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HAZMAT 15-0525 - 13050 48TH AVE S - GASOLINE OR OTHER FLAMMABLE LIQUID SPILL ON 2/6/2015
13050 48TH AVE S GASOLINE OR OTHER FLAMMABLE LIQUID SPILL HAZMAT # 15-0525 . Incident Report 2015-1500525 -000 Tukwila Fire Department 1 s Page 1 of 6 Printed: 02/17/2015 09:25:51 Basic Alarm Date and Time Arrival Time Controlled Date and Time Last Unit Cleared Date and Time Response Time Priority Response Completed Fire Department Station Shift Incident Type Initial Dispatch Code Aid Given or Received Mutual Aid Department Alarms Action Taken 1 Casualties Apparatus - Suppression Apparatus - Other Personnel - Suppression Personnel Personnel - Other Hazardous Material Released Property Use Location Type Address City, State Zip District Census Tract Directions 10:56:31 Friday, February 6, 2015 11:03:27 14:08:27 Friday, February 6, 2015 0:06:56 Yes Yes 53 B 411 - Gasoline or other flammable liquid spill SPILL 2 - Automatic aid received 17M08 -Kent FD 1 44 - Hazardous materials leak control & containment No 7 3 15 1 0 - Special hazmat actions required or spill >= 55 gallons 946 - Lake, river, stream Address 13050 48 AVE S TUKWILA, WA 98168 001 0272.00 13050 48TH AVE S Person Involved - Person, Last Name Business Name Street Address Phone Person Husky International 8668490 Hazmat Outside of Structure Population Density Area Affected Area Affected Unites Hazmat Action Taken 1 Hazmat Action Taken 2 Hazmat Action Taken 3 Cause of Release Factors Contributing To Release 1 Mitigating Factors 1 Disposition Mobile Equipment Type 1 1 - Urban Center - Densely populated 2 - Blocks 3 13 - Hazmat spill control and confinement 16 - Decontaminate persons or equipment 22 - Isolate area & establish hazard control zones 5 - Cause under investigation UU - Undetermined 17 - Released, slick on waterway 5 - Released to state agency 23 - Trailer - semi, designed for freight 0K Page 1 of 6 Printed: 02/17/2015 09:25:51 Incident Report 2015-1500525 -000 Tukwila Fire Department Hazmat Chemicals Chemical Name DOT ID Chemical ID Container Type Diesel fuel 30 - Class 3 - Flammable/Combustible Liquids 1202 41 - Vehicle fuel tank and associated piping Apparatus - FM51 Apparatus ID Apparatus Dispatch Date and Time En route to scene date and time Apparatus Clear Date and Time Apparatus priority response Number of People Apparatus Use Apparatus Type Personnel 1 FM51 11:02:46 Friday, February 6, 2015 11:02:46 Friday, February 6, 2015 11:38:48 Friday, February 6, 2015 Yes 1 1 92 - Chief officer car TF 1170 - Tomaso, Donald Position: BC Apparatus - E53 Apparatus ID Apparatus Dispatch Date and Time En route to scene date and time Apparatus Clear Date and Time Apparatus priority response Number of People Apparatus Use Apparatus Action Taken 1 Apparatus Type Personnel 1 Personnel 2 Personnel 3 E53 11:06:46 Friday, February 6, 2015 11:06:46 Friday, February 6, 2015 13:16:03 Friday, February 6, 2015 Yes 3 1 44 - Hazardous materials leak control & containment 11 - Engine TF 1124 - O'Brien, Patrick Position: FFI TF1135 - Beckman, Kenneth Position: CAPT TF2186 - Hartjoy, Jeffrey Position: FFIII Apparatus - B51 Apparatus ID Response Time Apparatus Dispatch Date and Time En route to scene date and time Apparatus Arrival Date and Time Apparatus Clear Date and Time Apparatus priority response Number of People Apparatus Use Apparatus Action Taken 1 Apparatus Type Personnel 1 B51 0:05:49 10:57:38 Friday, February 6, 2015 10:57:38 Friday, February 6, 2015 11:03:27 Friday, February 6, 2015 12:57:40 Friday, February 6, 2015 Yes 1 0 81 - Incident command 920 - Battalion Chief TF1122 - Peterson, Lavern Position: BC Page 2 of 6 Printed: 02/17/2015 09:25:51 Incident Report 2015-1500525 -000 Tukwila Fire Department Page 3 of 6 Printed: 02/17/2015 09:25:51 Apparatus - HM76 Apparatus ID Response Time Apparatus Dispatch Date and Time En route to scene date and time Apparatus Arrival Date and Time Apparatus Clear Date and Time Apparatus priority response Apparatus Use Apparatus Action Taken 1 Apparatus Type HM76 0:13:59 10:56:31 Friday, February 6, 2015 10:59:04 Friday, February 6, 2015 11:10:30 Friday, February 6, 2015 12:55:41 Friday, February 6, 2015 Yes 0 43 - Hazardous materials spill control and confmement 93 - HazMat unit Apparatus - E76 Apparatus ID Response Time Apparatus Dispatch Date and Time En route to scene date and time Apparatus Arrival Date and Time Apparatus Clear Date and Time Apparatus priority response Apparatus Use Apparatus Action Taken 1 Apparatus Type E76 0:10:48 10:59:42 Friday, February 6, 2015 10:59:42 Friday, February 6, 2015 11:10:30 Friday, February 6, 2015 12:55:41 Friday, February 6, 2015 Yes 0 43 - Hazardous materials spill control and confmement 11 - Engine Apparatus - E51 Apparatus ID Response Time Apparatus Dispatch Date and Time En route to scene date and time Apparatus Arrival Date and Time Apparatus Clear Date and Time Apparatus priority response Number of People Apparatus Use Apparatus Action Taken 1 Apparatus Type Personnel 1 Personnel 2 Personnel 3 Personnel 4 E51 0:13:06 10:57:38 Friday, February 6, 2015 10:57:38 Friday, February 6, 2015 11:10:44 Friday, February 6, 2015 13:09:50 Friday, February 6, 2015 Yes 4 1 43 - Hazardous materials spill control and confmement 11 - Engine TF 1106 - Johnson, Aaron Position: FFI TF1128 - Browning, Cathy Position: FFI TF2167 - Planellas, Gregory J Position: FFII TF2318 - Faire, Brody Position: FFP Apparatus - L54 Apparatus ID Response Time Apparatus Dispatch Date and Time L54 0:11:38 11:03:37 Friday, February 6, 2015 Page 3 of 6 Printed: 02/17/2015 09:25:51 Incident Report 2015-1500525 -000 Tukwila Fire Department Apparatus - L54 En route to scene date and time Apparatus Arrival Date and Time Apparatus Clear Date and Time Apparatus priority response Number of People Apparatus Use Apparatus Action Taken 1 Apparatus Type Personnel 1 Personnel 2 Personnel 3 11:04:00 11:15:15 12:59:54 Yes 3 1 43 - Hazardous materials spill control and confinement 13 - Quint TF 1114 - Konieczka, Jason Position: CAPT TF 1127 - Evans, Jim Position: FFI TF2186 - Hartjoy, Jeffrey Position: FFIII Friday, February 6, 2015 Friday, February 6, 2015 Friday, February 6, 2015 Apparatus - CH54 Apparatus ID Response Time Apparatus Dispatch Date and Time En route to scene date and time Apparatus Arrival Date and Time Apparatus Clear Date and Time Apparatus priority response Number of People Apparatus Use Apparatus Action Taken 1 Apparatus Type Personnel 1 CH54 0:11:50 11:10:23 Friday, February 6, 2015 11:10:23 Friday, February 6, 2015 11:22:13 Friday, February 6, 2015 12:45:19 Friday, February 6, 2015 Yes 1 1 81 - Incident command 920 - Battalion Chief TF 1112 - Grisham, Martin Position: BC Apparatus - B76 Apparatus ID Response Time Apparatus Dispatch Date and Time En route to scene date and time Apparatus Arrival Date and Time Apparatus Clear Date and Time Apparatus priority response Apparatus Use Apparatus Action Taken 1 Apparatus Type B76 0:27:46 11:04:00 Friday, February 6, 2015 11:04:00 Friday, February 6, 2015 11:31:46 Friday, February 6, 2015 12:34:19 Friday, February 6, 2015 Yes 1 70 - Assistance, other 920 - Battalion Chief Apparatus - BOT51 Apparatus ID Response Time Apparatus Dispatch Date and Time En route to scene date and time Apparatus Arrival Date and Time BOT51 0:01:34 11:44:28 11:44:28 11:46:02 Friday, February 6, 2015 Friday, February 6, 2015 Friday, February 6, 2015 Page 4 of 6 Printed: 02/17/2015 09:25:51 Incident Report 2015-1500525 -000 Tukwila Fire Department flammable liquid spill. Ten units were assigned to this incident. Thirteen personnel responded. We arrived on scene at 1103 hours and cleared at 1408 hours. The incident occurred at 13050 48TH Ave S, TUKWILA in District 001. The local station is 53. The general description of this property is lake, river, stream. The primary task(s) performed at the scene by responding personnel were hazardous materials leak control and containment. Automatic aid was received on this incident. Alarm number 1500525 has been assigned to this incident. E51 responded to a dispatch with B51, E76 and HM76 for a SPILL involving a large amount of oil or gas going into the river from a storm drain located at the end of 48th ave S along the river bank. E51 brought the Hazmat tow vehicle seeing the call type and classification of a large spill (Hazmat Tow apparatus has booms and adsorbent