"x0.06 " Lu=96 in Capacity: 3844 lb/pr 0.78-0K Beam Connector Fy=42 ksi Lvi 4: 3 pin OK I Mconn=4868 in -lb Mcap=12691 in -lb 0.38-0K Brace -Diagonal Fy=42 ksi I -Type 1-1/2x1-1/4x14ga 0.21-0K Base Plate Fy=36 ksi 8 in x 5 in x 0.375 in I Fixity= 0 in -lb 0.45-0K Anchor 2 per Base 0.5" x 3.25" Embed POWER STUD SD2 ESR 2502 Inspection Reqd (Net Seismic Uplift=2105 Ib) 0.825 - OK Slab & Soil 6" thk x 2500 psi slab on grade. 1000 psf Soil Bearing Pressure 0.52-0K Level Load Per Level Beam Spcg Brace Story Force Transv Story Force Longit. Column Axial Column Moment Conn. Moment Beam Connector 4 3,000 lb 18.0 in 24.0 in 367 lb 206 lb 3,100 lb 2,332 "# 4,868 "# 3 pin OK 5 3,000 lb 58.0 in 24.0 in 558 lb 312 lb 1,550 lb 4,531 "# 3,993 "# 3 pin OK 14.0 in Total: 1,128 lb 632 lb Notes NORMED -TYPE 4- TUNNEL BAY Page (o of ! 7 7/8/2013 Structural Concepts Engineering 1200 N. Jefferson Ste. Ste F Anaheim. CA 92807 Tel: 714.632.7330 Fax: 714.632.7763 By: RPL Project: NORM ED Project #: N-062613-4 Configuration & Summary: TYPE 5 SELECTIVE RACK D/R 180" T 68" 100" 96" 180" N 14" 24" 24" 4- 24" 24" 42" 44— 42" 4 **RACK COLUMN REACTIONS ASD LOADS AXIAL DL= 100 /b AXIAL LL= 3,600/b SEISMIC AXIAL Ps= -F/- 2,595 lb BASE MOMENT= 0 in -lb Seismic Criteria # Bm Lvls Frame Depth Frame Height # Diagonals Beam Length Frame Type Ss=1.501, Fa=1 2 42 in 180.0 in 6 96 in Single Row Component Description STRESS Column Fy=42 ksi Mecalux U80 P=3700 lb, M=22892 in -lb 0.62-0K Column & Backer None None None N/A Beam Fy=42 ksi StepBeam 4"x2.5"x0.06 " Lu=96 in Capacity: 3844 lb/pr 0.94-0K Beam Connector Fy=42 ksi Lvl 2: 3 pin OK 1 Mconn=4630 in -lb Mcap=12691 in -lb 0.36-0K Brace -Diagonal Fy=42 ksi I -Type 1-1/2x1-1/4x14ga 0.16 -OK Base Plate Fy=36 ksi 8 in x 5 in x 0.375 in Fixity= 0 in -lb 0.3-0K Anchor 2 per Base 0.5" x 3.25" Embed POWER STUD SD2 ESR 2502 Inspection Reqd (Net Seismic Uplift=1715 Ib) 0.667 - OK Slab & Soil 6" thk x 2500 psi slab on grade. 1000 psf Soil Bearing Pressure 0.42-0K Level Load Per Level Beam Spcg Brace Story Force Transv Story Force Longit. Column Axial Column Moment Conn. Moment Beam Connector 1 3,600 lb 100.0 in 24.0 in 314 lb 176 lb 3,700 lb 22,892 "# 13,214 "# 3 pin NG 2 3,600 lb 68.0 in 24.0 in 24.0 in 24.0 in 24.0 in 14.0 in 528 lb 296 lb 1,850 lb 5,030 "# 4,630 "# 3 pin OK Total: 842 lb 472 lb Notes BEAM @ LVL 1 WITH 4 PINS. NORMED -TYPE 5 Page / 7of 7/8/201.3 Sttura) rLoncepts Engineering 1200 N. Jefferson Ste. Ste F Anaheim. CA 92807 Tel: 714.632.7330 Fax: 714.632.7763 By: RPL Project: NORMED Project #: N-062613-4 Configuration & Summary: TYPE 6 SELECTIVE RACK D/R 180" 68" 24" 23" 23" 10" 96" 14" 24" 24" 180" .I 24" 24" 24" 42" " -I-42" —f **RACK COLUMN REACTIONS ASO LOADS AXIAL DL= 250 /b . AXIAL LL= 5,250 /b SEISMIC AXIAL Ps=+/- 3,121 lb BASE MOMENT= 0 in -lb Seismic Criteria # Bm Lvls Frame Depth Frame Height # Diagonals Beam Length Frame Type Ss=1.501, Fa=1 5 42 in 180.0 in 6 96 in Single Row Component Description STRESS Column Fy=42 ksi 3x3x14ga P=4700 lb, M=3907 in -lb 0.44-0K Column & Backer None None None N/A Beam Fy=42 ksi StepBeam 4"x2.5"x0.06 " Lu=96 in Capacity: 3844 lb/pr 0.78-0K Beam Connector Fy=42 ksi Lvl 4: 3 pin OK I Mconn=5988 in -lb Mcap=12691 in -lb 0.47 -OK Brace -Diagonal Fy=42 ksi I -Type 1-1/2x1-1/4x14ga 0.23 -OK Base Plate Fy=36 ksi 8 in x 5 in x 0.375 in Fixity= 0 in -lb 0.47-0K Anchor 2 per Base 0.5" x 3.25" Embed POWER STUD SD2 ESR 2502 Inspection Reqd (Net Seismic Uplift=1786 Ib) 0.733 - OK Slab & Soil 6" thk x 2500 psi slab on grade. 1000 psf Soil Bearing Pressure 0.54-0K Level Load Per Level Beam Spcg Brace Story Force Transv Story Force Longit. Column Axial Column Moment Conn. Moment Beam Connector 1 1,500 lb 10.0 in 24.0 in 24 lb 13 lb 5,500 lb 2,478 "# 3,542 "# 3 pin OK 2 3 4 5 1,500 lb 1,500 lb 3,000 lb 3,000 lb 22.5 in 22.5 in 24.0 in 68.0 in 24.0 in 24.0 in 24.0 in 24.0 in 14.0 in 78 lb 131 lb 360 lb 670 lb 44 lb 74 lb 202 lb 376 lb 4,700 lb 3,900 lb 3,100 lb 1,550 lb 3,907 "# 3,662 "# 3,465 "# 6,385 "# 3,986 "# 3,820 "# 5,988 "# 4,689 "# 3 pin OK 3 pin OK 3 pin OK 3 pin OK Total: 1,263 lb 708 lb Notes I BEAM 2.5"DEEPx16GA. @ LVL 1-3 & BEAM 4"DEEPx16GA @LVL 4-5. NORMED -TYPE 6 Page a0 of / 7/8/20 13 Structural Concepts Engineering 1200 N. Jefferson Ste. Ste F Anaheim. CA 92807 Tel: 714.632.7330 Fax: 714.632.7763 By: RPL Project: NORMED Project #: N-062613-4 Configuration & Summary: TYPE 7 SELECTIVE RACK D/R 180" 68" .l 18" 17" 17" 17" s6 180" 14" 24" 24" 24" 4- 24" 24" 42" —,/". 42" **RACK COLUMN REACTIONS ASD LOADS AXIAL DL= 300 /b AXIAL LL= 6,200 /b SEISMIC AXIAL Ps=+/- 3,564 /b BASE MOMENT= 0 in -lb Seismic Criteria # Bm Lvls Frame Depth Frame Height # Diagonals Beam Length Frame Type Ss=1.501, Fa=1 6 42 in 180.0 in 6 96 in Single Row Component Description STRESS Column Fy=42 ksi 3x3x14ga P=6500 Ib, M=2926 in -lb 0.52-0K Column & Backer None None None N/A Beam Fy=42 ksi StepBeam 4"x2.5"x0.06 " Lu=96 in Capacity: 3844 lb/pr 0.83-0K Beam Connector Fy=42 ksi Lvi 5: 3 pin OK ( Mconn=6185 in -lb Mcap=12691 in -lb 0.49-0K Brace -Diagonal Fy=42 ksi I -Type 1-1/2x1-1/4x14ga 0.27-0K Base Plate Fy=36 ksi 8 in x 5 in x 0.375 in ( Fixity= 0 in -lb 0.55-0K Anchor 2 per Base 0.5" x 3.25" Embed POWER STUD SD2 ESR 2502 Inspection Reqd (Net Seismic Uplift=1985 Ib) 0.833 - OK Slab & Soil 6" thk x 2500 psi slab on grade. 1000 psf Soil Bearing Pressure 0.64-0K Level Load Per Level Beam Spcg Brace Story Force Transv Story Force Longit. Column Axial Column Moment Conn. Moment Beam Connector 1 1,500 lb 10.0 in 24.0 in 25 lb 14 lb 6,500 lb 2,926 "# 3,515 "# 3 pin OK 2 1,500 lb 3 1,500 lb 4 1,500 lb 5 3,200 lb 6 3,200 lb 16.5 in 16.5 in 16.5 in 18.0 in 68.0 in 24.0 in 24.0 in 24.0 in 24.0 in 14.0 in 67 lb 109 lb 150 lb 397 lb 745 lb 37 lb 61 lb 84 lb 222 lb 417 lb 5,700 lb 4,900 lb 4,100 lb 3,300 lb 1,650 lb 3,390 "# 3,236 "# 2,986 "# 2,879 "# 7,098 "# 3,631 "# 3,479 "# 3,345 "# 6,185 "# 5,106 "# 3 pin OK 3 pin OK 3 pin OK 3 pin OK 3 pin OK Total: 1,493 lb 836 lb Notes BEAM 2.5"DEEPx16GA. @ LVL 1-4 & BEAM 4"DEEPx16GA @LVL 5-6. NORMED -TYPE 7 Page / Cif of 7/8/2013 NorMed stocks flammable material in a N.F.P.A. Code 30 OSHA rated 30 gallon fire cabinet inside the Silk Screen Room. Items inside the fire cabinet are: paints, promoter, Retardar, Screen wash and paint thinner. REVIEWED FOR CODE COMPLIANCE APPROVED AUG 21 2013 City of Tukwila BUILDING DIVISION X13-Z3�r ,- `FILE c v Pelma°& P RECEIVED CITY OF TUKWILA JUL 122013 PERMIT CENTER Material Safety Data Sheet Prepared in accordance with ISO 11014-1/ANSI standard Z400.1-2004 Print Date May -07-2012 Product code Product name Product category Manufacturer or supplier's details UNITED STATES Nazdar Company 8501 Hedge Lane Terrace Shawnee, KS 66227 Tel: 1-913-422-1888 Tel: 1-800-677-4657 Fax: 1-913-422-2294 59440 Process Blue 59000 Series Enamel Plus Gloss Screen Ink UNITED KINGDOM Nazdar Limited 7 Barton Road Heaton Mersey Industrial Estate Stockport, Cheshire SK4 3EG Tel: +44 161 442 2111 Revision Date May -07-2012 Emergency Telephone Number USA: Chemtrec: 1-800-424-9300 Outside USA: Chemtrec: 1-703-527-3887 Website: www.nazdar.com MSDS Information: 1-913-422-1888 ext 2305 MSDS Contact: Regulatory Compliance email: regcomp@nazdar.com This product is a preparation. Health hazard information is based on its components. Appearance Flammable Properties Emergency Overview Eyes Skin Inhalation Ingestion Colored liquid Combustible liquid and vapor. Aspiration hazard. Harmful: may cause lung damage if swallowed. Irritant. May cause drowsiness and dizziness. May cause eye irritation. May cause skin irritation and/or dermatitis. May cause irritation of respiratory tract. Inhalation of high vapour concentrations may cause symptoms like headache, dizziness, tiredness, nausea and vomiting. Harmful if swallowed. Potential for aspiration if swallowed. Risk of serious damage to the lungs (by aspiration). Component CAS -No Weight % Stoddard solvent 8052-41-3 10 - 30 Barium sulfate 7727-43-7 10 - 30 Titanium dioxide 13463-67-7 5 - 10 Solvent naphtha (petroleum), medium aliphatic 64742-88-7 1 - 5 Xylenes (o-, m-, p- isomers) 1330-20-7 1 - 5 Copper Phthalocyanine Compound Trade Secret 1 - 5 Ethyl benzene (contaminant) 100-41-4 < 0.5 Crystalline silica (cristobalite) 14464-46-1 < 0.5 • Component names which have the word (contaminant) are constituents contained in Aromatic Hydrocarbon ingredients and are an integral part of the ingredient and cannot be separated. The percentage listed for the contaminant is as contained in the Hydrocarbon ingredient. (Example: 100% Hydrocarbon, 10% Contaminant A, 3% Contaminant B) Eye Contact Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get medical attention immediately if irritation develops and persists. RECEIVED CITY OF TUKWILA JUL 12 2013 b‘)34 -r3 Page 1 / 7 PERMIT CENTER Product code 59440 - Process Blue Revision Date May -07-2012 Skin Contact Inhalation Ingestion AMP Wash off immediately with soap and plenty of water. Use a mild soap if available. Rinse immediately with plenty of water for at least 15 minutes. Remove contaminated clothing. If irritation develops, get medical attention. If breathed in, move person into fresh air. If breathing is irregular or stopped, administer artificial respiration. Get medical attention immediately. If swallowed, DO NOT induce vomiting. Call a physician or Poison Control Centre immediately. Never give anything by mouth to an unconscious person. m e. a +x,'.€14 v.. r r r x ;� c, r{r �iv.:x+tt srr.� at x 5, f IRE FIGHTING' :MEASURES 6Wr y}, r.1Li.•�. N Flammable Properties Suitable Extinguishing Media Protective Equipment and Precautions for Firefighters Specific Hazards Arising from the Chemical Combustible liquid and vapor. Foam. Carbon dioxide (CO2). Dry chemical. Water spray. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. As in any fire, wear self-contained breathing apparatus pressure -demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Keep away from fire, sparks and heated surfaces. Cool containers / tanks with water spray. Fire or intense heat may cause violent rupture of packages. Thermal decomposition can lead to release of irritating gases and vapours. Burning produces obnoxious and toxic fumes. AC -ID EN - 'RELEASE'MEASUR! Personal Precautions Methods for Cleaning Up Environmental Precautions Remove all sources of ignition. Ventilate the area. Avoid breathing dust or vapor. Avoid contact with skin, eyes and clothing. Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13). Do not use sparking tools. Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. Handling Storage 3It AND ILSTORA9 Avoid contact with skin, eyes and clothing. Ensure adequate ventilation. Remove and wash contaminated clothing before re -use. Discard contaminated shoes. When using do not smoke. Do not take internally. Harmful or fatal if swallowed. Take notice of the directions of use on the label. Keep containers tightly closed in a dry, cool and well -ventilated place. Keep container closed when not in use. Keep out of the reach of children. Keep away from heat and sources of ignition. ONa,.TI�Om L S(PES©N•..c. ALen. N Exposure Guidelines Component I ACGIH TLV OSHA PEL I NIOSH IDLH I Ontario TWAEV [ Mexico OEL (TWA) 7 Product code 59440 - Process Blue Revision Date May -07-2012 Stoddard solvent TWA: 100 ppm TWA: 100 ppm TWA: 525 mg/m3 TWA: 500 ppm TWA: 2900 mg/m3 20000 mg/m3 TWA: 525 mg/m3 TWA/LMPE-PPT: 100 ppm TWA/LMPE-PPT: 523 mg/m3 STEULMPE-CT: 200 ppm STEULMPE-CT: 1050 mg/m3 Barium sulfate TWA: 10 mg/m3 TWA: 10 mg/m3 (total dust) TWA: 5 mg/m3 (respirable fraction) TWA: 15 mg/m3 (total , dust) TWA: 10 mg/m3 (total dust) Titanium dioxide TWA: 10 mg/m3 TWA: 10 mg/m3 (total dust) TWA: 15 mg/m3 (total dust) 5000 mg/m3 TWA: 10 mg/m3 (total dust) TWA/LMPE-PPT: 10 mg/m3 (as Ti) STEULMPE-CT: 20 mg/m3 (as Ti) Solvent naphtha (petroleum), medium aliphatic TWA: 525 mg/m3 Xylenes (o-, m-, p- isomers) TWA: 100 ppm STEL: 150 ppm TWA: 100 ppm TWA: 435 mg/m3 STEL: 150 ppm STEL: 655 mg/m3 TWA: 100 ppm STEL: 150 ppm TWA/LMPE-PPT: 100 ppm TWA/LMPE-PPT: 435 mg/m3 STEULMPE-CT: 150 ppm STEULMPE-CT: 655 mg/m3 Ethyl benzene (contaminant) TWA: 20 ppm TWA: 100 ppm TWA: 435 mg/m3 STEL: 125 ppm STEL: 545 mg/m3 800 ppm (10% LEL) TWA: 100 ppm STEL: 125 ppm TWA/LMPE-PPT: 100 ppm TWA/LMPE-PPT: 435 mg/m3 STEULMPE-CT: 125 ppm STEULMPE-CT: 545 mg/m3 Crystalline silica (cristobalite) TWA: 0.025 mg/m3 (respirable fraction) TWA: 0.05 mg/m3 (respirable dust) 25 mg/m3 TWA: 0.05 mg/m3 (respirable) TWA/LMPE-PPT: 0.05 mg/m3 (respirable fraction) Engineering Measures Personal Protective Equipment Respiratory Protection Eye Protection Skin Protection General Hygiene Considerations Use ventilation adequate to keep exposures below recommended exposure limits. See MSDS. In case of insufficient ventilation, wear suitable respiratory equipment. Use the indicated respiratory protection if the occupational exposure limit is exceeded and/or in case of product release (dust). Respirator with a vapour filter. Ensure that eyewash stations and safety showers are close to the workstation location. Avoid contact with eyes. Safety glasses with side -shields. Goggles. Face -shield. Wear protective gloves/clothing. Solvent -resistant apron and boots. Handle in accordance with good industrial hygiene and safety practice. Wash hands before eating, drinking, or smoking. Remove and wash contaminated clothing before re -use. Avoid contact with skin, eyes and clothing. Wear suitable gloves and eye/face protection. Regular cleaning of equipment, work area and clothing is recommended. Appearance Odor pH Boiling point/Boiling Range Freezing Point/Range Evaporation Rate Vapour Pressure Flammability (solid, gas) Colored liquid Characteristic No information available >149 °C / >300 °F No information available No information available No information available No information available Om •r e•.:•..: �r HEiV1ICALPPERTIES„;�'t>,;;: Physical State Odor Threshold Autoignition Temperature Melting Point/Range Solubility Partition Coefficient (n-octanol/water) Vapour Density Liquid No information available No information available No information available No information available No information available Heavier than air Page 3 / 7 Product code 59440 - Process Blue Revision Date May -07-2012 Flash Point 46 °C/ 115 °F Method Setaflash closed cup Weight Per Gallon (lbs/gal) 9.88 VOC by weight % 30.76 VOC lbs/gal (less water) 3.04 Chemical Stability Conditions to Avoid Incompatible Products Flammability Limits in Air Upper No information available Lower No information available Photochemically Reactive No Specific Gravity 1.19 VOC by volume % No information available VOC grams/liter (less water) 364.36 , Stable under normal conditions. Heat, flames and sparks. Strong acids. Strong bases. Strong oxidizing agents. Reducing agents. Hazardous Decomposition Products Thermal decomposition can lead to release of irritating gases and vapours. Carbon dioxide (CO2). Carbon monoxide. Possibility of Hazardous Reactions None under normal processing. 14, r,1;NOXI.C;;OLOGICAL};INFORMATION„'; , Acute Toxicity Component LD50 Oral LD50 Dermal LC50 Inhalation Titanium dioxide >10000 mg/kg ( Rat ) Group 28 Solvent naphtha (petroleum), medium aliphatic >5000 mg/kg ( Rat) 3000 mg/kg ( Rabbit) >5.26 mg/L ( Rat) 4 h Xylenes (o-, m-, p- isomers) 4300 mg/kg ( Rat) >1700 mg/kg ( Rabbit) 5000 ppm ( Rat) 4 h 47635 mg/L ( Rat) 4 h Ethyl benzene (contaminant) 3500 mg/kg ( Rat) 15354 mg/kg ( Rabbit) 17.2 mg/L ( Rat) 4 h Chronic Toxicity Component ACGIH IARC NTP OSHA Titanium dioxide Group 28 X Ethyl benzene (contaminant) A3 Group 2B X Crystalline silica (cristobalite) Group 1 X ACG/H: (American Conference of Governmental Industrial Hygienists) IARC: (international Agency for Research on Cancer) OSHA: (Occupational Safety & Health Administration) A3 - Animal Carcinogen Group 1 - Carcinogenic to Humans Group 28 - Possibly Carcinogenic to Humans X - Present Sensitisation No information available Mutagenic Effects No information available Reproductive Effects No information available Developmental hazard No information available Teratogenicity No information available Chronic Effects Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may result in adverse health effect, such as mucous membrane and respiratory system irritation and adverse effect on kidney, liver and central nervous system. Target Organ Effects Central nervous system, Eyes, Kidney, Liver, Respiratory system, Skin. Page 4/7 4 Product code 59440 - Process Blue Revision Date May -07-2012 Ecotoxicity We have no quantitative data concerning the ecological effects of this product. Should not be released into the environment. Component Algae Fish Water Flea Solvent naphtha (petroleum), medium aliphatic 96h EC50 Pseudokirchneriella subcapitata: 450 mg/L 96h LC50 Pimephales promelas: 800 mg/L [static] 48h EC50 Daphnia magna: >100 mg/L Xylenes (o-, m-, p- isomers) • 96h LC50 Lepomis macrochirus: 13.1 - 16.5 mg/L [flow-through] 96h LC50 Oncorhynchus mykiss: 13.5 - 17.3 mg/L 96h LC50 Oncorhynchus mykiss: 2.661 - 4.093 mg/L [static] 96h LC50 Pimephales promelas: 23.53 - 29.97 mg/L [static] 96h LC50 Poecilia reticulata: 30.26 - 40.75 mg/L [static] 96h LC50 Lepomis macrochirus: 7.711 - 9.591 mg/L [static] 96h LC50 Pimephales promelas: 13.4 mg/L [flow-through] 96h LC50 Lepomis macrochirus: 19 mg/L 96h LC50 Cyprinus carpio: 780 mg/L [semi -static] 96h LC50 Cyprinus carpio: >780 mg/L 48h LC50 Gammarus lacustris: 0.6 mg/L 48h EC50 water flea: 3.82 mg/L Copper Phthalocyanine Compound 48h LC50 Oryzias latipes: >100 mg/L [static] Ethyl benzene (contaminant) 96h EC50 Pseudokirchneriella subcapitata: 1.7 - 7.6 mg/L [static] 72h EC50 Pseudokirchneriella subcapitata: 2.6 - 11.3 mg/L [static] 72h EC50 Pseudokirchneriella subcapitata: 4.6 mg/L 96h EC50 Pseudokirchneriella subcapitata: >438 mg/L 96h LC50 Oncorhynchus mykiss: 11.0 - 18.0 mg/L [static] 96h LC50 Pimephales promelas: 7.55 - 11 mg/L [flow-through] 96h LC50 Pimephales promelas: 9.1 - 15.6 mg/L [static] 96h LC50 Lepomis macrochirus: 32 mg/L [static] 96h LC50 Oncorhynchus mykiss: 4.2 mg/L [semi -static] 96h LC50 Poecilia reticulata: 9.6 mg/L [static] 48h EC50 Daphnia magna: 1.8 - 2.4 mg/L Persistence and Degradab lity No information available Bioaccumulation No information available Mobility in Environmental Media No information available Component log Pow Xylenes (o-, m-, p- isomers) 2.96 Copper Phthalocyanine Compound 6.6 Ethyl benzene (contaminant) 3.118 13r `QISP OSk1LONSiDERATI Waste Disposal Methods Dispose of contents/container in accordance with local regulation. Contaminated Packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. ���TRANSP"ORT�,�NFORINA7'ION�"; `t DOT Page 5/7 Product code 59440 - Process Blue Revision Date May -07-2012 UN1210, Printing Ink, 3, III In the U.S. and Canada, this material may be reclassified as a combustible liquid and is not regulated, via surface transportation, in containers less than 119 gallons or 450 liters [per 49 CFR 173.150 (f)] [per Transportation of Dangerous Goods Regulations/Clear Language Part 1.33]. ICAO/IATA UN1210, Printing Ink, 3, III IMDG/IMO UN1210, Printing Ink, 3, III r ne�ast•y; �, :•/xrn 1�s.,a:�,(�'.y„r-.Rn�trr. ",...ewt3•,:f�i` �REGULAT;QRY�IAIFO,RMATION� International Inventories Listed on TSCA. For further information, please contact: Manufacturer, importer, supplier U.S. Federal Regulations SARA 313 The following components are subject to reporting I Component CAS -No Weight g SARA 313 -Threshold 1330-20-7 1 - 5 X Values Ethyl benzene (contaminant) 100-41-4 < 0.5 0.1 Xylenes (o-, m-, p- isomers) 1330-20-7 1 - 5 1.0 Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) Component CAS -No Weight % Xylenes (o-, m-, p- isomers) 1330-20-7 1 - 5 U.S. State Regulations Component Massachusetts Right To Know Minnesota Right To Know New Jersey Right To Know Pennsylvania Right To Know Stoddard solvent X X X X Barium sulfate X X X X Titanium dioxide X X X X Solvent naphtha (petroleum), medium aliphatic Not Listed Not Listed X Not Listed Xylenes (o-, m-, p- isomers) X X X X Copper Phthalocyanine Compound Not Listed Not Listed X X Ethyl benzene (contaminant) X X X X Crystalline silica (cristobalite) X X X X California Prop. 65 WARNING! This product contains a chemical known in the State of California to cause cancer and / or WARNING! This product contains a chemical known in the State of California to cause birth defects or other reproductive harm Component CAS -No Weight % Ethyl benzene (contaminant) 100-41-4 < 0.5 Titanium dioxide 13463-67-7 5 - 10 Canada This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the information required by the CPR Component WHMIS Classifications of Components Stoddard solvent B3,D2B Barium sulfate Uncontrolled product according to WHMIS classification criteria Titanium dioxide D2A Solvent naphtha (petroleum), medium aliphatic B3 Xylenes (0-, m-, p- isomers) B2,D2A,D2B Copper Phthalocyanine Compound Uncontrolled product according to WHMIS classification criteria Ethyl benzene (contaminant) B2,D2A,D2B Page 617 Product code 59440 - Process Blue Revision Date May -07-2012 (Crystalline silica (cristobalite) D2A Component NPRI - National Pollutant Release Inventory Stoddard solvent Part 5 Substance Part 5, Other Groups and Mixtures Solvent naphtha (petroleum), medium aliphatic Part 5 Substance Part 5, Other Groups and Mixtures Xylenes (o-, m-, p- isomers) Part 1, Group 1 Substance Part 5 Substance Part 5, Isomer Groups Copper Phthalocyanine Compound Part 1, Group 1 Substance Ethyl benzene (contaminant) Part 4 Substance Part 1, Group 1 Substance Regulation (EC) No. 1907/2006 (REACH), Article 57 None known HMIS: Health 1* Flammability 2 Reactivity 0 PPE X Revision Date Revision Note May -07-2012 New MSDS format Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text End of MSDS Page 7 /7 Material Safety Data Sheet Prepared in accordance with ISO 11014-1/ANSI standard Z400.1-2004 Print Date May -07-2012 Revision Date May -07-2012 7Sv Product code Product name Product category Manufacturer or supplier's details UNITED STATES Nazdar Company 8501 Hedge Lane Terrace Shawnee, KS 66227 Tel: 1-913-422-1888 Tel: 1-800-677-4657 Fax: 1-913-422-2294 59204 Bright Red 59000 Series Enamel Plus Gloss Screen Ink UNITED KINGDOM Nazdar Limited 7 Barton Road Heaton Mersey Industrial Estate Stockport, Cheshire SK4 3EG Tel: +44 161 442 2111 Emergency Telephone Number USA: Chemtrec: 1-800-424-9300 Outside USA: Chemtrec: 1-703-527-3887 Website: www.nazdar.com MSDS Information: 1-913-422-1888 ext 2305 MSDS Contact: Regulatory Compliance email: regcomp@nazdar.com I1:0 C . This product is a preparation. Health hazard information is based on its components. Appearance Flammable Properties Emergency Overview Eyes Skin Inhalation Ingestion Colored liquid Combustible liquid and vapor. Aspiration hazard. Harmful: may cause lung damage if swallowed. Irritant. May cause drowsiness and dizziness. May cause eye irritation. May cause skin irritation and/or dermatitis. May cause irritation of respiratory tract. Inhalation of high vapour concentrations may cause symptoms like headache, dizziness, tiredness, nausea and vomiting. Harmful if swallowed. Potential for aspiration if swallowed. Risk of serious damage to the lungs (by aspiration). ,tw Component CAS -No Weight % Stoddard solvent 8052-41-3 10 - 30 Limestone 1317-65-3 10 - 30 Naphtha (petroleum), heavy aromatic 64742-94-5 1 - 5 Solvent naphtha (petroleum), medium aliphatic 64742-88-7 1 - 5 Xylenes (o-, m-, p- isomers) 1330-20-7 1 - 5 Ethyl benzene (contaminant) 100-41-4 < 0.5 Naphthalene (contaminant) 91-20-3 < 0.5 • Component names which have the word (contaminant) are constituents contained in Aromatic Hydrocarbon ingredients and are an integral part of the ingredient and cannot be separated. The percentage listed for the contaminant is as contained in the Hydrocarbon ingredient. (Example.- 100% Hydrocarbon, 10% Contaminant A, 3% Contaminant B) Eye Contact Skin Contact Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get medical attention immediately if irritation develops and persists. Wash off immediately with soap and plenty of water. Use a mild soap if available. Rinse immediately with plenty of water for at least 15 minutes. Remove contaminated clothing. If irritation develops, get medical attention. RECEIVED CITY OF TUKWILA eifteage 1 1, JUL 122013 PERMIT CENTER Product code 59204 - Bright Red Revision Date May -07-2012 Inhalation Ingestion If breathed in, move person into fresh air. If breathing is irregular or stopped, administer artificial respiration. Get medical attention immediately. If swallowed, DO NOT induce vomiting. Call a physician or Poison Control Centre immediately. Never give anything by mouth to an unconscious person. Flammable Properties Suitable Extinguishing Media Protective Equipment and Precautions for Firefighters Specific Hazards Arising from the Chemical Combustible liquid and vapor. Foam. Carbon dioxide (CO2). Dry chemical. Water spray. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. As in any fire, wear self-contained breathing apparatus pressure -demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Keep away from fire, sparks and heated surfaces. Cool containers / tanks with water spray. Fire or intense heat may cause violent rupture of packages. Thermal decomposition can lead to release of irritating gases and vapours. Burning produces obnoxious and toxic fumes. Personal Precautions Methods for Cleaning Up Environmental Precautions Remove all sources of ignition. Ventilate the area. Avoid breathing dust or vapor. Avoid contact with skin, eyes and clothing. Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13). Do not use sparking tools. Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. Handling Storage Avoid contact with skin, eyes and clothing. Ensure adequate ventilation. Remove and wash contaminated clothing before re -use. Discard contaminated shoes. When using do not smoke. Do not take internally. Harmful or fatal if swallowed. Take notice of the directions of use on the label. Keep containers tightly closed in a dry, cool and well -ventilated place. Keep container closed when not in use. Keep out of the reach of children. Keep away from heat and sources of ignition. Exposure Guidelines Component ACGIH TLV OSHA PEL NIOSH IDLH Ontario TWAEV Mexico OEL (TWA) Stoddard solvent TWA: 100 ppm TWA: 100 ppm TWA: 525 mg/m3 TWA: 500 ppm TWA: 2900 mg/m3 20000 mg/m3 TWA: 525 mg/m3 TWA/LMPE-PPT: 100 ppm TWA/LMPE-PPT: 523 mg/m3 STEULMPE-CT: 200 ppm STEULMPE-CT: 1050 mg/m3 • Y s Page 2 / 7 Product code 59204 - Bright Red Revision Date May -07-2012 Limestone TWA: 15 mg/m3 (total dust) TWA: 5 mg/m3 (respirable fraction) TWA/LMPE-PPT: 10 mg/m3 STEULMPE-CT: 20 mg/m3 Solvent naphtha (petroleum), medium aliphatic TWA: 525 mg/m3 Xylenes (o-, m-, p- isomers) TWA: 100 ppm STEL: 150 ppm TWA: 100 ppm TWA: 435 mg/m3 STEL: 150 ppm STEL: 655 mg/m3 TWA: 100 ppm STEL: 150 ppm TWA/LMPE-PPT: 100 ppm TWA/LMPE-PPT: 435 mg/m3 STEULMPE-CT: 150 ppm STEULMPE-CT: 655 mg/m3 Ethyl benzene (contaminant) TWA: 20 ppm TWA: 100 ppm TWA: 435 mg/m3 STEL: 125 ppm STEL: 545 mg/m3 800 ppm (10% LEL) TWA: 100 ppm STEL: 125 ppm TWA/LMPE-PPT: 100 ppm TWA/LMPE-PPT: 435 mg/m3 STEL/LMPE-CT: 125 ppm STEULMPE-CT: 545 mg/m3 Naphthalene (contaminant) TWA: 10 ppm STEL: 15 ppm Skin TWA: 10 ppm TWA: 50 mg/m3 STEL: 15 ppm STEL: 75 mg/m3 250 ppm TWA: 10 ppm STEL: 15 ppm Skin TWA/LMPE-PPT: 10 ppm TWA/LMPE-PPT: 50 mg/m3 STEULMPE-CT: 15 ppm STEULMPE-CT: 75 mg/m3 Engineering Measures Personal Protective Equipment Respiratory Protection Eye Protection Skin Protection General Hygiene Considerations Use ventilation adequate to keep exposures below recommended exposure limits. See MSDS. In case of insufficient ventilation, wear suitable respiratory equipment. Use the indicated respiratory protection if the occupational exposure limit is exceeded and/or in case of product release (dust). Respirator with a vapour filter. Ensure that eyewash stations and safety showers are close to the workstation location. Avoid contact with eyes. Safety glasses with side -shields. Goggles. Face -shield. Wear protective gloves/clothing. Solvent -resistant apron and boots. Handle in accordance with good industrial hygiene and safety practice. Wash hands before eating, drinking, or smoking. Remove and wash contaminated clothing before re -use. Avoid contact with skin, eyes and clothing. Wear suitable gloves and eye/face protection. Regular cleaning of equipment, work area and clothing is recommended. 74 aPwHY�SfC'A)nIAND �E,MICAL PROPER r airs Appearance Odor pH Boiling point/Boiling Range Freezing Point/Range Evaporation Rate Vapour Pressure Flammability (solid, gas) Flash Point Method Colored liquid Characteristic No information available >149 °C / >300 °F No information available No information available No information available No information available 46°C/115°F Setaflash closed cup Weight Per Gallon (lbs/gal) 8.84 VOC by weight % 33.71 VOC lbs/gal (less water) 2.98 Physical State Odor Threshold Autoignition Temperature Melting Point/Range Solubility Partition Coefficient (n-octanol/water) Vapour Density Liquid No information available No information available No information available No information available No information available Heavier than air Flammability Limits in Air Upper No information available Lower No information available Photochemically Reactive No Specific Gravity 1.06 VOC by volume % No information available VOC grams/liter (less water) 356.96 Page 3/7 Product code 59204 - Bright Red • Revision Date May -07-2012 Chemical Stability Conditions to Avoid Incompatible Products Stable under normal conditions. Heat, flames and sparks. Strong acids. Strong bases. Strong oxidizing agents. Reducing agents. Hazardous Decomposition Products Thermal decomposition can lead to release of irritating gases and vapours. (CO2). Carbon monoxide. Possibility of Hazardous Reactions None under normal processing. Carbon dioxide =n XICOLOGICAIL INFORMATIO Acute Toxicity Component LD50 Oral LD50 Dermal LC50 Inhalation Naphtha (petroleum), heavy aromatic >5000 mg/kg ( Rat) - >2000 mg/kg ( Rabbit) >590 mg/m3 ( Rat) 4 h Solvent naphtha (petroleum), medium aliphatic >5000 mg/kg ( Rat) 3000 mg/kg ( Rabbit) >5.28 mg/L ( Rat) 4 h • Xylenes (o-, m-, p- isomers) 4300 mg/kg ( Rat) >1700 mg/kg ( Rabbit) 5000 ppm ( Rat) 4 h 47635 mg/L ( Rat) 4 h Ethyl benzene (contaminant) 3500 mg/kg ( Rat) 15354 mg/kg ( Rabbit) 17.2 mg/L ( Rat) 4 h Naphthalene (contaminant) 490 mg/kg ( Rat) >2500 mg/kg ( Rat) >20 g/kg ( Rabbit ) >340 mg/m3 ( Rat) 1 h Chronic Toxicity Component ACGIH IARC NTP OSHA Ethyl benzene (contaminant) A3 Group 2B X Naphthalene (contaminant) Group 2B Reasonably Anticipated X ACGIH: (American Conference of Governmental industrial Hygienists) IARC: (International Agency for Research on Cancer) NTP: (National Toxicity Program) OSHA: (Occupational Safety & Health Administration) Sensitisation Mutagenic Effects Reproductive Effects Developmental hazard Teratogenicity Chronic Effects Target Organ Effects A3 - Animal Carcinogen Group 28 - Possibly Carcinogenic to Humans Reasonably Anticipated to be a Human Carcinogen X - Present No information available No information available No information available No information available No information available Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may result in adverse health effect, such as mucous membrane and respiratory system irritation and adverse effect on kidney, liver and central nervous system. Central nervous system, Eyes, Kidney, Respiratory system, Skin. 'ECOLOG,ICAL INFORMATION Ecotoxicity We have no quantitative data concerning the ecological effects of this product. Should not be released into the environment. Component Algae Fish Water Flea Page 4 / 7 Product code 59204.- Bright Red Revision Date May -07-2012 Naphtha (petroleum), heavy aromatic log Pow 96h LC50 Lepomis macrochirus: 1740 mg/L [static] 96h LC50 Pimephales promelas: 19 mg/L [static] 96h LC50 Pimephales promelas: 41 mg/L 96h LC50 Pimephales promelas: 45 mg/L [flow-through] 4.5 Solvent naphtha (petroleum), medium aliphatic 96h EC50 Pseudokirchneriella subcapitata: 450 mg/L 96h LC50 Pimephales promelas: 800 mg/L [static] 48h EC50 Daphnia magna: >100 mg/L Xylenes (o-, m-, p- isomers) 3.3 96h LC50 Lepomis macrochirus: 13.1 - 16.5 mg/L [flow-through] 96h LC50 Oncorhynchus mykiss: 13.5-17.3mg/L 96h LC50 Oncorhynchus mykiss: 2.661 - 4.093 mg/L [static] 96h LC50 Pimephales promelas: 23.53 - 29.97 mg/L [static] 96h LC50 Poecilia reticulata: 30.26 - 40.75 mg/L [static] 96h LC50 Lepomis macrochirus: 7.711 - 9.591 mg/L [static] 96h LC50 Pimephales promelas: 13.4 mg/L [flow-through] 96h LC50 Lepomis macrochirus: 19 mg/L 96h LC50 Cyprinus carpio: 780 mg/L [semi -static] 96h LC50 Cyprinus carpio: >780 mg/L 48h LC50 Gammarus lacustris: 0.6 mg/L 48h EC50 water flea: 3.82 mg/L Ethyl benzene (contaminant) 96h EC50 Pseudokirchneriella subcapitata: 1.7 - 7.6 mg/L [static] 72h EC50 Pseudokirchneriella subcapitata: 2.6 - 11.3 mg/L [static] 72h EC50 Pseudokirchneriella subcapitata: 4.6 mg/L 96h EC50 Pseudokirchneriella subcapitata: >438 mg/L 96h LC50 Oncorhynchus mykiss: 11.0 - 18.0 mg/L [static] 96h LC50 Pimephales promelas: 7.55 - 11 mg/L [flow-through] 96h LC50 Pimephales promelas: 9.1 - 15.6 mg/L [static] 96h LC50 Lepomis macrochirus: 32 mg/L [static] 96h LC50 Oncorhynchus mykiss: 4.2 mg/L [semi -static] 96h LC50 Poecilia reticulata: 9.6 mg/L [static] 48h EC50 Daphnia magna: 1.8 - 2.4 mg/L Naphthalene (contaminant) 72h EC50 Skeletonema costatum: 0.4 mg/L 96h LC50 Oncorhynchus mykiss: 0.91 - 2.82 mg/L [static] 96h LC50 Pimephales promelas: 5.74 - 6.44 mg/L [flow-through] 96h LC50 Oncorhynchus mykiss: 1.6 mg/L [flow-through] 96h LC50 Pimephales promelas: 1.99 mg/L [static] 96h LC50 Lepomis macrochirus: 31.0265 mg/L [static] 48h EC50 Daphnia magna: 1.09 - 3.4 mg/L [static] 48h EC50 Daphnia magna: 1.96 mg/L [Flow through] 48h LC50 Daphnia magna: 2.16 mg/L Persistence and Degradability No information available Bioaccumulation No information available Mobility in Environmental Media No information available Component log Pow Naphtha (petroleum), heavy aromatic 4.5 Xylenes (o-, m-, p- isomers) 2.96 Ethyl benzene (contaminant) 3.118 Naphthalene (contaminant) . 3.3 ; DISPOSA : CONSIDERATIOI Waste Disposal Methods Dispose of contents/container in accordance with local regulation. Page 5/7 Product code 59204 - Bright Red Revision Date May -07-2012 Contaminated Packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. (45 . RANSPOR,T INrFORMAT101 DOT UN1210, Printing Ink, 3, III In the U.S. and Canada, this material may be reclassified as a combustible liquid and is not regulated, via surface transportation, in containers less than 119 gallons or 450 liters [per 49 CFR 173.150 (f)] [per Transportation of Dangerous Goods Regulations/Clear Language Part 1.33]. ICAO/IATA UN1210, Printing Ink, 3, III IMDG/IMO UN1210, Printing Ink, 3, III rz '4474117-`1/4 SE akU~IATORI(� INF• ORIVIATIOIV' 44, International Inventories Listed on TSCA. For further information, please contact: Manufacturer, importer, supplier U.S. Federal Regulations SARA 313 The following components are subject to r Component CAS -No Weight % SARA 313 - Threshold Values Ethyl benzene (contaminant) 100-41-4 < 0.5 0.1 Xylenes (o-, m-, p- isomers) 1330-20-7 1 - 5 1.0 Naphthalene (contaminant) 91-20-3 < 0.5 0.1 Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) Component CAS -No Weight % Xylenes (o-, m-, p- isomers) 1330-20-7 1 - 5 U.S. State Regulations Component Massachusetts Right To Know Minnesota Right To Know New Jersey Right To Know Pennsylvania Right To Know Stoddard solvent X X X X Limestone X X X X Solvent naphtha (petroleum), medium aliphatic Not Listed Not Listed X Not Listed Xylenes (o-, m-, p- isomers) X X X X Ethyl benzene (contaminant) X X X X Naphthalene (contaminant) X X X X California Prop. 65 WARNING! This product contains a chemical known in the State of California to cause cancer and / or WARNING! This product contains a chemical known in the State of California to cause birth defects or other reproductive harm Component CAS -No Weight % Ethyl benzene (contaminant) 100-41-4 < 0.5 Naphthalene (contaminant) 91-20-3 < 0.5 Canada This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the information required by the CPR Component WHMIS Classifications of Components Stoddard solvent B3,D2B Page 6 l 7 Product code 59204 - Bright Red Revision Date May -07-2012 Limestone D2A Solvent naphtha (petroleum), medium aliphatic B3 Xylenes (o-, m-, p- isomers) B2,D2A,D2B Ethyl benzene (contaminant) B2,D2A,D2B Naphthalene (contaminant) B4,D2A Component NPRI - National Pollutant Release Inventory Stoddard solvent Part 5 Substance Part 5, Other Groups and Mixtures Naphtha (petroleum), heavy aromatic Part 5 Substance Part 5, Other Groups and Mixtures Solvent naphtha (petroleum), medium aliphatic Part 5 Substance Part 5, Other Groups and Mixtures Xylenes (o-, m-, p- isomers) Part 1, Group 1 Substance Part 5 Substance Part 5, Isomer Groups Ethyl benzene (contaminant) Part 4 Substance Part 1, Group 1 Substance Naphthalene (contaminant) Part 1, Group 1 Substance Regulation (EC) No. 1907/2006 (REACH), Article 57 None known HMIS: Health 1* Flammability 2 Reactivity 0 PPE X { ik ER` INFQRMAT Old -F .*$ '1..W11,11.417.1 Revision Date Revision Note May -07-2012 New MSDS format Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used In combination with any other materials or in any process, unless specified In the text End of MSDS Page 7/7 F Ink Technologies Product code Product name Product category Material Safety Data Sheet Prepared In accordance with ISO 11014-1/ANSI standard Z400.1-2004 Print Date May -07-2012 Manufacturer or supplier's details UNITED STATES Nazdar Company 8501 Hedge Lane Terrace Shawnee, KS 66227 Tel: 1-913-422-1888 Tel: 1-800-677-4657 Fax: 1-913-422-2294 =OMRi Revision Date May -07-2012 'Iifi1CAT10N z 59422 Reflex Blue 59000 Series Enamel Plus Gloss Screen Ink UNITED KINGDOM Nazdar Limited 7 Barton Road Heaton Mersey Industrial Estate Stockport, Cheshire SK4 3EG Tel: +44 161 442 2111 Emergency Telephone Number USA: Chemtrec: 1-800-424-9300 Outside USA: Chemtrec: 1-703-527-3887 Website: www.nazdar.com MSDS Information: 1-913-422-1888 ext 2305 MSDS Contact: Regulatory Compliance email: regcomp@nazdar.com . AZARDS IDENTIFICAT ION This product is a preparation. Health hazard information is based on its components. Appearance Flammable Properties Emergency Overview Eyes Skin Inhalation Ingestion Colored liquid Combustible liquid and vapor. Aspiration hazard. Harmful: may cause lung damage if swallowed. Irritant. May cause drowsiness and dizziness. May cause eye irritation. May cause skin irritation and/or dermatitis. May cause irritation of respiratory tract. Inhalation of high vapour concentrations may cause symptoms like headache, dizziness, tiredness, nausea and vomiting. Harmful if swallowed. Potential for aspiration if swallowed. Risk of serious damage to the lungs (by aspiration). 00.014 )0 INFORMATION 0 400. 1:0* r Component CAS -No Weight Stoddard solvent 8052-41-3 10 - 30 Barium sulfate 7727-43-7 10 - 30 Solvent naphtha (petroleum), medium aliphatic 64742-88-7 1 - 5 Titanium dioxide 13463-67-7 1 - 5 Copper Phthalocyanine Compound Trade Secret 1 - 5 Xylenes (o-, m-, p- isomers) 1330-20-7 1 - 5 Ethyl benzene (contaminant) 100-41-4 < 0.5 Crystalline silica (cristobalite) 14464-46-1 < 0.5 Cobalt Compounds Trade Secret < 0.5 • Component names which have the word (contaminant) are constituents contained in Aromatic Hydrocarbon ingredients and are an integral part of the ingredient and cannot be separated. The percentage listed for the contaminant is as contained in the Hydrocarbon ingredient. (Example: 100% Hydrocarbon, 10% Contaminant A, 3% Contaminant B) Eye Contact RST�`Arp�N1EA°SURE; Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get medical attention immediately if irritation develops and persists. Page 1 l 7 RECEIVED CITY OF TUKWILA JUL 1 2 2013 PERMIT CENTER Product code 59422 - Reflex Blue Revision Date May -07-2012% Skin Contact Inhalation Ingestion Wash off immediately with soap and plenty of water. Use a mild soap if available. Rinse immediately with plenty of water for at least 15 minutes. Remove contaminated clothing. If irritation develops, get medical attention. If breathed in, move person into fresh air. If breathing is irregular or stopped, administer artificial respiration. Get medical attention immediately. If swallowed, DO NOT induce vomiting. Call a physician or Poison Control Centre immediately. Never give anything by mouth to an unconscious person. ;014.0:01(0100:10.0:4114:000.I Flammable Properties Suitable Extinguishing Media Protective Equipment and Precautions for Firefighters Specific Hazards Arising from the Chemical Combustible liquid and vapor. Foam. Carbon dioxide (CO2). Dry chemical. Water spray. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. As in any fire, wear self-contained breathing apparatus pressure -demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Keep away from fire, sparks and heated surfaces. Cool containers / tanks with water spray. Fire or intense heat may cause violent rupture of packages. Thermal decomposition can lead to release of irritating gases and vapours. Burning produces obnoxious and toxic fumes. 011PFNTA41) S,E MEA MR! Personal Precautions Methods for Cleaning Up Environmental Precautions Remove all sources of ignition. Ventilate the area. Avoid breathing dust or vapor. Avoid contact with skin, eyes and clothing. Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13). Do not use sparking tools. Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. IrY'tf.'L,da. 7 HANDLING{ANALTO Handling Storage Avoid contact with skin, eyes and clothing. Ensure adequate ventilation. Remove and wash contaminated clothing before re -use. Discard contaminated shoes. When using do not smoke. Do not take internally. Harmful or fatal if swallowed. Take notice of the directions of use on the label. Keep containers tightly closed in a dry, cool and well -ventilated place. Keep container closed when not in use. Keep out of the reach of children. Keep away from heat and sources of ignition. SU REQ CONTRQ,4S/PERSONAL.; 'ROTECTIi Exposure Guidelines Component ACGIH TLV I OSHA PEL I NIOSH IDLH I Ontario TWAEV 1 Mexico OEL (TWA) Page 217 Product code 59422 - Reflex Blue Revision Date May -07-2012 Stoddard solvent TWA: 100 ppm TWA: 100 ppm TWA: 525 mg/m3 TWA: 500 ppm TWA: 2900 mg/m3 20000 mg/m3 TWA: 525 mg/m3 TWA/LMPE-PPT: 100 ppm TWA/LMPE-PPT: 523 mg/m3 STEULMPE-CT: 200 ppm STEULMPE-CT: 1050 mg/m3 Barium sulfate TWA: 10 mg/m3 TWA: 10 mg/m3 (total dust) TWA: 5 mg/m3 (respirable fraction) TWA: 15 mg/m3 (total dust) TWA: 10 mg/m3 (total dust) Solvent naphtha (petroleum), medium aliphatic TWA: 525 mg/m3 Titanium dioxide TWA: 10 mg/m3 TWA: 10 mg/m3 (total dust) TWA: 15 mg/m3 (total dust) 5000 mg/m3 TWA: 10 mg/m3 (total dust) TWA/LMPE-PPT: 10 mg/m3 (as Ti) STEULMPE-CT: 20 mg/m3 (as Ti) Xylenes (o-, m-, p- isomers) TWA: 100 ppm STEL: 150 ppm TWA: 100 ppm TWA: 435 mg/m3 STEL: 150 ppm STEL: 655 mg/m3 TWA: 100 ppm STEL: 150 ppm TWA/LMPE-PPT: 100 ppm TWA/LMPE-PPT: 435 mg/m3 STEL/LMPE-CT: 150 ppm STEULMPE-CT: 655 mg/m3 Ethyl benzene (contaminant) TWA: 20 ppm TWA: 100 ppm TWA: 435 mg/m3 STEL: 125 ppm STEL: 545 mg/m3 800 ppm (10% LEL) TWA: 100 ppm STEL: 125 ppm TWA/LMPE-PPT: 100 ppm TWA/LMPE-PPT: 435 mg/m3 STEULMPE-CT: 125 ppm STEULMPE-CT: 545 mg/m3 Crystalline silica (cristobalite) TWA: 0.025 mg/m3 (respirable fraction) TWA: 0.05 mg/m3 (respirable dust) 25 mg/m3 TWA: 0.05 mg/m3 (respirable) TWA/LMPE-PPT: 0.05 mg/m3 (respirable fraction) Engineering Measures Personal Protective Equipment Respiratory Protection Eye Protection Skin Protection General Hygiene Considerations Appearance Odor pH Boiling point/Boiling Range Freezing Point/Range Evaporation Rate Vapour Pressure Flammability (solid, gas) Use ventilation adequate to keep exposures below recommended exposure limits. See MSDS. In case of insufficient ventilation, wear suitable respiratory equipment. Use the indicated respiratory protection if the occupational exposure limit is exceeded and/or in case of product release (dust). Respirator with a vapour filter. Ensure that eyewash stations and safety showers are close to the workstation location. Avoid contact with eyes. Safety glasses with side -shields. Goggles. Face -shield. Wear protective gloves/clothing. Solvent -resistant apron and boots. Handle in accordance with good industrial hygiene and safety practice. Wash hands before eating, drinking, or smoking. Remove and wash contaminated clothing before re -use. Avoid contact with skin, eyes and clothing. Wear suitable gloves and eye/face protection. Regular cleaning of equipment, work area and clothing is recommended. r rfY3iCI1LIEIVIICAPRO�?Hop E i3 1 Colored liquid Characteristic No information available >149 °C / >300 °F No information available No information available No information available No information available Physical State Odor Threshold Autoignition Temperature Melting Point/Range Solubility Partition Coefficient (n-octanol/water) Vapour Density Liquid No information available No information available No information available No information available No information available Heavier than air Page 3/7 Product code 59422 - Reflex Blue Revision Date May -07-2012 t Flash Point 46°C/115 °F Method Setaflash closed cup Weight Per Gallon (lbs/gal) 9.82 VOC by weight % 30.62 VOC lbs/gal (less water) 3.01 Flammability Limits in Air Upper No information available Lower No information available Photochemically Reactive No Specific Gravity 1.18 VOC by volume % No information available VOC grams/liter (less water) 360.38 TABILI Y,AND;REACTI,V11 Chemical Stability Conditions to Avoid Incompatible Products Stable under normal conditions. Heat, flames and sparks. Strong acids. Strong bases. Strong oxidizing agents. Reducing agents. Hazardous Decomposition Products Thermal decomposition can lead to release of irritating gases and vapours. Carbon dioxide (CO2). Carbon monoxide. Possibility of Hazardous Reactions None under normal processing. DXI;C.OLOGICAL :INFQRMATIOI Acute Toxicity Component LD50 Oral LD50 Dermal LC50 Inhalation Solvent naphtha (petroleum), medium aliphatic >5000 mg/kg ( Rat) 3000 mg/kg ( Rabbit) >5.28 mg/L ( Rat) 4 h Titanium dioxide >10000 mg/kg ( Rat ) Ethyl benzene (contaminant) A3 Xylenes (o-, m-, p- isomers) 4300 mg/kg ( Rat) >1700 mg/kg ( Rabbit) 5000 ppm ( Rat) 4 h 47635 mg/L ( Rat) 4 h Ethyl benzene (contaminant) 3500 mg/kg ( Rat) 15354 mg/kg ( Rabbit) 17.2 mg/L ( Rat) 4 h Chronic Toxicity Component ACGIH IARC NTP OSHA Titanium dioxide Group 2B X Ethyl benzene (contaminant) A3 Group 2B X Crystalline silica (cristobalite) Group 1 X Cobalt Compounds Group 2B X ACG/H: (American Conference of Governmental Industrial Hygienists) IARC: (International Agency for Research on Cancer) OSHA: (Occupational Safety & Health Administration) A3 - Animal Carcinogen Group 1 - Carcinogenic to Humans Group 28 - Possibly Carcinogenic to Humans X - Present Sensitisation No information available Mutagenic Effects No information available Reproductive Effects No information available Developmental hazard No information available Teratogenicity No information available Chronic Effects Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may result in adverse health effect, such as mucous membrane and respiratory system irritation and adverse effect on kidney, liver and central nervous system. Target Organ Effects Central nervous system, Eyes, Kidney, Liver, Respiratory system, Skin. Page 4/7 } Product code 59422 - Reflex Blue Revision Date May -07-2012 ECOLOGICAL` INFORI�IIAT1i Ecotoxicity We have no quantitative data concerning the ecological effects of this product. Should not be released into the environment. Component Algae Fish Water Flea Solvent naphtha (petroleum), medium aliphatic 96h EC50 Pseudokirchneriella subcapitata: 450 mg/L 96h LC50 Pimephales promelas: 800 mg/L [static] 48h EC50 Daphnia magna: >100 mg/L Copper Phthalocyanine , Compound 48h LC50 Oryzias latipes: >100 mg/L [static] Xylenes (o-, m-, p- isomers) 96h LC50 Lepomis macrochirus: 13.1 - 16.5 mg/L [flow-through] 96h LC50 Oncorhynchus mykiss: 13.5 - 17.3 mg/L 96h LC50 Oncorhynchus mykiss: 2.661 - 4.093 mg/L [static] 96h LC50 Pimephales promelas: 23.53 - 29.97 mg/L [static] 96h LC50 Poecilia reticulata: 30.26 - 40.75 mg/L [static] 96h LC50 Lepomis macrochirus: 7.711 - 9.591 mg/L [static] 96h LC50 Pimephales promelas: 13.4 mg/L [flow-through] 96h LC50 Lepomis macrochirus: 19 mg/L 96h LC50 Cyprinus carpio: 780 mg/L [semi -static] 96h LC50 Cyprinus carpio: >780 mg/L 48h LC50 Gammarus lacustris: 0.6 mg/L 48h EC50 water flea: 3.82 mg/L Ethyl benzene (contaminant) 96h EC50 Pseudokirchneriella subcapitata: 1.7 - 7.6 mg/L [static] 72h EC50 Pseudokirchneriella subcapitata: 2.6 - 11.3 mg/L [static] 72h EC50 Pseudokirchneriella subcapitata: 4.6 mg/L 96h EC50 Pseudokirchneriella subcapitata: >438 mg/L 96h LC50 Oncorhynchus mykiss: 11.0 - 18.0 mg/L [static] 96h LC50 Pimephales promelas: 7.55 - 11 mg/L [flow-through] 96h LC50 Pimephales promelas: 9.1 - 15.6 mg/L [static] 96h LC50 Lepomis macrochirus: 32 mg/L [static] 96h LC50 Oncorhynchus mykiss: 4.2 mg/L [semi -static] 96h LC50 Poecilia reticulata: 9.6 mg/L [static] 48h EC50 Daphnia magna: 1.8 - 2.4 mg/L Persistence and Degradability No information available Bioaccumulation No information available Mobility in Environmental Media No information available Component log Pow Copper Phthalocyanine Compound 6.6 Xylenes (o-, m-, p- isomers) 2.96 Ethyl benzene (contaminant) 3.118 aA L',CONSIDERATION (fly dih :or Waste Disposal Methods Contaminated Packaging Dispose of contents/container in accordance with local regulation. Empty containers should be taken to an approved waste handling site for recycling or disposal. 1NS0ORT; INFORMA rIC Page 5/7 Product code 59422 - Reflex Blue Revision Date May -07-2012,4 DOT UN1210, Printing Ink, 3, III In the U.S. and Canada, this material may be reclassified as a combustible liquid and is not regulated, via surface transportation, in containers less than 119 gallons or 450 liters [per 49 CFR 173.150 (f)] [per Transportation of Dangerous Goods Regulations/Clear Language Part 1.33]. ICAO/IATA UN1210, Printing Ink, 3, III IMDG/IMO UN1210, Printing Ink, 3, III 15o' REGU.t`ATOR700.0004711 .. ,.. International Inventories Listed on TSCA. For further information, please contact: Manufacturer, importer, supplier U.S. Federal Regulations SARA 313 The following components are subject to reporting levels establi Component CAS -No Weight % SARA 313 - Threshold 1330-20-7 1 - 5 - Values Ethyl benzene (contaminant) 100-41-4 < 0.5 0.1 Xylenes (o-, m-, p- isomers) 1330-20-7 1 - 5 1.0 Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) Component CAS -No Weight % Xylenes (o-, m-, p- isomers) 1330-20-7 1 - 5 U.S. State Regulations Component Massachusetts Right To Know Minnesota Right To Know New Jersey Right To Know Pennsylvania Right To Know Stoddard solvent X X X X Barium sulfate X X X X Solvent naphtha (petroleum), medium aliphatic Not Listed Not Listed X Not Listed Titanium dioxide X X X X Copper Phthalocyanine Compound Not Listed Not Listed X X Xylenes (o-, m-, p- isomers) X X X X Ethyl benzene (contaminant) X X X X Crystalline silica (cristobalite) X X X X Cobalt Compounds Not Listed Not Listed X X California Prop. 65 WARNING! This product contains a chemical known in the State of California to cause cancer and / or WARNING! This product contains a chemical known in the State of California to cause birth defects or other reproductive harm Component CAS -No Weight % Ethyl benzene (contaminant) 100-41-4 < 0.5 Titanium dioxide 13463-67-7 1 - 5 Canada This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the information required by the CPR Component WHMIS Classifications of Components Stoddard solvent B3,D2B Barium sulfate Uncontrolled product according to WHMIS classification criteria Solvent naphtha (petroleum), medium aliphatic B3 Titanium dioxide - D2A Copper Phthalocyanine Compound Uncontrolled product according to WHMIS classification criteria Page 6/7 Product code 59422 - Reflex Blue Revision Date May -07-2012 Xylenes (o-, m-, p- isomers) B2,D2A,D2B Ethyl benzene (contaminant) B2,D2A,D2B Crystalline silica (cristobalite) D2A Component NPRI - National Pollutant Release Inventory Stoddard solvent Part 5 Substance Part 5, Other Groups and Mixtures Solvent naphtha (petroleum), medium aliphatic Part 5 Substance Part 5, Other Groups and Mixtures Copper Phthalocyanine Compound Part 1, Group 1 Substance Xylenes (o-, m-, p- isomers) Part 1, Group 1 Substance Part 5 Substance Part 5, Isomer Groups Ethyl benzene (contaminant) Part 4 Substance Part 1, Group 1 Substance Cobalt Compounds Part 1, Group 1 Substance Regulation (EC) No. 1907/2006 (REACH), Article 57 None known HMIS: Health 1* Flammability 2 Reactivity 0 PPE X THER I.FO:MATIOI Revision Date Revision Note May -07-2012 New MSDS format Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and Is not to be considered a warranty or quality specification. The Information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text End of MSDS Page 7/7 Product code Product name Product category Manufacturer or supplier's details UNITED STATES Nazdar Company 8501 Hedge Lane Terrace Shawnee, KS 66227 Tel: 1-913-422-1888 Tel: 1-800-677-4657 Fax: 1-913-422-2294 Material Safety Data Sheet Prepared in accordance with ISO 11014-1/ANSI standard Z400.1-2004 Print Date May -07-2012 59LF124 Brilliant Orange 59000 Series Enamel Plus Gloss Screen Ink UNITED KINGDOM Nazdar Limited 7 Barton Road Heaton Mersey Industrial Estate Stockport, Cheshire SK4 3EG Tel: +44 161 442 2111 Revision Date May -07-2012 Emergency Telephone Number USA: Chemtrec: 1-800-424-9300 Outside USA: Chemtrec: 1-703-527-3887 Website: www.nazdar.com MSDS Information: 1-913-422-1888 ext 2305 MSDS Contact: Regulatory Compliance email: regcomp@nazdar.com :100DE01;0E1diAti This product is a preparation. Health hazard information is based on its components. Appearance Flammable Properties Emergency Overview Eyes Skin Inhalation Ingestion Colored liquid Combustible liquid and vapor. Aspiration hazard. Harmful: may cause lung damage if swallowed. Irritant. May cause drowsiness and dizziness. May cause eye irritation. May cause skin irritation and/or dermatitis. May cause irritation of respiratory tract. Inhalation of high vapour concentrations may cause symptoms like headache, dizziness, tiredness, nausea and vomiting. Harmful if swallowed. Potential for aspiration if swallowed. Risk of serious damage to the lungs (by aspiration). UMPO it ON%1 kok001 NOI'NGRED• Component CAS -No Weight % Stoddard solvent 8052-41-3 10 - 30 Barium sulfate 7727-43-7 10 - 30 Solvent naphtha (petroleum), medium aliphatic 64742-88-7 1 - 5 Xylenes (o-, m-, p- isomers) 1330-20-7 1 - 5 Ethyl benzene (contaminant) 100-41-4 < 0.5 Crystalline silica (cristobalite) 14464-46-1 < 0.5 • Component names which have the word (contaminant) are constituents contained in Aromatic Hydrocarbon ingredients and are an integral part of the ingredient and cannot be separated. The percentage listed for the contaminant is as contained in the Hydrocarbon ingredient. (Example: 100% Hydrocarbon, 10% Contaminant A, 3% Contaminant 13) Eye Contact Skin Contact Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get medical attention immediately if irritation develops and persists. Wash off immediately with soap and plenty of water. Use a mild soap if available. Rinse immediately with plenty of water for at least 15 minutes. Remov contaminated clothing. If irritation develops, get medical attention. tLEIVED CITY OF TUKWILA JUL 122013 b\-- 2-39 Page 1 l 7 PERMIT CENTER Product code 59LF124 - Brilliant Orange • Revision Date May -07-2012k Inhalation Ingestion If breathed in, move person into fresh air. If breathing is irregular or stopped, administer artificial respiration. Get medical attention immediately. If swallowed, DO NOT induce vomiting. Call a physician or Poison Control Centre immediately. Never give anything by mouth to an unconscious person. :AFI RE} F IG t TI NGM EASP RES; Flammable Properties Suitable Extinguishing Media Protective Equipment and Precautions for Firefighters Specific Hazards Arising from the Chemical Combustible liquid and vapor. Foam. Carbon dioxide (CO2). Dry chemical. Water spray. