HomeMy WebLinkAboutHAZMAT 99-0382 - 3301 S NORFOLK ST - AMMONIA LEAK ON 2/3/19993301 S NORFOLK ST
AMMONIA LEAK
HAZMAT # 99-0382
* * *.* * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * *
NIOSH POCKET GUIDE TO CHEMICAL' HAZARDS
*
Produced by: US National Institute for Occupational Safety and Health *
Provided by: Canadian Centre for Occupational Health and Safety
* * * * * * * * * * * * * . * * * * * * * * * * NPG diskette - March 1998 *
CHEMICAL NAME
SYNONYMS
CAS REGISTRY NUMBER :
RTECS NUMBER
DOT/NAERG NUMBERS
CCOHS RECORD NUMBER .
MOLECULAR FORMULA
NOTE
DESCRIPTION
DESCRIPTION NOTE
Ammonia
Anhydrous ammonia
Aqua ammonia
Aqueous ammonia
7664-41-7
BO0875000
1005 / 125 (anhydrous)
2672 154 (10-35 percent solution)
2073 125 (>35-50 percent solution)
1005 125 (>50 percent solution)
28
NH3
: Often used in an aqueous solution.
: Colorless gas with a pungent, suffocating odor.
: Shipped as a liquefied compressed gas. Easily liquefied
under pressure.
*** EXPOSURE LIMITS
***
CONVERSION FACTOR :
1 ppm = 0.70 mg/m3 at 25 deg C and 1 atmosphere
NIOSH RECOMMENDED EXPOSURE LIMITS (REL)
TIME WEIGHTED AVERAGE (TWA) : 25 ppm (18 mg/m3)
SHORT TERM EXPOSURE LIMIT (STEL) : 35 ppm•(27 mg/m3)
OSHA CURRENT PERMISSIBLE EXPOSURE LIMITS (PEL)
TIME WEIGHTED AVERAGE (TWA) : 50 ppm (35 mg/m3)
OSHA 1989 (VACATED) PERMISSIBLE EXPOSURE LIMITS (PEL)
TIME WEIGHTED AVERAGE (TWA) : 25 ppm (18 mg/m3)
SHORT TERM EXPOSURE LIMIT (STEL) : 35 ppm (27 mg/m3)
IDLH CONCENTRATION : 300 ppm
*** RESPIRATORY PROTECTION ***
RECOMMENDATIONS FOR RESPIRATOR SELECTION
BASED ON NIOSH REL
s
UP TO 250 ppm:
Any chemical cartridge respirator with cartridge(s) providing protQction
against the compound of concern (APF = 10). Substance reported to pause eye
irritation or damage; requires eye protection
OR Any supplied -air respirator (APF = 10). Substance reported to cause eye
irritation or damage; requires eye protection
UP TO 300 ppm:
Any supplied -air respirator operated in a continuous -flow mode (APF = 25).
Substapce reported to cause eye irritation or damage; requires eye protection
OR Any powered, air -purifying respirator with cartridge(s) providing
protection against the compound of concern (APF = 25). Substance reported to
cause eye irritation or damage; requires eye protection
OR Any chemical cartridge respirator with a full facepiece anO'cartridge)s)
f
f
providing protection against the compound of concern (APF = 50)
'OR ,Any air -purifying, full-facepiece respitator..(gas mask) with a chin -style,
,'frdnt- or back -mounted canister providing protection against the compound of
concern (APF = 50)
OR Any self-contained breathing apparatus with a full facepiece (APF = 50)
OR Any supplied -air respirator with a full facepiece (APF = 50)
EMERGENCY OR PLANNED ENTRY INTO UNKNOWN CONCENTRATIONS OR IDLH CONDITIONS:
Any self-contained breathing apparatus that has a full facepiece and is
operated in a pressure -demand or other positive -pressure mode (APF = 10,000)
OR Any supplied -air respirator that has a full facepiece and is operated in a
pressure -demand or other positive -pressure mode in combination with an
auxiliary self-contained breathing apparatus operated in pressure -demand or
other positive -pressure mode (APF = 10,000)
ESCAPE:
Any air -purifying, full-facepiece respirator (gas mask) with a chin -style,
front- or back -mounted canister providing protection against the compound of
concern (APF = 50)
OR Any appropriate escape -type, self-contained breathing apparatus
*** PERSONAL PROTECTION AND SANITATION ***
SKIN PROTECTION :
Wear appropriate personal protective clothing to prevent skin contact.