material on Page 5 of 6 Printed: 02/17/2015 09:25:51 Apparatus - BOT51 Apparatus Clear Date and Time Apparatus priority response Number of People Apparatus Use Apparatus Action Taken 1 Apparatus Type Personnel 1 Personnel 2 Personnel 3 14:08:27 Friday, February 6, 2015 Yes 3 1 43 - Hazardous materials spill control and confinement 52 - Boat, no pump TF 1124 - O'Brien, Patrick Position: FFI Amount 1: $0.00 Amount 2: $0.00 TF1135 - Beckman, Kenneth Position: CAPT Amount 1: $0.00 Amount 2: $0.00 TF1110 - Nevens, Andrew Position: FFI Amount 1: $0.00 Amount 2: $0.00 1 Authority Reported By ',, A Officer In Charge ,:` Reviewer TF1106 - Johnson, Aaron 18:48:08 Friday, February 6, 2015 TF1122 - Peterson, Lavern 18:48:23 Friday, February 6, 2015 Narratives Narrative Name Narrative Type Narrative Date Author Author Rank Author Assignment Narrative Text 1500525 Incident 17:49:43 Friday, February 6, 2015 TF1106 - Johnson, Aaron FFI 1 At 1056 hours on Friday February 6, 2015 we were dispatched to a gasoline or other flammable liquid spill. Ten units were assigned to this incident. Thirteen personnel responded. We arrived on scene at 1103 hours and cleared at 1408 hours. The incident occurred at 13050 48TH Ave S, TUKWILA in District 001. The local station is 53. The general description of this property is lake, river, stream. The primary task(s) performed at the scene by responding personnel were hazardous materials leak control and containment. Automatic aid was received on this incident. Alarm number 1500525 has been assigned to this incident. E51 responded to a dispatch with B51, E76 and HM76 for a SPILL involving a large amount of oil or gas going into the river from a storm drain located at the end of 48th ave S along the river bank. E51 brought the Hazmat tow vehicle seeing the call type and classification of a large spill (Hazmat Tow apparatus has booms and adsorbent material on Page 5 of 6 Printed: 02/17/2015 09:25:51 Incident Report 2015-1500525 -000 Tukwila Fire Department Narratives board). E51 arrived with B51 already on scene and began size up and containment of fuel and water pouring from at storm drain outflow into the river. Utilizing adsorbent booms. HM76 arrived crossed staffed by E76 who provided additional booms and adsorbent pads. The adsorbent was place in a large arc around the storm drain outflow to limit the spread of the fuel oil into the river. The quantity of the spill was not able to be determined however a slick on the surface of the river was visible from Delta Marine (9800 block of the Duamish River) according to Boat 51. HM76 was assigned Hazmat Group Supervisor and coordinated the additional containment of the fuel oil and the monitoring of the product in the water. Readings were taken with a BW Gas Alert 4 gas monitor (02, H2S, LEL, CO) also equipped with a PID. Readings were normal at 20.9% 02, 0 H2S, 0% of LEL, 0 ppm CO and 0 ppm of VOC's indicated on the PID. The meter was last calibrated on 29 JAN 2015 by A. Johnson. The suspected fuel oil was also tested using a spilfyter strip which indicated on test site #4 positive for Petrol. Boat 51 had been previously dispatched by duamish command (E53 to the boat at Delta marine) and responded up river to the site of the spill. E51 provided adsorbent booms which boat 51 deployed across the river for secondary containment. Due to the 4 to 5 mph current of the river the booms were having trouble keeping the oil contained and 10-15% of the fuel oil was pushed under the booms. After the secondary containment of the booms were in place the Department of Ecology (DOE) arrived on scene and began their investigation of the spill. L54 had located a suspected source at the near by Husky International Company. The cause and specific origin of the spill was under investigation by DOE as well as an environmental cleaning contractor was enroute at the time which Tukwila Fire turned the scene over to the Department of Ecology. AJ Narrative Name 1500525 Narrative Type Incident Narrative Date 09:16:10 Tuesday, February 17, 2015 Author TF 1106 - Johnson, Aaron Author Rank FFI Author Assignment 1 Narrative Text The following Hazmat items were utilized at the scene which may be subject to billing of the responsible party. -2 large bag, Hazmat adsorbent booms -1 spilfyter strips for hazard identification -1 large bag of hydrocarbon adsorbent pads (white) -1 12mm 75' rope, kernmantle static utility line. -1 Water rescue throw rope, 75' End of Report Page 6 of 6 Printed: 02/17/2015 09:25:51 ') Pr �t kark&r \6112 HAZMAT OPEIA TIONS UIDE HAZMAT GROUP SUPERVISOR /C:1-0 BRANCH DIRECTOR NAME & ID: Q.‘) WA. EMD INCID NT #: DATE: r..•• COMMAND LOCATION: Radio Talk Groups: Command Entry Medical n Operation Vest and receive your section of the manual from the IC SJ ----7 ua,360 iEstablish Possible10-minute (look for temperature and other critical concerns) ®" 'mer foweather condi ' ns / Identify Hazard � tS s k}z,row, f � �Li Yfl aro O Offensive Mode 0 Defensive Mode Comecon/Investigate 0 Non -Intervention Mode (ponfirm isolation and evacuation of IDLH Area CI`1�./ GJdGO �G 1 O Evaluate resources (Request additional resources from Incident Co mander) ❑ Assemble hazardous material team members and confirm hazmat technician status ❑ Appoint positions • HazMat Assistant Safety Officer: T ______1.1j O Entry Team Leader: (TECH) \ / A 0 Decon Leader: (TECH) ✓l Research: (TECH) • - ❑ Hazmat Medical: In 01 ❑ Provide dressers and support personnel. ❑ Determine locations for Hazmat apparatus, decontamination corridor, Medical Group ❑ Review Incident Action Plan with Incident Commander ❑ Verify with Research and Safety Officers level and type of PPE to be worn by Entry Team, Standby Team and Decon Team ❑ Set action plan goals for Entry Team Leader O Attend pre entry briefing with IC, Entry Team Leader, Entry team members, Decon team, Research, Hazmat Medical and the Safety Officer(s) ❑ Communicate activities and progress to Incident Commander ❑ Monitor and record Entry Team activities in the Hot Zone ❑ Set demobilization plan with IC ❑ Assist in debriefing ❑ Complete forms and collect all others. Turn in to IC Hazardous Materials Incident Manual — Hazmat Group 1/12/2012 page 1 of 8 PRE -ENTRY CHECKLIST ❑ Participate in the development of the tactical plan with the Command Staff and record on the following page. Ensure monitoring and detection equipment has been warmed -up, calibrated and staged Ensure necessary tools and equipment have been staged ❑ Confirm Entry Team, Standby Team and Decon Teams have inspected and donned appropriate PPE ❑ Perform communications gear check with all team members ENTRY BRIEFING CHECKLIST (for Entry, Standby and Decon team members) Provide description of the incident, materials involved, structures and terrain as applicable ❑ Review hot, warm and cold zone locations, entry and exit points ❑ Explain tactical plan and objectives ❑ With Hazmat Medical, Hazmat Assistant Safety Officer and/or Research explain signs and symptoms, hazards and other pertinent information regarding the material(s) involved. ❑ With Hazmat Assistant Safety Officer and/or Research review PPE selection, material, breakthrough times, etc. ❑ Review emergency exits, evacuation routes, signals, communications, etc. as necessary ❑ With Decon Leader, review and explain decon process, solutions involved, steps, etc. ❑ Obtain starting air pressures for each team member and record Notes: \ -.)ecur) ci e col 4_,/v. 044 DvvJANs), . qct) Hazardous Materials Incident Manual — Hazmat Group 1/12/2012 page 2 of 8 PRIMARY CHEMICAL HAZARDS Hazardous material(s) involved: ❑ Explosive Cl Polymerization ❑ Gas ❑ Toxic/poisonous Flammable Liquid ❑ Corrosive ❑ Flammable Solid ❑ Cryogenic ❑ Oxidizer ❑ Asphyxiant ❑ Organic peroxide ❑ Water reactive ❑ Radioactive 0 Air Reactive ❑ Biological ❑ Other: Monitoring and detec io equi ent need d: ()PS 1 0 .