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. As in any fire, wear self-contained breathing apparatus pressure -demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Keep away from fire, sparks and heated surfaces. Cool containers / tanks with water spray. Fire or intense heat may cause violent rupture of packages. Thermal decomposition can lead to release of irritating gases and vapours. Burning produces obnoxious and toxic fumes. c ipeNTAL;:REI ASE .1yIEAsuREs Personal Precautions Methods for Cleaning Up Environmental Precautions Remove all sources of ignition. Ventilate the area. Avoid breathing dust or vapor. Avoid contact with skin, eyes and clothing. Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13). Do not use sparking tools. Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. ►NDUNGAND S$ORA Handling Storage Avoid contact with skin, eyes and clothing. Ensure adequate ventilation. Remove and wash contaminated clothing before re -use. Discard contaminated shoes. When using do not smoke. Do not take internally. Harmful or fatal if swallowed. Take notice of the directions of use on the label. Keep containers tightly closed in a dry, cool and well -ventilated place. Keep container closed when not in use. Keep out of the reach of children. Keep away from heat and sources of ignition. 01:40 tE 0 fiti# S104:0 AL,P.ROTECTI! Exposure Guidelines Component ACGIH TLV OSHA PEL NIOSH IDLH Ontario TWAEV Mexico OEL (TWA) Stoddard solvent TWA: 100 ppm TWA: 100 ppm TWA: 525 mg/m3 TWA: 500 ppm TWA: 2900 mg/m3 20000 mg/m3 TWA: 525 mg/m3 TWA/LMPE-PPT: 100 ppm TWA/LMPE-PPT: 523 mg/m3 STEULMPE-CT: 200 ppm STEULMPE-CT: 1050 mg/m3 Product code 59LF124 - Brilliant Orange Revision Date May -07-2012 Barium sulfate TWA: 10 mg/m3 TWA: 10 mg/m3 (total dust) TWA: 5 mg/m3 (respirable fraction) TWA: 15 mg/m3 (total dust) TWA: 10 mg/m3 (total dust) Solvent naphtha (petroleum), medium aliphatic TWA: 525 mg/m3 Xylenes (o-, m-, p- isomers) TWA: 100 ppm STEL: 150 ppm TWA: 100 ppm TWA: 435 mg/m3 STEL: 150 ppm STEL: 655 mg/m3 TWA: 100 ppm STEL: 150 ppm TWA/LMPE-PPT: 100 ppm TWA/LMPE-PPT: 435 mg/m3 STEULMPE-CT: 150 ppm STEULMPE-CT: 655 mg/m3 Ethyl benzene (contaminant) TWA: 20 ppm TWA: 100 ppm TWA: 435 mg/m3 STEL: 125 ppm STEL: 545 mg/m3 800 ppm (10% LEL) TWA: 100 ppm STEL: 125 ppm TWA/LMPE-PPT: 100 ppm TWA/LMPE-PPT: 435 mg/m3 STEULMPE-CT: 125 ppm STEULMPE-CT: 545 mg/m3 Crystalline silica (cristobalite) TWA: 0.025 mg/m3 (respirable fraction) TWA: 0.05 mg/m3 (respirable dust) 25 mg/m3 TWA: 0.05 mg/m3 (respirable) TWA/LMPE-PPT: 0.05 mg/m3 (respirable fraction) Engineering Measures Personal Protective Equipment Respiratory Protection Eye Protection Skin Protection General Hygiene Considerations Use ventilation adequate to keep exposures below recommended exposure limits. See MSDS. In case of insufficient ventilation, wear suitable respiratory equipment. Use the indicated respiratory protection if the occupational exposure limit is exceeded and/or in case of product release (dust). Respirator with a vapour filter. Ensure that eyewash stations and safety showers are close to the workstation location. Avoid contact with eyes. Safety glasses with side -shields. Goggles. Face -shield. Wear protective gloves/clothing. Solvent -resistant apron and boots. Handle in accordance with good industrial hygiene and safety practice. Wash hands before eating, drinking, or smoking. Remove and wash contaminated clothing before re -use. Avoid contact with skin, eyes and clothing. Wear suitable gloves and eye/face protection. Regular cleaning of equipment, work area and clothing is recommended. Y. SIRRTIESti, 3r - Appearance Odor pH Boiling point/Boiling Range Freezing Point/Range Evaporation Rate Vapour Pressure Flammability (solid, gas) Colored liquid Characteristic No information available >149 °C / >300 °F No information available No information available No information available No information available Flash Point 46 °C/ 115 °F Method Setaflash closed cup Weight Per Gallon (lbs/gal) 9.79 VOC by weight % 29.54 VOC lbs/gal (less water) 2.89 Physical State Odor Threshold Autoignition Temperature Melting Point/Range Solubility Partition Coefficient (n-octanol/water) Vapour Density Liquid No information available No information available No information available No information available No information available Heavier than air Flammability Limits in Air Upper No information available Lower No information available Photochemically Reactive No Specific Gravity 1.17 VOC by volume % No information available VOC grams/liter (less water) 346.55 Page 3/7 Product code 59LF124 - Brilliant Orange Revision Date May -07-2012 Chemical Stability Conditions to Avoid Incompatible Products Stable under normal conditions. Heat, flames and sparks. Strong acids. Strong bases. Strong oxidizing agents. Reducing agents. Hazardous Decomposition Products Thermal decomposition can lead to release of irritating gases and vapours. Carbon dioxide (CO2). Carbon monoxide. Possibility of Hazardous Reactions None under normal processing. Acute Toxicity Component LD50 Oral LD50 Dermal LC50 Inhalation Solvent naphtha (petroleum), medium aliphatic >5000 mg/kg ( Rat) 3000 mg/kg ( Rabbit) >5.28 mg/L ( Rat) 4 h Xylenes (o-, m-, p- isomers) 4300 mg/kg ( Rat) >1700 mg/kg ( Rabbit) 5000 ppm ( Rat) 4 h 47635 mg/L ( Rat) 4 h Ethyl benzene (contaminant) 3500 mg/kg (Rat) 15354 mg/kg (Rabbit) 17.2 mg/L ( Rat) 4 h Chronic Toxicity Component ACGIH IARC NTP OSHA Ethyl benzene (contaminant) A3 Group 2B X Crystalline silica (cristobalite) Group 1 X ACGIH: (American Conference of Governmental Industrial Hygienists) IARC: (International Agency for Research on Cancer) OSHA: (Occupational Safety & Health Administration) Sensitisation Mutagenic Effects Reproductive Effects Developmental hazard Teratogenicity Chronic Effects Target Organ Effects A3 - Animal Carcinogen Group 1 - Carcinogenic to Humans Group 2B - Possibly Carcinogenic to Humans X - Present No information available No information available No information available No information available No information available Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may result in adverse health effect, such as mucous membrane and respiratory system irritation and adverse effect on kidney, liver and central nervous system. Central nervous system, Eyes, Kidney, Respiratory system, Skin. Ecotoxicity We have no quantitative data concerning the ecological effects of this product. Should not be released into the environment. Component Algae Fish Water Flea Solvent naphtha (petroleum), medium aliphatic 96h EC50 Pseudokirchneriella subcapitata: 450 mg/L 96h LC50 Pimephales promelas: 800 mg/L (static] 48h EC50 Daphnia magna: >100 mg/L Page 4/7 Product code 59LF124 - Brilliant Orange Revision Date May -07-2012 Xylenes (o-, m-, p- isomers) log Pow 96h LC50 Lepomis macrochirus: 13.1 - 16.5 mg/L [flow-through] 96h LC50 Oncorhynchus mykiss: 13.5 - 17.3 mg/L 96h LC50 Oncorhynchus mykiss: 2.661 - 4.093 mg/L [static] 96h LC50 Pimephales promelas: 23.53 - 29.97 mg/L [static] 48h LC50 Gammarus lacustris: 0.6 mg/L 48h EC50 water flea: 3.82 mg/L Ethyl benzene (contaminant) 3.118 96h LC50 Poecilia reticulata: 30.26 - 40.75 mg/L [static] 96h LC50 Lepomis macrochirus: 7.711 - 9.591 mg/L [static] 96h LC50 Pimephales promelas: 13.4 mg/L [flow-through] 96h LC50 Lepomis macrochirus: 19 mg/L 96h LC50 Cyprinus carpio: 780 mg/L [semi -static] 96h LC50 Cyprinus carpio: >780 mg/L Ethyl benzene (contaminant) 96h EC50 Pseudokirchneriella 96h LC50 Oncorhynchus mykiss: 48h EC50 Daphnia magna: 1.8 - 2.4 subcapitata: 1.7 - 7.6 mg/L [static] 11.0 - 18.0 mg/L [static] mg/L 72h EC50 Pseudokirchneriella 96h LC50 Pimephales promelas: subcapitata: 2.6 - 11.3 mg/L [static] 7.55 - 11 mg/L [flow-through] 72h EC50 Pseudokirchneriella 96h LC50 Pimephales promelas: subcapitata: 4.6 mg/L 9.1 - 15.6 mg/L [static] 96h EC50 Pseudokirchneriella subcapitata: >438 mg/L 96h LC50 Lepomis macrochirus: 32 mg/L [static] 96h LC50 Oncorhynchus mykiss: 4.2 mg/L [semi -static] 96h LC50 Poecilia reticulata: 9.6 mg/L [static] Persistence and Degradability No information available Bioaccumulation No information available Mobility in Environmental Media No information available Component log Pow Xylenes (o-, m-, p- isomers) 2.96 Ethyl benzene (contaminant) 3.118 Waste Disposal Methods Contaminated Packaging Dispose of contents/container in accordance with local regulation. Empty containers should be taken to an approved waste handling site for recycling or disposal. DOT UN1210, Printing Ink, 3, Ill In the U.S. and Canada, this material may be reclassified as a combustible liquid and is not regulated, via surface transportation, in containers less than 119 gallons or 450 liters [per 49 CFR 173.150 (f)] [per Transportation of Dangerous Goods Regulations/Clear Language Part 1.33]. ICAO/IATA UN1210, Printing Ink, 3, III IMDG/IMO UN1210, Printing Ink, 3, Ill Page 5/7 Product code 59LF124 - Brilliant Orange Revision Date May -07-2012 International Inventories Listed on TSCA. For further information, please contact: Manufacturer, importer, supplier U.S. Federal Regulations SARA 313 The following components are subject to reporting levels established by SARA Title III, Section Component CAS -No Weight % SARA 313 - Threshold 1330-20-7 1 - 5 X Values Ethyl benzene (contaminant) 100-41-4 < 0.5 0.1 Xylenes (o-, m-, p- isomers) 1330-20-7 1 - 5 1.0 Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) Component CAS -No Weight % Xylenes (o-, m-, p- isomers) 1330-20-7 1 - 5 U.S. State Regulations Component Massachusetts Right To Know Minnesota Right To Know New Jersey Right To Know Pennsylvania Right To Know Stoddard solvent X X X X Barium sulfate X X X X Solvent naphtha (petroleum), medium aliphatic Not Listed Not Listed X Not Listed Xylenes (o-, m-, p- isomers) X X X X Ethyl benzene (contaminant) X X X X Crystalline silica (cristobalite) X X X X California Prop. 65 WARNING! This product contains a chemical known in the State of California to cause cancer and / or WARNING! This product contains a chemical known in the State of California to cause birth defects or other reproductive harm Component CAS -No Weight % Ethyl benzene (contaminant) 100-41-4 < 0.5 Canada This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the information required by the CPR Component WHMIS Classifications of Components Stoddard solvent B3,D2B Barium sulfate Uncontrolled product according to WHMIS classification criteria Solvent naphtha (petroleum), medium aliphatic B3 Xylenes (o-, m-, p- isomers) B2,D2A,D2B Ethyl benzene (contaminant) B2,D2A,D2B Crystalline silica (cristobalite) D2A Component NPRI - National Pollutant Release Inventory Stoddard solvent Part 5 Substance Part 5, Other Groups and Mixtures Solvent naphtha (petroleum), medium aliphatic Part 5 Substance Part 5, Other Groups and Mixtures Xylenes (o-, m-, p- isomers) Part 1, Group 1 Substance Part 5 Substance Part 5, Isomer Groups Ethyl benzene (contaminant) Part 4 Substance Part 1, Group 1 Substance Regulation (EC) No. 1907/2006 (REACH), Article 57 None known Page 6/7 1 Product code 59LF124 - Brilliant Orange Revision Date May -07-2012 HMIS: Health 1* Flammability 2 Reactivity 0 PPE X ..e.it NFORMATiO Revision Date Revision Note May -07-2012 New MSDS format Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text End of MSDS Page 7/7 Product code Product name Product category Manufacturer or supplier's details UNITED STATES Nazdar Company 8501 Hedge Lane Terrace Shawnee, KS 66227 Tel: 1-913-422-1888 Tel: 1-800-677-4657 Fax: 1-913-422-2294 Material Safety Data Sheet Prepared in accordance with ISO 11014-1/ANSI standard Z400.1-2004 Print Date Jul -25-2012 6112 Medium Yellow 6100 Series Fast Dry Enamel Screen Ink UNITED KINGDOM Nazdar Limited Barton Road Heaton Mersey Stockport, England SK4 3EG Tel: +44 161 442 2111 Revision Date Jul -25-2012 Emergency Telephone Number USA: Chemtrec: 1-800-424-9300 Outside USA: Chemtrec: 1-703-527-3887 Website: www.nazdar.com MSDS Information: 1-913-422-1888 ext 2305 MSDS Contact: Regulatory Compliance email: regcomp@nazdar.com This product is a preparation. Health hazard information is based on its components. Appearance Flammable Properties Emergency Overview Eyes Skin Inhalation Ingestion Colored liquid Combustible liquid and vapor. Aspiration hazard. Harmful: may cause lung damage if swallowed. Irritant. May cause drowsiness and dizziness. May cause eye irritation. May cause skin irritation and/or dermatitis. May cause irritation of respiratory tract. Inhalation of high vapour concentrations may cause symptoms like headache, dizziness, tiredness, nausea and vomiting. Harmful if swallowed. Potential for aspiration if swallowed. Risk of serious damage to the lungs (by aspiration). Component CAS -No Weight % Stoddard solvent 8052-41-3 10 - 30 Talc 14807-96-6 10 - 30 Naphtha (petroleum), heavy aromatic 64742-94-5 5 - 10 Titanium dioxide 13463-67-7 5 - 10 Petroleum naphtha, light aromatic 64742-95-6 1 - 5 1,2,4-Trimethylbenzene (contaminant) 95-63-6 1 - 5 Naphthalene (contaminant) 91-20-3 < 1 1,3,5-Trimethylbenzene (contaminant) 108-67-8 < 0.5 Cobalt Compounds Trade Secret < 0.5 Cobalt Compounds Trade Secret < 0.5 Cumene (contaminant) 98-82-8 < 0.5 • Component names which have the word (contaminant) are constituents contained in Aromatic Hydrocarbon ingredients and are an integral part of the ingredient and cannot be separated. The percentage listed for the contaminant is as contained in the Hydrocarbon ingredient. (Example: 100% Hydrocarbon, 10% Contaminant A, 3% Contaminant B) Eye Contact Immediately flush with plenty of water. After initial flushing, removitEGEWEeses and continue flushing for at least 15 minutes. Get medical attentej�iyiOiFteliOkitatipn develops and persists. YV L A JUL 1 2 2013 PERMIT CENTER Product code 6112 - Medium Yellow Revision Date Jul -25-2012 Skin Contact Inhalation Ingestion Wash off immediately with soap and plenty of water. Use a mild soap if available. Rinse immediately with plenty of water for at least 15 minutes. Remove contaminated clothing. If irritation develops, get medical attention. If breathed in, move person into fresh air. If breathing is irregular or stopped, administer artificial respiration. Get medical attention immediately. If swallowed, DO NOT induce vomiting. Call a physician or Poison Control Centre immediately. Never give anything by mouth to an unconscious person. Flammable Properties Suitable Extinguishing Media Protective Equipment and Precautions for Firefighters Specific Hazards Arising from the Chemical Combustible liquid and vapor. Foam. Carbon dioxide (CO2). Dry chemical. Water spray. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. As in any fire, wear self-contained breathing apparatus pressure -demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Keep away from fire, sparks and heated surfaces. Cool containers / tanks with water spray. Fire or intense heat may cause violent rupture of packages. Thermal decomposition can lead to release of irritating gases and vapours. Burning produces obnoxious and toxic fumes. Personal Precautions Methods for Cleaning Up Environmental Precautions Remove all sources of ignition. Ventilate the area. Avoid breathing dust or vapor. Avoid contact with skin, eyes and clothing. Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13). Do not use sparking tools. Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. Handling Storage Avoid contact with skin, eyes and clothing. Ensure adequate ventilation. Remove and wash contaminated clothing before re -use. Discard contaminated shoes. When using do not smoke. Do not take internally. Harmful or fatal if swallowed. Take notice of the directions of use on the label. Keep containers tightly closed in a dry, cool and well -ventilated place. Keep container closed when not in use. Keep out of the reach of children. Keep away from heat and sources of ignition. Exposure Guidelines Component ACGIH TLV OSHA PEL NIOSH IDLH _ Ontario TWAEV Mexico OEL (TWA) . • • Page 217 Product code 6112 - Medium Yellow Revision Date Jul -25-2012 Stoddard solvent TWA: 100 ppm TWA: 100 ppm TWA: 525 mg/m3 TWA: 500 ppm TWA: 2900 mg/m3 20000 mg/m3 TWA: 525 mg/m3 TWA/LMPE-PPT: 100 ppm TWA/LMPE-PPT: 523 mg/m3 STEULMPE-CT: 200 ppm STEULMPE-CT: 1050 mg/m3 Talc TWA: 2 mg/m3 (particulate matter) TWA: 2 mg/m3 (respirable dust) 1000 mg/m3 TWA: 2 mg/m3 (respirable) TWA/LMPE-PPT: 2 mg/m3 (respirable fraction) Titanium dioxide TWA: 10 mg/m3 TWA: 10 mg/m3 (total dust) TWA: 15 mg/m3 (total dust) 5000 mg/m3 TWA:.10 mg/m3 (total dust) TWA/LMPE-PPT: 10 mg/m3 (as Ti) STEULMPE-CT: 20 mg/m3 (as Ti) Naphthalene (contaminant) TWA: 10 ppm STEL: 15 ppm Skin TWA: 10 ppm TWA: 50 mg/m3 STEL: 15 ppm STEL: 75 mg/m3 250 ppm TWA: 10 ppm STEL: 15 ppm . Skin TWA/LMPE-PPT: 10 ppm TWA/LMPE-PPT: 50 mg/m3 STEULMPE-CT: 15 ppm STEULMPE-CT: 75 mg/m3 Cumene (contaminant) TWA: 50 ppm TWA: 50 ppm TWA: 245 mg/m3 Skin 900 ppm (10% LEL) TWA: 50 ppm TWA/LMPE-PPT: 50 ppm TWA/LMPE-PPT: 245 mg/m3 STEULMPE-CT: 75 ppm STEULMPE-CT: 365 mg/m3 Engineering Measures Personal Protective Equipment Respiratory Protection Eye Protection Skin Protection General Hygiene Considerations Use ventilation adequate to keep exposures below recommended exposure limits. See MSDS. In case of insufficient ventilation, wear suitable respiratory equipment. Use the indicated respiratory protection if the occupational exposure limit is exceeded and/or in case of product release (dust). Respirator with a vapour filter. Ensure that eyewash stations and safety showers are close to the workstation location.. Avoid contact with eyes. Safety glasses with side -shields. Goggles. Face -shield. Wear protective gloves/clothing. Solvent -resistant apron and boots. Handle in accordance with good industrial hygiene and safety practice. Wash hands before eating, drinking, or smoking. Remove and wash contaminated clothing before re -use. Avoid contact with skin, eyes and clothing. Wear suitable gloves and eye/face protection. Regular cleaning of equipment, work area and clothing is recommended. ;PHYSICAL9 AM CHEIIIIICAL PROPERTIES Appearance Odor pH Boiling point/Boiling Range Freezing Point/Range Evaporation Rate Vapour Pressure Flammability (solid, gas) Colored liquid Characteristic No information available >149 °C / >300 °F No information available No information available No information available No information available Flash Point 43 °C/ 110 °F Method Setaflash closed cup Weight Per Gallon (lbs/gal) 9.02 VOC by weight % 36.59 VOC lbs/gal (less water) 3.31 Physical State Odor Threshold Autoignitlon Temperature Melting Point/Range Solubility Partition Coefficient (n-octanollwater) Vapour Density Liquid No information available No information available No information available No information available No information available Heavier than air Flammability Limits in Air Upper No information available Lower No information available Photochemically Reactive Yes Specific Gravity 1.08 VOC by volume % 42.79 VOC grams/liter (less water) 396.06 Page 3/7 Product code 6112 - Medium Yellow 4 Revision Date Jul -25-2012 rt , 1 etTABILIT IS, .�;.�.,.-s'� Chemical Stability Conditions to Avoid Incompatible Products Stable under normal conditions. Heat, flames and sparks. Strong acids. Strong bases. Strong oxidizing agents. Reducing agents. Hazardous Decomposition Products Thermal decomposition can lead to release of irritating gases and vapours. Carbon dioxide (CO2). Carbon monoxide. Possibility of Hazardous Reactions None under normal processing. 1.tiiNFO.RMAn Acute Toxicity Component LD50 Oral LD50 Dermal LC50 Inhalation Naphtha (petroleum), heavy aromatic >5000 mg/kg ( Rat) >2000 mg/kg ( Rabbit) >590 mg/m3 ( Rat) 4.h Titanium dioxide >10000 mg/kg ( Rat ) Naphthalene (contaminant) Petroleum naphtha, light aromatic 8400 mg/kg ( Rat) >2000 mg/kg ( Rabbit) 3400 ppm ( Rat) 4 h >5.2 mg/L (Rat) 4h 1,2,4-Trimethylbenzene (contaminant) 3400 mg/kg ( Rat) >3160 mg/kg ( Rabbit) 18 g/m3 ( Rat) 4 h Naphthalene (contaminant) 490 mg/kg ( Rat) >2500 mg/kg ( Rat) >20 g/kg ( Rabbit ) >340 mg/m3 ( Rat) 1 h 1,3,5-Trimethylbenzene (contaminant) 5000 mg/kg ( Rat) 24 g/m3 ( Rat) 4 h Cumene (contaminant) 1400 mg/kg ( Rat) >3160 mg/kg ( Rabbit) 39000 mg/m3 ( Rat) 4 h Chronic Toxicity Component ACGIH IARC NTP OSHA Titanium dioxide Group 2B X Naphthalene (contaminant) Group 2B Reasonably Anticipated X Cobalt Compounds Group 2B X Cobalt Compounds Group 2B X Cumene (contaminant) Group 2B X Legend: IARC: (International Agency for Research on Cancer) NTP: (National Toxicity Program) OSHA: (Occupational Safety & Health Administration) Sensitisation No information available Mutagenic Effects No information available Reproductive Effects No information available Developmental hazard No information available Teratogenicity No information available Group 28 - Possibly Carcinogenic to Humans Reasonably Anticipated to be a Human Carcinogen X - Present Chronic Effects Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may result in adverse health effect, such as mucous membrane and respiratory system irritation and adverse effect on kidney, liver and central nervous system. Blood, Central nervous system, Central Vascular System, Eyes, Kidney, Respiratory system, Skin. Target Organ Effects tottoloor FO11.. T`i'OI� Page 417 Product code 6112 - Medium Yellow Revision Date Jul -25-2012 Ecotoxicity We have no quantitative data concerning the ecological effects of this product. Should not be released into the environment. Component Algae Fish Water Flea Talc 3.63 96h LC50 Brachydanio rerio: >100 g/L [semi -static] 3.3 Naphtha (petroleum), heavy aromatic 3.55 96h LC50 Lepomis macrochirus: 1740 mg/L [static] 96h LC50 Pimephales promelas: 19 mg/L [static] 96h LC50 Pimephales promelas: 41 mg/L 96h LC50 Pimephales promelas: 45 mg/L [flow-through] Petroleum naphtha, light aromatic 96h LC50 Oncorhynchus mykiss: 9.22 mg/L 48h EC50 Daphnia magna: 6.14 mg/L 1,2,4-Trimethylbenzene (contaminant) 96h LC50 Pimephales promelas: 7.19 - 8.28 mg/L [flow-through] 48h EC50 Daphnia magna: 6.14 mg/L Naphthalene (contaminant) 72h EC50 Skeletonema costatum: 0.4 mg/L 96h LC50 Oncorhynchus mykiss: 0.91 - 2.82 mg/L [static] 96h LC50 Pimephales promelas: 5.74 - 6.44 mg/L [flow-through] 96h LC50 Oncorhynchus mykiss: 1.6 mg/L [flow-through] 96h LC50 Pimephales promelas: 1.99 mg/L [static] 96h LC50 Lepomis macrochirus: 31.0265 mg/L [static] 48h EC50 Daphnia magna: 1.09 - 3.4 mg/L [static] 48h EC50 Daphnia magna: 1.96 mg/L [Flow through] 48h LC50 Daphnia magna: 2.16 mg/L 1,3,5-Trimethylbenzene (contaminant) 96h LC50 Pimephales promelas: 3.48 mg/L 24h EC50 Daphnia magna: 50 mg/L Cumene (contaminant) 72h EC50 Pseudokirchneriella subcapitata: 2.6 mg/L 96h LC50 Pimephales promelas: 6.04 - 6.61 mg/L [flow-through] 96h LC50 Oncorhynchus mykiss: 2.7 mg/L [semi -static] 96h LC50 Oncorhynchus mykiss: 4.8 mg/L [flow-through] 96h LC50 Poecilia reticulata: 5.1 mg/L [semi -static] 48h EC50 Daphnia magna: 7.9 -14.1 mg/L [static] 48h EC50 Daphnia magna: 0.6 mg/L Persistence and Degradability No information available Bioaccumulation No information available Mobility in Environmental Media No information available Component log Pow Naphtha (petroleum), heavy aromatic 4.5 1,2,4-Trimethylbenzene (contaminant) 3.63 Naphthalene (contaminant) 3.3 Cumene (contaminant) 3.55 •Dison` ktbPiSIDERATI Waste Disposal Methods Contaminated Packaging Dispose of contents/container in accordance with local regulation. Empty containers should be taken to an approved waste handling site for recycling or disposal. 0•100'..00)4000AT101 DOT Page 5 / 7 Product code 6112 - Medium Yellow Revision Date Jul -25-2012 UN1210, Printing Ink, 3, III In the U.S. and Canada, this material may be reclassified as a combustible liquid and is not regulated, via surface transportation, in containers less than 119 gallons or 450 liters [per 49 CFR 173.150 (f)] [per Transportation of Dangerous Goods Regulations/Clear Language Part 1.33]. ICAO/IATA UN1210, Printing Ink, 3, III IMDG/IMO UN1210, Printing Ink, 3, III s•s ,REGULATORY ;INFORMATION` International Inventories Listed on TSCA. For further information, please contact: Manufacturer, importer, supplier U.S. Federal Regulations SARA 313 The following components are subject to re in Component CAS -No Weight % SARA 313 - Threshold Pennsylvania Right To Know Stoddard solvent X Values Naphthalene (contaminant) 91-20-3 < 1 0.1 1,2,4-Trimethylbenzene (contaminant) 95-63-6 1 - 5 1.0 Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act Section 112 (40 CFR 61). U.S. State Regulations Component Massachusetts Right To Know Minnesota Right To Know New Jersey Right To Know Pennsylvania Right To Know Stoddard solvent X X X X Talc X X X X Titanium dioxide X X X X 1,2,4-Trimethylbenzene (contaminant) X X X X • Naphthalene (contaminant) X X X X 1,3,5-Trimethylbenzene (contaminant) X Not Listed Not Listed Not Listed Cobalt Compounds Not Listed Not Listed X X Cobalt Compounds Not Listed Not Listed X X Cumene (contaminant) X X X X California Prop. 65 WARNING! This product contains a chemical known in the State of Califomia to cause cancer and / or WARNING! This product contains a chemical known in the State of California to cause birth defects or other reproductive harm Component CAS -No Weight % Titanium dioxide 13463-67-7 5 - 10 Naphthalene (contaminant) 91-20-3 < 1 Cumene (contaminant) 98-82-8 < 0.5 Canada This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the information required by the CPR Component WHMIS Classifications of Components Stoddard solvent B3,D2B Talc D2A Titanium dioxide D2A Petroleum naphtha, light aromatic B3,D2B 1,2,4-Trimethylbenzene (contaminant) B3 Naphthalene (contaminant) B4,D2A 1,3,5-Trimethylbenzene (contaminant) B3 Page 6/7 Product code 6112 - Medium Yellow Revision Date Jul -25-2012 ICumene (contaminant) B2,D2A Component NPRI - National Pollutant Release Inventory Stoddard solvent Part 5 Substance Part 5, Other Groups and Mixtures Naphtha (petroleum), heavy aromatic Part 5 Substance Part 5, Other Groups and Mixtures Petroleum naphtha, light aromatic Part 5 Substance Part 5, Other Groups and Mixtures 1,2,4-Trimethylbenzene (contaminant) Part 4 Substance Part 1, Group 1 Substance Part 5, Individual Substance Naphthalene (contaminant) Part 1, Group 1 Substance 1,3,5-Trimethylbenzene (contaminant) Part 4 Substance Part 5, Isomer Groups Cobalt Compounds Part 1, Group 1 Substance Cobalt Compounds Part 1, Group 1 Substance Cumene (contaminant) Part 4 Substance Part 1, Group 1 Substance Regulation (EC) No. 1907/2006 (REACH), Article 57 This product does not contain substances of very high concern (Regulation (EC) No. 1907/2006 (REACH), Article 57) HMIS: Health 2* Flammability 2 Reactivity 0 PPE X kitr 00RM4T11 Revision Date Revision Note Jul -25-2012 New MSDS format Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text End of MSDS Page 717 crr- Material Safety Data Sheet Prepared in accordance with ISO 11014-1/ANSI standard 2400.1.2004 Print Date Jul -25-2012 Revision Date Jul -25-2012 )DI D:COM 34i9 i.00# ICATt Product code Product name Product category Manufacturer or supplier's details UNITED STATES Nazdar Company 8501 Hedge Lane Terrace Shawnee, KS 66227 Tel: 1-913-422-1888 Tel: 1-800-677-4657 Fax: 1-913-422-2294 6119 Fire Red 6100 Series Fast Dry Enamel Screen Ink UNITED KINGDOM Nazdar Limited Barton Road Heaton Mersey Stockport, England SK4 3EG Tel: +44 161 442 2111 Emergency Telephone Number USA: Chemtrec: 1-800-424-9300 Outside USA: Chemtrec: 1-703-527-3887 Website: www.nazdar.com MSDS Information: 1-913-422-1888 ext 2305 MSDS Contact: Regulatory Compliance email: regcomp@nazdar.com DS;IDENTIFICATI This product is a preparation. Health hazard information is based on its components. Appearance Flammable Properties Emergency Overview Eyes Skin Inhalation Ingestion Colored liquid Combustible liquid and vapor. Aspiration hazard. Harmful: may cause lung damage if swallowed. Irritant. May cause drowsiness and dizziness. Causes eye irritation. May cause skin irritation and/or dermatitis. May cause irritation of respiratory tract. Inhalation of high vapour concentrations may cause symptoms like headache, dizziness, tiredness, nausea and vomiting. Harmful if swallowed. Potential for aspiration if swallowed. Risk of serious damage to the lungs (by aspiration). 1« 3: OMPOSITIONiii0. RMATIO 00,01 GREDIENTS Component CAS -No Weight % Stoddard solvent 8052-41-3 10 - 30 Naphtha (petroleum), heavy aromatic 64742-94-5 10 - 30 Talc 14807-96-6 10 - 30 Petroleum naphtha, light aromatic 64742-95-6 1 - 5 1,2,4-Trimethylbenzene (contaminant) 95-63-6 1 - 5 Naphthalene (contaminant) 91-20-3 < 1 1,3,5-Trimethylbenzene (contaminant) 108-67-8 < 0.5 Cobalt Compounds Trade Secret < 0.5 Cobalt Compounds Trade Secret < 0.5 Cumene (contaminant) 98-82-8 < 0.5 • Component names which have the word (contaminant) are constituents contained in Aromatic Hydrocarbon ingredients and are an integral part of the ingredient and cannot be separated. The percentage listed for the contaminant is as contained in the Hydrocarbon ingredient. (Example: 100% Hydrocarbon, 10% Contaminant A, 3% Contaminant 8) Eye Contact Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get medical attentiorpEretttitf6ritation develops and persists. CITY OF T U K W I L A b'i JUL 122013 PERMIT CENTER Product code 6119 - Fire Red Revision Date Jul -25-2012 Skin Contact Inhalation Ingestion Wash off immediately with soap and plenty of water. Use a mild soap if available. Rinse immediately with plenty of water for at least 15 minutes. Remove contaminated clothing. If irritation develops, get medical attention. If breathed in, move person into fresh air. If breathing is irregular or stopped, administer artificial respiration. Get medical attention immediately. If swallowed, DO NOT induce vomiting. Call a physician or Poison Control Centre immediately. Never give anything by mouth to an unconscious person. FIRE.-FIGHTINGMEASUR Flammable Properties Combustible liquid and vapor. Suitable Extinguishing Media Foam. Carbon dioxide (CO2). Dry chemical. Water spray. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure -demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Keep away from fire, sparks and heated surfaces. Cool containers / tanks with water spray. Fire or intense heat may cause violent rupture of packages. Specific Hazards Arising from the Thermal decomposition can lead to release of irritating gases and vapours. Burning produces obnoxious and toxic fumes. Chemical El '11:16tif 413 AVCIDENTALI+REI EASEAMEA'SUR! Personal Precautions Methods for Cleaning Up Environmental Precautions Handling Storage Remove all sources of ignition. Ventilate the area. Avoid breathing dust or vapor. Avoid contact with skin, eyes and clothing. Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13). Do not use sparking tools. Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. ':HAND�1NGAfiND7 S1 BAGS k',�. �i�'s5S .x ti Avoid contact with skin, eyes and clothing. Ensure adequate ventilation. Remove and wash contaminated clothing before re -use. Discard contaminated shoes. When using do not smoke. Do not take internally. Harmful or fatal if swallowed. Take notice of the directions of use on the label. Keep containers tightly closed in a dry, cool and well -ventilated place. Keep container closed when not in use. Keep out of the reach of children. Keep away from heat and sources of ignition. 11 EXPOSURE CON�TROLjS/PERSONA. PROTECTION Exposure Guidelines Component I ACGIH TLV OSHA PEL I NIOSH IDLH _I Ontario TWAEV I Mexico OEL (TWA) • Page 2/7 r A Product code 6119 - Fire Red Revision Date Jul -25-2012 Stoddard solvent TWA: 100 ppm TWA: 100 ppm TWA: 525 mg/m3 TWA: 500 ppm TWA: 2900 mg/m3 20000 mg/m3 TWA: 525 mg/m3 TWA/LMPE-PPT: 100 ppm TWA/LMPE-PPT: 523 mg/m3 STEULMPE-CT: 200 ppm STEULMPE-CT: 1050 mg/m3 Talc TWA: 2 mg/m3 (particulate matter) TWA: 2 mg/m3 (respirable dust) 1000 mg/m3 TWA: 2 mg/m3 (respirable) TWA/LMPE-PPT: 2 mg/m3 (respirable fraction) Naphthalene (contaminant) TWA: 10 ppm STEL: 15 ppm Skin TWA: 10 ppm TWA: 50 mg/m3 STEL: 15 ppm STEL: 75 mg/m3 250 ppm TWA: 10 ppm STEL: 15 ppm Skin TWA/LMPE-PPT: 10 ppm TWA/LMPE-PPT: 50 mg/m3 STEL/LMPE-CT: 15 ppm STEULMPE-CT: 75 mg/m3 Cumene (contaminant) TWA: 50 ppm TWA: 50 ppm TWA: 245 mg/m3 Skin 900 ppm (10% LEL) TWA: 50 ppm TWA/LMPE-PPT: 50 ppm TWA/LMPE-PPT: 245 mg/m3 STEULMPE-CT: 75 ppm STEULMPE-CT: 365 mg/m3 Engineering Measures Personal Protective Equipment Respiratory Protection Eye Protection Skin Protection General Hygiene Considerations Use ventilation adequate to keep exposures below recommended exposure limits. See MSDS. In case of insufficient ventilation, wear suitable respiratory equipment. Use the indicated respiratory protection if the occupational exposure limit is exceeded and/or in case of product release (dust). Respirator with a vapour filter. Ensure that eyewash stations and safety showers are close to the workstation location. Avoid contact with eyes. Safety glasses with side -shields. Goggles. Face -shield. Wear protective gloves/clothing. Solvent -resistant apron and boots. Handle in accordance with good industrial hygiene and safety practice. Wash hands before eating, drinking, or smoking. Remove and wash contaminated clothing before re -use. Avoid contact with skin, eyes and clothing. Wear suitable gloves and eye/face protection. Regular cleaning of equipment, work area and clothing is recommended. 9:YPHY�SICAL AND CHE�UIIC''AL PRaO ERT1ES fga�� Appearance Odor pH Boiling point/Boiling Range Freezing Point/Range Evaporation Rate Vapour Pressure Flammability (solid, gas) Colored liquid Characteristic No information available >149 °C / >300 °F No information available No information available No information available No information available Flash Point 43°C/ 110 °F Method Setaflash closed cup Weight Per Gallon (lbs/gal) 8.56 VOC by weight % 39.99 VOC lbs/gal (less water) 3.43 Physical State Odor Threshold Autoignition Temperature Melting Point/Range Solubility Partition Coefficient (n-octanol/water) Vapour Density Liquid No information available No information available No information available No information available No information available Heavier than air Flammability Limits in Air Upper No information available Lower No information available Photochemically Reactive Yes Specific Gravity 1.03 VOC by volume % 44.39 VOC grams/liter (less water) 410.46 QAi •�,.M ih•l11'L ABILITY°�A ID.$ttE 1`C7'IVit Chemical Stability Stable under normal conditions. Page 3/7 Product code 6119 - Fire Red Revision Date Jul -25-2012 Conditions to Avoid Heat, flames and sparks. Incompatible Products Strong acids. Strong bases. Strong oxidizing agents. Reducing agents. Hazardous Decomposition Products Thermal decomposition can lead to release of irritating gases and vapours. Carbon dioxide (CO2). Carbon monoxide. Possibility of Hazardous Reactions None under normal processing. -n .;r got.. ,c p..: .. s y,,;. ,....r b •.. 1�1 �`�,�TOXIC;QLO,�GICALa INFORMATI� Acute Toxicity Component LD50 Oral LD50 Dermal LC50 Inhalation Naphtha (petroleum), heavy aromatic >5000 mg/kg ( Rat) >2000 mg/kg ( Rabbit) >590 mg/m3 ( Rat) 4 h Petroleum naphtha, light aromatic 8400 mg/kg ( Rat) >2000 mg/kg ( Rabbit) 3400 ppm ( Rat) 4 h >5.2mg/L (Rat) 4h 1,2,4-Trimethylbenzene (contaminant) 3400 mg/kg ( Rat) >3160 mg/kg ( Rabbit) -- 18 g/m3 ( Rat) 4 h Naphthalene (contaminant) 490 mg/kg ( Rat) >2500 mg/kg ( Rat) >20 g/kg ( Rabbit ) >340 mg/m3 ( Rat) 1 h 1,3,5-Trimethylbenzene (contaminant) 5000 mg/kg ( Rat) Group 2B 24 g/m3 ( Rat) 4 h Cumene (contaminant) 1400 mg/kg ( Rat) >3160 mg/kg ( Rabbit) 39000 mg/m3 ( Rat) 4 h Chronic Toxicity Component ACGIH IARC NTP OSHA Naphthalene (contaminant) Group 2B Reasonably Anticipated X Cobalt Compounds Group 2B X Cobalt Compounds Group 2B X Cumene (contaminant) Group 2B X IARC: (International Agency for Research on Cancer) NTP: (National Toxicity Program) OSHA: (Occupational Safety & Health Administration) Sensitisation No information available Mutagenic Effects No information available Reproductive Effects No information available Developmental hazard No information available Teratogenicity No information available Group 28 - Possibly Carcinogenic to Humans Reasonably Anticipated to be a Human Carcinogen X - Present Chronic Effects Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may result in adverse health effect, such as mucous membrane and respiratory system irritation and adverse effect on kidney, liver and central nervous system. Blood, Central nervous system, Central Vascular System, Eyes, Kidney, Respiratory system, Skin. Target Organ Effects -k0G1C4INFORMATIQ Ecotoxicity We have no quantitative data concerning the ecological effects of this product. Should not be released into the environment. Component j Algae Fish 1 Water Flea Page 4 / 7 Product code 6119 - Fire Red Revision Date Jul -25-2012 Naphtha (petroleum), heavy aromatic log Pow 96h LC50 Lepomis macrochirus: 1740 mg/L [static] 96h LC50 Pimephales promelas: 19 mg/L [static] 96h LC50 Pimephales promelas: 41 mg/L 96h LC50 Pimephales promelas: 45 mg/L [flow-through] 4.5 Talc 3.63 96h LC50 Brachydanio rerio: >100 g/L [semi -static] 3.3 Petroleum naphtha, light aromatic 3.55 96h LC50 Oncorhynchus mykiss: 9.22 mg/L 48h EC50 Daphnia magna: 6.14 mg/L 1,2,4-Trimethylbenzene (contaminant) 96h LC50 Pimephales promelas: 7.19 - 8.28 mg/L [flow-through] 48h EC50 Daphnia magna: 6.14 mg/L Naphthalene (contaminant) 72h EC50 Skeletonema costatum: 0.4 mg/L 96h LC50 Oncorhynchus mykiss: 0.91 - 2.82 mg/L [static] 96h LC50 Pimephales promelas: 5.74 - 6.44 mg/L [flow-through] 96h LC50 Oncorhynchus mykiss: 1.6 mg/L [flow-through] 96h LC50 Pimephales promelas: 1.99 mg/L [static] 96h LC50 Lepomis macrochirus: 31.0265 mg/L [static] 48h EC50 Daphnia magna: 1.09 - 3.4 mg/L [static] 48h EC50 Daphnia magna: 1.96 mg/L [Flow through] 48h LC50 Daphnia magna: 2.16 mg/L 1,3,5-Trimethylbenzene (contaminant) 96h LC50 Pimephales promelas: 3.48 mg/L 24h EC50 Daphnia magna: 50 mg/L Cumene (contaminant) 72h EC50 Pseudokirchneriella subcapitata: 2.6 mg/L 96h LC50 Pimephales promelas: 6.04 - 6.61 mg/L [flow-through] 96h LC50 Oncorhynchus mykiss: 2.7 mg/L [semi -static] 96h LC50 Oncorhynchus mykiss: 4.8 mg/L [flow-through] 96h LC50 Poecilia reticulata: 5.1 mg/L [semi -static] 48h EC50 Daphnia magna: 7.9 - 14.1 mg/L [static] 48h EC50 Daphnia magna: 0.6 mg/L Persistence and Degradability No information available Bioaccumulation No information available Mobility in Environmental Media No information available Component log Pow Naphtha (petroleum), heavy aromatic 4.5 1,2,4-Trimethylbenzene (contaminant) 3.63 Naphthalene (contaminant) 3.3 Cumene (contaminant) 3.55 ;I�ISPO; 'oNsiDIONrioN Waste Disposal Methods Contaminated Packaging Dispose of contents/container in accordance with local regulation. Empty containers should be taken to an approved waste handling site for recycling or disposal. NSP 0,51 ,00.0 T1N DOT UN1210, Printing Ink, 3, III In the U.S. and Canada, this material may be reclassified as a combustible liquid and is not regulated, via surface transportation, in containers less than 119 gallons or 450 liters [per 49 CFR 173.150 (f)] [per Transportation of Dangerous Goods Regulations/Clear Language Part 1.33]. ICAO/IATA UN1210, Printing Ink, 3, III IMDG/IMO Page 5/7 Product code 6119 - Fire Red Revision Date Jul -25-2012 UN1210, Printing Ink, 3, III n�RE��L'A'�'OR,Y�INFORNIATION International Inventories Listed on TSCA. For further information, please contact: Manufacturer, importer, supplier U.S. Federal Regulations SARA 313 The following components are subject to reporti Component CAS -No Weight % SARA 313 - Threshold Pennsylvania Right To Know Stoddard solvent X Values Naphthalene (contaminant)- 91-20-3 < 1 0.1 1,2,4-Trimethylbenzene (contaminant) 95-63-6 1 - 5 1.0 Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act Section 112 (40 CFR 61). U.S. State Regulations Component Massachusetts Right To Know Minnesota Right To Know New Jersey Right To Know Pennsylvania Right To Know Stoddard solvent X X X X Talc X X X X 1,2,4-Trimethylbenzene (contaminant) X X X X Naphthalene (contaminant) X X X X 1,3,5-Trimethylbenzene (contaminant) X Not Listed Not Listed Not Listed Cobalt Compounds Not Listed Not Listed X X Cobalt Compounds Not Listed Not Listed X X Cumene (contaminanty X X X X California Prop. 65 WARNING! This product contains a chemical known in the State of California to cause cancer and / or WARNING! This product contains a chemical known in the State of California to cause birth defects or other reproductive harm Component CAS -No Weight % Naphthalene (contaminant) 91-20-3 < 1 Cumene (contaminant) 98-82-8 < 0.5 Canada This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the information required by the CPR Component WHMIS Classifications of Components Stoddard solvent B3,D2B Talc D2A Petroleum naphtha, light aromatic B3,D2B 1,2,4-Trimethylbenzene (contaminant) B3 Naphthalene (contaminant) B4,D2A 1,3,5-Trimethylbenzene (contaminant) B3 Cumene (contaminant) _ B2,D2A Component NPRI - National Pollutant Release Inventory Stoddard solvent Part 5 Substance Part 5, Other Groups and Mixtures Naphtha (petroleum), heavy aromatic Part 5 Substance Part 5, Other Groups and Mixtures Petroleum naphtha, light aromatic Part 5 Substance Part 5, Other Groups and Mixtures Page 6/7 Product code 6119 - Fire Red Revision Date Jul -25-2012 1,2,4-Trimethylbenzene (contaminant) Part 4 Substance Part 1, Group 1 Substance Part 5, Individual Substance Naphthalene (contaminant) Part 1, Group 1 Substance 1,3,5-Trimethylbenzene (contaminant) Part 4 Substance Part 5, Isomer Groups Cobalt Compounds Part 1, Group 1 Substance Cobalt Compounds Part 1, Group 1 Substance Cumene (contaminant) Part 4 Substance Part 1, Group 1 Substance Regulation (EC) No. 1907/2006 (REACH), Article 57 This product does not contain substances of very high concern (Regulation (EC) No. 1907/2006 (REACH), Article 57) HMIS: Health 2* Flammability 2 Reactivity 0 PPE X ,6'„QTHER:1#0, ' MATIi Revision Date Revision Note Jul -25-2012 New MSDS format Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text End of MSDS Page 7/7 ink Technologies Material Safety Data Sheet Prepared in accordance with ISO 11014-1/ANSI standard Z400.1-2004 Print Date Jul -25-2012 Revision Date Jul -25-2012 PMRODUCT- AND CCMP. [I.DENTIFICAT;IAN Product code Product name Product category Manufacturer or supplier's details UNITED STATES Nazdar Company 8501 Hedge Lane Terrace Shawnee, KS 66227 Tel: 1-913-422-1888 Tel: 1-800-677-4657 Fax: 1-913-422-2294 6122 Ultra Blue 6100 Series Fast Dry Enamel Screen Ink UNITED KINGDOM Nazdar Limited Barton Road Heaton Mersey Stockport, England SK4 3EG Tel: +44 161 442 2111 Emergency Telephone Number USA: Chemtrec: 1-800-424-9300 Outside USA: Chemtrec: 1-703-527-3887 Website: www.nazdar.com MSDS Information: 1-913-422-1888 ext 2305 MSDS Contact: Regulatory Compliance email: regcomp@nazdar.com LIZARDS ;IDENTIFICATII This product is a preparation. Health hazard information is based on its components. Appearance Flammable Properties Emergency Overview Eyes Skin Inhalation Ingestion Colored liquid Combustible liquid and vapor. Aspiration hazard. Harmful: may cause lung damage if swallowed. Irritant. May cause drowsiness and dizziness. Causes eye irritation. May cause skin irritation and/or dermatitis. May cause irritation of respiratory tract. Inhalation of high vapour concentrations may cause symptoms like headache, dizziness, tiredness, nausea and vomiting. Harmful if swallowed. Potential for aspiration if swallowed. Risk of serious damage to the lungs (by aspiration). �COMPA�S�1_•'��ION/1NFORM/t�'It LtNGREDIENTS Component CAS -No Weight % Stoddard solvent 8052-41-3 10 - 30 Naphtha (petroleum), heavy aromatic 64742-94-5 10 - 30 Talc 14807-96-6 10 - 30 Titanium dioxide 13463-67-7 1 - 5 Copper Phthalocyanine Compound Trade Secret 1 - 5 1,2,4-Trimethylbenzene (contaminant) 95-63-6 1 - 5 Petroleum naphtha, light aromatic 64742-95-6 1 - 5 Naphthalene (contaminant) 91-20-3 < 1 1,3,5-Trimethylbenzene (contaminant) 108-67-8 < 0.5 Cobalt Compounds Trade Secret < 0.5 Cobalt Compounds Trade Secret < 0.5 Cumene (contaminant) 98-82-8 < 0.5 • Component names which have the word (contaminant) are constituents contained in Aromatic Hydrocarbon ingredients and are an integral part of the ingredient and cannot be separated. The percentage listed for the contaminant is as contained in the Hydrocarbon ingredient. (Example: 100% Hydrocarbon, 10% Contaminant A, 3% Contaminant B) ST AiDME1 $URE 1311 Page 1 / 7 RECEIVED CITY OF TUKWILA JUL 122013 PERMIT CENTER Product code 6122 - Ultra Blue Revision Date Jul -25-2012 Eye Contact Skin Contact Inhalation Ingestion Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get medical attention immediately if irritation develops and persists. Wash off immediately with soap and plenty of water. Use a mild soap if available. Rinse immediately with plenty of water for at least 15 minutes. Remove contaminated clothing. If irritation develops, get medical attention. If breathed in, move person into fresh air. If breathing is irregular or stopped, administer artificial respiration. Get medical attention immediately. If swallowed, DO NOT induce vomiting. Call a physician or Poison Control Centre immediately. Never give anything by mouth to an unconscious person. • t Ezi.TFI`GH`I1 NGiM EASU RES Flammable Properties Suitable Extinguishing Media Protective Equipment and Precautions for Firefighters Combustible liquid and vapor. Foam. Carbon dioxide (CO2). Dry chemical. Water spray. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. As in any fire, wear self-contained breathing apparatus pressure -demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Keep away from fire, sparks and heated surfaces. Cool containers / tanks with water spray. Fire or intense heat may cause violent rupture of packages. Specific Hazards Arising from the Thermal decomposition can lead to release of irritating gases and vapours. Burning produces obnoxious and toxic fumes. Chemical Z p*., v ,j el aa•�xav �wuN xn t f y .� n 'ax- �n , or FitEL•EASEIf1EAStiRE$ Personal Precautions Methods for Cleaning Up Environmental Precautions Remove all sources of ignition. Ventilate the area. Avoid breathing dust or vapor. Avoid contact with skin, eyes and clothing. Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13). Do not use sparking tools. Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. ,,,.mss. Handling Storage Avoid contact with skin, eyes and clothing. Ensure adequate ventilation. Remove and wash contaminated clothing before re -use. Discard contaminated shoes. When using do not smoke. Do not take internally. Harmful or fatal if swallowed. Take notice of the directions of use on the label. Keep containers tightly closed in a dry, cool and well -ventilated place. Keep container closed when not in use. Keep out of the reach of children. Keep away from heat and sources of ignition. XP SURE,CtOTROLS/P itSONAL,` 097ECTIi Exposure'Guidelines Component ,ar ACGIH TLV „ I O3HgPEL . I NIOSHA13tH "I Ontario TWAEV 1 Mexico OEL (TWA) Page 2/7 Product code 6122 - Ultra Blue Revision Date Jul -25-2012 Stoddard solvent TWA: 100 ppm TWA: 100 ppm TWA: 525 mg/m3 TWA: 500 ppm TWA: 2900 mg/m3 20000 mg/m3 TWA: 525 mg/m3 TWA/LMPE-PPT: 100 ppm TWA/LMPE-PPT: 523 mg/m3 STEULMPE-CT: 200 ppm STEULMPE-CT: 1050 mg/m3 Talc TWA: 2 mg/m3 (particulate matter) TWA: 2 mg/m3 (respirable dust) 1000 mg/m3 TWA: 2 mg/m3 (respirable) TWA/LMPE-PPT: 2 mg/m3 (respirable fraction) Titanium dioxide TWA: 10 mg/m3 TWA: 10 mg/m3 (total dust) TWA: 15 mg/m3 (total dust) 5000 mg/m3 TWA: 10 mg/m3 (total dust) TWA/LMPE-PPT: 10 mg/m3 (as Ti) STEULMPE-CT: 20 mg/m3 (as Ti) Naphthalene (contaminant) TWA: 10 ppm STEL: 15 ppm Skin TWA: 10 ppm TWA: 50 mg/m3 STEL: 15 ppm STEL: 75 mg/m3 250 ppm TWA: 10 ppm STEL: 15 ppm Skin TWA/LMPE-PPT: 10 ppm TWA/LMPE-PPT: 50 mg/m3 STEULMPE-CT: 15 ppm STEULMPE-CT: 75 mg/m3 Cumene (contaminant) TWA: 50 ppm TWA: 50 ppm TWA: 245 mg/m3 Skin 900 ppm (10% LEL) TWA: 50 ppm TWA/LMPE-PPT: 50 ppm TWA/LMPE-PPT: 245 mg/m3 STEULMPE-CT: 75 ppm STEULMPE-CT: 365 mg/m3 Engineering Measures Personal Protective Equipment Respiratory Protection Eye Protection Skin Protection General Hygiene Considerations Use ventilation adequate to keep exposures below recommended exposure limits. See MSDS. In case of insufficient ventilation, wear suitable respiratory equipment. Use the indicated respiratory protection if the occupational exposure limit is exceeded and/or in case of product release (dust). Respirator with a vapour filter. Ensure that eyewash stations and safety showers are close to the workstation location. Avoid contact with eyes. Safety glasses with side -shields. Goggles. Face -shield. Wear protective gloves/clothing. Solvent -resistant apron and boots. Handle in accordance with good industrial hygiene and safety practice. Wash hands before eating, drinking, or smoking. Remove and wash contaminated clothing before re -use. Avoid contact with skin, eyes and clothing. Wear suitable gloves and eye/face protection. Regular cleaning of equipment, work area and clothing is recommended. ►ND °CHEMIG�IIL�PROPERT ES.��F`'%'4� � ' Appearance Odor pH Boiling point/Boiling Range Freezing Point/Range Evaporation Rate Vapour Pressure Flammability (solid, gas) Colored liquid Characteristic No information available >149 °C / >300 °F No information available No information available No information available No information available Flash Point 43 °C / 110 °F Method Setaflash closed cup Weight Per Gallon (lbs/gal) 8.81 • VOC by weight % 39.29 VOC lbs/gal (less water) 3.46 Physical State Odor Threshold Autoignition Temperature Melting Point/Range Solubility Partition Coefficient (n-octanol/water) Vapour Density Liquid No information available No information available No information available No information available No information available Heavier than air Flammability Limits in Air Upper No information available Lower No information available Photochemically Reactive Yes Specific Gravity 1.06 VOC by volume % 44.84 VOC grams/liter (less water) 415.08 Page 317 Product code 6122 - Ultra Blue Revision Date Jul -25-2012 t I OST�AB i LIT�lf111 1 rREACt101 Chemical Stability Conditions to Avoid Incompatible Products Stable under normal conditions. Heat, flames and sparks. Strong acids. Strong bases. Strong oxidizing agents. Reducing agents. Hazardous Decomposition Products Thermal decomposition can lead to release of irritating gases and vapours. Carbon dioxide (CO2). Carbon monoxide. Possibility of Hazardous Reactions None under normal processing. Acute Toxicity Component LD50 Oral LD50 Dermal LC50 Inhalation Naphtha (petroleum), heavy aromatic >5000 mg/kg ( Rat) >2000 mg/kg ( Rabbit) >590 mg/m3 ( Rat) 4 h Titanium dioxide >10000 mg/kg ( Rat ) Naphthalene (contaminant) 1,2,4-Trimethylbenzene (contaminant) 3400 mg/kg ( Rat) >3160 mg/kg ( Rabbit) 18 g/m3 ( Rat) 4 h Petroleum naphtha, light aromatic 8400 mg/kg ( Rat) >2000 mg/kg ( Rabbit) 3400 ppm ( Rat) 4 h >5.2 mg/L (Rat) 4h Naphthalene (contaminant) 490 mg/kg ( Rat) >2500 mg/kg ( Rat) >20 g/kg (Rabbit_) >340 mg/m3 (Rat) 1 h 1,3,5-Trimethylbenzene (contaminant) 5000 mg/kg ( Rat) 24 g/m3 ( Rat) 4 h Cumene (contaminant) 1400 mg/kg (Rat) _ >3160 mg/kg ( Rabbit) 39000 mg/m3 ( Rat) 4 h Chronic Toxicity Component ACGIH IARC NTP OSHA Titanium dioxide Group 2B X Naphthalene (contaminant) Group 2B Reasonably Anticipated X Cobalt Compounds Group 2B X Cobalt Compounds Group 2B X Cumene (contaminant) Group 2B X Legend: IARC: (International Agency for Research on Cancer) NTP: (National Toxicity Program) OSHA: (Occupational Safety & Health Administration) Sensitisation No information available Mutagenic Effects No information available Reproductive Effects No information available Developmental hazard No information available Teratogenicity No information available Group 28 - Possibly Carcinogenic to Humans Reasonably Anticipated to be a Human Carcinogen X - Present Chronic Effects Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may result in adverse health effect, such as mucous membrane and respiratory system irritation and adverse effect on kidney, liver and central nervous system. Blood, Central nervous system, Central Vascular System, Eyes, Kidney, Liver, Respiratory system, Skin. Target Organ Effects �QRMAT;11 Page 417 Product code 6122 - Ultra Blue Revision Date Jul -25-2012 Ecotoxicity We have no quantitative data concerning the ecological effects of this product. Should not be released into the environment. Component Algae Fish Water Flea Naphtha (petroleum), heavy aromatic 6.6 96h LC50 Lepomis macrochirus: 1740 mg/L [static] 96h LC50 Pimephales promelas: 19 mg/L [static] 96h LC50 Pimephales promelas: 41 mg/L 96h LC50 Pimephales promelas: 45 mg/L [flow-through] 3.63 Talc 3.3 96h LC50 Brachydanio rerio: >100 g/L [semi -static] 3.55 Copper Phthalocyanine Compound 48h LC50 Oryzias latipes: >100 mg/L [static] 1,2,4-Trimethylbenzene (contaminant) 96h LC50 Pimephales promelas: 7.19 - 8.28 mg/L [flow-through] 48h EC50 Daphnia magna: 6.14 mg/L Petroleum naphtha, light aromatic 96h LC50 Oncorhynchus mykiss: 9.22 mg/L 48h EC50 Daphnia magna: 6.14 mg/L Naphthalene (contaminant) 72h EC50 Skeletonema costatum: 0.4 mg/L 96h LC50 Oncorhynchus mykiss: 0.91 - 2.82 mg/L [static] 96h LC50 Pimephales promelas: 5.74 - 6.44 mg/L [flow-through] 96h LC50 Oncorhynchus mykiss: 1.6 mg/L [flow-through] 96h LC50 Pimephales promelas: 1.99 mg/L [static] 96h LC50 Lepomis macrochirus: 31.0265 mg/L [static] 48h EC50 Daphnia magna: 1.09 - 3.4 mg/L [static] ... 