EYE PROTECTION :
Wear appropriate eye protection to prevent eye contact.
SKIN CLEAN-UP :
The worker should immediately wash the skin when it becomes contaminated.
(solution)
CLOTHING/PPE REMOVAL :
Work clothing that becomes wet or significantly contaminated should be removed
and replaced. (solution)
CLOTHING/PPE CHANGE :
No recommendation is made specifying the need for the worker to change clothing
after the workshift.
PPE FACILITIES :
Eyewash fountains should be provided in areas where there is any possibility
that workers could be exposed to the substances; this is irrespective of the
recommendation involving the wearing of eye protection. (>10 percent),
Facilities for quickly drenching the body should be provided within the
immediate work area for emergency use where there is a possibility of exposure.
(>10 percent)
*** HEALTH HAZARDS AND FIRST AID ***
POTENTIAL ROUTES OF EXPOSURE :
Inhalation; Ingestion; (solution) Skin and/or eye contact; (solution/liquid)
POTENTIAL SYMPTOMS OF EXPOSURE :
Irritation eyes, nose, throat; dyspnea (breathing difficulty), bronchospasm,
chest pain; pulmonary edema; pink frothy sputum; skin burns, vesiculation;
liquid: frostbite
TARGET ORGANS :
Eyes, skin, respiratory system
EYES - FIRST AID :
'If this chemical contacts the eyes, immediately wash the eyes with large
amouAts of water, occasionally lifting the lower and upper lids. Get medical
attention immediately. Contact lenses should not be worn when working with
this chemical. (solution/liquid)
SKIN - FIRST AID :
If this chemical contacts the skin, immediately flush the contaminated skin
with water. If this chemical penetrates the clothing, immediately remove the
clothing and flush the skin with water. Get medical attention promptly.
(solution/liquid)
INHALATION - FIRST AID :
If a person breathes large amounts of this chemical, move the exposed person to
fresh air at once. If breathing has stopped, perform mouth-to-mouth
resuscitation. Keep the affected person warm and at rest. Get medical
attention as soon as possible.
INGESTION - FIRST AID :
If this chemical has been swallowed, get medical attention immediately.
(solution)
*** PHYSICAL AND CHEMICAL PROPERTIES ***
MOLECULAR WEIGHT
BOILING POINT
FREEZING POINT
SOLUBILITY
VAPOR PRESSURE
RELATIVE GAS DENSITY
FLASH POINT
LOWER EXPLOSIVE LIMIT
UPPER EXPLOSIVE LIMIT
IONIZATION POTENTIAL
FLAMMABILITY CLASS :
: 17.0
-28 deg F
-108 deg F
: 34 percent
: 8.5 atm
: 0.60
: Not applicable. (Gas)
: 15 percent
: 28 percent
: 10.18 eV
[Note: Although NH3 does not meet the DOT definition of a Flammable Gas (for
labeling purposes), it should be treated as one.]
INCOMPATIBILITIES AND REACTIVITIES :
Strong oxidizers, acids, halogens, salts of silver & zinc
NOTE :
Corrosive to copper & galvanized surfaces.