� O�a.U��i Decon process description (method, layout): kP1ri I Decon solution: Neutralization material: PPE SELECTION Level A B ' �v ''` !, . Suit Type: Suit Material: Break through time: Suit Glove Type: Compatibility check: Face shield Type: Compatibility check Outer glove: Compatibility check Boot Type: Inner glove: Evacuation Strategy: Hazardous Materials Incident Manual — Hazmat Group 1/12/2012 page 3 of 8 Hazard Identification ❑ Chemical Hazard ❑ Adjacent Chemicals U Contents liquefied U Ability to flow U Neutralization effects U Engulfment U Reaction U Polymerization U Combustion products U Thermal U Cryogenic U Steam or heat ❑ Heat Exposure ❑ Contents boiling U Contents heated U Contents refrigerated U Mechanical ❑ Expansion Ratio U Contents pressurized U Detonation or violent rupture U Electrical Hazards U Pneumatic hazards U Mechanical Hazards U Hydraulic Hazards U Radiological hazard U Biological hazard ❑ Container U Quantity of material U Container type U Container size U Container condition U Container Breach ❑ Disintegration ❑ Puncture U Runaway Cracking ❑ Spilt or tear ❑ Shut-off/isolation valves U Venting Ports U Drains ❑ Piping ❑ Automatic pumps U Automatic switching U Confinement hazard ❑ Bulk Storage ❑ Containment El LI LI CI LI Conditions Emergency Exits Adjacent Buildings Overhead hazards Entanglement Slip, trip fall Weather conditions Vulnerability Analysis o o o o o o LI Ll CI LI LI LI LI LI LI LI LI LI ❑ LI 121 LI People & Occupancy Schools Daycare Center Nursing Home Hospital Bus Stop Down wind area Down stream area Down hill area Manufacturing Business Residential Rural Population sensitivity Population density Occupancy type Environment Park Stream Pond Wetland Infrastructure & Assets Utility Vaults Parking Area Cafeteria Streets Rail roads Gas Line Phone Sewer Storm Drain Power Risk Analysis o o ❑ LI El LI LI Ll GI LI CI LI LI LI LI Exposure Acute Chronic Carcinogen High risk group Potential to injure Shut downs Evacuations Transportation Utility interruption Property Damage Temporary Damage Recoverable Damage Permanent Damage Environmental Damage Wind Effect Terrain Effect Hazardous Materials Incident Manual — Hazmat Group 1/12/2012 page 4 of 8 MITIGATION STRATEGY Mode of Operations: Offensive Defensive Non -Intervention Rescue: N/A Hot Zone Victims Disoriented / Disabled Technical Spill Control / Confinement strategy: ❑ N/A ❑ Absorption ❑ Adsorption U Covering U Damming ❑ Diking U Dilution ❑ Diversion U Dispersion U Vapor Dispersion U Vapor Suppression U Retention Leak Control / Containment strategy: ❑ N/A ❑ Over -pack U Patching / Plugging U Vacuum U Neutralization U Press. Reduction/Isolation U Solidification Hazardous Materials Incident Manual — Hazmat Group 1/12/2012 page 5 of 8 Aok5 sy;Il 1-1toki lof' 1319.'5 Lig 5., 564-Liz,,voq- cmcit 1 166. aaP5 $qqo Hazardous Materials Incident Manual — Hazmat Group 1/12/2012 page 6 of 8 HAZMAT UNIT LOG INCIDENT NAME: UNIT NAME/DESIGNATORS: WA. EMD INCIDENT #: DATE/TIME PREPARED: OPERATIONAL PERIOD: UNIT LEADER NAME : PERSON TER ASSIGNED NAME ICS POSITION HOME BASE ACTIVITY L,Q TIME MAJOR EVENTS Prepared by: Hazardous Materials Incident Manual — Hazmat Group 1/12/2012 page 7 of 8 HAZMAT UNIT LOG (CONT'D) TIME MAJOR EVENTS Prepared by: Hazardous Materials Incident Manual — Hazmat Group 1/12/2012 page 8 of 8 . HAZMAT PLANNING/RESER CH GUIDE PLANNING OR RESEARCH NAME: 51-rp j WA. EMD INCIDENT #: DATE: oZ, fq 11 COMMAND LOCATION: 4 GENERAL RESPONSIBILITES: ❑ Gather, evaluate and document all information pertinent to the incident. ❑ Develop and recommend mitigation strategies ❑ Evaluate and recommend PPE, monitoring & detection and decontamination methods and strategies ❑ Perform a formal Hazard and Risk Assessment to include hazard identification, vulnerability and risk analysis for the incident. ❑ With Industrial Hygienists and the Medical Officer, evaluate and document recommended exposure guidelines, signs and symptoms and medical treatment for exposure. ❑ Provide technical support to Command Staff and responders START-UP CHECKLIST ❑ Gather witnesses, and others knowledgeable in the process, chemicals, building etc. ❑ Obtain MSDS sheets, site maps, building drawings, process information, etc. ❑ Utilize computer, books, witnesses and technical experts to obtain the below listed information and record on the following pages: ❑ Primary chemical and physical properties of the material(s) involved ❑ Incompatibility and reactivity ❑ Extinguishing agents and methods ❑ Evacuation and isolation distances ❑ Exposure guidelines ❑ Routes of exposure and symptoms ❑ Medical treatment and first aid ❑ PPE requirements for Entry, Standby, Decon and Medical teams ❑ Necessary monitoring and detection methods and equipment ❑ Decon methods and solutions ❑ Hazard, vulnerability and risk analysis of the incident ❑ Mitigation, confinement, containment and neutralization strategies WEATHER Time (10 minute intervals) (1 1'50 Temperature59 Wind Direction Wind Speed Humidity in % Hazardous Materials Incident Manual —Research 1/12/2012 page 1 of 8 PRIMARY HAZARDS Chemical Name(s) 0; � 3 rj ° t CAS 6 i r 30 - 2. < Formula I W Q II ' 44.1 Polymerizing .LEULFL, UEUUFL UN ID Number 3` , OM V70 Incompatibility DOT Hazard Class �40 II NFPA Ignitability 59 O' r F NFPA Reactivity Cj NFPA Health j Primary Hazard -F ay►,,l cor1b&',.bla- Secondary Hazard DX) C . PHYSICAL PROPERTIES Solid, Liquid, Gas? u,, d 144,,a � 3 rj ° t Solubility Vapor Pressure < Color I W Q II ' 44.1 Polymerizing .LEULFL, UEUUFL Odore/l 4 Sw}eJ , OM V70 Incompatibility Molecular Weight t ov--` Boiling Point 59 O' r F Melting Point ^ 6O1 ©i ° -f Freezing Point Ionization Potential FLAMMABILITY PROPERTIES Flash Point Nodc,u�o1 / wee' � 3 rj ° t Method(s) Vapor Pressure < I rn M II y1 Polymerizing .LEULFL, UEUUFL $' 70 , OM V70 Incompatibility 5-frona Ot(; c INCOMPATIBILITY AND REACTIVITY Oxidizer Nodc,u�o1 / wee' Method(s) Pyrophoric Polymerizing Incompatibility 5-frona Ot(; c t ov--` EXTINGUISHING Agent(s) Nodc,u�o1 / wee' Method(s) (01 on, �nk.A►•I RECOMMENDED EVACUATION AND ISOLATION DISTANCES ISOLATION EVACUATION Hazardous Materials Incident Manual —Research 1/12/2012 page 2 of 8 EXPOSURE GUIDELINES ( ppm = (mg/m3)(24.45)/mw ) Chemical Name(s) Qi(, TLV -TWA I QO M 3 TLV -STEL TLV -C IDLH LC50 LD50 PEL REL Carcinogen? ROUTES OF EXPOSURE & SYMPTOMS Chemical Name(s) Inhalation Ingestion Injection Absorption ROUTES OF EXPOSURE & TREATMENT & FIRST AID Chemical Name(s) Inhalation Ingestion Injection Absorption Hazardous Materials Incident Manual —Research 1/12/2012 page 3 of 8 PPE COMPATIBILITY & BREAKTHROUGH TIME Chemical Name(s) Chemical • Water, laundry detergent or liquid soap Unknown Level A or B suit breakthrough time n (CA • 0.5% Calcium Hypochlorite (swimming pool chlorine) • 0.5% Sodium hypochlorite (household bleach) Pesticides, fungicides, chlorinated phenols, pentachlorophenol, dioxains, cyanides, ammonia, other inorganic (non-acid) like arsenic, nerve agents, blister agents, biological agents and blood-borne pathogens (HIV, hepatitis, TB, etc.). Level A or B glove Y c\ • 5% acetic acid (vinegar) Alkaline corrosives Outer glove OK? 1)1 00+ Technical Decon Strategy: 4Q(jr1 CFC- COO I In 19 uclecy Inner gloves OK? An \10( Nomex coveralls n q Boots OK? n Ft Outer boots OK? V\ li M Face shield OK? lq DECONTAMINATION PPE/Equipment Decon Solutions Chemical • Water, laundry detergent or liquid soap Unknown • 5% sodium carbonate • 5% trisodium phosphate (TSP) • 5% calcium carbonate • Laundry detergent or liquid soap Inorganic acids, metal processing wastes, PCB's, heavy metals • 0.5% Calcium Hypochlorite (swimming pool chlorine) • 0.5% Sodium hypochlorite (household bleach) Pesticides, fungicides, chlorinated phenols, pentachlorophenol, dioxains, cyanides, ammonia, other inorganic (non-acid) like arsenic, nerve agents, blister agents, biological agents and blood-borne pathogens (HIV, hepatitis, TB, etc.). • 5% Trisodium phosphate, household detergents or soaps. Solvents and organic liquids like toluene, MEK, acetone, chloroform. PCB's, oils and other greases. • 5% acetic acid (vinegar) Alkaline corrosives • Calcium oxide (lime) calcium hydroxide (quick lime) or calcium carbonate. Hydrofluoric acid Technical Decon Strategy: 4Q(jr1 CFC- COO I In 19 uclecy � Emergency Decon Strategy:htfiL \ t 1n Qi It) Hazardous Materials Incident Manual —Research 1/12/2012 page 4 of 8 MONITORING & DETECTION STRATEGY Observation Physical State ❑Gas Liquid ❑Solid Material Color and Transparency: vc. h .n o✓\ y r 5 m___ Identify Location for Measurement (Hot zone, perimeter, reoccupy) Radiation: (Twice baseline) Baseline µR/hr = ❑Y VN Temperature profile (Laser, Thermal Imaging) ❑Y p(N Corrosive Atmosphere (pH strip, wetted) ❑YpIN Multi -gas meter Oxygen Content: (< 19.5% or >23%) ❑Y 214'; Flammability: (> 10% of the LEULFL),Calibration Gas: ❑Y PEfi Volatility (PID): (> 10 ppm VOC) ❑Y Et< Toxic Detectors (CO or H2S): (Indication of toxin) ❑Y 2h FID ❑Y ❑N Agent Detec r t4/7 l Ion Mobility Spectrometer (CAM, APD200) (Tox Industrial, Nerve/Blister, Explosive, Narc) Y ❑N Flame Photometric Detector(AP2C) (Nerve, Blister) Y ❑N M256A1 (CWA) ❑Y ❑N HandI p Colorimetric tubes: (Indication of toxic material) Poly I, Poly IV, other Y N ❑ ❑ Indicator paper Potassium Iodide Starch paper: (Positive for oxidizer, potential explosive) Y ❑N pH paper (liquid material): (pH less than 6 greater than 9) Y ❑N M-9 tape (liquid material): (Indication of chemical warfare agent) Y ❑N Other: Spilfyter (Lead, Petrol/Solvent, fluoride, halogen, pH, Ox, nitrates, sulfide) IV N 141 p I Toxicity Sa ling n C\ Bio 20/20 Kit protein presence ❑Y ❑N Bio Agent Ticket Raman Spectrometer Hazmat ID Infrared Document Photo Log, Video Sketch area X— 9,( iVl� C6,vl kty 01- , Hazardous Materials Incident Manual —Research 1/12/2012 page 5 of 8 INCIDENT MAP 5 v4 ccktJ mcf' Hazardous Materials Incident Manual —Research 1/12/2012 page 6 of 8 Google Maps Google Page 1 of 1 https://maps.google.com/maps?ie=UTF8&II=47.486541,-122.268026... 