48h EC50 Daphnia magna: 1.96 mg/L [Flow through] 48h LC50 Daphnia magna: 2.16 mg/L 1,3,5-Trimethylbenzene (contaminant) 96h LC50 Pimephales promelas: 3.48 mg/L 24h EC50 Daphnia magna: 50 mg/L Cumene (contaminant) 72h EC50 Pseudokirchneriella subcapitata: 2.6 mg/L 96h LC50 Pimephales promelas: 6.04 - 6.61 mg/L [flow-through] 96h LC50 Oncorhynchus mykiss: 2.7 mg/L [semi -static] 96h LC50 Oncorhynchus mykiss: 4.8 mg/L [flow-through] 96h LC50 Poecilia reticulata: 5.1 mg/L [semi -static] 48h EC50 Daphnia magna: 7.9 - 14.1 mg/L [static] 48h EC50 Daphnia magna: 0.6 mg/L Persistence and Degradability Bioaccumulation Mobility in Environmental Media No information available No information available No information available Component �1;3tQSP log Pow Naphtha (petroleum), heavy aromatic 4.5 Copper Phthalocyanine Compound 6.6 1,2,4-Trimethylbenzene (contaminant) 3.63 Naphthalene (contaminant) 3.3 Cumene (contaminant) 3.55 Waste Waste Disposal Methods Contaminated Packaging -.71.014S, Dispose of contents/container in accordance with local regulation. Empty containers should be taken to an approved waste handling site for recycling or disposal. ITRANSPORTINFORMATI DOT Page 5/7 Product code 6122 - Ultra Blue Revision Date Jul -25-2012 UN1210, Printing Ink, 3, III In the U.S. and Canada, this material may be reclassified as a combustible liquid and is not regulated, via surface transportation, in containers less than 119 gallons or 450 liters [per 49 CFR 173.150 (f)] [per Transportation of Dangerous Goods Regulations/Clear Language Part 1.33]. ICAO/IATA UN1210, Printing Ink, 3, III IMDG/IMO UN1210, Printing Ink, 3, III 15: REGULATORY INFORMATION. ItAk International Inventories Listed on TSCA. For further information, please contact: Manufacturer, importer, supplier U.S. Federal Regulations SARA 313 The following components are subject to reporti Component CAS -No Weight % SARA 313 - Threshold Pennsylvania Right To Know Stoddard solvent X Values Naphthalene (contaminant) - 91-20-3 < 1 0.1 - 1,2,4-Trimethylbenzene (contaminant) 95-63-6 1 - 5 1.0 Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act Section 112 (40 CFR 61). U.S. State Regulations Component Massachusetts Right To Know Minnesota Right To Know New Jersey Right To Know Pennsylvania Right To Know Stoddard solvent X X X X Talc X X X X Titanium dioxide X X X X Copper Phthalocyanine Compound Not Listed Not Listed X X 1,2,4-Trimethylbenzene (contaminant) X X X X Naphthalene (contaminant) X X X X 1,3,5-Trimethylbenzene (contaminant) X Not Listed Not Listed Not Listed Cobalt Compounds Not Listed Not Listed X X Cobalt Compounds Not Listed Not Listed X X Cumene (contaminant) X X X X California Prop. 65 WARNING! This product contains a chemical known in the State of California to cause cancer and / or WARNING! This product contains a chemical known in the State of California to cause birth defects or other reproductive harm Component CAS -No Weight % Titanium dioxide 13463-67-7 1 - 5 Naphthalene (contaminant) 91-20-3 < 1 Cumene (contaminant) 98-82-8 < 0.5 Canada This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the information required by the CPR Component WHMIS Classifications of Components Stoddard solvent B3,D2B Talc D2A Titanium dioxide D2A - Copper Phthalocyanine Compound Uncontrolled product according to WHMIS classification criteria 1,2,4-Trimethylbenzene (contaminant) B3 Petroleum naphtha, light aromatic B3,D2B Page 617 Product code 6122 - Ultra Blue Revision Date Jul -25-2012 Naphthalene (contaminant) B4,D2A 1,3,5-Trimethylbenzene (contaminant) B3 Cumene (contaminant) B2,D2A Component NPRI - National Pollutant Release Inventory Stoddard solvent Part 5 Substance Part 5, Other Groups and Mixtures Naphtha (petroleum), heavy aromatic Part 5 Substance Part 5, Other Groups and Mixtures Copper Phthalocyanine Compound Part 1, Group 1 Substance 1,2,4-Trimethylbenzene (contaminant) Part 4 Substance Part 1, Group 1 Substance Part 5, Individual Substance Petroleum naphtha, light aromatic Part 5 Substance Part 5, Other Groups and Mixtures Naphthalene (contaminant) Part 1, Group 1 Substance 1,3,5-Trimethylbenzene (contaminant) Part 4 Substance Part 5, Isomer Groups Cobalt Compounds Part 1, Group 1 Substance Cobalt Compounds Part 1, Group 1 Substance Cumene (contaminant) - Part 4 Substance Part 1, Group 1 Substance Regulation (EC) No. 1907/2006 (REACH), Article 57 This product does not contain substances of very high concern (Regulation (EC) No. 1907/2006 (REACH), Article 57) HMIS: Health 2* Flammability 2 Reactivity 0 PPE X Revision Date Revision Note Jul -25-2012 New MSDS format Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text End of MSDS Page 7/7 ink Technologies Material Safety Data Sheet Prepared In accordance with ISO 11014-1/ANSI standard Z400.1.2004 Print Date Jul -25-2012 Revision Date Jul -25-2012 igir# tOPPAR ND' COMPANTAIDE,NTIF cs...„ Natt� Product code Product name Product category Manufacturer or supplier's details UNITED STATES Nazdar Company 8501 Hedge Lane Terrace Shawnee, KS 66227 Tel: 1-913-422-1888 Tel: 1-800-677-4657 Fax: 1-913-422-2294 6152 Super Opaque Black 6100 Series Fast Dry Enamel Screen Ink UNITED KINGDOM Nazdar Limited Barton Road Heaton Mersey Stockport, England SK4 3EG Tel: +44 161 442 2111 Emergency Telephone Number USA: Chemtrec: 1-800-424-9300 Outside USA: Chemtrec: 1-703-527-3887 Website: www.nazdar.com MSDS Information: 1-913-422-1888 ext 2305 MSDS Contact: Regulatory Compliance email: regcomp@nazdar.com IiAZARDSI4ENTIFICATION This product is a preparation. Health hazard information is based on its components. Appearance Flammable Properties Emergency Overview Eyes Skin Inhalation Ingestion Colored liquid Combustible liquid and vapor. Aspiration hazard. Harmful: may cause lung damage if swallowed. Irritant. May cause drowsiness and dizziness. Causes eye irritation. May cause skin irritation and/or dermatitis. May cause irritation of respiratory tract. Inhalation of high vapour concentrations may cause symptoms like headache, dizziness, tiredness, nausea and vomiting. Harmful if swallowed. Potential for aspiration if swallowed. Risk of serious damage to the lungs (by aspiration). 1 ; P ' 'oMt. ...>AN ¢. .. Nw.�.1w rt- z3eCOMPOSI?IO_N%NEONAMATIO, ONSGR DiENTS Av}vAh ?Y00. [i? ...X."� Component CAS -No Weight % Stoddard solvent 8052-41-3 10 - 30 Naphtha (petroleum), heavy aromatic 64742-94-5 10 - 30 Talc 14807-96-6 5 -10 Carbon black 1333-86-4 5 - 10 Petroleum naphtha, light aromatic 64742-95-6 1 - 5 1,2,4-Trimethylbenzene (contaminant) 95-63-6 1 - 5 Propylene glycol monomethyl ether acetate 108-65-6 1 - 5 Vinyl toluene 25013-15-4 1 - 5 Trimethylbenzene (contaminant) 25551-13-7 1 - 5 Naphthalene (contaminant) 91-20-3 < 1 1,3,5-Trimethylbenzene (contaminant) 108-67-8 < 0.5 Cumene (contaminant) 98-82-8 < 0.5 Cobalt Compounds Trade Secret < 0.5 Cobalt Compounds Trade Secret < 0.5 Ethyl benzene (contaminant) 100-41-4 < 0.5 • Component names which have the word (contaminant) are constituents contained in Aromatic Hydrocarbon ingredients and are an integral part of the ingredient and cannot be separated. The percentage listed for the contaminant is as contained in the Hydrocarbon ingredient. (Example: 100% Hydrocarbon, 10% Contaminant A, 3% Contaminant B) RECEIVED JUL 1 2 2013 Page PERMIT CENTER Product code 6152 - Super Opaque Black Revision Date Jul -25-2042 Eye Contact Skin Contact Inhalation Ingestion Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get medical attention immediately if irritation develops and persists. Wash off immediately with soap and plenty of water. Use a mild soap if available. Rinse immediately with plenty of water for at least 15 minutes. Remove contaminated clothing. If irritation develops, get medical attention. If breathed in, move person into fresh air. If breathing is irregular or stopped, administer artificial respiration. Get medical attention immediately. If swallowed, DO NOT induce vomiting. Call a physician or Poison Control Centre immediately. Never give anything by mouth to an unconscious person. kRjIA�RESIEFGHTINPPAStJ Flammable Properties Suitable Extinguishing Media Protective Equipment and Precautions for Firefighters Specific Hazards Arising from the Chemical Combustible liquid and vapor. Foam. Carbon dioxide (CO2). Dry chemical. Water spray. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. As in any fire, wear self-contained breathing apparatus pressure -demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Keep away from fire, sparks and heated surfaces. Cool containers / tanks with water spray. Fire or intense heat may cause violent rupture of packages. Thermal decomposition can lead to release of irritating gases and vapours. Burning produces obnoxious and toxic fumes. 6CCtDENTA�``REL�ASE,ME/tJRES rrt Personal Precautions Methods for Cleaning Up Environmental Precautions Remove all sources of ignition. Ventilate the area. Avoid breathing dust or vapor. Avoid contact with skin, eyes and clothing. Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13). Do not use sparking tools. Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. ijariaAte, elmIgetf ,0:414.04:0.41,0T41 '141'( 041 *K AnG Handling Storage Avoid contact with skin, eyes and clothing. Ensure adequate ventilation. Remove and wash contaminated clothing before re -use. Discard contaminated shoes. When using do not smoke. Do not take internally. Harmful or fatal if swallowed. Take notice of the directions of use on the label. Keep containers tightly closed in a dry, cool and well -ventilated place. Keep container closed when not in use. Keep out of the reach of children. Keep away from heat and sources of ignition. N q•s '� epsuRE ,CONTROLS/PERSONAL'';;PROTECTI Exposure Guidelines ~ •Page 2i1*. L1 Product code 6152 - Super Opaque Black Revision Date Jul -25-2012 Component ACGIH TLV OSHA PEL NIOSH IDLH Ontario TWAEV Mexico OEL (TWA) Stoddard solvent TWA: 100 ppm TWA: 100 ppm TWA: 525 mg/m3 TWA: 500 ppm TWA: 2900 mg/m3 20000 mg/m3 TWA: 525 mg/m3 TWA/LMPE-PPT: 100 ppm TWA/LMPE-PPT: 523 mg/m3 STEULMPE-CT: 200 ppm STEULMPE-CT: 1050 mg/m3 Talc TWA: 2 mg/m3 (particulate matter) TWA: 2 mg/m3 (respirable dust) 1000 mg/m3 TWA: 2 mg/m3 (respirable) TWA/LMPE-PPT: 2 mg/m3 (respirable fraction) Carbon black TWA: 3 mg/m3 (inhalable fraction) TWA: 3.5 mg/m3 1750 mg/m3 TWA: 3.5 mg/m3 TWA/LMPE-PPT: 3.5 mg/m3 STEULMPE-CT: 7 mg/m3 Propylene glycol monomethyl ether acetate TWA: 50 ppm TWA: 270 mg/m3 Vinyl toluene TWA: 50 ppm STEL: 100 ppm TWA: 100 ppm TWA: 480 mg/m3 400 ppm TWA: 50 ppm STEL: 100 ppm TWA/LMPE-PPT: 50 ppm TWA/LMPE-PPT: 240 mg/m3 STEULMPE-CT: 100 ppm STEULMPE-CT: 485 mg/m3 Trimethylbenzene (contaminant) TWA: 25 ppm TWA: 25 ppm TWA: 125 mg/m3 TWA: 25 ppm TWA/LMPE-PPT: 25 ppm TWA/LMPE-PPT: 125 mg/m3 STEULMPE-CT: 35 ppm STEULMPE-CT: 170 mg/m3 Naphthalene (contaminant) TWA: 10 ppm STEL: 15 ppm Skin TWA: 10 ppm TWA: 50 mg/m3 STEL: 15 ppm STEL: 75 mg/m3 250 ppm TWA: 10 ppm STEL: 15 ppm Skin TWA/LMPE-PPT: 10 ppm TWA/LMPE-PPT: 50 mg/m3 STEULMPE-CT: 15 ppm STEULMPE-CT: 75 mg/m3 Cumene (contaminant) TWA: 50 ppm TWA: 50 ppm TWA: 245 mg/m3 Skin 900 ppm (10% LEL) TWA: 50 ppm TWA/LMPE-PPT: 50 ppm TWA/LMPE-PPT: 245 mg/m3 STEULMPE-CT: 75 ppm STEULMPE-CT: 365 mg/m3 Ethyl benzene (contaminant) TWA: 20 ppm TWA: 100 ppm TWA: 435 mg/m3 STEL: 125 ppm STEL: 545 mg/m3 800 ppm (10% LEL) TWA: 100 ppm STEL: 125 ppm TWA/LMPE-PPT: 100 ppm TWA/LMPE-PPT: 435 mg/m3 STEULMPE-CT: 125 ppm STEULMPE-CT: 545 mg/m3 Engineering Measures Personal Protective Equipment Respiratory Protection Eye Protection Skin Protection General Hygiene Considerations Use ventilation adequate to keep exposures below recommended exposure limits. See MSDS. In case of insufficient ventilation, wear suitable respiratory equipment. Use the indicated respiratory protection if the occupational exposure limit is exceeded and/or in case of product release (dust). Respirator with a vapour filter. Ensure that eyewash stations and safety showers are close to the workstation location. Avoid contact with eyes. Safety glasses with side -shields. Goggles. Face -shield. Wear protective gloves/clothing. Solvent -resistant apron and boots. Handle in accordance with good industrial hygiene and safety practice. Wash hands before eating, drinking, or smoking. Remove and wash contaminated clothing before re -use. Avoid contact with skin, eyes and clothing. Wear suitable gloves and eye/face protection. Regular cleaning of equipment, work area and clothing is recommended. • .. Ac.„*001.0041004V000:0,010. Appearance Odor Colored liquid Characteristic Physical State Odor Threshold Liquid No information available Page 3/8 Product code 6152 - Super Opaque Black Revision Date Jul -25-2032 pH Boiling point/Boiling Range Freezing Point/Range Evaporation Rate Vapour Pressure Flammability (solid, gas) No information available >149 °C / >300 °F No information available No information available No information available No information available Flash Point 43 °C/ 110 °F Method Setaflash closed cup Weight Per Gallon (lbs/gal) 8.47 VOC by weight % 41.71 VOC lbs/gal (less water) 3.54 Autoignition Temperature Melting Point/Range Solubility Partition Coefficient (n-octanol/water) Vapour Density No information available No information available No information available No information available Heavier than air Flammability Limits in Air Upper No information available Lower No information available Photochemically Reactive Yes Specific Gravity 1.02 VOC by volume % 45.83 VOC grams/liter (less water) 423.76 Vj p AB,ILI�I'YANQ REACTIYI' Tf Chemical Stability Conditions to Avoid Incompatible Products Stable under normal conditions. Heat, flames and sparks. Strong acids. Strong bases. Strong oxidizing agents. Reducing agents. Hazardous Decomposition Products Thermal decomposition can lead to release of irritating gases and vapours. Carbon dioxide (CO2). Carbon monoxide. Possibility of Hazardous Reactions None under normal processing. _y, T�yy�9.tir1 rtt ICt OGIC 1191FORMATI Acute Toxicity Component LD50 Oral LD50 Dermal LC50 Inhalation Naphtha (petroleum), heavy aromatic >5000 mg/kg ( Rat) >2000 mg/kg ( Rabbit) >590 mg/m3 ( Rat) 4 h Carbon black >15400 mg/kg ( Rat) >3 g/kg ( Rabbit ) Petroleum naphtha, light aromatic 8400 mg/kg ( Rat) >2000 mg/kg ( Rabbit) 3400 ppm ( Rat) 4 h >5.2 mg/L (Rat) 4h 1,2,4-Trimethylbenzene (contaminant) 3400 mg/kg ( Rat) >3160 mg/kg ( Rabbit) 18 g/m3 ( Rat) 4 h Propylene glycol monomethyl ether acetate 8532 mg/kg ( Rat) 5000 mg/kg ( Rabbit ) Vinyl toluene 2255 mg/kg ( Rat) Trimethylbenzene (contaminant) 8970 mg/kg ( Rat ) Naphthalene (contaminant) 490 mg/kg ( Rat) >2500 mg/kg ( Rat) >20 g/kg ( Rabbit ) >340 mg/m3 ( Rat) 1 h 1,3,5-Trimethylbenzene (contaminant) 5000 mg/kg ( Rat) 24 g/m3 ( Rat) 4 h Cumene (contaminant) 1400 mg/kg ( Rat) >3160 mg/kg ( Rabbit) 39000 mg/m3 ( Rat) 4 h Ethyl benzene (contaminant) 3500 mg/kg ( Rat) 15354 mg/kg ( Rabbit) 17.2 mg/L ( Rat) 4 h Chronic Toxicity Component ACGIH IARC NTP OSHA Carbon black A3 Group 2B X Page 4/8 Product code 6152 - Super Opaque Black Revision Date Jul -25-2012 Naphthalene (contaminant) Algae Group 2B Reasonably Anticipated X Cumene (contaminant) 96h LC50 Lepomis macrochirus: 1740 mg/L [static] 96h LC50 Pimephales promelas: 19 mg/L [static] 96h LC50 Pimephales promelas: 41 mg/L 96h LC50 Pimephales promelas: 45 mg/L [flow-through] Group 2B Talc X Cobalt Compounds Group 2B X Cobalt Compounds Petroleum naphtha, light aromatic Group 2B 96h LC50 Oncorhynchus mykiss: 9.22 mg/L X Ethyl benzene (contaminant) A3 Group 2B 48h EC50 Daphnia magna: 6.14 mg/L X Carbon black is classifiedas a carcinogen by the IARC (possibly carcinogenic to humans, Group 28). In their evaluation of carbon black, IARC indicates exposure to carbon black, per se, does not occur when it remains bound within a product matrix, specifically, rubber, ink, or paint. Carbon black is present only in a bound form in this preparation. Legend: ACGIH: (American Conference of Governmental Industrial Hygienists) IARC: (International Agency for Research on Cancer) NTP: (National Toxicity Program) OSHA: (Occupational Safety & Health Administration) Sensitisation Mutagenic Effects Reproductive Effects Developmental hazard Teratogenicity Chronic Effects Target Organ Effects A3 - Animal Carcinogen Group 2B - Possibly Carcinogenic to Humans Reasonably Anticipated to be a Human Carcinogen X - Present No information available No information available No information available No information available No information available Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may result in adverse health effect, such as mucous membrane and respiratory system irritation and adverse effect on kidney, liver and central nervous system. Blood, Central nervous system, Central Vascular System, Eyes, Kidney, Respiratory system, Skin. ` " lCOGICAL. INF4 4A°4. Ecotoxicity We have no quantitative data concerning the ecological effects of this product. Should not be released into the environment. Component Algae Fish Water Flea Naphtha (petroleum), heavy aromatic 96h LC50 Lepomis macrochirus: 1740 mg/L [static] 96h LC50 Pimephales promelas: 19 mg/L [static] 96h LC50 Pimephales promelas: 41 mg/L 96h LC50 Pimephales promelas: 45 mg/L [flow-through] Talc 96h LC50 Brachydanio rerio: >100 g/L [semi -static] Carbon black 24h EC50 Daphnia magna: >5600 mg/L Petroleum naphtha, light aromatic 96h LC50 Oncorhynchus mykiss: 9.22 mg/L 48h EC50 Daphnia magna: 6.14 mg/L 1,2,4-Trimethylbenzene (contaminant) 96h LC50 Pimephales promelas: 7.19 - 8.28 mg/L [flow-through] 48h EC50 Daphnia magna: 6.14 mg/L Propylene glycol monomethyl ether acetate 96h LC50 Pimephales promelas: 161 mg/L [static] 48h EC50 Daphnia magna: >500 mg/L Vinyl toluene 96h LC50 Pimephales rafinesque: 23.4 mg/L Trimethylbenzene (contaminant) 96h LC50 Pimephales promelas: 7.72 mg/L [[flow-through]] Page 518 Product code 6152 - Super Opaque Black Revision Date Jul -25-20'42 Naphthalene (contaminant) 72h EC50 Skeletonema costatum: 0.4 mg/L 96h LC50 Oncorhynchus mykiss: 0.91 - 2.82 mg/L [static] 96h LC50 Pimephales promelas: 5.74 - 6.44 mg/L [flow-through] 96h LC50 Oncorhynchus mykiss: 1.6 mg/L [flow-through] 96h LC50 Pimephales promelas: 1.99 mg/L [static] 96h LC50 Lepomis macrochirus: 31.0265 mg/L [static] 48h EC50 Daphnia magna: 1.09 - 3.4 mg/L [static] 48h EC50 Daphnia magna: 1.96 mg/L [Flow through] 48h LC50 Daphnia magna: 2.16 mg/L 1,3,5-Trimethylbenzene (contaminant) 3.63 96h LC50 Pimephales promelas: 3.48 mg/L 24h EC50 Daphnia magna: 50 mg/L Cumene (contaminant) 72h EC50 Pseudokirchneriella subcapitata: 2.6 mg/L 96h LC50 Pimephales promelas: 6.04 - 6.61 mg/L [flow-through] 96h LC50 Oncorhynchus mykiss: 2.7 mg/L [semi -static] 96h LC50 Oncorhynchus mykiss: 4.8 mg/L [flow-through] 96h LC50 Poecilia reticulata: 5.1 mg/L [semi -static] 48h EC50 Daphnia magna: 7.9 - 14.1 mg/L [static] 48h EC50 Daphnia magna: 0.6 mg/L Ethyl benzene (contaminant) 96h EC50 Pseudokirchneriella subcapitata: 1.7 - 7.6 mg/L [static] 72h EC50 Pseudokirchneriella subcapitata: 2.6 - 11.3 mg/L [static] 72h EC50 Pseudokirchneriella subcapitata: 4.6 mg/L 96h EC50 Pseudokirchneriella subcapitata: >438 mg/L 96h LC50 Oncorhynchus mykiss: 11.0 - 18.0 mg/L [static] 96h LC50 Pimephales promelas: 7.55 - 11 mg/L [flow-through] 96h LC50 Pimephales promelas: 9.1 - 15.6 mg/L [static] 96h LC50 Lepomis macrochirus: 32 mg/L [static] 96h LC50 Oncorhynchus mykiss: 4.2 mg/L [semi -static] 96h LC50 Poecilia reticulata: 9.6 mg/L [static] 48h EC50 Daphnia magna: 1.8 - 2.4 mg/L Persistence and Degradability No information available Bioaccumulation No information available Mobility in Environmental Media No information available Component log Pow Naphtha (petroleum), heavy aromatic 4.5 1,2,4-Trimethylbenzene (contaminant) 3.63 Propylene glycol monomethyl ether acetate 0.43 Vinyl toluene 3.36 Naphthalene (contaminant) 3.3 Cumene (contaminant) 3.55 Ethyl benzene (contaminant) 3.118 ate. 1 044u x(:0 ,w,-> zg kff.; • Waste Disposal Methods Contaminated Packaging Dispose of contents/container in accordance with local regulation. Empty containers should be taken to an approved waste handling site for recycling or disposal. swr�'��QTR�QNSP:bRINF[iRM°OT 1.4 DOT UN1210, Printing Ink, 3, Ill In the U.S. and Canada, this material may be reclassified as a combustible liquid and is not regulated, via surface transportation, in containers less than 119 gallons or 450 liters [per 49 CFR 173.150 (f)] [per Transportation of Dangerous Goods Regulations/Clear Language Part 1.33]. ICAO/IATA UN1210, Printing Ink, 3, III IMDG/IMO Page 6/8 Product code 6152 - Super Opaque Black Revision Date Jul -25-2012 UN1210, Printing Ink, 3, III REGU4 A,10 yN,FORNI'AT�•ON International Inventories Listed on TSCA. For further information, please contact: Manufacturer, importer, supplier U.S. Federal Regulations SARA 313 The following components ar Component CAS -No Weight % SARA 313 - Threshold Values Ethyl benzene (contaminant) 100-41-4 < 0.5 0.1 Naphthalene (contaminant) 91-20-3 < 1 0.1 1,2,4-Trimethylbenzene (contaminant) 95-63-6 1 - 5 1.0 Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act Section 112 (40 CFR 61). U.S. State Regulations Component Massachusetts Right To Know Minnesota Right To Know New Jersey Right To Know Pennsylvania Right To Know Stoddard solvent X X X X Talc X X X X Carbon black X X X X 1,2,4-Trimethylbenzene (contaminant) X X X X Vinyl toluene X X X X Trimethylbenzene (contaminant) X X X X Naphthalene (contaminant) X X X X 1,3,5-Trimethylbenzene (contaminant) X Not Listed Not Listed Not Listed Cumene (contaminant) X X X X Cobalt Compounds Not Listed Not Listed X X Cobalt Compounds Not Listed Not Listed X X Ethyl benzene (contaminant) X X X X California Prop. 65 WARNING! This product contains a chemical known in the State of California to cause cancer and / or WARNING! This product contains a chemical known in the State of California to r' i icc intim rlef Component CAS -No Weight % Ethyl benzene (contaminant) 100-41-4 < 0.5 Carbon black 1333-86-4 5 - 10 Naphthalene (contaminant) 91-20-3 < 1 Cumene (contaminant) 98-82-8 < 0.5 Canada This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the information required by the CPR Component WHMIS Classifications of Components Stoddard solvent B3,D2B Talc D2A Carbon black D2A Petroleum naphtha, light aromatic B3,D2B 1,2,4-Trimethylbenzene (contaminant) B3 Propylene glycol monomethyl ether acetate B3 Vinyl toluene B3,D2B Trimethylbenzene (contaminant) B3 Naphthalene (contaminant) B4,D2A 1,3,5-Trimethylbenzene (contaminant) B3 Page 718 Product code 6152 - Super Opaque Black Revision Date Jul -25-2012 Cumene (contaminant) B2,D2A Ethyl benzene (contaminant) B2,D2A,D2B Component NPRI - National Pollutant Release Inventory Stoddard solvent Part 5 Substance Part 5, Other Groups and Mixtures Naphtha (petroleum), heavy aromatic Part 5 Substance Part 5, Other Groups and Mixtures Petroleum naphtha, light aromatic Part 5 Substance Part 5, Other Groups and Mixtures 1,2,4-Trimethylbenzene (contaminant) Part 4 Substance Part 1, Group 1 Substance Part 5, Individual Substance Propylene glycol monomethyl ether acetate Part 4 Substance Part 5, Other Groups and Mixtures Vinyl toluene Part 4 Substance Trimethylbenzene (contaminant) Part 5 Substance Part 5, Isomer Groups Naphthalene (contaminant) Part 1, Group 1 Substance 1,3,5-Trimethylbenzene (contaminant) Part 4 Substance Part 5, Isomer Groups Cumene (contaminant) Part 4 Substance Part 1, Group 1 Substance Cobalt Compounds Part 1, Group 1 Substance Cobalt Compounds Part 1, Group 1 Substance Ethyl benzene (contaminant) Part 4 Substance Part 1, Group 1 Substance Regulation (EC) No. 1907/2006 (REACH), Article 57 This product does not contain substances of very high concern (Regulation (EC) No. 1907/2006 (REACH), Article 57) H M IS: Health 2* Flammability 2 Reactivity 0 PPE X Revision Date Revision Note Jul -25-2012 New MSDS format Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text End of MSDS Page 8/8 to Ink Technologies Material Safety Data Sheet Prepared in accordance with ISO 11014-1/ANSI standard 2400.1-2004 Print Date Jul -25-2012 Revision Date Jul -25-2012 R 0.0o.t EIiND CO�`MPANI(f IDENTIFIGATii tiA, 1�R!lu:. Product code Product name Product category Manufacturer or supplier's details UNITED STATES Nazdar Company 8501 Hedge Lane Terrace Shawnee, KS 66227 Tel: 1-913-422-1888 Tel: 1-800-677-4657 Fax: 1-913-422-2294 6169 Green 6100 Series Fast Dry Enamel Screen Ink UNITED KINGDOM Nazdar Limited Barton Road Heaton Mersey Stockport, England SK4 3EG Tel: +44 161 442 2111 Emergency Telephone Number USA: Chemtrec: 1-800-424-9300 Outside USA: Chemtrec: 1-703-527-3887 Website: www.nazdar.com MSDS Information: 1-913-422-1888 ext 2305 MSDS Contact: Regulatory Compliance email: regcomp@nazdar.com ittimg ENTIFIC l r`77 This product is a preparation. Health hazard information is based on its components. Appearance Flammable Properties Emergency Overview Eyes Skin Inhalation Ingestion Colored liquid Combustible liquid and vapor. Aspiration hazard. Harmful: may cause lung damage if swallowed. Irritant. May cause drowsiness and dizziness. Causes eye irritation. May cause skin irritation and/or dermatitis. May cause irritation of respiratory tract. Inhalation of high vapour concentrations may cause symptoms like headache, dizziness, tiredness, nausea and vomiting. Harmful if swallowed. Potential for aspiration if swallowed. Risk of serious damage to the lungs (by aspiration). �VC'OMPOSITION/lt FORMATIOWoNliNCREDIEN7 Component CAS -No Weight % Stoddard solvent 8052-41-3 10 - 30 Naphtha (petroleum), heavy aromatic 64742-94-5 10 - 30 Talc 14807-96-6 10 - 30 Titanium dioxide 13463-67-7 5 - 10 Copper Phthalocyanine Compound Trade Secret 1 - 5 Petroleum naphtha, light aromatic 64742-95-6 1 - 5 1,2,4-Trimethylbenzene (contaminant) 95-63-6 1 - 5 Copper Phthalocyanine Compound Trade Secret 1 - 5 Naphthalene (contaminant) 91-20-3 < 1 1,3,5-Trimethylbenzene (contaminant) 108-67-8 < 0.5 Cumene (contaminant) 98-82-8 < 0.5 Cobalt Compounds Trade Secret < 0.5 Cobalt Compounds Trade Secret < 0.5 • Component names which have the word (contaminant) are constituents contained in Aromatic Hydrocarbon ingredients and are an integral part of the ingredient and cannot be separated. The percentage listed for the contaminant is as contained in the Hydrocarbon ingredient. (Example: 100% Hydrocarbon, 10% Contaminant A, 3% Contaminant B) FIRST:-AIQ".MEASURE RECEIVFn b 4Z9Page 1 / 7 JUL 122013 PERMIT CENTER Product code 6169 - Green Revision Date Jul -25-2012 Eye Contact Skin Contact Inhalation Ingestion Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get medical attention immediately if irritation develops and persists. Wash off immediately with soap and plenty of water. Use a mild soap if available. Rinse immediately with plenty of water for at least 15 minutes. Remove contaminated clothing. If irritation develops, get medical attention. If breathed in, move person into fresh air. If breathing is irregular or stopped, administer artificial respiration. Get medical attention immediately. If swallowed, DO NOT induce vomiting. Call a physician or Poison Control Centre immediately. Never give anything by mouth to an unconscious person. usTn ju ra $ ra to 7±w cvrw r mw - f. �:. r� , FSS:�f�,IRE�Fi�Gk1't�ING�,MEAS_URES� Flammable Properties Suitable Extinguishing Media Protective Equipment and Precautions for Firefighters Specific Hazards Arising from the Chemical Combustible liquid and vapor. Foam. Carbon dioxide (CO2). Dry chemical. Water spray. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. As in any fire, wear self-contained breathing apparatus pressure -demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Keep away from fire, sparks and heated surfaces. Cool containers / tanks with water spray. Fire or intense heat may cause violent rupture of packages. Thermal decomposition can lead to release of irritating gases and vapours. Burning produces obnoxious and toxic fumes. CCIDEk AL RELEAspitiEASURES, Mit Personal Precautions Methods for Cleaning Up Environmental Precautions Remove all sources of ignition. Ventilate the area. Avoid breathing dust or vapor. Avoid contact with skin, eyes and clothing. Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13). Do not use sparking tools. Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. ,a &�*'• �.sma..+qry«->/ »yam v. awn' •. ffilt3pLIN AND STO,0,_ Handling Storage Avoid contact with skin, eyes and clothing. Ensure adequate ventilation. Remove and wash contaminated clothing before re -use. Discard contaminated shoes. When using do not smoke. Do not take internally. Harmful or fatal if swallowed. Take notice of the directions of use on the label. Keep containers tightly closed in a dry, cool and well -ventilated place. Keep container closed when not in use. Keep out of the reach of children. Keep away from heat and sources of ignition. r- t ••sw* eay.*au...: a id .p+ ,:0 0,4 ,..l t, .n• • *�8EJ(POSUREt,CONTROLS/PERSONA tq EGTIpN A.Y.-.uY+. �' .�4.�.-.r•u Exposure Guidelines Component ACGIH TLV O$HA.PELf I NIOSH jI LT1 Ontario TWAEV I Mexico OEL (TWA) Page 2/7 r,+ Product code 6169 - Green Revision Date Jul -25-2012 Stoddard solvent TWA: 100 ppm TWA: 100 ppm TWA: 525 mg/m3 TWA: 500 ppm TWA: 2900 mg/m3 20000 mg/m3 TWA: 525 mg/m3 TWA/LMPE-PPT: 100 ppm TWA/LMPE-PPT: 523 mg/m3 STEULMPE-CT: 200 ppm STEULMPE-CT: 1050 mg/m3 Talc TWA: 2 mg/m3 (particulate matter) TWA: 2 mg/m3 (respirable dust) 1000 mg/m3 TWA: 2 mg/m3 (respirable) TWA/LMPE-PPT: 2 mg/m3 (respirable fraction) Titanium dioxide TWA: 10 mg/m3 TWA: 10 mg/m3 (total dust) TWA: 15 mg/m3 (total dust) 5000 mg/m3 TWA: 10 mg/m3 (total dust) TWA/LMPE-PPT: 10 mg/m3 (as Ti) STEULMPE-CT: 20 mg/m3 (as Ti) Naphthalene (contaminant) TWA: 10 ppm STEL: 15 ppm Skin TWA: 10 ppm TWA: 50 mg/m3 STEL: 15 ppm STEL: 75 mg/m3 250 ppm TWA: 10 ppm STEL: 15 ppm Skin TWA/LMPE-PPT: 10 ppm TWA/LMPE-PPT: 50 mg/m3 STEULMPE-CT: 15 ppm STEULMPE-CT: 75 mg/m3 Cumene (contaminant) TWA: 50 ppm TWA: 50 ppm TWA: 245 mg/m3 Skin 900 ppm (10% LEL) TWA: 50 ppm TWA/LMPE-PPT: 50 ppm TWA/LMPE-PPT: 245 mg/m3 STEULMPE-CT: 75 ppm STEULMPE-CT: 365 mg/m3 Engineering Measures Personal Protective Equipment Respiratory Protection Eye Protection Skin Protection General Hygiene Considerations Use ventilation adequate to keep exposures below recommended exposure limits. See MSDS. In case of insufficient ventilation, wear suitable respiratory equipment. Use the indicated respiratory protection if the occupational exposure limit is exceeded and/or in case of product release (dust). Respirator with a vapour filter. Ensure that eyewash stations and safety showers are close to the workstation location. Avoid contact with eyes. Safety glasses with side -shields. Goggles. Face -shield. Wear protective gloves/clothing. Solvent -resistant apron and boots. Handle in accordance with good industrial hygiene and safety practice. Wash hands before eating, drinking, or smoking. Remove and wash contaminated clothing before re -use. Avoid contact with skin, eyes and clothing. Wear suitable gloves and eye/face protection. Regular cleaning of equipment, work area and clothing is recommended. •ASPi'n.Y. YSIC 1 .Ake es),,goi Appearance Odor pH Boiling point/Boiling Range Freezing Point/Range Evaporation Rate Vapour Pressure Flammability (solid, gas) Colored liquid Characteristic No information available >149.°C / >300 °F No information available No information available No information available No information available Flash Point 43 °C/ 110 °F Method Setaflash closed cup Weight Per Gallon (lbs/gal) VOC by weight VOC lbs/gal (less water) Physical State Odor Threshold Autoignition Temperature Melting Point/Range Solubility Partition Coefficient (n-octanol/water) Vapour Density Liquid No information available No information available No information available No information available No information available Heavier than air Flammability Limits in Air Upper No information available Lower No information available Photochemically Reactive Yes 9.18 Specific Gravity 1.1 37.72 VOC by volume % 44.91 3.47 VOC grams/liter (less water) 415.37 Page 3/7 Product code 6169 - Green Revision Date Jul -25-2012 t Chemical Stability Conditions to Avoid Incompatible Products �sT/io►�ii<< Stable under normal conditions. Heat, flames and sparks. Strong acids. Strong bases. Strong oxidizing agents. Reducing agents. Hazardous Decomposition Products Thermal decomposition can lead to release of irritating gases and vapours. Carbon dioxide (CO2). Carbon monoxide. Possibility of Hazardous Reactions None under normal processing. XI'COLOGICAL INFORNIATI Acute Toxicity Component LD50 Oral LD50 Dermal LC50 Inhalation Naphtha (petroleum), heavy aromatic >5000 mg/kg ( Rat) >2000 mg/kg ( Rabbit ). >590 mg/m3 ( Rat) 4 h ` Titanium dioxide >10000 mg/kg ( Rat ) Naphthalene (contaminant) Copper Phthalocyanine Compound 3000 mg/kg ( Rat ) X Cumene (contaminant) Petroleum naphtha, light aromatic 8400 mg/kg ( Rat) >2000 mg/kg ( Rabbit) 3400 ppm ( Rat) 4 h >5.2 mg/L tRat ) 4 h 1,2,4-Trimethylbenzene (contaminant) 3400 mg/kg ( Rat) >3160 mg/kg ( Rabbit) 18 g/m3 ( Rat) 4 h Naphthalene (contaminant) 490 mg/kg ( Rat) >2500 mg/kg ( Rat) >20 g/kg ( Rabbit ) >340 mg/m3 ( Rat) 1 h 1,3,5-Trimethylbenzene (contaminant) 5000 mg/kg ( Rat) 24 g/m3 ( Rat) 4 h Cumene (contaminant) 1400 mg/kg ( Rat )_ >3160 mg/kg ( Rabbit) 39000 mg/m3 ( Rat) 4 h Chronic Toxicity Component ACGIH IARC NTP OSHA Titanium dioxide Group 2B X Naphthalene (contaminant) Group 2B Reasonably Anticipated X Cumene (contaminant) Group 2B X Cobalt Compounds Group 2B X Cobalt Compounds Group 2B X Legend: IARC: (International Agency for Research on Cancer) NTP: (National Toxicity Program) OSHA: (Occupational Safely & Health Administration) Group 2B - Possibly Carcinogenic to Humans Reasonably Anticipated to be a Human Carcinogen X - Present Sensitisation No information available Mutagenic Effects No information available Reproductive Effects No information available Developmental hazard No information available Teratogenicity No information available Chronic Effects Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may result in adverse health effect, such as mucous membrane and respiratory system irritation and adverse effect on kidney, liver and central nervous system. Target Organ Effects Blood, Central nervous system, Central Vascular System, Eyes, Kidney, Liver, Respiratory system, Skin. Page 4/7 Product code 6169 - Green Revision Date Jul -25-2012 1 r e 4 , �'...i?I 'I' •- ¢ i-� mnnn:...c.�.+c-w 1..a-$' .nNvt ... 1?+t�+ '12ECOL?O�GICALINFORMATION, Ecotoxicity We have no quantitative data concerning the ecological effects of this product. Should not be released into the environment. Component Algae Fish Water Flea Naphtha (petroleum), heavy aromatic 3.63 96h LC50 Lepomis macrochirus: 1740 mg/L [static] 96h LC50 Pimephales promelas: 19 mg/L [static] 96h LC50 Pimephales promelas: 41 mg/L 96h LC50 Pimephales promelas: 45 mg/L [flow-through] 3.3 Talc 3.55 96h LC50 Brachydanio rerio: >100 g/L [semi -static] Copper Phthalocyanine Compound 96h LC50 Lepomis macrochirus: 752.4 mg/L [static] 24h EC50 Daphnia magna Straus: >500 mg/L Petroleum naphtha, light aromatic 96h LC50 Oncorhynchus mykiss: 9.22 mg/L 48h EC50 Daphnia magna: 6.14 mg/L 1,2,4-Trimethylbenzene (contaminant) 96h LC50 Pimephales promelas: 7.19 - 8.28 mg/L (flow-through] 48h EC50 Daphnia magna: 6.14 mg/L Naphthalene (contaminant) 72h EC50 Skeletonema costatum: 0.4 mg/L 96h LC50 Oncorhynchus mykiss: 0.91 - 2.82 mg/L [static] 96h LC50 Pimephales promelas: 5.74 - 6.44 mg/L [flow-through] 96h LC50 Oncorhynchus mykiss: 1.6 mg/L [flow-through] 96h LC50 Pimephales promelas: 1.99 mg/L [static] 96h LC50 Lepomis macrochirus: 31.0265 mg/L [static] 48h EC50 Daphnia magna: 1.09 - 3.4 mg/L [static] 48h EC50 Daphnia magna: 1.96 mg/L [Flow through] 48h LC50 Daphnia magna: 2.16 mg/L 1,3,5-Trimethylbenzene (contaminant) 96h LC50 Pimephales promelas: 3.48 mg/L 24h EC50 Daphnia magna: 50 mg/L Cumene (contaminant) 72h EC50 Pseudokirchneriella subcapitata: 2.6 mg/L 96h LC50 Pimephales promelas: 6.04 - 6.61 mg/L [flow-through] 96h LC50 Oncorhynchus mykiss: 2.7 mg/L [semi -static] 96h LC50 Oncorhynchus mykiss: 4.8 mg/L [flow-through] 96h LC50 Poecilia reticulata: 5.1 mg/L (semi -static] 48h EC50 Daphnia magna: 7.9 - 14.1 mg/L [static] 48h EC50 Daphnia magna: 0.6 mg/L Persistence and Degradability No information available Bioaccumulation No information available Mobility in Environmental Media No information available Component log Pow Naphtha (petroleum), heavy aromatic 4.5 1,2,4-Trimethylbenzene (contaminant) 3.63 Naphthalene (contaminant) 3.3 Cumene (contaminant) 3.55 ,n.r ,DIS#100.. ;CION { � � � SIDFRAT,I�ONS,� -ter• Waste Disposal Methods Contaminated Packaging Dispose of contents/container in accordance with local regulation. Empty containers should be taken to an approved waste handling site for recycling or disposal. ~ ; Vit*TRANSPORT iNFORNIATIO Page 5/7 Product code 6169 - Green • Revision Date Jul -25-2012 DOT UN1210, Printing Ink, 3, III In the U.S. and Canada, this material may be reclassified as a combustible liquid and is not regulated, via surface transportation, in containers less than 119 gallons or 450 liters [per 49 CFR 173.150 (f)] [per Transportation of Dangerous Goods Regulations/Clear Language Part 1.33]. ICAO/IATA UN1210, Printing Ink, 3, III IMDG/IMO UN1210, Printing Ink, 3, III A } k x., 15 !REGIJLATC NFORMATI International Inventories Listed on TSCA. For further information, please contact: Manufacturer, importer, supplier U.S. Federal Regulations SARA 313 The following components are subject to r Component CAS -No Weight % SARA 313 - Threshold Values Naphthalene (contaminant) 91-20-3 < 1 0.1 1,2,4-Trimethylbenzene (contaminant) 95-63-6 1 - 5 1.0 Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act Section 112 (40 CFR 61). U.S. State Regulations Component Massachusetts Right To Know Minnesota Right To Know New Jersey Right To Know Pennsylvania Right To Know Stoddard solvent X X X X Talc X X X X Titanium dioxide X X X X Copper Phthalocyanine Compound Not Listed Not Listed X X 1,2,4-Trimethylbenzene (contaminant) X X X X Copper Phthalocyanine Compound Not Listed Not Listed X X Naphthalene (contaminant) X X X X 1,3,5-Trimethylbenzene (contaminant) X Not Listed Not Listed Not Listed Cumene (contaminant) X X X X Cobalt Compounds Not Listed Not Listed X X Cobalt Compounds Not Listed Not Listed X X California Prop. 65 WARNING! This product contains a chemical known in the State of California to cause cancer and / or WARNING! This product contains a chemical known in the State of California to cause birth defects or other reproductive harm Component CAS -No Weight % Titanium dioxide 13463-67-7 5 - 10 Naphthalene (contaminant) 91-20-3 < 1 Cumene (contaminant) 98-82-8 < 0.5 Canada This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the information required by the CPR Component WHMIS Classifications of Components Stoddard solvent B3,D2B Talc D2A Titanium dioxide D2A Petroleum naphtha, light aromatic B3,D2B Page 617 Product code 6169 - Green Revision Date Jul -25-2012 1,2,4-Trimethylbenzene (contaminant) B3 Naphthalene (contaminant) B4,D2A 1,3,5-Trimethylbenzene (contaminant) B3 Cumene (contaminant) 62,D2A Component NPRI - National Pollutant Release inventory Stoddard solvent Part 5 Substance Part 5, Other Groups and Mixtures Naphtha (petroleum), heavy aromatic Part 5 Substance Part 5, Other Groups and Mixtures Copper Phthalocyanine Compound Part 1, Group 1 Substance Petroleum naphtha, light aromatic Part 5 Substance Part 5, Other Groups and Mixtures 1,2,4-Trimethylbenzene (contaminant) Part 4 Substance Part 1, Group 1 Substance Part 5, Individual Substance Copper Phthalocyanine Compound Part 1, Group 1 Substance Naphthalene (contaminant) Part 1, Group 1 Substance 1,3,5-Trimethylbenzene (contaminant) Part 4 Substance Part 5, Isomer Groups Cumene (contaminant) Part 4 Substance Part 1, Group 1 Substance Cobalt Compounds Part 1, Group 1 Substance Cobalt Compounds Part 1, Group 1 Substance Regulation (EC) No. 1907/2006 (REACH), Article 57 This product does not contain substances of very high concern (Regulation (EC) No. 1907/2006 (REACH), Article 57) HMIS: Health 2* Flammability 2 Revision Date Revision Note Jul -25-2012 New MSDS format Reactivity 0 Yv'ir, M t -Tl R INFQRM !Ft_ K PPE X Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text End of MSDS Page 7 /7 Material Safety Data Sheet Prepared In accordance with ISO 11014-1/ANSI standard Z400.1-2004 Print Date Apr -08-2009 Revision Date Apr -08-2009 xL s+a a s &+�x':.xs•� ',t �e•yvtrS rY a t w.�s•^rn - xiY�:a:n. a ax r u7 G ?RiODUCT��IND COMPp1Y1DENTitlt''ATIOIV y .w�,C� ; Product code Product name Product description Manufacturer or supplier's details UNITED STATES Nazdar Company 8501 Hedge Lane Terrace Shawnee, KS 66227 Tel: 1-913-422-1888 Tel: 1-800-677-4657 Fax: 1-913-422-2294 70111 Black 70000 Series Plasti-Vac Gloss Screen Ink UNITED KINGDOM Nazdar Limited 7 Barton Road Heaton Mersey Industrial Estate Stockport, Chesire SK4 3EG Tel: +44 161 442 2111 Emergency Telephone Number USA: Chemtrec: 1-800-424-9300 Outside USA: Chemtrec: 1-703-527-3887 Website: www.nazdar.com MSDS Information: 1-913-422-1888 ext 2305 MSDS Contact: Regulatory Compliance email: regcomp@nazdar.com age" M:zi ram sxt:' t Yx� s .•1,, -"..wm *tv.r .,-470 R a7 I:44.0iW • { NIAZARDS I,DE1;�7°IFtCA IAzN.`' n` .''� .'• This product is a preparation. Health hazard information is based on its components. Appearance Flammable Properties Emergency Overview Eyes Skin Inhalation Ingestion Viscous liquid Combustible liquid and vapor. Harmful. Irritant. May cause drowsiness and dizziness. Moderately irritating to the eyes. The liquid splashed in the eyes may cause irritation and reversible damage. Harmful in contact with skin. May cause skin irritation and/or dermatitis. Prolonged or repeated skin contact with liquid may cause defatting resulting in drying, redness and possible blistering. May be harmful if absorbed through skin. Causes skin irritation. Prolonged skin contact may defat the skin and produce dermatitis. Inhalation of high vapour concentrations may cause symptoms like headache, dizziness, tiredness, nausea and vomiting. Harmful if swallowed. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. rte'44tt ftai. y+...y,st,«.c..;.rs .�.�.w •...,.r.„.w: ro:•t, a: }.ir Y.r„ i•-r�•a* s�c h;. aa� � 3.,. ,�4 'COMPOSLTION%INF,O IlI�ATION ON 1N4R00.0TS� ., Component CAS -No Weight % 2-Butoxvethanol 111-76-2 10 - 30 Diacetone alcohol 123-42-2 10 - 30 Ethyl 3-Ethoxvpropionate 763-69-9 5 - 10 Naphtha (petroleum), heavy aromatic 64742-94-5 5 - 10 Isophorone 78-59-1 5 - 10 Carbon black 1333-86-4 1 - 5 Naphthalene (contaminant) 91-20-3 < 1 1.2,4-Trimethvlbenzene (contaminant) 95-63-6 < 1 1,3,5-Trimethylbenzene (contaminant) 108-67-8 < 0.5 • Component names which have the word (contaminant) are constituents contained in Aromatic Hydrocarbon ingredients and are an integral part of the ingredient and cannot be separated. The percentage listed for the contaminant is as contained in the Hydrocarbon ingredient. (Example: 100% Hydrocarbon, 10% Contaminant A, 3% Contaminant 8) Page 1 18 CITY OF TUKWILA JUL 12 2013 PERMIT CENTER Product code 70111 - Black Skin Contact Eye Contact Inhalation Ingestion Revision Date Apr -08-2009 Wash off immediately with soap and plenty of water. Use a mild soap if available. Rinse immediately with plenty of water for at least 15 minutes. Remove contaminated clothing. If irritation develops, get medical attention. Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get medical attention immediately if irritation develops and persists. Move to fresh air. If breathed in, move person into fresh air. If breathing is irregular or stopped, administer artificial respiration. Get medical attention immediately. If swallowed, DO NOT induce vomiting. Call a physician or Poison Control Centre immediately. Never give anything by mouth to an unconscious person. Flammable Properties Suitable Extinguishing Media Protective Equipment and Precautions for Firefighters Specific Hazards Arising from the Chemical Combustible liquid and vapor. Foam. Carbon dioxide (CO2). Dry chemical. Water spray. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. As in any fire, wear self-contained breathing apparatus pressure -demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Keep away from fire, sparks and heated surfaces. Keep container tightly closed. Cool containers / tanks with water spray. Fire or intense heat may cause violent rupture of packages. Thermal decomposition can lead to release of irritating gases and vapours. Burning produces obnoxious and toxic fumes. Personal Precautions Methods for Cleaning Up Environmental Precautions Remove all sources of ignition. Heat, flames and sparks. Ventilate the area. Avoid breathing dust or vapor. Avoid contact with skin, eyes and clothing. Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13). Do not use sparking tools. Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. Handling Storage Keep away from open flames, hot surfaces and sources of ignition. Take precautionary measures against static discharges. To avoid ignition of vapours by static electricity discharge, all metal parts of the equipment must be grounded. Avoid contact with skin, eyes and clothing. Ensure adequate ventilation. Remove and wash contaminated clothing before re -use. Discard contaminated shoes. When using do not smoke. Take notice of labels and material safety data sheets for the working chemicals. Do not take internally. Harmful or fatal if swallowed. Keep containers tightly closed in a dry, cool and well -ventilated place. Keep container closed when not in use. Keep out of the reach of children. Keep away from heat and sources of ignition. Take notice of the directions of use on the label. • e 1,. ,ar i Page 218 Product code 70111 - Black Exposure Guidelines Revision Date Apr -08-2009 Component Weight % ACGIH TLV OSHA PEL Ontario TWAEV 2-Butoxyethanol 10 - 30 TWA: 20 ppm TWA: 120 mg/m3 TWA: 25 ppm Skin TWA: 50 ppm TWA: 240 mq/m3 TWA: 20 ppm Skin Diacetone alcohol 10 - 30 TWA: 50 ppm TWA: 50 ppm TWA: 240 mg/m3 TWA: 240 mg/m3 TWA: 50 ppm STEL: 360 mg/m3 STEL: 75 ppm Ethyl 3-Ethoxypropionate 5 -10 1 - 5 1750 mg/m3 TWA: 300 mg/m3 TWA: 50 ppm Isophorone 5 -10 Ceiling: 5 ppm TWA: 4 ppm TWA: 23 mg/m3 TWA: 25 ppm TWA: 140 mq/m3 CEV: 28 mg/m3 CEV: 5 ppm Carbon black 1 - 5 TWA: 3.5 mq/m3 TWA: 3.5 mq/m3 TWA: 3.5 mq/m3 Naphthalene (contaminant) < 1 TWA: 10 ppm Skin STEL: 15 ppm TWA: 50 mg/m3 TWA: 10 ppm STEL: 15 ppm STEL: 75 mg/m3 TWA: 10 ppm TWA: 52 mg/m3 STEL: 15 ppm STEL: 78 mg/m3 1,2,4-Trimethylbenzene (contaminant) < 1 TWA: 25 ppm TWA: 25 ppm TWA: 123 mo/m3 1,3,5-Trimethylbenzene (contaminant) < 0.5 TWA: 25 ppm TWA: 123 mg/m3 TWA: 25 ppm Component Weight % NIOSH IDLH Mexico OEL (TWA) 2-Butoxyethanol 10 - 30 700 ppm TWA: 120 mg/m3 TWA: 26 ppm STEL: 360 mg/m3 STEL: 75 ppm Diacetone alcohol 10 - 30 1800 ppm 10% LEL TWA: 240 mg/m3 TWA: 50 ppm STEL: 75 ppm STEL: 360 mq/m3 Isophorone 5 - 10 200 ppm Peak: 25 mg/m3 Peak: 5 ppm Carbon black 1 - 5 1750 mg/m3 TWA: 3.5 mg/m3 STEL: 7 mm3 Naphthalene (contaminant) < 1 250 ppm TWA: 10 ppm TWA: 50 mg/m3 STEL: 75 mg/m3 STEL: 15 ppm 1,2,4-Trimethylbenzene (contaminant) < 1 TWA: 125 mg/m3 TWA: 25 ppm STEL: 35 ppm STEL: 170 mq/m3 1,3,5-Trimethylbenzene (contaminant) < 0.5 TWA: 125 mg/m3 TWA: 25 ppm STEL: 35 ppm STEL: 170 mg/m3 NIOSH IDLH: Immediately Dangerous to Life or Health Engineering Measures Personal Protective Equipment Respiratory Protection Eye Protection Skin Protection General Hygiene Considerations Use only with adequate ventilation. Use ventilation adequate to keep exposures below recommended exposure limits. See MSDS. In case of insufficient ventilation, wear suitable respiratory equipment. Use the indicated respiratory protection if the occupational exposure limit is exceeded and/or in case of product release (dust). Respirator with a vapour filter. Ensure that eyewash stations and safety showers are close to the workstation location. Avoid contact with eyes. Safety glasses with side -shields. Goggles. Face -shield. Wear protective gloves/clothing. Solvent -resistant apron and boots. Handle in accordance with good industrial hygiene and safety practice. Ensure that eyewash stations and safety showers are close to the workstation location. Wash hands before eating, drinking, or smoking. Remove and wash contaminated clothing before re -use. Regular cleaning of equipment, work area and clothing. Avoid contact with skin, eyes and clothing. Wear suitable gloves and eye/face protection. Page 3 / 8 Product code 70111 - Black Revision Date Apr -08-2009 ,11I11 SICAL ANDtHIEMIC"4611ROPER r. !w Appearance Odor pH Boiling point/Boiling Range Freezing Point/Range Evaporation Rate Vapour Pressure Flammability (solid, gas) Flammability Limits in Air Upper No information available Lower No information available Viscous liquid Characteristic No information available >149°C / >300°F No information available No information available No information available No information available Weight Per Gallon (lbs/gal) VOC by weight VOC lbs/gal 8.404 64.341 5.413 "1 n�-�• t9•Ski 4.. ➢ Physical State Odor Threshold Autoignition Temperature Melting Point/Range Solubility Partition Coefficient (n- octanol/water) Vapour Density Liquid No information available No information available No information available No information available No information available Heavier than air Flash Point 52°C / 125°F Method Setaflash closed cup Photochemically Reactive Specific Gravity VOC by volume VOC grams/liter Yes 1.008 65.652 648.584 T1a• YL1 Chemical Stability Conditions to Avoid Incompatible Products Hazardous Decomposition Products Stable under normal conditions. Heat, flames and sparks. Strong acids. Strong bases. Strong oxidizing agents. Reducing agents. Thermal decomposition can lead to release of irritating gases and vapours. Carbon dioxide (CO2). Carbon monoxide. Possibility of Hazardous Reactions None under normal processing. .. �ran•u.itya.:S x- n,aa`a:er:T[°yCf' •z•:nc�•hea�.:.r..i'K:,,. .. an:.y: �Q3lbC4?OG1.CLIJ!iORIfATIb, Acute Toxicity Component LD50 Oral LD50 Dermal LC50 Inhalation 2-Butoxyethanol 470 mg/kg ( Rat) 2270 mg/kg ( Rat) 220 mg/kg ( Rabbit) _ 2.21 mg/L ( Rat) 4 h 450 ppm ( Rat ) 4 h Diacetone alcohol 4 q/kq ( Rat) 13500 mq/kq (Rabbit ) A3 Ethyl 3-Ethoxypropionate 3200 mq/kq ( Rat) 10 mUkq ( Rabbit" Carbon black Naphtha (petroleum), heavy aromatic 5000 mg/kg ( Rat) 2000 mg/kg ( Rabbit) 590 mg/m3( Rat ) 4 h Isophorone 1870 mq/kq ( Rat) 1390 mq/kq ( Rat) 7 mq/L ( Rat) 4 h Carbon black 15400 mq/ka ( Rat) 3 a/ka ( Rabbit ) Naphthalene (contaminant) 490 mq/kg ( Rat) 2500 mq/kgj Rat ) 20 q/kq ( Rabbit )_ 340 mg/m3( Rat) 1 h 1,2,4-Trimethylbenzene (contaminant) 3400 mg/kg ( Rat) 8970 mg/kg ( Rat 3160 mg/kg ( Rabbit) 18 g/m3( Rat) 4 h 1,3,5-Trimethylbenzene (contaminant) 8970 mg/kg ( Rat) 5000 mg/kg ( Rat ) 24 g/m3( Rat ) 4 h Chronic Toxicity Component ACGIH IARC NTP OSHA 2-Butoxyethanol A3 Isophorone A3 Carbon black Group 2B X Naphthalene (contaminant) Group 2B Reasonably Anticipated X Page 4/8 Product code 70111 - Black Revision Date Apr -08-2009 Carbon black is classified as a carcinogen by the IARC (possibly carcinogenic to humans, Group 2B). In their evaluation of carbon black, IARC indicates exposure to carbon black, per se, does not occur when it remains bound within a product matrix, specifically, rubber, ink, or paint. Carbon black is present. only in a bound form in this preparation. Legend: ACG/H: (American Conference of Governmental Industrial Hygienists) IARC: (International Agency for Research on Cancer) NTP: (National Toxicity Program) OSHA: (Occupational Safety & Health Administration) Sensitisation No information available Mutagenic Effects No information available Reproductive Effects No information available Developmental Effects No information available Teratogenicity No information available A3 - Animal Carcinogen Group 2B - Possibly Carcinogenic to Humans Reasonably Anticipated to be a Human Carcinogen X - Present Chronic Effects Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may result in adverse health effect, such as mucous membrane and respiratory system irritation and adverse effect on kidney, liver and central nervous system. Blood, Central nervous system, Eyes, Hematopoietic System, Kidney, Liver, Lymphatic System, Respiratory system, Skin. Target Organ Effects x`12 ;ECOLO ICAO 100 1 ` Et Ecotoxicity We have no quantitative data concerning the ecological effects of this product. Should not be released into the environment. Component Freshwater Algae Freshwater Fish Water Flea 2-Butoxyethanol 1.03 96 Hr LC50 Lepomis macrochirus: 2950 mq/L 24 Hr EC50 water flea: 1720 mg/L; 24 Hr LC50 Daphnia magna: 1698-1940 mq/L Diacetone alcohol 96 Hr LC50 Lepomis macrochirus: 420 mq/L 48 Hr EC50 water flea: 8750 mg/L Ethyl 3-Ethoxypropionate 96 Hr LC50 Pimephales promelas: 62 mq/L [static] 48 Hr EC50 Daphnia magna: 970 mg/L Naphtha (petroleum), heavy aromatic 72 Hr EC50 Skeletonema costatum: 2.5 mg/L 96 Hr LC50 Pimephales promelas: 19 mg/L [static]; 96 Hr LC50 Oncorhynchus mykiss: 2.34 mg/L; 96 Hr LC50 Lepomis macrochirus: 1740 mq/L [static] 48 Hr EC50 Daphnia magna: 0.95 mg/L Isophorone 72 Hr EC50 Scenedesmus subspicatus: 475.4 mg/L; 96 Hr EC50 Selenastrum caoricornutum: 126 ma/L 96 Hr LC50 Pimephales promelas: 145 mg/L [flow - through]; 96 Hr LC50 Lepomis macrochirus: 220 ma/L [static] 48 Hr EC50 Daphnia magna: 117 mg/L Carbon black 24 Hr EC50 Daphnia magna: >5600 mq/L Naphthalene (contaminant) 96 Hr EC50 Skeletonema costatum: 0.4 ma/ 96 Hr LC50 Pimephales promelas: 1.99 mq/L [static] 48 Hr EC50 water flea: 2.16 mg/L 1,2,4-Trimethylbenzene (contaminant) 96 Hr LC50 Pimephales promelas: 7.72 mg/L [flow- through] 48 Hr EC50 Daphnia magna: 6.14 mg/L 1,3,5-Trimethylbenzene (contaminant) 96 Hr LC50 Pimephales promelas: 3.48 mg/L 96 Hr LC50 Pimephales promelas: 7.72 mq/L [flow-through] 24 Hr EC50 water flea: 50 mg/L Persistence and Degradability No information available Bioaccumulation No information available Mobility in Environmental Media No information available Component log Pow 2-Butoxvethanol 0.81 Diacetone alcohol 1.03 Page 518 Product code 70111 - Black Revision Date Apr -08-2009 Component log Pow Ethyl 3-Ethoxmropionate 1.35 Naphtha (petroleum), heavy aromatic 2.9 - 6.1 Isophorone 1.66 ISPOS' 'CONSIDERATEOI Waste Disposal Methods Contaminated Packaging Dispose of contents/container in accordance with local regulation. Empty containers should be taken to an approved waste handling site for recycling or disposal. a '144 RA.NSPORT INF9RNIATIQI DOT UN1210, Printing Ink Related Material, 3, III In the U.S. and Canada, this material may be reclassified as a combustible liquid and is not regulated, via surface transportation, in containers less than 119 gallons or 450 liters [per 49 CFR 173.150 (f)] [per Transportation of Dangerous Goods Regulations/Clear Language Part 1.33]. ICAO/IATA UN1210, Printing Ink Related Material, 3, Ill IMDG/IMO UN1210, Printing Ink Related Material, 3, III I. �a5 sREGUATOR411NFORIIAAIMON Yi International Inventories Listed on TSCA. For further information, please contact: Manufacturer, importer, supplier U.S. Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 Component CAS -No Weight % SARA 313 - Threshold 78-59-1 5 - 10 Benzene Values 2-Butoxvethanol 111-76-2 10 - 30 1.0 Naphthalene (contaminant) 91-20-3 < 1 0.1 Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) This product contains the following HAPs: Component CAS -No Weight % Isophorone 78-59-1 5 - 10 U.S. State Regulations California Prop. 65 WARNING! This product contains a chemical known in the State of California to cause cancer. WARNING! This product contains a chemical known in the State of California to Component v CAS -No Weight % Toluene 108-88-3 < 0.001 Benzene 71-43-2 < 0.0001 Ethyl acrylate 140-88-5 < 0.001 Formaldehyde 50-00-0 < 0.01 Naphthalene (contaminant) 91-20-3 < 1 Carbon black 1333-86-4 1 - 5 Page 6/8 Product code 70111 - Black Revision Date Apr -08-2009 State Right -to -Know Component Minnesota Florida New Jersey Pennsylvania Massachusetts Rhode Island 2-Butoxyethanol Not Listed Not Listed X X X X Diacetone alcohol Not Listed Not Listed X X X X Ethyl 3-Ethoxvpropionate Not Listed Not Listed Not Listed Not Listed Not Listed Not Listed Naphtha (petroleum), heavy aromatic Not Listed Not Listed Not Listed Not Listed Not Listed Not Listed Isophorone Not Listed Not Listed X X X X Carbon black Not Listed Not Listed X X X X Naphthalene (contaminant) Not Listed Not Listed X X X X 1,2,4Trimethylbenzene (contaminant) Not Listed Not Listed X X X X 1,3,5-Trimethylbenzene (contaminant) Not Listed Not Listed X X X X Canada This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the information required by the CPR Component WHMIS Classifications of Components 2-Butoxyethanol B3, D1A, D2B Diacetone alcohol B3, D2B Ethyl 3-Ethoxypropionate B3, D2B Isophorone B3, D2B Carbon black D2A Naphthalene (contaminant) B4, D2A 1,2,4-Trimethylbenzene (contaminant) B3 1,3,5-Trimethylbenzene (contaminant) B3 Component NPRI - National Pollutant Release Inventory 2-Butoxvethanol Part 4 Substance Part 1. Group 1 Substance: Part 5 Substance Diacetone alcohol Part 4 Substance Ethyl 3-Ethoxypropionate Part 4 Substance Naphtha (petroleum), heavy aromatic Part 5 Substance Part 4 Substance Isophorone Part 4 Substance Naphthalene (contaminant) Part 1. Group 1 Substance Part 4 Substance 1,2,4-Trimethylbenzene (contaminant) Part 1, Group 1 Substance; Part 5 Substance Part 5 Substance (except 1,2,4- Trimethyl benzene) Part 4 Substance 1,3,5-Trimethylbenzene (contaminant) Part 5 Substance (except 1,2,4-Trimethyl benzene) Part 4 Substance REACH: Substances of Very High Concern (SVHC): Article 57 of Regulation (EC) No 1907/2006 Does NOT contain a listed substance HMIS: Health 2* Flammability Reactivity 2 0 Revision Date Revision Summary Apr -08-2009 New MSDS format IEI INFORATION';YY; PPE X Page 7 18 Iry Product code 70111 - Black Revision Date Apr -08-2009 Disclaimer The information provided in this Safety Data Sheet Is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text End of MSDS Page 818 Ink Mchnotagies Material Safety Data Sheet Prepared in accordance with ISO 11014-1/ANSI standard Z400.1-2004 Print Date Oct -24-2012 Revision Date Oct -24-2012 �'1�PR�4UC4T N i CO�iA, i 01,40ENtlfrt4 {:ONt _ i Product code Product name Product category Manufacturer or supplier's details UNITED STATES Nazdar Company 8501 Hedge Lane Terrace Shawnee, KS 66227 Tel: 1-913-422-1888 Tel: 1-800-677-4657 Fax: 1-913-422-2294 PA21 Yellow PA Series Poly -All Screen Ink UNITED KINGDOM Nazdar Limited Barton Road Heaton Mersey Stockport, England SK4 3EG Tel: +44 161 442 2111 Emergency Telephone Number USA: Chemtrec: 1-800-424-9300 Outside USA: Chemtrec: 1-703-527-3887 Website: www.nazdar.com MSDS Information: 1-913-422-1888 ext 2305 MSDS Contact: Regulatory Compliance email: regcomp@nazdar.com Tiff' 'ARDStikit D ihCATION 'I;w This product is a preparation. Health hazard information is based on its components. Appearance Flammable Properties Emergency Overview Eyes Skin Inhalation Ingestion Colored liquid Combustible liquid and vapor. Aspiration hazard. Harmful: may cause lung damage if swallowed. Irritant. May cause drowsiness and dizziness. Causes eye irritation. May cause skin irritation and/or dermatitis. May cause irritation of respiratory tract. Inhalation of high vapour concentrations may cause symptoms like headache, dizziness, tiredness, nausea and vomiting. Harmful if swallowed. Potential for aspiration if swallowed. Risk of serious damage to the lungs (by aspiration). i" Or1APOS1�T10NliNFORMATIONON NGREDIENTS > .A,.i.+... y , Z. .Ae.L... ,,,.�..,..4i...�.n.-r �,.wo .. .oe-...�e.l.. .. .......x. A.L..�..n�..Aa....�....F.L�1�2 Component CAS -No Weight % Naphtha (petroleum), heavy aromatic 64742-94-5 30 - 60 Petroleum naphtha, light aromatic 64742-95-6 5 - 10 Titanium dioxide 13463-67-7 5 - 10 Naphthalene (contaminant) 91-20-3 1 - 5 Xylenes (o-, m-, p- isomers) 1330-20-7 1 - 5 1,2,4-Trimethylbenzene (contaminant) 95-63-6 1 - 5 Ethyl benzene (contaminant) 100-41-4 < 1 Cumene (contaminant) 98-82-8 < 0.5 • Component names which have the word (contaminant) are constituents contained in Aromatic Hydrocarbon ingredients and are an integral part of the ingredient and cannot be separated. The percentage listed for the contaminant is as contained in the Hydrocarbon ingredient. (Example: 100% Hydrocarbon, 10% Contaminant A, 3% Contaminant B) Eye Contact Immediately flush with plenty of water. After initial flushing, remove y�t buses and continue flushing for at least 15 minutes. Get medical attention imm 6ittft develops and persists. CITY OF TUKWILA 2 3 iq Page 1/7 JUL 122013 PERMIT CENTER Product code PA21 - Yellow Revision Date Oct -24-2012 Skin Contact Inhalation Ingestion Wash off immediately with soap and plenty of water. Use a mild soap if available. Rinse immediately with plenty of water for at least 15 minutes. Remove contaminated clothing. If irritation develops, get medical attention. If breathed in, move person into fresh air. If breathing is irregular or stopped, administer artificial respiration. Get medical attention immediately. If swallowed, DO NOT induce vomiting. Call a physician or Poison Control Centre immediately. Never give anything by mouth to an unconscious person. X.6,.4 9' Ibi g _fsN a+. '4' t ASC...:tt de.l.+.Y'.'.TLY.J t•,+,.• 5 .r `Sµ FIRE FIGFrTING ME SURE Flammable Properties Suitable Extinguishing Media Protective Equipment and Precautions for Firefighters Specific Hazards Arising from th Chemical Combustible liquid and vapor. Foam. Carbon dioxide (CO2). Dry chemical. Water spray. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. As in any fire, wear self-contained breathing apparatus pressure -demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Keep away from fire, sparks and heated surfaces. Cool containers / tanks with water spray. Fire or intense heat may -cause violent rupture of packages. e Thermal decomposition can lead to release of irritating gases and vapours. Burning produces obnoxious and toxic fumes. ACCIDEN, AL ; IN�t�i LEAS NIEASURES Personal Precautions Methods for Cleaning Up Environmental Precautions Remove all sources of ignition. Ventilate the area. Avoid breathing dust or vapor. Avoid contact with skin, eyes and clothing. Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13). Do not use sparking tools. Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. ANDLIN Handling Storage Avoid contact with skin, eyes and clothing. Ensure adequate ventilation. Remove and wash contaminated clothing before re -use. Discard contaminated shoes. When using do not smoke. Do not take internally. Harmful or fatal if swallowed. Take notice of the directions of use on the label. Keep containers tightly closed in a dry, cool and well -ventilated place. Keep container closed when not in use. Keep out of the reach of children. Keep away from heat and sources of ignition. POSURE;CONTROLS E� ►NAL. PROTECTI Exposure Guidelines • Component ACGIH TLV OSHA PEL NIOSH IDLH Ontario TWAEV Mexico OEL (TWA) Titanium dioxide TWA: 10 mg/m3 TWA: 10 mg/m3 (total dust) TWA: 15 mg/m3 (total 446:151‘) !,�'�' 5000 mg/m3 r TWA: 10 mg/m3 (total dust • ,4,,e` i `• TWA/LMPE-PPT: 10 mg/m3 (as Ti) STEL/LMPE-CT: 20 mg/m3 (as Ti) Page 217 i Product code PA21 - Yellow Revision Date Oct -24-2012 Naphthalene (contaminant) TWA: 10 ppm STEL: 15 ppm Skin TWA: 10 ppm TWA: 50 mg/m3 STEL: 15 ppm STEL: 75 mg/m3 250 ppm TWA: 10 ppm STEL: 15 ppm Skin TWA/LMPE-PPT: 10 ppm TWA/LMPE-PPT: 50 mg/m3 STEULMPE-CT: 15 ppm STEULMPE-CT: 75 mg/m3 Xylenes (o-, m-, p- isomers) TWA: 100 ppm STEL: 150 ppm TWA: 100 ppm TWA: 435 mg/m3 STEL: 150 ppm STEL: 655 mg/m3 TWA: 100 ppm STEL: 150 ppm TWA/LMPE-PPT: 100 ppm TWA/LMPE-PPT: 435 mg/m3 STEULMPE-CT: 150 ppm STEL/LMPE-CT: 655 mg/m3 Ethyl benzene (contaminant) TWA: 20 ppm TWA: 100 ppm TWA: 435 mg/m3 STEL: 125 ppm STEL: 545 mg/m3 800 ppm (10% LEL) TWA: 100 ppm STEL: 125 ppm TWA/LMPE-PPT: 100 ppm TWA/LMPE-PPT: 435 mg/m3 STEULMPE-CT: 125 ppm STEULMPE-CT: 545 mg/m3 Cumene (contaminant) TWA: 50 ppm TWA: 50 ppm TWA: 245 mg/m3 Skin 900 ppm (10% LEL) TWA: 50 ppm TWA/LMPE-PPT: 50 ppm TWA/LMPE-PPT: 245 mg/m3 STEULMPE-CT: 75 ppm STEULMPE-CT: 365 mg/m3 Engineering Measures Personal Protective Equipment Respiratory Protection Eye Protection Skin Protection General Hygiene Considerations Use ventilation adequate to keep exposures below recommended exposure limits. See MSDS. In case of insufficient ventilation, wear suitable respiratory equipment. Use the indicated respiratory protection if the occupational exposure limit is exceeded and/or in case of product release (dust). Respirator with a vapour filter. Ensure that eyewash stations and safety showers are close to the workstation location. Avoid contact with eyes. Safety glasses with side -shields. Goggles. Face -shield. Wear protective gloves/clothing. Solvent -resistant apron and boots. Handle in accordance with good industrial hygiene and safety practice. Wash hands before eating, drinking, or smoking. Remove and wash contaminated clothing before re -use. Avoid contact with skin, eyes and clothing. Wear suitable gloves and eye/face protection. Regular cleaning of equipment, work area and clothing is recommended. t G. 'jar. ` *,4•4 34 PHYSICAL -AND CHEM1C'AL �P Appearance Odor pH Boiling point/Boiling Range Freezing Point/Range Evaporation Rate Vapour Pressure Flammability (solid, gas) Colored liquid Characteristic No information available >149 °C / >300 °F No information available No information available No information available No information available Flash Point 49 °C / 120 °F Method Setaflash closed cup Weight Per Gallon (lbs/gal) 8.67 VOC by weight % (less water) 51.27 VOC lbs/gal (less water) 4.45 Physical State Odor Threshold Autoignition Temperature Melting Point/Range Solubility Partition Coefficient (n-octanol/water) Vapour Density Liquid No information available No information available No information available No information available No information available Heavier than air Flammability Limits in Air Upper No information available Lower No information available Photochemically Reactive Yes Specific Gravity 1.04 VOC by volume % (less water) 55.06 VOC grams/liter (less water) 533.39 Page 3 /7 Product code PA21 - Yellow Revision Date Oct -24-2012 v aarti es _ a. ,rsin.. ..ti �,. t.. v.,�_. ..-+�.. ...a..ta.s, �, •.�..tre .�;-...1��?l. �� Chemical Stability Conditions to Avoid Incompatible Products Stable under normal conditions. Heat, flames and sparks. Strong acids. Strong bases. Strong oxidizing agents. Reducing agents. Hazardous Decomposition Products Thermal decomposition can lead to release of irritating gases and vapours. Carbon dioxide (CO2). Carbon monoxide. Possibility of Hazardous Reactions None under normal processing. rr COLO ICA NF RMATI. Acute Toxicity Component LD50 Oral LD50 Dermal LC50 Inhalation Naphtha (petroleum), heavy aromatic >5000 mg/kg ( Rat) >2000 mg/kg ( Rabbit) >590 mg/m3 ( Rat.) 4 h Petroleum naphtha, light aromatic 8400 mg/kg ( Rat) >2000 mg/kg ( Rabbit) 3400 ppm ( Rat) 4 h >5.2mg/L (Rat)4h Titanium dioxide >10000 mg/kg ( Rat ) X Ethyl benzene (contaminant) Naphthalene (contaminant) 490 mg/kg ( Rat) >2500 mg/kg ( Rat) >20 g/kg ( Rabbit ) >340 mg/m3 ( Rat) 1 h Xylenes (o-, m-, p- isomers) 4300 mg/kg ( Rat) >1700 mg/kg ( Rabbit) 5000 ppm ( Rat) 4 h 47635 mg/L ( Rat) 4 h 1,2,4-Trimethylbenzene (contaminant) 3400 mg/kg ( Rat) >3160 mg/kg ( Rabbit) 18 g/m3 ( Rat) 4 h Ethyl benzene (contaminant) 3500 mg/kg ( Rat) 15354 mg/kg ( Rabbit) 17.2 mg/L ( Rat) 4 h Cumene (contaminant) 1400 mg/kg (Rat) _ >3160 mg/kg ( Rabbit) 39000 mg/m3 ( Rat ) 4 h Chronic Toxicity Component ACGIH IARC NTP OSHA Titanium dioxide Group 2B X Naphthalene (contaminant) Group 2B Reasonably Anticipated X Ethyl benzene (contaminant) A3 Group 2B X Cumene (contaminant) Group 2B X ACGIH: (American Conference of Governmental Industrial Hygienists) IARC: (International Agency for Research on Cancer) NTP: (National Toxicity Program) OSHA: (Occupational Safety & Health Administration) Sensitisation Mutagenic Effects Reproductive Effects Developmental hazard Teratogenicity Chronic Effects Target Organ Effects A3 - Animal Carcinogen Group 28 - Possibly Carcinogenic to Humans Reasonably Anticipated to be a Human Carcinogen X - Present No information available No information available No information available No information available No information available Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may result in adverse health effect, such as mucous membrane and respiratory system irritation and adverse effect on kidney, liver and central nervous system. Blood, Central nervous system, Eyes, Kidney, Liver, Respiratory system, Skin. !:�E'CQLuO.GtCAL�ai NFORNIATlC tM Page 4/7 Product code PA21 - Yellow Revision Date Oct -24-2012 Ecotoxicity We have no quantitative data concerning the ecological effects of this product. Should not be released into the environment. Component Algae Fish Water Flea Petroleum naphtha, light aromatic 3.3 96h LC50 Oncorhynchus mykiss: 9.22 mg/L 2.96 Naphthalene (contaminant) 72h EC50 Skeletonema costatum: 0.4 mg/L 96h LC50 Oncorhynchus mykiss: 0.91 - 2.82 mg/L [static] 96h LC50 Pimephales promelas: 5.74 - 6.44 mg/L [flow-through] 96h LC50 Oncorhynchus mykiss: 1.6 mg/L [flow-through] 96h LC50 Pimephales promelas: 1.99 mg/L [static] 96h LC50 Lepomis macrochirus: 31.0265 mg/L [static] 48h EC50 Daphnia magna: 1.09 - 3.4 mg/L [static] 48h EC50 Daphnia magna: 1.96 mg/L [Flow through] 48h LC50 Daphnia magna: 2.16 mg/L 1,2,4-Trimethylbenzene (contaminant) 3.55 96h LC50 Pimephales promelas: 7.19 - 8.28 mg/L [flow-through] 48h EC50 Daphnia magna: 6.14 mg/L Ethyl benzene (contaminant) 96h EC50 Pseudokirchneriella subcapitata: 1.7 - 7.6 mg/L [static] 72h EC50 Pseudokirchneriella subcapitata: 2.6 - 11.3 mg/L [static] 72h EC50 Pseudokirchneriella subcapitata: 4.6 mg/L 96h EC50 Pseudokirchneriella subcapitata: >438 mg/L 96h LC50 Oncorhynchus mykiss: 11.0 - 18.0 mg/L [static] 96h LC50 Pimephales promelas: 7.55 - 11 mg/L [flow-through] 96h LC50 Pimephales promelas: 9.1 - 15.6 mg/L [static] 96h LC50 Lepomis macrochirus: 32 mg/L [static] 96h LC50 Oncorhynchus mykiss: 4.2 mg/L [semi -static] 96h LC50 Poecilia reticulata: 9.6 mg/L [static] 48h EC50 Daphnia magna: 1.8 - 2.4 mg/L Cumene (contaminant) 72h EC50 Pseudokirchneriella subcapitata: 2.6 mg/L 96h LC50 Pimephales promelas: 6.04 - 6.61 mg/L [flow-through] 96h LC50 Oncorhynchus mykiss: 2.7 mg/L [semi -static] 96h LC50 Oncorhynchus mykiss: 4.8 mg/L [flow-through] 96h LC50 Poecilia reticulata: 5.1 mg/L [semi -static] 48h EC50 Daphnia magna: 7.9 - 14.1 mg/L [static] 48h EC50 Daphnia magna: 0.6 mg/L Persistence and Degradability No information available Bioaccumulation No information available Mobility in Environmental Media No information available Component log Pow Naphtha (petroleum), heavy aromatic 4.5 Naphthalene (contaminant) 3.3 Xylenes (o-, m-, p- isomers) 2.96 1,2,4-Trimethylbenzene (contaminant) 3.63 Ethyl benzene (contaminant) 3.118 Cumene (contaminant) 3.55 DISP�;OSAL CONSIDERATION; • f""a�64 s`t. Waste Disposal Methods Contaminated Packaging Dispose of contents/container in accordance with local regulation. Empty containers should be taken to an approved waste handling site for recycling or disposal. iNSPORT INFORATIl DOT Page 517 Product code PA21 - Yellow Revision Date Oct -24-2012 UN1210, Printing Ink, 3, III In the U.S. and Canada, this material may be reclassified as a combustible liquid and is not regulated, via surface transportation, in containers less than 119 gallons or 450 liters [per 49 CFR 173.150 (f)] [per Transportation of Dangerous Goods Regulations/Clear Language Part 1.33]. ICAO/IATA UN1210, Printing Ink, 3, III IMDG/IMO UN1210, Printing Ink, 3, III REGULATORY �INFORMAII International Inventories Listed on TSCA. For further information, please contact: Manufacturer, importer, supplier U.S. Federal Regulations SARA 313 The following components are subject to r Component CAS -No Weight % SARA 313 - Threshold Values Ethyl benzene (contaminant) 100-41-4 < 1 0.1 - Xylenes (o-, m-, p- isomers) 1330-20-7 1 - 5 1.0 Naphthalene (contaminant) 91-20-3 1 - 5 0.1 1,2,4-Trimethylbenzene (contaminant) 95-63-6 1 - 5 1.0 Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) Component CAS -No Weight % Xylenes (o-, m-, p- isomers) 1330-20-7 1 - 5 Naphthalene (contaminant) 91-20-3 1 - 5 U.S. State Regulations Component Massachusetts Right To Know Minnesota Right To Know New Jersey Right To Know Pennsylvania Right To Know Titanium dioxide X X X X Naphthalene (contaminant) X X X X Xylenes (o-, m-, p- isomers) X X X X 1,2,4-Trimethylbenzene (contaminant) X X X X Ethyl benzene (contaminant) X X X X Cumene (contaminant) X X X X California Prop. 65 WARNING! This product contains a chemical known in the State of California to cause cancer and / or WARNING! This product contains a chemical known in the State of California to cause birth defects or other reproductive harm Component CAS -No Weight % Ethyl benzene (contaminant) 100-41-4 < 1 Titanium dioxide 13463-67-7 5 - 10 Naphthalene (contaminant) 91-20-3 1 - 5 Cumene (contaminant) 98-82-8 < 0.5 Canada This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the information required by the CPR Component WHMIS Classifications of Components Petroleum naphtha, light aromatic _ B3,D2B Titanium dioxide D2A Naphthalene (contaminant) B4,D2A Xylenes (o-, m-, p- isomers) _ B2,D2A,D2B Page 6 / 7 Product code PA21 - Yellow Revision Date Oct -24-2012 1,2,4-Trimethylbenzene (contaminant) B3 Ethyl benzene (contaminant) B2,D2A,D2B Cumene (contaminant) B2,D2A Component NPRI - National Pollutant Release Inventory Naphtha (petroleum), heavy aromatic Part 5 Substance Part 5, Other Groups and Mixtures Petroleum naphtha, light aromatic Part 5 Substance Part 5, Other Groups and Mixtures Naphthalene (contaminant) Part 1, Group 1 Substance Xylenes (o-, m-, p- isomers) Part 1, Group 1 Substance Part 5 Substance Part 5, Isomer Groups 1,2,4-Trimethylbenzene (contaminant) Part 4 Substance Part 1, Group 1 Substance Part 5, Individual Substance Ethyl benzene (contaminant) Part 4 Substance Part 1, Group 1 Substance Cumene (contaminant) Part 4 Substance Part 1, Group 1 Substance Regulation (EC) No. 1907/2006 (REACH), Article 57 This product does not contain substances of very high concern (Regulation (EC) No. 1907/2006 (REACH), Article 57) HMIS: Revision Date Revision Note Health 2* Flammability 2 Reactivity 0 4s,.•n ` �fh�s''''ERtfNFOR,�AT10N���,�t'� Oct -24-2012 New MSDS format PPE X Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text End of MSDS Page 7 /7 I Ink Technologies Material Safety Data Sheet Prepared in accordance with ISO 11014-1/ANSI standard Z400.1-2004 Print Date Oct -24-2012 Revision Date Oct -24-2012 ;IA yOi? A�Y 1:D N let Product code Product name Product category Manufacturer or supplier's details UNITED STATES Nazdar Company 8501 Hedge Lane Terrace Shawnee, KS 66227 Tel: 1-913-422-1888 Tel: 1-800-677-4657 Fax: 1-913-422-2294 PA30 Emerald Green PA Series Poly -All Screen Ink UNITED KINGDOM Nazdar Limited Barton Road Heaton Mersey Stockport, England SK4 3EG Tel: +44 161 442 2111 Emergency Telephone Number USA: Chemtrec: 1-800-424-9300 Outside USA: Chemtrec: 1-703-527-3887 Website: www.nazdar.com MSDS Information: 1-913-422-1888 ext 2305 MSDS Contact: Regulatory Compliance email: regcomp@nazdar.com AZARDSIDENTIF.ICATIO This product is a preparation. Health hazard information is based on its components. Appearance Flammable Properties Emergency Overview Eyes Skin Inhalation Ingestion Colored liquid Combustible liquid and vapor. Aspiration hazard. Harmful: may cause lung damage if swallowed. Irritant. May cause drowsiness and dizziness. Causes eye irritation. May cause skin irritation and/or dermatitis. May cause irritation of respiratory tract. Inhalation of high vapour concentrations may cause symptoms like headache, dizziness, tiredness, nausea and vomiting. Harmful if swallowed. Potential for aspiration if swallowed. Risk of serious damage to the lungs (by aspiration). COMPOSITIONHNFORMATiON ONIN;GREDIEN7 Component CAS -No Weight % Naphtha (petroleum), heavy aromatic 64742-94-5 30 - 60 Petroleum naphtha, light aromatic 64742-95-6 5 - 10 Titanium dioxide 13463-67-7 1 - 5 Naphthalene (contaminant) 91-20-3 1 - 5 Xylenes (o-, m-, p- isomers) 1330-20-7 1-5 1,2,4-Trimethylbenzene (contaminant) 95-63-6 1 - 5 Copper Phthalocyanine Compound Trade Secret 1 - 5 Ethyl benzene (contaminant) 100-41-4 < 1 Cumene (contaminant) 98-82-8 < 0.5 • Component names which have the word (contaminant) are constituents contained in Aromatic Hydrocarbon ingredients and are an integral part of the ingredient and cannot be separated. The percentage listed for the contaminant is as contained in the Hydrocarbon ingredient. (Example: 100% Hydrocarbon, 10% Contaminant A, 3% Contaminant B) Eye Contact Immediately flush with plenty of water. After initial flushing, remove any contact lenses and develops and persists. RECEIVED continue flushing for at least 15 minutes. Get medical attention immediately if irritation CITY OF TUKWILA JUL 122013 Page 1 / 7 PERMIT CENTER Product code PA30 - Emerald Green Revision Date Oct -24-2012 Skin Contact Inhalation Ingestion Wash off immediately with soap and plenty of water. Use a mild soap if available. Rinse immediately with plenty of water for at least 15 minutes. Remove contaminated clothing. If irritation develops, get medical attention. If breathed in, move person into fresh air. If breathing is irregular or stopped, administer artificial respiration. Get medical attention immediately. If swallowed, DO NOT induce vomiting. Call a physician or Poison Control Centre immediately. Never give anything by mouth to an unconscious person. ,V Jff 14• ,...7!" „PA IR!141G{MEASU,RE v ,,i' k Flammable Properties Combustible liquid and vapor. Suitable Extinguishing Media Foam. Carbon dioxide (CO2). Dry chemical. Water spray. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure -demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Keep away from fire, sparks and heated surfaces. Cool containers / tanks with water spray. Fire or intense heat may cause violent rupture of packages. Specific Hazards Arising from the Thermal decomposition can lead to release of irritating gases and vapours. Burning produces obnoxious and toxic fumes. Chemical -17641, f.Y: `. 'taiRa..y V�.ti Or ru , y�•- .zz •�.- ,p. I�6 k�C • IDE 1� 'AL 1tELEASE MEAS,CI.R • Personal Precautions Methods for Cleaning Up Environmental Precautions Remove all sources of ignition. Ventilate the area. Avoid breathing dust or vapor. Avoid contact with skin, eyes and clothing. Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13). Do not use sparking tools. Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. 'iciPy!!Att” ,A, A'NDLING+ANDS? RAG! Handling Storage Avoid contact with skin, eyes and clothing. Ensure adequate ventilation. Remove and wash contaminated clothing before re -use. Discard contaminated shoes. When using do not smoke. Do not take internally. Harmful or fatal if swallowed. Take notice of the directions of use on the label. Keep containers tightly closed in a dry, cool and well -ventilated place. Keep container closed when not in use. Keep out of the reach of children. Keep away from heat and sources of ignition. cr ,P3 iU �zCO.NTe1tOLS/PERSONAL`�P Exposure Guidelines Component ACGIH TLV OSHA PEL NIOSH IDLH Ontario TWAEV Mexico OEL (TWA) Titanium dioxide • TWA: 10 mg/m3 TWA: 10 mg/m3 (total dust) TWA: 15 mg/m3 (total dust) 5000 mg/m3 --.,,,, 1 TWA: 10 mg/m3 (total dust) .IP y', TWA/LMPE-PPT: 10 mg/m3 (as Ti) STEULMPE-CT: 20 mg/m3 (as Ti) • . •yc.. r. • Page 2/7 Product code PA30 - Emerald Green Revision Date Oct -24-2012 Naphthalene (contaminant) TWA: 10 ppm STEL: 15 ppm Skin TWA: 10 ppm TWA: 50 mg/m3 STEL: 15 ppm STEL: 75 mg/m3 250 ppm TWA: 10 ppm STEL: 15 ppm Skin TWA/LMPE-PPT: 10 ppm TWA/LMPE-PPT: 50 mg/m3 STEULMPE-CT: 15 ppm STEULMPE-CT: 75 mg/m3 Xylenes (o-, m-, p- isomers) TWA: 100 ppm STEL: 150 ppm TWA: 100 ppm TWA: 435 mg/m3 STEL: 150 ppm STEL: 655 mg/m3 TWA: 100 ppm STEL: 150 ppm TWA/LMPE-PPT: 100 ppm TWA/LMPE-PPT: 435 mg/m3 STEULMPE-CT: 150 ppm STEULMPE-CT: 655 mg/m3 Ethyl benzene (contaminant) TWA: 20 ppm TWA: 100 ppm TWA: 435 mg/m3 STEL: 125 ppm STEL: 545 mg/m3 800 ppm (10% LEL) TWA: 100 ppm STEL: 125 ppm TWA/LMPE-PPT: 100 ppm TWA/LMPE-PPT: 435 mg/m3 STEULMPE-CT: 125 ppm STEULMPE-CT: 545 mg/m3 Cumene (contaminant) TWA: 50 ppm TWA: 50 ppm TWA: 245 mg/m3 Skin 900 ppm (10% LEL) TWA: 50 ppm TWA/LMPE-PPT: 50 ppm TWA/LMPE-PPT: 245 mg/m3 STEULMPE-CT: 75 ppm STEULMPE-CT: 365 mg/m3 Engineering Measures Personal Protective Equipment Respiratory Protection Eye Protection Skin Protection General Hygiene Considerations Use ventilation adequate to keep exposures below recommended exposure limits. See MSDS. In case of insufficient ventilation, wear suitable respiratory equipment. Use the indicated respiratory protection if the occupational exposure limit is exceeded and/or in case of product release (dust). Respirator with a vapour filter. Ensure that eyewash stations and safety showers are close to the workstation location. Avoid contact with eyes. Safety glasses with side -shields. Goggles. Face -shield. Wear protective gloves/clothing. Solvent -resistant apron and boots. Handle in accordance with good industrial hygiene and safety practice. Wash hands before eating, drinking, or smoking. Remove and wash contaminated clothing before re -use. Avoid contact with skin, eyes and clothing. Wear suitable gloves and eye/face protection. Regular cleaning of equipment, work area and clothing is recommended. a ?9PHYSIC}ALAN i4CHEMICALPROPERTIES;® Appearance Odor pH Boiling point/Boiling Range Freezing Point/Range Evaporation Rate Vapour Pressure Flammability (solid, gas) Colored liquid Characteristic No information available >149 °C / >300 °F No information available No information available No information available No information available Flash Point 49 °C / 120 °F Method Setaflash closed cup Weight Per Gallon (lbs/gal) 8.64 VOC by weight % (less water) 51.77 VOC lbs/gal (less water) 4.48 Physical State Odor Threshold Autoignition Temperature Melting Point/Range Solubility Partition Coefficient (n-octanol/water) Vapour Density Liquid No information available No information available No information available No information available No information available Heavier than air Flammability Limits in Air Upper No information available Lower No information available Photochemically Reactive Yes Specific Gravity 1.04 VOC by volume % (less water) 55.47 VOC grams/liter (less water) 536.4 Page 3/7 Product code PA30 - Emerald Green Revision Date Oct -24-2012 Ns LI'I���AF���i�EACTAIV Chemical Stability Conditions to Avoid Incompatible Products Stable under normal conditions. Heat, flames and sparks. Strong acids. Strong bases. Strong oxidizing agents. Reducing agents. Hazardous Decomposition Products Thermal decomposition can lead to release of irritating gases and vapours. Carbon dioxide (CO2). Carbon monoxide. Possibility of Hazardous Reactions None under normal processing. Acute Toxicity Idled GI�CAI lir ORNIAt oNr Component LD50 Oral LD50 Dermal LC50 Inhalation Naphtha (petroleum), heavy aromatic >5000 mg/kg ( Rat) >2000 mg/kg ( Rabbit) >590 mg/m3 ( Rat) 4 h Petroleum naphtha, light aromatic . 8400 mg/kg ( Rat) >2000 mg/kg ( Rabbit) 3400 ppm ( Rat ) 4 h >5.2 mg/L (Rat) 4h Titanium dioxide >10000 mg/kg ( Rat ) X Ethyl benzene (contaminant) Naphthalene (contaminant) 490 mg/kg ( Rat) >2500 mg/kg ( Rat) >20 g/kg ( Rabbit ) >340 mg/m3 ( Rat) 1 h Xylenes (o-, m-, p- isomers) 4300 mg/kg ( Rat) >1700 mg/kg ( Rabbit) 5000 ppm ( Rat) 4 h 47635 mg/L ( Rat) 4 h 1,2,4-Trimethylbenzene (contaminant) 3400 mg/kg ( Rat) >3160 mg/kg ( Rabbit) 18 g/m3 ( Rat) 4 h Copper Phthalocyanine Compound 3000 mg/kg ( Rat ) Ethyl benzene (contaminant) 3500 mg/kg ( Rat) 15354 mg/kg ( Rabbit) 17.2 mg/L ( Rat) 4 h Cumene (contaminant) 1400 mg/kg ( Rat) >3160 mg/kg ( Rabbit) 39000 mg/m3 ( Rat) 4 h Chronic Toxicity Component ACGIH IARC NTP OSHA Titanium dioxide Group 2B X Naphthalene (contaminant) Group 2B Reasonably Anticipated X Ethyl benzene (contaminant) A3 Group 2B X Cumene (contaminant) Group 2B X ACGIH: (American Conference of Governmental Industrial Hygienists) IARC: (International Agency for Research on Cancer) NTP: (National Toxicity Program) OSHA: (Occupational Safety & Health Administration) Sensitisation Mutagenic Effects Reproductive Effects Developmental hazard Teratogenicity Chronic Effects Target Organ Effects A3 - Animal Carcinogen Group 2B - Possibly Carcinogenic to Humans Reasonably Anticipated to be a Human Carcinogen X - Present No information available No information available No information available No information available No information available Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may result in adverse health effect, such as mucous membrane and respiratory system irritation and adverse effect on kidney, liver and central nervous system. Blood, Central nervous system, Eyes, Kidney, Liver, Respiratory system, Skin. aECOLOGICAL INFORMATION Page 4/7 Product code PA30 - Emerald Green Revision Date Oct -24-2012 Ecotoxicity We have no quantitative data concerning the ecological effects of this product. Should not be released into the environment. Component Algae Fish Water Flea Petroleum naphtha, light aromatic 3.3 96h LC50 Oncorhynchus mykiss: 9.22 mg/L 2.96 Naphthalene (contaminant) 72h EC50 Skeletonema costatum: 0.4 mg/L 96h LC50 Oncorhynchus mykiss: 0.91 - 2.82 mg/L [static] 96h LC50 Pimephales promelas: 5.74 - 6.44 mg/L [flow-through] 96h LC50 Oncorhynchus mykiss: 1.6 mg/L [flow-through] 96h LC50 Pimephales promelas: 1.99 mg/L [static] 96h LC50 Lepomis macrochirus: 31.0265 mg/L [static] 48h EC50 Daphnia magna: 1.09 - 3.4 mg/L [static] 48h EC50 Daphnia magna: 1.96 mg/L [Flow through] 48h LC50 Daphnia magna: 2.16 mg/L 1,2,4-Trimethylbenzene (contaminant) 3.55 96h LC50 Pimephales promelas: 7.19 - 8.28 mg/L [flow-through] 48h EC50 Daphnia magna: 6.14 mg/L Copper Phthalocyanine Compound 96h LC50 Lepomis macrochirus: 752.4 mg/L [static] 24h EC50 Daphnia magna Straus: >500 mg/L Ethyl benzene (contaminant) 96h EC50 Pseudokirchneriella subcapitata: 1.7 - 7.6 mg/L [static] 72h EC50 Pseudokirchneriella subcapitata: 2.6 - 11.3 mg/L [static] 72h EC50 Pseudokirchneriella subcapitata: 4.6 mg/L 96h EC50 Pseudokirchneriella subcapitata: >438 mg/L 96h LC50 Oncorhynchus mykiss: 11.0 - 18.0 mg/L [static] 96h LC50 Pimephales promelas: 7.55 - 11 mg/L [flow-through] 96h LC50 Pimephales promelas: 9.1 - 15.6 mg/L [static] 96h LC50 Lepomis macrochirus: 32 mg/L [static] 96h LC50 Oncorhynchus mykiss: 4.2 mg/L [semi -static] 96h LC50 Poecilia reticulata: 9.6 mg/L [static] 48h EC50 Daphnia magna: 1.8 - 2.4 mg/L Cumene (contaminant) 72h EC50 Pseudokirchneriella subcapitata: 2.6 mg/L 96h LC50 Pimephales promelas: 6.04 - 6.61 mg/L [flow-through] 96h LC50 Oncorhynchus mykiss: 2.7 mg/L [semi -static] 96h LC50 Oncorhynchus mykiss: 4.8 mg/L [flow-through] 96h LC50 Poecilia reticulata: 5.1 mg/L [semi -static] 48h EC50 Daphnia magna: 7.9 - 14.1 mg/L [static] 48h EC50 Daphnia magna: 0.6 mg/L Persistence and Degradability No information available Bioaccumulation No information available Mobility In Environmental Media No information available Component log Pow Naphtha (petroleum), heavy aromatic 4.5 Naphthalene (contaminant) 3.3 Xylenes (o-, m-, p- isomers) 2.96 1,2,4-Trimethylbenzene (contaminant) 3.63 Ethyl benzene (contaminant) 3.118 Cumene (contaminant) 3.55 !DISPO'SAL5CONSID,ERATIO za Waste Disposal Methods Contaminated Packaging Dispose of contents/container in accordance with local regulation. Empty containers should be taken to an approved waste handling site for recycling or disposal. Page 5/7 Product code PA30 - Emerald Green e. Revision Date Oct -24-2012 DOT UN1210, Printing Ink, 3, III In the U.S. and Canada, this material may be reclassified as a combustible liquid and is not regulated, via surface transportation, in containers less than 119 gallons or 450 liters [per 49 CFR 173.150 (f)] [per Transportation of Dangerous Goods Regulations/Clear Language Part 1.33]. ICAO/IATA UN1210, Printing Ink, 3, III IMDG/IMO UN1210, Printing Ink, 3, III =REOULAT:ORY INFORMATION International Inventories Listed on TSCA. For further information, please contact: Manufacturer, importer, supplier U.S. Federal Regulations SARA 313 The following components are subject to r Component CAS -No Weight /o SARA 313 - Threshold Values Ethyl benzene (contaminant) 100-41-4 < 1 0.1 Xylenes (o-, m-, p- isomers) 1330-20-7 1 - 5 1.0 Naphthalene (contaminant) 91-20-3 1 - 5 0.1 1,2,4-Trimethylbenzene (contaminant) 95-63-6 1 - 5 1.0 Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) Component CAS -No Weight % Xylenes (o-, m-, p- isomers) 1330-20-7 1 - 5 Naphthalene (contaminant) 91-20-3 1 - 5 U.S. State Regulations Component Massachusetts Right To Know Minnesota Right To Know New Jersey Right To Know Pennsylvania Right To Know Titanium dioxide X X X X Naphthalene (contaminant) X X X X Xylenes (o-, m-, p- isomers) X X X X 1,2,4-Trimethylbenzene (contaminant) X X X X Copper Phthalocyanine Compound Not Listed Not Listed X X Ethyl benzene (contaminant) X X X X Cumene (contaminant) X X X X California Prop. 65 WARNING! This product contains a chemical known in the State of California to cause cancer and / or WARNING! This product contains a chemical known in the State of California to cause birth defects or other reproductive harm Component CAS -No Weight % Ethyl benzene (contaminant) 100-41-4 < 1 Titanium dioxide 13463-67-7 1 - 5 Naphthalene (contaminant) 91-20-3 1 - 5 Cumene (contaminant) 98-82-8 < 0.5 Canada This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the information required by the CPR Component WHMIS Classifications of Components Petroleum naphtha, light aromatic B3,D2B Titanium dioxide D2A Page 6/7 Product code PA30 - Emerald Green Revision Date Oct -24-2012 Naphthalene (contaminant) B4,D2A Xylenes co-, m-, p- isomers) B2,D2A,D2B 1,2,4-Trimethylbenzene (contaminant) B3 Ethyl benzene (contaminant) B2,D2A,D2B Cumene (contaminant) B2,D2A Component NPRI - National Pollutant Release Inventory Naphtha (petroleum), heavy aromatic Part 5 Substance Part 5, Other Groups and Mixtures Petroleum naphtha, light aromatic Part 5 Substance Part 5, Other Groups and Mixtures Naphthalene (contaminant) Part 1, Group 1 Substance Xylenes (o-, m-, p- isomers) Part 1, Group 1 Substance Part 5 Substance Part 5, Isomer Groups 1,2,4-Trimethylbenzene (contaminant) Part 4 Substance Part 1, Group 1 Substance Part 5, Individual Substance Copper Phthalocyanine Compound Part 1, Group 1 Substance Ethyl benzene (contaminant) Part 4 Substance Part 1, Group 1 Substance Cumene (contaminant) Part 4 Substance Part 1, Group 1 Substance Regulation (EC) No. 1907/2006 (REACH), Article 57 This product does not contain substances of very high concern (Regulation (EC) No. 1907/2006 (REACH), Article 57) HMIS: Health 2* Flammability 2 Reactivity 0 PPE X T�HERINFORATION'4'`��° Revision Date Revision Note Oct -24-2012 New MSDS format Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text End of MSDS Page 7/7 Ink Technologies Material Safety Data Sheet Prepared in accordance with ISO 11014-1/ANSI standard Z400.1-2004 Print Date Oct -24-2012 Revision Date Oct -24-2012 Ftgl,:a a -r i .�sn -,.4�i,rm t}�eK-1, a'.....w�.e.r ze �zrg.:egar p....Eirk4ut ^'! r RDt�C'IAO'�N�Wk TI'©; Product code Product name Product category Manufacturer or supplier's details UNITED STATES Nazdar Company 8501 Hedge Lane Terrace Shawnee, KS 66227 Tel: 1-913-422-1888 Tel: 1-800-677-4657 Fax: 1-913-422-2294 PA43 Royal Blue PA Series Poly -All Screen Ink UNITED KINGDOM Nazdar Limited Barton Road Heaton Mersey Stockport, England SK4 3EG Tel: +44 161 442 2111 Emergency Telephone Number USA: Chemtrec: 1-800-424-9300 Outside USA: Chemtrec: 1-703-527-3887 Website: www.nazdar.com MSDS Information: 1-913-422-1888 ext 2305 MSDS Contact: Regulatory Compliance email: regcomp@nazdar.com kL-a(et, ,.�y,,. f W'•:•. M. .!-rex ♦.M4'A4'e'd iAZARDS IDENTIFICATION ' 1 vr4 This product is a preparation. Health hazard information is based on its components. Appearance Flammable Properties Emergency Overview Eyes Skin Inhalation Ingestion Colored liquid Combustible liquid and vapor. Aspiration hazard. Harmful: may cause lung damage if swallowed. Irritant. May cause drowsiness and dizziness. Causes eye irritation. May cause skin irritation and/or dermatitis. May cause irritation of respiratory tract. Inhalation of high vapour concentrations may cause symptoms like headache, dizziness, tiredness, nausea and vomiting. Harmful if swallowed. Potential for aspiration if swallowed. Risk of serious damage to the lungs (by aspiration). OMPOSMON/INFORMATION+ON INtGREDIENT :r Component CAS -No Weight % Naphtha (petroleum), heavy aromatic 64742-94-5 30 - 60 Copper Phthalocyanine Compound Trade Secret 5 -10 Petroleum naphtha, light aromatic 64742-95-6 5 - 10 Naphthalene (contaminant) 91-20-3 1 - 5 Xylenes (o-, m-, p- isomers) 1330-20-7 1 - 5 1,2,4-Trimethylbenzene (contaminant) 95-63-6 1 - 5 Titanium dioxide 13463-67-7 1 - 5 Ethyl benzene (contaminant) 100-41-4 < 1 Cumene (contaminant) 98-82-8 < 0.5 • Component names which have the word (contaminant) are constituents contained in Aromatic Hydrocarbon ingredients and are an integral part of the ingredient and cannot be separated. The percentage listed for the contaminant is as contained in the Hydrocarbon ingredient. (Example: 100% Hydrocarbon, 10% Contaminant A, 3% Contaminant 8) •1RSTAIDMEASURES"u' Eye Contact Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get medical attention immediately if irritation develops and persists. RECEIVED CITY OF TUKWILA JUL 11 2013 Page 117 9 PERMIT CENTER Product code PA43 - Royal Blue • Revision Date Oct -24-2012 Skin Contact Inhalation Ingestion Wash off immediately with soap and plenty of water. Use a mild soap if available. Rinse immediately with plenty of water for at least 15 minutes. Remove contaminated clothing. If irritation develops, get medical attention. If breathed in, move person into fresh air. If breathing is irregular or stopped, administer artificial respiration. Get medical attention immediately. If swallowed, DO NOT induce vomiting. Call a physician or Poison Control Centre immediately. Never give anything by mouth to an unconscious person. IRE=F I GHTINwMEAStJ RES Flammable Properties Suitable Extinguishing Media Protective Equipment and Precautions for Firefighters Specific Hazards Arising from the Chemical Combustible liquid and vapor. Foam. Carbon dioxide (CO2). Dry chemical. Water spray. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. As in any fire, wear self-contained breathing apparatus pressure -demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Keep away from fire, sparks and heated surfaces. Cool containers / tanks with water spray. Fire or intense heat may cause violent rupture of packages. Thermal decomposition can lead to release of irritating gases and vapours. Burning produces obnoxious and toxic fumes. r err "Ccb ar CIDENTAL E�EASE`MEASURESx Personal Precautions Methods for Cleaning Up Environmental Precautions Remove all sources of ignition. Ventilate the area. Avoid breathing dust or vapor. Avoid contact with skin, eyes and clothing. Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13). Do not use sparking tools. Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. NDLtNG %RAGI Handling Storage Avoid contact with skin, eyes and clothing. Ensure adequate ventilation. Remove and wash contaminated clothing before re -use. Discard contaminated shoes. When using do not smoke. Do not take internally. Harmful or fatal if swallowed. Take notice of the directions of use on the label. Keep containers tightly closed in a dry, cool and well -ventilated place. Keep container closed when not in use. Keep out of the reach of children. Keep away from heat and sources of ignition. PQSUR'CONTROLS/PERSONAL PROTECTIet Exposure Guidelines Component ACGIH TLV OSHA PEL NIOSH IDLH Ontario TWAEV a:r '-fl Mexico OEL (TWA) Page 217 Product code PA43 - Royal Blue Revision Date Oct -24-2012 Naphthalene (contaminant) TWA: 10 ppm STEL: 15 ppm Skin TWA: 10 ppm TWA: 50 mg/m3 STEL: 15 ppm STEL: 75 mg/m3 250 ppm TWA: 10 ppm STEL: 15 ppm Skin TWA/LMPE-PPT: 10 ppm TWA/LMPE-PPT: 50 mg/m3 STEULMPE-CT: 15 ppm STELMP T: mg/m3 Xylenes (o-, m-, p- isomers) • TWA: 100 ppm STEL: 150 ppm TWA: 100 ppm TWA: 435 m /m3 9 STEL: 150 ppm STEL: 655 mg/m3 TWA: 100 STEL: 150 ppm ppm TWAT -P 100 TW WA/LM E -P: ppm TWA/LMPE-PPT: 435 mg/m3 STEULMPE-CT: 150 ppm STEULMPE-CT: 655 mg/m3 Titanium dioxide TWA: 10 mg/m3 TWA: 10 mg/m3 (total dust) TWA: 15 mg/m3 (total dust) 5000 mg/m3 TWA: 10 mg/m3 (total dust) TWA/LMPE-PPT: 10 mg/m3 (as Ti) STEULMPE-CT: 20 mg/m3 (as Ti) Ethyl benzene (contaminant) TWA: 20 ppm TWA: 100 ppm TWA: 435 mg/m3 STEL: 125 ppm STEL: 545 mg/m3 800 ppm (10% LEL) TWA: 100 ppm STEL: 125 ppm TWA/LMPE-PPT: 100 ppm TWA/LMPE-PPT: 435 mg/m3 STEULMPE-CT: 125 ppm STEL/LMPE-CT: 545 mg/m3 Cumene (contaminant) TWA: 50 ppm TWA: 50 ppm TWA: 245 mg/m3 Skin 900 ppm (10% LEL) TWA: 50 ppm - TWA/LMPE-PPT: 50 ppm TWA/LMPE-PPT: 245 mg/m3 STEULMPE-CT: 75 ppm STEULMPE-CT: 365 mg/m3 Engineering Measures Personal Protective Equipment Respiratory Protection Eye Protection Skin Protection General Hygiene Considerations Use ventilation adequate to keep exposures below recommended exposure limits. See MSDS. In case of insufficient ventilation, wear suitable respiratory equipment. Use the indicated respiratory protection if the occupational exposure limit is exceeded and/or in case of product release (dust). Respirator with a vapour filter. Ensure that eyewash stations and safety showers are close to the workstation location. Avoid contact with eyes. Safety glasses with side -shields. Goggles. Face -shield. Wear protective gloves/clothing. Solvent -resistant apron and boots. Handle in accordance with good industrial hygiene and safety practice. Wash hands before eating, drinking, or smoking. Remove and wash contaminated clothing before re -use. Avoid contact with skin, eyes and clothing. Wear suitable gloves and eye/face protection. Regular cleaning of equipment, work area and clothing is recommended. -yy;,, N^ .w-+- »q.ayyy.:(,,nx+nb PHYSICAL;�1NWCHEM CAL ROPERTt S Jr, Appearance Odor pH Boiling point/Boiling Range Freezing Point/Range Evaporation Rate Vapour Pressure Flammability (solid, gas) Colored liquid Characteristic No information available >149 °C / >300 °F No information available No information available No information available No information available Flash Point 49 °C / 120 °F Method Setaflash closed cup Physical State Odor Threshold Autoignition Temperature Melting Point/Range Solubility Partition Coefficient (n-octanollwater) Vapour Density Liquid No information available No information available No information available No information available No information available Heavier than air Flammability Limits in Air Upper No information available Lower No information available Photochemically Reactive Yes Page 3/7 Product code PA43 - Royal Blue Revision Date Oct -24-2012 Weight Per Gallon (lbs/gal) 8.5 VOC by weight % (less water) 53.38 VOC lbs/gal (less water) 4.54 Specific Gravity 1.02 VOC by volume % (less water)56.32 VOC grams/liter (less water) 544.24 4.41 it CTIVIrve Chemical Stability Conditions to Avoid Incompatible Products Stable under normal conditions. Heat, flames and sparks. Strong acids. Strong bases. Strong oxidizing agents. Reducing agents. Hazardous Decomposition Products Thermal decomposition can lead to release of irritating gases and vapours. Carbon dioxide (CO2). Carbon monoxide. Possibility of Hazardous Reactions None under normal processing. y.. ..0• py�dN. '. 2'''"yv' dbiroGICA a I FORMA i Acute Toxicity Component LD50 Oral LD50 Dermal LC50 Inhalation Naphtha (petroleum), heavy aromatic >5000 mg/kg ( Rat) >2000 mg/kg ( Rabbit) >590 mg/m3 ( Rat) 4 h Petroleum naphtha, light aromatic 8400 mg/kg ( Rat) >2000 mg/kg ( Rabbit) 3400 ppm ( Rat) 4 h >5.2mg/L (Rat) 4h Naphthalene (contaminant) 490 mg/kg ( Rat) >2500 mg/kg ( Rat) >20 g/k9 ( Rabbit ) >340 mg/m3 ( Rat) 1 h Xylenes (o-, m-, p- isomers) 4300 mg/kg ( Rat) >1700 mg/kg ( Rabbit) 5000 ppm ( Rat) 4 h 47635 mg/L ( Rat) 4 h 1,2,4-Trimethylbenzene (contaminant) 3400 mg/kg ( Rat) >3160 mg/kg ( Rabbit) 18 g/m3 ( Rat) 4 h Titanium dioxide >10000 mg/kg ( Rat ) Ethyl benzene (contaminant) 3500 mg/kg ( Rat) 15354 mg/kg ( Rabbit) 17.2 mg/L ( Rat) 4 h Cumene (contaminant) 1400 mg/kg ( Rat) >3160 mg/kg ( Rabbit) 39000 mg/m3 ( Rat) 4 h Chronic Toxicity Component ACGIH IARC NTP OSHA Naphthalene (contaminant) Group 28 Reasonably Anticipated X Titanium dioxide Group 2B X Ethyl benzene (contaminant) A3 Group 2B X Cumene (contaminant) Group 26 X ACGIH: (American Conference of Governmental Industrial Hygienists) IARC: (International Agency for Research on Cancer) NTP: (National Toxicity Program) OSHA: (Occupational Safety & Health Administration) Sensitisation Mutagenic Effects Reproductive Effects Developmental hazard Teratogenicity Chronic Effects Target Organ Effects A3 - Animal Carcinogen Group 28 - Possibly Carcinogenic to Humans Reasonably Anticipated to be a Human Carcinogen X - Present No information available No information available No information available No information available No information available Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may result in adverse health effect, such as mucous membrane and respiratory system irritation and adverse effect on kidney, liver and central nervous system. Blood, Central nervous system, Eyes, Kidney, Liver, Respiratory system, Skin. Page 4 / 7 Product code PA43 - Royal Blue Revision Date Oct -24-2012 :144 `;gECOLOGI OA Ecotoxicity We have no quantitative data concerning the ecological effects of this product. Should not be released into the environment. Component Algae Fish Water Flea Petroleum naphtha, light aromatic 3.3 96h LC50 Oncorhynchus mykiss: 9.22 mg/L 2.96 Naphthalene (contaminant) 72h EC50 Skeletonema costatum: 0.4 mg/L 96h LC50 Oncorhynchus mykiss: 0.91 - 2.82 mg/L [static] 96h LC50 Pimephales promelas: 5.74 - 6.44 mg/L [flow-through] 96h LC50 Oncorhynchus mykiss: 1.6 mg/L [flow-through] 96h LC50 Pimephales promelas: 1.99 nig/L [static] 96h LC50 Lepomis macrochirus: 31.0265 mg/L [static] 48h EC50 Daphnia magna: 1.09 - 3.4 mg/L [static] 48h EC50 Daphnia magna: 1.96 mg/L [Flow through] 48h LC50 Daphnia magna: 2.16 mg/L 1,2,4-Trimethylbenzene (contaminant) 3.55 96h LC50 Pimephales promelas: 7.19 - 8.28 mg/L [flow-through] 48h EC50 Daphnia magna: 6.14 mg/L Ethyl benzene (contaminant) 96h EC50 Pseudokirchneriella subcapitata: 1.7 - 7.6 mg/L [static] 72h EC50 Pseudokirchneriella subcapitata: 2.6 - 11.3 mg/L [static] 72h EC50 Pseudokirchneriella subcapitata: 4.6 mg/L 96h EC50 Pseudokirchneriella subcapitata: >438 mg/L 96h LC50 Oncorhynchus mykiss: 11.0 - 18.0 mg/L [static] 96h LC50 Pimephales promelas: 7.55 - 11 mg/L [flow-through] 96h LC50 Pimephales promelas: 9.1 - 15.6 mg/L [static] 96h LC50 Lepomis macrochirus: 32 mg/L [static] 96h LC50 Oncorhynchus mykiss: 4.2 mg/L [semi -static] 96h LC50 Poecilia reticulata: 9.6 mg/L [static] 48h EC50 Daphnia magna: 1.8 - 2.4 mg/L Cumene (contaminant) 72h EC50 Pseudokirchneriella subcapitata: 2.6 mg/L 96h LC50 Pimephales promelas: 6.04 - 6.61 mg/L [flow-through] 96h LC50 Oncorhynchus mykiss: 2.7 mg/L [semi -static] 96h LC50 Oncorhynchus mykiss: 4.8 mg/L [flow-through] 96h LC50 Poecilia reticulata: 5.1 mg/L [semi -static] 48h EC50 Daphnia magna: 7.9 - 14.1 mg/L [static] 48h EC50 Daphnia magna: 0.6 mg/L Persistence and Degradability No information available Bioaccumulation No information available Mobility in Environmental Media No information available Component log Pow Naphtha (petroleum), heavy aromatic 4.5 Naphthalene (contaminant) 3.3 Xylenes (o-, m-, p- isomers) 2.96 1,2,4-Trimethylbenzene (contaminant) 3.63 Ethyl benzene (contaminant) 3.118 Cumene (contaminant) 3.55 Waste Disposal Methods Contaminated Packaging . fDISPOSAL C01 SIDERATlONS r Dispose of contents/container in accordance with local regulation. Empty containers should be taken to an approved waste handling site for recycling or disposal. sR`ANSPORTy 1NFORMATIC Page 517 Product code PA43 - Royal Blue 4 Revision Date Oct -24-2012 DOT UN1210, Printing Ink, 3, III In the U.S. and Canada, this material may be reclassified as a combustible liquid and is not regulated, via surface transportation, in containers less than 119 gallons or 450 liters [per 49 CFR 173.150 (f)] [per Transportation of Dangerous Goods Regulations/Clear Language Part 1.33]. ICAO/IATA UN1210, Printing Ink, 3, Ill IMDG/IMO UN1210, Printing Ink, 3, III is REGs,U ttriOORMATIC International Inventories Listed on TSCA. For further information, please contact: Manufacturer, importer, supplier U.S. Federal Regulations SARA 313 The following components are subject to r Component CAS -No Weight % SARA 313 - Threshold Values Ethyl benzene (contaminant) 100-41-4 < 1 0.1 Xylenes (o-, m-, p- isomers) 1330-20-7 1 - 5 1.0 Naphthalene (contaminant) 91-20-3 1 - 5 0.1 1,2,4-Trimethylbenzene (contaminant) 95-63-6 1 - 5 1.0 Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) Component CAS -No Weight % Xylenes (o-, m-, p- isomers) 1330-20-7 1 - 5 Naphthalene (contaminant) 91-20-3 1 - 5 U.S. State Regulations Component Massachusetts Right To Know Minnesota Right To Know New Jersey Right To Know Pennsylvania Right To Know Copper Phthalocyanine Compound Not Listed Not Listed X X Naphthalene (contaminant) X X X X Xylenes (o-, m-, p- isomers) X X X X 1,2,4-Trimethylbenzene (contaminant) X X X X Titanium dioxide X X X X Ethyl benzene (contaminant) X X X X Cumene (contaminant) X X X X California Prop. 65 WARNING! This product contains a chemical known in the State of California to cause cancer and / or WARNING! This product contains a chemical known in the State of California to cause birth defects or other reproductive harm Component CAS -No Weight % Ethyl benzene (contaminant) 100-41-4 • < 1 Titanium dioxide 13463-67-7 1 - 5 Naphthalene (contaminant) 91-20-3 1 - 5 Cumene (contaminant) 98-82-8 < 0.5 Canada This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the information required by the CPR Component WHMIS Classifications of Components Petroleum naphtha, light aromatic B3,D2B Page 6/7 Product code PA43 - Royal Blue Revision Date Oct -24-2012 Naphthalene (contaminant) B4,D2A Xylenes (o-, m-, p- isomers) B2,D2A,D2B 1,2,4-Trimethylbenzene (contaminant) B3 Titanium dioxide D2A Ethyl benzene (contaminant) B2,D2A,D2B Cumene (contaminant) B2,D2A Component NPRI - National Pollutant Release Inventory Naphtha (petroleum), heavy aromatic Part 5 Substance Part 5, Other Groups and Mixtures Copper Phthalocyanine Compound Part 1, Group 1 Substance Petroleum naphtha, light aromatic Part 5 Substance Part 5, Other Groups and Mixtures Naphthalene (contaminant) Part 1, Group 1 Substance Xylenes (o-, m-, p- isomers) Part 1, Group 1 Substance Part 5 Substance Part 5, Isomer Groups 1,2,4-Trimethylbenzene (contaminant) Part 4 Substance Part 1, Group 1 Substance Part 5, Individual Substance Ethyl benzene (contaminant) -- Part 4 Substance Part 1, Group 1 Substance Cumene (contaminant) Part 4 Substance Part 1, Group 1 Substance Regulation (EC) No. 1907/2006 (REACH), Article 57 This product does not contain substances of very high concern (Regulation (EC) No. 1907/2006 (REACH), Article 57) HMIS: Health 2* Flammability 2 Reactivity 0 PPE X ;+O' ERIN ..Oftf IlA'T101 Revision Date Revision Note Oct -24-2012 New MSDS format Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text End of MSDS Page 7/7 is Ink Technologies Material Safety Data Sheet Prepared in accordance with ISO 11014-1/ANSI standard Z400.1-2004 Print Date Oct -24-2012 Revision Date Oct -24-2012 7 cPRODP.Ar„ C;*4"1:111VY ICEIdT1FFtC TtO„N' Product code Product name Product category Manufacturer or supplier's details UNITED STATES Nazdar Company 8501 Hedge Lane Terrace Shawnee, KS 66227 Tel: 1-913-422-1888 Tel: 1-800-677-4657 Fax: 1-913-422-2294 PA52 Bright Red PA Series Poly -All Screen Ink UNITED KINGDOM Nazdar Limited Barton Road Heaton Mersey Stockport, England SK4 3EG Tel: +44 161 442 2111 Emergency Telephone Number USA: Chemtrec: 1-800-424-9300 Outside USA: Chemtrec: 1-703-527-3887 Website: www.nazdar.com MSDS Information: 1-913-422-1888 ext 2305 MSDS Contact: Regulatory Compliance email: regcomp@nazdar.com This product is a preparation. Health hazard information is based on its components. Appearance Flammable Properties Emergency Overview Eyes Skin Inhalation Ingestion Colored liquid Combustible liquid and vapor. Aspiration hazard. Harmful: may cause lung damage if swallowed. Irritant. May cause drowsiness and dizziness. Causes eye irritation. May cause skin irritation and/or dermatitis. May cause irritation of respiratory tract. Inhalation of high vapour concentrations may cause symptoms like headache, dizziness, tiredness, nausea and vomiting. Harmful if swallowed. Potential for aspiration if swallowed. Risk of serious damage to the lungs (by aspiration). OIIAPOSITION/l NFORMATtONON ,INGREDIENTS; Component CAS -No Weight % Naphtha (petroleum), heavy aromatic 64742-94-5 30 - 60 Petroleum naphtha, light aromatic 64742-95-6 5 - 10 Xylenes (o-, m-, p- isomers) 1330-20-7 1 - 5 Naphthalene (contaminant) 91-20-3 1 - 5 1,2,4-Trimethylbenzene (contaminant) 95-63-6 1 - 5 Titanium dioxide 13463-67-7 1 - 5 Ethyl benzene (contaminant) 100-41-4 < 1 Cumene (contaminant) 98-82-8 < 0.5 • Component names which have the word (contaminant) are constituents contained in Aromatic Hydrocarbon ingredients and are an integral part of the ingredient and cannot be separated. The percentage listed for the contaminant is as contained in the Hydrocarbon ingredient. (Example: 100% Hydrocarbon, 10% Contaminant A, 3% Contaminant B) Eye Contact Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get medical attention immediately if irritation develops and persists. RECEIVED CITY OF TUKWILA JUL 12 2013 Page 1 l7 PERMIT CENTER Product code PA52 - Bright Red ti Revision Date Oct -24-2012 Skin Contact Inhalation Ingestion Wash off immediately with soap and plenty of water. Use a mild soap if available. Rinse immediately with plenty of water for at least 15 minutes. Remove contaminated clothing. If irritation develops, get medical attention. If breathed in, move person into fresh air. If breathing is irregular or stopped, administer artificial respiration. Get medical attention immediately. If swallowed, DO NOT induce vomiting. Call a physician or Poison Control Centre immediately. Never give anything by mouth to an unconscious person. iFIRE�`FI ' i & MEAS,URES';` i' • s: Flammable Properties Combustible liquid and vapor. Suitable Extinguishing Media Foam. Carbon dioxide (CO2). Dry chemical. Water spray. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure -demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Keep away from fire, sparks and heated surfaces. Cool containers / tanks with water spray. Fire or intense heat may cause violent rupture of packages. Specific Hazards Arising from the Thermal decomposition can lead to release of irritating gases and vapours. Burning produces obnoxious and toxic fumes. Chemical iti471.r ,r�;. ;#alr 3°'"*yrs A,F•.,..«�j�..E`ASEMI ��6x,�A��D,�EN;TA Personal Precautions Methods for Cleaning Up Environmental Precautions Remove all sources of ignition. Ventilate the area. Avoid breathing dust or vapor. Avoid contact with skin, eyes and clothing. Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13). Do not use sparking tools. Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. j<6 Tg§'>"� .{�' '• r a. �°"'hY'..,'q. sil �k J'• l:{n the�yy��. nF: t'S'. L �ritjn"}jrY"�4ifj� Handling Storage Avoid contact with skin, eyes and clothing. Ensure adequate ventilation. Remove and wash contaminated clothing before re -use. Discard contaminated shoes. When using do not smoke. Do not take internally. Harmful or fatal if swallowed. Take notice of the directions of use on the label. Keep containers tightly closed in a dry, cool and well -ventilated place. Keep container closed when not in use. Keep out of the reach of children. Keep away from heat and sources of ignition. EXPOSORE.CONTROLS/PERSONALEP,ROTECTIOI! Exposure Guidelines Component ACGIH TLV OSHA PEL I NIOSH IDLH I Ontario TWAEV I Mexico OEL (TWA) . • Page 2/7 1 I Product code PA52 - Bright Red Revision Date Oct -24-2012 Xylenes (o-, m-, p- isomers) TWA: 100 ppm STEL: 150 ppm TWA: 100 ppm TWA: 435 mg/m3 STEL: 150 ppm STEL: 655 mg/m3 TWA: 100 ppm STEL: 150 ppm TWA/LMPE-PPT: 100 ppm TWA/LMPE-PPT: 435 mg/m3 STEULMPE-CT: 150 ppm STEULMPE-CT: 655 mg/m3 Naphthalene (contaminant) TWA: 10 ppm STEL: 15 ppm Skin TWA: 10 ppm TWA: 50 mg/m3 STEL: 15 ppmSkin STEL: 75 mg/m3 250 ppm TWA: 10 ppm STEL: 15 ppm TWA/LMPE-PPT: 10 ppm TWA/LMPE-PPT: 50 mg/m3 STEULMPE-CT: 15 ppm STEULMPE-CT: 75 mg/m3 Titanium dioxide TWA: 10 mg/m3 TWA: 10 mg/m3 (total dust) TWA: 15 mg/m3 (total dust) 5000 mg/m3 TWA: 10 mg/m3 (total dust) TWA/LMPE-PPT: 10 mg/m3 (as Ti) STEULMPE-CT: 20 mg/m3 (as T1) Ethyl benzene (contaminant) TWA: 20 ppm TWA: 100 ppm TWA: 435 mg/m3 STEL: 125 ppm STEL: 545 mg/m3 800 ppm (10% LEL) TWA: 100 ppm STEL: 125 ppm TWA/LMPE-PPT: 100 ppm TWA/LMPE-PPT: 435 mg/m3 STEULMPE-CT: 125 ppm STEULMPE-CT: 545 mg/m3 Cumene (contaminant) TWA: 50 ppm TWA: 50 ppm TWA: 245 mg/m3 - Skin 900 ppm (10% LEL) TWA: 50 ppm TWA/LMPE-PPT: 50 ppm TWA/LMPE-PPT: 245 mg/m3 STEULMPE-CT: 75 ppm STEULMPE-CT: 365 mg/m3 Engineering Measures Personal Protective Equipment Respiratory Protection Eye Protection Skin Protection General Hygiene Considerations Use ventilation adequate to keep exposures below recommended exposure limits. See MSDS. In case of insufficient ventilation, wear suitable respiratory equipment. Use the indicated respiratory protection if the occupational exposure limit is exceeded and/or in case of product release (dust). Respirator with a vapour filter. Ensure that eyewash stations and safety showers are close to the workstation location. Avoid contact with eyes. Safety glasses with side -shields. Goggles. Face -shield. Wear protective gloves/clothing. Solvent -resistant apron and boots. Handle in accordance with good industrial hygiene and safety practice. Wash hands before eating, drinking, or smoking. Remove and wash contaminated clothing before re -use. Avoid contact with skin, eyes and clothing. Wear suitable gloves and eye/face protection. Regular cleaning of equipment, work area and clothing is recommended. ,gra Appearance Odor pH Boiling point/Boiling Range Freezing Point/Range Evaporation Rate Vapour Pressure Flammability (solid, gas) Colored liquid Characteristic No information available >149 °C / >300 °F No information available No information available No information available No information available Flash Point 49 °C / 120 °F Method Setaflash closed cup Physical State Odor Threshold Autoignition Temperature Melting Point/Range Solubility Partition Coefficient (n-octanol/water) Vapour Density Liquid No information available No information available No information available No information available No information available Heavier than air Flammability Limits in Air Upper No information available Lower No information available Photochemically Reactive Yes Page 3/7 Product code PA52 - Bright Red Revision Date Oct -24-2012 Weight Per Gallon (lbs/gal) 8.42 VOC by weight % (less water) 53.3 VOC lbs/gal (less water) 4.49 Specific Gravity 1.01 VOC by volume % (less water) 55.8 VOC grams/liter (less water) 538.06 s �tz1 t 41 , l BiLITY �g REACTI) ,Jt Chemical Stability Conditions to Avoid Incompatible Products Stable under normal conditions. Heat, flames and sparks. Strong acids. Strong bases. Strong oxidizing agents. Reducing agents. Hazardous Decomposition Products Thermal decomposition can lead to release of irritating gases and vapours. Carbon dioxide (CO2). Carbon monoxide. Possibility of Hazardous Reactions None under normal processing. GOLOGIGAL'INFORMATI• i av; • Acute Toxicity Component LD50 Oral LD50 Dermal LC50 Inhalation Naphtha (petroleum), heavy aromatic >5000 mg/kg ( Rat) >2000 mg/kg ( Rabbit) >590 mg/m3 ( Rat) 4 h Petroleum naphtha, light aromatic 8400 mg/kg ( Rat) >2000 mg/kg ( Rabbit) 3400 ppm ( Rat) 4 h >5.2 mg/L (Rat) 4h Xylenes (o-, m-, p- isomers) 4300 mg/kg ( Rat) >1700 mg/kg ( Rabbit) 5000 ppm ( Rat) 4 h 47635 mg/L ( Rat) 4 h Naphthalene (contaminant) 490 mg/kg ( Rat) >2500 mg/kg ( Rat) >20 g/kg ( Rabbit ) >340 mg/m3 ( Rat) 1 h 1,2,4-Trimethylbenzene (contaminant) 3400 mg/kg ( Rat) >3160 mg/kg ( Rabbit) 18 g/m3 ( Rat) 4 h Titanium dioxide >10000 mg/kg ( Rat ) Ethyl benzene (contaminant) 3500 mg/kg ( Rat) 15354 mg/kg ( Rabbit) 17.2 mg/L ( Rat) 4 h Cumene (contaminant) 1400 mg/kg ( Rat) >3160 mg/kg ( Rabbit) 39000 mg/m3 ( Rat) 4 h Chronic Toxicity Component ACGIH IARC NTP OSHA Naphthalene (contaminant) Group 2B Reasonably Anticipated X Titanium dioxide Group 2B X Ethyl benzene (contaminant) A3 Group 2B X Cumene (contaminant) Group 2B X ACGIH: (American Conference of Governmental industrial Hygienists) IARC: (International Agency for Research on Cancer) NTP: (National Toxicity Program) OSHA: (Occupational Safety & Health Administration) Sensitisation Mutagenic Effects Reproductive Effects Developmental hazard Teratogenicity Chronic Effects Target Organ Effects A3 - Animal Carcinogen Group 2B - Possibly Carcinogenic to Humans Reasonably Anticipated to be a Human Carcinogen X - Present No information available No information available No information available No information available No information available Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may result in adverse health effect, such as mucous membrane and respiratory system irritation and adverse effect on kidney, liver and central nervous system. Blood, Central nervous system, Eyes, Kidney, Liver, Respiratory system, Skin. Page 4 / 7 Product code PA52 - Bright Red Revision Date Oct -24-2012 2ECiittoC 420 001MrATI Ecotoxicity We have no quantitative data concerning the ecological effects of this product. Should not be released into the environment. Component Algae Fish Water Flea Petroleum naphtha, light aromatic 2.96 96h LC50 Oncorhynchus mykiss: 9.22 mg/L 3.3 Naphthalene (contaminant) 72h EC50 Skeletonema costatum: 0.4 mg/L 96h LC50 Oncorhynchus mykiss: 0.91 - 2.82 mg/L [static] 96h LC50 Pimephales promelas: 5.74 - 6.44 mg/L [flow-through] 96h LC50 Oncorhynchus mykiss: 1.6 mg/L [flow-through] 96h LC50 Pimephales promelas: 1.99 mg/L [static] 96h LC50 Lepomis macrochirus: 31.0265 mg/L [static] 48h EC50 Daphnia magna: 1.09 - 3.4 mg/L [static] 48h EC50 Daphnia magna: 1.96 mg/L [Flow through] 48h LC50 Daphnia magna: 2.16 mg/L 1,2,4-Trimethylbenzene (contaminant) 3.55 96h LC50 Pimephales promelas: 7.19 - 8.28 mg/L [flow-through] 48h EC50 Daphnia magna: 6.14 mg/L Ethyl benzene (contaminant) 96h EC50 Pseudokirchneriella subcapitata: 1.7 - 7.6 mg/L [static] 72h EC50 Pseudokirchneriella subcapitata: 2.6 - 11.3 mg/L [static] 72h EC50 Pseudokirchneriella subcapitata: 4.6 mg/L 96h EC50 Pseudokirchneriella subcapitata: >438 mg/L 96h LC50 Oncorhynchus mykiss: 11.0 - 18.0 mg/L [static] 96h LC50 Pimephales promelas: 7.55 - 11 mg/L [flow-through] 96h LC50 Pimephales promelas: 9.1 - 15.6 mg/L [static] 96h LC50 Lepomis macrochirus: 32 mg/L [static] 96h LC50 Oncorhynchus mykiss: 4.2 mg/L [semi -static] 96h LC50 Poecilia reticulata: 9.6 mg/L [static] 48h EC50 Daphnia magna: 1.8 - 2.4 mg/L Cumene (contaminant) 72h EC50 Pseudokirchneriella subcapitata: 2.6 mg/L 96h LC50 Pimephales promelas: 6.04 - 6.61 mg/L [flow-through] 96h LC50 Oncorhynchus mykiss: 2.7 mg/L [semi -static] 96h LC50 Oncorhynchus mykiss: 4.8 mg/L [flow-through] 96h LC50 Poecilia reticulata: 5.1 mg/L [semi -static] 48h EC50 Daphnia magna: 7.9 - 14.1 mg/L [static] 48h EC50 Daphnia magna: 0.6 mg/L Persistence and Degradability No information available Bioaccumulation No information available Mobility in Environmental Media No information available Component log Pow Naphtha (petroleum), heavy aromatic 4.5 Xylenes (o-, m-, p- isomers) 2.96 Naphthalene (contaminant) 3.3 1,2,4-Trimethylbenzene (contaminant) 3.63 Ethyl benzene (contaminant) 3.118 Cumene (contaminant) 3.55 13 YDISP,�O �'.. r•' iHiw�-a:{Ner IN Da "ate OMSIDERA;'TIO.NS Waste Disposal Methods Contaminated Packaging Dispose of contents/container in accordance with local regulation. Empty containers should be taken to an approved waste handling site for recycling or disposal. :.TRANSPORT INEORNIATIO } Page 5/7 Product code PA52 - Bright Red Revision Date Oct -24-2012 DOT UN1210, Printing Ink, 3, III In the U.S. and Canada, this material may be reclassified as a combustible liquid and is not regulated, via surface transportation, in containers less than 119 gallons or 450 liters [per 49 CFR 173.150 (f)] [per Transportation of Dangerous Goods Regulations/Clear Language Part 1.33]. ICAO/IATA UN1210, Printing Ink, 3, III IMDG/IMO UN1210, Printing Ink, 3, III Ri:0,04A toRY`INFoRPAAT10I International Inventories Listed on TSCA. For further information, please contact: Manufacturer, importer, supplier U.S. Federal Regulations SARA 313 The following components are subject to reporting levels establish Component CAS -No Weight % SARA 313 - Threshold Values Ethyl benzene (contaminant) 100-41-4 < 1 0.1 Xylenes (o-, m-, p- isomers) 1330-20-7 1 - 5 1.0 Naphthalene (contaminant) 91-20-3 1 - 5 0.1 1,2,4-Trimethylbenzene (contaminant) 95-63-6 1 - 5 1.0 Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) Component CAS -No Weight % Xylenes (o-, m-, p- isomers) 1330-20-7 1 - 5 Naphthalene (contaminant) 91-20-3 1 - 5 U.S. State Regulations Component Massachusetts Right To Know Minnesota Right To Know New Jersey Right To Know Pennsylvania Right To Know Xylenes (o-, m-, p- isomers) X X X X Naphthalene (contaminant) X X X X 1,2,4-Trimethylbenzene (contaminant) X X X X Titanium dioxide X X X X Ethyl benzene (contaminant) X X X X Cumene (contaminant) X X X X California Prop. 65 WARNING! This product contains a chemical known in the State of California to cause cancer and / or WARNING! This product contains a chemical known in the State of California to cause birth defects or other reproductive harm Component CAS -No Weight % Ethyl benzene (contaminant) 100-41-4 < 1 Titanium dioxide 13463-67-7 1 - 5 Naphthalene (contaminant) 91-20-3 1 - 5 Cumene (contaminant) 98-82-8 < 0.5 Canada This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the information required by the CPR Component WHMIS Classifications of Components Petroleum naphtha, light aromatic B3,D2B Xylenes (o-, m-, p- isomers) B2,D2A,D2B Page 617 Product code PA52 - Bright Red Revision Date Oct -24-2012 Naphthalene (contaminant) B4,D2A 1,2,4-Trimethylbenzene (contaminant) B3 Titanium dioxide D2A Ethyl benzene (contaminant) B2,D2A,D2B Cumene (contaminant) B2,D2A Component NPRI - National Pollutant Release Inventory Naphtha (petroleum), heavy aromatic Part 5 Substance Part 5, Other Groups and Mixtures Petroleum naphtha, light aromatic Part 5 Substance Part 5, Other Groups and Mixtures Xylenes (o-, m-, p- isomers) Part 1, Group 1 Substance Part 5 Substance Part 5, Isomer Groups Naphthalene (contaminant) Part 1, Group 1 Substance 1,2,4-Trimethylbenzene (contaminant) Part 4 Substance Part 1, Group 1 Substance Part 5, Individual Substance Ethyl benzene (contaminant) Part 4 Substance Part 1, Group 1 Substance Cumene (contaminant) Part 4 Substance Part 1, Group 1 Substance Regulation (EC) No. 1907/2006 (REACH), Article 57 This product does not contain substances of very high concern (Regulation (EC) No. 1907/2006 (REACH), Article 57) HMIS: Health 2* Revision Date Revision Note Oct -24-2012 Flammability 2 Reactivity 0 HEl1:'4•_ �RIU�AT10,�'dti ;,� New MSDS format PPE X Disclaimer The information provided in this Safety Data Sheet Is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text End of MSDS Page 7 /7 Ink ?technologies Material Safety Data Sheet Prepared in accordance with ISO 11014-1/ANSI standard Z400.1-2004 Print Date Oct -24-2012 iy Revision Date Oct -24-2012 tir wry its “4,-,16,, :PRO D;;COM1.1A-MTAYAN,TIFICAT�N � s Product code Product name Product category Manufacturer or supplier's details UNITED STATES Nazdar Company 8501 Hedge Lane Terrace Shawnee, KS 66227 Tel: 1-913-422-1888 Tel: 1-800-677-4657 Fax: 1-913-422-2294 F .` PA70 Black PA Series Poly -All Screen Ink UNITED KINGDOM Nazdar Limited Barton Road Heaton Mersey Stockport, England SK4 3EG Tel: +44 161 442 2111 Emergency Telephone Number USA: Chemtrec: 1-800-424-9300 Outside USA: Chemtrec: 1-703-527-3887 Website: www.nazdar.com MSDS Information: 1-913-422-1888 ext 2305 MSDS Contact: Regulatory Compliance email: regcomp@nazdar.com This product is a preparation. Health hazard information is based on its components. ..� AZAlitii IDEMTIFICATION;-, Appearance Flammable Properties Emergency Overview Eyes Skin Inhalation Ingestion 9 Colored liquid Combustible liquid and vapor. Aspiration hazard. Harmful: may cause lung damage if swallowed. Irritant. May cause drowsiness and dizziness. Causes eye irritation. May cause skin irritation and/or dermatitis. May cause irritation of respiratory tract. Inhalation of high vapour concentrations may cause symptoms like headache, dizziness, tiredness, nausea and vomiting. Harmful if swallowed. Potential for aspiration if swallowed. Risk of serious damage to the lungs (by aspiration). OMPOSITION/INFORMATIONi`INGREDIEN'• Component CAS -No Weight % Naphtha (petroleum), heavy aromatic 64742-94-5 30 - 60 Petroleum naphtha, light aromatic 64742-95-6 5 - 10 Carbon black 1333-86-4 5 - 10 Naphthalene (contaminant) 91-20-3 1 - 5 Xylenes (o-, m-, p- isomers) 1330-20-7 1 - 5 1,2,4-Trimethylbenzene (contaminant) 95-63-6 1 - 5 Ethyl benzene (contaminant) 100-41-4 < 1 Cumene (contaminant) 98-82-8 < 0.5 • Component names which have the word (contaminant) are constituents contained in Aromatic Hydrocarbon ingredients and are an integral part of the ingredient and cannot be separated. The percentage listed for the contaminant is as contained in the Hydrocarbon ingredient. (Example: 100% Hydrocarbon, 10% Contaminant A, 3% Contaminant B) Eye Contact D1' St/KtSe �$ Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get medical attention immediately if irritation develops and persists. RECEIVED CITY OF TUKWILA JUL 1 2 2013 bk.Z3ti Page 1 / 7 PERMIT CENTER Product code PA70 - Black Revision Date Oct -24-2012 Skin Contact Inhalation Ingestion Wash off immediately with soap and plenty of water. Use a mild soap if available. Rinse immediately with plenty of water for at least 15 minutes. Remove contaminated clothing. If irritation develops, get medical attention. If breathed in, move person into fresh air. If breathing is irregular or stopped, administer artificial respiration. Get medical attention immediately. If swallowed, DO NOT induce vomiting. Call a physician or Poison Control Centre immediately. Never give anything by mouth to an unconscious person. S FIREFIGHTING FMEAS�I'JRES wew Flammable Properties Suitable Extinguishing Media Protective Equipment and Precautions for Firefighters Specific Hazards Arising from the Chemical Combustible liquid and vapor. Foam. Carbon dioxide (CO2). Dry chemical. Water spray. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. As in any fire, wear self-contained breathing apparatus pressure -demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Keep away from fire, sparks and heated surfaces. Cool containers / tanks with water spray. Fire or intense heat may cause violent rupture of packages. Thermal decomposition can lead to release of irritating gases and vapours. Burning produces obnoxious and toxic fumes. . ,;��:. �ni.r✓ rw+: sic.+.�v q * .r� � s..0 .;.a,..� y�:.:�rw:.�x.>��.w,a.a ACC�IDE0:itx s t:.4. E EA3.URES Personal Precautions Methods for Cleaning Up Environmental Precautions Remove all sources of ignition. Ventilate the area. Avoid breathing dust or vapor. Avoid contact with skin, eyes and clothing. Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13). Do not use sparking tools. Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. 7Y`�HANDLINGn%1, Handling Storage Avoid contact with skin, eyes and clothing. Ensure adequate ventilation. Remove and wash contaminated clothing before re -use. Discard contaminated shoes. When using do not smoke. Do not take internally. Harmful or fatal if swallowed. Take notice of the directions of use on the label. Keep containers tightly closed in a dry, cool and well -ventilated place. Keep container closed when not in use. Keep out of the reach of children. Keep away from heat and sources of ignition. FOSURE! CONTROLS/PERSONALltPROTECTIO Exposure Guidelines Component ACGIH TLV OSHA PEL NIOSH IDLH Ontario TWAEV Mexico OEL (TWA) Carbon black TWA: 3 mg/m3 (inhalable fraction) TWA: 3.5 mg/m3 _ 1750 mg/m3 �.., TWA: 3.5 mg/m3 R • TWA/LMPE-PPT: 3.5 mg/m3 STEL/LMPE-CT: 7 mg/m3 • ors— Page 2/7 Product code PA70 - Black Revision Date Oct -24-2012 Naphthalene (contaminant) TWA: 10 ppm STEL: 15 ppm Skin TWA: 10 ppm TWA: 50 mg/m3 STEL: 15 ppm STEL: 75 mg/m3 250 ppm TWA: 10 ppm STEL: 15 ppm Skin TWA/LMPE-PPT: 10 ppm TWA/LMPE-PPT: 50 mg/m3 STEULMPE-CT: 15 ppm STEULMPE-CT: 75 mg/m3 Xylenes(o-, m-, y p- isomers) TWA: 100 ppm STEL: 150 ppm TWA: 100 ppm TWA: 435 mg/m3 STEL: 150 ppm STEL: 655 mg/m3 TWA: 100 ppm STEL: 150 ppm TWA/LMPE-PPT: 100 ppm TWA/LMPE-PPT: 435 mg/m3 STEULMPE-CT: 150 ppm STEULMPE-CT: 655 mg/m3 Ethyl benzene (contaminant) TWA: 20 ppm TWA: 100 ppm TWA: 435 mg/m3 STEL: 125 ppm STEL: 545 mg/m3 800 ppm (10% LEL) TWA: 100 ppm STEL: 125 ppm TWA/LMPE-PPT: 100 ppm TWA/LMPE-PPT: 435 mg/m3 STEULMPE-CT: 125 ppm STEULMPE-CT: 545 mg/m3 Cumene (contaminant) TWA: 50 ppm TWA: 50 ppm TWA: 245 mg/m3 Skin 900 ppm (10% LEL) TWA: 50 ppm TWA/LMPE-PPT: 50 ppm TWA/LMPE-PPT: 245 mg/m3 STEL/LMPE-CT: 75 ppm STEULMPE-CT: 365 mg/m3 Engineering Measures Personal Protective Equipment Respiratory Protection Eye Protection Skin Protection General Hygiene Considerations Use ventilation adequate to keep exposures below recommended exposure limits. See MSDS. In case of insufficient ventilation, wear suitable respiratory equipment. Use the indicated respiratory protection if the occupational exposure limit is exceeded and/or in case of product release (dust). Respirator with a vapour filter. Ensure that eyewash stations and safety showers are close to the workstation location. Avoid contact with eyes. Safety glasses with side -shields. Goggles. Face -shield. Wear protective gloves/clothing. Solvent -resistant apron and boots. Handle in accordance with good industrial hygiene and safety practice. Wash hands before eating, drinking, or smoking. Remove and wash contaminated clothing before re -use. Avoid contact with skin, eyes and clothing. Wear suitable gloves and eye/face protection. Regular cleaning of equipment, work area and clothing is recommended. �� t �,9#PHYSICAL ,4 CHEMICAL iPROPERTI pax Appearance Odor pH Boiling point/Boiling Range Freezing Point/Range Evaporation Rate Vapour Pressure Flammability (solid, gas) Colored liquid Characteristic No information available >149 °C / >300 °F No information available No information available No information available No information available Flash Point 49 °C / 120 °F Method Setaflash closed cup Weight Per Gallon (lbs/gal) 8.32 VOC by weight % (less water) 57.4 VOC lbs/gal (less water) 4.78 Physical State Odor Threshold Autoignition Temperature Melting Point/Range Solubility Partition Coefficient (n-octanol/water) Vapour Density Liquid No information available No information available No information available No information available No information available Heavier than air Flammability Limits in Air Upper No information available Lower No information available Photochemically Reactive Yes Specific Gravity 1 VOC by volume % (less water)59.72 VOC grams/liter (less water) 572.98 Page 3/7 Product code PA70 - Black Revision Date Oct -24-2012 Chemical Stability Conditions to Avoid Incompatible Products Stable under normal conditions. Heat, flames and sparks. Strong acids. Strong bases. Strong oxidizing agents. Reducing agents. Hazardous Decomposition Products Thermal decomposition can lead to release of irritating gases and vapours. Carbon dioxide (CO2). Carbon monoxide. Possibility of Hazardous Reactions None under normal processing. 1)4 T XICOL;OGIC` LIINFORM,TI Acute Toxicity Component LD50 Oral LD50 Dermal LC50 Inhalation Naphtha (petroleum), heavy aromatic >5000 mg/kg ( Rat) >2000 mg/kg ( Rabbit) >590 mg/m3 ( Rat) 4 h Petroleum naphtha, light aromatic 8400 mg/kg ( Rat) >2000 mg/kg ( Rabbit) 3400 ppm ( Rat) 4 h >5.2 mg/L (Rat) 4h Carbon black >15400 mg/kg ( Rat) >3 g/kg ( Rabbit ) Ethyl benzene (contaminant) Naphthalene (contaminant) 490 mg/kg ( Rat) >2500 mg/kg ( Rat) >20 g/kg ( Rabbit ) >340 mg/m3 ( Rat) 1 h Xylenes (o-, m-, p- isomers) 4300 mg/kg ( Rat) >1700 mg/kg ( Rabbit) 5000 ppm ( Rat) 4 h 47635 mg/L ( Rat) 4 h 1,2,4-Trimethylbenzene (contaminant) 3400 mg/kg ( Rat) >3160 mg/kg ( Rabbit) 18 g/m3 ( Rat) 4 h Ethyl benzene (contaminant) 3500 mg/kg ( Rat) 15354 mg/kg ( Rabbit) 17.2 mg/L (Rat) 4 h Cumene (contaminant) 1400 mg/kg f Rat) >3160 mg/kg ( Rabbit) 39000 mg/m3 ( Rat) 4 h Chronic Toxicity Component ACGIH IARC NTP OSHA Carbon black A3 Group 2B X Naphthalene (contaminant) Group 2B Reasonably Anticipated X Ethyl benzene (contaminant) A3 Group 26 X Cumene (contaminant) Group 2B X Carbon black is classified as a carcinogen by the IARC (possibly carcinogenic to humans, Group 2B). In their evaluation of carbon black, IARC indicates exposure to carbon black, per se, does not occur when it remains bound within a product matrix, specifically, rubber, ink, or paint. Carbon black is present only in a bound form in this preparation. ACGIH: (American Conference of Governmental Industrial Hygienists) IARC: (International Agency for Research on Cancer) NTP: (National Toxicity Program) OSHA: (Occupational Safety & Health Administration) Sensitisation Mutagenic Effects Reproductive Effects Developmental hazard Teratogenicity Chronic Effects Target Organ Effects A3 - Animal Carcinogen Group 2B - Possibly Carcinogenic to Humans Reasonably Anticipated to be a Human Carcinogen X - Present No information available No information available No information available No information available No information available Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may result in adverse health effect, such as mucous membrane and respiratory system irritation and adverse effect on kidney, liver and central nervous system. Blood, Central nervous system, Eyes, Kidney, Liver, Respiratory system, Skin. Page 417 Product code PA70 - Black Revision Date Oct -24-2012 c jcr�l[.T.i - L'OGICAL>INFORM'A IONir'^% nes- Ecotoxicity We have no quantitative data concerning the ecological effects of this product. Should not be released into the environment. Component Algae Fish Water Flea Petroleum naphtha, light aromatic 3.3 96h LC50 Oncorhynchus mykiss: 9.22 mg/L 2.96 Carbon black 3.63 Ethyl benzene (contaminant) 24h EC50 Daphnia magna: >5600 mg/L Naphthalene (contaminant) 72h EC50 Skeletonema costatum: 0.4 mg/L 96h LC50 Oncorhynchus mykiss: 0.91 - 2.82 mg/L [static] 96h LC50 Pimephales promelas: 5.74 - 6.44 mg/L [flow-through] 96h LC50 Oncorhynchus mykiss: 1.6 mg/L [flow-through] 96h LC50 Pimephales promelas: 1.99 mg/L [static] 96h LC50 Lepomis macrochirus: 31.0265 mg/L [static] 48h EC50 Daphnia magna: 1.09 - 3.4 mg/L [static] 48h EC50 Daphnia magna: 1.96 mg/L [Flow through] 48h LC50 Daphnia magna: 2.16 mg/L 1,2,4-Trimethylbenzene (contaminant) 96h LC50 Pimephales promelas: 7.19 - 8.28 mg/L [flow-through] 48h EC50 Daphnia magna: 6.14 mg/L ' Ethyl benzene (contaminant) 96h EC50 Pseudokirchneriella subcapitata: 1.7 - 7.6 mg/L [static] 72h EC50 Pseudokirchneriella subcapitata: 2.6 - 11.3 mg/L [static] 72h EC50 Pseudokirchneriella subcapitata: 4.6 mg/L 96h EC50 Pseudokirchneriella subcapitata: >438 mg/L 96h LC50 Oncorhynchus mykiss: 11.0 - 18.0 mg/L [static] 96h LC50 Pimephales promelas: 7.55 - 11 mg/L [flow-through] 96h LC50 Pimephales promelas: 9.1 - 15.6 mg/L [static] 96h LC50 Lepomis macrochirus: 32 mg/L [static] 96h LC50 Oncorhynchus mykiss: 4.2 mg/L [semi -static] 96h LC50 Poecilia reticulata: 9.6 mg/L [static] 48h EC50 Daphnia magna: 1.8 - 2.4 mg/L Cumene (contaminant) 72h EC50 Pseudokirchneriella subcapitata: 2.6 mg/L 96h LC50 Pimephales promelas: 6.04 - 6.61 mg/L [flow-through] 96h LC50 Oncorhynchus mykiss: 2.7 mg/L [semi -static] 96h LC50 Oncorhynchus mykiss: 4.8 mg/L [flow-through] 96h LC50 Poecilia reticulata: 5.1 mg/L [semi -static] 48h EC50 Daphnia magna: 7.9 - 14.1 mg/L [static] 48h EC50 Daphnia magna: 0.6 mg/L Persistence and Degradability No information available Bioaccumulation No information available Mobility in Environmental Media No information available Component log Pow Naphtha (petroleum), heavy aromatic 4.5 Naphthalene (contaminant) 3.3 Xylenes (o-, m-, p- isomers) 2.96 1,2,4-Trimethylbenzene (contaminant) 3.63 Ethyl benzene (contaminant) 3.118 Cumene (contaminant) 3.55 RATIAN Waste Disposal Methods Contaminated Packaging Dispose of contents/container in accordance with local regulation. Empty containers should be taken to an approved waste handling site for recycling or disposal. 4N0O* INFORMATII • Page 5/7 Product code PA70 - Black Revision Date Oct -24-2012 DOT UN1210, Printing Ink, 3, III In the U.S. and Canada, this material may be reclassified as a combustible liquid and is not regulated, via surface transportation, in containers less than 119 gallons or 450 liters [per 49 CFR 173.150 (f)] [per Transportation of Dangerous Goods Regulations/Clear Language Part 1.33]. ICAO/IATA UN1210, Printing Ink, 3, III IMDG/IMO UN1210, Printing Ink, 3, III EUI:i ht F QR.M4T!C International Inventories Listed on TSCA. For further information, please contact: Manufacturer, importer, supplier U.S. Federal Regulations SARA 313 The following components ar Component CAS -No Weight % SARA 313 - Threshold Values Ethyl benzene (contaminant) 100-41-4 < 1 0.1 Xylenes (o-, m-, p- isomers) 1330-20-7 1 - 5 1.0 Naphthalene (contaminant) 91-20-3 1 - 5 0.1 1,2,4-Trimethylbenzene (contaminant) 95-63-6 1 - 5 1.0 Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) Component CAS -No Weight % Xylenes (o-, m-, p- isomers) 1330-20-7 1 - 5 Naphthalene (contaminant) 91-20-3 1 - 5 U.S. State Regulations Component Massachusetts Right To Know Minnesota Right To Know New Jersey Right To Know Pennsylvania Right To Know Carbon black X X X X Naphthalene (contaminant) X X X X Xylenes (o-, m-, p- isomers) X X X X 1,2,4-Trimethylbenzene (contaminant) X X X X Ethyl benzene (contaminant) X X X X Cumene (contaminant) X X X X California Prop. 65 WARNING! This product contains a chemical known in the State of California to cause cancer and / or WARNING! This product contains a chemical known in the State of California to cause birth defects or other reproductive harm Component CAS -No Weight % Ethyl benzene (contaminant) 100-41-4 < 1 Carbon black 1333-86-4 5 - 10 Naphthalene (contaminant) 91-20-3 1 - 5 Cumene (contaminant) 98-82-8 < 0.5 Canada This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the information required by the CPR Component WHMIS Classifications of Components Petroleum naphtha, light aromatic B3,D2B Carbon black D2A Page 617 Product code PA70 - Black Revision Date Oct -24-2012 Naphthalene (contaminant) B4,D2A Xylenes (o-, m-, p- isomers) B2,D2A,D2B 1,2,4-Trimethylbenzene (contaminant) B3 Ethyl benzene (contaminant) B2,D2A,D2B Cumene (contaminant) B2,D2A Component NPRI - National Pollutant Release Inventory Naphtha (petroleum), heavy aromatic Part 5 Substance Part 5, Other Groups and Mixtures Petroleum naphtha, light aromatic Part 5 Substance Part 5, Other Groups and Mixtures Naphthalene (contaminant) Part 1, Group 1 Substance Xylenes (o-, m-, p- isomers) Part 1, Group 1 Substance Part 5 Substance Part 5, Isomer Groups 1,2,4-Trimethylbenzene (contaminant) Part 4 Substance Part 1, Group 1 Substance Part 5, Individual Substance Ethyl benzene (contaminant) Part 4 Substance Part 1, Group 1 Substance Cumene (contaminant) Part 4 Substance Part 1, Group 1 Substance Regulation (EC) No. 1907/2006 (REACH), Article 57 This product does not contain substances of very high concern (Regulation (EC) No. 1907/2006 (REACH), Article 57) HMIS: Revision Date Revision Note Health 2* Flammability 2 Oct -24-2012 New MSDS format Reactivity 0 PPE X Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text End of MSDS Page 7 / 7 9 Material Safety Data Sheet Prepared in accordance with ISO 11014-1/ANSI standard 2400.1-2004 Print Date May -02-2012 Revision Date May -02-2012 •6 Product code Product name Product category Manufacturer or supplier's details UNITED STATES Nazdar Company 8501 Hedge Lane Terrace Shawnee, KS 66227 Tel: 1-913-422-1888 Tel: 1-800-677-4657 Fax: 1-913-422-2294 's: NB80 UV Adhesion Promoter Ink Product UNITED KINGDOM Nazdar Limited 7 Barton Road Heaton Mersey Industrial Estate Stockport, Cheshire SK4 3EG Tel: +44 161 442 2111 Emergency Telephone Number USA: Chemtrec: 1-800-424-9300 Outside USA: Chemtrec: 1-703-527-3887 Website: www.nazdar.com MSDS Information: 1-913-422-1888 ext 2305 MSDS Contact: Regulatory Compliance email: regcomp@nazdar.com `,�:.: fit' -Ng....: D;S11DE_HITIEICATIO,,��{�s�� �;; This product is a preparation. Health hazard information is based on its components. Appearance Emergency Overview Eyes Skin Inhalation Ingestion ti; 6141 Water -white Irritant. Persons allergic to isocyanates, and particularly those suffering from asthma or other respiratory conditions, should not work with isocyanates. Sensitizer. Harmful. May cause eye irritation. May cause eye irritation with susceptible persons. May cause skin irritation and/or dermatitis. May be harmful in contact with skin (after often repeated exposure). May cause sensitization by skin contact. Repeated or prolonged skin contact may cause allergic reactions with susceptible persons. May cause irritation of respiratory tract. Inhalation of high vapour concentrations may cause symptoms like headache, dizziness, tiredness, nausea and vomiting. May be harmful by inhalation (after often repeated exposure). May cause allergic respiratory reaction. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. May be harmful if swallowed. May cause additional affects as listed under "Inhalation". f , frtt+6`16.6. ONIPwO`�SITIOI�/i�l�FOitIVIATI'ONkO���IN6`�RED�IE�TS `._..�fE .®,i.,.,.a....,� �.., w�m� Yt....... ai,.,..o.3.mee,,...�.....-.......s....., ..a w...ai Component CAS -No Weight % Hexamethylene diisocyanate homopolymer 28182-81-2 60 - 100 Hexamethylene diisocyanate 822-06-0 <0.5 n, 44.4 '1 .i. K'tY. iF'7fii yfhI Y.;I •':�tit7 4i riftt OkmEASURE stiR Eye Contact Skin Contact Inhalation Ingestion Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get medical attention immediately if irritation develops and persists. Wash off immediately with soap and plenty of water. Use a mild soap if available. Rinse immediately with plenty of water for at least 15 minutes. Remove contaminated clothing. If irritation develops, get medical attention. If breathed in, move person into fresh air. If breathing is irregular or stopped, administer artificial respiration. Get medical attention immediately. RECEIVED If swallowed, DO NOT induce vomiting. Call a physician or Poison Cc jvrreo f TU K W ILA immediately. Never give anything by mouth to an unconscious person. Page 1 /2. 1%, JUL 1 1 2013 PERMIT CENTER Product code NB80 - UV Adhesion Promoter Revision Date May -02-2012 us 6 IREnFIGHT1INO Flammable Properties Suitable Extinguishing Media Protective Equipment and Precautions for Firefighters Specific Hazards Arising from the Chemical No information available Foam. Carbon dioxide (CO2). Dry chemical. Water spray. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. As in any fire, wear self-contained breathing apparatus pressure -demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Keep away from fire, sparks and heated surfaces. Cool containers / tanks with water spray. Fire or intense heat may cause violent rupture of packages. Thermal decomposition can lead to release of irritating gases and vapours. Burning produces obnoxious and toxic fumes. May cause sensitization by inhalation and skin contact. ' 6 A C DI EN, RELEASE MEASURES Personal Precautions Methods for Cleaning Up Environmental Precautions Handling Storage Remove all sources of ignition. Ventilate the area. Avoid breathing dust or vapor. Avoid contact with skin, eyes and clothing. Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13). Do not use sparking tools. Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. Avoid contact with skin, eyes and clothing. Ensure adequate ventilation. Remove and wash contaminated clothing before re -use. Discard contaminated shoes. When using do not smoke. Do not take internally. Harmful or fatal if swallowed. Take notice of the directions of use on the label. Keep containers tightly closed in a dry, cool and well -ventilated place. Keep container closed when not in use. Keep out of the reach of children. Keep away from heat and sources of ignition. t• 6, vv»v *NM/. ..w mats *TIM It. .$' n.:,.wia�-.a.' r $ r.Yya.mr+ y'�y;+e tyi y*++r. EPbSURE CON7TROLS/PERSON%1L PROTE I ON, a.:ue.+..�.m..t..._.:...�c:..r......atx,.�....,:..c.. .. ...l.d�....L.7..�.'� Exposure Guidelines Component ACGIH TLV OSHA PEL NIOSH IDLH Ontario TWAEV Mexico OEL (TWA) Hexamethylene diisocyanate TWA: 0.005 ppm TWA: 0.005 ppm TWA: 0.005 ppm CEV: 0.02 ppm Engineering Measures Personal Protective Equipment .Respiratory Protection Eye Protection Use ventilation adequate to keep exposures below recommended exposure limits. See MSDS. In case of insufficient ventilation, wear suitable respiratory equipment. Use the indicated respiratory protection if the occupational exposure limit is exceeded and/or in case of product release (dust). Respirator with a vapour filter. Ensure that eyewash stations and safety showers are close to the workstation location. Avoid contact with eyes. Safety glasses with side -shields. Goggles. Face -shield. 0, Page 2/5 -gs Product code NB80 - UV Adhesion Promoter Revision Date May -02-2012 Skin Protection Wear protective gloves/clothing. Solvent -resistant apron and boots. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Wash hands before eating, drinking, or smoking. Remove and wash contaminated clothing before re -use. Avoid contact with skin, eyes and clothing. Wear suitable gloves and eye/face protection. Regular cleaning of equipment, work area and clothing is recommended. A ND GI EIN!CAL PROPERTIES Appearance Water -white Odor Characteristic pH No information available Boiling point/Boiling Range >149 °C / >300 °F Freezing Point/Range No information available Evaporation Rate No information available Vapour Pressure No information available Flammability (solid, gas) No information available Flash Point > 93 °C / > 200 °F Method Setaflash closed cup Weight Per Gallon (lbs/gal) 9.76 VOC by weight % 0.2 VOC lbs/gal (less water) 0.02 Chemical Stability Conditions to Avoid Incompatible Products STABILITY:; Physical State Liquid Odor Threshold No information available Autoignition Temperature No information available Melting Point/Range No information available Solubility No information available Partition Coefficient No information available (n-octanol/water) Vapour Density Heavier than air Flammability Limits In Air Upper No information available Lower No information available Photochemically Reactive No Specific Gravity 1.17 VOC by volume % 0.2 VOC grams/liter (less water) 2.34 Stable under normal conditions. Heat, flames and sparks. Strong acids. Strong bases. Strong oxidizing agents. Reducing agents. Hazardous Decomposition Products Thermal decomposition can lead to release of irritating gases and vapours. Carbon dioxide (CO2). Carbon monoxide. Possibility of Hazardous Reactions None under normal processing. - ICOLOGICAL4INFORMATION Acute Toxicity Component LD50 Oral LD50 Dermal LC50 Inhalation Hexamethylene diisocyanate homopolymer 18500 mg/m3 ( Rat) 1 h Hexamethylene diisocyanate 710 mg/kg ( Rat) 570 mg/kg ( Rabbit) 0.29 mg/L ( Rat) 1 h 0.15 mg/L ( Rat) 4 h Chronic Toxicity No information available Sensitisation May cause sensitization of susceptible persons. Mutagenic Effects No information available Page 3/5 Product code NB80 - UV Adhesion Promoter Revision Date May -02-2012 Reproductive Effects No information available Developmental hazard No information available Teratogenicity No information available Chronic Effects Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may result in adverse health effect, such as mucous membrane and respiratory system irritation and adverse effect on kidney, liver and central nervous system. Repeated contact may cause allergic reactions in very susceptible persons. Avoid repeated exposure. No information available Target Organ Effects "'°'PYA �9 M'aw, tfz t�'w t a�.,,r •+.+rn ,_ r,,,../94,`,1,4,1:e 2w ECOLOGL AL' INFORMATION Ecotoxicity We have no quantitative data concerning the ecological effects of this product. Should not be released into the environment. Component Algae Fish Water Flea Hexamethylene diisocyanate 96h LC50 Brachydanio rerio: 26.1 mg/L [static] Persistence and Degradability No information available Bioaccumulation No information available Mobility in Environmental Media No information available g'1 t D I SPQSALC O I I D EMT I O N Waste Disposal Methods Dispose of contents/container in accordance with local regulation. Contaminated Packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. DOT Printing Ink Related Material, Liquid, Not Regulated ICAO/IATA Not classified as dangerous in the meaning of transport regulations IMDG/IMO Not classified as dangerous in the meaning of transport regulations ��!: x .c-• ���%'r''' n, us -r j "'4Yvm.. .r a mrd t o.., ;, ,J _ W._ 15. REaitra Oiffrai QRMATION '1, International Inventories Listed on TSCA. For further information, please contact: Manufacturer, importer, supplier U.S. Federal Regulations SARA 313 The following components are subject to reporting levels established by SARA Title Ill, Section 313: None known Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act Section 112 (40 CFR 61). U.S. State Regulations Component Massachusetts Right To Know Minnesota Right To Know New Jersey Right To Know Pennsylvania Right To Know Page 4/5 Product code NB80 - UV Adhesion Promoter Revision Date May -02-2012 Hexamethylene diisocyanate X X J X Not Listed Canada This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the information required by the CPR Component Hexamethylene diisocyanate WHMIS Classifications of Components D1A,D2A,D2B,E Regulation (EC) No. 1907/2006 (REACH), Article 57 None known H M IS: Health 3* Flammability 1 Reactivity 1 PPE X AjVI�AA?iW�• V .C„Q .�.. i' HER 0 . R. na t • Revision Date Revision Note May -02-2012 New MSDS format Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used In combination with any other materials or in any process, unless specified in the text End of MSDS Page 5 15 r ink Technologies Product code Product name Product category Material Safety Data Sheet Prepared in accordance with ISO 11014-1/ANSI standard Z400.1-2004 Print Date Oct -24-2012 lit40: !'!'CT A,ND cO Manufacturer or supplier's details UNITED STATES Nazdar Company 8501 Hedge Lane Terrace Shawnee, KS 66227 Tel: 1-913-422-1888 Tel: 1-800-677-4657 Fax: 1-913-422-2294 FP460 Flow Promoter Ink Product UNITED KINGDOM Nazdar Limited Barton Road Heaton Mersey Stockport, England SK4 3EG Tel: +44 161 442 2111 Revision Date Oct -24-2012 Emergency Telephone Number USA: Chemtrec: 1-800-424-9300 Outside USA: Chemtrec: 1-703-527-3887 Website: www.nazdar.com MSDS Information: 1-913-422-1888 ext 2305 MSDS Contact: Regulatory Compliance email: regcomp@nazdar.com Yy raKr. ^F s frOfti Olt 00AV Olt: This product is a preparation. Health hazard information is based on its components. Appearance Flammable Properties Emergency Overview Eyes Skin Inhalation Ingestion F. ��wss�4grt�i Water -white FLAMMABLE LIQUID AND VAPOR. Aspiration hazard. Harmful: may cause lung damage if swallowed. Irritant. May cause drowsiness and dizziness. Moderately irritating to the eyes. Causes skin irritation. May cause irritation of respiratory tract. Inhalation of high vapour concentrations may cause symptoms like headache, dizziness, tiredness, nausea and vomiting. Harmful if swallowed. Potential for aspiration if swallowed. Risk of serious damage to the lungs (by aspiration). CO,MR4 SITI9NIINF4RMATION ON I NGREDI ITS Component CAS -No Weight % Petroleum naphtha, light aromatic 64742-95-6 60 - 100 Trimethylbenzene (contaminant) 25551-13-7 30 - 60 1,2,4-Trimethylbenzene (contaminant) 95-63-6 10 - 30 Xylenes (o-, m-, p- isomers) (contaminant) 1330-20-7 1 - 5 Cumene (contaminant) 98-82-8 1 - 5 Ethyl benzene (contaminant) 100-41-4 < 1 • Component names which have the word (contaminant) are constituents contained in Aromatic Hydrocarbon ingredients and are an integral part of the ingredient and cannot be separated. The percentage listed for the contaminant is as contained in the Hydrocarbon ingredient. (Example: 100% Hydrocarbon, 10% Contaminant A, 3% Contaminant 8) Eye Contact Skin Contact STAID': MEASURl Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get medical attention immediately if irritation develops and persists. Wash off immediately with soap and plenty of water. Use a mild soRTeei6,,,,tinse immediately with plenty of water for at least 15 minutes. Renee mtai)ainfh'n . If irritation develops, get medical attention.Vr�I♦,/jLg,4 Product code FP460 - Flow Promoter • Revision Date Oct -24-2012 Inhalation Ingestion If breathed in, move person into fresh air. If breathing is irregular or stopped, administer artificial respiration. Get medical attention immediately. If swallowed, DO NOT induce vomiting. Call a physician or Poison Control Centre immediately. Never give anything by mouth to an unconscious person. 'P:F'li'iiF 9•Y.::.•r•f I, -Fi `;l Flammable Properties FLAMMABLE LIQUID AND VAPOR. Suitable Extinguishing Media Foam. Carbon dioxide (CO2). Dry chemical. Water spray. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Protective Equipment and Precautions for Firefighters Specific Hazards Arising from the Chemical As in any fire, wear self-contained breathing apparatus pressure -demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Keep away from fire, sparks and heated surfaces. Cool containers / tanks with water spray. Fire or intense heat may cause violent rupture of packages. Thermal decomposition can lead to release of irritating gases and vapours. Burning produces obnoxious and toxic fumes. Keep product and empty container away from heat and sources of ignition. Risk of ignition. =CCIDENTAL" RELEASE MEASUR Personal Precautions Methods for Cleaning Up Environmental Precautions Remove all sources of ignition. Ventilate the area. Avoid breathing dust or vapor. Avoid contact with skin, eyes and clothing. Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13). Do not use sparking tools. Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. AND Handling Storage Avoid contact with skin, eyes and clothing. Ensure adequate ventilation. Remove and wash contaminated clothing before re -use. Discard contaminated shoes. When using do not smoke. Do not take internally. Harmful or fatal if swallowed. Take notice of the directions of use on the label. Keep containers tightly closed in a dry, cool and well -ventilated place. Keep container closed when not in use. Keep out of the reach of children. Keep away from heat and sources of ignition. /AM + Yt !, k vr.v...�in,�p,..• r,ra •'-+p aws.v;.+ .. -t i..... y l'p l v;.•nJp r --1 i OREAcPA3URE • ONT OLS/PERSONAL PROTECtIO Exposure Guidelines Component ACGIH TLV OSHA PEL NIOSH IDLH Ontario TWAEV Mexico OEL (TWA) Trimethylbenzene (contaminant) . TWA: 25 ppm TWA: 25 ppm TWA: 125 mg/m3 TWA: 25 ppm TWA/LMPE-PPT: 25 ppm TWA/LMPE-PPT: 125 mg/m3 STEULMPE-CT: 35 ppm STEULMPE-CT: 170 mg/m3 f� 7 .4 Page 217` -' 54, Product code FP460 - Flow Promoter Revision Date Oct -24-2012 Xylenes (o-, m-, p- isomers) (contaminant) TWA: 100 ppm STEL: 150 ppm TWA: 100 ppm TWA: 435 mg/m3 STEL: 150 ppm STEL: 655 mg/m3 TWA: 100 ppm STEL: 150 ppm TWA/LMPE-PPT: 100 ppm TWA/LMPE-PPT: 435 mg/m3 STEULMPE-CT: 150 ppm STEULMPE-CT: 655 mg/m3 Cumene (contaminant) TWA: 50 ppm TWA: 50 ppm 900 ppm TWA: 50 ppm TWA/LMPE-PPT: 50 ppm TWA: 245 mg/m3 Skin (10% LEL) TWA/LMPE-PPT: 245 mg/m3 STEULMPE-CT: 75 ppm STEULMPE-CT: 365 mg/m3 Ethyl benzene (contaminant) TWA: 20 ppm TWA: 100 ppm 800 ppm TWA: 100 ppm TWA/LMPE-PPT: 100 ppm TWA: 435 mg/m3 STEL: 125 ppm (10% LEL) STEL: 125 ppm TWA/LMPE-PPT: 435 mg/m3 STEL: 545 mg/m3 STEULMPE-CT: 125 ppm STEULMPE-CT: 545 mg/m3 Engineering Measures Personal Protective Equipment Respiratory Protection Eye Protection Skin Protection General Hygiene Considerations Use ventilation adequate to keep exposures below recommended exposure limits. See MSDS. In case of insufficient ventilation, wear suitable respiratory equipment. Use the indicated respiratory protection if the occupational exposure limit is exceeded and/or in case of product release (dust). Respirator with a vapour filter. Ensure that eyewash stations and safety showers are close to the workstation location. Avoid contact with eyes. Safety glasses with side -shields. Goggles. Face -shield. Wear protective gloves/clothing. Solvent -resistant apron and boots. Handle in accordance with good industrial hygiene and safety practice. Wash hands before eating, drinking, or smoking. Remove and wash contaminated clothing before re -use. Avoid contact with skin, eyes and clothing. Wear suitable gloves and eye/face protection. Regular cleaning of equipment, work area and clothing is recommended. 9: PHY"�SICAL�:iikND CHEINICALy PROPERfiIE, Appearance Odor pH Boiling point/Boiling Range Freezing Point/Range Evaporation Rate Vapour Pressure Flammability (solid, gas) Water -white Characteristic No information available >149 °C / >300 °F No information available No information available No information available No information available Flash Point 32 °C / 90 °F Method Tag closed cup Weight Per Gallon (lbs/gal) 7.29 VOC by weight % (less water) 84 VOC lbs/gal (less water) 6.13 Physical State Odor Threshold Autoignition Temperature Melting Point/Range Solubility Partition Coefficient (n-octanollwater) Vapour Density Liquid No information available No information available No information available No information available No information available Heavier than air Flammability Limits in Air Upper No information available Lower No information available Photochemically Reactive Yes Specific Gravity 0.87 VOC by volume % (less water)84 VOC grams/liter (less water) 734.51 BIanY ND':REACTINITI� Chemical Stability Stable under normal conditions. Page 317 Product code FP460 - Flow Promoter Revision Date Oct -24-2012 Conditions to Avoid Heat, flames and sparks. Incompatible Products Strong acids. Strong bases. Strong oxidizing agents. Reducing agents. Hazardous Decomposition Products Thermal decomposition can lead to release of irritating gases and vapours. Carbon dioxide (CO2). Carbon monoxide. Possibility of Hazardous Reactions None under normal processing. igit.1 ' 010: INFORMATit• dr Acute Toxicity Component LD50 Oral LD50 Dermal LC50 inhalation Petroleum naphtha, light aromatic 8400 mg/kg ( Rat) >2000 mg/kg ( Rabbit) 3400 ppm ( Rat ) 4 h >5.2 mg/L (Rat) 4h Trimethylbenzene (contaminant) 8970 mg/kg ( Rat ) Ethyl benzene (contaminant) A3 1,2,4-Trimethylbenzene (contaminant) 3400 mg/kg ( Rat) >3160 mg/kg ( Rabbit) 18 g/m3 ( Rat) 4 h Xylenes (o-, m-, p- isomers) (contaminant) 4300 mg/kg ( Rat) . >1700 mg/kg ( Rabbit) 5000 ppm ( Rat) 4 h 47635 mg/L ( Rat) 4 h Cumene (contaminant) 1400 mg/kg ( Rat) >3160 mg/kg ( Rabbit) 39000 mg/m3 ( Rat) 4 h Ethyl benzene (contaminant) 3500 mg/kg ( Rat) 15354 mg/kg ( Rabbit) 17.2 mg/L ( Rat) 4 h Chronic Toxicity Component ACGIH IARC NTP OSHA Cumene (contaminant) 96h LC50 Oncorhynchus mykiss: 9.22 mg/L Group 2B Trimethylbenzene (contaminant) X Ethyl benzene (contaminant) A3 Group 2B X Legend: ACGIH: (American Conference of Governmental Industrial Hygienists) IARC: (International Agency for Research on Cancer) OSHA: (Occupational Safety & Health Administration) Sensitisation Mutagenic Effects Reproductive Effects Developmental hazard Teratogenicity Chronic Effects Target Organ Effects A3 - Animal Carcinogen Group 28 - Possibly Carcinogenic to Humans X - Present No information available No information available No information available No information available No information available Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may result in adverse health effect, such as mucous membrane and respiratory system irritation and adverse effect on kidney, liver and central nervous system. Blood, Central nervous system, Eyes, Respiratory system, Skin. 1103,1, A' :S�fdt ?