MEASUREMENT METHOD :
Silica gel tube with special coding; Water; Visible spectrophotometry; NIOSH
Manual of Analytical Methods (NMAM), 4th edition #6015 Also #6016
*** END OF RECORD ***
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Chemical Database - Response Information Data Sheet
'Preferred Name: AMMONIA, [ANHYDROUS]
is out. Isolate area until gas has dispersed. (EPA, 1990)
Protective Clothing
For emergency situations, wear a positive pressure, pressure -demand, full facepiece
self-contained breathing apparatus (SCBA) or pressure- demand supplied air respirator
with escape SCBA and a fully -encapsulating, chemical resistant suit. ((c)EPA, 1990)
MATERIAL RATINGS
BARRICADE
FABRIC 1-3 hours
BUTYL
FABRIC > 3 hours
GLOVES > 3 hours
BUTYL/NEOP
FABRIC > 3 hours
CHECKMATE
FABRIC > 3 hours
CHEMREL
FABRIC < 1 hour
CHEMREL MAX
FABRIC > 3 hours
CPE
FABRIC 1-3 hours
CPF III
FABRIC < 1 hour
FEP TEFLON
FACESHIELD > 3 hours
INTERCEPTOR
FABRIC > 3 hours
02/11/99
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Chemical Database - Response Information Data Sheet
Preferred Name: AMMONIA, [ANHYDROUS]
NAT RUB
FABRIC < 1 hour
NEOP
FABRIC 1-3 hours
GLOVES > 3 hours
BOOTS > 3 hours
NEOP/BUTYL
GLOVES > 3 hours
NIT+POLYURETHANE+PVC
BOOTS > 3 hours
NITRILE
GLOVES > 3 hours
PE
FABRIC < 1 hour
POLYURETHANE
FABRIC < 1 hour
PTFE TEFLON
FABRIC < 1 hour
PVC
FABRIC < 1 hour
RESPONDER
FSC > 3 ho rs-
SARANEX23P
FABRIC < 1 hour
VITON
FABRIC < 1 hour
VITON/NEOP
02/11/99
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Chemical Database - Response Information Data Sheet
`Preferred Name: AMMONIA, [ANHYDROUS]
FABRIC > 3 hours
Non -Fire Response
Keep material out of water sources and sewers. Attempt
personnel hazard. Use' water spray to knock -down vapors.
corrosive or toxic and should be diked for containment.
lagoon, holding area to contain liquid or solid material
soil, sand bags, foamed polyurethane, or foamed concrete
ash or cement powder. Neutralize with vinegar or other
Neutralize with dilute acid. Use mechanical dredges or
masses of pollutants and precipitates. ((c) AAR, 1991)
to stop leak if without undue
Vapor knockdown water is
Land spill: Dig a pit, pond,
. Dike surface flow using
▪ Absorb bulk liquid with fly
dilute acid. Water spill:
lifts to remove immobilized
Health Hazard
Vapors cause irritation of eyes and respiratory tract. Liquid will burn
Poisonous; may be fatal if inhaled. Contact may cause burns to skin and
with liquid may cause frostbite. (EPA, 1990)
Properties
Flash Point: Not Applicable. Not flammable under conditions
encountered. (USCG, 1991)
Lower Exp Limit: 16 % (EPA, 1990)
Upper Exp Limit: 25 % (EPA, 1990)
Auto Igtn Temp: 1204 F (USCG, 1991)
Melting Point: -107.9 F (EPA, 1990)
Vapor Pressure: 400 mm at -49.72 F (EPA, 1990)
Vapor Density (air = 1): 0.6 (EPA, 1990)
Specific Gravity, Liquid: 0.6818 at -28.03 F (EPA, 1990)
Boiling Point: -28.03 F at 760 mm (EPA, 1990)
Molecular Weight: 17.03 (EPA, 1990)
IDLH: 300 ppm (NIOSH, 1994)
TLV TWA: 25 ppm ((c)ACGIH, 1991)
TLV STEL: 35 ppm ((c)ACGIH, 1991)
skin and eyes.
eyes. Contact
likely to be
First Aid
Warning: Ammonia is extremely corrosive to the skin, eyes, and mucous membranes.
Contact with the liquified gas may cause frostbite. Caution is advised.
Signs and Symptoms of Acute Ammonia Exposure: Inhalation of ammonia may cause
irritation and burns of the respiratory tract, laryngitis, dyspnea (shortness of
02/11/99
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Chemical Database - Response Information Data Sheet
'Preferred Name: AMMONIA, [ANHYDROUS]
breath), stridor (high-pitched respirations), and chest pain. Pulmonary edema and
pneumonia may also result from inhalation. A pink frothy sputum, convulsions, and
coma are often seen following exposure to high concentrations. When ammonia is
ingested, nausea and vomiting may result; oral, esophageal, and stomach burns are
common. If ammonia has contacted the eyes, irritation, pain, conjunctivitis (red,
inflamed eyes), lacrimation (tearing), and corneal erosion may occur. Loss of vision
is possible. Dermal exposure may result in severe burns and pain.
Emergency Life -Support Procedures: Acute exposure to ammonia may require
decontamination and life support for the victims. Emergency personnel should wear
protective clothing appropriate to the type and degree of contamination.