2/6/2015 Hazardous Materials Exposure Information Service Hazardous Materials Call to the Washington Poison Center On -Scene Call Complete On -Scene Response Form Responder requesting information? Yes Call Poison Center Physician Toxicologist Health Professional Call Provide Information. Offer Physician Consult Call Receiving Facility. Give treatment recommendations. Other Hazardous Materials Incident Manual —Research 1/12/2012 page 7 of 8 Hazardous Materials Exposure Information Service WPC tall needs the following information: n o, — VO eX P O5UYQS Exposure Date Exposure Time Location Chemical(s) Form (solid, liquid, gas) and concentration Estimated quantities (available, released) Absorption Ingestion Injection Fire: ❑ Yes Enclosed Space: ❑ Yes Setting: ❑ Urban ❑ No ❑ No ❑ Rural ❑ Sunny ❑ Partly Cloudy ❑ Overcast ❑ Raining ❑ Snow Temperature Wind speed/direction Site Sampling ❑ Yes ❑ No Known human exposure ❑ Yes ❑ No Route of entry Number of people Inhalation Absorption Ingestion Injection Duration of human exposure: Symptoms (Yes/No): Describe: Decontamination (Yes/No): Describe: Medical Treatment (Yes/No): Describe: Additional Incident Information? Hazardous Materials Incident Manual —Research 1/12/2012 page 8 of 8 VALERO MATERIAL SAFETY DATA SHEET 1. Product and Company Identification Material name Version # Issue date Revision date Supersedes date MSDS Number Product use Synonyms) Manufacturer/Supplier General Assistance Emergency 2. Hazards Identification Physical state Appearance Emergency overview OSHA regulatory status Potential health effects Routes of exposure Eyes Skin Inhalation Ingestion Target organs DIESEL FUELS 03 09 -November -2010 25 -June -2013 04 -November --2012 102 Refinery feedstock. Diesel Fuels AU Grades, Diesel Fuel No.2, Fuel ON No.2, High Sulfur Diesel Fuel, Low Sulfur Diesel Fuel, Ultra Low Sulfur Diesel Fuel, CARB (California Air Resource Board) Diesel Fuel, Off -Road Diesel Fuel, Dyed Diesel Fuel, X Grade Diesel Fuel, X-1 Diesel Fuel, R5 ULSD, B5 ULS D See section 16 for complete information. Valero Marketing & Supply Company and Affiliates P.O. Box 696000 San Antonio, TX 78269-6000 210-345-4593 24 Hour Emergency 866-565-5220 1-800-424-9300 (CHEMTREC USA) Liquid. Liquid (may be dyed red). WARNING! Combustible liquid and vapor. May be ignited by heat, sparks or flames. Heat may cause the containers to explode. Harmful if inhaled or swallowed. May be harmful if absorbed through skin. Aspiration may cause lung damage. Irritating to eyes, respiratory system and skin. In high concentrations, vapors and spray mists are narcotic and may cause headache, fatigue, dizziness and nausea. Suspect cancer hazard - may cause cancer. Prolonged exposure may cause chronic effects. Diesel exhaust has been reported to be an occupational hazard due to NIOSH -reported potential carcinogenic properties. Hydrogen sulfide, a highly toxic gas, may be present or released. Signs and symptoms of overexposure to hydrogen sulfide indude respiratory and eye irritation, dizziness, nausea, coughing, a sensation of dryness and pain in the nose, and Toss of consciousness. Odor does not provide a reliable indicator of the presence of hazardous levels in the atmosphere. Toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment. The toxicological properties of this material have not been fully investigated. Static accumulating flammable materials can become electrostatically charged even in bonded and grounded equipment. Sparks may ignite material and vapor may cause flash fire (or explosion). This product is considered hazardous under 29 CFR 1910.1200 (Hazard Communication). Inhalation. Ingestion. Skin contact Eye contact. Contact may irritate or bum eyes. Eye contact may result in corneal injury. May be harmful if absorbed through skin. Irritating to skin. Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis. Harmful if inhaled. Irritating to respiratory system. In high concentrations, vapors and spray mists are narcotic and may cause headache, fatigue, dizziness and nausea. May cause breathing disorders and lung damage. May cause cancer by inhalation. Prolonged inhalation may be harmful. Harmful if swallowed. Ingestion may result in vomiting; aspiration (breathing) of vomitus into lungs must be avoided as even small quantities may result in aspiration pneumonitis. Irritating to mouth, throat, and stomach. Blood. Eyes. Liver. Respiratory system. Skin. Kidneys. Central nervous system. DIESEL FUELS 3541 Prepared by 3E Company Version #: 03 Revison date: 25 -June -2013 Print date: 25 -June -2013 1 / 13 Chronic effects Suspect cancer hazard - may cause cancer. Liver injury may occur. Kidney injury may occur. Exposure may cause lung cancer and also noted a positive association with an increased risk of bladder cancer. May cause central nervous system disorder (e.g., narcosis involving a Ices of coordination, weakness, fatigue, mental confusion and blurred vision) and/or damage. Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis. Signs and symptoms Irritation of nose and throat. Irritation of eyes and mucous membranes. Skin irritation. Unconsciousness. Comeal damage. Narcosis. Decrease in motor functions. Behavioral changes. Edema. Liver enlargement. Jaundice. Conjunctivitis. Proteinuria. Defatting of the skin. Rash. The toxicological properties of this product have not been thoroughly investigated. Use appropriate precautions. Potential environmental effects Toxic to aquatic organisms. May cause Tong -term adverse effects in the aquatic environment. 3. Composition / Information on Ingredients Components CAS # Percent Fuels, diesel, no. 2 68476-34-6 85 -100 Biodiesel - Fatty acid methyl esters 67762-38-3 0 - 5 Fuels, diesel, C9 -18 -alkane branched and linear 1159170-26-9 0 - 5 n-Nonane 111-84-2 1 - 3 Octane (All isomers) 111-65-9 1 - 2 Hexane (Other isomers) 96-14-0 0 -1 Naphthalene 91-20-3 0 -1 n-Heptane 142-82-5 0 -1 n -Hexane 110-54-3 0 -1 4. First Aid Measures First aid procedures Eye contact Skin contact Inhalation Ingestion Notes to physician General advice 5. Fire Fighting Measures Flammable properties Extinguishing media Suitable extinguishing media Unsuitable extinguishing media Protection of firefighters Protective equipment and precautions for firefighters Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention. Remove contaminated dothing and shoes. Wash off immediately with soap and plenty of water. Get medical attention if irritation develops or persists. Wash clothing separately before reuse. Destroy or thoroughly dean contaminated shoes. If high pressure injection under the skin occurs, always seek medical attention. Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Get medical attention. Rinse mouth thoroughly. Do not induce vomiting without advice from poison control center. Do not give mouth-to-mouth resuscitation. If vomiting occurs, keep head low so that stomach content does not get into the lungs. Get medical attention immediately. In case of shortness of breath, give oxygen. Keep victim warm. Keep victim under observation. Symptoms may be delayed. The toxicological properties of this material have not been fully investigated. If exposed or concemed: get medical attention/advice. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. Wash contaminated dothing before re -use. Combustible liquid and vapor. Containers may explode when heated. Water spray. Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Do not use a solid water stream as it may scatter and spread fire. Wear full protective dothing, induding helmet, self-contained positive pressure or pressure demand breathing apparatus, protective clothing and face mask. DIESEL FUELS 3541 Prepared by 3E Company Version #: 03 Revison date: 25 -June -2013 Print date: 25 -June -2013 2/13 Fire fighting equipmenttihstructions Specific methods Hazardous combustion products Wear full protective clothing, including helmet, self-contained positive pressure or pressure demand breathing apparatus, protective dothing and face mask. Withdraw immediately in case of rising sound from venting safety devices or any discoloration of tanks due to fire. Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Move containers from fire area if you can do it without risk. In the event of fire, cool tanks with water spray. Cool containers exposed to flames with water until well after the fire is out. For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from area and let fire bum. Water runoff can cause environmental damage. Use compatible foam to minimize vapor generation as needed. In the event of fire and/or explosion do not breathe fumes. Carbon monoxide. Carbon Dioxide. Sulfur oxides. Nitrogen oxides (NOx). Hydrocarbons. Hydrogen sulfide. 6. Accidental Release Measures Personal precautions Environmental precautions Methods for containment Methods for cleaning up Keep unnecessary personnel away. Local authorities should be advised if significant spills cannot be contained. Keep upwind. Keep out of low areas. Ventilate dosed spaces before entering. Do not touch damaged containers or spilled material unless wearing appropriate protective dothing. See Section 8 of the MSDS for Personal Protective Equipment. If facility or operation has an "oil or hazardous substance contingency plan", activate its procedures. Stay upwind and away from spill. Wear appropriate protective equipment induding respiratory protection as conditions warrant. Do not enter or stay in area unless monitoring indicates that it is safe to do so. Isolate hazard area and restrict entry to emergency crew. Flammable. Review Firefighting Measures, Section 5, before proceeding with dean up. Keep all sources of ignition (flames, smoking, flares, etc.) and hot surfaces away from release. Contain spill in smallest possible area. Recover as much product as possible (e.g. by vacuuming). Stop leak if it can be done without risk. Use water spray to disperse vapors. Use compatible foam to minimize vapor generation as needed. Spilled material may be absorbed by an appropriate absorbent, and then handled in accordance with environmental regulations. Prevent spilled material from entering sewers, storm drains, other unauthorized treatment or drainage systems and natural waterways. Contact fire authorities and appropriate federal, state and local agencies. If spill of any amount is made into or upon navigable waters, the contiguous zone, or adjoining shorelines, contact the National Response Center at 1-800-424-8802. For highway or railways spills, contact Chemtrec at 1-800-424-9300. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Local authorities should be advised if significant spillages cannot be contained. Stop leak if you can do so without risk. This material is a water pollutant and should be prevented from contaminating soil or from entering sewage and drainage systems and bodies of water. Dike the spilled material, where this is possible. Prevent entry into waterways, sewers, basements or confined areas. Use non -sparking tools and explosion -proof equipment. Small Spills: Absorb spill with vermiculite or other inert material, then place in a container for chemical waste. Clean surface thoroughly to remove residual contamination. This material and its container must be disposed of as hazardous waste. Large Spills: Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Prevent product from entering drains. Do not allow material to contaminate ground water system. Should not be released into the environment. Other information Clean up in accordance with all applicable regulations. 7. Handling and Storage Handling Storage Eliminate sources of ignition. Avoid spark promoters. Ground/bond container and equipment. These alone may be insufficient to remove static electricity. Wear personal protective equipment. Avoid breathing dust/fume/gas/mistivapors/spray. Avoid contact with eyes, skin, and clothing. Do not taste or swallow. Avoid prolonged exposure. Use only with adequate ventilation. Wash thoroughly after handling. The product is combustible, and heating may generate vapors which may form explosive vapor/air mixtures. DO NOT handle, store or open near an open flame, sources of heat or sources of ignition. Protect material from direct sunlight. Take precautionary measures against static discharges. All equipment used when handling the product must be grounded. Use non -sparking tools and explosion -proof equipment. When using, do not eat, drink or smoke. Avoid release to the environment. Flammable liquid storage. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. The pressure in sealed containers can increase under the influence of heat. Keep container tightly dosed in a cool, well -ventilated place. Keep away from food, drink and animal feedingstuffs. Keep out of the reach of children. DIESEL FUELS 3541 Prepared by 3E Company Version #: 03 Revison date: 25 -June -2013 Print date: 25 -June -2013 3 / 13 8. Exposure Controls / Personal Protection Occupational exposure limits US. ACGIH Threshold Limit Values Components Type Value Form Fuels, diesel, no. 2 (CAS TWA 100 mg/m3 Inhalable fraction and 68476-34-6) vapor. Hexane (Other isomers) STEL 1000 ppm (CAS 96-14-0) TWA 500 ppm Naphthalene (CAS 91-20-3) STEL 15 ppm TWA 10 ppm n-Heptane (CAS 142-82-5) STEL 500 ppm TWA 400 ppm n -Hexane (CAS 110-54-3) TWA 50 ppm n-Nonane (CAS 111-84-2) TWA 200 ppm Octane (All isomers) (CAS TWA 300 ppm 111-65-9) US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Components Type Value Naphthalene (CAS 91-20-3) PEL 50 mg/m3 10 ppm n-Heptane (CAS 142-82-5) PEL 2000 mg/m3 500 ppm n -Hexane (CAS 110-54-3) PEL 1800 mg/m3 500 ppm Octane (All isomers) (CAS PEL 2350 mg/m3 111-65-9) 500 ppm Canada. Alberta OELs (Occupational Health & Safety Code, Schedule 1, Table 2) Components Type Value Fuels, diesel, no. 2 (CAS TWA 100 mg/m3 68476-34-6) Hexane (Other isomers) STEL 3500 mg/m3 (CAS 96-14-0) 1000 ppm TWA 1760 mg/m3 500 ppm Naphthalene (CAS 91-20-3) STEL 79 mg/m3 15 ppm TWA 52 mg/m3 10 ppm n-Heptane (CAS 142-82-5) STEL 2050 mg/m3 500 ppm TWA 1640 mg/m3 400 ppm n -Hexane (CAS 110-54-3) TWA 176 mg/m3 50 ppm n-Nonane (CAS 111-84-2) TWA 1050 mg/m3 200 ppm Octane (All isomers) (CAS TWA 1400 mg/m3 111-65-9) 300 ppm Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and Safety Regulation 296/97, as amended) Components Type Value Form Fuels, diesel, no. 2 (CAS TWA 100 mg/m3 Vapor and aerosol. 