%1�ux1'P.^'.0/1•IJI J,"Y:'Cl'fY'?.'k.vraN.- rt dL: � N.A•: ,.. qr Jl. (`. y{��- V'12 EC;iDLOGCAvikitiRNirkir N Ecotoxicity We have no quantitative data concerning the ecological effects of this product. Should not be released into the environment. Component Algae Fish Water Flea Petroleum naphtha, light aromatic 96h LC50 Oncorhynchus mykiss: 9.22 mg/L Trimethylbenzene (contaminant) 96h LC50 Pimephales promelas: 7.72 mg/L [[flow-through]) 1,2,4-Trimethylbenzene (contaminant) 96h LC50 Pimephales promelas: 7.19 - 8.28 mg/L [flow-through] 48h EC50 Daphnia magna: 6.14 mg/L Page 4/7 116 Product code FP460 - Flow Promoter Revision Date Oct -24-2012 Cumene (contaminant) 72h EC50 Pseudokirchneriella 96h LC50 Pimephales promelas: 48h EC50 Daphnia magna: 7.9 - 14.1 Xylenes (o-, m-, p- isomers) (contaminant) subcapitata: 2.6 mg/L 6.04 - 6.61 mg/L [flow-through] mg/L [static] Ethyl benzene (contaminant) 3.118 96h LC50 Oncorhynchus mykiss: 48h EC50 Daphnia magna: 0.6 mg/L 1,2,4-Trimethylbenzene (contaminant) 95-63-6 2.7 mg/L [semi -static] 1.0 96h LC50 Oncorhynchus mykiss: 4.8 mg/L [flow-through] 96h LC50 Poecilia reticulata: 5.1 mg/L [semi -static] Ethyl benzene (contaminant) 96h EC50 Pseudokirchneriella 96h LC50 Oncorhynchus mykiss: 48h EC50 Daphnia magna: 1.8 - 2.4 subcapitata: 1.7 - 7.6 mg/L [static] 11.0 - 18.0 mg/L [static] mg/L 72h EC50 Pseudokirchneriella 96h LC50 Pimephales promelas: subcapitata: 2.6 - 11.3 mg/L [static] 7.55 - 11 mg/L [flow-through] 72h EC50 Pseudokirchneriella 96h LC50 Pimephales promelas: subcapitata: 4.6 mg/L 9.1 - 15.6 mg/L [static] 96h EC50 Pseudokirchneriella subcapitata: >438 mg/L 96h LC50 Lepomis macrochirus: 32 mg/L [static] 96h LC50 Oncorhynchus mykiss: 4.2 mg/L [semi -static] 96h LC50 Poecilia reticulata: 9.6 mg/L [static] Persistence and Degradability No information available Bioaccumulation No information available Mobility in Environmental Media No information available Component log Pow 1,2,4-Trimethylbenzene (contaminant) 3.63 Xylenes (o-, m-, p- isomers) (contaminant) 2.96 Cumene (contaminant) 3.55 Ethyl benzene (contaminant) 3.118 Waste Disposal Methods Contaminated Packaging :� .�, a:.�:r.;,;-h"•'>ar,21.. ..-;-.c:� »r^snx.�a^.vc,-rye$*;�•,- {,t�.y-:t'.w •. � ��r.�3��'IS.P�OS4,LCO�iSIDERAT�4NS:� Dispose of contents/container in accordance with local regulation. Empty containers should be taken to an approved waste handling site for recycling or disposal. N''M F t- j'I i 4 DOT UN1210, Printing Ink Related Material, 3, III ICAO/IATA UN1210, Printing Ink Related Material, 3, III IMDG/IMO UN1210, Printing Ink Related Material, 3, III 1.41 R1(A�NF©RMATti .`I ..awa..:f r International Inventories Listed on TSCA. For further information, please contact: Manufacturer, importer, supplier U.S. Federal Regulations SARA 313 The following components ar Component CAS -No Weight % SARA 313 - Threshold Values Ethyl benzene (contaminant) 100-41-4 < 1 0.1 Xylenes (o-, m-, p- isomers) (contaminant) 1330-20-7 1 - 5 1.0 1,2,4-Trimethylbenzene (contaminant) 95-63-6 10 - 30 1.0 Page 517 Product code FP460 - Flow Promoter Revision Date Oct -24-2012 Cumene (contaminant) 98-82-8 1-5 1.0 Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) Component CAS -No Weight % Xylenes (o-, m-, p- isomers) (contaminant) 1330-20-7 1 - 5 . Cumene (contaminant) 98-82-8 1 - 5 U.S. State Regulations Component Massachusetts Right To Know Minnesota Right To Know New Jersey Right To Know Pennsylvania Right To Know Trimethylbenzene (contaminant) X X X X 1,2,4-Trimethylbenzene (contaminant) X X X X Xylenes (o-, m-, p- isomers) (contaminant) X X X X Cumene (contaminant) X X X X Ethyl benzene (contaminant) X X X X California Prop. 65 WARNING! This product contains a chemical known in the State of California to cause cancer and / or WARNING! This product contains a chemical known in the State of California to cause birth defects or other reproductive harm Component CAS -No Weight % Ethyl benzene (contaminant) 100-41-4 < 1 Cumene (contaminant) 98-82-8 1 - 5 Canada This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the information required by the CPR Component WHMIS Classifications of Components Petroleum naphtha, light aromatic B3,D2B Trimethylbenzene (contaminant) B3 1,2,4-Trimethylbenzene (contaminant) B3 Xylenes (o-, m-, p- isomers) (contaminant) B2,D2A,D2B Cumene (contaminant) B2,D2A Ethyl benzene (contaminant) B2,D2A,D2B Component NPRI - National Pollutant Release Inventory Petroleum naphtha, light aromatic Part 5 Substance Part 5, Other Groups and Mixtures Trimethylbenzene (contaminant) Part 5 Substance Part 5, Isomer Groups 1,2,4-Trimethylbenzene (contaminant) Part 4 Substance Part 1, Group 1 Substance Part 5, Individual Substance Xylenes (o-, m-, p- isomers) (contaminant) Part 1, Group 1 Substance Part 5 Substance Part 5, Isomer Groups Cumene (contaminant) Part 4 Substance Part 1, Group 1 Substance Ethyl benzene (contaminant) Part 4 Substance Part 1, Group 1 Substance Regulation (EC) No. 1907/2006 (REACH), Article 57 This product does not contain substances of very high concern (Regulation (EC) No. 1907/2006 (REACH), Article 57) HMIS: Health Flammability Reactivity 2* 3 0 PPE X Page 6 l 7 Product code FP460 - Flow Promoter Revision Date Oct -24-2012 Mi1.:. M1 Via �f r..,r.• 1 T v ;nlAla}w 1' !Y THER INFORMATIQNn,,• Revision Date Revision Note Oct -24-2012 New MSDS format Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text End of MSDS Page 7 / 7 Material Safety Data Sheet Prepared In accordance with ISO 11014-1/ANSI standard Z400.1-2004 Print Date Oct -27-2010 Revision Date Oct -27-2010 IDENIfTIF 4 gT 4 Product code Product name Product description Manufacturer or supplier's details UNITED STATES Nazdar Company 8501 Hedge Lane Terrace Shawnee, KS 66227 Tel: 1-913-422-1888 Tel: 1-800-677-4657 Fax: 1-913-422-2294 9731 Retarder Ink Product UNITED KINGDOM Nazdar Limited 7 Barton Road Heaton Mersey Industrial Estate Stockport, Chesire SK4 3EG Tel: +44 161 442 2111 Emergency Telephone Number USA: Chemtrec: 1-800-424-9300 Outside USA: Chemtrec: 1-703-527-3887 Website: www.nazdar.com MSDS Information: 1-913-422-1888 ext 2305 MSDS Contact: Regulatory Compliance email: regcomp@nazdar.com IRDS1 DEN .I,F1Ci?7101!i This product is a preparation. Health hazard information is based on its components. Appearance Flammable Properties Emergency Overview Eyes Skin Inhalation Ingestion Water -white Combustible liquid and vapor. Irritant. Moderately irritating to the eyes. Risk of serious damage to eyes. Avoid contact with eyes. May cause skin irritation and/or dermatitis. May cause irritation of respiratory tract. Inhalation of high vapour concentrations may cause symptoms like headache, dizziness, tiredness, nausea and vomiting. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. OMPy6Si oNLINF IATI° ,io) ;1 ,670160,1 •,i A,. Component CAS -No Ethyl 3-Ethoxypropionate Gamma Butvrolactone 763-69-9 Weight % 30-60 96-48-0 30 - 60 FIRST AID,; MEASURE Eye Contact Skin Contact Inhalation Ingestion Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get medical attention immediately if irritation develops and persists. Wash off immediately with soap and plenty of water. Use a mild soap if available. Rinse immediately with plenty of water for at least 15 minutes. Remove contaminated clothing. If irritation develops, get medical attention. Move to fresh air. If breathed in, move person into fresh air. If breathing is irregular or stopped, administer artificial respiration. Get medical attention immediately. If swallowed, DO NOT induce vomiting. Call a physician or Poison Control Centre immediately. Never give anything by mouth to an unconscious person. FIRE IGHWNG`MEASURES* Flammable Properties Combustible liquid and vapor. bR2L3LI RECEIVED CITY OF TUKWILA JUL 122013 PERMIT CENTER Product code 9731 - Retarder • Revision Date Oct -27-201 Suitable Extinguishing Media Protective Equipment and Precautions for Firefighters Specific Hazards Arising from the Chemical Foam. Carbon dioxide (CO2). Dry chemical. Water spray. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. As in any fire, wear self-contained breathing apparatus pressure -demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Keep away from fire, sparks and heated surfaces. Keep container tightly closed. Cool containers / tanks with water spray. Fire or intense heat may cause violent rupture of packages. Thermal decomposition can lead to release of irritating gases and vapours. Burning produces obnoxious and toxic fumes. C D „ jfll;L'; RE1400, 001100 Personal Precautions Methods for Cleaning Up Environmental Precautions Remove all sources of ignition. Heat, flames and sparks. Ventilate the area. Avoid breathing dust or vapor. Avoid contact with skin, eyes and clothing. Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13). Do not use sparking tools. Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. �,-.r Jr.. DLI& Handling Storage Exposure Guidelines Avoid contact with skin, eyes and clothing. Ensure adequate ventilation. Remove and wash contaminated clothing before re -use. Discard contaminated shoes. When using do not smoke. Take notice of labels and material safety data sheets for the working chemicals. Do not take internally. Harmful or fatal if swallowed. Keep containers tightly closed in a dry, cool and well -ventilated place. Keep container closed when not in use. Keep out of the reach of children. Keep away from heat and sources of ignition. Take notice of the directions of use on the label. Component ACGIH TLV OSHA PEL NIOSH IDLH Ontario TWAEV Mexico OEL (TWA) Ethyl 3-Ethoxypropionate TWA: 300 mg/m3 TWA: 50 ppm Engineering Measures Personal Protective Equipment Respiratory Protection Eye Protection Skin Protection General Hygiene Considerations Use only with adequate ventilation. Use ventilation adequate to keep exposures below recommended exposure limits. See MSDS. In case of insufficient ventilation, wear suitable respiratory equipment. Use the indicated respiratory protection if the occupational exposure limit is exceeded and/or in case of product release (dust). Respirator with a vapour filter. Ensure that eyewash stations and safety showers are close to the workstation location. Avoid contact with eyes. Safety glasses with side -shields. Goggles. Face -shield. Wear protective gloves/clothing. Solvent -resistant apron and boots. Handle in accordance with good industrial hygiene and safety practice. Ensure that eyewash stations and safety showers are close to the workstation location. Wash hands before eating, drinking, or smoking. Remove and wash contaminated clothing before re -use. Regular cleaning of equipment, work area and clothing. Avoid contact with skin, eyes and clothing. Wear suitable gloves and eye/face protection. Page 2:/,5` r��roduct code 9731 - Retarder Revision Date Oct -27-2010 Appearance Odor pH Boiling point/Boiling Range Freezing Point/Range Evaporation Rate Vapour Pressure Flammability (solid, gas) Flammability Limits in Air Upper No information available Lower No information available `"✓ 3 cro ro.:y.. .,y+�,v VK x ✓k sic::R'-c:a4n`.ye.;:� � .�c:C.vsl .. r ii3'.i." ►���HY�SICAL'�AND�Cy��i11;�fAL�;�P�QP�ER�i1ESx Water -white Characteristic No information available >149°C / >300°F No information available No information available No information available No information available Weight Per Gallon (lbs/gal) 8.584 VOC by weight % 100 VOC lbs/gal (less water) 8.645 Physical State Odor Threshold Autoignition Temperature Melting Point/Range Solubility Partition Coefficient (n- octanol/water) Vapour Density \ J Liquid No information available No information available No information available No information available No information available No information available Flash Point 63°C / 145°F Method Pensky Martens Closed Cup (PMCC) Photochemically Reactive Specific Gravity VOCbyvolume% VOC grams/liter (less water) No 1.029 100 1035.899 � a. � °,..x.�r�i-1 a +�;.et ung �..,a•:..:.a..•e:. • e�`�r�,4. 4.. TABU IrkAt WitEACTIa/1; . tAiteM Chemical Stability Conditions to Avoid Incompatible Products Hazardous Decomposition Products Possibility of Hazardous Reactions Stable under normal conditions. Heat, flames and sparks. Strong acids. Strong bases. Strong oxidizing agents. Reducing agents. Thermal decomposition can lead to release of irritating gases and vapours. Carbon dioxide (CO2). Carbon monoxide. None under normal processing. a: k XICI ALO ICAL%I:NFORMATION, {b ` 7,11571-"t.!'Nv6Y�ie Acute Toxicity Component LD50 Oral LD50 Dermal LC50 Inhalation Ethyl 3-Ethoxvpropionate 3200 mq/kq ( Rat) 10 mUkq ( Rabbit ) Gamma Butyrolactone 1540 mq/kq ( Rat) 2.68 mq/L ( Rat) 4 h Chronic Toxicity No information available Sensitisation Mutagenic Effects Reproductive Effects Developmental Effects Teratogenicity Chronic Effects Target Organ Effects No information available No information available No information available No information available No information available Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may result in adverse health effect, such as mucous membrane and respiratory system irritation and adverse effect on kidney, liver and central nervous system. No information available Page 315 Product code 9731 - Retarder Revision Date Oct -27-201' 2� PCOL°tgG'ICAtr. " N ORMA1TIOYNk Ecotoxicity We have no quantitative data concerning the ecological effects of this product. Should not be released into the environment. Component Freshwater Algae Freshwater Fish Water Flea Ethyl 3-Ethoxypropionate Massachusetts 96 Hr LC50 Pimephales promelas: 62 mq/L Istaticl 48 Hr EC50 Daphnia magna: 970 mg/L Gamma Butyrolactone 72 Hr EC50 Scenedesmus subspicatus: 360 mg/L; 96 Hr EC50 Scenedesmus subspicatus: 79 mq/L 96 Hr LC50 Leuciscus idus: 220-460 mg/L [static] 48 Hr EC50 Daphnia magna Straus: >500 mg/L Persistence and Degradability No information available Bioaccumulation No information available Mobility in Environmental Media No information available Component Ethyl 3-Ethoxypropionate log Pow 1.35 Gamma Butyrolactone -0.566 DISPOSAL CONSIDERATIONS Waste Disposal Methods Contaminated Packaging Dispose of contents/container in accordance with local regulation. Empty containers should be taken to an approved waste handling site for recycling or disposal. 14: �;RANSPO .TINFORMATIONk T DOT Printing Ink Related Material, Liquid, Not Regulated ICAO/IATA Not classified as dangerous in the meaning of transport regulations IMDG/IMO Not classified as dangerous in the meaning of transport regulations Y aO0iN00R TIO`I International Inventories Listed on TSCA. For further information, please contact: Manufacturer, importer, supplier U.S. Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) This product does not contain any HAPs. U.S. State Regulations State Right -to -Know Component Minnesota Florida New Jersey Pennsylvania Massachusetts Rhode Island Ethyl 3-Ethoxypropionate Not Listed Not Listed Not Listed Not Listed Not Listed Not Listed Gamma Butyrolactone Not Listed Not Listed Not Listed Not Listed _ Not Listed Not Listed Page 415 ,;product code 9731 - Retarder Revision Date Oct -27-2010 Canada This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the information required by the CPR Component Ethyl 3-Ethoxypropionate WHMIS Classifications of Components B3, D2B Component NPRI - National Pollutant Release Inventory Ethyl 3-Ethoxyoropionate Part 4 Substance Gamma Butyrolactone Part 4 Substance REACH: Substances of Very High Concern (SVHC): Article 57 of Regulation (EC) No 1907/2006 Does NOT contain a listed substance HMIS: Health 3* Flammability Reactivity 2 0 PPE X .SU•i�lT < ��j�{ 5%AnC a! i h g1 i.4 ERd11 FORMA I , .1.1Ae esti,.. a fat Y' 1t. Revision Date Revision Summary Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text Oct -27-2010 New MSDS format End of MSDS Page 5/5 Material Safety Data Sheet Prepared in accordance with ISO 11014-1/ANSI standard Z400.1-2004 Print Date Oct -27-2010 Revision Date Oct -27-2010 •'10PRODl7CT tmA's�:+i«n t.rxys:es,, srca.w,ngars.*;. b'W.§V,YJ� NDCOMPAI�IY4IDEh n,tn ban . FICATIO • Product code Product name Product description Manufacturer or supplier's details UNITED STATES Nazdar Company 8501 Hedge Lane Terrace Shawnee, KS 66227 Tel: 1-913-422-1888 Tel: 1-800-677-4657 Fax: 1-913-422-2294 CARE53 Gel Retarder Ink Product UNITED KINGDOM Nazdar Limited 7 Barton Road Heaton Mersey Industrial Estate Stockport, Chesire SK4 3EG Tel: +44 161 442 2111 Emergency Telephone Number USA: Chemtrec: 1-800-424-9300 Outside USA: Chemtrec: 1-703-527-3887 Website: www.nazdar.com MSDS Information: 1-913-422-1888 ext 2305 MSDS Contact: Regulatory Compliance email: regcomp@nazdar.com ;RE NT) A KION This product is a preparation. Health hazard information is based on its components. Viscous liquid Irritant. Appearance Emergency Overview Eyes Skin Inhalation Ingestion May cause eye irritation. May cause skin irritation and/or dermatitis. May cause irritation of respiratory tract. Inhalation of high vapour concentrations may cause symptoms like headache, dizziness, tiredness, nausea and vomiting. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. 3 COMPOSITION/INFORMATi9 ON NGREM NTS t Component CAS -No Weight % Dimethyl Glutarate 1119-40-0 30 - 60 Dimethvi Adipate 627-93-0 10 - 30 Dimethyl Succinate 106-65-0 10 - 30 114 ST mDMEASU '•1 Eye Contact Skin Contact Inhalation Ingestion Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get medical attention immediately if irritation develops and persists. Wash off immediately with soap and plenty of water. Use a mild soap if available. Rinse immediately with plenty of water for at least 15 minutes. Remove contaminated clothing. If irritation develops, get medical attention. Move to fresh air. If breathed in, move person into fresh air. If breathing is irregular or stopped, administer artificial respiration. Get medical attention immediately. If swallowed, DO NOT induce vomiting. Call a physician or Poison Control Centre immediately. Never give anything by mouth to an unconscious person. to, 3;FIRE-FIG ITJNc f EASUREs Flammable Properties No information available RECEIVED CITY OF TUKWILA JUL 1 1 2013 PERMIT CENTER Product code CARE53 - Gel Retarder Revision Date Oct -27-2010 Suitable Extinguishing Media Protective Equipment and Precautions for Firefighters Specific Hazards Arising from the Chemical Foam. Carbon dioxide (CO2). Dry chemical. Water spray. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. As in any fire, wear self-contained breathing apparatus pressure -demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Keep away from fire, sparks and heated surfaces. Keep container tightly closed. Cool containers / tanks with water spray. Fire or intense heat may cause violent rupture of packages. Thermal decomposition can lead to release of irritating gases and vapours. Burning produces obnoxious and toxic fumes. as tt IDENTALRELEA'SEMEASURE$ y*; •i° v is �'Ys &-: Personal Precautions Methods for Cleaning Up Environmental Precautions Remove all sources of ignition. Heat, flames and sparks. Ventilate the area. Avoid breathing dust or vapor. Avoid contact with skin, eyes and clothing. Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13). Do not use sparking tools. Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. L'+ 7 4ANDLiNGIIND'S`TI RA Handling Storage Avoid contact with skin, eyes and clothing. Ensure adequate ventilation. Remove and wash contaminated clothing before re -use. Discard contaminated shoes. When using do not smoke. Take notice of labels and material safety data sheets for the working chemicals. Do not take internally. Harmful or fatal if swallowed. Keep containers tightly closed in a dry, cool and well -ventilated place. Keep container closed when not in use. Keep out of the reach of children. Keep away from heat and sources of ignition. Take notice of the directions of use on the label. l!E tSONyAkOTE*1 QH:t Exposure Guidelines This product does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies. Engineering Measures Personal Protective Equipment Respiratory Protection Eye Protection Skin Protection General Hygiene Considerations Use only with adequate ventilation. Use ventilation adequate to keep exposures below recommended exposure limits. See MSDS. In case of insufficient ventilation, wear suitable respiratory equipment. Use the indicated respiratory protection if the occupational exposure limit is exceeded and/or in case of product release (dust). Respirator with a vapour filter. Ensure that eyewash stations and safety showers are close to the workstation location. Avoid contact with eyes. Safety glasses with side -shields. Goggles. Face -shield. Wear protective gloves/clothing. Solvent -resistant apron and boots. Handle in accordance with good industrial hygiene and safety practice. Ensure that eyewash stations and safety showers are close to the workstation location. Wash hands before eating, drinking, or smoking. Remove and wash contaminated clothing before re -use. Regular cleaning of equipment, work area and clothing. Avoid contact with skin, eyes and clothing. Wear suitable gloves and eye/face protection. tN Sy r " 215' � r• Product code CARE53 - Gel Retarder Revision Date Oct -27-2010 Appearance Odor pH Boiling point/Boiling Range Freezing Point/Range Evaporation Rate Vapour Pressure Flammability (solid,. gas) Flammability Limits in Air Upper No information available Lower No information available Viscous liquid Characteristic No information available >149°C / >300°F No information available No information available No information available No information available Weight Per Gallon (lbs/gal) VOC by weight % VOC lbs/gal (less water) :ORE IfI 0A : ,P ORIER Physical State Odor Threshold Autoignition Temperature Melting Point/Range Solubility Partition Coefficient (n- octanol/water) Vapour Density Liquid No information available No information available No information available No information available No information available No information available Flash Point > 93°C / > 200°F Method Pensky Martens Closed Cup (PMCC) Photochemically Reactive 9.466 Specific Gravity 92.43 VOC by volume % 8.758 VOC grams/liter (less water) No 1.136 96.093 1049.469 �;AI�D�REA`CT11�IT1 Chemical Stability Conditions to Avoid Incompatible Products Hazardous Decomposition Products Possibility of Hazardous Reactions Stable under normal conditions. Heat, flames and sparks. Strong acids. Strong bases. Strong oxidizing agents. Reducing agents. Thermal decomposition can lead to release of irritating gases and vapours. Carbon dioxide (CO2). Carbon monoxide. None under normal processing. • C{/���zY t_''y& " Z Ea � �' x�C .lat:' �a4'• ta¢ Q' CAL' NFbRr .A,T o .3. Acute Toxicity Component LD50 Oral LD50 Dermal LC50 Inhalation Dimethyl Glutarate 8191 mg/kg ( Rat) 5.6 mq/L ( Rat) 4 h Dimethyl Adipate 1920 mg/kg ( Rat ) Dimethyl Succinate 5000 mg/kg ( Rat) 5000 mq/kq ( Rabbit ) Chronic Toxicity No information available Sensitisation Mutagenic Effects Reproductive Effects Developmental Effects Teratogenicity Chronic Effects Target Organ Effects No information available No information available No information available No information available No information available Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may result in adverse health effect, such as mucous membrane and respiratory system irritation and adverse effect on kidney, liver and central nervous system. No information available Page 3 15 Product code CARE53 - Gel Retarder Revision Date Oct -27-2010 cleiVEcogoeicAviNcog. ,Ano_ Ecotoxicity We have no quantitative data concerning the ecological effects of this product. Should not be released into the environment. Component Freshwater Algae Freshwater Fish Water Flea Dimethyl Glutarate Massachusetts 96 Hr LC50 Pimephales promelas: 19.6-26.2 mq/L [static] 48 Hr EC50 Daphnia magna: 122.1- 163.5 mq/L Dimethyl Succinate Not Listed 96 Hr LC50 Brachydanio rerio: 50-100 mg/L [static] Not Listed Persistence and Degradability No information available Bioaccumulation No information available Mobility in Environmental Media No information available Component log Pow Dimethyl Succinate 0.19 13 DISROSALr CONSIDERATION !t: Waste Disposal Methods Contaminated Packaging Dispose of contents/container in accordance with local regulation. Empty containers should be taken to an approved waste handling site for recycling or disposal. • 4 Xeit:i �> �{ t r .ti'.:t°i iit rti"tT , '4! t Zl M4 .A .41 '4r�TR�ANSPC�RT NFORIIiIAn.0� DOT Printing Ink Related Material, Liquid, Not Regulated ICAO/IATA Not classified as dangerous in the meaning of transport regulations IMDG/IMO Not classified as dangerous in the meaning of transport regulations ya AMA 'tWsa+uS� '.y. yY EGU:d7 International Inventories Listed on TSCA. For further information, please contact: Manufacturer, importer, supplier U.S. Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 Clean Air Act, Section 112 Hazardous Air Pollutants (HAPS) (see 40 CFR 61) This product does not contain any HAPs. U.S. State Regulations State Riaht-to-Know Component Minnesota Florida New Jersey Pennsylvania Massachusetts Rhode Island Dimethyl Glutarate Not Listed Not Listed Not Listed Not Listed Not Listed Not Listed Dimethyl Adipate Not Listed Not Listed Not Listed Not Listed Not Listed Not Listed Dimethyl Succinate Not Listed Not Listed Not Listed Not Listed Not Listed Not Listed Page 4/5 Product code CARE53 - Gel Retarder Revision Date Oct -27-2010 Canada This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the information required by the CPR Component NPRI - National Pollutant Release Inventory Dimethyl Glutarate Part 4 Substance Dimethyl Adipate Part 4 Substance Dimethyl Succinate Part 4 Substance REACH: Substances of Very High Concern (SVHC): Article 57 of Regulation (EC) No 1907/2006 Does NOT contain a listed substance HMIS: Health 1* Flammability 1 Reactivity 0 PPE X Revision Date Revision Summary Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text Oct -27-2010 New MSDS format End of MSDS Page 5/5 A' Ink Technologies Material Safety Data Sheet Prepared in accordance with ISO 11014-1/ANSI standard Z400.1-2004 Print Date Jan -02-2013 Revision Date Jan -02-2013 " I Product code Product name Product category Manufacturer or supplier's details UNITED STATES Nazdar Company 8501 Hedge Lane Terrace Shawnee, KS 66227 Tel: 1-913-422-1888 Tel: 1-800-677-4657 Fax: 1-913-422-2294 2555 Screen Wash Ink Product UNITED KINGDOM Nazdar Limited Barton Road Heaton Mersey Stockport, England SK4 3EG Tel: +44 161 442 2111 Emergency Telephone Number USA: Chemtrec: 1-800-424-9300 Outside USA: Chemtrec: 1-703-527-3887 Website: www.nazdar.com MSDS Information: 1-913-422-1888 ext 2305 MSDS Contact: Regulatory Compliance email: regcomp@nazdar.com �i'ARD�S:�I;p�1�T1�IC`'ATIQ This product is a preparation. Health hazard information is based on its components. Appearance Flammable Properties Emergency Overview Eyes Skin Inhalation Ingestion Water -white FLAMMABLE LIQUID AND VAPOR. Irritant. Sensitizer. May cause drowsiness and dizziness. Moderately irritating to the eyes. May cause skin irritation and/or dermatitis. Prolonged or repeated skin contact with liquid may cause defatting resulting in drying, redness and possible blistering. Repeated or prolonged skin contact may cause allergic reactions with susceptible persons. May cause sensitization by skin contact. May cause irritation of respiratory tract. Inhalation of high vapour concentrations may cause symptoms like headache, dizziness, tiredness, nausea and vomiting. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. OMPOSITIOgniitORliATIOkti ING tifilk Component CAS -No Weight % Xylenes (o-, m-, p- isomers) 1330-20-7 60 - 100 Ethyl benzene (contaminant) 100-41-4 10 - 30 • Component names which have the word (contaminant) are constituents contained in Aromatic Hydrocarbon ingredients and are an integral part of the ingredient and cannot be separated. The percentage fisted for the contaminant is as contained in the Hydrocarbon ingredient. (Example: 100% Hydrocarbon, 10% Contaminant A, 3% Contaminant B) Eye Contact Skin Contact Inhalation Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get medical attention immediately if irritation develops and persists. Wash off immediately with soap and plenty of water. Use a mild soap if available. Rinse immediately with plenty of water for at least 15 minutes. Remove contaminated clothing. If irritation develops, get medical attention. If breathed in, move person into fresh air. If breathing is irregular or stgvp� minister artificial respiration. Get medical attention immediately. t (tCadminister CITY OF TUKWILA JUL 12 2013 1 239 1 PERMIT CENTER Product code 2555 - Screen Wash • Revision Date Jan -02-2013 Ingestion If swallowed, DO NOT induce vomiting. Call a physician or Poison Control Centre immediately. Never give anything by mouth to an unconscious person. E=FIGHTINGMEASUR Flammable Properties Suitable Extinguishing Media Protective Equipment and Precautions for Firefighters Specific Hazards Arising from the Chemical FLAMMABLE LIQUID AND VAPOR. Foam. Carbon dioxide (CO2). Dry chemical. Water spray. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. As in any fire, wear self-contained breathing apparatus pressure -demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Keep away from fire, sparks and heated surfaces. Cool containers / tanks with water spray. Fire or intense heat may cause violent rupture of packages. Thermal decomposition can lead to release of irritating gases and vapours. Burning produces obnoxious and toxic fumes. Keep product and empty container away from heat and sources of ignition. Risk of ignition. CCIDENTAIr RELEASE;NIEASURES Personal Precautions Methods for Cleaning Up Environmental Precautions Remove all sources of ignition. Ventilate the area. Avoid breathing dust or vapor. Avoid contact with skin, eyes and clothing. Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13). Do not use sparking tools. Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. 0:00-04-404 Handling Storage Avoid contact with skin, eyes and clothing. Ensure adequate ventilation. Remove and wash contaminated clothing before re -use. Discard contaminated shoes. When using do not smoke. Do not take intemally. Harmful or fatal if swallowed. Take notice of the directions of use on the label. Keep containers tightly closed in a dry, cool and well -ventilated place. Keep container closed when not in use. Keep out of the reach of children. Keep away from heat and sources of ignition. XPLOSURECONTRQLS/PERSONAL PROTECTION Exposure Guidelines Component ACGIH TLV OSHA PEL NIOSH IDLH Ontario TWAEV Mexico OEL (TWA) Xylenes (o-, m-, p- isomers) TWA: 100 ppm STEL: 150 ppm TWA: 100 ppm TWA: 435 mg/m3 STEL: 150 ppm STEL: 655 mg/m3 TWA: 100 ppm STEL: 150 ppm TWA/LMPE-PPT: 100 ppm TWA/LMPE-PPT: 435 mg/m3 STEULMPE-CT: 150 ppm STEULMPE-CT: 655 mg/m3 44. .I 41110,1.... --Page 216 Product code 2555 - Screen Wash Revision Date Jan -02-2013 Ethyl benzene (contaminant) TWA: 20 ppm TWA: 100 ppm 800 ppm TWA: 100 ppm TWA/LMPE-PPT: 100 ppm TWA: 435 mg/m3 STEL: 125 ppm (10% LEL) STEL: 125 ppm TWA/LMPE-PPT: 435 mg/m3 STEL: 545 mg/m3 STEULMPE-CT: 125 ppm STEULMPE-CT: 545 mg/m3 Engineering Measures Use ventilation adequate to keep exposures below recommended exposure limits. See MSDS. In case of insufficient ventilation, wear suitable respiratory equipment. Personal Protective Equipment Respiratory Protection Use the indicated respiratory protection if the occupational exposure limit is exceeded and/or in case of product release (dust). Respirator with a vapour filter. Eye Protection Ensure that eyewash stations and safety showers are close to the workstation location. Avoid contact with eyes. Safety glasses with side -shields. Goggles. Face -shield. Skin Protection Wear protective gloves/clothing. Solvent -resistant apron and boots. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Wash hands before eating, drinking, or smoking. Remove and wash contaminated clothing before re -use. Avoid contact with skin, eyes and clothing. Wear suitable gloves and eye/face protection. Regular cleaning of equipment, work area and clothing is recommended. • PH�1fS1CA�=�NCt�C�6�lfl�°'�¢ M.'a: Appearance Water -white Physical State Liquid Odor Characteristic Odor Threshold No information available pH No information available Autoignition Temperature No information available Boiling point/Boiling Range >149 °C / >300 °F Melting Point/Range No information available Freezing Point/Range No information available Solubility No information available Evaporation Rate No information available Partition Coefficient No information available (n-octanol/water) Vapour Pressure No information available Vapour Density Heavier than air Flammability (solid, gas) No information available Flash Point 27 °C / 81 °F Method Tag closed cup Weight Per Gallon (lbs/gal) 7.25 VOC by weight % (less water) 100 VOC lbs/gal (less water) 7.25 Flammability Limits in Air Upper No information available Lower No information available Photochemically Reactive Yes Specific Gravity 0.87 VOC by volume % (less water)100 VOC grams/liter (less water) 869.11 BILif'C AND TI! Chemical Stability Conditions to Avoid Incompatible Products Stable under normal conditions. Heat, flames and sparks. Strong acids. Strong bases. Strong oxidizing agents. Reducing agents. Hazardous Decomposition Products Thermal decomposition can lead to release of irritating gases and vapours. Carbon dioxide (CO2). Carbon monoxide. Possibility of Hazardous Reactions None under normal processing. i COLOG 10AL1 N FOitMATI i Page 316 Product code 2555 - Screen Wash Revision Date Jan -02-2013 Acute Toxicity Component LD50 Oral LD50 Dermal LC50 Inhalation Xylenes (o-, m-, p- isomers) 4300 mg/kg ( Rat) >1700 mg/kg ( Rabbit) 5000 ppm ( Rat) 4 h 47635 mg/L ( Rat) 4 h Ethyl benzene (contaminant) 3500 mg/kg ( Rat) 15354 mg/kg ( Rabbit) 17.2 mg/L ( Rat) 4 h Chronic Toxicity Component ACGIH IARC NTP OSHA Ethyl benzene (contaminant) A3 Group 2B X ACGIH: (American Conference of Governmental Industrial Hygienists) IARC: (International Agency for Research on Cancer) OSHA: (Occupational Safety & Health Administration) Sensitisation Mutagenic Effects Reproductive Effects Developmental hazard Teratogenicity Chronic Effects Target Organ Effects A3 - Animal Carcinogen Group 28 - Possibly Carcinogenic to Humans X - Present May cause sensitization of susceptible persons. No information available No information available No information available No information available Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may result in adverse health effect, such as mucous membrane and respiratory system irritation and adverse effect on kidney, liver and central nervous system. Central nervous system, Eyes, Respiratory system, Skin. ►GICAL''INEORM4 Ecotoxicity We have no quantitative data concerning the ecological effects of this product. Should not be released into the environment. Component Algae Fish Water Flea Ethyl benzene (contaminant) 96h EC50 Pseudokirchneriella 96h LC50 Oncorhynchus mykiss: 48h EC50 Daphnia magna: 1.8 - 2.4 subcapitata: 1.7 - 7.8 mg/L [static] 11.0 - 18.0 mg/L [static] mg/L 72h EC50 Pseudokirchneriella 96h LC50 Pimephales promelas: subcapitata: 2.6 - 11.3 mg/L [static] 7.55 - 11 mg/L [flow-through] 72h EC50 Pseudokirchneriella 96h LC50 Pimephales promelas: subcapitata: 4.6 mg/L 9.1 - 15.6 mg/L [static] 96h EC50 Pseudokirchneriella subcapitata: >438 mg/L 96h LC50 Lepomis macrochirus: 32 mg/L [static] 96h LC50 Oncorhynchus mykiss: 4.2 mg/L [semi -static] 96h LC50 Poecilia reticulata: 9.6 mg/L [static] Persistence and Degradability No information available Bioaccumulation No information available Mobility in Environmental Media No information available Component log Pow Xylenes (o-, m-, p- isomers) 2.96 Ethyl benzene (contaminant) 3.118 c:,sr,.r SPOS �OIi1S�DERA�l01 Waste Disposal Methods Dispose of contents/container in accordance with local regulation. Contaminated Packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Page 4/6 Product code 2555 - Screen Wash Revision Date Jan -02-2013 r. �W r..�, � •�»,tT.y, �sr�a,m'f, ,atWt.w; I , • DOT UN1210, Printing Ink Related Material, 3, III ICAO/IATA UN1210, Printing Ink Related Material, 3, III IMDG/IMO UN1210, Printing Ink Related Material, 3, III ULA' International Inventories Listed on TSCA. For further information, please contact: Manufacturer, importer, supplier U.S. Federal Regulations SARA 313 The following components are subject to r Component CAS -No Weight /o SARA 313 - Threshold 100-41-4 10 - 30 Xylenes (o-, m-, p- isomers) Values Ethyl benzene (contaminant) 100-41-4 10 - 30 0.1 Xylenes (o-, m-, p- isomers) 1330-20-7 60 - 100 1.0 Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) Component CAS -No Weight % Ethyl benzene (contaminant) 100-41-4 10 - 30 Xylenes (o-, m-, p- isomers) 1330-20-7 60 - 100 U.S. State Regulations Component Massachusetts Right To Know Minnesota Right To Know New Jersey Right To Know Pennsylvania Right To Know Xylenes (o-, m-, p- isomers) X X X X Ethyl benzene (contaminant) X X X X California Prop. 65 WARNING! This product contains a chemical known in the State of California to cause cancer and / or WARNING! This product contains a chemical known in the State of Component CAS -No Weight % Ethyl benzene (contaminant) 100-41-4 10 - 30 Toluene 108-88-3 < 1 Canada This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the information required by the CPR Component WHMIS Classifications of Components Xylenes (o-, m-, p- isomers) B2,D2A,D2B Ethyl benzene (contaminant) B2,D2A,D2B Component NPRI - National Pollutant Release Inventory Xylenes (o-, m-, p- isomers) Part 1, Group 1 Substance Part 5 Substance Part 5, Isomer Groups Ethyl benzene (contaminant) Part 4 Substance Part 1, Group 1 Substance Page 5/6 Product code 2555 - Screen Wash Revision Date Jan -02-2013 Regulation (EC) No. 1907/2006 (REACH), Article 57 This product does not contain substances of very high concern (Regulation (EC) No. 1907/2006 (REACH), Article 57) HMIS: Health 2* Flammability 3 Reactivity 0 PPE X Revision Date Revision Note Jan -02-2013 New MSDS format Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given Is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text End of MSDS Page 616 ink Technologies Material Safety Data Sheet Prepared in accordance with ISO 11014-1/ANSI standard 2400.1-2004 Print Date May -29-2012 Revision Date May -29-2012 1. PRo""64dCT ANDC" DENTrFC`ATetNe Product code Product name Product category Manufacturer or supplier's details UNITED STATES Nazdar Company 8501 Hedge Lane Terrace Shawnee, KS 66227 Tel: 1-913-422-1888 Tel: 1-800-677-4657 Fax: 1-913-422-2294 SW37 Universal Screen Wash Ink Product UNITED KINGDOM Nazdar Limited Barton Road Heaton Mersey Stockport, England SK4 3EG Tel: +44 161 442 2111 Emergency Telephone Number USA: Chemtrec: 1-800-424-9300 Outside USA: Chemtrec: 1-703-527-3887 Website: www.nazdar.com MSDS Information: 1-913-422-1888 ext 2305 MSDS Contact: Regulatory Compliance email: regcomp@nazdar.com IAZARDSgDENT1, ICAs This product is a preparation. Health hazard information is based on its components. Appearance Flammable Properties Emergency Overview Eyes Skin Inhalation Ingestion Water -white FLAMMABLE LIQUID AND VAPOR. Irritant. Sensitizer. May cause drowsiness and dizziness. The liquid splashed in the eyes may cause irritation and reversible damage. Severe eye irritant. Causes skin irritation. Prolonged skin contact may defat the skin and produce dermatitis. May be harmful if absorbed through skin. Prolonged or repeated skin contact with liquid may cause defatting resulting in drying, redness and possible blistering. Repeated or prolonged skin contact may cause allergic reactions with susceptible persons. May cause sensitization by skin contact. May be absorbed through the skin in harmful amounts. Inhalation of vapours is irritating to the respiratory system, may cause throat pain and cough. Inhalation of high vapour concentrations may cause symptoms like headache, dizziness, tiredness, nausea and vomiting. Risk of serious damage to the lungs (by inhalation). Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. `Y.Y,,parz.iW �tMyHT fkY"X TJ+ y, a. L 6 rii4i�.V.0- 1.0"'/L,i, i% kyhC-{'jc'iLl-•� ,1COMPOS TIPNIRIT.ORMAT#ONION 114Ai EDIEN�TT Component CAS -No Weight % Xylenes (o-, m-, p- isomers) 1330-20-7 60 - 100 Ethylene glycol monopropyl ether 2807-30-9 10 - 30 Ethyl benzene (contaminant) 100-41-4 10 - 30 Diacetone alcohol 123-42-2 10 - 30 • Component names which have the word (contaminant) are constituents contained in Aromatic Hydrocarbon ingredients and are an integral part of the ingredient and cannot be separated. The percentage listed for the contaminant is as contained in the Hydrocarbon ingredient. (Example: 100% Hydrocarbon, 10% Contaminant A, 3% Contaminant 8) MEASIRESI9;�^r= Eye Contact Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get medical attention imiataJvlIfjgibtion develops and persists. CITY OF TUI(WILA JUL 1 1 2013 PERMIT CENTER Product code SW37 - Universal Screen Wash 7 • Revision Date May -29-20121 Skin Contact Inhalation Ingestion Wash off immediately with soap and plenty of water. Use a mild soap if available. Rinse immediately with plenty of water for at least 15 minutes. Remove contaminated clothing. If irritation develops, get medical attention. If breathed in, move person into fresh air. If breathing is irregular or stopped, administer artificial respiration. Get medical attention immediately. If swallowed, DO NOT induce vomiting. Call a physician or Poison Control Centre immediately. Never give anything by mouth to an unconscious person. Flammable Properties Suitable Extinguishing Media Protective Equipment and Precautions for Firefighters Specific Hazards Arising from the Chemical FLAMMABLE LIQUID AND VAPOR. Foam. Carbon dioxide (CO2). Dry chemical. Water spray. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. As in any fire, wear self-contained breathing apparatus pressure -demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Keep away from fire, sparks and heated surfaces. Cool containers / tanks with water spray. Fire or intense heat may cause violent rupture of packages. Thermal decomposition can lead to release of irritating gases and vapours. Burning produces obnoxious and toxic fumes. Keep product and empty container away from heat and sources of ignition. Risk of ignition. CGIDENTAt,::RELEASE'MEASURESt Personal Precautions Methods for Cleaning Up Environmental Precautions Remove all sources of ignition. Ventilate the area. Avoid breathing dust or vapor. Avoid contact with skin, eyes and clothing. Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13). Do not use sparking tools. Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. Handling Storage Avoid contact with skin, eyes and clothing. Ensure adequate ventilation. Remove and wash contaminated clothing before re -use. Discard contaminated shoes. When using do not smoke. Do not take internally. Harmful or fatal if swallowed. Take notice of the directions of use on the label. Keep containers tightly closed in a dry, cool and well -ventilated place. Keep container closed when not in use. Keep out of the reach of children. Keep away from heat and sources of ignition. ;EXPOSURE CONTROLS/PERSONAL"PROTECTION Exposure Guidelines Component ACGIH TLV OSHA PEL NIOSH IDLH h, ,0,10L'* Ontario TWAEV Mexico OEL (TWA) Page 2/7 Product code SW37 - Universal Screen Wash Revision Date May -29-2012 Xylenes (o-, m-, p- isomers) TWA: 100 ppm STEL: 150 ppm TWA: 100 ppm TWA: 435 mg/m3 STEL: 150 ppm STEL: 655 mg/m3 TWA: 100 ppm STEL: 150 ppm TWA/LMPE-PPT: 100 ppm TWA/LMPE-PPT: 435 mg/m3 STEULMPE-CT: 150 ppm STEULMPE-CT: 655 mg/m3 Ethylene glycol monopropyi ether TWA: 25 ppm TWA: 110 mg/m3 Skin Ethyl benzene (contaminant) TWA: 20 ppm TWA: 100 ppm TWA: 435 mg/m3 STEL: 125 ppm STEL: 545 mg/m3 800 ppm (10% LEL) TWA: 100 ppm STEL: 125 ppm TWA/LMPE-PPT: 100 ppm TWA/LMPE-PPT: 435 mg/m3 STEULMPE-CT: 125 ppm STEULMPE-CT: 545 mg/m3 Diacetone alcohol TWA: 50 ppm TWA: 50 ppm TWA: 240 mg/m3 1800 ppm (10% LEL) TWA: 50 ppm TWA: 240 mg/m3 STEL: 75 ppm STEL: 360 mg/m3 TWA/LMPE-PPT: 50 ppm TWA/LMPE-PPT: 240 mg/m3 STEULMPE-CT: 75 ppm STEULMPE-CT: 360 mg/m3 Engineering Measures Personal Protective Equipment Respiratory Protection Eye Protection Skin Protection General Hygiene Considerations' Use ventilation adequate to keep exposures below recommended exposure limits. See MSDS. In case of insufficient ventilation, wear suitable respiratory equipment. Use the indicated respiratory protection if the occupational exposure limit is exceeded and/or in case of product release (dust). Respirator with a vapour filter. Ensure that eyewash stations and safety showers are close to the workstation location. Avoid contact with eyes. Safety glasses with side -shields. Goggles. Face -shield. Wear protective gloves/clothing. Solvent -resistant apron and boots. Handle in accordance with good industrial hygiene and safety practice. Wash hands before eating, drinking, or smoking. Remove and wash contaminated clothing before re -use. Avoid contact with skin, eyes and clothing. Wear suitable gloves and eye/face protection. Regular cleaning of equipment, work area and clothing is recommended. PHYSIC' ICAL?PRO PERTI Appearance Odor pH Boiling point/Boiling Range Freezing Point/Range Evaporation Rate Vapour Pressure Flammability (solid, gas) Water -white Characteristic No information available >149 °C / >300 °F No information available No information available No information available No information available Flash Point 27 °C / 80 °F Method Tag closed cup Weight Per Gallon (lbs/gal) 7.39 VOC by weight % 100 VOC lbs/gal (less water) 7.4 Physical State Odor Threshold Autoignition Temperature Melting Point/Range Solubility Partition Coefficient (n-octanollwater) Vapour Density Liquid No information available No information available No information available No information available No information available Heavier than air Flammability Limits in Air Upper No information available Lower No information available Photochemically Reactive Yes Specific Gravity 0.89 VOC by volume % 100 VOC grams/liter (less water) 886.38 F{Y.t.:. Ru°m.+.t.c• t"f :aG`.a:i:X:ab�" )11)4'TSY ANDREA 5. r _i7+::; y; � c µi'. "+.a Page 3 17 Product code SW37 - Universal Screen Wash Revision Date May -29-2012 Chemical Stability Stable under normal conditions. Conditions to Avoid Heat, flames and sparks. Incompatible Products Strong acids. Strong bases. Strong oxidizing agents. Reducing agents. Hazardous Decomposition Products Thermal decomposition can lead to release of irritating gases and vapours. Carbon dioxide (CO2). Carbon monoxide. Possibility of Hazardous Reactions None under normal processing. XICOLOGICAL INFORMATION Acute Toxicity Component LD50 Oral LD50 Dermal LC50 Inhalation Xylenes (o-, m-, p- isomers) 4300 mg/kg ( Rat) >1700 mg/kg ( Rabbit) 5000 ppm ( Rat) 4 h 47635 mg/L ( Rat) 4 h Ethylene glycol monopropyl ether 3089 mg/kg ( Rat) 960 NL/kg ( Rabbit ) Ethyl benzene (contaminant) 3500 mg/kg ( Rat ) 15354 mg/kg ( Rabbit) 17.2 mg/L (Rat) 4 h Diacetone alcohol 4 g/kg ( Rat) 13500 mg/kg ( Rabbit ) Chronic Toxicity Component ACGIH IARC NTP OSHA Ethyl benzene (contaminant) A3 Group 2B X Legend: ACG/H: (American Conference of Governmental Industrial Hygienists) IARC: (international Agency for Research on Cancer) OSHA: (Occupational Safety & Health Administration) Sensitisation Mutagenic Effects Reproductive Effects Developmental hazard Teratogenicity Chronic Effects Target Organ Effects A3 - Animal Carcinogen Group 28 - Possibly Carcinogenic to Humans X - Present May cause sensitization of susceptible persons. No information available No information available No information available No information available Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may result in adverse health effect, such as mucous membrane and respiratory system irritation and adverse effect on kidney, liver and central nervous system. Central nervous system, Eyes, Liver, Respiratory system, Skin. 14 4441.."‘ a. tai i.� Ecotoxicity We have no quantitative data concerning the ecological effects of this product. Should not be released into the environment. Component Algae I Fish Water Flea Page 4/7 -, Product code SW37 - Universal Screen Wash Revision Date May -29-2012 Xylenes (o-, m-, p- isomers) log Pow 96h LC50 Lepomis macrochirus: 13.1 - 16.5 mg/L [flow-through] 96h LC50 Oncorhynchus mykiss: 13.5-17.3 mg/L 96h LC50 Oncorhynchus mykiss: 2.661 - 4.093 mg/L [static] 96h LC50 Pimephales promelas: 23.53 - 29.97 mg/L [static] 48h LC50 Gammarus lacustris: 0.6 mg/L 48h EC50 water flea: 3.82 mg/L Ethyl benzene (contaminant) 3.118 96h LC50 Poecilia reticulata: 30.26 - 1.03 40.75 mg/L [static] 96h LC50 Lepomis macrochirus: 7.711 - 9.591 mg/L [static] 96h LC50 Pimephales promelas: 13.4 mg/L [flow-through] 96h LC50 Lepomis macrochirus: 19 mg/L 96h LC50 Cyprinus carpio: 780 mg/L [semi -static] 96h LC50 Cyprinus carpio: >780 mg/L Ethyl benzene (contaminant) 96h EC50 Pseudokirchneriella 96h LC50 Oncorhynchus mykiss: 48h EC50 Daphnia magna: 1.8 - 2.4 subcapitata: 1.7 - 7.6 mg/L [static] 11.0 - 18.0 mg/L [static] mg/L 72h EC50 Pseudokirchneriella 96h LC50 Pimephales promelas: .- subcapitata: 2.6 - 11.3 mg/L [static] 7.55 - 11 mg/L [flow-through] 72h EC50 Pseudokirchneriella 96h LC50 Pimephales promelas: subcapitata: 4.6 mg/L 9.1 - 15.6 mg/L [static] 96h EC50 Pseudokirchneriella subcapitata: >438 mg/L 96h LC50 Lepomis macrochirus: 32 mg/L [static] 96h LC50 Oncorhynchus mykiss: 4.2 mg/L [semi -static] 96h LC50 Poecilia reticulata: 9.6 mg/L [static] Diacetone alcohol 96h LC50 Lepomis macrochirus: 24h EC50 Daphnia magna: 8750 mg/L 420 mg/L 96h LC50 Lepomis macrochirus: 420 mg/L [static] Persistence and Degradab lity Bioaccumulation Mobility in Environmental Media No information available No information available No information available Component log Pow Xylenes (0-, m-, p- isomers) 2.96 Ethyl benzene (contaminant) 3.118 Diacetone alcohol 1.03 M1W ►POS`A ON 07Fi t Wtne Waste Disposal Methods Contaminated Packaging Dispose of contents/container in accordance with local regulation. Empty containers should be taken to an approved waste handling site for recycling or disposal. ` TRANS T T fNE.QRMATlON DOT UN1210, Printing Ink Related Material, 3, III ICAO/IATA UN1210, Printing Ink Related Material, 3, Ill IMDG/IMO UN1210, Printing Ink Related Material, 3, Ill Page 5/7 Product code SW37 - Universal Screen Wash Revision Date May -29-2012 �wvS�Av.[ a"y�.s3', L: i+ 1efitedI: iT,ORTINFORMATTION International Inventories Listed on TSCA. For further information, please contact: Manufacturer, importer, supplier U.S. Federal Regulations SARA 313 The following components are subject to reporting levels establish Component CAS -No Weight % SARA 313 - Threshold Values Ethyl benzene (contaminant) 100-41-4 10 - 30 0.1 Xylenes (o-, m-, p- isomers) 1330-20-7 60 - 100 1.0 Ethylene glycol monopropyl ether _ 2807-30-9 10 - 30 1.0 Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) Component CAS -No Weight % Ethyl benzene (contaminant) 100-41-4 10 - 30 Xylenes (o-, m-, p- isomers" 1330-20-7 60 - 100 . Ethylene glycol monopropyl ether 2807-30-9 10 - 30 U.S. State Regulations Component Massachusetts Right To Know Minnesota Right To Know New Jersey Right To Know Pennsylvania Right To Know Xylenes (0-, m-, p- isomers) X X X X Ethylene glycol monopropyl ether Not Listed Not Listed X X Ethyl benzene (contaminant) X X X X Diacetone alcohol X X X X California Prop. 65 WARNING! This product contains a chemical known in the State of California to cause cancer and / or WARNING! This product contains a chemical known in the State of California to cause birth defects or other reproductive harm Component CAS -No Weight % Ethyl benzene (contaminant) 100-41-4 10 - 30 Toluene 108-88-3 < 1 Canada This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the information required by the CPR Component WHMIS Classifications of Components Xylenes (o-, m-, p- isomers) B2,D2A,D2B Ethylene glycol monopropyl ether B3,D1 B,D2B Ethyl benzene (contaminant) B2,D2A,D2B Diacetone alcohol B3,D2B Component NPRI - National Pollutant Release Inventory Xylenes (o-, m-, p- isomers) Part 1, Group 1 Substance Part 5 Substance Part 5, Isomer Groups Ethylene glycol monopropyl ether Part 4 Substance Ethyl benzene (contaminant) Part 4 Substance Part 1, Group 1 Substance Diacetone alcohol Part 4 Substance Regulation (EC) No. 1907/2006 (REACH), Article 57 This product does not contain substances of very high concern (Regulation (EC) No. 1907/2006 (REACH), Article 57) Page 6 / 7 Product code SW37 - Universal Screen Wash . Revision Date May -29-2012 HMIS: Revision Date Revision Note Health 2* May -29-2012 New MSDS format Flammability 3 ERCN1 Reactivity 0 PPE X Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used In combination with any other materials or in any process, unless specified in the text End of MSDS Page 7 / 7 Product Code: Product Name: Manufacturer Information Company Name: Phone Number: Emergency Contact: Information: Web site address: Preparer Name: Intended Use: Synonyms GML170, QML170, CML170, QML170L, DML170, GML170P, GML17OPTEMP, G17024, PA12782, Q17014 2. Hazards Identification SAFETY DATA SHEET Page: 1 Lacquer Thinner HEALTH fr, I 2 FLAMMABILITY 3 PHYSICAL -7.