Air -purifying or supplied -air respiratory equipment should also be worn, as necessary.
Inhalation Exposure:
1. Move victims to fresh air. Emergency personnel should avoid self -exposure to
ammonia.
2. Evaluate vital signs including pulse and respiratory rate, and note any trauma.
If no pulse is detected, provide CPR. If not breathing, provide artificial
respiration. If breathing is labored, administer oxygen or other respiratory support.
3. Obtain authorization and/or further instructions from the local hospital for
administration of an antidote or performance of other invasive procedures.
4. Transport to a health care facility.
Dermal/Eye Exposure:
1. Remove victims from exposure. Emergency personnel should avoid self- exposure to
ammonia.
2. Evaluate vital signs including pulse and respiratory rate, and note any trauma.
If no pulse is detected, provide CPR. If not breathing, provide artificial
respiration. If breathing is labored, administer oxygen or other respiratory support.
Warning: Do not attempt to neutralize with an acid wash; excessive liberation of heat
may result.
3. If eye exposure has occurred, eyes must IMMEDIATELY be flushed with lukewarm water
for at least 15 minutes.
4. Remove contaminated clothing as soon as possible.
5. Wash exposed skin areas THOROUGHLY with soap and water.
6. Obtain authorization and/or further instructions from the local hospital for
administration of an antidote or performance of other invasive procedures.
7. Transport to a health care facility.
Ingestion Exposure:
1. Evaluate vital signs including pulse and respiratory rate, and note any trauma.
If no pulse is detected, provide CPR. If not breathing, provide artificial
respiration. If breathing is labored, administer oxygen or other respiratory support.
2. DO NOT induce vomiting or attempt to neutralize!'
3. Obtain authorization and/or further instructions from the local hospital for
administration of an antidote or performance of other invasive procedures.
4. Activated charcoal does not strongly bind ammonia, and therefore is of little or
no value.
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Chemical Database - Response Information Data Sheet
Preferred Name: AMMONIA, [ANHYDROUS]
5. Give the victims water or milk: children up to 1 year old, 125 mL (4 oz or 1/2
cup); children 1 to 12 years old, 200 mL (6 oz or 3/4 cup); adults, 250 mL (8 oz or 1
cup). Water or milk should be given only if victims are conscious and alert.
6. Transport to a health care facility. (EPA, 1990)
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Chemical Database - Response Information Data Sheet
Preferred Name: AMMONIA, [ANHYDROUS]
Regulatory Name:AMMONIA
AMMONIA (ANHYDROUS)
Chemical Source:NOEPA NOAA #:4860
NFPA Codes F: 1 - Must be preheated to burn
H: 3 - Extremely hazardous - use full protection
R: 0 - Normally stable
S:
General Description
Anhydrous ammonia is a clear colorless gas with a characteristic odor. It is used as
a fertilizer, as a refrigerant, and in the manufacture of other chemicals. Although
it is classed as a nonflammable gas, it will burn within certain vapor concentration
limits, and the fire hazard will increase in the presence of oil or other combustible
materials. Its "combustibility" is definitely not a common problem in the event of
leakage. It is shipped as a liquid under pressure. Contact with the liquid can cause
frostbite. It is soluble in water forming a corrosive liquid. Although ammonia is
lighter than air, the vapors from a leak initially hug the ground. It weighs 6
lbs/gallon. Long term exposure to low concentrations or short term exposure to high
concentrations can result in adverse health effects from inhalation. ((c) AAR, 1991)
Fire Hazard
Mixing of ammonia with several chemicals can cause severe fire hazards and/or
explosions. Ammonia in container may explode in heat of fire.
Incompatible with many materials including silver and gold salts, halogens, alkali
metals, nitrogen trichloride, potassium chlorate, chromyl chloride, oxygen halides,
acid vapors, azides, ethylene oxide, picric acid and many other chemicals. Mixing with
other chemicals and water. Hazardous polymerization may not occur.
(EPA, 1990)
Fire Fighting
Wear positive pressure breathing apparatus and full protective clothing.
Small fires: dry chemical or carbon dioxide. Large fires: water spray, fog or foam.
Apply water gently to the surface. Do not get water inside container. Move container
from fire area if you can do it without risk. Stay away from ends of tanks. Cool
containers that are exposed to flames with water from the side until well after fire
02/11/99
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