68476-34-6) DIESEL FUELS 3541 Prepared by 3E Company Version #: 03 Revison date: 25 -June -2013 Print date: 25 -June -2013 4 / 13 Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and Safety Regulation 296/97, as amended) Components Type Value Form Hexane (Other isomers) TWA 200 ppm (CAS 96-14-0) Naphthalene (CAS 91-20-3) STEL 15 ppm TWA 10 ppm n-Heptane (CAS 142-82-5) STEL 500 ppm TWA 400 ppm n -Hexane (CAS 110-54-3) TWA 20 ppm n-Nonane (CAS 111-84-2) TWA 200 ppm Octane (All isomers) (CAS TWA 300 ppm 111-65-9) Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents) Components Type Value Form Fuels, diesel, no. 2 (CAS TWA 100 mg/m3 Inhalable fraction and 68476-34-6) vapor. Hexane (Other isomers) STEL 1000 ppm (CAS 96-14-0) TWA 500 ppm Naphthalene (CAS 91-20-3) STEL 15 ppm TWA 10 ppm n-Heptane (CAS 142-82-5) STEL 500 ppm TWA 400 ppm n -Hexane (CAS 110-54-3) TWA 50 ppm n-Nonane (CAS 111-84-2) TWA 200 ppm Octane (All isomers) (CAS TWA 300 ppm 111-65-9) Canada. Quebec OELs. (Ministry of Labor - Regulation Respecting the Quality of the Work Environment) Components Type Value Hexane (Other isomers) STEL 3500 mg/m3 (CAS 96-14-0) 1000 ppm TWA 1760 mg/m3 500 ppm Naphthalene (CAS 91-20-3) STEL 79 mg/m3 15 ppm TWA 52 mg/m3 10 ppm n-Heptane (CAS 142-82-5) STEL 2050 mg/m3 500 ppm TWA 1640 mg/m3 400 ppm n -Hexane (CAS 110-54-3) TWA 176 mg/m3 50 ppm n-Nonane (CAS 111-842) TWA 1050 mg/m3 200 ppm Octane (All isomers) (CAS STEL 1750 mg/m3 111-65-9) TWA Mexico. Occupational Exposure Limit Values Components Type 375 ppm 1400 mg/m3 300 ppm Value Hexane (Other isomers) (CAS 96-14-0) STEL 3500 mg/m3 TWA 1000 ppm 1760 mg/m3 DIESEL FUELS 3541 Prepared by 3E Company Version #: 03 Revison date: 25 -June -2013 Print date: 25 -June -2013 5 / 13 Mexico. Occupational Exposure Limit Values Components Type Value Naphthalene (CAS 91-20-3) n-Heptane (CAS 142-82-5) n -Hexane (CAS 110-54-3) n-Nonane (CAS 111-84-2) Octane (All isomers) (CAS 111-65-9) STEL TWA STEL TWA TWA STEL TWA STEL TWA Exposure guidelines Canada - Alberta OELs: Skin designation Naphthalene (CAS 91-20-3) n -Hexane (CAS 110-54-3) Canada - British Columbia OELs: Skin designation Fuels, diesel, no. 2 (CAS 68476-34-6) Naphthalene (CAS 91-20-3) n -Hexane (CAS 110-54-3) Canada - Manitoba OELs: Skin designation Fuels, diesel, no. 2 (CAS 68476-34-6) Naphthalene (CAS 91-20-3) n -Hexane (CAS 110-54-3) Canada - Ontario OELs: Skin designation Fuels, diesel, no. 2 (CAS 68476-34-6) Naphthalene (CAS 91-20-3) n -Hexane (CAS 110-54-3) Canada - Quebec OELs: Skin designation n -Hexane (CAS 110-54-3) Canada - Saskatchewan OELs: Skin designation Fuels, diesel, no. 2 (CAS 68476-34-6) Naphthalene (CAS 91-20-3) n -Hexane (CAS 110-54-3) Mexico OELs: Skin designation n-Heptane (CAS 142-82-5) US - California OELs: Skin designation n -Hexane (CAS 110-54-3) US ACGIH Threshold Limit Values: Skin designation Fuels, diesel, no. 2 (CAS 68476-34-6) Naphthalene (CAS 91-20-3) n -Hexane (CAS 110-54-3) Engineering controls 500 ppm 75 mghn3 15 ppm 50 mg/m3 10 ppm 2000 mg/m3 500 ppm 1600 mg/m3 400 ppm 176 mg/m3 50 ppm 1300 mg/m3 250 ppm 1050 mg/m3 200 ppm 1800 mg/m3 375 ppm 1450 mghn3 300 ppm Can be absorbed through the skin. Can be absorbed through the skin. Can be absorbed through the skin. Can be absorbed through the skin. Can be absorbed through the skin. Can be absorbed through the skin. Can be absorbed through the skin. Can be absorbed through the skin. Can be absorbed through the skin. Can be absorbed through the skin. Can be absorbed through the skin. Can be absorbed through the skin. Can be absorbed through the skin. Can be absorbed through the skin. Can be absorbed through the skin. Can be absorbed through the skin. Can be absorbed through the skin. Can be absorbed through the skin. Can be absorbed through the skin. Can be absorbed through the skin. Provide adequate general and local exhaust ventilation. Use process enclosures, local exhaust ventilation, or other engineering controls to control airbome levels below recommended exposure limits. Use explosion -proof equipment. Personal protective equipment Eye / face protection Wear safety glasses. If splash potential exists, wear full face shield or chemical goggles. DIESEL FUELS 3541 Prepared by 3E Company Version #: 03 Revison date: 25 -June -2013 Print date: 25 -June -2013 6 / 13 Skin protection Respiratory protection General hygiene considerations Wear chemical -resistant, impervious gloves. Full body suit and boots are recommended when handling large volumes or in emergency situations. Flame retardant protective clothing is recommended. Use a properly fitted, air -purifying or air -fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. If workplace exposure limits for product or components are exceeded, NIOSH approved equipment should be wom. Proper respirator selection should be determined by adequately trained personnel, based on the contaminants, the degree of potential exposure and published respiratory protection factors. This equipment should be available for nonroutine and emergency use. Consult supervisor for special handling instructions. Avoid contact with eyes. Avoid contact with skin. Keep away from food and drink. Wash hands before breaks and immediately after handling the product. Provide eyewash station and safety shower. Handle in accordance with good industrial hygiene and safety practice. 9. Physical & Chemical Properties Appearance Physical state Form Color Odor Odor threshold pH Vapor pressure Vapor density Boiling point Melting point/Freezing point Solubility (water) Specific gravity Flash point Flammability limits in air, upper, % by volume Flammability limits in air, lower, % by volume Auto -ignition temperature Evaporation rate Viscosity Other data Flash point class Liquid (may be dyed red). Liquid. Liquid. Clear. Straw. Kerosene (strong). Not available. Not available. < 1 mm Hg (20°C) 3(Air =1) 325 - 700 °F (162.78 - 371.11 °C) -60.07 °F (-51.15 °C) Estimated Not available. 0.82 - 0.87 (60°F) > 100.0 °F (> 37.8 °C) Closed Cup 8% 0.4 % 494.96 °F (257.2 °C) 0 2 - 4.5 mm2/s Combustible II 10. Chemical Stability & Reactivity Information Chemical stability Conditions to avoid Incompatible materials Hazardous decomposition products Possibility of hazardous reactions Stable under normal temperature conditions and recommended use. Heat, flames and sparks. Ignition sources. Contact with incompatible materials. Do not pressurize, cut, weld, braze, solder, drill, grind or expose empty containers to heat, flame, sparks, static electricity, or other sources of ignition; they may explode and cause injury or death. Strong oxidizing agents. Carbon oxides. Sulfur oxides. Nitrogen oxides (NOx). Hydrocarbons. Hydrogen sulfide. Hazardous polymerization does not occur. DIESEL FUELS 3541 Prepared by 3E Company Version #: 03 Revison date: 25 -June -2013 Print date: 25 -June -2013 7 / 13 11. Toxicological Information Toxicological data Components Species Test Results Fuels, diesel, no. 2 (CAS 68476-34-6) Acute Inhalation LC50 Rat 4.1 mg/I, 4 hours Naphthalene (CAS 91-20-3) Acute Dermal LD50 Rabbit > 2 g/kg Oral LD50 Rat 490 mg/kg n-Heptane (CAS 142-82-5) Acute Inhalation LC50 Rat 103 mgA, 4 Hours n -Hexane (CAS 110-54-3) Acute Oral LD50 Rat 28710 mg/kg n-Nonane (CAS 111-84-2) Acute Inhalation LC50 Rat 3200 mgA, 4 Hours Octane (All isomers) (CAS 111-65-9) Acute Inhalation LC50 Rat 118 mgs, 4 Hours Sensitization This substance may have a potential for sensitization which may provoke an allergic reaction among sensitive individuals. Acute effects Harmful if inhaled, absorbed through skin, or swallowed. Harmful: may cause lung damage if swallowed. Irritating to eyes, respiratory system and skin. In high concentrations, vapors and spray mists are narcotic and may cause headache, fatigue, dizziness and nausea. Hydrogen sulfide, a highly toxic gas, may be present. Signs and symptoms of overexposure to hydrogen sulfide indude respiratory and eye irritation, dizziness, nausea, coughing, a sensation of dryness and pain in the nose, and Toss of consciousness. Odor does not provide a reliable indicator of the presence of hazardous levels in the atmosphere. The toxicological properties of this material have not been fuNy investigated. Chronic effects Contains organic solvents which in case of overexposure may depress the central nervous system causing dizziness and intoxication. Repeated exposure to naphthalene may cause cataracts, allergic skin rashes, destruction of red blood cells, and anemia, jaundice, kidney and liver damage. Danger of serious damage to health by prolonged exposure. Prolonged or repeated overexposure may cause central nervous system, kidney, liver, and lung damage. Subchronic effects Liver and kidney damage may occur after prolonged and repeated exposure. Carcinogenicity International Agency for Research on Cancer (IARC): Whole diesel engine exhaust — IARC Group 1. Exposure may cause lung cancer and also noted a positive association with an increased risk of bladder cancer. Diesel exhaust has been reported to be an occupational hazard due to NIOSH -reported potential carcinogenic properties. ACGIH Carcinogens Fuels, diesel, no. 2 (CAS 68476-34-6) A3 Confirmed animal carcinogen with unknown relevance to humans. Naphthalene (CAS 91-20-3) A4 Not classifiable as a human carcinogen. IARC Monographs. Overall Evaluation of Carcinogenicity Fuels, diesel, no. 2 (CAS 68476-34-6) 3 Not classifiable as to carcinogenicity to humans. DIESEL FUELS 3541 Prepared by 3E Company Version #: 03 Revison date: 25 -June -2013 Print date: 25 -June -2013 8 / 13 Naphthalene (CAS 91-20-3) 2B Possibly carcinogenic to humans. US NTP Report on