— PPE X PPE Flammability Instability Health Special Hazard 1. Product and Company Identification 1605.48 Lacquer Thinner W. M. Barr 2105 Channel Avenue Memphis, TN 38113 (901)775-0100 3E 24 Hour Emergency Contact W.M. Barr Customer Service www.wmbarr.com W.M. Barr EHS Dept Paint thinning Printed: 07/24/2012 Revision: 06/08/2011 Supercedes Revision: 05/21/2009 (800)451-8346 (800)398-3892 (901)775-0100 GHS Classification GHS Hazard Phrases No data available. GHS Precaution Phrases No data available. GHS Response Phrases No data available. GHS Storage and Disposal Phrases No data available. Potential Health Effects (Acute and Chronic) Inhalation Acute Exposure Effects: Vapor harmful. May cause dizziness; headache; watering of eyes; irritation of respiratory tract; weakness; drowsiness; nausea; numbness in fingers, arms and legs; depression of central nervous system; loss of appetite; fatigue; hallucinations; light headedness; visual disturbances; giddiness and intoxication; sleepiness; cough and dyspnea; cold, clammy extremities; diarrhea; vomiting; dilation of pupils; spotted vision. Severe overexposure may cause convulsions; unconsciousness; coma; and death. Intentional misuse of this product by deliberately concentrating and inhaling can be harmful or fatal. RECEIVED CITY OF TUKWILA JUL 1 2 2013 PERMIT CENTER Skin Contact Acute Exposure Effects: May be absorbed through the skin. May cause irritation; numbness in the fingers and arms; drying of skin; and dermatitis. May cause increased severity of symptoms listed under inhalation. Eye Contact Acute Exposure Effects: This material is an eye irritant. May cause irritation; burns; conjunctivitis of eyes; and corneal ulcerations of the eye. Vapors may irritate eyes. Licensed to W.M. Barr and Company GHS format SAFETY DATA SHEET Lacquer Thinner Page: 2 4 Printed: 07/24/2012 Revision: 06/08/2011 Supercedes Revision: 05/21/2009 Ingestion Acute Exposure Effects: Poison. Cannot be made non-poisonous. May be fatal or cause blindness. May cause dizziness; headache; nausea; vomiting; burning sensation in mouth, throat, and stomach; loss of coordination; depression of the central nervous system; narcosis; stupor; gastrointestinal irritation; liver, kidney, and heart damage; diarrhea; loss of appetite; coma and death. May produce symptoms listed under inhalation. Chronic Exposure Effects: Reports have associated repeated and prolonged overexposure to solvents with neurological and other physiological damage. Prolonged or repeated contact may cause dermatitis. Prolonged skin contact may result in absorption of a harmful amount of this material. May cause conjunctivitis; gastric disturbances; insomnia; dizziness; headache; weakness; fatigue; nausea; heart palpitations; skin irritation; numbness in hands and feet; permanent central nervous system changes; some loss of memory; pancreatic damage; giddiness; visual impairment or blindness; kidney or liver damage; and death. May cause symptoms listed under inhalation. Target Organs: Central Nervous System, Liver, Kidney, Heart, Stomach, Respiratory System Primary Routes of Entry: Inhalation, Ingestion, Skin Absorption Medical Conditions Generally Aggravated By Exposure Diseases of the skin, eyes, liver, kidneys, central nervous system and respiratory system. OSHA Regulatory Status: This material is classified as hazardous under OSHA regulations. 3. Composition/Information on Ingredients Hazardous Components (Chemical Name) 1. Methanol {Methyl alcohol; Carbinol; Wood alcohol) 2. Toluene {Benzene, Methyl-; Toluol} 3. Acetone {2-Propanone} . 4. 'Ethanoi,'2-Butoxy- {Ethylene glycol n -butyl ether, (a glycol ether)) 5. Acetic acid, ethyl ester {Ethyl acetate) 6. Light aliphatic solvent naphtha (petroleum) CAS # Concentration 67-56-1 15.0 -40.0 % 108-88-3 1.0 -5.0 % 67-64-1 10.0 -30.0 % 111-76-2 1.0 -5.0 % 141-78-6 7.0 -13.0 % 64742-89-8 15.0 -40.0 % 4. First Aid Measures Emergency and First Aid Procedures Skin: Immediately begin washing the skin thoroughly with large amounts of water and mild soap, if available, while removing contaminated clothing. Seek medical attention if irritation persists. Eyes: Immediately begin to flush eyes with water, remove any contact lens. Continue to flush the eyes for at least 15 minutes, then seek immediate medical attention. Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. Ingestion: If swallowed, do not induce vomiting. Seek immediate medical attention. Call a physician, hospital emergency room, or poison control center immediately. Never give anything by mouth to an unconscious person. 40, Licensed to W.M. Barr and Company '° " `'� .. f GHS format V SAFETY DATA SHEET Lacquer Thinner Page: 3 Printed: 07/24/2012 • Revision: 06/08/2011 Supercedes Revision: 05/21/2009 Note to Physician Poison. This product contains methanol. Methanol is metabolized to formaldehyde and formic acid. These metabolites may cause metabolic acidosis, visual disturbances and blindness. Since metabolism is required for these toxic symptoms, their onset may be delayed from 6 to 30 hours following ingestion. Ethanol competes for the same metabolic pathway and has been used as an antidote. Methanol is effectively removed by hemodialysis. Call your local poison control center for further information. Signs and Symptoms Of Exposure See Potential Health Effects. 5. Fire Fighting Measures Flammability Classification: NFPA Class IB Flash Pt: -4.0 F Method Used: Setaflash Closed Cup (Rapid Setaflash) Explosive Limits: LEL: No data. UEL: No data. Autoignition Pt: No data available. Fire Fighting Instructions Self-contained respiratory protection should be provided for fire fighters fighting fires in buildings or confined areas. Storage containers exposed to fire should be kept cool with water spray to prevent pressure build-up. Stay away from heads of containers that have been exposed to intense heat or flame. Flammable Properties and Hazards No data available. Hazardous Combustion Products Carbon monoxide and carbon dioxide. Suitable Extinguishing Media Use carbon dioxide, dry powder, or foam. Unsuitable Extinguishing Media Do not use a solid water stream, as this may spread the fire. 6. Accidental Release Measures Steps To Be Taken In Case Material Is Released Or Spilled Vapors may cause flash fire or ignite explosively. Clean up: Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind, out of low areas, and ventilate closed spaces before entering. Shut off ignition sources; keep flares, smoking or flames out of hazard area. Use non -sparking tools. Use proper bonding and grounding methods for all equipment and processes. Keep out of waterways and bodies of water. Be cautious of vapors collecting in small enclosed spaces, sewers, low lying areas, confined spaces, etc. Small spills: Take up with sand, earth or other noncombustible absorbent material and place in a plastic container where applicable. Large spills: Dike far ahead of spill for later disposal. Waste Disposal: Dispose in accordance with applicable local, state and federal regulations. Licensed to W.M. Barr and Company GHS format SAFETY DATA SHEET Lacquer Thinner 7. Handling and Storage Page: 4 Printed: 07/24/2012 Revision: 06/08/2011 Supercedes Revision: 05/21/2009 Precautions To Be Taken in Handling Do not use in small enclosed spaces, such as basements and bathrooms. Vapors can accumulate and explode if ignited. Read carefully all cautions and directions on product label before use. Since empty container retains residue, follow all label warnings even after container is empty. Dispose of empty container according to all regulations. Do not reuse this container. Do not use this product near any source of heat or open flame, furnace areas, pilot lights, stoves, etc. Do not use in small enclosed spaces, such as basements and bathrooms. Vapors can accumulate and explode if ignited. Do not spread this product over large surface areas because fire and health safety risks will increase dramatically. Precautions To Be Taken in Storing Keep container tightly closed when not in use. Store in a cool, dry place. Do not store near flames or at elevated temperatures. 8. Exposure Controls/Personal Protection Hazardous Components (Chemical Name) 1. Methanol {Methyl alcohol; Carbinol; Wood alcohol) 2. Toluene {Benzene, Methyl-; Toluol) 3. Acetone {2-Propanone) 4. Ethanol, 2-Butoxy- {Ethylene glycol n -butyl ether, (a glycol ether)) 5. Acetic acid, ethyl ester {Ethyl acetate) 6. Light aliphatic solvent naphtha (petroleum) Respiratory Equipment (Specify Type) For OSHA controlled work place and other regular users. Use only with adequate ventilation under engineered air control systems designed to prevent exceeding appropriate TLV. CAS # OSHA TWA 67-56-1 PEL: 200 ppm 108-88-3 PEL: 200 ppm STEL: 500 ppm/(10min) CEIL: 300 ppm 67-64-1 PEL: 1000 ppm 111-76-2 PEL: 50 ppm 141-78-6 PEL: 400 ppm 64742-89-8 No data. ACGIH TWA TLV: 200 ppm STEL: 250 ppm TLV: 50 ppm TLV: 500 ppm STEL: 750 ppm TLV: 20 ppm TLV: 400 ppm No data. Other Limits No data. No data. No data. No data. No data. No data. For occasional use, where engineered air control is not feasible, use properly maintained and properly fitted NIOSH approved respirator for organic solvent vapors. A dust mask does not provide protection against vapors. Eye Protection Protect eyes with chemical splash goggles. Protective Gloves Wear gloves with as much resistance to the chemical ingredients as possible. Glove materials such as nitrile rubber may provide protection. Glove selection should be based on chemicals being used and conditions of use. Consult your glove supplier for additional information. Gloves contaminated with product should be discarded and not reused. Other Protective Clothing Various application methods can dictate use of additional protective safety equipment, such as impermeable aprons, etc., to minimize exposure. Licensed to W.M. Barr and Company GHS format SAFETY DATA SHEET Lacquer Thinner Page: 5 Printed: 07/24/2012 Revision: 06/08/2011 Supercedes Revision: 05/21/2009 Engineering Controls (Ventilation etc.) Use only with adequate ventilation to prevent build-up of vapors. Open all windows and doors. Use only with a cross ventilation of moving fresh air across the work area. If strong odor is noticed or you experience slight dizziness, headache, nausea, or eye -watering - Stop - ventilation is inadequate. Leave area immediately. Do not use in small enclosed spaces, such as basements and bathrooms. Work/Hygienic/Maintenance Practices A source of clean water should be available in the work area for flushing eyes and skin. Do not eat, drink, or smoke in the work area. Wash hands thoroughly after use. Before reuse, thoroughly clean any clothing or protective equipment that has been contaminated by prior use. Discard any clothing or other protective equipment that cannot be decontaminated, such as gloves or shoes. 9. Physical and Chemical Properties Physical States: [ ] Gas [ X ] Liquid [ ] Solid Melting Point: No data. Boiling Point: 130 F Autoignition Pt: No data. Flash Pt: -4.0 F Method Used: Setaflash Closed Cup (Rapid Setaflash) Specific Gravity (Water = 1): 0.7742 - 0.7942 Density: 6.518 LB/GL Vapor Pressure (vs. Air or mm Hg): 115 MM HG at 68 F Vapor Density (vs. Air = 1): > 1 Evaporation Rate: > 1 Solubility in Water: Slight Percent Volatile: 100 % by weight. VOC / Volume: 590 G/L Viscosity: Water thin Appearance and Odor Water White / Free and Clear 10. Stability and Reactivity Stability: Unstable [ ] Stable [ X ] Conditions To Avoid - Instability No data available. Incompatibility - Materials To Avoid Incompatible with strong oxidizing agents, strong caustics, hydrogen peroxide, and nitrates. Hazardous Decomposition Or Byproducts Decomposition may produce carbon monoxide; carbon dioxide; formaldehyde; and unidentified organic compounds in black smoke. Possibility of Hazardous Reactions: Will occur [ ] Will not occur [ X ] Conditions To Avoid - Hazardous Reactions No data available. Licensed to W.M. Barr and Company GHS format SAFETY DATA SHEET Lacquer Thinner 11. Toxicological Information Page: 6 Printed: 07/24/2012 4 Revision: 06/08/2011 Supercedes Revision: 05/21/2009 Toxicological Information This product has not been tested as a whole. Information below will be for individual ingredients. ' Acute Toxicity: Methanol: LD50 Rat oral 5628 mg/kg LC50 Rat inhalation 64000 ppm/4 hr LD50 Mouse oral 7300 mg/kg Toluene: LD50 Rat oral 2.6 to 7.5 g/kg LD50 Rabbit dermal 14.1 ml/kg LC50 Mice inhalation 5320 ppm/8 hr Acetone: LD50 Rat oral 10.7 mL/kg (=8450 mg/kg bw); acetone given by gastric intubation to groups of five non-fasted Carworth-Wistar female rats LD50 Rat oral 9800 mg/kg/ bw LC50 Rat inhalation exposure 76 mg/L/4 hr LD50 Rabbit dermal 20 mg/kg bw 2-Butoxyethanol: LD50 Rat oral 1.48 g/kg LD50 Mouse oral 1.2 g/kg LD50 Rabbit oral 0.32 g/kg LD50 Rabbit dermal 400 mg/kg LC50 Rat (male) inhalation 486 ppm/4 hr /from table/ LC50 Mouse inhalation 700 ppm/7 hr /from table/ Skin Corrosion/Irritation: Methanol, toluene, MEK, and acetone are skin irritants. Serious Eye Damage/Irritation: Methanol and acetone are eye irritants. Toluene and MEK are severe eye irritants. Respiratory or Skin Sensitization: No data available. Aspiration Hazard: No data available. Chronic Toxicological Effects This product has not been tested as a whole. Information below will be for individual ingredients. Germ Cell Mutagenicity: No data available. Reproductive Toxicity: Gross toluene exposure during pregnancy can produce renal toxicity, fetal toxicity, and teratogenicity. Licensed to W.M. Barr and Company GHS format SAFETY DATA SHEET Lacquer Thinner STOT-Single Exposure: No data available. STOT-Repeated Exposure: No data available. Carcinogenicity/Other Information IARC 3: Not Classifiable as to Carcinogenicity in Humans ACGIH A3 - Confirmed Animal Carcinogen with Unknown Relevance to Humans ACGIH A4 - Not Classifiable as a Human Carcinogen Page: 7 Printed: 07/24/2012 Revision: 06/08/2011 Supercedes Revision: 05/21/2009 Hazardous Components (Chemical Name) CAS # NTP IARC ACGIH OSHA 1. Methanol {Methyl alcohol; Carbinol; Wood 67-56-1 n.a. n.a. n.a. n.a. alcohol) 2. Toluene {Benzene, Methyl-; Toluol) 108-88-3 n.a. 3 A4 n.a. 3. Acetone {2-Propanone) 67-64-1 n.a. n.a. A4 n.a. 4. Ethanol, 2-Butoxy- {Ethylene glycol n -butyl 111-76-2 n.a. 3 A3 n.a. ether, (a glycol ether)) 5. Acetic acid, ethyl ester {Ethyl acetate) 141-78-6 n.a. n.a. n.a. n.a. 6. Light aliphatic solvent naphtha (petroleum) 64742-89-8 n.a. n.a. n.a. - n.a. 12. Ecological Information General Ecological Information No information available for this product as a whole. Information below will be for individual ingredients: Toxicity: Toluene: LC50 FOR BLUEGILL WAS 17 MG/L/24 HR & 13 MG/L/96 HR Acetone: LC50 Pimephales promelas (Fathead minnow, age 33 days, length 22.6 mm, weight 0.159 g) 8,120 mg/L/96 h (95% confidence limit: 7,530-8,760 mg/L); flow through, 25.0 deg C, dissolved oxygen 6.7 mg/L, hardness 48.5 mg/L CaCO3, alkalinity 45.8 mg/L CaCO3, pH 7.58 /99% pure/ Persistence and Degradability: Toluene is readily degradable. Acetone: Based on a vapor pressure of 231 mm Hg at 25 deg C, acetone is expected to exist solely as a vapor in the ambient atmosphere. Vapor -phase acetone is degraded in the atmosphere by reaction with photochemically-produced hydroxyl radicals with an estimated atmospheric half-life of about 79 days. Acetone also undergoes photodecomposition by sunlight with an estimated half-life of about 80 days. Bioaccumulative Potential: Methanol is not expected to bioaccumulate in the environment. Toluene: Bioaccumulation is low to moderate. Acetone: Volatilization from moist soil surfaces is also expected based upon the measured Henry's Law constant of 3.97X10-5 atm -cu mmol. This compound is expected to biodegrade under aerobic and anaerobic conditions based upon the results of numerous screening tests. If released into water, acetone is not expected to adsorb to suspended solids or sediment based upon its estimated Koc value. Methyl ethyl ketone may volatilize from dry soil surfaces based upon its vapor pressure. Mobility in Soil: Methanol is expected to have very high mobility in soil. Toluene is expected to have high to moderate mobility in soil. Acetone is expected to have very high mobility in soils. Other Adverse Effects: No data available. Licensed to W.M. Barr and Company GHS format SAFETY DATA SHEET Lacquer Thinner 13. Disposal Considerations Waste Disposal Method Dispose of in accordance with all applicable local, state, and federal regulations. 14. Transport Information LAND TRANSPORT (US DOT) DOT Proper Shipping Name Paint Related Material DOT Hazard Class: 3 DOT Hazard Label: FLAMMABLE LIQUID UN/NA Number: UN1263 Packing Group: II Additional Transport Information For D.O.T. information, contact W.M. Barr Technical Services at 1-800-398-3892. Page: 8 Printed: 07/24/2012 Revision: 06/08/2011 Supercedes Revision: 05/21/2009 The shipper/supplier may apply one of the following exceptions: Combustible Liquid, Consumer Commodity, Limited Quantity, Viscous Liquid; Does Not Sustain Combustion, or others, as allowed under 49CFR Hazmat Regulations. Please consult 49CFR Subchapter C to ensure that subsequent shipments comply with these exceptions. 15. Regulatory Information US EPA SARA Title Ill Hazardous Components (Chemical Name) CAS # Sec.302 (EHS) Sec.304 RQ Sec.313 (TRI) Sec.110 1. Methanol {Methyl alcohol; Carbinol; Wood 67-56-1 No Yes 5000 LB Yes No alcohol) 2. Toluene {Benzene, Methyl-; Toluol) 108-88-3 No Yes 1000 LB Yes Yes 3. Acetone (2-Propanone} 67-64-1 No Yes 5000 LB No Yes 4. Ethanol, 2-Butoxy- {Ethylene glycol n -butyl 111-76-2 No No Yes -Cat. N230 No ether, (a glycol ether)) 5. Acetic acid, ethyl ester {Ethyl acetate) 141-78-6 No Yes 5000 LB No No 6. Light aliphatic solvent naphtha (petroleum) 64742-89-8 No No No No US EPA CAA, CWA, TSCA Hazardous Components (Chemical Name) CAS # EPA CAA EPA CWA NPDES EPA TSCA CA PROP 65 1. Methanol {Methyl alcohol; Carbinol; Wood 67-56-1 HAP, ODC 0 No Inventory Yes alcohol) 2. Toluene {Benzene, Methyl-; Toluol) 108-88-3 HAP, ODC () Yes Inventory, 8A CAIR Yes 3. Acetone {2-Propanone} 67-64-1 HAP, ODC 0 No Inventory, 4 Test No 4. Ethanol, 2-Butoxy- {Ethylene glycol n -butyl 111-76-2 HAP, ODC () No Inventory No ether, (a glycol ether)) 5. Acetic acid, ethyl ester {Ethyl acetate) 141-78-8 HAP, ODC 0 No Inventory, 4 Test No 6. Light aliphatic solvent naphtha (petroleum) 64742-89-8 HAP, ODC 0 No Inventory No EPA Hazard Categories: This material meets the EPA 'Hazard Categories' defined for SARA Title III Sections 311/312 as indicated: [X] Yes [ ] No Acute (immediate) Health Hazard [X] Yes [ ] No Chronic (delayed) Health Hazard [X] Yes [ ] No Fire Hazard [ ] Yes [X] No Sudden Release of Pressure Hazard [ ] Yes [X] No Reactive Hazard Licensed to W.M. Barr and Company GHS format • SAFETY DATA SHEET Lacquer Thinner 16. Other Information Page: 9 Printed: 07/24/2012 Revision: 06/08/2011 Supercedes Revision: 05/21/2009 Company Policy or Disclaimer The information contained herein is presented in good faith and believed to be accurate as of the effective date shown above. This information is furnished without warranty of any kind. Employers should use this information only as a supplement to other information gathered by them and must make independent determination of suitability and completeness of information from all sources to assure proper use of these materials and the safety and health of employees. Any use of this data and information must be determined by the user to be in accordance with applicable federal, state and local laws and regulations. Licensed to W.M. Barr and Company GHS format Product Code: Product Name: Manufacturer Information Company Name: Phone Number: Emergency Contact: Information: Web site address: Preparer Name: Synonyms CKPT94402, DKPT94403, EKPT94401, GKPT94002, GKPT94002P, GKPT94400, GPT1KS, QKPT94003, QKPT94203, QPT1KS, QPT720, QKPC94001, GKPT94002L, QKPC94001L, QKPT94003L 2. Composition/Information on Ingredients MATERIAL SAFETY DATA SHEET Paint Thinner HEALTH * 1 FLAMMABILITY 2 PHYSICAL HAZ. 0 PPE C Flammability Instability Health Special 1. Product and Company Identification 1677.8 Paint Thinner W. M. Barr 2105 Channel Avenue Memphis, TN 38113 (901)775-0100 3E 24 Hour Emergency Contact W.M. Barr Customer Service www.wmbarr.com W.M. Barr and Company, Inc. Page: 1 Printed: 12/31/2008 Revision: 11/13/2008 Supercedes Revision: 09/25/2008 Date Created: 11/09/2005 (800)451-8346 (800)398-3892 (901)775-0100 Hazardous Components (Chemical Name) 1. Stoddard solvent {Mineral spirits; Aliphatic Petroleum Distillates; White spirits} CAS # Concentration OSHA PEL ACGIH TWA ACGIH STEL 8052-41-3 95.0 -100.0 % 500 ppm 100 ppm 250 ppm 3. Hazards Identification Emergency Overview Caution! Combustible. Keep away from heat, sparks, flame and all other sources of ignition. Vapors may cause fire. Vapors may travel long distances to other areas and rooms away from work site. Do not smoke. Extinguish all flames and pilot lights, and turn off stoves, heaters, electric motors and all other sources of ignition anywhere in the structure, dwelling or building during use and until all vapors are gone from work site and all areas away from work site. Keep away from electrical outlets and switches. Beware of static electricity that may be generated by synthetic clothing and other sources. OSHA Regulatory Status: This material is classified as hazardous under OSHA regulations. Potential Health Effects (Acute and Chronic) Inhalation Acute Exposure Effects: May cause dizziness; headache; watering of eyes; eye irritation; weakness; nausea; muscle twitches, and depression of central nervous system. Severe overexposure may cause convulsions; unconsciousness; and death. Intentional misuse of this product by deliberately concentrating and inhaling can be harmful or fatal. Skin Contact Acute Exposure Effects: May cause irritation; numbness in the fingers and arms; drying of skin; and dermatitis. May cause increased severity of symptoms listed under inhalation. Eye Contact Acute Exposure Effects: This material is an eye irritant. May cause irritation; burns; conjunctivitis of eyes; and corneal ulcerations of the eye. Vapors may irritate eyes. Ingestion Acute Exposure Effects: Licensed to W.M. Barr and Company RECEIVED CITY OF TUKWILA JUL 122013 ANSI Z400.1 Format DCrRRI-r r+e Aim-r-r- MATERIAL SAFETY DATA SHEET Page: 2 Paint Thinner Printed: 12/31/2008 Revision: 11/13/2008 Supercedes Revision: 09/25/2008 Harmful or fatal if swallowed. May cause nausea; weakness; muscle twitches; gastrointestinal irritation; and diarrhea. Severe overexposure may cause convulsions; unconsciousness; and death. Chronic Exposure Effects: Reports have associated repeated and prolonged overexposure to solvents with neurological and other physiological damage. Prolonged or repeated contact may cause dermatitis. May cause jaundice; bone marrow damage; liver damage; anemia; and skin irritation. Signs and Symptoms Of Exposure Inhalation, ingestion, and dermal are possible routes of exposure. Medical Conditions Generally Aggravated By Exposure Diseases of the skin, eyes, liver, kidneys, central nervous system and respiratory system. 4. First Aid Measures Emergency and First Aid Procedures Inhalation: If user experiences breathing difficulty, move to air free of vapors, Administer oxygen or artificial medical assistance can be rendered. Skin Contact: Wash with soap and large quantities of water and seek medical attention if irritation from contact persists. Eye Contact: Flush with large quantities of water for at least 15 minutes and seek immediate medical attention. Ingestion: Do not induce vomiting. Call your local poison control center, hospital emergency room or physician immediately for instructions to induce vomiting. If spontaneous vomiting is about to occur,place victim's head below knees. If victim is drowsy or unconscious, place on the left side with head down. Never give anything by mouth to a person who is not fully conscious. Do not leave victim unattended. Seek medical attention immediately. Note to Physician Call your local poison control center for further information. Inhalation: Inhalation overexposure can produce toxic effects. Monitor for respiratory distress. If cough or difficulty in breathing develops, evaluate for upper respiratory tract inflammation, bronchitis, and pneumonitis. Administer supplemental oxygen with assisted ventilation as required. Ingestion: If ingested, this material presents a significant aspiration and chemical pneumonitis hazard. Induction of emesis is not recommended. Consider activated charcoal and/or gastric lavage. If patient is obtunded, protect the airway by cuffed endotracheal intubation or by placement of the body in a Trendelenburg and left lateral decubitus position. Flammability Classification: Flash Pt: Explosive Limits: Autoignition Pt: 5. Fire Fighting Measures Class II >= 101.00 F Method Used: Setaflash Closed Cup (Rapid Setaflash) LEL: — 0.5 % UEL: — 6 % 446.00 F • Licensed to W.M. Barr and Company ANSI Z400.1 Format MATERIAL SAFETY DATA SHEET Paint Thinner Page: 3 Printed: 12/31/2008 Revision: 11/13/2008 Supercedes Revision: 09/25/2008 Fire Fighting Instructions Self-contained respiratory protection should be provided for fire fighters fighting fires in buildings or confined areas. Storage containers exposed to fire should be kept cool with water spray to prevent pressure build-up. Stay away from heads of containers that have been exposed to intense heat or flame. Flammable Properties and Hazards Combustible Liquid. Hazardous Combustion Products Carbon dioxide, carbon monoxide, smoke, fumes, and/or unburned hydrocarbons. Extinguishing Media Use carbon dioxide, dry powder, or foam. Unsuitable Extinguishing Media No data available. 6. Accidental Release Measures Steps To Be Taken In Case Material Is Released Or Spilled Clean up: Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind, out of low areas, and ventilate closed spaces before entering. Shut off ignition sources; keep flares, smoking or flames out of hazard area. Small spills: Take up with sand, earth or other noncombustible absorbent material and place in a plastic container where applicable. Large spills: Dike far ahead of spill for later disposal. Waste Disposal: Dispose in accordance with applicable local, state and federal regulations. 7. Handling and Storage Precautions To Be Taken in Handling Read carefully all cautions and directions on product label before use. Since empty container retains residue, follow all label warnings even after container is empty. Dispose of empty container according to all regulations. Do not reuse this container. A static electrical charge can accumulate when this material is flowing through pipes, nozzles or filters, and when it is agitated. A static spark discharge can ignite accumulated vapors particularly during dry weather conditions. Always use proper bonding and grounding procedures. Precautions To Be Taken in Storing Keep container tightly closed when not in use. Store in a cool, dry place. Do not store near flames or at elevated temperatures. Licensed to W.M. Barr and Company ANSI Z400.1 Format MATERIAL SAFETY DATA SHEET Paint Thinner Page: 4 Printed: 12/31/2008 Revision: 11/13/2008 Supercedes Revision: 09/25/2008 8. Exposure Controls/Personal Protection Respiratory Equipment (Specify Type) For OSHA controlled work place and other regular users. Use only with adequate ventilation under engineered air control systems designed to prevent exceeding appropriate TLV. For occasional use, where engineered air control is not feasible, use properly maintained and properly fitted NIOSH approved respirator for organic solvent vapors. A dust mask does not provide protection against vapors. Eye Protection Safety glasses, goggles or face shields are recommended to safeguard against potential eye contact, irritation, or injury. Contact lenses should not be worn while working with chemicals. Protective Gloves Wear impermeable gloves. Gloves contaminated with product should be discarded. Promptly remove clothing that becomes soiled with product. Other Protective Clothing Various application methods can dictate use of additional protective safety equipment, such as impermeable aprons, etc., to minimize exposure. Before reuse, thoroughly clean any clothing or protective equipment that has been contaminated by prior use. Discard any clothing or other protective equipment that cannot be decontaminated, such as gloves or shoes. Engineering Controls (Ventilation etc.) Use only with adequate ventilation to prevent build-up of vapors. Open all windows and doors. Use only with a cross ventilation of moving fresh air across the work area. If strong odor is noticed or you experience slight dizziness, headache, nausea, or eye -watering - Stop - ventilation is inadequate. Leave area immediately. Work/Hygienic/Maintenance Practices A source of clean water should be available in the work area for flushing eyes and skin. Do not eat, drink, or smoke in the work area. Wash hands thoroughly after use. 9. Physical and Chemical Properties Physical States: Melting Point: Boiling Point: Autoignition Pt: Flash Pt: Explosive Limits: Specific Gravity (Water = 1): Vapor Pressure (vs. Air or mm Hg): Vapor Density (vs. Air = 1): Evaporation Rate (vs Butyl Acetate=l ): Solubility in Water: Solubility Notes Very slightly soluble in cold wa Percent Volatile: VOC / Volume: Corrosion Rate: pH: Appearance and Odor Water White / Free and Clear [ ] Gas [ X ] Liquid [ ] Solid No data. 298.00 F - 400.00 F 446.00 F >= 101.00 F Method Used: Setaflash Closed Cup (Rapid Setaflash) LEL: — 0.5 % UEL: — 6 % 0.78 0.22 MM HG at 68.0 F 4.7 No data. No data. ter. 100.0 % by weight. 784.0000 G/L No data. No data. Licensed to W.M. Barr and Company ANSI Z400.1 Format 1 ). MATERIAL SAFETY DATA SHEET Paint Thinner Page: 5 Printed: 12/31/2008 Revision: 11/13/2008 Supercedes Revision: 09/25/2008 10. Stability and Reactivity Stability: Unstable [ ] Stable [ X ] Conditions To Avoid - Instability No data available. Incompatibility - Materials To Avoid Incompatible with strong acids, alkalies, and oxidizers such as liquid chlorine and oxygen. Hazardous Decomposition Or Byproducts Decomposition may produce carbon monoxide and carbon dioxide. Hazardous Polymerization: Will occur [ ] Will not occur [ X ] Conditions To Avoid - Hazardous Polymerization No data available. No data available. Carcinogenicity/Other Information No data available. Hazardous Components (Chemical Name) 1. Stoddard solvent {Mineral spirits; Aliphatic Petroleum Distillates; White spirits} No data available. 11. Toxicological Information CAS # NTP 8052-41-3 n.a. IARC- n.a. ARC n.a. 12. Ecological Information 13. Disposal Considerations Waste Disposal Method Dispose in accordance with federal, state, and local regulations. 14. Transport Information LAND TRANSPORT (US DOT) DOT Proper Shipping Name Paint Related Material, Not Regulated Additional Transport Information For D.O.T. information, contact W.M. Barr Technical Services at 1-800-398-3892. ACGIH n.a. OSHA n.a. The supplier may apply one of the following exceptions: Combustible Liquid, Consumer Commodity, Limited Quantity, Viscous Liquid, Does Not Sustain Combustion, or others, as allowed under 49CFR Hazmat Regulations. Please consult 49CFR Subchapter C to ensure that subsequent shipments comply with these exceptions. 15. Regulatory Information US EPA SARA Title Ill Hazardous Components (Chemical Name) CAS # Sec.302 (EHS) Sec.304 RQ Sec.313 (TRI) Sec.110 1. Stoddard solvent {Mineral spirits; Aliphatic 8052-41-3 No No No No Petroleum Distillates; White spirits) SARA (Superfund Amendments and Reauthorization Act of 1986) Lists: Sec.302: EPA SARA Title III Section 302 Extremely Hazardous Chemical with TPQ. * indicates 10000 LB TPQ if not volatile. Sec.304: EPA SARA Title III Section 304: CERCLA Reportable + Sec.302 with Reportable Quantity. ** indicates statutory RQ. Sec.313: EPA SARA Title III Section 313 Toxic Release Inventory. Note: -Cat indicates a member of a chemical category. Licensed to W.M. Barr and Company ANSI Z400.1 Format MATERIAL SAFETY DATA SHEET Paint Thinner Page: 6 Printed: 12/31/2008 Revision: 11/13/2008 Supercedes Revision: 09/25/2008 Sec.110: EPA SARA 110 Superfund Site Priority Contaminant List EPA Hazard Categories: This material meets the EPA 'Hazard Categories' defined for SARA Title III Sections 311/312 as indicated: [X] Yes [ ] No Acute (immediate) Health Hazard [X] Yes [ ] No Chronic (delayed) Health Hazard [ ] Yes [X] No Fire Hazard [ ] Yes [X] No Sudden Release of Pressure Hazard [ ] Yes [X] No Reactive Hazard 16. Other Information Company Policy or Disclaimer The information contained herein is presented in good faith and believed to be accurate as of the effective date shown above. This information is furnished without warranty of any kind. Employers should use this information only as a supplement to other information gathered by them and must make independent determination of suitability and completeness of information from all sources to assure proper use of these materials and the safety and health of employees. Any use of this data and information must be determined by the user to be in accordance with applicable federal, state and local laws and regulations. Licensed to W.M. Barr and Company ANSI Z400.1 Format A • q Material Safety Data Sheet Prepared in accordance with ISO 11014-1/ANSI standard Z400.1-2004 Print Date Oct -24-2012 Revision Date Oct -24-2012 RODt+JGTN©OIRN,Y �IDIrtCATOI Product code Product name Product category Manufacturer or supplier's UNITED STATES Nazdar Company 8501 Hedge Lane Terrace Shawnee, KS 66227 Tel: 1-913-422-1888 Tel: 1-800-677-4657 Fax: 1-913-422-2294 details PA7 Thinner PA Series Poly -All Screen Ink UNITED KINGDOM Nazdar Limited Barton Road Heaton Mersey Stockport, England SK4 3EG Tel: +44 161 442 2111 Emergency Telephone Number USA: Chemtrec: 1-800-424-9300 Outside USA: Chemtrec: 1-703-527-3887 Website: www.nazdar.com MSDS Information: 1-913-422-1888 ext 2305 MSDS Contact: Regulatory Compliance email: regcomp@nazdar.com • r. .:,,:vx�. RDSIDEITIFI'CATLONs This product is a preparation. Health Appearance Flammable Properties Emergency Overview Eyes Skin Inhalation Ingestion hazard information is based on its components. Water -white Combustible liquid and vapor. Aspiration hazard. Harmful: may cause lung damage if swallowed. Irritant. May cause drowsiness and dizziness. Causes eye irritation. May cause skin irritation and/or dermatitis. May cause irritation of respiratory tract. Inhalation of high vapour concentrations may cause symptoms like headache, dizziness, tiredness, nausea and vomiting. Harmful if swallowed. Potential for aspiration if swallowed. Risk of serious damage to the lungs (by aspiration). ',OMPOSITI ON/INFO.RM1T1 OI (.INGREDIENT; Component CAS -No Weight % Naphtha (petroleum), heavy aromatic 64742-94-5 60 - 100 Naphthalene (contaminant) 91-20-3 5 - 10 1,2,4-Trimethylbenzene (contaminant) 95-63-6 1 - 5 • Component names which have the word (contaminant) are constituents contained in Aromatic Hydrocarbon ingredients and are an integral part of the ingredient and cannot be separated. The percentage listed for the contaminant is as contained in the Hydrocarbon ingredient. (Example: 100% Hydrocarbon, 10% Contaminant A, 3% Contaminant B) ;-*C LSTCAID1MEASURES Eye Contact Skin Contact Inhalation Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get medical attention immediately if irritation develops and persists. Wash off immediately with soap and plenty of water. Use a mild soap if available. Rinse immediately with plenty of water for at least 15 minutes. Remove contaminated clothing. If irritation develops, get medical attention. If breathed in, move person into fresh air. If breathing is irregular or sto ikkAu EtD artificial respiration. Get medical attention immediately. CITY OF TUKWILA JUL 1 1 2013 Page/16 PERMIT CENTER Product code PA7 - Thinner A V Revision Date Oct -24-2012 I' Ingestion If swallowed, DO NOT induce vomiting. Call a physician or Poison Control Centre immediately. Never give anything by mouth to an unconscious person. :yJ IRETIGHTINGINIEASURESt Flammable Properties Combustible liquid and vapor. Suitable Extinguishing Media Foam. Carbon dioxide (CO2). Dry chemical. Water spray. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure -demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Keep away from fire, sparks and heated surfaces. Cool containers / tanks with water spray. Fire or intense heat may cause violent rupture of packages. Specific Hazards Arising from the Thermal decomposition can lead to release of irritating gases and vapours. Burning produces obnoxious and toxic fumes. Chemical .tYSpputt NE EAsu RES Personal Precautions Methods for Cleaning Up Environmental Precautions Handling Storage Remove all sources of ignition. Ventilate the area. Avoid breathing dust or vapor. Avoid contact with skin, eyes and clothing. Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13). Do not use sparking tools. Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. �NDL�NG�AND`�STORiAG Avoid contact with skin, eyes and clothing. Ensure adequate ventilation. Remove and wash contaminated clothing before re -use. Discard contaminated shoes. When using do not smoke. Do not take internally. Harmful or fatal if swallowed. Take notice of the directions of use on the label. Keep containers tightly closed in a dry, cool and well -ventilated place. Keep container closed when not in use. Keep out of the reach of children. Keep away from heat and sources of ignition. OSURECONTROLS/P,ERSONAj ';PROTECTT101 3 Exposure Guidelines Component ACGIH TLV OSHA PEL NIOSH IDLH Ontario TWAEV Mexico OEL (TWA) Naphthalene (contaminant) TWA: 10 ppm STEL: 15 ppm Skin TWA: 10 ppm TWA: 50 mg/m3 STEL: 15 ppm STEL: 75 mg/m3 250 ppm TWA: 10 ppm STEL: 15 ppm Skin TWA/LMPE-PPT: 10 ppm TWA/LMPE-PPT: 50 mg/m3 STEULMPE-CT: 15 ppm STEULMPE-CT: 75 mg/m3 Engineering Measures Personal Protective Equipment Use ventilation adequate to keep exposures below recommended exposure limits. See MSDS. In case of insufficient ventilation, wear suitable respiratory equipment. • ' 2r 7 ;Page 2 16 1 Product code PA7 - Thinner Revision Date Oct -24-2012 Respiratory Protection Eye Protection Skin Protection General Hygiene Considerations Use the indicated respiratory protection if the occupational exposure limit is exceeded and/or in case of product release (dust). Respirator with a vapour filter. Ensure that eyewash stations and safety showers are close to the workstation location. Avoid contact with eyes. Safety glasses with side -shields. Goggles. Face -shield. Wear protective gloves/clothing. Solvent -resistant apron and boots. Handle in accordance with good industrial hygiene and safety practice. Wash hands before eating, drinking, or smoking. Remove and wash contaminated clothing before re -use. Avoid contact with skin, eyes and clothing. Wear suitable gloves and eye/face protection. Regular cleaning of equipment, work area and clothing is recommended. 0,3 .. •i:�uji,.+a: %t :�. P Y IY„SIC'Ae,kr HEMICpL PROPERTIE Appearance Odor pH Boiling point/Boiling Range Freezing Point/Range Evaporation Rate Vapour Pressure Flammability (solid, gas) Water -white Characteristic No information available >149 °C / >300 °F No information available No information available No information available No information available Flash Point 61 °C / 142 °F Method Tag closed cup Weight Per Gallon (lbs/gal) 7.49 VOC by weight % (less water) 100 VOC lbs/gal (less water) 7.49 Physical State Odor Threshold Autoignition Temperature Melting Point/Range Solubility Partition Coefficient (n-octanol/water) Vapour Density Liquid No information available No information available No information available No information available No information available Heavier than air Flammability Limits in Air Upper No information available Lower 1.0 Photochemically Reactive Yes Specific Gravity 0.9 VOC by volume % (less water)100 VOC grams/liter (less water) 897.46 alp �,1 19tiiil+tq}' TAB'ItLITY AND'REA'CTIV1 SY Chemical Stability Conditions to Avoid Stable under normal conditions. Heat, flames and sparks. Incompatible Products Strong acids. Strong bases. Strong oxidizing agents. Reducing agents. Hazardous Decomposition Products Thermal decomposition can lead to release of irritating gases and vapours. Carbon dioxide (CO2). Carbon monoxide. Possibility of Hazardous Reactions None under normal processing. Acute Toxicity is .'ai.•sZiT.`Stvtla .. _ .bi..tu .'uc:t:.::rP..,f..,et.. 11'140X1 C°LOG CAI INFORMA4AT1< Component LD50 Oral LD50 Dermal LC50 Inhalation Naphtha (petroleum), heavy aromatic >5000 mg/kg ( Rat) >2000 mg/kg ( Rabbit) >590 mg/m3 ( Rat) 4 h Naphthalene (contaminant) 490 mg/kg ( Rat) >2500 mg/kg ( Rat) >20 g/kg ( Rabbit ) >340 mg/m3 ( Rat) 1 h 1,2,4-Trimethylbenzene (contaminant) 3400 mg/kg ( Rat) >3160 mg/kg ( Rabbit) 18 g/m3 ( Rat ) 4 h Page 3/6 Product code PA7 - Thinner Revision Date Oct -24-2012 Chronic Toxicity Component ACGIH IARC NTP OSHA Naphthalene (contaminant) 96h LC50 Oncorhynchus mykiss: Group 2B Reasonably Anticipated X IARC: (International Agency for Research on Cancer) NTP: (National Toxicity Program) OSHA: (Occupational Safety & Health Administration) Sensitisation Mutagenic Effects Reproductive Effects Developmental hazard Teratogenicity Chronic Effects Target Organ Effects Group 2B - Possibly Carcinogenic to Humans Reasonably Anticipated to be a Human Carcinogen X - Present No information available No information available No information available No information available No information available Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may result in adverse health effect, such as mucous membrane and respiratory system irritation and adverse effect on kidney, liver and central nervous system. Blood, Central nervous system, Eyes, Kidney, Liver, Respiratory system, Skin. 2.' ECOLOGICAL ;INFORMAT1I Ni Ecotoxicity We have no quantitative data concerning the ecological effects of this product. Should not be released into the environment. Component Algae Fish Water Flea Naphthalene (contaminant) 72h EC50 Skeletonema costatum: 96h LC50 Oncorhynchus mykiss: 48h EC50 Daphnia magna: 1.09 - 3.4 0.4 mg/L 0.91 - 2.82 mg/L [static] mg/L [static] 96h LC50 Pimephales promelas: 48h EC50 Daphnia magna: 1.96 mg/L 5.74 - 6.44 mg/L [flow-through] [Flow through] 96h LC50 Oncorhynchus mykiss: 48h LC50 Daphnia magna: 2.16 mg/L 1.6 mg/L [flow-through] 96h LC50 Pimephales promelas: 1.99 mg/L [static] 96h LC50 Lepomis macrochirus: 31.0265 mg/L [static] 1,2,4-Trimethylbenzene 96h LC50 Pimephales promelas: 48h EC50 Daphnia magna: 6.14 mg/L (contaminant) 7.19 - 8.28 mg/Liflow-through] Persistence and Degradability No information available Bioaccumulation No information available Mobility in Environmental Media No information available Component log Pow Naphtha (petroleum), heavy aromatic 4.5 Naphthalene (contaminant) 3.3 1,2,4-Trimethylbenzene (contaminant) 3.63 Er. 44 Ii3DQISPOS�L�CO�tS1;DERATI�ON Waste Disposal Methods Contaminated Packaging Dispose of contents/container in accordance with local regulation. Empty containers should be taken to an approved waste handling site for recycling or disposal. NSP;OITIIFQtAl1AT10N�• DOT Printing Ink Related Material, Liquid, Not Regulated ICAO/IATA Page 416 Product code PA7 - Thinner Revision Date Oct -24-2012 Not classified as dangerous in the meaning of transport regulations IMDG/IMO Not classified as dangerous in the meaning of transport regulations GPLAT OR INFORMATI International Inventories Listed on TSCA. For further information, please contact: Manufacturer, importer, supplier U.S. Federal Regulations SARA 313 The following components are Component CAS -No Weight /o SARA 313 - Threshold 91-20-3 5 - 10 X Values Naphthalene (contaminant) 91-20-3 5 - 10 0.1 1,2,4-Trimethylbenzene (contaminant) 95-63-6 1 - 5 1.0 Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) Component CAS -No Weight % Naphthalene (contaminant) 91-20-3 5 - 10 U.S. State Regulations Component Massachusetts Right To Know Minnesota Right To Know New Jersey Right To Know Pennsylvania Right To Know Naphthalene (contaminant) X X X X 1,2,4-Trimethylbenzene (contaminant) X X X X California Prop. 65 WARNING! This product contains a chemical known in the State of California to cause cancer and / or WARNING! This product contains a chemical known in the State of • Component CAS -No Weight % Naphthalene (contaminant) 91-20-3 5 - 10 Canada This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the information required by the CPR Component WHMIS Classifications of Components Naphthalene (contaminant) B4,D2A 1,2,4-Trimethylbenzene (contaminant) B3 Component NPRI - National Pollutant Release Inventory Naphtha (petroleum), heavy aromatic Part 5 Substance Part 5, Other Groups and Mixtures Naphthalene (contaminant) Part 1, Group 1 Substance 1,2,4-Trimethylbenzene (contaminant) Part 4 Substance Part 1, Group 1 Substance Part 5, Individual Substance Regulation (EC) No. 1907/2006 (REACH), Article 57 This product does not contain substances of very high concern (Regulation (EC) No. 1907/2006 (REACH), Article 57) HMIS: Health Flammability Reactivity 2* 2 0 PPE X Page 5/6 Product code PA7 - Thinner Revision Date Oct -24-2012 �rvLs+�ia. xS Cr. arx iRtte t07�t�1�!1�0 Revision Date Revision Note Oct -24-2012 New MSDS format Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text End of MSDS Page 6 / 6 Material Safety Data Sheet Prepared in accordance with ISO 11014-1/ANSI standard Z400.1-2004 Print Date Oct -27-2010 Revision Date Oct -27-2010 RODUCT iD COMPANY O,DENTiFICATIC Product code Product name Product description Manufacturer or supplier's details UNITED STATES Nazdar Company 8501 Hedge Lane Terrace Shawnee, KS 66227 Tel: 1-913-422-1888 Tel: 1-800-677-4657 Fax: 1-913-422-2294 5560 Fast Thinner Ink Product UNITED KINGDOM Nazdar Limited 7 Barton Road Heaton Mersey Industrial Estate Stockport, Chesire SK4 3EG Tel: +44 161 442 2111 Emergency Telephone Number USA: Chemtrec: 1-800-424-9300 Outside USA: Chemtrec: 1-703-527-3887 Website: www.nazdar.com MSDS Information: 1-913-422-1888 ext 2305 MSDS Contact: Regulatory Compliance email: regcomp@nazdar.com 'Rps.-1DENTI This product is a preparation. Health hazard information is based on its components. Appearance Flammable Properties Emergency Overview Eyes Skin Inhalation Ingestion Water -white Combustible liquid and vapor. Aspiration hazard. Harmful: may cause lung damage if swallowed. Irritant. May cause drowsiness and dizziness. Moderately irritating to the eyes. Causes skin irritation. May cause irritation of respiratory tract. Inhalation of high vapour concentrations may cause symptoms like headache, dizziness, tiredness, nausea and vomiting. Harmful if swallowed. Potential for aspiration if swallowed. Risk of serious damage to the lungs (by aspiration). CO1V� OSITaON/INFQIVIA`oONQ EQIEl�il' Component CAS -No Weight % Petroleum naphtha, light aromatic 64742-95-6 60 - 100 1,2,4-Trimethylbenzene (contaminant) 95-63-6 30 - 60 1,3,5-Trimethylbenzene (contaminant) 108-67-8 10 - 30 Cumene (contaminant) 98-82-8 5 - 10 1.2.3-Trimethylbenzene (contaminant) 526-73-8 1 - 5 Xylenes (o-, m-, p- isomers) (contaminant) 1330-20-7 1 - 5 • Component names which have the word (contaminant) are constituents contained in Aromatic Hydrocarbon ingredients and are an integral part of the ingredient and cannot be separated. The percentage listed for the contaminant is as contained in the Hydrocarbon ingredient. (Example: 100% Hydrocarbon, 10% Contaminant A, 3% Contaminant B) IRSTSAID2 WURES: Eye Contact Skin Contact Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get medical attention immediately if irritation develops and persists. Wash off immediately with soap and plenty of water. Use a mild soap if available. Rinse immediately with plenty of water for at least 15 minutes. Remove contated clothing. If irritation develops, get medical attention. m CEIVED CITY OF TUKWILA JUL 11 2013 PERMIT CENTER b 1 3 Pa Product code 5560 - Fast Thinner Revision Date Oct -27-2010 Inhalation Ingestion Move to fresh air. If breathed in, move person into fresh air. If breathing is irregular or stopped, administer artificial respiration. Get medical attention immediately. If swallowed, DO NOT induce vomiting. Call a physician or Poison Control Centre immediately. Never give anything by mouth to an unconscious person. IRE-FIGHTINGMEASURES' Flammable Properties Suitable Extinguishing Media Protective Equipment and Precautions for Firefighters Specific Hazards Arising from the Chemical Combustible liquid and vapor. Foam. Carbon dioxide (CO2). Dry chemical. Water spray. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. As in any fire, wear self-contained breathing apparatus pressure -demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Keep away from fire, sparks and heated surfaces. Keep container tightly closed. Cool containers / tanks with water spray. Fire or intense heat may cause violent rupture of packages. Thermal decomposition can lead to release of irritating gases and vapours. Burning produces obnoxious and toxic fumes. ti IDENTAL REL, be EA$URE$; Personal Precautions Methods for Cleaning Up Environmental Precautions Remove all sources of ignition. Heat, flames and sparks. Ventilate the area. Avoid breathing dust or vapor. Avoid contact with skin, eyes and clothing. Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local 1 national regulations (see section 13). Do not use sparking tools. Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. TOI Handling Storage Avoid contact with skin, eyes and clothing. Ensure adequate ventilation. Remove and wash contaminated clothing before re -use. Discard contaminated shoes. When using do not smoke. Take notice of labels and material safety data sheets for the working chemicals. Do not take internally. Harmful or fatal if swallowed. Keep containers tightly closed in a dry, cool and well -ventilated place. Keep container closed when not in use. Keep out of the reach of children. Keep away from heat and sources of ignition. Take notice of the directions of use on the label. POSI RE CoNTRO.S/PERSONAL` PROTECTI Exposure Guidelines Component ACGIH TLV OSHA PEL NIOSH IDLH Ontario TWAEV Mexico OELITWA) 1,2,4-Trimethylbenzene (contaminant) TWA: 25 ppm TWA: 25 ppm TWA: 123 mg/m3 TWA: 125 mg/m3 TWA: 25 ppm STEL: 35 ppm STEL: 170 mg/m3 1,3,5-Trimethylbenzene (contaminant) TWA: 25 ppm TWA: 123 mg/m3 TWA: 25 ppm TWA: 125 mg/m3 TWA: 25 ppm STEL: 35 ppm STEL: 170 mq/m3 Cumene (contaminant) TWA: 50 ppm TWA: 245 mg/m3 TWA: 50 ppm Skin 900 ppm 10% LEL TWA: 50 ppm TWA: 245 mg/m3 Skin TWA: 245 mg/m3 TWA: 50 ppm STEL: 365 mg/m3 STEL: 75 ppm or .Y• Page 216-` Product code 5560 - Fast Thinner Revision Date Oct -27-2010 Component ACGIH TLV OSHA PEL NIOSH IDLH Ontario TWAEV Mexico OEL (TWA) 1,2,3-Trimethylbenzene (contaminant) TWA: 25 ppm TWA: 123 mg/m3 TWA: 25 ppm TWA: 25 ppm TWA: 125 mg/m3 STEL: 170 mq/m3 STEL: 35 ppm Xylenes (o-, m-, p- isomers) (contaminant) TWA: 100 ppm STEL: 150 ppm TWA: 100 ppm TWA: 435 mg/m3 STEL: 150 ppm STEL: 655 mq/m3 TWA: 100 ppm TWA: 435 mg/m3 STEL: 150 ppm STEL: 650 mg/m3 TWA: 435 mg/m3 TWA: 100 ppm STEL: 150 ppm STEL: 655 mg/m3 Engineering Measures Personal Protective Equipment Respiratory Protection Eye Protection Skin Protection General Hygiene Considerations Use only with adequate ventilation. Use ventilation adequate to keep exposures below recommended exposure limits. See MSDS. In case of insufficient ventilation, wear suitable respiratory equipment. Use the indicated respiratory protection if the occupational exposure limit is exceeded and/or in case of product release (dust). Respirator with a vapour filter. Ensure that eyewash stations and safety showers are close to the workstation location. Avoid contact with eyes. Safety glasses with side -shields. Goggles. Face -shield. Wear protective gloves/clothing. Solvent -resistant apron and boots. Handle in accordance with good industrial hygiene and safety practice. Ensure that eyewash stations and safety showers are close to the workstation location. Wash hands before eating, drinking, or smoking. Remove and wash contaminated clothing before re -use. Regular cleaning of equipment, work area and clothing. Avoid contact with skin, eyes and clothing. Wear suitable gloves and eye/face protection. T -v .,+ �- e�.»,i � �:Fxv «a c:s ,�.i:�h+;.:"1�cyh.�F .:., �g31A'._ .a8x�d:'a:�.n.'". rPHYSICA AND'CHEMICAI$P 2OPERTI Appearance Odor pH Boiling point/Boiling Range Freezing Point/Range Evaporation Rate Vapour Pressure Flammability (solid, gas) Flammability Limits in Air Upper No information available Lower No information available Water -white Characteristic No information available >149°C / >300°F No information available No information available No information available No information available Weight Per Gallon (lbs/gal) 7.303 VOC by weight % 100 VOC lbs/gal (less water) 7.303 Physical State Odor Threshold Autoignition Temperature Melting Point/Range Solubility Partition Coefficient (n- octanol/water) Vapour Density Liquid No information available No information available No information available No information available No information available No information available Flash Point 41°C / 105°F Method Setaflash closed cup Photochemically Reactive Specific Gravity VOC by volume % VOC grams/liter (less water) Yes 0.876 100 875.092 ,STABIL 1 :'REACTIVITY Chemical Stability Conditions to Avoid Incompatible Products Hazardous Decomposition Stable under normal conditions. Heat, flames and sparks. Strong acids. Strong bases. Strong oxidizing agents. Reducing agents. Products Thermal decomposition can lead to release of irritating gases and vapours. Carbon dioxide (CO2). Carbon monoxide. Possibility of Hazardous Reactions None under normal processing. Page 316 Product code 5560 - Fast Thinner Revision Date Oct -27-2010 XICOLOGICAL. INFORMATI; Acute Toxicity Component LD50 Oral LD50 Dermal LC50 Inhalation Petroleum naphtha, light aromatic 8400 mg/kg ( Rat) 2000 mg/kg ( Rabbit) 5.2 mg/L ( Rat) 4 h 3400 ppm ( Rat ) 4h 1,2,4-Trimethylbenzene (contaminant) 3400 mg/kg ( Rat) 8970 mg/kg ( Rat 3160 mg/kg ( Rabbit) 18 g/m3( Rat ) 4 h 1,3,5-Trimethylbenzene (contaminant) 8970 mg/kg ( Rat) 5000 mg/kg ( Rat 96 Hr LC50 Pimephales promelas: 3.48 mg/L 96 Hr LC50 Pimephales promelas: 7.72 mq/L (flow-through] 24 g/m3( Rat ) 4 h Cumene (contaminant) 1400 mg/kg ( Rat) 3160 mq/kq ( Rabbit) 39000 mg/m3( Rat) 4 h 1,2 3-Trimethylbenzene (contaminant) 8970 mg/kg ( Rat ) 96 Hr LC50 Pimephales promelas: 7.72 ma/ [flow-through] Xylenes (o-, m-, p- isomers) (contaminant) 4300 mg/kg ( Rat) 1700 mg/kg ( Rabbit) 5000 ppm ( Rat) 4 h 47635 mg/L Rat) 4 h Chronic Toxicity No information available Sensitisation Mutagenic Effects Reproductive Effects Developmental Effects Teratogenicity Chronic Effects Target Organ Effects No information available No information available No information available No information available No information available Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may result in adverse health effect, such as mucous membrane and respiratory system irritation and adverse effect on kidney, liver and central nervous system. Blood, Central nervous system, Eyes, Respiratory system, Skin. 2.;EcO. GICAL' 1NF,ORMATioN Ecotoxicity We have no quantitative data concerning the ecological effects of this product. Should not be released into the environment. Component Freshwater Algae Freshwater Fish Water Flea Petroleum naphtha, light aromatic 96 Hr LC50 Oncorhynchus mykiss: 9.22 mq/L 48 Hr EC50 Daphnia magna: 6.14 mq/L 1,2,4-Trimethylbenzene (contaminant) 96 Hr LC50 Pimephales promelas: 7.72 mq/L [flow-through] 48 Hr EC50 Daphnia magna: 6.14 mq/L 1,3,5-Trimethylbenzene (contaminant) 96 Hr LC50 Pimephales promelas: 3.48 mg/L 96 Hr LC50 Pimephales promelas: 7.72 mq/L (flow-through] 24 Hr EC50 water flea: 50 mg/L Cumene (contaminant) 72 Hr EC50 Selenastrum capricornutum: 2.6 mq/L 96 Hr LC50 Oncorhynchus mykiss: 4.8 mq/L [flow-through] 48 Hr EC50 water flea: 0.6 mg/L 1,2,3-Trimethylbenzene (contaminant) 96 Hr LC50 Pimephales promelas: 7.72 ma/ [flow-through] Xylenes (o-, m-, p- isomers) (contaminant) 96 Hr LC50 Pimephales promelas: 13.4 mg/L [flow-through]; 96 Hr LC50 Oncorhynchus mykiss: 8.05 mg/L [flow-through]; 96 Hr LC50 Lepomis macrochirus: 16.1 mg/L [flow-through]; 96 Hr LC50 Pimephales promelas: 26.7 mg/L [static 48 Hr EC50 water flea: 3.82 mg/L; 48 Hr LC50 Gammarus lacustris: 0.6 mg/L Persistence and Degradability No information available Bioaccumulation No information available Mobility in Environmental Media No information available Page 4 / 6 `1 Product code 5560 - Fast Thinner Revision Date Oct -27-2010 .o.;-,,..400,3.94630;606046004,01 *OILN; s 4 t C, Waste Disposal Methods Contaminated Packaging Dispose of contents/container in accordance with local regulation. Empty containers should be taken to an approved waste handling site for recycling or disposal. Ri4N10010lNFORMATI DOT UN1210, Printing Ink Related Material, 3, III In the U.S. and Canada, this material may be reclassified as a combustible liquid and is not regulated, via surface transportation, in containers less than 119 gallons or 450 liters [per 49 CFR 173.150 (f)] [per Transportation of Dangerous Goods Regulations/Clear Language Part 1.33]. ICAO/IATA UN1210, Printing Ink Related Material, 3, III IMDG/IMO UN1210, Printing Ink Related Material, 3, III ai � REGUL AT.ORY NF.ORMATIO. International Inventories Listed on TSCA. For further information, please contact: Manufacturer, importer, supplier U.S. Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 Component CAS -No Weight % SARA 313 - Threshold Values Xylenes (o-, m-, p- isomers) (contaminant) 1330-20-7 1 - 5 1.0 1,2,4-Trimethylbenzene (contaminant) 95-63-6 30 - 60 1.0 Cumene (contaminant) 98-82-8 5 -10 1.0 Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) This product contains the following HAPs: Component CAS -No Xylenes (o-, m-, p- isomers) (contaminant) Cumene (contaminant) 1330-20-7 Weight % 1-5 98-82-8 5-10 U.S. State Regulations California Prop. 65 WARNING! This product contains a chemical known in the State of California to cause cancer. WARNING! This product contains a chemical known in the State of California to cause birth defects or other reproductive harm. Component CAS -No Cumene (contaminant) 98-82-8 Weight % 5-10 State Right -to -Know Component Minnesota Florida New Jersey Pennsylvania Massachusetts Rhode Island Petroleum naphtha. light aromatic Not Listed Not Listed Not Listed Not Listed Not Listed Not Listed 1,2,4-Trimethylbenzene (contaminant) Not Listed Not Listed X X X X Page 5 16 Product code 5560 - Fast Thinner Revision Date Oct -27-2010 1,3,5-Trimethylbenzene (contaminant) Not Listed Not Listed X X X X Cumene (contaminant) Not Listed Not Listed X X X X 1,2,3-Trimethylbenzene (contaminant) Not Listed Not Listed X X X X Xylenes (o-, m-, p- isomers) (contaminant) Not Listed Not Listed X X X X Canada This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the information required by the CPR Component WHMIS Classifications of Components Petroleum naphtha, light aromatic B3, D2B 1,2,4-Trimethylbenzene (contaminant) B3 1,3,5-Trimethvlbenzene (contaminant) B3 Cumene (contaminant) B2 1,2,3-Trimethvlbenzene (contaminant) B3 Xylenes (o-, m-, p- isomers) (contaminant) B2, D2A, D2B Component NPRI • National Pollutant Release Inventory Petroleum naphtha, light aromatic Part_5 Substance 1,2,4-Trimethylbenzene (contaminant) Part 1, Group 1 Substance; Part 5 Substance Part 5 Substance (except 1,2,4- Trimethyl benzenel Part 4 Substance 1,3,5-Trimethvlbenzene (contaminant) Part 5 Substance (except 1.2—Trimethvl benzene) Part 4 Substance Cumene (contaminant) Part 4 Substance Part 1, Group 1 Substance 1,2,3-Trimethvlbenzene (contaminant) Part 5 Substance (except 1,2,4-Trimethyl benzene) Part 4 Substance Xylenes (o-, m-, p -isomers) (contaminant) _ Part 4 Substance Part 1, Group 1 Substance; Part 5 Substance REACH: Substances of Very High Concern (SVHC): Article 57 of Regulation (EC) No 1907/2006 Does NOT contain a listed substance HMIS: Health 2* Flammability Reactivity 2 0 PPE X Revision Date Revision Summary Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and Is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text Oct -27-2010 New MSDS format ERNFfRMQTiON End of MSDS Page 6/6 Material Safety Data Sheet Prepared In accordance with ISO 11014-1/ANSI standard 2400.1-2004 Print Date Jul -11-2012 Revision Date Jul -11-2012 Tri fr! .. RAIDD`UC'>r(AND;,C`QI PAN IDENTIFICAT)O Product code Product name Product category Manufacturer or supplier's details UNITED STATES Nazdar Company 8501 Hedge Lane Terrace Shawnee, KS 66227 Tel: 1-913-422-1888 Tel: 1-800-677-4657 Fax: 1-913-422-2294 9050 Retarder Thinner Ink Product UNITED KINGDOM Nazdar Limited Barton Road Heaton Mersey Stockport, England SK4 3EG Tel: +44 161 442 2111 Emergency Telephone Number USA: Chemtrec: 1-800-424-9300 Outside USA: Chemtrec: 1-703-527-3887 Website: www.nazdar.com MSDS Information: 1-913-422-1888 ext 2305 MSDS Contact: Regulatory Compliance email: regcomp@nazdar.com "'2,Ht1ZARD�`SWDENTIFICATION'r�'{ This product is a preparation. Health hazard information is based on its components. Appearance Flammable Properties Emergency Overview Eyes Skin Inhalation Ingestion Water -white Combustible liquid and vapor. Aspiration hazard. Harmful: may cause lung damage if swallowed. Irritant. May cause drowsiness and dizziness. Causes eye irritation. May cause skin irritation and/or dermatitis. May cause irritation of respiratory tract. Inhalation of high vapour concentrations may cause symptoms like headache, dizziness, tiredness, nausea and vomiting. Harmful if swallowed. Potential for aspiration if swallowed. Risk of serious damage to the lungs (by aspiration). �N�I?• OSITION/INFORM'ATION�;ON INGREDIENTS • • na:S$a7 .:\�ltY• Component CAS -No Weight % Naphtha (petroleum), heavy aromatic 64742-94-5 60 - 100 Naphthalene (contaminant) 91-20-3 5 - 10 1,2,4-Trimethylbenzene (contaminant) 95-63-6 1 - 5 • Component names which have the word (contaminant) are constituents contained in Aromatic Hydrocarbon ingredients and are an integral part of the ingredient and cannot be separated. The percentage listed for the contaminant is as contained in the Hydrocarbon ingredient. (Example: 100% Hydrocarbon, 10% Contaminant A, 3% Contaminant B) RSTtAI )MEASUREi" k i ;(J•'L�i.VAlSY�� .'eldl�:. Eye Contact Skin Contact Inhalation 1 Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get medical attention immediately if irritation develops and persists. Wash off immediately with soap and plenty of water. Use a mild soap if available. Rinse immediately with plenty of water for at least 15 minutes. Remove contaminated clothing. If irritation develops, get medical attention. R r ��cn If breathed in, move person into fresh air. If breathing is irregula�,orjtop etl! r'VIEDr artificial respiration. Get medical attention immediately.�L jY� OF TUKWILA JUL 11 2013 Page 1j 6 PEHMIT CENTER Product code 9050 - Retarder Thinner Revision Date Jul -11-2012 Ingestion If swallowed, DO NOT induce vomiting. Call a physician or Poison Control Centre immediately. Never give anything by mouth to an unconscious person. Flammable Properties Suitable Extinguishing Media Protective Equipment and Precautions for Firefighters Combustible liquid and vapor. Foam. Carbon dioxide (CO2). Dry chemical. Water spray. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. As in any fire, wear self-contained breathing apparatus pressure -demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Keep away from fire, sparks and heated surfaces. Cool containers / tanks with water spray. Fire or intense heat may cause violent rupture of packages. Specific Hazards Arising from the Thermal decomposition can lead to release of irritating gases and vapours. Burning produces obnoxious and toxic fumes. Chemical oho .‘"Z`,.7'16q•"Heal y r ri NTAV RIELEASE xM iseSgUREST„� Personal Precautions Methods for Cleaning Up Environmental Precautions Remove all sources of ignition. Ventilate the area. Avoid breathing dust or vapor. Avoid contact with skin, eyes and clothing. Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13). Do not use sparking tools. Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. 'i MA DL•g, •' t. Handling Storage Avoid contact with skin, eyes and clothing. Ensure adequate ventilation. Remove and wash contaminated clothing before re -use. Discard contaminated shoes. When using do not smoke. Do not take internally. Harmful or fatal if swallowed. Take notice of the directions of use on the label. Keep containers tightly closed in a dry, cool and well -ventilated place. Keep container closed when not in use. Keep out of the reach of children. Keep away from heat and sources of ignition. . � rrxnwctf^+K+n-•n� ie� � tr�•ro+� -n t^ ps'�. ro � .vy �,.v....s-.v.i. 8: �E�XPOS,�U�tEfCONT�ROLS/P�ERS.ONAL rte. PROTECTION Exposure Guidelines Component ACGIH TLV OSHA PEL NIOSH IDLH Ontario TWAEV Mexico OEL (TWA) Naphthalene (contaminant) TWA: 10 ppm STEL: 15 ppm Skin TWA: 10 ppm TWA: 50 mg/m3 STEL: 15 ppm STEL: 75 mg/m3 250 ppm TWA: 10 ppm STEL: 15 ppm Skin TWA/LMPE-PPT: 10 ppm TWA/LMPE-PPT: 50 mg/m3 STEL/LMPE-CT: 15 ppm STEL/LMPE-CT: 75 mg/m3 Engineering Measures Use ventilation adequate to keep exposures below recommended exposure limits. See MSDS. In case of insufficient ventilation, wear suitable respiratory equipment. Personal Protective Equipment • • ..• .. Rage 2 / 6, r Product code 9050 - Retarder Thinner Revision Date Jul -11-2012 Respiratory Protection Eye Protection Skin Protection General Hygiene Considerations Use the indicated respiratory protection if the occupational exposure limit is exceeded and/or in case of product release (dust). Respirator with a vapour filter. Ensure that eyewash stations and safety showers are close to the workstation location. Avoid contact with eyes. Safety glasses with side -shields. Goggles. Face -shield. Wear protective gloves/clothing. Solvent -resistant apron and boots. Handle in accordance with good industrial hygiene and safety practice. Wash hands before eating, drinking, or smoking. Remove and wash contaminated clothing before re -use. Avoid contact with skin, eyes and clothing. Wear suitable gloves and eye/face protection. Regular cleaning of equipment, work area and clothing is recommended. 4. f.ptW-'flTh31..af 4Yi'`•'x2+ 'r' -i i ? '.liay'•=.I:,.fH; s.iN.�..' MMt 9� PF;iYSICAL-"ANDGifkOitOgiC OPERTIES Appearance Odor pH Boiling point/Boiling Range Freezing Point/Range Evaporation Rate Vapour Pressure Flammability (solid, gas) Water -white Characteristic No information available >149 °C / >300 °F No information available No information available No information available No information available Flash Point 61 °C / 142 °F Method Tag closed cup Weight Per Gallon (lbs/gal) 7.49 VOC by weight % 100 VOC lbs/gal (less water) 7.49 Physical State Odor Threshold Autoignition Temperature Melting Point/Range Solubility Partition Coefficient (n-octanol/water) Vapour Density Liquid No information available No information available No information available No information available No information available Heavier than air Flammability Limits in Air Upper No information available Lower 1.0 Photochemically Reactive Yes Specific Gravity 0.9 VOC by volume % 100 VOC grams/liter (less water) 897.46 .STABILIP -CTIVITY Chemical Stability Conditions to Avoid Incompatible Products Stable under normal conditions. Heat, flames and sparks. Strong acids. Strong bases. Strong oxidizing agents. Reducing agents. Hazardous Decomposition Products Thermal decomposition can lead to release of irritating gases and vapours. Carbon dioxide (CO2). Carbon monoxide. Possibility of Hazardous Reactions None under normal processing. '.;K.44.4, •. - eri�✓�aS.._.;s.'. 3 '.A d -z " A - \ 1`" '1�7' 4. 4.&411,,, 1 xhTOXICOLOGICAL:INF;ORMATIONi Acute Toxicity Component LD50 Oral LD50 Dermal LC50 Inhalation Naphtha (petroleum), heavy aromatic >5000 mg/kg ( Rat) >2000 mg/kg ( Rabbit) >590 mg/m3 ( Rat) 4 h Naphthalene (contaminant) 490 mg/kg ( Rat) >2500 mg/kg ( Rat) >20 g/kg ( Rabbit ) >340 mg/m3 ( Rat) 1 h 1,2,4-Trimethylbenzene (contaminant) 3400 mg/kg ( Rat) >3160 mg/kg ( Rabbit) 18 g/m3 ( Rat ) 4 h Page 3/6 Product code 9050 - Retarder Thinner Revision Date Jul -11-2012 Chronic Toxicity Component ACGIH IARC NTP OSHA Naphthalene (contaminant) 96h LC50 Lepomis macrochirus: 1740 mg/L [static] 96h LC50 Pimephales promelas: 19 mg/L [static] 96h LC50 Pimephales promelas: 41 mg/L 96h LC50 Pimephales promelas: 45 mg/L [flow-through] Group 2B Reasonably Anticipated X IARC: (International Agency for Research on Cancer) NTP: (National Toxicity Program) OSHA: (Occupational Safety & Health Administration) Sensitisation Mutagenic Effects Reproductive Effects Developmental hazard Teratogenicity Chronic Effects Target Organ Effects Group 28 - Possibly Carcinogenic to Humans Reasonably Anticipated to be a Human Carcinogen X - Present No information available No information available No information available No information available No information available Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may result in adverse health effect, such as mucous membrane and respiratory system irritation and adverse effect on kidney, liver and central nervous system. Blood, Central nervous system, Eyes, Kidney, Liver, Respiratory system, Skin. #4040'1041. 00.100.4-i Ecotoxicity We have no quantitative data concerning the ecological effects of this product. Should not be released into the environment. Component Algae Fish Water Flea Naphtha (petroleum), heavy aromatic 3.3 96h LC50 Lepomis macrochirus: 1740 mg/L [static] 96h LC50 Pimephales promelas: 19 mg/L [static] 96h LC50 Pimephales promelas: 41 mg/L 96h LC50 Pimephales promelas: 45 mg/L [flow-through] 3.63 Naphthalene (contaminant) 72h EC50 Skeletonema costatum: 0.4 mg/L 96h LC50 Oncorhynchus mykiss: 0.91 - 2.82 mg/L [static] 96h LC50 Pimephales promelas: 5.74 - 6.44 mg/L [flow-through] 96h LC50 Oncorhynchus mykiss: 1.6 mg/L [flow-through] 96h LC50 Pimephales promelas: 1.99 mg/L [static] 96h LC50 Lepomis macrochirus: 31.0265 mg/L [static] 48h EC50 Daphnia magna: 1.09 - 3.4 mg/L [static] 48h EC50 Daphnia magna: 1.96 mg/L [Flow through] 48h LC50 Daphnia magna: 2.16 mg/L 1,2,4-Trimethylbenzene (contaminant) 96h LC50 Pimephales promelas: 7.19 - 8.28 mg/L [flow-through] 48h EC50 Daphnia magna: 6.14 mg/L Persistence and Degradability No information available Bioaccumulation No information available Mobility in Environmental Media No information available Component log Pow Naphtha (petroleum), heavy aromatic 4.5 Naphthalene (contaminant) 3.3 1,2,4-Trimethylbenzene (contaminant) 3.63 ;140,0.00:00.NSID0„ott NS Waste Disposal Methods Contaminated Packaging Dispose of contents/container in accordance with local regulation. Empty containers should be taken to an approved waste handling site for recycling or disposal. Page 4/6 Product code 9050 - Retarder Thinner Revision Date Jul -11-2012 SPORljN�ORMATi40[> DOT Printing Ink Related Material, Liquid, Not Regulated ICAO/IATA Not classified as dangerous in the meaning of transport regulations IMDG/IMO Not classified as dangerous in the meaning of transport regulations }'-�'M:•,.'.,1 - b J"V.JWas7a.. ,.J2a V4'/. ,y.M-�: X15IIREGULATORYANFORMATION International Inventories Listed on TSCA. For further information, please contact: Manufacturer, importer, supplier U.S. Federal Regulations SARA 313 The following components are Component CAS -No Weight % SARA -313 - Threshold 91-20-3 5 - 10 X Values Naphthalene (contaminant) 91-20-3 5 - 10 0.1 1,2,4-Trimethylbenzene (contaminant) 95-63-6 1 - 51.0 Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) Component CAS -No Weight % Naphthalene (contaminant) 91-20-3 5 - 10 U.S. State Regulations Component Massachusetts Right To Know Minnesota Right To Know New Jersey Right To Know Pennsylvania Right To Know Naphthalene (contaminant) X X X X 1,2,4-Trimethylbenzene (contaminant) X X X X California Prop. 65 WARNING! This product contains a chemical known in the State of Califomia to cause cancer and / or WARNING! This product contains a chemical known in the State of Component CAS -No Weight % Naphthalene (contaminant) 91-20-3 5 - 10 Canada This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the information required by the CPR Component WHMIS Classifications of Components Naphthalene (contaminant) B4,D2A 1,2,4-Trimethylbenzene (contaminant) B3 Component NPRI - National Pollutant Release Inventory Naphtha (petroleum), heavy aromatic Part 5 Substance Part 5, Other Groups and Mixtures Naphthalene (contaminant) Part 1, Group 1 Substance 1,2,4-Trimethylbenzene (contaminant) Part 4 Substance Part 1, Group 1 Substance Part 5, Individual Substance Page 5 / 6 Product code 9050 - Retarder Thinner w; Revision Date,Jul-11-2012 r, Regulation (EC) No. 1907/2006 (REACH), Article 57 This product does not contain substances of very high concern (Regulation (EC) No. 1907/2006 (REACH), Article 57) HMIS: Health 2* Flammability 2 Reactivity 0 PPE X Revision Date Revision Note Jul -11-2012 New MSDS format Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified In the text End of MSDS Page 6 / 6 4/1/2014 City of Tukwila Department of Community Development LIESA KOLONICS 4310 S 131 PL TUKWILA, WA 98168 RE: Permit No. D13-234 NORMED 4320 S 131 PL Dear Permit Holder: Jim Haggerton, Mayor Jack Pace, Director In reviewing our current records, the above noted permit has not received a final inspection by the City of Tukwila Building Division. Per the International Building Code, International Mechanical Code, Uniform Plumbing Code and/or the National Electric Code, every permit issued by the Building Division under the provisions of these codes shall expire by limitation and become null and void if the building or work authorized by such permit has not begun within 180 days from the issuance date of such permit, or if the building or work authorized by such permit is suspended or abandoned at any time after the work has begun for a period of 180 days. Your permit will expire on 5/6/2014. Based on the above, you are hereby advised to: 1) Call the City of Tukwila Inspection Request Line at 206-438-9350 to schedule for the next or final inspection. Each inspection creates a new 180 day period, provided the inspection shows progress. -or- 2) Submit a written request for permit extension to the Permit Center at least seven(7) days before it is due to expire. Address your extension request to the Building Official and state your reason(s) for the need to extend your permit. The Building Code does allow the Building Official to approve one extension of up to 180 days. If it is determined that your extension request is granted, you will be notified by mail. In the event you do not call for an inspection and/or receive an extension prior to 5/6/2014, your permit will become null and void and any further work on the project will require a new permit and associated fees. Thank you for your cooperation in this matter. Sincerely, er Marshall t Technician File No: D13-234 6300 Southcenter Boulevard Suite #100 • Tukwila, Washington 98188 • Phone 206-431-3670 • Fax 206-431-3665 Date: Requested By: Firm/Company: OFF HOURS INSPECTION Reimbursement authorization/approval to conduct inspection activities during off hours. I \I Permit Number: D P.) G� C.cs acfor5 Inspection Information Project Name: t' mea Project Address/Location: 120 S . ) .2jl k. Requested Date for Inspection: 2 I 1 t V� Requested Time: 5- : 00 �PM Contact Name: Nn 1 Skt4 \feeir Phone Number: 14' t5 - �l 2"-f 2'31 Special Conditions for Consideration: ** Contractor will be charged a minimum for three (3) hour inspection time for any off -hours inspection work at $97.50 per hour (minimum total of $292.50). This is to be paid at the time of request. ** The undersigned, as an authorized representative of the above firm, hereby agrees to reimburse the City for its overtime inspections on the above referenced project. A separate invoice will be issued for all inspection time in excess of (3) hours. Signature: 1-knA(l°) Date: T,1 t off- �J Printed Name: Yl\CS citYe.I. e°Only: �Jf1, Approved: Disapproved: Paid: f `Z Receipt No: 1 - 0 L- J ie 1 Fl Date of Approval/Disapproval: Remarks: Authorized Reviewer: I H:\Permit Center Forms\Off Hours Inspection.docx Premier Warehouse Permits, Inc. 1800 E. McFadden Ave #200A Santa Ana, Ca 92705 Ph: (714) 269-8693 Fx: (877) 269-8657 Tukwila Building Division Attn: Allen Johannessen Correction Check list for D13-234 1. Correction #1 — Revised plans to reflect egress lighting arrangement per D13-014, egress path can be seen on Sheet 2 Inez remier Warehouse Permits, RECEIVED CITY OF TUKWILA AUG 0 9 202 PERMIT CENTER Premier Warehouse Permits, Inc. 1800 E. McFadden Ave #200A Santa Ana, Ca 92705 Ph: (714)269-8693 Fx: (877) 269-8657 Tukwila Fire Prevention Bureau Attn: Al Metzler Correction Check list for D13-234 1. Correction #1 — Please see clouded notes on plans 2. Correction #2 — Please see clouded notes on plans 3. Correction #3 — Please see clouded smoke vent on plans (Sheet 2) Joh Pr house Permits, Inc. RECEIVED CITY OF TUKWILA AUG 092013 PERMIT CENTER rl July 23, 2013 Liesa Kolonics Normed 4310 S 131 P1 Tukwila, WA 98168 • City of Tukwila Jim Haggerton, Mayor Department of Community Development Jack Pace, Director RE: Correction Letter #1 Development Permit Application Number D13-234 Normed — 4320 S 131 PI Dear Ms. Kolonics, This letter is to inform you of corrections thatmust be addressed before your development permit can be approved. All correction requests from each department must be addressed at the same time and reflected on your drawings. I have enclosed comments from the Building, and Fire Departments. At this time the Planning and Public Works Departments have no comments. Building Department: Allen Johannessen at 206 433-7163 if you have questions regarding the attached comments. Fire Department: Alan Metzler at 206 971-8718 if you have questions regarding the attached comments. Please address the attached comments in an itemized format with applicable revised plans, specifications, and/or other documentation. The City requires that two (2) sets of revised plans, specifications and/or other documentation be resubmitted with the appropriate revision block. In order to better expedite your resubmittal, a `Revision Submittal Sheet' must accompany every resubmittal. I have enclosed one for your convenience. Corrections/revisions must be made in person and will not be accepted through the mail or by a messenger service. If you have any questions, I can be reached at (206) 431-3670. Sincerely, '1,20 7-61,4 Bill Rambo Permit Technician File No. D13-234 W: (Permit CenterlCorrection Letters120131D13-234 Correction Letter #1.docx 6300 Southcenter Boulevard, Suite #100 • Tukwila, Washington 98188 • Phone 206-431-3670 • Fax 206-431-3665 • Tukwila Building Division Allen Johannessen, Plan Examiner Building Division Review Memo Date: July 23, 2013 Project Name: NORMED Permit #: D13-324 Plan Review: Allen Johannessen, Plans Examiner The Building Division conducted a plan review on the subject permit application. Please address the following comments in an itemized format with revised plans, specifications and/or other applicable documentation. (GENERAL NOTE) PLAN SUBMITTALS: (Min. size 1lx17 to maximum size of 24x36; all sheets shall be the same size. New revised plan sheets shall be the same size sheets as those previously submitted.) (If applicable) Structural Drawings and structural calculations sheets by a registered engineer shall have a current signed stamp -seal. Architectural design sheets and documents by a registered architect shall also have a current signed stamp -seal. 1. The racking layout for this permit is not consistent with layout shown on permit plan D13-014. This affects emergency egress paths and emergency lighting plan arrangement. Provide a revised egress plan that shows emergency egress paths and racking layouts are consistent in both permits D13-014 and Dl3-324. Should there be questions concerning the above requirements, contact the Building Division at 206-431-3670. No further comments at this time. Tukwila Fire Prevention Bureau Al Metzler, Fire Project Coordinator Fire Prevention Bureau Review Memo Date: July 19, 2013 Project Name: Normed Address: 4320 S 131St P1 Permit #: D13-234 Plan Reviewer: Al Metzler, Fire Project Coordinator The Fire Prevention Bureau conducted a plan review on the subject permit application. Please address the following comments in an itemized format with revised plans, specifications and/or other applicable documentation. 1. Please provide the existing fire sprinkler density in the proposed rack storage area. 2. Please provide a detailed description of the types of commodities to be stored on the racks. 3. The rack layout drawing shows what appears to be smoke vents. However, there is no legend or labeling on the plan to confirm. Should there be questions concerning the above requirements, contact the Fire Prevention Bureau at 206- 971-8718. No further comments at this time. ``PERMIT COORD COPY t PLAN REVIEW/ROUTING SLIP ACTIVITY NUMBER: D13-234 DATE: 08/09/13 PROJECT NAME: NORMED SITE ADDRESS: 4320 S 131 PL Original Plan Submittal X Response to Correction Letter # 1 Response to Incomplete Letter # Revision # after Permit Issued DEPARTMENTS: toc Building Division Public Works C Ayl 0\C Oiit '19 Fire Prevention Structural Planning Division ❑ Permit Coordinator 111 DETERMINATION OF COMPLETENESS: (Tues., Thurs.) Complete Comments: Incomplete DUE DATE: 08/13/13 Not Applicable ❑ Permit Center Use Only INCOMPLETE LETTER MAILED: LETTER OF COMPLETENESS MAILED: Departments determined incomplete: Bldg ❑ Fire ❑ Ping ❑ PW ❑ Staff Initials: TUES/THURS ROUTING: Please Route" Structural Review Required n No further Review Required ❑ REVIEWER'S INITIALS: DATE: APPROVALS OR CORRECTIONS: Approved ❑ Approved with Conditions Notation: REVIEWER'S INITIALS: DUE DATE: 09/10/13 Not Approved (attach comments) ❑ DATE: Permit Center Use Only CORRECTION LETTER MAILED: Departments issued corrections: Bldg ❑ Fire 0 Ping 0 PW 0 Staff Initials: • • PLAN REVIEW/ROUTING SLIP ACTIVITY NUMBER: D13-234 PROJECT NAME: NORMED SITE ADDRESS: 4320 S 131 PL X Original Plan Submittal Response to Incomplete Letter # DATE: 07-12-13 Response to Correction Letter # Revision # After Permit Issued EPAR MENTS: S .ewi 313 uilding Division Public Works n 4W\ AA#114 Fire Prevention Structural ri Planning Division Permit Coordinator n DETERMINATION OF COMPLETENESS: (Tues., Thurs.) Complete Incomplete n DUE DATE: 07-16-13 Not Applicable Comments: Permit Center Use Only INCOMPLETE LETTER MAILED: LETTER OF COMPLETENESS MAILED: Departments determined incomplete: Bldg 0 Fire 0 Ping 0 PW 0 Staff Initials: TUES/THURS ROUTING: Please Route7:1 Structural Review Required n No further Review Required REVIEWER'S INITIALS: DATE: n APPROVALS OR CORRECTIONS: Approved Notation: Approved with Conditions DUE DATE: 08-13-13 Not Approved (attach comments) NI REVIEWER'S INITIALS: DATE: Permit Center Use Only CORRECTION LETTER MAILED: 1-'21-13 Departments issued corrections: Bldg - Fire, Ping 0 PW 0 Staff Initials: We. Documents/routing slip.doc 2-28-02 City of Tukwila Department of Community Development 6300 Southcenter Boulevard, Suite #100 Tukwila, Washington 98188 Phone: 206-431-3670 Fax: 206-431-3665 Web site: http://www.ci.tukwilawa_us Revision submittals must* submitted in person at the Permit Center. Revisions will not be accepted through the mail, fad etc. Date: Plan Check/Permit Number: D13-234 ❑ Response to Incomplete Letter # • Response to Correction Letter # 1 O Revision # after Permit is Issued ❑ Revision requested by a City Building Inspector or Plans Examiner Project Name: Nonmed Project Address: 4320 r\D(C51VC-C' S131 P1 Contact Person: b�Sct. Phone Number: - -O�-P g —� a ac-g Summary of Revision: Sheet Number(s): "Cloud" or highlight all areas of revision including date of revision Received at the City of Tukwila Permit Center by: Entered in Permits Plus on 0 cb \applications\forms-applications on linekevision submittal Created: 8-13-2004 Revised: Contractors or Tradespeople Pror Friendly Page General/Specialty Contractor A business registered as a construction contractor with LIiI to perform construction work within the scope of its specialty. A General or Specialty construction Contractor must maintain a surety bond or assignment of account and carry general liability insurance. Business and Licensing Information Name TCL PARTNERS CORPORATION UBI No. 602930767 Phone 4253163500 Status Active Address 16000 Mill Creek Blvd License No. TCLPAPC919QD Suite/Apt. SUITE 103 License Type Construction Contractor City Mill Creek Effective Date 11/4/2009 State WA Expiration Date 7/10/2015 Zip 98012 Suspend Date County Snohomish Specialty 1 General Business Type Corporation Specialty 2 Unused Parent Company Other Associated Licenses License Name Type Specialty 1 Specialty 2 Effective Date Expiration Date Status J85COC*916MSJB5 CORPORATION Construction Contractor General Unused 7/10/2009 7/10/2011 Inactive Business Owner Information Name Role Effective Date Expiration Date SYLESTER, FRANCES MARIAN Agent 11/04/2009 Amount MERISKO, CARL WILLIAM Chief Financial Officer 06/22/2011 DTC05A09225ATIL11 MERISKO, BRIAN JAMES President 11/04/2009 MERISKO, DAVID JAMES Secretary 11/04/2009 Travelers Property Cas Co of A SYLVESTER, SUSAN MARIE Treasurer 11/04/2009 SYLVESTER, SCOTT JAMES Vice President 11/04/2009 5 SYLVESTOR, JAMES RAYMOND Vice President 11/04/2009 09/06/2012 Bond Information Bond Company Name American Contractors Indem CO Bond 1 Page 1 of 2 Bond Account Number Effective Date Expiration Date Cancel Date Impaired Date Bond Amount Received Date 100087506 11/04/2009 Until Cancelled $12,000.00 07/10/2009 Assignment of Savings Information No records found for the previous 6 year period Insurance Information Insurance Company Name Policy Number Effective Date Expiration Date Cancel Date Impaired Date Amount Received Date 7 Travelers Indemnity Co of Ame DTC05A09225ATIL11 09/06/2012 09/06/2013 $1,000,000.00 09/12/2012 6 Travelers Property Cas Co of A DTSMCUP5A09225ATIL11 09/06/2011 09/06/2012 $4,000,000.00 09/10/2011 5 Travelers Property Cas Co of A BA5A09225ACNS11 09/06/2011 09/06/2012 $1,000,000.0009/10/2011 4 Travelers Property Cas Co of A DTC05A09225ATIL11 09/06/2011 09/06/2012 $1,000,000.0009/10/2011 3 Western Heritage Ins Co SCP0828666 10/27/2010 10/27/2011 $1,000,000.00 06/07/2011 2 SCP0755799 06/05/2010 06/05/2011 $1,000,000.0006/04/2010 httos://fortress.wa. Qov/lni/bbip/Print.aspx 08/22/2013 0 Ct Cis) w 0 U z w 0 w LL rl NEW DRIVE IN RAMP W/WALL FARE ROLL UP DOORS p DRIVE IN DOOR ACCESS DOOR ROLL UP DOORS REVISIONS No changes shall be made to the scope of work without prior approval of Tukwila Building Division. NOTE: iclilan I ttal an may nudeadditional plan review fees. DOCK DOOR ACCESS DOOR ■ IIIII HIM 11.1 co IJ pia ACCESS DOOR -_ - I�LJ►J�1_- I I I I-Liv-iimounir FILE COPY Permit No. ACCESS DOOR FIRE DEPARMENT ACCESS ROAD VAN S. .44 Plan review approval Is subject to errors and omissione Approval of construction documents does not authorize the violation of any adopted code or ordinance. Receipt of approved Field Copy and contions Is By 1 W/o rI-K-I A Dabir� 9: City Of Tukwila BUILDING DIVISION FIRE DEPARMENT ACCESS ROAD SO.,T 131ST DAC VICINITY MAP FIRE DEPARTMENT HIGH PILE STORAGE NOTES: SCOPE OF WORK: THIS PLAN IS INTENDED FOR CONSTRUCTION IT IS A HIGH PILED STORAGE DESIGN AND REPORT IN CONJUCTION WITH BUILDING STRUCTURAL PLANS. IT'S PURPOSE IT TO ESTABLISH THE STORAGE REQUIREMENTS FOR THE TENANT AND BUILDING WHICH COMPLIES WITH THE APPLICABLE 2009 INTERNATIONAL FIRE CODE, NEPA 13 2010 EDITION, AND 2009 INTERNATIONAL BUILDING CODE REQUIREMENTS. ANY AND ALL MODIFICATIONS TO THE BUILDING ARE THE SOLE RESPONSIBILITY OF THE OWNER/TENANT. THE OWNER/TENANT SHALL OBTAIN A LICENSED CONTRACTOR TO PERFORM SUCH WORK. ALS). WITH THE NECESSARY PERMIT FOR SUCH WORK PROPOSED HIGH PILE STORAGE COMMODITIES: \_ CLASS IV COMMODITIES: PER IFC 2303.5 ALL COMMODITIES LISTED BELOW ARE CARTONED AND STORED ON WOOD PALLETS COMMODITY: GROUP A PLASTIC MEDICAL SUPPLY PARTS AND ACCESSORIES ALL COMMODITIES IN PARTITIONED CARDBOARD BOXES, PLACED ON WOOD PALLETS, SHRINK WRAPPED FOUR SIDES (NON -ENCAPSULATED) PLACED ON RACKS TO A HEIGHT OF 20'-0" TOP OF STORAGE THESE COMMODITIES SHALL BE CLASSIFIED AS HIGH HAZARD PER 2303.6 PER THE GROUP A PLSTICS FLORAL ARRANGEMENTS AND DECORATIONS. NOTE: CARTONS THAT CONTAIN GROUP A PLASTIC MATERIAL CAN BE TREATED AS CLASS IV COMMODITIES UNDER THE FOLLOWING CONDITIONS: 1.) THERE SHALL BE MULTIPLE LAYERS OF CORRUGATION OR EQUIVALENT OUTER MATERIAL THAT WOULD SIGNIFICATLY DELAY FIRE INVOLVEMENT OF GROUP A PLASTICS. 2.) THE AMOUNT AND ARRANGEMENT OF GROUP A PLASTIC MATERIAL WITHIN AN ORDINARY CARTON WOULD NOT BE EXPECTED TO SIGNIFICANTLY INCREASE THE FIRE HAZARD. FIRE SPRINKLER DESIGN: THE CALCULATED SYSTEM HAS A MIN. DENSITY OF .60 GPM OVER THE REMOTE 2,000 SQ. FT. WITH SPRINKLER HEADS WITH A TEMPERATURE RATING OF 286°F. HIGH TEMPERATURE SPRINKLER HEADS WITH A 11.2K FACTOR DESIGN CRITERIA FOR RACK STORAGE: NFPA 13 (2010) REFERENCES TO TABLE 16.2.1.3.2(D) CURVE -E 8e G CLASS IV COMMODITIES FOR STORAGE UP TO 20'-0" . THIS DESIGN REQUIRES A CEILING SPRINKLER DENSITY OF .495 GPM/2,000 SQ. FT. WITH 286°F HEADS WITH MINIMUM FOR CURVE -E AND .580 GPM/2,000 SQ. FT. WITH 286°F HEADS FOR CURVE -G WITH AISLES BETWEEN 4'-O" AND 8'-0" NFPA 13 SECTION 1 6.2.1 .3.2.1 (A) HAS BEEN APPLIED DIRECT LINEAL INTERPOLATION FOR AISLES BETWEEN 4' AND 8' FOR A DENSITY OF .52 GPM (7'-0" MIN. AISLES) THIS SPRINKLER SYSTEM ALLOWS FOR STORAGE UP TO 2O'-0" FEET OR WITHIN 18" OF SPRINKLER HEADS, WHICHEVER IS LESS FOR THE FOLLOWING COMMODITIES: -CLASS IV COMMODITIES -CONVENTIONAL PALLETS -CARTONED OR EXPOSED WAREHOUSE INFORMATION: OCCUPANCY TYPE: B (OFFICE), S-1 (WAREHOUSE / STORAGE) CONSTRUCTION TYPE: TYPE III -B FIRE SPRINKLERS: FULLY SPRINKLED BUILDING CLEAR HEIGHT: 28'-0" FROM SLAB TO ROOF SHEATHING STORAGE INFORMATION + MAXIMUM STORAGE HEIGHT: STORAGE METHOD: RACK STORAGE NUMBER OF TIERS: SEE RACK ELEVATIONS -MAXIMUM STORAGE HEIGHT: 20'-0" FT. RACK STORAGE - DEPTH OF RACKS: - LONGITUDINAL FLUE SPACE: -AISLE WIDTHS BETWEEN RACKS: - WIDTH OF INDIVIDUAL BAYS: - SHELF TYPE: -WAREHOUSE AREA: -WAREHOUSE HIGH -PILE AREA: 3'-6" FEET 12 INCHES 7' FT - 0" INCHES MINIMUM SEE RACK ELEVATIONS BEAM LOADED OR WIRE MESH DECKS 23,561 SQ. FT. OF WAREHOUSE AREA 18,714 SQ. FT. OF HIGH -PILE STORAGE SMOKE VENT INFORMATION + CALCULATION: PER TABLE 2306.2 OF IFC (12,001 - 20,000 SQ. FT) ALL SMOKE AND HEAT VENTS ARE REQUIRED FOR HIGH PILE STORAGE VENT RATIO PER TABLE 910.3 OPTION 1 ALL SMOKE AND HEAT VENTS SHALL BE IN ACCORDANCE WITH CFC 2306.7 MINIMUM VENT TO FLOOR RATIO OF SMOKE & HEAT VENTS IS 1:100 COMMODITIES FOR STORAGE HEIGHTS UP TO 20' (CFC TABLE 910.3 OPTION 1) FUSIBLE LINK TEMPERATURE: 386°F (MINIMUM) IF FUSIBLE LINK IS NOT ADEQUATE, OWNER MUST CHANGE TO COMPLY 18,714 SQ. FT. x 1.00% (1:100) 32 SQ. FT. (4' x 8' SMOKE VENT) SMOKE VENTS REQUIRED: 6 SMOKE VENTS REQUIRED SMOKE VENTS INSTALLED: 8 SMOKE VENTS INSTALLED IN HPS AREA = SMOKE VENT >< COLUMN FIRE SPRINKLER PROTECTION: PER TABLE NFPA 13 (2010) TABLE 16.1.4.1 NOTE REQUIRED: BASED ON EXISTING OVERHEARD CEILING SPRINKLERS HAVING A DENSITY GREATER THAN .57 GPM (CLASS IV COMMODITY) EXISTING SPRINKLER DENSITY: .60/2,000 FIRE EXTINGUISHERS: PORTABLE FIRE EXTINGUISHERS SHALL BE PROVIDED IN ACCORDANCE WITH 2009 IFC SECTION 906 AND TUKWILA FIRE DEPARTMENT STANDARDS FOR EXTRA HAZARD SEPARATE PERMIT REQUIRED FOR: Mechanical Electrical Plumbing Gas Piping ,a of Tukwila ' .:, DIVISION EXISTING FIRE HYDRANTS: ACCESSIBLE HYDRANT(S) SHALL BE PROVIDED AND LOCATED WITHIN 150 FEET OF ALL PORTIONS OF EXTERIOR WALL ON THE FIRST FLOOR AS MEASURED IN AN APPROVED ROUTE AROUND THE BUILDING IN CONFORMANCE WITH CITY STANDARDS. ALL PRIVATE FIRE HYDRANT CAPS MUST BE PAINTED IN ACCORDANCE WITH TUKWILA FIRE DEPARTMENT STANDARDS IDLE PALLET STORAGE: THERE WILL BE NO IDLE PALLET STORAGE IN THIS WAREHOUSE AT THIS TIME BUILDING ACCESS - PER TABLE 2306.2 OF IFC (12,001 - 20,000 SQ. FT) BUILDING ACCESS IS REQUIRED (SEE PLAN FOR ACCESS CURTAIN BOARD INFORMATION: PER TABLE 2306.2 OF IFC (12,001 - 20,000 SQ. I- I ) DRAFT CURTAINS ARE NOT REQUIRED REQUIRED FLUE SPACES: IFC TABLE 2308.3 LONGITUDINAL: MINIMUM _6 INCHES TRANSVERSE: MINIMUM 3 INCHES, VERTICALLY ALIGNED NOT FIRE DETECTION SYSTEM: PER TABLE 2306.2 OF IFC (12,001 - 20,000 SQ. FT) A FIRE DETECTION SYSTEM IS NOT REQUIRED NOTE: FIRE DEPARTMENT FINAL INSPECTION REQUIRED. SCHEDULE ALL INSPECTIONS A MINIMUM 48 HOURS IN ADVANCE BY CALLING (206) 575-4404 NOTE: FIRE APPARATUS ACCESS ROADS SHALL BE UNOBSTRUCTED. ACCESS GATES SHALL BE APPROVED PRIOR TO INSTALLATION AND SHALL BE IN COMPLIANCE WITH IFC 504 AND TUKWILA FIRE DEPARTMENT STANDARDS ROAD AND °vIE'wEu"FQ� i CODE COMPLIANCE APPROVED AUG 21 2013 City of T k iia REQUIREDftr:.,ING i1SION NOTE: AUTOMATIC FIRE SPRINKLER SYSTEMS AND ALL CONTROL VALVES SHALL BE MONITORED BYA U.L. LISTED CENTRAL ALARM STATION OR BE SUPERVISED PER 2009 IFC CHAPERT 9. A SEPARATE PLAN SUBMITTAL IS REQUIRED FOR THE INSTALLATION OF THE MONITORING SYSTEM. NOTE: A CFC PERMIT IS REQUIRED FOR HIGH PILE STORAGE. THIS PERMIT WILL BE ISSUED BY AN TUKWILA FIRE DEPARTMENT FIRE INSPECTOR. NOTE: EXIT DOORS SHALL BE OPENABLE FROM THE INSIDE WITH OUT THE USE OF A KEY OR ANY SPECIAL KNOWLEDGE OR EFFORT. DOORS SHALL NOT BE PROVIDED WITH THUMB -TURN LOCKS OR DEADBOLTS THAT DO NOT UNLATCH IN TANDEM WITH THE NORMAL OPERATING LEVEL. THE OPENING FORCE FOR INTERIOR DOORS WITHOUT CLOSER SHALL NOT EXCEED 5 POUNDS THE UNLATCHING AND OPENING FORCE FOR OTHER DOORS SHALL NOT EXCEED 15 POUNDS I.B.C. 1008. NOTE: ALL EXTERIOR ACCESS DOORS SHALL BE 6'-8" X 3'-0" MAN DOORS WITH CITY OF TUKWILA ONE MOTION HARDWARE ACCESSIBLE FROM INSIDE AND OUTSIDE. ALL ACCESS DOORS TO HAVE EXTERIOR LEVER HARDWARE AND ABLE TO OPEN FROM OUTSIDE. NOTE: 5 YEAR SPRINKLER CERTIFICATION IS REQUIRED TO BE CURRENT NOTE: A 013 RECEWED PROPERTY EQUIPPED WITH FIRE DEPARTMENT CONNECTIONS NOTE: PERMIT CENTER IF ANY HOSE RACKS EXIST, THEY MUST BE REMOVED AND CAPPED OFF AT THE CEILING NOTE: STORAGE, DISPENSING OR USE OF ANY FLAMMABLE AND COMBUSTIBLE LIQUIDS, FLAMMABLE AND COMPRESSED GASES, AND OTHER HAZARDOUS MATERIALS SHALL COMPLY WITH IFC REGULATIONS. NOTE: KNOX BOXES SHALL BE PROVIDED IN ACCORDANCE WITH TUKWILA FIRE DEPARTMENT STANDARDS, LOCATIONS SHALL BE PROVIDED BY PROPERTY OWNER KNOX BOX LOCATION LOCATED IN FRONT ENTRANCE OF OFFICE NOTE: THERE WILL NOT BE ANY FIRE SPRINKLER ALTERATIONS TO THE EXISTING SPRINKLER SYSTEM AT THIS TIME, IF ANY ALTERNATIONS ARE TO BE PERFORMED A SEPARATE PERMIT WILL NEEDED TO PERFORM SUCH WORK NOTE: THIS REVIEW DID NOT INCLUDE ANALYSIS OF ANY FLAMMABLE LIQUIDS OR HAZARDOUS MATERIALS TO BE PRESENT. IF THERE ARE TO BE ANY HAZARDOUS MATERIALS PRESENT IN EXCESS OF EXEMPT AMOUNTS, THE APPLICANT MUST PROVIDE A LEI I ER IDENTIFYING THE MATERIALS TO BE STORED AND/OR USED AND RETURN IT TO THE FIRE DEPARTMENT FOR REVIEW AND APPROVAL PRIOR TO INTRODUCTION OF SUCH MATERIALS INTO THE BUILDING CODE REFERENCES: 2009 INTERNATIONAL FIRE CODE 2009 INTERNATIONAL BUILDING CODE NFPA 13 2010 EDITION TUKWILA FIRE DEPARTMENT STANDARDS ▪ t 4' CORRECTION LT R# DA3-2-3i1 Irl °Tai ✓^` �� EXPIRES10/25/ Mit 0 8 2013 REVISIONS THS DOCUMENT CONTAINS PURPOSE NOR USED PREMIER WAREHOUSE APPROVALS W c W a. ID W V W C.) - • • SIZE D PROJECT# PWP 94)106x: SCALE 1" = 30'-0" SHEET 1 OF 2 12" 12" 12" 82" Li] 50" o Ty I � 45' 40' 40' 180" TOP OF UPRIGHT 180" TOP OF UPRIGHT 50" 0- 180" TOP OF UPRIGHT 80" 50" 40'-4" co 0 0 IZ J 0 / 96"/132"/144" 10" >s � A- 42" .L 42" 96" i 10" — A 42"-/s-42"�' f-- 94"/96" 10" — /-42"-11-42" SELECTIVE RACK TYPE SELECTIVE RACK TYPE 2 SELECTIVE RACK TYPE 3 ACCESS DOOR CI ff 2 2 2 —J 6-1 LACCESS DOOR 5 180" TOP OF UPRIGHT LLI Cr 0 64" TOP OF UPRIGHT 1511111111111'- maillE111111ie lk 04008'4,1A 3 WM WM WW MW AM FIF t— 96"/144" , SELECTIVE RACK TYPE 4 SELECTIVE RACK TYPE 5 3 ft12 REVIEWED FOR CODE COMPLIANCE APPROVED AUG 2 1 2013 FIRE DEPARTMENT HIGH PILE STORAGE NOTES: SCOPE OF WORK: THIS PLAN IS INTENDED FOR CONSTRUCTION IT IS A HIGH PILED STORAGE DESIGN AND REPORT IN CONJUCTION WITH BUILDING STRUCTURAL PLANS. IT'S PURPOSE IT TO ESTABLISH THE STORAGE REQUIREMENTS FOR THE TENANT AND BUILDING WHICH COMPLIES WITH THE APPLICABLE 2009 INTERNATIONAL FIRE CODE, NEPA 13 2010 EDITION, AND 2009 INTERNATIONAL BUILDING CODE REQUIREMENTS. ANY AND ALL MODIFICATIONS TO THE BUILDING ARE THE SOLE RESPONSIBILITY OF THE OWNER/TENANT. THE OWNER/TENANT SHALL OBTAIN A LICENSED CONTRACTOR TO PERFORM SUCH WORK. PROPOSED HIGH PILE STORAGE COMMODITIES: CLASS IV COMMODITIES: PER IFC 2303.5 ALL COMMODITIES LISTED BELOW ARE CARTONED AND STORED ON WOOD PALLETS COMMODITY: GROUP A PLASTIC MEDICAL SUPPLY PARTS AND ACCESSORIES ALL COMMODITIES IN PARTITIONED CARDBOARD BOXES, PLACED ON WOOD PALLETS, SHRINK WRAPPED FOUR SIDES (NON -ENCAPSULATED) PLACED ON RACKS TO A HEIGHT OF 20'-0" TOP OF STORAGE THESE COMMODITIES SHALL BE CLASSIFIED AS HIGH HAZARD PER 2303.6 PER THE GROUP A PLSTICS FLORAL ARRANGEMENTS AND NOTE: CARTONS THAT CONTAIN GROUP A PLASTIC MATERIAL CAN BE TREATED AS CLASS IV COMMODITIES UNDER THE FOLLOWING CONDITIONS: 1.) THERE SHALL BE MULTIPLE LAYERS OF CORRUGATION OR EQUIVALENT OUTER MATERIAL THAT WOULD SIGNIFICATLY DELAY FIRE INVOLVEMENT OF GROUP A PLASTICS. 2.) THE AMOUNT AND ARRANGEMENT OF GROUP A PLASTIC MATERIAL WITHIN AN ORDINARY CARTON WOULD NOT BE EXPECTED TO SIGNIFICANTLY INCREASE THE FIRE HAZARD. FIRE SPRINKLER DESIGN: THE CALCULATED SYSTEM HAS A MIN. DENSITY OF .60 GPM OVER THE REMOTE 2,000 SQ. FT. WITH SPRINKLER HEADS WITH A TEMPERATURE RATING OF 286°F. HIGH TEMPERATURE SPRINKLER HEADS WITH A 11.2K FACTOR DESIGN CRITERIA FOR RACK STORA.\GE: NFPA 13 (2010) REFERENGE TO TABLE 16.2.1.3.2(D) CURVE—E & G CLASS IV COMMODITIES FOR STORAGE UP TO 2C-0" . THIS DESIGN REQUIRES A CEILING SPRINKLER DENSITY OF .495 GPM/2,000 SQ. FT. WITH 286°F HEADS WITH MINIMUM FOR CURVE— E AND .580 GPM/2,000 SQ. FT. WITH 286°F HEADS FOR CURVE—G ACCESS DOOR PATH OF EGRESS EN ACCESS DOOR WAREHOUSE INFORMATION: OCCUPANCY TYPE: B (OFFICE), S-1 (WAREHOUSE / STORAGE) CONSTRUCTION TYPE: TYPE III—B FIRE SPRINKLERS: FULLY SPRINKLED BUILDING CLEAR HEIGHT: 28'-0" FROM SLAB TO ROOF SHEATHING STORAGE INFORMATION + MAXIMUM STORAGE HEIGHT: STORAGE METHOD: NUMBER OF TIERS: —MAXIMUM STORAGE HEIGHT: —DEPTH OF RACKS: —LONGITUDINAL FLUE SPACE: —AISLE WIDTHS BETWEEN RACKS: —WIDTH OF INDIVIDUAL BAYS: —SHELF TYPE: —WAREHOUSE AREA: —WAREHOUSE HIGH—PILE AREA: RACK STORAGE SEE RACK ELEVATIONS 20'-0" FT RACK STORAGE 12 INCHES 7' FT — 0" INCHES MINIMUM SEE RACK ELEVATIONS BEAM LOADED OR WIRE MESH DECKS 23,561 SQ. H . OF WAREHOUSE AREA 18,714 SQ. FT. OF HIGH—PILE STORAGE 180" TOP OF UPRIGHT 64" SMOKE VENT INFORMATION CALCULATION: PER TABLE 2306.2 OF IFC (12,001 — 20,000 SQ. FT) ALL SMOKE AND HEAT VENTS ARE REQUIRED FOR HIGH PILE STORAGE VENT RATIO PER TABLE 910.3 OPTION 1 ALL SMOKE AND HEAT VENTS SHALL BE IN ACCORDANCE WITH CFC 2306.7 MINIMUM VENT TO FLOOR RATIO OF SMOKE & HEAT VENTS IS 1:100 COMMODITIES FOR STORAGE HEIGHTS UP TO 20' (CFC TABLE 910.3 OPTION 1 ) FUSIBLE LINK TEMPERATURE: 386°F (MINIMUM) IF FUSIBLE LINK IS NOT ADEQUATE, OWNER MUST CHANGE TO COMPLY 18,714 SQ. FT. x 1.00% (1:100) SMOKE VENTS REQUIRED: 6 SMOKE VENTS REQUIRED SMOKE VENTS INSTALLED: 8 SMOKE VENTS INSTALLED IN HPS AREA = SMOKE VENT NEPA 13 SECTION 16.2.1.3.2.1(A) HAS BEEN APPLIED DIRECT LINEAL INTERPOLATION FOR AISLES BETWEEN .AND 8' . FOR- Ao DENSITY OF .52 GPM (7' —0" MIN. AISLES) THIS SPRINKLER SYSTEM ALLOWS FOR...STORAGE UP TO 2C-0" FEET OR WITHIN 18" OF SPRINKLER HEADS, WHICHEVER IS LESS FOR THE FOLLOWING COMMODITIES: —CLASS IV COMMODITIES —CONVENTIONAL PALLETS —CARTONED OR EXPOSED COLUMN FIRE SPRINKLER PROTECTION: PER TABLE NFPA 13 (2010) TABLE 16.1.4.1 NOTE REQUIRED: BASED ON EXISTING OVERHEARD CEILING SPRINKLERS HAVING A DENSITY GREATER THAN .57 GPM (CLASS IV COMMODITY) EXISTING SPRINKLER DENSITY: .60/2,000 FIRE EXTINGUISHERS: PORTABLE FIRE EXTINGUISHERS SHALL BE PROVIDED IN ACCORDANCE WITH 2009 IFC SECTION 906 AND TUKWILA FIRE DEPARTMENT STANDARDS FOR EXTRA HAZARD City of Tukwila BUILDING DIVISION EXISTING FIRE HYDRANTS: ACCESSIBLE HYDRANT(S) SHALL BE PROVIDED AND LOCATED WITHIN 150 FEET OF ALL PORTIONS OF EXTERIOR WALL ON THE FIRST FLOOR AS MEASURED IN AN APPROVED ROUTE AROUND THE BUILDING IN CONFORMANCE WITH CITY STANDARDS.. ALL PRIVATE FIRE HYDRANT CAPS MUST BE PAINTED IN ACCORDANCE WITH TUKWILA FIRE DEPARTMENT STANDARDS IDLE PALLET STORAGE: THERE WILL BE NO IDLE PALLET STORAGE IN THIS WAREHOUSE AT THIS TIME BUILDING ACCESS: PER TABLE 2306.2 OF IFC (12,001 — 20,000 SQ. FT) BUILDING ACCESS IS REQUIRED (SEE PLAN FOR ACCESS ROAD AND DOORS) CURTAIN BOARD INFORMATION: PER TABLE 2306.2 OF IFC (12,001 — 20,000 SQ. FT) DRAFT CURTAINS ARE NOT REQUIRED REQUIRED FLUE SPACES IFC TABLE 2308.3 LONGITUDINAL: MINIMUM 6 INCHES TRANSVERSE: MINIMUM 3 INCHES, VERTICALLY ALIGNED NOT REQUIRED ARE DETECTION SYSTEM: PER TABLE 2306.2 OF IFC (12,001 — 20,000 SQ. F1) A FIRE DETECTION SYSTEM IS NOT REQUIRED NOTE: FIRE DEPARTMENT FINAL INSPECTION REQUIRED. SCHEDULE ALL INSPECTIONS A MINIMUM 48 HOURS IN ADVANCE BY CALLING (206) 575-4404 NOTE: FIRE APPARATUS ACCESS ROADS SHALL BE UNOBSTRUCTED. ACCESS GATES SHALL BE APPROVED PRIOR TO INSTALLATION AND SHALL BE IN COM PLIANCE WITH IFC 504 AND TUKWILA FIRE DEPARTMENT STANDARDS NOTE: AUTOMATIC FIRE SPRINKLER SYSTEMS AND ALL CONTROL VALVES SHALL BE MONITORED BYA U.L. LISTED CENTRAL ALARM STATION OR BE SUPERVISED PER 2009 IFC CHAPERT 9. A SEPARATE PLAN SUBMITTAL IS REQUIRED FOR THE INSTALLATION OF THE MONITORING SYSTEM. NOTE: A CFC PERMIT IS REQUIRED FOR HIGH PILE STORAGE. THIS PERMIT WILL BE ISSUED BY AN TUKWILA FIRE DEPARTMENT FIRE INSPECTOR. 20" 20" 20" 96" 180" TOP OF UPRIGHT 64" SELECTIVE RACK TYPE 6 42" --wk SELECTIVE RACK TYPE 7 NOTE: EXIT DOORS SHALL BE OPENABLE FROM THE INSIDE WITH OUT THE USE OF A KEY OR ANY SPECIAL KNOWLEDGE OR EFFORT. DOORS SHALL NOT BE PROVIDED WITH THUMB—TURN LOCKS OR DEADBOLTS THAT DO NOT UNLATCH IN TANDEM WITH THE NORMAL OPERATING LEVEL. THE OPENING FORCE FOR INTERIOR DOORS WITHOUT CLOSER SHALL NOT EXCEED 5 POUNDS THE UNLATCHING AND OPENING FORCE FOR OTHER DOORS SHALL NOT EXCEED 15 POUNDS I.B.C. 1008. NOTE: ALL EXTERIOR ACCESS DOORS SHALL BE 6'-8" X 3' —0" MAN DOORS WITH ONE MOTION HARDWARE ACCESSIBLE FROM INSIDE AND OUTSIDE. ALL ACCESS DOORS TO HAVE EXTERIOR LEVER HARDWARE AND ABLE TO OPEN FROM OUTSIDE. NOTE: 5 YEAR SPRINKLER CERTIFICATION IS REQUIRED TO BE CURRENT NOTE: PROPERTY EQUIPPED WITH FIRE DEPARTMENT CONNECTIONS NOTE: IF ANY HOSE RACKS EXIST, THEY MUST BE REMOVED AND CAPPED OFF AT THE CEILING SPECIAL INSPECTION FOR STORAGE CKS (OVER 8 FEET) Periodic special inspection is required during the anchorage of access floors and storage racks 8 feet or greater in height in structures assigned to Seismic Design Category D, E or F. IBC 1707.5 and TABLE 1704.4 (4) Inspection of anchors installed in hardened concrete. NOTE: STORAGE, DISPENSING OR USE OF ANY FLAMMABLE AND COMBUSTIBLE LIQUIDS, FLAMMABLE AND COMPRESSED GASES, AND OTHER HAZARDOUS MATERIALS SHALL COMPLY WITH IFC REGULATIONS. NOTE: KNOX BOXES SHALL BE PROVIDED IN ACCORDANCE WITH TUKWILA FIRE DEPARTMENT STANDARDS, LOCATIONS SHALL BE PROVIDED BY PROPERTY OWNER KNOX BOX LOCATION LOCATED IN FRONT ENTRANCE OF OFFICE NOTE: THERE WILL NOT BE ANY FIRE SPRINKLER ALTERATIONS TO THE EXISTING SPRINKLER SYSTEM AT THIS TIME, IF ANY ALTERNATIONS ARE TO BE PERFORMED A SEPARATE PERMIT WILL NEEDED TO PERFORM SUCH WORK NOTE: THIS REVIEW DID NOT INCLUDE ANALYSIS OF ANY FLAMMABLE LIQUIDS OR HAZARDOUS MATERIALS TO BE PRESENT. IF THERE ARE TO BE ANY HAZARDOUS MATERIALS PRESENT IN EXCESS OF EXEMPT AMOUNTS, THE APPLICANT MUST PROVIDE A LETTER IDENTIFYING THE MATERIALS TO BE STORED AND/OR USED AND RETURN IT TO THE FIRE DEPARTMENT FOR REVIEW AND APPROVAL PRIOR TO INTRODUCTION OF SUCH MATERIALS INTO THE BUILDING. CODE REFERENCES: 2009 INTERNATIONAL FIRE CODE 2009 INTERNATIONAL BUILDING CODE NFPA 13 2010 EDITION TUKWILA FIRE DEPARTMENT STANDARDS Structural Conc. 7.n i.,,ntece,i77 1200 N. iettersc 'FIRE HAY 06-2014 EXPIRES 10/25/ NA 0 8 2013 SIZE SCALE PROJECT# PWP00653 SHEET 2 OF Z. 11 COLUMN NOTES: USE @ ALL SELECTIVE RACK COLUMN/BASE LOCATIONS TYP. DESCRIPTION MATERIAL 11 ■ �o I(3) 1/2" GR. 5 BOLT REQ'D PER ATTACHMENT. wasureawnwrizeorrmonsm " 1/8" 3/8" 1 1"H' P. /8"0 ATTACHMENT: ATTACH W/ (4) 5/16" 0 X 3/4" ASTM A 325 BOLTS PER BRACE, (2) @ EA. END BASE PLATE: 8" x 5" 3/8" THICK PLATE DESCRIPTION MATERIAL STEEL YIELD ASTM A36, Fy=36,000 PSI NOTES: SAFETY PIN DESIGNED TO WITHSTAND 1000# UPLIFT FORCE. - _1 3/8" 1 7/16"l GR 55 RIVET 5/16"0 SAFETY CLIP STEEL YIELD 1/8 V COLUMN: SPECTRUM 14 GAGE THK STEEL ASTM A570, Fy=42,000 KSI <TYP. 'I J TYP'>1/8;" V DESCRIPTION MATERIAL STEEL YIELD BRACING: HORIZ. & DIAG. 14 GAGE STEEL ASTM A570, Fy=42,000 KSI NOTES: USE @ ALL BRACE LOCATIONS TYP. HORIZ BRACE NAG.`` BRACE GENERAL INFORMATION COLUMN ROW SPACER EAM ADEPICT NI - F O O THIS PROJECT 3 3/8" 12" i 1/2 3/8"3 X 7/8" SLOT 4 PLCS f NOTES: CONFIRM O.A.L. OF iNCHORS WITH INSTALLER TO ENSURE REQUIREDiM'BEDMENT IS OBTAINED. CONNECTOR BASE PLATE 0 F.F. 1/2 3 1/4" MIN. EMBED. DESCRIPTION 3 -PIN CONNECTOR MATERIAL 7 GAGE STEEL YIELD NOTES: SAFETY PIN DESIGNED TO WITHSTAND 1000# UPLIFT FORCE. ASTM A570, Fy=42,000 KSI 1 3/8"-t 5/16"0 SAFETY CLIP NOTES: USE @ ALL BEAM TO COLUMN CONNECTION LOCATIONS TYP. U.O.N. 0 • • " "1 "1 7/16" GR 55 RIVET 1/8" I TYP DESCRIPTION ROW SPACER MATERIAL 14 GAGE STEEL YIELD ASTM A36, Fy = 36,000 000 PSI / 1 1/2" NOTES: ATTACH WITH (4) 3/8 O GR.5 BOLTS, (2) EACH END /T / / 1 5/8'1 2 /2" DESCRIPTION SIZE POVER STUD SD2 ANCHOR 1/2"f X 3-1/4" MIN: EMBED. ICBG/ESR# 2501, NOTES: SEE NOTE #4 ABOVE FOR ANCHOR SPECS. 1 3/4" 3/4" __/ / / / / / / / / / / / / / / 1 5/8" / / / / / " DESCRIPTION 4 -PIN CONNECTOR MATERIAL; STEEL YIELD 7GAGE ASTM A570, Fy=42,000 KSI NOTES: USE@LVL1 TYPE5BEAMTOCOLUMN CONNECTION LOCATIONS TYP. DESCR: PTION MATERIAL STEEL YIELD 2-1/2" BEAM 16 GAGE ASTM Y A570, F 42,000 KSI NOTES: USE @ LVL 1-3 TYPE 6, LVL 1-4 TYPE 7 BEAM LOCATIONS TYP. DESCRIPTION MATERIAL STEEL YIELD 4"EAM 16 'AGE A M A570, F =42 00 KSI Y ,0 NOTES: USE@ ALL SPECTRUM BEAM LOCATIONS U.O.N. GENERAL PROJECT NOTES 1. DESIGNED PER REQUIREMENTS OF T -IE 2009 IBC, ASCE 7-05 AND THE 2008 RMI RACK DESIGN MANUAL 2. SEISMIC CRITERIA Ss =1.501, S1 = 0.518, Fa = 1.00, Fv = 1.50 Ip = 1.0 (NO PUBLIC ACCESS), Sds = 1.001, Sd1 = 0.518, OCC: CATAG. II, SITE CLASS D, SEISMIC DESIGN CATAG. D 3. STORAGE CAPACITY: TYPE 1 = 3200# PER LEVEL TYP. TYPE 2 = 2800# PER LEVEL TYP. TYPE 3 = 2200# PER LEVEL TYP. TYPE 4 = 3000# PER LEVEL TYP. TYPE 5 .= 3600# PER LEVEL TYP. TYPE 6= 1500# PER LEVEL 1-3, 3000# PER LEVEL 4,5. ;. TYPE 7= 1500# PER LEVEL 1-4, 3200# PER LEVEL 5,6. 4. ANCHORS POWER STUD SD2 ESR #2502,1/2"0 x 3-1/4" MIN. EMBEDT. OR APPROVED EQUAL. (2) ANCHOR PER BASE PLATE 5. PERIODIC SPECIAL INSPECTION IS REQUIRED DURING ANCHOR INSTALLATION. 6. EXISTING S.O.G. CONCRETE THICKNESS & COMPRESSIVE STRENGTH, 6" x 2500 PSI 7. SOIL BEARING PRESSURE 1000 PSF @ GRADE OR BETTER 8. ALL RACK INSTALLATIONS AND RACKS MANUFACTURED IN CONFORMITY WITH THIS STANDARD SHALL DISPLAY IN ONE OR MORE CONSPICUOUS LOCATIONS A PERMANENT PLAQUE EACH NOT LESS THAN 50 SQUARE INCHES IN AREA AND SHOWING THE MAXIMUM PERMISSIBLE UNIT LOAD IN CLEAR, LEGIBLE PRINT. 9. ALL BOLTS GR..5 OR BETTER. INSTALL TO SNUG TIGHT FIT WITH ALL PLYS IN FLAT CONTACT 10. ALL WELDING PERFORMED IN THE SHOP OF AN APPROVED FABRICATOR BY AWS CERTIFIED WELDERS USING E70XX ELECTRODE OR BETTER. FIELD WELDS, IF ANY, SHALL BE PROVIDED UNDER THE SUPERVISION OF A LICENSED DEPUTY INSPECTOR. 11. THE CLEAR SPACE BELOW SPRINKLERS18" SHALL BE A MIN. OF BETWEEN TOP OF THE STORAGE AND THE CEILING SPRINKLER DEFLECTOR. MAY 0'14 REVIEWED FOR CODE COMPLIANCE APPROVED AUG 2 1 2013 City of Tukwila BUILDING DIVISION • 30' "if SEE ATTACHED WESTCOAST WHSE CONSULTANTS IE: I RSA R ca FOR STORAGE RACK ELEVATIONS. RECEIVED a RES 102. CITY OF TUKWILA AUG 0 9 2013 PERMIT CENTER AUG 0 8 2013 DESCRIPTION STORAGE RACK ELEVATION LL cn z 0• v U_ LL I 8 JOB NO. N-062613-4 SHEET NO. SCE1OF1