Carcinogens: Anticipated carcinogen Naphthalene (CAS 91-20-3) Reasonably Anticipated to be a Human Carcinogen. Epidemiology Studies have shown a risk of spontaneous abortions in women exposed to high concentrations of organic solvents during pregnancy. Pre-existing skin conditions induding dermatitis might be aggravated by exposure to this product. Mutagenicity No component of this product present at levels greater than or equal to 0.1% is identified as a mutagen by OSHA. Neurological effects Chronic exposure to high concentrations of various hydrocarbon blends may lead to polyneuropathy (peripheral nerve damage), charaderized by progressive weakness and numbness in the extremities, Toss of deep tendon reflexes and reduction of motor nerve conduction velocity. Numerous cases of polyneuritis have been reported following prolonged exposures to a petroleum fraction containing various isomers of heptane as major ingredients. May cause central nervous system disorder (e.g., narcosis involving a loss of coordination, weakness, fatigue) and/or damage. Reproductive effects Napthalene interferes with embryo development in experimental animals at dose levels that cause matemal toxicity. In humans, excessive exposure to this agent may cause hemolytic anemia in the mother and fetus. Teratogenicity The components of this product are not reported to cause teratogenic effects in humans. Based on best current information, there is no known teratogenicity associated with this product. Further information Symptoms may be delayed. Toxicological properties of this material have not been fully investigated. 12. Ecological Information Ecotoxicological data Components Species Test Results Fuels, diesel, no. 2 (CAS 68476-34-6) Aquatic Acute Crustacea EL50 Daphnia magna 68 mg/I, 48 hours Fish LL50 Oncorhynchus mykiss 65 mgA, 96 hours Naphthalene (CAS 91-20-3) Aquatic Crustacea EC50 Water flea (Daphnia magna) 1.09 - 3.4 mgA, 48 hours Fish LC50 Pink salmon (Oncorhynchus gorbuscha) 1.11 - 1.68 mgA, 96 hours n-Heptane (CAS 142-82-5) Aquatic Fish LC50 Westem mosquitofish (Gambusia affinis) 4924 mgA, 96 hours n -Hexane (CAS 110-54-3) Aquatic Fish LC50 Fathead minnow (Pimephales promelas) 2.101 - 2.981 mg/I, 96 hours Ecotoxicity Toxic to aquatic organisms, may cause Tong -term adverse effects in the aquatic environment. Aquatic toxicity Toxic to aquatic organisms, may cause Tong -term adverse effects in the aquatic environment. Persistence and degradability Not available. Bioaccumulation / Not available. Accumulation Partition coefficient Hexane (Other isomers) (CAS 96-14-0) 3.6 Octane (All isomers) (CAS 111-65-9) 5.18 n-Heptane (CAS 142-82-5) 4.66 n -Hexane (CAS 110-54-3) 3.9 n-Nonane (CAS 111-84-2) 5.46 Mobility in environmental No data available. media 13. Disposal Considerations Waste codes D001: Waste Flammable material with a flash point <140 °F DIESEL FUELS 3541 Prepared by 3E Company Version #: 03 Revison date: 25 -June -2013 Print date: 25 -June -2013 9113 US RCRA Hazardous Waste U Ust: Reference Naphthalene (CAS 91-20-3) U165 Disposal instructions 14. Transport Information DOT Basic shipping requirements: UN number Proper shipping name Hazard class Packing group Environmental hazards Marine pollutant Additional information: Special provisions Packaging exceptions Packaging non bulk Packaging bulk IATA UN number UN proper shipping name Transport hazard class(es) Packing group Environmental hazards Labels required ERG code Special precautions for user IMDG UN number UN proper shipping name Transport hazard class(es) Packing group Environmental hazards Marine pollutant Labels required EmS Transport in bulk according to Annex Il of MARPOL 73/78 and the IBC Code TDG UN number Proper shipping name Hazard class Packing group Marine pollutant Special provisions Dispose in accordance with all applicable regulations. Dispose of this material and its container to hazardous or special waste collection point. Incinerate the material under controlled conditions in an approved incinerator. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. UN1202 Diesel fuel Combustible Liquid lit Yes 144, B1, IB3, T2, TP1 150 203 242 UN1202 Diesel fuel 3 III Yes 3 3L Read safety instructions, SDS and emergency procedures before handling. UN1202 DIESEL FUEL 3 Ili Yes 3 F -E, S -E Not applicable. However, this product is a liquid and if transported in bulk covered under MARPOL 73/78, Annex 1. UN1202 DIESEL FUEL Combustible Liquid Ili Yes 82, 88 15. Regulatory Information US federal regulations TSCA Section 12(b) Export Notification (40 CFR 707, Subpt D) n-Nonane (CAS 111-84-2) 1.0 % One -Time Export Notification only. Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPS) List Naphthalene (CAS 91-20-3) n -Hexane (CAS 110-54-3) US EPCRA (SARA Tide 111) Section 313 - Toxic Chemical: De minimis concentration Naphthalene (CAS 91-20-3) 0.1 % n -Hexane (CAS 110-54-3) 1.0 % DIESEL FUELS 3541 Version alk 03 Revison date: 25 -June -2013 Print date: 25 -June -2013 Prepared by 3E Company 10 / 13 US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance Naphthalene (CAS 91-20-3) Listed. n -Hexane (CAS 110-54-3) Listed. CERCLA (Superfund) reportable quantity (lbs) (40 CFR 302.4) n-Nonane: 100 Octane (All isomers): 100 Hexane (Other isomers): 100 Naphthalene: 100 n -Hexane: 5000 Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Yes Delayed Hazard - Yes Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Section 302 extremely No hazardous substance (40 CFR 355, Appendix A) SARA 311/312 Hazardous Yes chemical Drug Enforcement Not controlled Administration (DEA) (21 CFR 1308.11-15) WHMIS status Controlled WHMIS classification B3 - Combustible Liquids D2A - Other Toxic Effects -VERY TOXIC D2B - Other Toxic Effects -TOXIC WHMIS labeling Inventory status Country(s) or region Australia Canada Canada China Europe Inventory name On inventory (yes/nor Australian Inventory of Chemical Substances (AICS) Yes Domestic Substances List (DSL) Yes Non -Domestic Substances List (NDSL) No Inventory of Existing Chemical Substances in China (IECSC) Yes European Inventory of Existing Commercial Chemical Yes Substances (EINECS) Europe European List of Notified Chemical Substances (ELINCS) No Japan Inventory of Existing and New Chemical Substances (ENCS) No Korea Existing Chemicals List (ECL) Yes New Zealand New Zealand Inventory Yes Philippines Philippine Inventory of Chemicals and Chemical Substances Yes (PICCS) United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes *A "Yes" indicates this product complies with the inventory requirements administered by the goveming country(s). A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). State regulations WARNING: This product contains chemicals known to the State of Califomia to cause cancer and birth defects or other reproductive harm. US - Califomia Hazardous Substances (Director's): Listed substance Hexane (Other isomers) (CAS 96-14-0) Listed. Naphthalene (CAS 91-20-3) Listed. n-Heptane (CAS 142-82-5) Listed. DIESEL FUELS 3541 Prepared by 3E Company Version #: 03 Revison date: 25 -June -2013 Print date: 25 -June -2013 11 / 13 n -Hexane (CAS 110-54-3) n-Nonane (CAS 111-84-2) Octane (All isomers) (CAS 1 US - California Proposition 65 Benzene (CAS 71-43-2) Toluene (CAS 108-88-3) US - California Proposition 65 Benzene (CAS 71-43-2) US - California Proposition 65 Benzene (CAS 71-43-2) Toluene (CAS 108-88-3) US - California Proposition 65 Toluene (CAS 108-88-3) US - California Proposition 65 Benzene (CAS 71-43-2) US - New Jersey RTK - Substances: Listed substance Naphthalene (CAS 91-20-3) n-Heptane (CAS 142-82-5) n -Hexane (CAS 110-54-3) n-Nonane (CAS 111-84-2) Octane (All isomers) (CAS 111-65-9) US. Massachusetts RTK - Substance List Hexane (Other isomers) (CAS 96-14-0) Naphthalene (CAS 91-20-3) n-Heptane (CAS 142-82-5) n -Hexane (CAS 110-54-3) n-Nonane (CAS 111-84-2) Octane (All isomers) (CAS 111-65-9) US. New Jersey Worker and Community Right -to -Know Act Usted. Listed. 11-65-9) Listed. - Carcinogens & Reproductive Toxicity (CRT): Usted substance Listed. Listed. - CRT: Listed date/Carcinogenic substance Listed: February 27, 1987 Carcinogenic. - CRT: Listed date/Developmental toxin Listed: December 26, 1997 Developmental toxin. Listed: January 1, 1991 Developmental toxin. - CRT: Listed date/Female reproductive toxin Listed: August 7, 2009 Female reproductive toxin. - CRT: Listed date/Male reproductive toxin Listed: December 26, 1997 Male reproductive toxin. Listed. Listed. Usted. Listed. Listed. Listed. Listed. Listed. Listed. Listed. Listed. Fuels, diesel, no. 2 (CAS 68476-34-6) Naphthalene (CAS 91-20-3) n -Hexane (CAS 110-54-3) US. Pennsylvania RTK - Hazardous Substances Fuels, diesel, no. 2 (CAS 68476-34-6) Hexane (Other isomers) (CAS 96-14-0) Naphthalene (CAS 91-20-3) n-Heptane (CAS 142-82-5) n -Hexane (CAS 110-54-3) n-Nonane (CAS 111-84-2) Octane (All isomers) (CAS 111-65-9) 10000 lbs 500 lbs 500 lbs Listed. Listed. Usted. Usted. Usted. Listed. Listed. Mexico regulations This safety data sheet was prepared in accordance with the Official Mexican Standard (NMX-R-019-SCFI-2011). 16. Other Information Further information Other information HMIS® ratings NFPA ratings HMIS® is a registered trade and service mark of the NPCA. Note: This material Safety Data Sheet applies to the listed products and synonym descriptions for Hazard Communication purposes only. Technical Specifications vary greatly depending on the products and are not reflected in this document. Consult specification sheets for technical information. Health: 2* Flammability: 2 Physical hazard: 0 Health: 2 Flammability: 2 Instability: 0 DIESEL FUELS 3541 Prepared by 3E Company Version #: 03 Revison date: 25 -June -2013 Print date: 25 -June -2013 12 / 13 CAD/Ti Detailed History for Fire Inc #TF150000462 As of 2/06/2015 14:47:19 Output for: TF1138 Priority:2 Type:SPILL - Flammable Liquid Location:DAYS INN, TUK at 13050 48TH AVE S, TUK LocCross:btwn END and INTERURBAN AVE S Created: 02/06/2015 10:56:26 PD33 V01013 Entered: 02/06/2015 10:56:26 PD33 V01013 Dispatch: 02/06/2015 10:56:31 FD23 V01029 Enroute: 02/06/2015 10:57:38 FD24 V01229 Onscene: 02/06/2015 11:03:27 FD24 V01229 Closed: 02/06/2015 14:08:27 FD23 V01161 ICUnit: PrimeUnit:BOT51 Dispo: Type:SPILL - Flammable Liquid Agency:TF Group:FIR4(T9) Station:53 Map Box:TF815W Case #:CKF150002223, CTF150000525 ❑ Detail Page 1 of 3 15-0- 10:56:26 CREATE 10:56:26 ENTRY 10:56:26 -SELECT 10:56:26 -SGGEST 10:56:26 -PREMIS 10:56:31 DISP 10:56:31 DISP 10:56:31 DISP 10:56:31 DISP 10:56:31-PRIU 10:56:31 -CASE 10:56:31 -CASE 10:57:09 REDIR 10:57:25 CLEAR 10:57:38 BACKER 10:57:38 BACKER 10:57:46 CLEAR 10:57:51 PRMPT 10:57:51 -PRIU 10:58:54 *ENRTE 10:59:04 *ENRTE 10:59:25 *ENRTE 10:59:42 BACKER 11:00:11 MISCN 11:00:58 *ENRTE 11:02:11 COMBIN 11:02:46 BACKER Location:DAYS INN, TUK Type:SPILL Group:T9 RD/MapBox:TF815W TypeDesc:Flammable Liquid LocDesc:at 13050 48TH AVE S, TUK LocCross:btwn END and INTERURBAN AVE S Priority:2 Response:SPILLTF Agency:TF Beat/Stn:53 LocType:C Comment:LARGE AMOUNT OF OIL OR GAS GOING INTO RIVER, PD ONSCN, GO DOWN 48 AVE S FROM LOC TO THE DEAD END BY THE GREN RIVER TRAIL Unit:L54 TFBC HM76I HM76 Comment:PPR, FPR L54 Operator:TF1114 TF2186 TF1127 OperNames:KONIECZKA, J; HARTJOY, JEFF; EVANS, JAMES E. TFBC HM76I HM76 Operator:KF0236 OperNames:STROBEL, NATHAN (PEER) L54 L54 Case#:CTF150000525 HM76I Case#:CKF150002223 Group:T9-->FIR3 TFBC E51 UnitID:L54 Location:DAYS INN, TUK Operator:TF1106 TF2318 TF1128 TF2167 OperNames:JOHNSON, AARON; FAIRE, BRODY; BROWNING, CATHY; PLANELLAS, GREG B51 UnitID:L54 Location:DAYS INN, TUK Operator:TF1122 OperNames:PETERSON, LAVERN HM76I L54 HM76 E51 HM76 HM76 E76 UnitID:HM76 Location:DAYS INN, TUK Operator:KF0210 KF0226 KF0236 OperNames:HARDMAN, DAN (PEER); MAU, JOSEPH; STROBEL, NATHAN (PEER) E51 Comment:2 HAZMAT TECHS, KETTLE TRUCK W/ABSORBENT E76 Service:F Inc:#TF150000463 Type:ODORXT Agency:TF FM51 UnitID:B51 Location:DAYS INN, TUK Operator:TF1170 OperNames:TOMASO, DON (FM51)206.396.8910 http://vcc-tib-webB780LiveCAD/Html/SystemDocs/CADlnterface.aspx?CHQ+CTF 15000... 2/6/2015 CAD/Ti Page 2 of 3 11:03:27 ONSCN 11:03:37 BACKER 11:04:00 BACKER 11:05:23 CLOS 11:05:39 MISCN 11:05:57 CLOS 11:06:46 BACKER 11:07:07 MISCN 11:07:27 MISCN 11:08:11 PG 11:08:41 MISCN 11:09:06 MISCN 11:09:42 MISCN 11:10:08 MISCN 11:10:23 BACKER 11:10:28 *ENRTE 11:10:30 ONSCN 11:10:44 ONSCN 11:12:50 MISCN 11:13:55 MISCN 11:15:14 *ENRTE 11:15:15 *ONSCN 11:15:21 MISCN 11:15:53 MISCN 11:16:45 MISCN 11:17:12 REDIR 11:17:52 MISCN 11:20:04 CLOS 11:20:27 MISCN 11:20:55 MISCN 11:21:07 MISCN 11:22:07 CLOS 11:22:13 *ONSCN 11:26:48 MISCN 11:28:24 MISCN 11:30:49 CLOS 11:30:58 CLOS 11:31:46 *ONSCN 11:32:13 MISCN 11:35:02 MISCN 11:38:48 *AOR 11:38:48 *CLEAR 11:39:38 MISCN 11:40:21 MISCN B51 L54 UnitID:E51 Location:12400 42 AV S Operator:TF1114 TF2186 TF1127 OperNames:KONIECZKA, J; HARTJOY, JEFF; EVANS, JAMES E. Comment:WBOOMS B76 UnitID:E76 Location:DAYS INN, TUK Operator:KF0133 OperNames:THOMPSON, GUY FM51 Location:42/RIVER Comment:ODOR INV B51 Comment:PRODUCT OUT OF STORM DRAIN, ADD E53 TO BOAT FOR FURTHER INSTRUCTIONS. B51 Location:DUWAMISH COMMAND E53 UnitID:E51 Location:PICKUP BOAT Operator:TF1135 TF2186 TF1124 OperNames:BECKMAN, KEN; HARTJOY, JEFF; OBRIEN, PATRICK Comment:FROM STN 68 B51 Comment:CONTACT DOE FM51 Comment:GOOD SHEEN ALL THE WAY PAST COMM CENTER, AT LEAST TO 115TH BY NOW. E53 Comment:CONF'ING YOU ARE GOING TO THE BOAT, PER B51. HM76 Comment:HELD UP BY TRAIN FMSI Comment:WSP TO I5, 115/42, POSS I5 SPILL B51 Comment:NOT I5, IS FROM STORM DRAIN ON 48TH E51 Comment:NEED AS MANY BOOMS AS POSSIBLE CH54 UnitID:E51 Location:DAYS INN, TUK Operator:TF1112 OperNames:GRISHAM, MARTY Comment:WBOOMS FROM STN 51 HM76 E76 E51 E53 Comment:COME UP TO 48TH B51 Comment:PUBLIC WORKS/PUBLIC WORKS SUPERVISOR CH54 L54 B51 Comment:DOE ONSC RESPONSE REQ'D/B51 DIRECT # 206-396-0361 E53 Comment:10 MINS TO THE BOAT B51 Comment:TPD FRONT COUNTER CALLING OUT PUBLIC WORKS Group:FIR3—>FIR4 FM51 Comment:SHEEN JUST PASSING 112TH PEDESTRIAN BRIDGE EU L54 Location:RECON/LOCAL STORAGE YARDS Comment:ATTEMPTING TO DETERMINE SOURCE E51 Comment:IN PROGRESS, APPROX 2 MINS ETA TO BOOMS IN PLACE CH54 Comment:UPON ARRIVAL, REPORT TO COMMAND POST CH54 Comment:BRINGING PACKAGE OF BOOMS AND ADDITIONAL PADS B51 Location:DUWAMISH COMMAND Comment:KEYSTAION TO 53/54 CH54 CH54 Comment:CANCEL KEY STN MOVE TO 54 L54 Comment:TO COMMAND: 1 RP SAYS LARGE SHEEN ON NEARBY RD, WHERE INTERURBAN TURNS INTO EM NEAR COMM CENTER E76 Location:HAZMAT GROUP SUPV E51 L4 Location:HAZMAT GROUP B76 L54 Comment:TO HAZMAT GROUP SUPV:SURVEY OF YARD? WORKING ON IT NOW, WORKING UP SOUTH SIDE OF 48TH AND WILL COME BACK DOWN SOUTH SIDE E51 Comment:SPILL STILL COMING OUT OF STORM DRAIN, 90% CONTAINMENT W/PRIMARY BOOM, PRELIM ESTIMATION OF 50 GALLONS, RECOMMEND SECONDARY BOOM FM51 FM51 B51 Comment:TO E76:PUBLIC WORKS ONSC? E76: NEG - CHECKING ETA B51 Comment:PUBLIC WORKS ENRT, ETA 5 MINS TO COMMAND POST http://vcc-tib-webB780LiveCAD/Html/SystemDocs/CADlnterface.aspx?CHQ+CTF 15000... 2/6/2015 CAD/Ti Page 3 of 3 11:40:32 MISCN B51 Comment:TELEPHONE CONTACT W/DOE, ALSO ENRT 11:41:35 MISCN E51 Comment:START AIR QUALITY MONITORING 11:43:07 MISCN E76 Comment:IN CHARGE OF ANY DECON NECESSARY 11:44:28 BACKER BOT51 UnitID:E53 Location:PICKUP BOAT 11:44:39 MISCN BOT51 Comment:IN THE WATER, ENRT, UNDER HAZMAT GROUP 11:44:46 CHGLOC B51 Location:HAZMAT GROUP 11:45:18 MISCN B51 Comment:ON ARRIVAL, TIE IN W/E51 - WILL RECEIVE DIRECTIONS ON PLACING THE BOOM @ END OF 48 AV S 11:46:02 ONSCN BOT51 11:47:43 MISCN B51 Comment:PUBLIC WORKS OS 11:53:25 MISCN L54 Comment:POSS FOUND LEAK, COMING FROM A TRUCK IN A PARKING LOT THAT WAS BEING WORKED ON...IS NOT LEAKING NOW, JUST RESIDUAL ON SURFACE 12:11:39 MISCN BOT51 Comment:RETRIEVING ADDITIONAL BOOMS FROM STN 51 12:16:30 CLOS B51 Location:DUWAMISH COMMAND Comment:DOE ONSC 12:17:41 CLOS E53 Location:BOT 51 12:18:14 CLOS L54 Location:HUSKY INTERNATIONAL, TUK Comment:AND 76 DIESEL ISLAND/CHECKING FOR POSSIBLE SOURCE 12:34:19 CLEAR B76 12:41:00 MISCN B51 Comment:DISBANDING HAZMAT GROUP 12:41:08 CHGLOC E76 12:41:10 ONSCN E76 12:41:17 CHGLOC E51 12:41:19 ONSCN E51 12:42:28 MISCN B51 Comment:NOT SEEING MUCH PRODUCT, NO NEED FOR MORE BOOMS. 12:45:19 *AOR CH54 12:45:19 *CLEAR CH54 12:55:41 CLEAR HM76 E76 12:57:08 MISCN BOT51 Comment:RELEASED FROM SCENE 12:57:38 MISCN B51 Comment:DISBANDING COMMAND, DOE HAVING PRIVATE CONTRACTOR RESPOND, ALL UNITS AV 12:57:40 CLEAR B51 12:57:42 AVAIL BOT51 E51 E53 L54 12:59:54 *AOR L54 12:59:54 *CLEAR L54 13:09:50 *AOR E51 13:09:50 *CLEAR E51 13:16:03 *AOR E53 13:16:03 *CLEAR E53 14:08:27 CLEAR BOT51 14:08:27 -PRIU BOT51 14:08:27 -CLEAR 14:08:27 CLOSE http://vcc-tib-webB780LiveCAD/Html/SystemDocs/CADlnterface.aspx?CHQ+CTF 15000... 2/6/2015